CN109641176A - 用于从富氢气体中除去有机硫化合物的方法和装置 - Google Patents

用于从富氢气体中除去有机硫化合物的方法和装置 Download PDF

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Publication number
CN109641176A
CN109641176A CN201780052048.9A CN201780052048A CN109641176A CN 109641176 A CN109641176 A CN 109641176A CN 201780052048 A CN201780052048 A CN 201780052048A CN 109641176 A CN109641176 A CN 109641176A
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CN
China
Prior art keywords
hydrogen
gas
catalyst
rich gas
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201780052048.9A
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English (en)
Chinese (zh)
Inventor
迈克尔·列赫尔
霍尔格·蒂勒特
伊娃·斯比尔曼斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
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ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
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Publication of CN109641176A publication Critical patent/CN109641176A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8603—Removing sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/002—Removal of contaminants
    • C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
    • C10K1/004—Sulfur containing contaminants, e.g. hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/34—Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B01D2251/102—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/202—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/10—Noble metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/306—Organic sulfur compounds, e.g. mercaptans
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/30—Sulfur compounds
    • B01D2257/308—Carbonoxysulfide COS
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C01B2203/045—Purification by catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Industrial Gases (AREA)
  • Hydrogen, Water And Hydrids (AREA)
CN201780052048.9A 2016-09-01 2017-08-25 用于从富氢气体中除去有机硫化合物的方法和装置 Pending CN109641176A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102016116306.6 2016-09-01
DE102016116306.6A DE102016116306A1 (de) 2016-09-01 2016-09-01 Verfahren und Vorrichtung zum Entfernen von organischen Schwefelverbindungen aus wasserstoffreichen Gasen
PCT/EP2017/071397 WO2018041728A1 (de) 2016-09-01 2017-08-25 Verfahren und vorrichtung zum entfernen von organischen schwefelverbindungen aus wasserstoffreichen gasen

Publications (1)

Publication Number Publication Date
CN109641176A true CN109641176A (zh) 2019-04-16

Family

ID=59738333

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780052048.9A Pending CN109641176A (zh) 2016-09-01 2017-08-25 用于从富氢气体中除去有机硫化合物的方法和装置

Country Status (7)

Country Link
EP (1) EP3506995A1 (de)
JP (1) JP2019529306A (de)
KR (1) KR102242266B1 (de)
CN (1) CN109641176A (de)
DE (1) DE102016116306A1 (de)
UA (1) UA123236C2 (de)
WO (1) WO2018041728A1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114196449A (zh) * 2021-12-08 2022-03-18 浙江三龙催化剂有限公司 高炉煤气的前脱硫工艺及其应用
CN116462159A (zh) * 2023-05-11 2023-07-21 清华大学 氢气提纯系统及方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB340016A (en) * 1929-09-16 1930-12-16 Ig Farbenindustrie Ag A process for the catalytic desulphurization of gases
JPS59232175A (ja) * 1983-06-16 1984-12-26 Tokyo Gas Co Ltd ガスの精製法
US4505880A (en) * 1982-05-25 1985-03-19 Institut Francais Du Petrole Process for the hydrodesulfurization and deoxygenation of a gas containing oxygen and organic sulfur compounds
JPS6189294A (ja) * 1984-10-09 1986-05-07 Kawasaki Steel Corp コ−クス炉ガスの精製法
JPH04106194A (ja) * 1990-08-27 1992-04-08 Kawasaki Steel Corp コークス炉ガスの精製方法
CN102497919A (zh) * 2009-09-15 2012-06-13 约翰森·马瑟公开有限公司 脱硫方法
CN102548642A (zh) * 2009-09-29 2012-07-04 普莱克斯技术有限公司 用于从炼油厂废气中去除硫的方法
CN103372369A (zh) * 2012-04-13 2013-10-30 中国石油化工股份有限公司 一种脱除合成气中微量杂质的方法及合成气的应用

