CN109629235A - Superfine mulberry silk fiber silk scarf fabrics - Google Patents
Superfine mulberry silk fiber silk scarf fabrics Download PDFInfo
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- CN109629235A CN109629235A CN201811555503.XA CN201811555503A CN109629235A CN 109629235 A CN109629235 A CN 109629235A CN 201811555503 A CN201811555503 A CN 201811555503A CN 109629235 A CN109629235 A CN 109629235A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D23/00—Scarves; Head-scarves; Neckerchiefs
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic System; Aluminates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
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- Life Sciences & Earth Sciences (AREA)
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- General Chemical & Material Sciences (AREA)
- Woven Fabrics (AREA)
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Abstract
The invention discloses a kind of superfine mulberry silk fiber silk scarf fabrics, preparation method specifically includes starching processing, after winder and silk is twisted, weaving and refining processing, the chiffon fabric of experienced white superfine mulberry silk fiber prepared by the present invention is not easy to break end when having weaving, cloth cover is smooth, and cloth cover is soft and frivolous, cloth cover elasticity is good the feature low with washing shrinkage.In addition, the strong operability of the processing method, is suitble to industrialized production, and production cost is low.
Description
Technical field
The invention belongs to field of fabric producing technology, and in particular to a kind of superfine mulberry silk fiber silk scarf fabrics.
Background technique
The most of scarf are the long scarves being trapped among in neck, and the method for production has woven, woollen yarn knitting etc. by hand, material with
Based on silk and wool, the sense of touch of silk scarf is smooth, with soft, frivolous, elasticity is good, washing shrinkage is low, slides as silk
The feature of the feel and pendency sense of feeling well soft.Prior art discloses the manufacture crafts of silk chiffon fabric, first true by 7-10 strands
Silk fiber and 1-2 strands of elastomers add Z to twist, and add Z to twist 6-9 strands of cocoon fibers and 2-3 strands of elastomers, then warp and weft are handed over
Fork weaving, intersecting angle are 20-40 degree, prepare silk chiffon fabric.
Silk has the characteristics that elongated, soft, moisture absorption, good luster, traditional silk (four moultinism silks or five dormancy age silkworms
Silk) wrinkle resistance is poor, it is unable to fabric ultrathin type silk and product；The method of existing modified silk fiber is the three moultinism product that are bred as
Kind silkworm, such as dawn, SG, 305, production fiber number are about the silk of 2.0 daniers；It is bred as three moultinism kind silkworm of mutagenesis, uses drug
By common four moultinisms silk mutagenesis at three molt silkworms, silk ultra-fine is produced；Or with " ultra-fine element " (the chloro- N- phenylimidazole of 2,4- bis-)
Four molt silkworms, three dormancyization is induced, silk ultra-fine is produced；Or be uniformly sprayed on mulberry leaf surface with anti-JH and add food to silkworm, make
Common four dormancies silkworm, three dormancyization produces silk ultra-fine.But since ultrafine mulberry silk fiber number is small, fibre strength is lower, therefore,
And silk twisting process in because the problem of strength, frequent fracture of wire, in addition due to through to tension and steel during looming weaving
The factor of reed friction often breaks end, is not used to produce.
Summary of the invention
To solve the above problems, the invention discloses a kind of superfine mulberry silk fiber silk scarf fabrics, preparation method
The following steps are included:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to silk fiber and broadwise silk fiber；Then
It will be through being woven as mulberry silk fiber chiffon fabric to silk fiber and broadwise silk fiber；
(3) mulberry silk fiber chiffon fabric successively passes through desizing treatment, enzymatic treatment and hot water treatment, then dries, and obtains ultra-fine
Mulberry silk fiber silk scarf fabrics.
A kind of preparation method of superfine mulberry silk fiber silk scarf fabrics, comprising the following steps:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to silk fiber and broadwise silk fiber；Then
It will be through being woven as mulberry silk fiber chiffon fabric to silk fiber and broadwise silk fiber；
(3) mulberry silk fiber chiffon fabric successively passes through desizing treatment, enzymatic treatment and hot water treatment, then dries, and obtains ultra-fine
Mulberry silk fiber silk scarf fabrics.
A kind of superfine mulberry silk fiber silk scarf preparation method of starching ultrafine mulberry silk, includes the following steps, will
Ultra-fine Raw Silk impregnates by water-soluble poly ester polyether slurry, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, receives
The starching solution that rice corpuscles, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain ultra-fine silkworm
Silk fiber silk scarf starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea.
