CN1095670A - Shift marble paper and preparation and the application in the decoration under ceramic glaze - Google Patents
Shift marble paper and preparation and the application in the decoration under ceramic glaze Download PDFInfo
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- CN1095670A CN1095670A CN 93111513 CN93111513A CN1095670A CN 1095670 A CN1095670 A CN 1095670A CN 93111513 CN93111513 CN 93111513 CN 93111513 A CN93111513 A CN 93111513A CN 1095670 A CN1095670 A CN 1095670A
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Abstract
The invention discloses under a kind of glaze to decorate with real does not have cover film wet separation and shifts marble paper and preparation method and the application in pottery is particularly decorated under the light ceramics glaze.This marble paper adopts the former oiliness of hydrophily connection material replacement to connect material, thereby has abandoned the marble paper commentaries on classics is pasted in the prior art masking layer or tack coat, and carries the fine and close year paper of paper replacement quality with porous.Marble paper production process of the present invention is reduced, and applique process is simple, and it is reliable to change subsides performance and steady quality, has improved decorative effect under the glaze greatly.
Description
The present invention relates to decorate under a kind of glaze, particularly the glaze of ceramic is decorated with shifting marble paper and preparation method down.
Glaze is decorated down, particularly glaze such as ceramic such as pottery, stoneware, porcelain, face brick are decorated down, a kind of more convenient method is to adopt the wet separation applique transferring, and the decorative layer that soon is printed in advance on the marble paper changes the product surface that is attached to required decoration, and glaze firing is carried out in glazing then.
Wet separation commonly used shifts marble paper, is divided into two classes by the transfer medium difference.
One class is to cover the film marble paper, and it is the water-soluble release agent of precoating layer on year paper, presses look according to the required colorant kind number of decoration then and divides version to print upward required decorative layer in turn, at last at decorative layer surface coated thin film or varnish (abbreviation cover film).Decorative layer move the picture applique be by (together with) cover film one runs up and is attached to the surface of decorated goods.The shortcoming that cover film marble paper is used for decorating under the glaze is: marble paper is difficult to direct applique on the base substrate of porous, high water absorbing capacity, even adopt adhesive or film softening agent, one operational sequence of not only many increases, and effect is also bad, makes this class marble paper scope of application be subjected to restriction to a certain degree.Secondly, decorative position is owing to there is hydrophobic cover film to exist, thereby can not adsorb glaze slip well, causes defectives such as sagging, starved glaze easily.Behind applique, adopt methods such as baking, carbonization, high-temperature calcination to handle, make the modification of cover film, burn mistake or decorative layer is burnt firm billet surface, in order to the absorption glaze slip, not only increased production process, nor be beneficial to energy savings.
In order to overcome the defective of above-mentioned cover film marble paper, DRP DE-2141336 discloses another kind of improved no cover film marble paper, it mainly improves is to have abandoned the cover film that is unfavorable for adsorbing glaze slip especially that former cover film marble paper used since the midium or long term, and replaces with hydrophilic cellulose family bonding coat.Specifically, it to be that decorative layer surface-coated one deck at marble paper is subject to water moistening and the tack coat of activation is realized applique to replace the cover film.Though this marble paper has removed the cover film that is difficult to adsorb glaze slip, be subject to the tack coat of the moistening activation of water but still need brushing one deck applique transferring to use, thereby do not simplify production process.And since the cellulose family tack coat to meet the water activation capacity relatively poor, viscous force a little less than, decorate still difficulty of applique transferring down for the glaze of the less biscuit of some water absorption rates, so the application of this class marble paper still has certain limitation.
In addition, a common drawback of above-mentioned two class marble papers is that the printing in the decorative layer connects material and is hydrophobic oily matter, thereby function singleness, only can play connection and carry paper and the effect of decorating color material, not only the decorative layer sucking is poor, and the commentaries on classics of decorative layer subsides need in addition by cover film or tack coat.Secondly, the papery of carrying paper is thicker closeer, changes when pasting suction and separates slowlyer, and needs when pasting changeing in advance that to paste on the base substrate water moistening changeing, and then applique.Operational sequence is many, also is its deficiency.
