CN1095462C - 气雾相式三氧化硫磺化甲酯制备脂肪酸酯磺酸盐的方法 - Google Patents
气雾相式三氧化硫磺化甲酯制备脂肪酸酯磺酸盐的方法 Download PDFInfo
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- CN1095462C CN1095462C CN00119001A CN00119001A CN1095462C CN 1095462 C CN1095462 C CN 1095462C CN 00119001 A CN00119001 A CN 00119001A CN 00119001 A CN00119001 A CN 00119001A CN 1095462 C CN1095462 C CN 1095462C
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- sulfonation
- methyl
- sulfur trioxide
- reaction
- bleaching
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- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 title claims description 23
- 239000000443 aerosol Substances 0.000 title claims description 6
- -1 SO3 sulfonated formate Chemical class 0.000 title abstract description 13
- 238000002360 preparation method Methods 0.000 title description 4
- 238000000034 method Methods 0.000 claims abstract description 56
- 238000006277 sulfonation reaction Methods 0.000 claims abstract description 47
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims abstract description 38
- 150000004702 methyl esters Chemical class 0.000 claims abstract description 32
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 15
- 238000004061 bleaching Methods 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 238000000889 atomisation Methods 0.000 claims description 12
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 12
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- 238000005507 spraying Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 150000004675 formic acid derivatives Chemical class 0.000 claims description 5
- 238000000703 high-speed centrifugation Methods 0.000 claims description 4
- 230000003472 neutralizing effect Effects 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 230000001360 synchronised effect Effects 0.000 claims 1
- 230000008569 process Effects 0.000 abstract description 18
- 239000000194 fatty acid Substances 0.000 abstract description 11
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 9
- 229930195729 fatty acid Natural products 0.000 abstract description 9
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 230000032683 aging Effects 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 230000036632 reaction speed Effects 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 10
- 230000032050 esterification Effects 0.000 description 10
- 238000005886 esterification reaction Methods 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 239000012467 final product Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 150000002632 lipids Chemical class 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000010408 film Substances 0.000 description 5
- 239000002932 luster Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 4
- 230000008676 import Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000007812 deficiency Effects 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000004044 response Effects 0.000 description 2
- 230000011218 segmentation Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 208000005156 Dehydration Diseases 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- XTHPWXDJESJLNJ-UHFFFAOYSA-N sulfurochloridic acid Chemical compound OS(Cl)(=O)=O XTHPWXDJESJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
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CN00119001A CN1095462C (zh) | 2000-10-08 | 2000-10-08 | 气雾相式三氧化硫磺化甲酯制备脂肪酸酯磺酸盐的方法 |
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CN00119001A CN1095462C (zh) | 2000-10-08 | 2000-10-08 | 气雾相式三氧化硫磺化甲酯制备脂肪酸酯磺酸盐的方法 |
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CN1297886A CN1297886A (zh) | 2001-06-06 |
CN1095462C true CN1095462C (zh) | 2002-12-04 |
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CN00119001A Expired - Fee Related CN1095462C (zh) | 2000-10-08 | 2000-10-08 | 气雾相式三氧化硫磺化甲酯制备脂肪酸酯磺酸盐的方法 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100469430C (zh) * | 2006-12-01 | 2009-03-18 | 谢仁华 | 含脂肪酸乙酯磺酸盐的混合物及其制备方法 |
CN101693678A (zh) * | 2009-10-27 | 2010-04-14 | 南京工业大学 | 制备α-磺基脂肪酸甲酯钠盐的方法 |
CN102531973B (zh) * | 2012-01-17 | 2014-04-09 | 谢仁华 | 制备脂肪酸酯磺酸盐粉体的方法 |
CN105384662A (zh) * | 2015-11-13 | 2016-03-09 | 无锡清杨机械制造有限公司 | 一种有机物喷射式磺化反应工艺 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5916870A (ja) * | 1982-07-20 | 1984-01-28 | Lion Corp | 高品質α−スルホ脂肪酸エステル塩の製造法 |
SU1162794A1 (ru) * | 1984-02-23 | 1985-06-23 | Волгодонской Филиал Всесоюзного Научно-Исследовательского И Проектного Института Поверхностно-Активных Веществ | Способ получени эмульгатора дл жировани кож |
JPS61167655A (ja) * | 1985-01-21 | 1986-07-29 | Kao Corp | 硫酸化物の製造方法 |
-
2000
- 2000-10-08 CN CN00119001A patent/CN1095462C/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5916870A (ja) * | 1982-07-20 | 1984-01-28 | Lion Corp | 高品質α−スルホ脂肪酸エステル塩の製造法 |
SU1162794A1 (ru) * | 1984-02-23 | 1985-06-23 | Волгодонской Филиал Всесоюзного Научно-Исследовательского И Проектного Института Поверхностно-Активных Веществ | Способ получени эмульгатора дл жировани кож |
JPS61167655A (ja) * | 1985-01-21 | 1986-07-29 | Kao Corp | 硫酸化物の製造方法 |
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CN1297886A (zh) | 2001-06-06 |
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Owner name: ZHENJIANG HAIXI INDUSTRIAL CO., LTD. Free format text: FORMER OWNER: XIE RENHUA Effective date: 20101015 |
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Free format text: CORRECT: ADDRESS; FROM: 213002 ROOM 202, UNIT A, BUILDING 83, SUNJIA VILLAGE, SHENGLI VILLAGE COMMITTEE, HONGMEI TOWNSHIP, CHANGZHOU CITY, JIANGSU PROVINCE TO: 212132 NO.1, TONGGANG ROAD, DAGANG, NEW DISTRICT, ZHENJIANG CITY, JIANGSU PROVINCE |
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Effective date of registration: 20101015 Address after: 212132 No. 1 Dagang Road, Dagang District, Zhenjiang, Jiangsu Patentee after: Zhenjiang Haixi Industry Co., Ltd. Address before: 213002, Room 202, unit 83, Sun Village, Shengli village, Hongmei Town, Jiangsu, Changzhou Patentee before: Xie Renhua |
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Owner name: JIANGSU HAIQING BIOTECHNOLOGY CO., LTD. Free format text: FORMER OWNER: ZHENJIANG HAIXI INDUSTRIAL CO., LTD. Effective date: 20110120 |
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Free format text: CORRECT: ADDRESS; FROM: 212132 NO.1, TONGGANG ROAD, DAGANG, NEW DISTRICT, ZHENJIANG CITY, JIANGSU PROVINCE TO: 212132 WEST OF TONGGANG ROAD, DAGANG, ZHENJIANG NEW DISTRICT, JIANGSU PROVINCE |
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Effective date of registration: 20110120 Address after: 212132 Dagang Road, Dagang District, Zhenjiang, Jiangsu Patentee after: Jiangsu Hai Qing biological science and Technology Co Ltd Address before: 212132 No. 1 Dagang Road, Dagang District, Zhenjiang, Jiangsu Patentee before: Zhenjiang Haixi Industry Co., Ltd. |
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Granted publication date: 20021204 Termination date: 20121008 |