CN1070629A - The ceramic glaze single firing process of prizing - Google Patents

The ceramic glaze single firing process of prizing Download PDF

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Publication number
CN1070629A
CN1070629A CN 91109069 CN91109069A CN1070629A CN 1070629 A CN1070629 A CN 1070629A CN 91109069 CN91109069 CN 91109069 CN 91109069 A CN91109069 A CN 91109069A CN 1070629 A CN1070629 A CN 1070629A
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additive
prizing
color base
green
brown
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CN 91109069
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Chinese (zh)
Inventor
张新才
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LIYUAN CERAMICS FACTORY KAIPING DISTRICT TANGSHAN
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LIYUAN CERAMICS FACTORY KAIPING DISTRICT TANGSHAN
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Priority to CN 91109069 priority Critical patent/CN1070629A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/54—Pigments; Dyes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Glass Compositions (AREA)

Abstract

The ceramic glaze single firing process of prizing is specially adapted to the decoration of domestic ceramics and architectural pottery goods.It is characterized in that the color base of making colorant and being different colours is mixed into the mill wet mixing with additive respectively, burns till back fine grinding dry for standby.Additive is made up of quartz, feldspar, clay, Wingdale, porcelain powder, talcum, bone ash and metal oxide.Colorant and additive are used by a certain percentage.The applique caking agent is made up of methylcellulose gum, water, industrial spirit, and the once-firing temperature is between 1180-1320 ℃.
The present invention has that thorough elimination is plumbous, the cadmium stripping, and characteristics such as reduce cost.