The objective of the invention is to overcome the deficiency of above-mentioned prior art, provide a kind of making simple, easy to use, change subsides, good decorating effect, real nothing cover film adapts to the transfer marble paper of decorating under the glaze fully.
Second purpose of the present invention is to provide a kind of preparation method of above-mentioned transfer marble paper.
The 3rd purpose of the present invention is above-mentioned transfer marble paper is applied to ceramic body, and particularly the glaze of light ceramics biscuiting base substrate is decorated down.
Invent the realization of first purpose, its solution is to have abandoned oiliness connection material in the decorative layer, replaces and connect material with hydrophily, and year paper adopts porous paper.Specifically, glaze of the present invention decoration down comprises and carries paper and be printed on the described year China ink material decorative layer on the paper with shifting marble paper, it is characterized in that said black material mainly connects material by hydrophily and forms with the color material of decoration, and said year paper is porous paper.
The color material of decoration of the present invention is known by the technical staff, and the various color bases that can adapt to decorated body and institute's glazing kind glaze firing are formed.
Hydrophily of the present invention connects material, is a kind of water-soluble binder of dual-use material, and it is to adhere to the attachment of decorating color material for adapting to the wet method print request, is again to change the binding agent that pastes decorative layer.When printing the making marble paper, rely on its even dispersion to decorate coloured silk and expect, and will decorate coloured silk and expect to adhere on year paper by the printing of design grain pattern; During applique transferring, meeting activation performance viscosity under the water moisture state, decorative layer is pasted required decoration surface, thereby omitted the applique transferring tack coat, really reaching does not have the cover film.The water-wet behavior that connects material makes decorative layer can adsorb glaze slip preferably, effectively prevents generation of defects such as sagging, starved glaze.Connection material of the present invention can be various hydrophilic, meet the material that water could activate and show viscosity, as a kind of or several combinations such as dextrin, polyvinyl alcohol, carbohydrate, the bletilla striata, natural gum, sodium alginates, they are made the paste that is suitable for printing, and be in harmonious proportion with the color material of decoration.
Decorate color material is connected material with hydrophily cooperation by decorating color and luster requirements, color base shade, connect material viscosity and print request decide, this be known to the technical staff, it is generally acknowledged to connect the use amount of expecting can be suitable for printing and commentaries on classics subsides requirement gets final product.
Porous of the present invention is carried paper, except having paper (transfer medium of undertake the printing of decorative layer and the applique transferring) effect of carrying of general transfer marble paper, wherein another effect is to connect material for adapting to above-mentioned printing, the quick easily separated property of carrying paper and decorative layer when assurance and raising applique transferring.Carry the porous of paper, both be suitable for fast permeable speed, make and to be connected material with less water with fast speeds infiltration year paper and activation, work continuously to adapt to fast; Porosity characteristic makes decorative layer weaken in the adhesion strength of carrying on the paper again simultaneously, is easy to decorative layer and the wet separation of carrying paper, to improving the integrality of changeing the pinup picture case positive role is arranged.Some porous paper all can be used as the present invention and carry paper.Carry for reducing a paper cost, fast permeable speed, the present invention preferably adopts the slim paper of the porous that certain mechanical strength is arranged under moisture state, for example the slim paper of porous made of water-fast fiber such as mulberry skin, rice paper, typewriting base stock etc.
Be for some decorative patterns and disperse picture discontinuous or that connecting portion is more tiny, be globality and the integrality that improves its pattern transferring, can add an adhesion layer one between paper and run up and be attached to the decoration surface with carrying at the decorative layer of marble paper.Be fine absorption glaze slip, adhesion layer should adopt hydroaropic substance, wherein preferably adopt the less relatively connection material of the viscosity material close to form with the glaze composition, use the close glaze that improves adhesion layer and with the easily separated property of carrying paper, change the integrality of pasting decorative layer thereby significantly improve, the adhesion layer area should be slightly larger than decorative layer.