A kind of superfine mulberry silk fiber silk scarf preparation method of raw silk starching solution, includes the following steps, by water
Dissolubility polyester polyethers slurry, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, nanoparticle, adhesive SD28, ginger
Flavine and water mixing composition superfine mulberry silk fiber silk scarf raw silk starching solution；The nanoparticle is by nano oxidized
Yttrium, boric acid, urea are prepared.
In the present invention, water-soluble poly ester polyether slurry, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, bonding
Agent SD28, curcumin are all existing product, wherein water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azepine
Cycloheptyl -2- ketone, curcumin are commercial products, for example water-soluble poly ester polyether slurry SH, adhesive SD28 are open product.This hair
It is bright to configure new size composition using these open substances, silk ultra-fine fiber is surface-treated, can be increased ultra-fine
The intensity of silk fiber, make its and silk twisting process and looming weaving during avoid being broken, water-soluble poly ester polyether slurry
Material is as basic processes composition, its dispersibility can be improved in turkey red oil, and the guess of 1- orthododecyl nitrogen heterocyclo heptane-2-ketone can
To increase organic matter in the even flat effect on superfine mulberry silk fiber surface, adhesive improves the bonding force of organic component, curcumin
Size composition especially nanoparticle should be can be further improved in the combination effect of fiber surface.It is organic with existing routine
Object slurry is different, and the present invention is directed to special superfine mulberry silk fiber, has developed nanoparticle, preparation method is, by urea
It being dispersed in water, boric acid and ethyl alcohol is then added, nano yttrium oxide is added after stirring, stirring removed solvent after 2~2.5 hours,
Obtain solids, then by solids under nitrogen, 950~1000 DEG C calcine 5 hours, obtain nanoparticle using crushing.
Nanoparticle is not directly used in starching by any surface treatment, on the one hand since surface treatment does not have effect to silk gum, separately
On the one hand also avoid the coupling agent of surface treatment to the unfavorable of paste compound and to the unfavorable of subsequent desizing, generally without place
The nanoparticle application effect of reason is poor, this is common sense, and the present invention is using turkey red oil and 1- positive dodecyl aza cyclohepta-
2- ketone is added in water-soluble poly ester polyether slurry, it is evident that the dispersibility that nanoparticle can be improved, it is several in conjunction with curcumin
Additive effectively improves nanoparticle in the attachment on superfine mulberry silk fiber surface.Fibre can be improved using nanoparticle in the present invention
The tensile strength of dimension, more important is avoid the residual to silk gum in desizing processes, improve desizing effect.
In the present invention, nano yttrium oxide, boric acid, urea mass ratio be 50: 65: 100；In starching solution, water-soluble poly
The mass fraction of ester polyether slurry is 10%~20%, and the mass fraction of turkey red oil is 0.4%~0.6%, 1- dodecyl
The mass fraction of azacyclo- hept- 2- ketone is 0.2%~0.5%, and the mass fraction of adhesive SD28 is 3%~5%, the matter of nanoparticle
Measuring score is 3~3.3%, and the mass fraction of curcumin is 2~2.2%, remaining is water.Ultra-fine silkworm can be improved in such proportion
The effect of impregnation of silk fiber, so that size composition is uniformly dispersed in fiber surface, in terms of embodiment effect, ultrafine mulberry silk is fine
The tensile strength of dimension is improved, and desizing effect is good.
In the present invention, starching handle when, bath raio be 1:5~1:10, temperature be 30 DEG C~40 DEG C, the time be 25min~
30min；After the completion of starching, ultrafine mulberry silk is dry in hot-air drying device after centrifugal dehydration, obtains the ultra-fine mulberry of starching
Silk.
In the present invention, the specification of ultra-fine Raw Silk is 9/11D, by the ultra-fine silkworm list that fiber number is 1.0~1.2 daniers
Silk filature obtains, and is existing product, and raw silk is by filature by product made of the mutual obvolvent of several Bombyx-mori Baves, and fine denier is raw
Silk weaving at fabric have wrinkle resistance it is strong, rich in the characteristics such as gloss, dyeing effect be good, but the prior art has no with this fineness
Report of the mulberry silk as scarf fabrics, main cause is exactly that mechanical strength described in background is too low, and the present invention passes through starching
Processing solves existing technical problem.