Description

The ceramic glaze single firing process of prizing
The present invention relates to a kind of ceramic glaze single firing process of prizing, belong to the decoration of ceramic, be specially adapted to the decoration of domestic ceramics and architectural pottery goods.
Twice firing process of the general employing of the production that existing ceramic glaze is prized, it mainly is applique on the ceramic whiteware tire after burning till for the first time, burning till through the second time, this technology has reduced more effectively stripping quantity plumbous, cadmium, its weak point is that twice firing process energy consumption is big, and a colorant part is dissolved in the glaze in sintering process, and a part still floats on the glaze, though can reduce plumbous, quantity of cadmium release, can not thoroughly eliminate the stripping of lead, cadmium.
The objective of the invention is in order to overcome above-mentioned weak point of the prior art, and a kind of ceramic glaze single firing process of prizing is provided.
The objective of the invention is to realize by following measure:
The preparation of colorant: the color base of different colours is mixed into mill wet mixing 4-8 hour with additive respectively, kiln is gone in oven dry then, in oxydizing flame or neutral flame atmosphere, burn till through 500-1150 ℃, be incubated after 1-3 hour, reenter mill wet mixing fine grinding 48-60 hour or separately additive is burnt till back and color base mixing fine grinding, make it to pass through 10000-hole sieve, dry for standby, its additive is by quartzy 5-40%, feldspar 10-60%, and clay 10-80%, Wingdale (rhombspar, interior amphibole) 2-20%, porcelain powder 2-20%, talcum 1-40%, bone ash 2-15%, metal oxide 0.5-12% form; The proportioning for preparing versicolor colorant and additive is additive 0-95%, color base 5-100%, the colorant that makes in order to the top method is printed to decal paper, decal paper is bonded on the base substrate after the glazing with caking agent, form through once-firing, firing range is between 1180-1320 ℃, and its caking agent is formulated by methylcellulose gum 1-30%, clear water 20-80%, alcohol 2-40%.
The present invention will now be further detailed embodiment:
What ceramic glaze provided by the invention prized that single firing process mainly solves is decal paper and firing process, what decal paper technology mainly solved is the preparation of decal paper with colorant, the measure that the present invention takes is that the color base of different colours is mixed into mill wet mixing 4-8 hour with additive respectively, kiln is gone in oven dry then, in oxydizing flame or neutral flame atmosphere, burn till through 500-1150 ℃, be incubated after 1-3 hour, reenter mill wet mixing fine grinding 48-60 hour or separately additive is burnt till back and color base mixing fine grinding, make it to pass through 10000-hole sieve, dry for standby, its additive is by quartzy 5-40%, feldspar 10-60%, clay 10-80%, Wingdale (rhombspar, interior amphibole) 2-20%, porcelain powder 2-20%, talcum 1-40%, bone ash 2-15%, metal oxide 0.5-12% forms, the proportioning of prepared versicolor colorant and additive is: additive 0-95%, color base 5-100%.
The chemical ingredients of additive is listed as follows: %
Content is generally best
Title
SiO 260-70 60-66
Al 2O 310-35 13-32
Fe 2O 30-1 0-0.8
CaO 0.5-12 1-10
MgO 0-10 0-8
K 2O 1-7 2-6
Na 2O 1-4 1.5-3.6
TiO 20-0.6 0-0.5
ZnO 0-2.4 0-1
P 2O 50-2 0-1
According to the high low melt situation of different colorant refractory temperatures, and the deep or light depth of tone requires to transfer to the additive of heterogeneity content.
The embodiment of additive:
Embodiment 1, additive are made up of quartz 25.5%, feldspar 29.2%, clay 32.7%, burning talcum 2.6%, Wingdale 4.4%, porcelain powder 4%, zinc oxide 1.6%.In order to adjust deep green, yellow, brown, vanadium zirconium yellow, vanadium blueness, brown etc.
Embodiment 2, additive are made up of quartz 27.3%, feldspar 25%, clay 40.5%, Wingdale 2.2%, porcelain powder 2%, talcum 1.8%, zinc oxide 1.2%.In order to adjust colors such as cobalt blue, black, pea green look, redness.
Embodiment 3, additive are made up of quartz 26%, feldspar 35%, clay 23%, Wingdale 10%, rhombspar 3.5%, zinc oxide 2.5%.In order to adjust shallow blackish green, light yellow, shallow pea green look, shallow vanadium blueness, light red, light brown, light green, color such as faint yellow.
The proportioning embodiment of versicolor colorant and additive such as following table:
Color additives % color base %
Cobalt blue 0-80 cobalt oxide 20-100
Shallow cobalt blue 50-95 cobalt oxide 5-50
The blackish green color base 30-70 of blackish green 20-70
The shallow blackish green color base 5-50 of shallow blackish green 50-95
The yellow 10-70 vanadium of vanadium zirconium zirconium chloroaniline 20-80
Faint yellow 51-80 vanadium zirconium chloroaniline 20-49
Black 0-50 fast black base 30-100
The pea green color base 30-100 of pea green look 0-50
The pea green color base 50-79 of shallow pea green look 21-50
The blue basic 20-100 of the blue 0-50 vanadium of vanadium
The blue basic 30-59 of the blue 41-70 vanadium of shallow vanadium
The red basic 40-100 of red 0-50
The red basic 70-89 of light red 11-30
Brown 10-60 brown chromophore 20-80
Light brown 61-90 brown chromophore 10-39
The light green color base 50-100 of light green 0-30
Brown 0-50 brown base 30-100
The ceramic glaze single firing process of prizing mainly is to utilize that the big film high-temp. of plastic-blasting is unleaded, marble paper applique on glazed body of cadmium printing pigment, and its method is: decal paper is sticked on the base substrate after the glazing with caking agent, form through once-firing.The optimum range of firing temperature is at 1200-1280 ℃.Its caking agent is by methylcellulose gum 1-30%, water 20-80%, and alcohol 2-40% batching forms.
The embodiment of applique caking agent:
Embodiment 1, caking agent formula scope: methylcellulose gum 5-15%, clear water 40-60%, industrial spirit 8-30%.
Embodiment 2, decal paper is sticked on the base substrate after the glazing with caking agent, form through once-firing.Firing range is at 1200-1280 ℃.
By above-mentioned prescription methylcellulose gum is soaked with clear water or tea (15-90 ℃), make it thoroughly soluble in water, become pasty state.The molten back of industrial spirit and water is stuck with paste with methylcellulose gum and is mixed, and its concentration is reached
Figure 91109069X_IMG1
Between the é 30-60, optimum value is
Figure 91109069X_IMG2
é 50, and the caking agent sealing that mixes up is preserved, and avoid the alcohol volatilization, adjust according to actual conditions during use.
The prize applique process of once-firing of ceramic glaze, the concrete practice be, with the dry body behind the glaze at need applique place with caking agent of wool brush brush, then brush caking agent second time, marble paper is by good position, flat with little palm brush brush, drive in the colored face bubble out of and can go into klining one-tenth.
The ceramic glaze single firing process flow process of prizing is: feedstock production (requires the same with ordinary porcelain base glaze, neutral glaze adapts to the most) → that pigment ratio (color base of different colours is mixed with additive respectively by service requirements) → go into mill carries out dried wet-milling is broken → and go into kiln (easy fired in oxydizing flame or neutral flame atmosphere is incubated after 1-3 hour) → go into levigate mill (enabling to pass through 10000-hole sieve) → oven dry → carry out stamp → clipping and carving paper → preparation caking agent → applique → drying (control moisture and be lower than 1%) → adorn saggar and go into kiln → burn till → kiln discharge with colorant.
Because the effect of caking agent, the plastic-blasting film is unaffected when burning more than 500 ℃, when reaching 800 ℃, oiliness flower face on the openpore is not owing to there is the effect of low-temperature solvent, beginning changes mealiness flower face into by oiliness, mealiness flower face since the effect of additive along with the rising of temperature, the progressively combination of base glaze pigment has realized eliminating purpose plumbous, the cadmium once-firing.
Compare original technology, the present invention has the following advantages:
1, colorant additive adjustment, glaze and marble paper burn till in a sintering curve, and glaze and colorant combine together, can thoroughly eliminate the stripping of lead, cadmium.
2, the present invention is once-firing, and energy savings reduces cost more than 30%.
3, adjust each layer of printed layer melt temperature with additive, can solve the defective of stripping flower.