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1545470A1 (de) 1966-10-05 1970-02-05 Pichler Dr Phil Helmut Verfahren zur Umwandlung von Koksofengas in ein gegen Erdgas austauschbares Gas
US4041130A (en) 1975-12-29 1977-08-09 The Ralph M. Parsons Company Process for desulfurization of coke oven gas
JPS57151693A (en) * 1981-03-13 1982-09-18 Jgc Corp Production of town gas from solid waste
JPS5849604A (ja) * 1981-09-21 1983-03-23 Kansai Coke & Chem Co Ltd コ−クス炉ガスの精製法
JPS59232174A (ja) * 1983-06-16 1984-12-26 Tokyo Gas Co Ltd コ−クス炉ガスの精製法
JPS61186203A (ja) * 1985-02-15 1986-08-19 Tokyo Gas Co Ltd コ−クス炉ガスの精製方法
NL185225C (nl) 1988-01-13 1992-03-16 Comprimo Bv Werkwijze voor het omzetten en verwijderen van zwavelverbindingen uit een co-bevattend gas.
FR2758278B1 (fr) * 1997-01-15 1999-02-19 Inst Francais Du Petrole Catalyseur comprenant un sulfure mixte et utilisation en hydroraffinage et hydroconversion d'hydrocarbures
CA2372652A1 (en) 2001-02-21 2002-08-21 Paul S. Wallace Utilization of cos hydrolysis in high pressure gasification
FR2823193B1 (fr) 2001-04-04 2004-02-13 Pro Catalyse Agglomeres d'alumine, leur procede de preparation, et leurs utilisations comme support de catalyseur, catalyseur ou absorbant
FR2823194B1 (fr) 2001-04-10 2004-02-13 Pro Catalyse Agglomeres d'alumine utilisables, notamment, comme supports de catalyseur, catalyseurs ou adsorbants, et leurs procedes de preparation
DE102011105353A1 (de) 2011-06-22 2012-12-27 Süd-Chemie AG Multifunktionaler Katalysator zur simultanen Entfernung/Umwandlung von teerartigen und schwefelhaltigen Kohlenwasserstoffen
DE102013009885A1 (de) 2013-01-09 2014-07-10 Thyssenkrupp Uhde Gmbh Verfahren zur Herstellung von Synthesegas aus Steinkohle

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB340016A (en) * 1929-09-16 1930-12-16 Ig Farbenindustrie Ag A process for the catalytic desulphurization of gases
US4505880A (en) * 1982-05-25 1985-03-19 Institut Francais Du Petrole Process for the hydrodesulfurization and deoxygenation of a gas containing oxygen and organic sulfur compounds
JPS59232175A (ja) * 1983-06-16 1984-12-26 Tokyo Gas Co Ltd ガスの精製法
JPS6189294A (ja) * 1984-10-09 1986-05-07 Kawasaki Steel Corp コ−クス炉ガスの精製法
JPH04106194A (ja) * 1990-08-27 1992-04-08 Kawasaki Steel Corp コークス炉ガスの精製方法
CN102497919A (zh) * 2009-09-15 2012-06-13 约翰森·马瑟公开有限公司 脱硫方法
CN102548642A (zh) * 2009-09-29 2012-07-04 普莱克斯技术有限公司 用于从炼油厂废气中去除硫的方法
CN103372369A (zh) * 2012-04-13 2013-10-30 中国石油化工股份有限公司 一种脱除合成气中微量杂质的方法及合成气的应用

Also Published As

Publication number Publication date
DE102016116306A1 (de) 2018-03-01
UA123236C2 (uk) 2021-03-03
EP3506995A1 (de) 2019-07-10
WO2018041728A1 (de) 2018-03-08
KR102242266B1 (ko) 2021-04-21
KR20190041520A (ko) 2019-04-22
JP2019529306A (ja) 2019-10-17

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Inventor after: Michael Lehr

Inventor after: Holger Thielert

Inventor after: Eva Camp

Inventor before: Michael Lehr

Inventor before: Holger Thielert

Inventor before: Eva Spermans

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