For improving decorative layer decorative effect under glaze, make glaze slip, decorative layer, base face three combination when glaze firing more become perfect, can be mixed with an amount of stabilizing agent and wetting agent in the China ink material of described decorative layer.The introducing of stabilizing agent can improve and decorate the chemical stability of color material to glaze, also can be used as filler simultaneously and uses, and uses to adjust and decorates the colourity of color material under glaze.Stabilizing agent can adopt the oxide that heat resistance is strong, high temperature viscosity is big, generally can kaolin, adding such as china clay, potter's clay, porcelain stone, silica, base mud.The introducing of wetting agent, its effect are improve to decorate the binding ability of color material between base, glaze, make it to infiltrate base substrate well when glaze firing and combine with glaze to form firm intermediate layer.The glaze generation of defects contracts when the color material of moistening decoration also can reduce glaze firing.Another effect of wetting agent is to use to adjust the firing temperature of decorating color material.Some high temperature viscosities are little, good fluidity and be beneficial to the oxide of crystal growth, all can be used as wetting agent, as oxides such as lead, boron, alkali metal, are that the frit of main composition adds adding appropriate to the occasion with these oxides.
The preparation of transfer marble paper of the present invention, comprise that porous is carried paper is combined into the composite sheet that is suitable for mechanical presswork with the base stock with certain tension intensity, carry on the paper with mainly connecting material, decorate the printing ink that is suitable for printing that color material, water or other solution reconcile in the porous of composite sheet by hydrophily, go up required decorative layer with the printing process printing, the paper that carries that will be printed on decorative layer again separates with base stock.
The used printing process of the present invention can be adopted the known method of technical staff, and wherein a kind of printing process preferably is for adopting the method for serigraphy (biting).
In the inventive method, the effect of base stock is to make in the marble paper process in printing, uses to strengthen the tension intensity that porous is carried paper, makes it to be suitable for mechanical presswork.Simultaneously, the use of base stock, but also attenuate carries paper thickness, and the use of thin paper is favourable to reducing the marble paper cost and changeing the subsides operation.Base stock among the present invention can be used repeatedly.
Carry the compound of paper and base stock, can adopt various ways, make in the marble paper process in printing, can be fitted on the base stock, and finish presswork with base stock is mobile so that carry paper.Complex method commonly used can have Electrostatic Absorption, or on base stock, apply the big coating of one deck confficient of static friction, or apply one deck wax layer, or mount with starchy material such as low viscosity adhesive such as numb taro powder, lily root flour, fecula and sodium alginate, natural gum etc. and to close as the typewriting Waxpaper.
The mediation of printing-ink is advisable to adapt to the wet method print request, can adopt conventional method, connects the solution that material, other auxiliary material, water or other be suitable for modulating printing ink and evenly is in harmonious proportion decorating color material, hydrophily, rare, thick with satisfied be printed as suitable.After printing, water evaporates in printing ink is promptly being carried the surperficial formation one of paper mainly by connecting the decorative layer that the color material of material and decoration is formed.
As required, between decorative layer and year paper, increase by a hydrophilic adhesion layer, then can be before the printed decoration pattern, apply or use method for printing screen, with mainly by with the close material of institute's glazing composition be connected the material concordant pastel, apply on the paper or printing one deck is slightly larger than the adhesion layer of decorative pattern carrying of composite sheet, to be dried after again by required decoration requirement, the color separation printing is decorative pattern upward.
The above-mentioned wet method that makes shifts marble paper, the underglaze colour that can be used for multiple ceramic is as required decorated, wherein a kind of typical application, for the glaze of the ceramic body that is used to have certain water absorption rate is decorated down, it may further comprise the steps: the transfer marble paper that will produce is counter to be affixed on required decorative position, and the paper back side is moistening with water carrying, and the paper that carries that will drench is thrown off, after glazing glaze firing, promptly get decorative product under the glaze of being satisfied with.Because base substrate has certain water absorption rate, help changeing decal paper and fully absorb water and activate and connect material, therefore should shift a kind of better purposes of marble paper, for the underglaze colour of the light ceramics biscuit that is used for twice firing is decorated.