In the present invention, winder, simultaneously silk twisting and weaving can carry out network originally as the prior art on slack winder
Cylinder processing carries out simultaneously silk twisting processing on simultaneously silk twisting mill, is weaved on loom；The present invention is preferably through to silk fiber
For 4/9/11D mulberry silk 14T/2S2Z, broadwise silk fiber is 2/9/11D mulberry silk 18T/2S2Z.Mulberry silk of the present invention
Fiber chiffon fabric is plain weave, and through being 48/10cm to density, latitudinal density is 51/10cm.The product of this specification
In desizing, effect is fine, and obtained fabric warmth retention property is good, wrinkle resistance is excellent.
In the present invention, desizing treatment carries out in desizing solution, and enzymatic treatment carries out in enzyme solutions, and hot water treatment is in hot water
It is carried out in solution；In desizing solution, the mass fraction of sodium carbonate is 1.5%~2.0%, remaining is water, and the bath raio of desizing treatment is
1:30, temperature are 80 DEG C~85 DEG C, and the time is 30 min~60min；In enzyme solutions, the mass fraction of alkali protease is 0.2%
~0.5%, the mass fraction of sodium sulphate is 0.1%~0.2%, and the mass fraction of sodium carbonate is 0.5%, remaining is water, enzymatic treatment
Bath raio is 1:30, and temperature is 55 DEG C~65 DEG C, and the time is 60 min~90min；In hydrothermal solution, the mass fraction of acetic acid is
0.2%~0.3%, remaining is water, and the bath raio of hot water treatment is 1:30, and temperature is 90 DEG C, and the time is 30 min.After the completion of processing,
Drying and processing is carried out in single roller blanket equipment, superfine mulberry silk fiber silk scarf fabrics are made, to practice white superfine silkworm
Silk fiber fabric.The effect of this step is removal silk gum, and then embodies the excellent properties of silk fiber, such as warming, soft, anti-
Wrinkle, the present invention is using three step process and provides processing solution and Parameter Conditions, can cooperate starching condition, and silk gum processing is dry
Only, optimum performance is provided for silk fabric.
Compared with thick denier (filament number is 2.6~3.0 daniers) silk, fine-denier (1.0~1.2 danier of monofilament) silk
Refractive property it is more preferable, reflecting feel is strong, and pendency sense is strong, can improve the smooth and elastic of squeeze, and dyeing and printing products are bright in luster
Degree is preferable.But since ultrafine mulberry silk fiber number is small, fibre strength is lower.Therefore, because of strength in simultaneously silk twisting process
Problem, frequent fracture of wire, in addition due to often breaking end through the factor to tension and reed friction during looming weaving, it can not
For producing.Therefore, improve the sizing technique of fine-denier silk, improve ultrafine mulberry silk strength and cohesive force, be prepare it is ultra-fine true
The key technology of silk chiffon fabric.
The present invention improves strength of raw silk by starching processing, and the scarf fabrics of preparation have the function of wear-resisting, high-strength, increase
The service life of scarf fabrics can effectively remove silk gum by refining treatment, so that scarf fabrics have good warmth retention property
Energy；The mulberry silk that the present invention uses intensity originally relatively low is raw material, and in conjunction with preparation process, not only wool type is rich for manufactured scarf fabrics
Full, warming moisture-absorbing is good, luxurious, beautiful top grade ventilative to light, comfortable, and it is crease-resistant, intensity is good, harmless to human skin.
Compared with prior art, the sizing technique that the present invention limits improves the intensity of fiber, hence it is evident that reduces ultra-fine mulberry
Silk fiber the phenomenon that fracture of wire frequent occurrence, improves the cohesive force of superfine mulberry silk fiber in simultaneously silk twisting process, increases
Lubricity；It in concise scouring processes, can remove completely, not influence the service performance of mulberry silk fiber, especially starching and handle
Effect is also improved to the silk performance after degumming, estimation is swollen in soaking process silk gum, and inorganic agent is allowed to have a little infiltration
Effect thoroughly, in conjunction with desizing, the process of enzymatic treatment hot water treatment, obtained superfine mulberry silk fiber silk scarf fabrics gas permeability
And warmth retention property is preferable；And the strong operability of processing method of the present invention, it is suitble to industrialized production, processing cost is low.
