CN109503214B - Preparation method of ceramic with pattern - Google Patents

Preparation method of ceramic with pattern Download PDF

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Publication number
CN109503214B
CN109503214B CN201910009172.8A CN201910009172A CN109503214B CN 109503214 B CN109503214 B CN 109503214B CN 201910009172 A CN201910009172 A CN 201910009172A CN 109503214 B CN109503214 B CN 109503214B
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water
parts
ceramic
paper
stripping
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CN109503214A (en
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佘少歆
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/001—Applying decorations on shaped articles, e.g. by painting
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M1/00—Inking and printing with a printer's forme
    • B41M1/12—Stencil printing; Silk-screen printing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/14—Printing inks based on carbohydrates

Abstract

The embodiment of the invention discloses a preparation method of a ceramic with patterns, which comprises the steps of producing and printing stained paper with a water stripping effect, and the application of the stained paper with the water stripping effect on a ceramic soil blank or a biscuit blank. According to the preparation method of the ceramic with the pattern, provided by the embodiment of the invention, by adopting the stained paper with the water stripping effect, when the ceramic is used, only one piece of water needs to be dipped into the stained paper with the water stripping effect, then the stained paper with the water stripping effect is attached to the formed ceramic soil blank or biscuit blank, the base paper is torn off after the stained paper is dried, the pattern can be transferred to the ceramic blank body, and then the porcelain glaze is applied, so that the whole process is simple and convenient, and the colored drawing pattern with the water stripping effect can be rapidly manufactured on the ceramic.