Transfer paste marble paper of the present invention, owing to decorate in the China ink material and adopt hydrophilic connection material, particularly select viscosity carbohydrate connection preferably material for use, make and connect material one thing dual-purpose, be not only printing and connect the attachment of decorating color material, and be again the binding agent of applique transferring under moisture state, thereby really omitted the cover film that shifts marble paper, make the marble paper production process reduce, adhesive property is good.The hydrophily that connects material helps the absorption of glaze slip again, easily produces glazing defectives such as sagging, starved glaze thereby avoided former use oiliness to connect material, has significantly improved the glazing effect.The application of slim year paper of porous makes applique transferring easily and fast, and the applique operation is simple, can directly counter being affixed on of marble paper be needed decorative position, connects material with the moistening activation of water, decorative layer is separated with year paper adhere to decorative position.Performance is pasted in the more notable commentaries on classics that has improved marble paper of the application of adhesion layer, the integrality of promptly easily separated property and commentaries on classics pinup picture case.Decorate in the China ink material and add an amount of stabilizing agent and wetting agent, the colourity and the temperature of both having aligned the underglaze colour material have improved decorative effect and product qualified rate simultaneously again.
Fig. 1 is the marble paper structural representation of the compound base stock of band of the present invention.
Fig. 2 does not have adhesion layer marble paper structural representation for the present invention.
Fig. 3 has adhesion layer marble paper structural representation for the present invention.
Fig. 4 is an applique transferring schematic diagram of the present invention.
Embodiment 1: with multicolored pattern is example, printer's ink material according to the form below weighing compatibility (weight %).Printer's ink material preparation table (seeing attached list)
Carry out precomminution with 2,3.Soak 4 and be mixed into slurry with clear water.Press 1 batching of all kinds, mixing after calcine, pulverize standby.Then with 1,2,3,4, combination is modulated into the printing ink that is suitable for printing.
According to the requirement of design rough sketch, galley is made in color separation, adopt the automatic silk screen machine that China ink material of all kinds is carried out the color separation chromatography carrying through the porous of mounting the composite sheet that closes on 3 on the paper, treat that can will carry paper after decorative layer 5 dryings separates with base stock, promptly gets transfer marble paper as shown in Figure 2.
Composite sheet is then mounted with wooden papermaking 1 with lily root flour, gum-solution 2 by the slim paper 3 of mulberry cortex porous and is closed.
Embodiment 2: as embodiment 1 referring to Fig. 3 to before the composite sheet color separation printing, carry in porous with the silk screen version earlier that printing one deck is based on the adhesion layer 4 of glaze composition on 3 on the paper, its spreading area is advisable to be slightly larger than decorative patterns, capable again color separation printing after waiting to do.
Embodiment 3: with the anti-moulded pottery not yet put in a kiln to bake surface that is affixed on the once-firing ceramic of above-mentioned marble paper, carrying paper 3 back sides, flicking moistening with clear water, make its imbibition, connect the material activation in the China ink material and present viscosity, decorative layer is cemented in base substrate 6 surfaces, to carry paper then and throw off (as Fig. 4), glaze firing is carried out in glazing again.
Embodiment 4: with anti-fine pottery biscuit 6 surfaces of adopting double-firing process that are affixed on of above-mentioned marble paper, carrying paper 3 back sides, flicking moistening with clear water, stay a minute, can will carry paper 3 and throw off.Through changeing the biscuiting base substrate that pastes underglaze colour, can enter glazing machine glazing and glaze firing.
Embodiment 5: through the face brick of biscuiting with soaking glaze or spray glazing glazing, treat after the glaze layer drying that with the anti-glaze laminar surface that is affixed on of above-mentioned marble paper it is moistening with water to carry the paper back side, send into glaze kiln glaze firing after taking off paper, in the melting process of glaze, decorative layer promptly sinks in the glaze after burning, and melts altogether with glaze.