Specific embodiment
The invention patent is further described below with reference to embodiment:
Polyester polyethers slurry SH, turkey red oil, 1- orthododecyl nitrogen heterocyclo heptane-2-ketone, curcumin are commercially available, open produce
Product, adhesive are commercial product, such as adhesive SD28, adhesive HD.
Synthesis example
10Kg urea is dispersed in 30 liters of water, 13Kg boric acid and 50L ethyl alcohol is then added, it is nano oxidized that 20Kg is added after stirring
Yttrium stirs 2.5 hours back spins and boils off except solvent, obtains solids, then by solids under nitrogen, 950 DEG C calcine 5 hours,
Nanoparticle is obtained using crushing, aerodynamic particle size is between 500~700 nanometers.
Embodiment one
On cone dyeing machine, by 9/11D superfine mulberry silk fiber cheese, (raw silk is 1.0~1.2 daniers by fiber number
Ultra-fine silkworm monofilament filature obtains, breaking strength 0.9CN/dtex) impregnate it is bis- macro by 50Kg polyester polyethers slurry SH(), 2 Kg it is native
Ear its red oil, 2Kg 1- orthododecyl nitrogen heterocyclo heptane-2-ketone (letter health), 15 Kg adhesive SD28,16Kg nanoparticles,
The starching solution of 10Kg curcumin and 405Kg water mixing composition, bath raio 1:8,30 DEG C of soaking temperature, soaking time 30min.Starching
After the completion, it is dehydrated on centrifugal dehydrator, then, is dried in hot wind drying plant, the silk fiber cheese dried,
For starching ultrafine mulberry silk (breaking strength 2.1CN/dtex).
The silk fiber cheese of above-mentioned drying is subjected to winder processing on slack winder, then in simultaneously silk twisting mill
It is upper to carry out and silk twisting processing, it prepares through to silk fiber and broadwise silk fiber；Wherein through being 4/9/11D to silk fiber
Mulberry silk 14T/2S2Z, broadwise silk fiber are 2/9/11D mulberry silk 18T/2S2Z.It will be through to silk fiber and latitude on loom
Prepare mulberry silk fiber chiffon fabric to silk fiber weaving, obtained mulberry silk fiber chiffon fabric be plain weave, through to
Density is 48/10cm, and latitudinal density is 51/10cm；Starching ultrafine mulberry silk is in addition to improving filament strength in monofilament surface
Except, the cohesive force also between increase monofilament, the two, which combines, effectively increases strength of raw silk, solves existing ultra-fine raw silk and adds in simultaneously silk
Because of the problem of strength frequent fracture of wire during twirl, due to through the factor to tension and reed friction during looming weaving,
Often broken end is not used to the problem of producing, and entire production process is smooth, no fracture, if directly using 9/11D ultrafine mulberry silk
Fracture of wire situation then occurs for fiber package yarn and silk twisting, and weaving process is even more broken end problem occur.Raw silk fracture is stretched before and after starching
Long rate is 15.23%, 16.62%, and elongation at break can be used as the indirect indexes for measuring silk fiber flexibility, illustrates place of the present invention
The raw silk deformability of reason is more preferable, than having better flexibility before handling.
It hangs and practices in slot in silk, above-mentioned mulberry silk fiber chiffon fabric is impregnated by 46 Kg sodium carbonate and 2955Kg water group
At desizing solution, bath raio 1:30 is warming up to 85 DEG C, and handles 50min at this temperature, after the completion of processing, drain；It is added
The enzymatic treatment liquid that 6 Kg alkali proteases, 5Kg sodium sulphate, 15Kg sodium carbonate and 2974Kg water form, bath raio 1:30 are warming up to
60 DEG C, and 90min is handled at this temperature, after the completion of processing, drain；Addition 7Kg acetic acid and 2993Kg water, bath raio 1:30,
90 DEG C are warming up to, and handles 30min at this temperature.After the completion of processing, successively washed with 80 DEG C, 60 DEG C, then wash 3 with cold water
Time, drying processing is finally carried out in single roller blanket equipment, and superfine mulberry silk fiber silk scarf fabrics, chiffon fabric is made
Unit area weight be 25.8 grams/m, thickness 0.98mm；Soft, wrinkling resistance is good, is made with turnaround time after folding
For the auxiliary characteristics for characterizing wrinkling resistance, the scarf fabrics prepared after starching improve 48% compared with scarf fabrics prepared by non-starching；It adopts
It is tested with gas permeability of the fabric air-permeability amount instrument to scarf fabrics, 3 average out to 352mm/S, using flat insulation instrument pair
Scarf fabrics carry out heat preservation rate test, and 3 average out to 22.8% illustrate that fabric of the invention has preferable gas permeability and keeps warm
Effect；The scarf fabrics warmth retention property and gas permeability of non-starching preparation are poor, respectively 20.1%, 319 mm/S.Directly adopt grain
Diameter boron nitride nanometer particle between 400~500 nanometers replaces above-mentioned nanoparticle, and obtained starching ultrafine mulberry silk fracture is strong
1.7CN/dtex is spent, elongation at break 16.03, guess is since nanoparticle prepared by the present invention is irregular, in silk gum swelling
When may be easier in conjunction with fiber.