Description

Preparation method of ceramic with pattern
Technical Field
The embodiment of the invention relates to the technical field of ceramic processes, in particular to a preparation method of ceramic with patterns.
Background
At present, in order to produce ceramic decoration with a water stripping effect, commonly called as flower surface, artificial colored drawing is needed, pigment with the water stripping effect is colored, and then color filling and drawing are carried out on the basis of colored drawing. The operation workers are required to have certain art skill, the ceramic pigment is required to be burnt to develop color, the production process of the product depends on the skill of the technicians, and the production efficiency and the quality of the ceramic are severely limited.
If the decal paper of the silk-screen printing is used for decal application and increasing the efficiency, the prior silk-screen printing can only produce the decal paper pasted on the blank surface of the ceramic after glazing, and the decal paper is pasted by using special glue, so that the surface of the decal paper is attached to the surface of the ceramic after glazing. However, the method has no water stripping effect of hand color painting, cannot achieve the three-dimensional effect of concave-convex pattern surface, even if the traditional stained paper is pasted on a ceramic soil blank and then glazed, the traditional stained paper has no water stripping effect, the produced product has no water stripping effect of hand color painting, and finally, the hand color painting is manually carried out, and the working efficiency is very low. Moreover, the hand painting workers are concentrated in a large number of places such as Hunan and Chaozhou, other ceramic production bases such as Shanxi, Shandong, Sichuan and Guangxi are also required to produce the product with the water stripping effect, so that technicians are engaged from the places at high price, and mass production is not possible under the condition of personnel shortage.
Therefore, how to rapidly and conveniently manufacture the colored drawing with the water stripping effect on the ceramic becomes a problem to be solved urgently.
Disclosure of Invention
Therefore, the embodiment of the invention provides a preparation method of a ceramic with a pattern, so as to realize the quick and convenient manufacture of colored drawings with a water stripping effect on the ceramic.
In order to achieve the above object, an embodiment of the present invention provides the following:
in a first aspect of embodiments of the present invention, a method for preparing a ceramic with a pattern is provided, which includes a production printing of a stained paper with a water-removing effect, and an operation of applying the stained paper with the water-removing effect on a ceramic blank or a biscuit blank, wherein the operation of applying the stained paper with the water-removing effect on the ceramic blank or the biscuit blank includes attaching the stained paper with the water-removing effect on the formed ceramic blank or biscuit blank after dipping water, then drying the stained paper with the water-removing effect, tearing off a base paper, and then glazing the ceramic blank or biscuit blank.
In one embodiment of the invention, the water comprises tap water.
In a second aspect of the embodiment of the invention, a self-peeling flower paper is provided, and the self-peeling flower paper is applied to any one of the preparation methods of the ceramic with patterns.
In one embodiment of the invention, the self-peeling water effect fancy paper comprises base paper, a peeling layer printed on the base paper, base color, a color layer printed on the peeling layer or the base color, and a cover surface printed on the color layer.
In a third aspect of embodiments of the present invention, there is provided a method for preparing the self-peeling stained paper, comprising the following steps:
step one, preparing water-stripping ink mixing glue, and mixing the water-stripping ink mixing glue and a pigment in proportion to prepare a mixture for later use;
step two, printing the mixture prepared in the step one on base paper to obtain a water stripping layer;
and step three, printing colors on the water stripping layer or the water stripping layer-free layer by adopting a conventional screen printing technology, and then printing a cover surface to obtain the stained paper with the water stripping effect.
In one embodiment of the invention, the raw materials for preparing the water stripping and ink mixing glue comprise silicone oil, organic tin, a waterproof agent, maltose, methyl cellulose, acrylic acid, peach gum and glycerol.
In one embodiment of the invention, the raw materials for preparing the water-stripping ink mixing glue comprise the following components in parts by weight: 1-5 parts of silicone oil, 0.03-0.05 part of organic tin, 10-20 parts of a waterproof agent, 40-50 parts of maltose, 10-20 parts of methyl cellulose, 5-20 parts of acrylic acid, 5-20 parts of peach gum and 20-45 parts of glycerol. In one embodiment of the invention, the waterproof agent comprises potassium methyl silicate, sodium methyl silicate and lithium methyl silicate, and the weight parts of the components in the raw materials for preparing the water stripping and ink mixing glue are 1-8 parts of potassium methyl silicate, 1-8 parts of sodium methyl silicate and 2-3 parts of lithium methyl silicate. In one embodiment of the invention, the water-stripping toning glue and the pigment are mixed in a mass ratio of 70-100: 100.
According to the embodiment of the invention, the following advantages are provided: the embodiment of the invention provides a preparation method of ceramic with patterns, and the required patterns can be transferred to a ceramic earth blank or biscuit firing blank body only by using tap water when the stained paper with the water stripping effect is used. The whole process is simple and convenient, and the colored drawing with the water stripping effect can be quickly manufactured on the ceramic; the invention also provides a method for preparing the stained paper with the water stripping effect, which is characterized in that the water stripping and ink mixing glue is prepared by adopting the raw materials, the water stripping and ink mixing glue and the pigment are mixed and then are printed on the base paper to obtain the water stripping layer, so that the stained paper with the water stripping effect is adhered to a formed ceramic earth embryo or biscuit embryo after being wetted, the base paper is torn after the water stripping effect flower paper is dried, then the ceramic embryo body is glazed, also called glazing, and the water stripping effect on the stained paper can enable partial or whole enamel on the stained paper to be stripped without the enamel, thereby forming the uneven pattern.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below. It should be apparent that the drawings in the following description are merely exemplary, and that other embodiments can be derived from the drawings provided by those of ordinary skill in the art without inventive effort.
Fig. 1 is a schematic view of a patterned ceramic according to a method for manufacturing a ceramic according to an embodiment of the present invention, wherein stained paper is attached to a formed ceramic;
fig. 2 is one of schematic diagrams illustrating a method for preparing a ceramic product with a pattern according to an embodiment of the present invention, wherein the pattern on the stained paper is printed on the ceramic product;
fig. 3 is a second schematic view of a patterned ceramic according to an embodiment of the present invention after a pattern on a decal is printed on a ceramic;
FIG. 4 is a schematic view of a patterned ceramic according to one embodiment of the present invention after removing the paper substrate;
fig. 5 is one of schematic diagrams illustrating a three-dimensional concave-convex effect formed by automatically peeling off enamel after glazing a patterned paper with water peeling function in a method for manufacturing a ceramic with a pattern according to another embodiment of the present invention;
fig. 6 is a second schematic view illustrating that the enamel is automatically peeled off after the water-stripping patterned paper is glazed in the method for preparing the ceramic with patterns according to another embodiment of the present invention to form a concave-convex stereoscopic effect;