Applique is decorated after the aforementioned glazing, also can topped more thereon one deck glaze liquid.
The foregoing description is not to be limitation of the invention, and according to the difference of decorative product, glaze kind, colorant is formed also can be different.Hydrophily connects material, stabilizing agent, wetting agent and ratio and also can suitably change and adjust.
Claims (15)
1, decoration comprises and carries paper and be printed on the described year China ink material decorative layer on the paper with shifting marble paper under a kind of glaze, it is characterized in that said black material mainly connects material by hydrophily and the color material of decoration is formed, and said year paper is porous paper.
2,, it is characterized in that said hydrophily connects material a kind of or several mixtures for maltose, rock sugar, the bletilla striata, natural gum, sodium alginate according to the described transfer marble paper of claim 1.
3,, it is characterized in that said porous paper is the slim paper of porous according to the described transfer marble paper of claim 1.
4,, it is characterized in that being mixed with an amount of stabilizing agent and wetting agent in the said China ink material according to claim 1,2 or 3 described transfer marble papers.
5, according to the described transfer marble paper of claim 4, it is characterized in that said stabilizing agent is kaolin, base mud, porcelain stone, silica, wetting agent is the Pb-B-Zn clinker.
6,, it is characterized in that said decorative layer and carry between paper that one hydrophilic adhesion layer is arranged according to the described transfer marble paper of claim 5.
7,, it is characterized in that said adhesion layer is slightly larger than decorative layer according to the described transfer marble paper of claim 6.
8, according to the described transfer marble paper of claim 7.It is characterized in that said adhesion layer forms by connecting the close material with the glaze composition of material.
9, the preparation method of the described transfer marble paper of a kind of claim 1 comprises:
(1) porous is carried paper and be combined into the composite sheet that is suitable for mechanical presswork with base stock with certain tension intensity;
(2) carry on the paper with mainly connecting material, decorate the printing ink that is suitable for printing that color material, water or other solution reconcile in the porous of composite sheet, go up required decorative layer with the printing process printing by hydrophily;
(3) paper that carries that will be printed on decorative layer separates with base stock.
10,, it is characterized in that said printing process is a silk screen method according to the preparation method of the described transfer marble paper of claim 9.
11, according to the preparation method of the described transfer marble paper of claim 10, it is characterized in that the printed decoration layer before, carry earlier and apply the hydrophilic adhesion layer of one deck on the paper, again at adhesion layer surface printing decoration layer in the porous of composite sheet.
12,, it is characterized in that the coating of said adhesion layer also is silk screen process according to the preparation method of the described transfer marble paper of claim 11.
13,, it is characterized in that it is to mount with low viscosity adhesive to close that said porous is carried the compound of paper and base stock according to the preparation method of claim 9,10,11 or 12 described transfer marble papers.
14, the application during the described transfer marble paper of a kind of claim 1 is decorated under having the ceramic bad body glaze of certain water absorption rate comprises:
(1) counter being affixed on of described transfer marble paper needed decorative position;
(2) moistening at year paper back side with water;
The paper that carries that (3) will drench is thrown off;
(4) glazing and carry out glaze firing.