Comparative example one
On cone dyeing machine, by 9/11D superfine mulberry silk fiber cheese, (raw silk is 1.0~1.2 daniers by fiber number
Ultra-fine silkworm monofilament filature obtains, breaking strength 0.9CN/dtex) impregnate it is bis- macro by 50Kg polyester polyethers slurry SH(), 2 Kg it is native
Ear its red oil, 2Kg 1- orthododecyl nitrogen heterocyclo heptane-2-ketone (letter health), 15 Kg adhesive SD28,10Kg curcumins and
The starching solution of 421Kg water mixing composition, bath raio 1:8,30 DEG C of soaking temperature, soaking time 30min.After the completion of starching, from
It is dehydrated on heart dewaterer, then, is dried in hot wind drying plant, the silk fiber cheese dried is that starching is ultra-fine
Mulberry silk (breaking strength 1.7CN/dtex, elongation at break 15.99%).By the silk fiber cheese of above-mentioned drying in pine
Winder processing is carried out on formula bobbin-winding machine, then and silk twisting mill on carry out and silk twisting processing, prepare through to silk fiber
With broadwise silk fiber；Wherein through being 4/9/11D mulberry silk 14T/2S2Z to silk fiber, broadwise silk fiber is 2/9/11D
Mulberry silk 18T/2S2Z.It will be through preparing mulberry silk fiber chiffon face to silk fiber and broadwise silk fiber weaving on loom
Material, obtained mulberry silk fiber chiffon fabric be plain weave, through to density be 48/10cm, latitudinal density be 51/
10cm；Entire production process is broken, than directly using 9/11D superfine mulberry silk fiber cheese and silk twisting generation fracture of wire feelings
Condition is few.
It hangs and practices in slot in silk, above-mentioned mulberry silk fiber chiffon fabric is impregnated by 46 Kg sodium carbonate and 2955Kg water group
At desizing solution, bath raio 1:30 is warming up to 85 DEG C, and handles 50min at this temperature, after the completion of processing, drain；It is added
The enzymatic treatment liquid that 6 Kg alkali proteases, 5Kg sodium sulphate, 15Kg sodium carbonate and 2974Kg water form, bath raio 1:30 are warming up to
60 DEG C, and 90min is handled at this temperature, after the completion of processing, drain；Addition 7Kg acetic acid and 2993Kg water, bath raio 1:30,
90 DEG C are warming up to, and handles 30min at this temperature.After the completion of processing, successively washed with 80 DEG C, 60 DEG C, then wash 3 with cold water
Time, drying processing is finally carried out in single roller blanket equipment, and superfine mulberry silk fiber silk scarf fabrics, chiffon fabric is made
Unit area weight be 25.8 grams/m, thickness 0.98mm；It is soft, it is crease-resistant using turnaround time after folding as characterizing
The auxiliary characteristics of ability, the scarf fabrics prepared after starching improve 29% compared with scarf fabrics prepared by non-starching；The scarf face of preparation
Expect that warmth retention property and gas permeability are poor, respectively 21.9%, 338 mm/S.