fig. 7 is a third schematic view of the method for manufacturing a ceramic with patterns according to another embodiment of the present invention, in which an enamel is automatically peeled off after a water-stripping patterned paper is glazed, so as to form a three-dimensional concave-convex effect;
FIG. 8 is a schematic view of a ceramic fired after glazing a patterned paper with water-removing effect according to a method for manufacturing a ceramic having a pattern according to still another embodiment of the present invention;
fig. 9 is a second schematic view of a ceramic fired after glazing from a paper with a water-removing effect according to a method for preparing a ceramic with a pattern according to yet another embodiment of the present invention.
Detailed Description
The present invention is described in terms of particular embodiments, other advantages and features of the invention will become apparent to those skilled in the art from the following disclosure, and it is to be understood that the described embodiments are merely exemplary of the invention and that it is not intended to limit the invention to the particular embodiments disclosed. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
The embodiment provides a preparation method of a ceramic with a pattern, which comprises the steps of producing and printing a stained paper with a water stripping effect, and performing applique operation on the stained paper with the water stripping effect on a ceramic soil blank or a biscuit blank, wherein the applique operation of the stained paper with the water stripping effect on the ceramic soil blank or the biscuit blank comprises the steps of attaching the stained paper with the water stripping effect on the formed ceramic soil blank or the biscuit blank after soaking in water, then drying the stained paper with the water stripping effect, tearing off a base paper, glazing the ceramic soil blank or the biscuit blank, also called glazing, and the water stripping effect on the stained paper can enable the stained paper to be partially or wholly free of enamel so as to form a concave-convex pattern.
Further, the water includes tap water, but is not limited thereto.
According to the preparation method of the ceramic with the patterns, the stained paper with the water stripping effect is adopted, and the required patterns can be transferred to the ceramic earth blank or biscuit firing blank body only by using tap water during use. After the patterned paper with the water stripping effect is dried and the base paper is torn off, glazing is carried out on the ceramic blank, also called glazing, and the water stripping effect on the patterned paper can enable the patterned paper to be partially or wholly free of ceramic glaze, so that concave-convex patterns are formed.
Example two
The embodiment provides a flower paper with a water peeling effect, which is applied to the preparation method of the ceramic with the pattern in the first embodiment. The flower paper with the water stripping effect comprises base paper, a water stripping layer printed on the base paper, a color layer printed on the water stripping layer or a water non-stripping layer, and a cover face printed on the color layer.
EXAMPLE III
The embodiment provides a method for preparing the decal paper with the water peeling effect, which comprises the following steps:
step one, preparing water-stripping ink mixing glue, and mixing the water-stripping ink mixing glue and a pigment in proportion to prepare a mixture for later use;
step two, printing the mixture prepared in the step one on base paper to obtain a water stripping layer;
and step three, printing colors on the water stripping layer or the water stripping layer-free layer by adopting a conventional screen printing technology, and then printing a cover surface to obtain the stained paper with the water stripping effect.
Further, the raw materials for preparing the water-stripping ink-mixing glue comprise the following components in parts by weight: 1 part of silicone oil, 0.03 part of organic tin, 10 parts of a waterproof agent, 40 parts of maltose, 10 parts of methyl cellulose, 5 parts of acrylic acid, 5 parts of peach gum and 20 parts of glycerol.
Further, the waterproof agent comprises methyl potassium silicate, methyl sodium silicate and methyl lithium silicate, and the weight parts of the components in the raw materials for preparing the water stripping and ink mixing glue are 1 part of methyl potassium silicate, 1 part of methyl sodium silicate and 2 parts of methyl lithium silicate.
Further, the water stripping ink mixing glue and the pigment are mixed according to the proportion of 70: 100.
Example four
The embodiment provides a method for preparing the decal paper with the water peeling effect, which comprises the following steps:
step one, preparing water-stripping ink mixing glue, and mixing the water-stripping ink mixing glue and a pigment in proportion to prepare a mixture for later use;
step two, printing the mixture prepared in the step one on base paper to obtain a water stripping layer;
and step three, printing colors on the water stripping layer by adopting a conventional screen printing technology, and then pasting a covering surface to obtain the stained paper with the water stripping effect.
Further, the raw materials for preparing the water-stripping ink-mixing glue comprise the following components in parts by weight: 5 parts of silicone oil, 0.05 part of organic tin, 20 parts of a waterproof agent, 50 parts of maltose, 20 parts of methyl cellulose, 20 parts of acrylic acid, 20 parts of peach gum and 45 parts of glycerol.
Further, the waterproof agent comprises 8 parts of methyl potassium silicate, 8 parts of methyl sodium silicate and 3 parts of methyl lithium silicate in parts by weight of the components in the raw materials for preparing the water stripping and ink mixing glue.
Further, the water stripping ink mixing glue and the pigment are mixed according to the proportion of 100: 100.
EXAMPLE five
The embodiment provides a method for preparing the decal paper with the water peeling effect, which comprises the following steps:
step one, preparing water-stripping ink mixing glue, and mixing the water-stripping ink mixing glue and a pigment in proportion to prepare a mixture for later use;
step two, printing the mixture prepared in the step one on base paper to obtain a water stripping layer;
and step three, printing colors on the water stripping layer by adopting a conventional screen printing technology, and then pasting a covering surface to obtain the stained paper with the water stripping effect.
Further, the raw materials for preparing the water-stripping ink-mixing glue comprise the following components in parts by weight: 3 parts of silicone oil, 0.04 part of organic tin, 15 parts of a waterproof agent, 45 parts of maltose, 15 parts of methyl cellulose, 12.5 parts of acrylic acid, 12.5 parts of peach gum and 32.5 parts of glycerol.
Further, the waterproof agent comprises methyl potassium silicate, methyl sodium silicate and methyl lithium silicate, and the weight parts of the components in the raw materials for preparing the water stripping and ink mixing glue are 4.5 parts of methyl potassium silicate, 4.5 parts of methyl sodium silicate and 2.5 parts of methyl lithium silicate.
Further, the water stripping ink mixing glue and the pigment are mixed according to the proportion of 100: 100.
The third embodiment or the fifth embodiment provides a method for preparing the stained paper with the water stripping effect, the water stripping and ink mixing glue is prepared by adopting the raw materials, the water stripping and ink mixing glue and the pigment are mixed and then are printed on the base paper to obtain the water stripping layer, so that the stained paper with the water stripping effect only needs to be pasted on the ceramic when in use, after the base paper is torn off after the water stripping effect stained paper is dried, the ceramic blank is glazed, namely glazing is also called, the water stripping effect on the stained paper can enable the partial or whole enamel on the stained paper to be stripped without the enamel, and the concave-convex pattern is formed.
Although the invention has been described in detail above with reference to a general description and specific examples, it will be apparent to one skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.