Claims (5)

1, a kind of ceramic glaze single firing process of prizing is applicable to it is characterized in that the decoration of domestic ceramics and architectural pottery goods:
The preparation of a, colorant: the color base of different colours is mixed into mill wet mixing 4-8 hour with additive respectively, kiln is gone in oven dry then, in oxydizing flame or neutral flame atmosphere, burn till through 500-1150 ℃, be incubated after 1-3 hour, reenter mill wet mixing fine grinding 48-60 hour or separately additive is burnt till back and color base mixing fine grinding, make it to pass through 10000-hole sieve, dry for standby, additive is by quartzy 5-40%, feldspar 10-60%, and clay 10-80%, Wingdale (rhombspar, interior amphibole) 2-20%, porcelain powder 2-20%, talcum 1-40%, bone ash 2-15%, metal oxide 0.5-12% form; The proportioning for preparing versicolor colorant and additive is additive 0-95%, color base 5-100%;
The preparation of b, applique caking agent: decal paper is bonded on the base substrate after the glazing with caking agent, forms through once-firing, firing temperature is between 1180-1320 ℃, and its caking agent is formulated by methylcellulose gum 1-30%, water 20-80%, alcohol 2-40%.
2, the ceramic glaze according to claim 1 single firing process of prizing is characterized in that the best formation scope of additive is: quartzy 10-30%, feldspar 15-50%, clay 20-75%, Wingdale (rhombspar, interior amphibole) 3-18%, porcelain powder 4-18%, talcum 2-30%, bone ash 4-100%, zinc oxide 1-8%.
3, the ceramic glaze according to claim 1 single firing process of prizing is characterized in that the best ratio range for preparing versicolor colorant and additive is: the cobalt aluminate look: cobalt oxide 20-100%, additive 0-80%; Shallow cobalt aluminate: cobalt oxide 5-50%, additive 50-95%; Blackish green: blackish green color base 30-70%, additive 20-70%, shallow blackish green color base 5-50%, additive 50-95%; Vanadium zirconium Huang: vanadium zirconium chloroaniline 20-80%, additive 10-70%; Faint yellow: vanadium zirconium chloroaniline 20-49%, additive 51-80%; Black: fast black base 30-100%, additive 0-50%; Peak green: green soya bean color base 30-100%, additive 0-50%; Shallow pea green look: green soya bean color base 50-79%, additive 21-51%; Vanadium blueness: vanadium blue basic 20-100%, additive 0-50%, vanadium blue basic 30-59%, additive 41-70%; Red: red basic 40-100%, additive 0-30%; Incarnadine: red basic 70-89%, additive 11-30%; Brown: brown chromophore 20-80%, additive 10-60%; Light brown: brown chromophore 10-39%, additive 61-90%; Light green: light green color base 50-100%, additive 0-30%; Brown: brown base 30-100%, additive 0-50%.
4, the ceramic glaze according to claim 1 single firing process of prizing is characterized in that decal paper is sticked on the base substrate after the glazing with caking agent, forms through once-firing, and the optimum range of its firing temperature is at 1200-1280 ℃.
5, according to claim 1 or the 4 described ceramic glazes single firing process of prizing, it is characterized in that the best formation scope of applique caking agent is methylcellulose gum 5-15%, clear water or tea 40-60%, industrial spirit 8-30%.
CN 91109069 1991-09-18 1991-09-18 The ceramic glaze single firing process of prizing Pending CN1070629A (en)