Comparative example two
On cone dyeing machine, by 9/11D superfine mulberry silk fiber cheese, (raw silk is 1.0~1.2 daniers by fiber number
Ultra-fine silkworm monofilament filature obtains, breaking strength 0.9CN/dtex) impregnate it is bis- macro by 50Kg polyester polyethers slurry SH(), 2 Kg it is native
Ear its red oil, 2Kg 1- orthododecyl nitrogen heterocyclo heptane-2-ketone (letter health), 15 Kg adhesive SD28,16Kg nanoparticles and
The starching solution of 415Kg water mixing composition, bath raio 1:8,30 DEG C of soaking temperature, soaking time 30min.After the completion of starching, from
It is dehydrated on heart dewaterer, then, is dried in hot wind drying plant, the silk fiber cheese dried is that starching is ultra-fine
Mulberry silk (breaking strength 1.5CN/dtex, elongation at break 16.23%).By the silk fiber cheese of above-mentioned drying in pine
Winder processing is carried out on formula bobbin-winding machine, then and silk twisting mill on carry out and silk twisting processing, prepare through to silk fiber
With broadwise silk fiber；Wherein through being 4/9/11D mulberry silk 14T/2S2Z to silk fiber, broadwise silk fiber is 2/9/11D
Mulberry silk 18T/2S2Z.It will be through preparing mulberry silk fiber chiffon face to silk fiber and broadwise silk fiber weaving on loom
Material, obtained mulberry silk fiber chiffon fabric be plain weave, through to density be 48/10cm, latitudinal density be 51/
10cm；Entire production process is broken, than directly using 9/11D superfine mulberry silk fiber cheese and silk twisting generation fracture of wire feelings
Condition is few.
It hangs and practices in slot in silk, above-mentioned mulberry silk fiber chiffon fabric is impregnated by 46 Kg sodium carbonate and 2955Kg water group
At desizing solution, bath raio 1:30 is warming up to 85 DEG C, and handles 50min at this temperature, after the completion of processing, drain；It is added
The enzymatic treatment liquid that 6 Kg alkali proteases, 5Kg sodium sulphate, 15Kg sodium carbonate and 2974Kg water form, bath raio 1:30 are warming up to
60 DEG C, and 90min is handled at this temperature, after the completion of processing, drain；Addition 7Kg acetic acid and 2993Kg water, bath raio 1:30,
90 DEG C are warming up to, and handles 30min at this temperature.After the completion of processing, successively washed with 80 DEG C, 60 DEG C, then wash 3 with cold water
Time, drying processing is finally carried out in single roller blanket equipment, and superfine mulberry silk fiber silk scarf fabrics, chiffon fabric is made
Unit area weight be 25.8 grams/m, thickness 0.98mm；It is soft, it is crease-resistant using turnaround time after folding as characterizing
The auxiliary characteristics of ability, the scarf fabrics prepared after starching improve 35% compared with scarf fabrics prepared by non-starching；Using fabric air-permeability
Amount instrument the gas permeability of scarf fabrics is tested, 3 average out to 343mm/S, using flat insulation instrument to scarf fabrics into
The test of row heat preservation rate, 3 average out to 22.2%.
Comparative example three
On cone dyeing machine, by 9/11D superfine mulberry silk fiber cheese, (raw silk is 1.0~1.2 daniers by fiber number
Ultra-fine silkworm monofilament filature obtains, breaking strength 0.9CN/dtex) impregnate it is bis- macro by 50Kg polyester polyethers slurry SH(), 2 Kg it is native
Ear its red oil, 2Kg 1- orthododecyl nitrogen heterocyclo heptane-2-ketone (letter health), 15 Kg adhesive SD28,16Kg nanoparticles,
The starching solution of 10Kg curcumin and 405Kg water mixing composition, bath raio 1:8,30 DEG C of soaking temperature, soaking time 30min.Starching
After the completion, it is dehydrated on centrifugal dehydrator, then, is dried in hot wind drying plant, the silk fiber cheese dried,
For starching ultrafine mulberry silk.The silk fiber cheese of above-mentioned drying is subjected to winder processing on slack winder, is then existed
And carried out on silk twisting mill and silk twisting processing, it prepares through to silk fiber and broadwise silk fiber；Wherein through to silk fibroin
Dimension is 4/9/11D mulberry silk 14T/2S2Z, and broadwise silk fiber is 2/9/11D mulberry silk 18T/2S2Z.On loom will through to
Silk fiber and broadwise silk fiber weaving prepare mulberry silk fiber chiffon fabric, and obtained mulberry silk fiber chiffon fabric is flat
Line tissue, through being 48/10cm to density, latitudinal density is 51/10cm.
