CN1061017C - Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method - Google Patents
Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method Download PDFInfo
- Publication number
- CN1061017C CN1061017C CN97122358A CN97122358A CN1061017C CN 1061017 C CN1061017 C CN 1061017C CN 97122358 A CN97122358 A CN 97122358A CN 97122358 A CN97122358 A CN 97122358A CN 1061017 C CN1061017 C CN 1061017C
- Authority
- CN
- China
- Prior art keywords
- coating
- butyral
- present
- marble paper
- biscuit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to paint of underglaze decoration butyral film stained paper suitable for pasting on a ceramic green blank or a biscuit, which is characterized in that the present invention is composed of the following components (weight percentage): 28.5 to 32% of SiO2, 8 to 10% of Al2O3, 3.5 to 4.5% of CaO, 0 to 0.5% of MgO, 3.5 to 4.5% of K2O, 4 to 4.5% of Na2O, 0 to 0.3% of Li2O, 16 to 18% of B2O3, 3.5 to 4.5% of ZnO and 23 to 25% of PbO. The present invention can cause butyral stained paper to be used for manufacturing underglaze decoration ceramic, and the cmbination of grain pattern pigment and blanks is firm. The present invention has no plumbum and cadmium dissolution, and can not be faded for ever. Simultaneously, underglaze decoration ceramic can be produced by an over-glaze decoration device. The present invention can save investment and enhance product quality and grade.
Description
The present invention relates to a kind of ceramic coating, particularly a kind of coating that is used for pasting on blue or green base or the biscuit butyral marble paper.
As everyone knows, ceramic under glazed has incomparable advantage than over-glaze decoration.The paper film of under glazed decal paper is cotton mulberry paper both at home and abroad at present, and its technology is that marble paper is affixed on blue or green base or the biscuit, then mulberry paper is slowly torn, and is dried slightly, and glazing is gone into kiln and burnt till through 1150-1400 ℃.This method is big because of product shrinks, and the picture frangibility tear cotton mulberry paper and easily will spend face to disable, and efficient is low, causes the raising of cost.
The paper film is that the decal paper of butyral is made simply, and cost is than paper, and imitated ability is strong, and floral designs are true to nature, levels are rich, and the mechanization degree height is convenient to scale operation.Fire but can not be directly used on blue or green base or the biscuit applique glazing, its main difficult point is: directly be affixed on blue or green base or the biscuit with the butyral marble paper, because of butyral is hydrophobic, can not combine with the glaze slip that contains moisture content; As being affixed on blue or green base or the biscuit with the butyral marble paper, right rear membrane, though butyral 500 ℃ of-900 ℃ of all volatilizable eliminatings, flower color can not be securely attached on blue or green base or the biscuit.
Experiment shows, the face of flower below 800 ℃ combines bad with biscuit, and the flower emaciated face falls when being used for wiping, more than 800 ℃ combination poor, can not pick, carrying, can not successfully enter the glaze spraying operation.Therefore, directly adopting butyral marble paper applique on blue or green base or biscuit to fire under-glaze decoration ceramic is that prior art can't realize.
One of purpose of the present invention is to provide a kind of coating that is applicable to the under glazed butyral film marble paper that is attached on green ceramic blank or the biscuit.
Two of purpose of the present invention is to provide a kind of under glazed butyral film marble paper on green ceramic blank or the biscuit that can be used in.
Three of purpose of the present invention is to provide the method for the butyral film marble paper that a kind of making can be used under glazed on green ceramic blank or the biscuit.
Four of purpose of the present invention is to provide a kind of method of firing under-glaze decoration ceramic with butyral film marble paper.
One of purpose of the present invention is realized by following measures: the one-tenth of this coating is grouped into (weight percent) and is: SiO
2: 28.5-32%, Al
2O
3: 8-10%, CaO:3.5-4.5%, MgO:0-0.5%, K
2O:3.5-4.5%, Na
2O:4-4.5%, Li
2O:0-0.3%, B
2O
3: 16-18%, ZnO:3.5-4.5%PbO:23-25%.
Two of purpose of the present invention is realized by following measures: it comprises base stock and is imprinted on floral designs pigment above it, is characterized in, is attached with the above-mentioned coating of finishing one of goal of the invention of one deck on base stock.
Two of purpose of the present invention can also be realized by following measures: the above-mentioned coating of finishing one of goal of the invention is positioned in the middle of base stock and the floral designs pigment.
Three of purpose of the present invention is realized by following measures: at first on the base stock of marble paper according to the identical method printing last layer coating of printing floral designs, the floral designs of the various pigment of printing on coating then.
Four of purpose of the present invention is realized by following measures: the operation steps of making under-glaze decoration ceramic with the above-mentioned coating of finishing one of goal of the invention is:
ⅰ) the butyral film marble paper that will be printed with coating is attached on green ceramic blank or the biscuit;
ⅱ) under 800-900 ℃ of temperature, arrange film;
ⅲ) glaze spraying or glazing;
ⅳ) glaze firing.
Above-mentioned row's film temperature can be selected to carry out under 805 ℃, 810 ℃, 850 ℃, the 880 ℃ temperature.