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Application Number Priority Date Filing Date Title
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CN 91109069 CN1070629A (en) 1991-09-18 1991-09-18 The ceramic glaze single firing process of prizing

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100337985C (en) * 2005-01-21 2007-09-19 卢培鑫 Ceramics preparation method
CN103524112A (en) * 2012-07-07 2014-01-22 醴陵市艺林美术瓷厂 Preparation method of double-sided underglazed five-color porcelain plate
CN105110644A (en) * 2015-07-23 2015-12-02 潮州市三元陶瓷(集团)有限公司 Preparation method of in-glaze daily-used glass ceramic
CN105819692A (en) * 2015-12-31 2016-08-03 宁海县火龙陶瓷有限公司 Brown non-transparent glaze, and method for making vase by using glaze
CN108437676A (en) * 2018-05-07 2018-08-24 唐山市恒瑞瓷业有限公司 Ceramic marble paper and manufacture craft and application process in a kind of discoloration glaze

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100337985C (en) * 2005-01-21 2007-09-19 卢培鑫 Ceramics preparation method
CN103524112A (en) * 2012-07-07 2014-01-22 醴陵市艺林美术瓷厂 Preparation method of double-sided underglazed five-color porcelain plate
CN103524112B (en) * 2012-07-07 2015-12-02 醴陵市艺林美术瓷厂 A kind of preparation method of two-sided five color painting in the glaze porcelain plate
CN105110644A (en) * 2015-07-23 2015-12-02 潮州市三元陶瓷(集团)有限公司 Preparation method of in-glaze daily-used glass ceramic
CN105110644B (en) * 2015-07-23 2017-05-24 广东三元玉瓷文化发展股份有限公司 Preparation method of in-glaze daily-used glass ceramic
CN105819692A (en) * 2015-12-31 2016-08-03 宁海县火龙陶瓷有限公司 Brown non-transparent glaze, and method for making vase by using glaze
CN105819692B (en) * 2015-12-31 2018-08-21 宁海驰骋金属制品有限公司 A kind of brown opaque glaze and the method with glaze making vase
CN108437676A (en) * 2018-05-07 2018-08-24 唐山市恒瑞瓷业有限公司 Ceramic marble paper and manufacture craft and application process in a kind of discoloration glaze

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