It hangs and practices in slot in silk, above-mentioned mulberry silk fiber chiffon fabric is impregnated by 46 Kg sodium carbonate and 2955Kg water group
At desizing solution, bath raio 1:30 is warming up to 85 DEG C, and handles 50min at this temperature, after the completion of processing, drain；It is added
7Kg acetic acid and 2993Kg water, bath raio 1:30 are warming up to 90 DEG C, and handle 30min at this temperature.After the completion of processing, successively
It is washed with 80 DEG C, 60 DEG C, then is washed 3 times with cold water, drying processing is finally carried out in single roller blanket equipment, ultra-fine silkworm is made
Silk fiber silk scarf fabrics, the unit area weight of chiffon fabric are 26.5 grams/m, thickness 0.99mm；Feel is slightly soft；
It is tested using gas permeability of the fabric air-permeability amount instrument to scarf fabrics, 3 average out to 291mm/S, using flat insulation instrument
Heat preservation rate test, 3 average out to 22.3% are carried out to scarf fabrics.
Scarf is as one of winter warming ornament, and the performances such as warming, comfortable of fabric material are increasingly by people
Attention.The fine-denier of fiber is the pursuit of the mankind, and the textile fabric used earliest is natural fiber-cotton, fiber crops, hair, silk,
Middle mulberry silk surely belongs to best one of the fiber of wears performance, no matter dress comfort or appearance in terms of have
Unique advantage.Unfortunately, ultrafine mulberry silk poor mechanical property is not used to the preparation of scarf fabrics, is easy fracture of wire, the present invention
It sets about from the simultaneously fracture of wire of silk twisting and weaving process is solved, by the combination of size composition and technique, realizes that raw silk is disconnected
The raising of resistance to spalling in production process without fracture of wire phenomenon, while improving the wrinkling resistance of finished fabric, breathable heat insulating ability.
Claims (10)
1. a kind of superfine mulberry silk fiber silk scarf fabrics, which is characterized in that the superfine mulberry silk fiber silk scarf face
The preparation method of material the following steps are included:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to silk fiber and broadwise silk fiber；Then
It will be through being woven as mulberry silk fiber chiffon fabric to silk fiber and broadwise silk fiber；
(3) mulberry silk fiber chiffon fabric successively passes through desizing treatment, enzymatic treatment and hot water treatment, then dries, and obtains ultra-fine
Mulberry silk fiber silk scarf fabrics.
2. superfine mulberry silk fiber silk scarf fabrics according to claim 1, which is characterized in that the preparation side of nanoparticle
Method is to be dispersed in water urea, and boric acid and ethyl alcohol is then added, and nano yttrium oxide is added after stirring, is stirred 2~2.5 hours
After remove solvent, obtain solids, then by solids under nitrogen, 950~1000 DEG C calcine 5 hours, using crushing
To nanoparticle.
3. superfine mulberry silk fiber silk scarf fabrics according to claim 2, which is characterized in that nano yttrium oxide, boric acid,
The mass ratio of urea is 50: 65: 100.
4. superfine mulberry silk fiber silk scarf fabrics according to claim 1, which is characterized in that water-soluble in starching solution
Property polyester polyethers slurry mass fraction be 10%~20%, the mass fraction of turkey red oil is 0.4%~0.6%, 1- positive 12
The mass fraction of alkyl azacyclo- hept- 2- ketone is 0.2%~0.5%, and the mass fraction of adhesive SD28 is 3%~5%, nanoparticle
Mass fraction be 3~3.3%, the mass fraction of curcumin is 2~2.2%, remaining is water.
5. superfine mulberry silk fiber silk scarf fabrics according to claim 1, which is characterized in that when starching is handled, bath raio
For 1:5~1:10, temperature is 30 DEG C~40 DEG C, and the time is 25min~30min；After the completion of starching, ultrafine mulberry silk is by centrifugation
It is dry in hot-air drying device after dehydration, obtain starching ultrafine mulberry silk.
6. superfine mulberry silk fiber silk scarf fabrics according to claim 1, which is characterized in that the rule of ultra-fine Raw Silk
Lattice are 9/11D, are obtained by the ultra-fine silkworm monofilament filature that fiber number is 1.0~1.2 daniers；Through being 4/9/11D to silk fiber
Mulberry silk 14T/2S2Z, broadwise silk fiber are 2/9/11D mulberry silk 18T/2S2Z；The mulberry silk fiber chiffon fabric is flat
Line tissue, through being 48/10cm to density, latitudinal density is 51/10cm.
7. superfine mulberry silk fiber silk scarf fabrics according to claim 1, which is characterized in that desizing treatment is in desizing
It is carried out in solution, in desizing solution, the mass fraction of sodium carbonate is 1.5%~2.0%, remaining is water, and the bath raio of desizing treatment is
1:30, temperature are 80 DEG C~85 DEG C, and the time is 30 min~60min.