The present invention has following advantage and positively effect: 1) butyral film marble paper can be used for under-glaze decoration ceramic by coating of the present invention, coating all combines well with base, glaze, can make colorant be penetrated into glaze layer 50-70 μ m, is penetrated into base substrate 25-35 μ m, unleaded, cadmium stripping, will never fade.2) can utilize over-glaze decoration existing equipment condition to produce under-glaze decoration ceramic, save investment, save energy, improve quality product and class, increase added value.
Coating of the present invention and the butyral film marble paper that is covered with this coating can be used for decoration firing system technology under the multiple ceramic glazes such as sclerotin porcelain, bule and white porcelain.Can be used in the production of domestic ceramics, artistic porcelain, architectural ceramics, stoneware with coating material production under-glaze decoration ceramic technology of the present invention.
Elaborate below in conjunction with embodiment:
Embodiment one: make raw material with the various natural mineral that contain coating composition of the present invention, through weighing, ball milling, sieve, to become content be following coating: SiO for deironing, dry mixed
2: 31.2%, Al
2O
3: 9%, CaO:3.5%, MgO:0.5%, K
2O:4%, Na
2O:4.5%, Li
2O:0.3%, B
2O
3: 18%, ZnO:4%, PbO:25%.
Embodiment two: the method for making the butyral film marble paper that is used for blue or green base or biscuit under glazed of coating of the present invention: at first print a coating by the identical method of printing floral designs on the base stock of marble paper, then the floral designs of printing pigment of all kinds on coating.
Embodiment three: the method for making under-glaze decoration ceramic of coating of the present invention: be attached on green ceramic blank or the biscuit with the butyral marble paper that is printed with coating of the present invention, and 800 ℃ of temperature row films, glaze spraying then, last glaze firing goes out finished product.
Claims (6)
1, a kind of coating that is applicable to the under glazed butyral film marble paper that is attached on green ceramic blank or the biscuit is characterized in that being grouped into (weight percent) SiO by following one-tenth
2: 28.5-32%, Al
2O
3: 8-10%, CaO:3.5-4.5%, MgO:0-0.5%, K
2O:3.5-4.5%, Na
2O:4-4.5%, Li
2O:0-0.3%, B
2O
3: 16-18%, ZnO:3.5-4.5%, PbO:23-25%.
2, a kind of butyral film marble paper that is used for green ceramic blank or biscuit under glazed comprises base stock and the floral designs pigment that is imprinted on above it, it is characterized in that: be attached with the described coating of one deck claim 1 on base stock.
3, butyral film marble paper according to claim 2, it is characterized in that: the described coating of claim 1 is positioned at the centre of base stock and floral designs pigment.
4, make the method for under glazed butyral film marble paper of the described coating of claim 1, it is characterized in that: at first on the base stock of marble paper, print last layer coating, then the floral designs of the various pigment of printing on coating according to the identical method of printing floral designs.
5, the method for making under-glaze decoration ceramic with the described coating of claim 1 is characterized in that, according to the following steps operation:
ⅰ) the butyral film marble paper that will be printed with coating is attached on green ceramic blank or the biscuit;
ⅱ) under 800-900 ℃ of temperature, arrange film;
ⅲ) glaze spraying or glazing;
ⅳ) glaze firing.
6, the method for making under-glaze decoration ceramic according to claim 5 is characterized in that: row's film temperature can be 805 ℃, 810 ℃, 850 ℃, 880 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97122358A CN1061017C (en) | 1997-12-06 | 1997-12-06 | Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN97122358A CN1061017C (en) | 1997-12-06 | 1997-12-06 | Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1184090A CN1184090A (en) | 1998-06-10 |
| CN1061017C true CN1061017C (en) | 2001-01-24 |
Family
ID=5176795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN97122358A Expired - Fee Related CN1061017C (en) | 1997-12-06 | 1997-12-06 | Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1061017C (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109503214B (en) * | 2019-01-04 | 2021-05-25 | 佘少歆 | Preparation method of ceramic with pattern |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4998811A (en) * | 1973-01-16 | 1974-09-18 | ||
| GB2099760A (en) * | 1981-06-06 | 1982-12-15 | Heraeus Gmbh W C | Decalcomanias |
| US5132165A (en) * | 1990-06-19 | 1992-07-21 | Commerical Decal, Inc. | Wet printing techniques |
| CN1095670A (en) * | 1993-05-25 | 1994-11-30 | 江苏省陶瓷研究所 | Shift marble paper and preparation and the application in the decoration under ceramic glaze |
-
1997
- 1997-12-06 CN CN97122358A patent/CN1061017C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4998811A (en) * | 1973-01-16 | 1974-09-18 | ||
| GB2099760A (en) * | 1981-06-06 | 1982-12-15 | Heraeus Gmbh W C | Decalcomanias |
| US5132165A (en) * | 1990-06-19 | 1992-07-21 | Commerical Decal, Inc. | Wet printing techniques |
| CN1095670A (en) * | 1993-05-25 | 1994-11-30 | 江苏省陶瓷研究所 | Shift marble paper and preparation and the application in the decoration under ceramic glaze |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1184090A (en) | 1998-06-10 |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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