15,, it is characterized in that said ceramic body is the light ceramics biscuit according to the purposes of the described transfer marble paper of claim 14.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93111513 CN1095670A (en) | 1993-05-25 | 1993-05-25 | Shift marble paper and preparation and the application in the decoration under ceramic glaze |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93111513 CN1095670A (en) | 1993-05-25 | 1993-05-25 | Shift marble paper and preparation and the application in the decoration under ceramic glaze |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1095670A true CN1095670A (en) | 1994-11-30 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93111513 Pending CN1095670A (en) | 1993-05-25 | 1993-05-25 | Shift marble paper and preparation and the application in the decoration under ceramic glaze |
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| CN (1) | CN1095670A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1061017C (en) * | 1997-12-06 | 2001-01-24 | 张淑德 | Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method |
| CN1302937C (en) * | 2004-06-17 | 2007-03-07 | 尹彦征 | Method for avoiding image background color infiltration between colored drawing and applique of cadmium red vitreous enamel |
| CN102604482A (en) * | 2012-03-09 | 2012-07-25 | 冯建忠 | Fabric pattern transfer ink and preparing method thereof |
| CN105713534A (en) * | 2016-03-30 | 2016-06-29 | 安徽青花坊瓷业股份有限公司 | Pasting liquid for manufacturing of ceramic underglaze decal paper |
| CN106493841A (en) * | 2016-12-15 | 2017-03-15 | 衡东县中兴陶瓷有限公司 | ceramic applique device |
| CN106626932A (en) * | 2016-12-24 | 2017-05-10 | 福建省德化县新顺盛陶瓷工艺有限公司 | Once shaped electroplating stained paper, preparation method thereof and ceramic decoration method |
| CN109503214A (en) * | 2019-01-04 | 2019-03-22 | 佘少歆 | A kind of preparation method of the figuratum ceramics of band |
| CN110857540A (en) * | 2018-08-22 | 2020-03-03 | 全斯福新材料（苏州）有限公司 | Transfer paper for hard media and method for preparing same |
| CN112592630A (en) * | 2020-11-02 | 2021-04-02 | 广东天元汇邦新材料股份有限公司 | Pearlescent transfer film and preparation method and application thereof |
| CN115093249A (en) * | 2022-05-11 | 2022-09-23 | 蒙娜丽莎集团股份有限公司 | Self-luminous rock plate and preparation method thereof and application of self-luminous rock plate in dining table |
-
1993
- 1993-05-25 CN CN 93111513 patent/CN1095670A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1061017C (en) * | 1997-12-06 | 2001-01-24 | 张淑德 | Paint suitable for butyral color film as underglaze color stuck onto green ceramic blank and its use method |
| CN1302937C (en) * | 2004-06-17 | 2007-03-07 | 尹彦征 | Method for avoiding image background color infiltration between colored drawing and applique of cadmium red vitreous enamel |
| CN102604482A (en) * | 2012-03-09 | 2012-07-25 | 冯建忠 | Fabric pattern transfer ink and preparing method thereof |
| CN105713534A (en) * | 2016-03-30 | 2016-06-29 | 安徽青花坊瓷业股份有限公司 | Pasting liquid for manufacturing of ceramic underglaze decal paper |
| CN106493841A (en) * | 2016-12-15 | 2017-03-15 | 衡东县中兴陶瓷有限公司 | ceramic applique device |
| CN106626932A (en) * | 2016-12-24 | 2017-05-10 | 福建省德化县新顺盛陶瓷工艺有限公司 | Once shaped electroplating stained paper, preparation method thereof and ceramic decoration method |
| CN110857540A (en) * | 2018-08-22 | 2020-03-03 | 全斯福新材料（苏州）有限公司 | Transfer paper for hard media and method for preparing same |
| CN109503214A (en) * | 2019-01-04 | 2019-03-22 | 佘少歆 | A kind of preparation method of the figuratum ceramics of band |
| CN109503214B (en) * | 2019-01-04 | 2021-05-25 | 佘少歆 | Preparation method of ceramic with pattern |
| CN112592630A (en) * | 2020-11-02 | 2021-04-02 | 广东天元汇邦新材料股份有限公司 | Pearlescent transfer film and preparation method and application thereof |
| CN115093249A (en) * | 2022-05-11 | 2022-09-23 | 蒙娜丽莎集团股份有限公司 | Self-luminous rock plate and preparation method thereof and application of self-luminous rock plate in dining table |
| CN115093249B (en) * | 2022-05-11 | 2023-06-30 | 蒙娜丽莎集团股份有限公司 | Self-luminous rock plate, preparation method thereof and application thereof in dining table |
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