8. superfine mulberry silk fiber silk scarf fabrics according to claim 1, which is characterized in that enzymatic treatment is in enzyme solutions
Middle progress, in enzyme solutions, the mass fraction of alkali protease is 0.2%~0.5%, the mass fraction of sodium sulphate is 0.1%~
0.2%, the mass fraction of sodium carbonate is 0.5%, remaining is water, and the bath raio of enzymatic treatment is 1:30, and temperature is 55 DEG C~65 DEG C, the time
For 60 min~90min.
9. superfine mulberry silk fiber silk scarf fabrics according to claim 1, which is characterized in that hot water treatment is in hot water
It is carried out in solution, in hydrothermal solution, the mass fraction of acetic acid is 0.2%~0.3%, remaining is water, and the bath raio of hot water treatment is 1:
30, temperature is 90 DEG C, and the time is 30 min.
10. a kind of preparation method of superfine mulberry silk fiber silk scarf fabrics, which comprises the following steps:
(1) ultra-fine Raw Silk is impregnated by water-soluble poly ester polyether slurry, turkey red oil, 1- dodecyl azacyclo-
The starching solution that hept- 2- ketone, nanoparticle, adhesive SD28, curcumin and water form carries out starching processing, then dries, obtain
To starching ultrafine mulberry silk；The nanoparticle is prepared by nano yttrium oxide, boric acid, urea；
(2) starching ultrafine mulberry silk is twisted by winder and silk, preparation is through to silk fiber and broadwise silk fiber；Then
It will be through being woven as mulberry silk fiber chiffon fabric to silk fiber and broadwise silk fiber；
(3) mulberry silk fiber chiffon fabric successively passes through desizing treatment, enzymatic treatment and hot water treatment, then dries, and obtains ultra-fine
Mulberry silk fiber silk scarf fabrics.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110499565A (en) * | 2019-07-30 | 2019-11-26 | 嘉兴市南秀丝语丝绸有限公司 | A kind of silk scarf of high color fastness |
| CN110623348A (en) * | 2019-07-30 | 2019-12-31 | 嘉兴市南秀丝语丝绸有限公司 | Silk scarf with surface brightening treatment |
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| CN103147326A (en) * | 2013-03-13 | 2013-06-12 | 盛虹集团有限公司 | Method for producing elastic silk-like chiffon fabric |
| CN103710814A (en) * | 2013-12-03 | 2014-04-09 | 浙江大学 | Extra-fine mulberry silk crepe satin plain production method |
| CN105908498A (en) * | 2016-05-18 | 2016-08-31 | 浙江钱江纺织印染有限公司 | Process of high-speed digital printing and interweaving of silks with gold and silver wires |
| CN107119454A (en) * | 2017-05-11 | 2017-09-01 | 江苏银桥纺织科技有限公司 | A kind of real silk fabric anti-crease finishing technique |
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|---|---|---|---|---|
| CN103147326A (en) * | 2013-03-13 | 2013-06-12 | 盛虹集团有限公司 | Method for producing elastic silk-like chiffon fabric |
| CN103710814A (en) * | 2013-12-03 | 2014-04-09 | 浙江大学 | Extra-fine mulberry silk crepe satin plain production method |
| CN105908498A (en) * | 2016-05-18 | 2016-08-31 | 浙江钱江纺织印染有限公司 | Process of high-speed digital printing and interweaving of silks with gold and silver wires |
| CN107119454A (en) * | 2017-05-11 | 2017-09-01 | 江苏银桥纺织科技有限公司 | A kind of real silk fabric anti-crease finishing technique |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110499565A (en) * | 2019-07-30 | 2019-11-26 | 嘉兴市南秀丝语丝绸有限公司 | A kind of silk scarf of high color fastness |
| CN110623348A (en) * | 2019-07-30 | 2019-12-31 | 嘉兴市南秀丝语丝绸有限公司 | Silk scarf with surface brightening treatment |
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Denomination of invention: Ultrafine mulberry silk fiber silk scarf fabric Effective date of registration: 20230804 Granted publication date: 20210402 Pledgee: Shanghai Rural Commercial Bank Co.,Ltd. Huangpu sub branch Pledgor: SHANGHAI ZHAOWU BRAND MANAGEMENT CO.,LTD. Registration number: Y2023310000432 |
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