Claims (3)

1. A preparation method of ceramic with patterns is characterized by comprising the following steps: the method comprises the steps of producing and printing the stained paper with the water stripping effect and the applique operation of the stained paper with the water stripping effect on a ceramic blank, wherein the applique operation of the stained paper with the water stripping effect on the ceramic blank comprises the steps of dipping the stained paper with the water stripping effect into water, attaching the stained paper to the formed ceramic blank or biscuit blank, drying the stained paper with the water stripping effect, tearing off base paper, and glazing the ceramic blank;
the flower paper with the water stripping effect comprises base paper, a water stripping layer printed on the base paper, a color layer printed on the water stripping layer and a cover face printed on the color layer;
the method for the stained paper with the water peeling effect comprises the following steps:
step one, preparing water-stripping ink mixing glue, and mixing the water-stripping ink mixing glue and a pigment in proportion to prepare a mixture for later use;
step two, printing the mixture prepared in the step one on base paper to obtain a water stripping layer;
printing colors on the water stripping layer by adopting a conventional screen printing technology, and then printing a cover surface to obtain the stained paper with the water stripping effect;
the raw materials for preparing the water-stripping ink-mixing glue comprise silicone oil, organic tin, a waterproof agent, maltose, methyl cellulose, acrylic acid, peach gum and glycerol;
the raw materials for preparing the water-stripping ink-mixing glue comprise the following components in parts by weight: 1-5 parts of silicone oil, 0.03-0.05 part of organic tin, 10-20 parts of a waterproof agent, 40-50 parts of maltose, 10-20 parts of methyl cellulose, 5-20 parts of acrylic acid, 5-20 parts of peach gum and 20-45 parts of glycerol;
the waterproof agent comprises 1-8 parts of methyl potassium silicate, 1-8 parts of methyl sodium silicate and 2-3 parts of methyl lithium silicate in parts by weight.
2. The method for preparing a patterned ceramic according to claim 1, wherein: the water comprises tap water.
3. The method of claim 1, wherein: the water stripping ink mixing glue and the pigment are mixed according to the mass ratio of 70-100: 100.
CN201910009172.8A 2019-01-04 2019-01-04 Preparation method of ceramic with pattern Active CN109503214B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1095670A (en) * 1993-05-25 1994-11-30 江苏省陶瓷研究所 Shift marble paper and preparation and the application in the decoration under ceramic glaze
JP2005138457A (en) * 2003-11-07 2005-06-02 Kanamaru Tensha:Kk Method for decoration with scratch pattern and transfer paper sheet used therefor
CN101070033A (en) * 2007-04-28 2007-11-14 占国华 Underglaze transfer pattern paper, its preparing method and ceramic underglaze use

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1061017C (en) * 1997-12-06 2001-01-24 张淑德 Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method
CN2756684Y (en) * 2005-01-10 2006-02-08 冯文印 Flower paper for porcelain glass decoration surface and its matching printing paper
CN101255068A (en) * 2008-03-31 2008-09-03 陆奕歆 Art ware structure and manufacturing technique thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1095670A (en) * 1993-05-25 1994-11-30 江苏省陶瓷研究所 Shift marble paper and preparation and the application in the decoration under ceramic glaze
JP2005138457A (en) * 2003-11-07 2005-06-02 Kanamaru Tensha:Kk Method for decoration with scratch pattern and transfer paper sheet used therefor
CN101070033A (en) * 2007-04-28 2007-11-14 占国华 Underglaze transfer pattern paper, its preparing method and ceramic underglaze use

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