CN109456856A - A kind of natural fruit and vegetables detergent - Google Patents

A kind of natural fruit and vegetables detergent Download PDF

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Publication number
CN109456856A
CN109456856A CN201811478255.3A CN201811478255A CN109456856A CN 109456856 A CN109456856 A CN 109456856A CN 201811478255 A CN201811478255 A CN 201811478255A CN 109456856 A CN109456856 A CN 109456856A
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CN
China
Prior art keywords
fruits
vegetables
detergent
vegetables detergent
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811478255.3A
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Chinese (zh)
Inventor
钟晓明
叶伟杰
钟秀欣
曾永权
陈娅婷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zigong Innovation Center of Zhejiang University
Original Assignee
Zigong Innovation Center of Zhejiang University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zigong Innovation Center of Zhejiang University filed Critical Zigong Innovation Center of Zhejiang University
Priority to CN201811478255.3A priority Critical patent/CN109456856A/en
Publication of CN109456856A publication Critical patent/CN109456856A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/94Mixtures with anionic, cationic or non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/32Protein hydrolysates; Fatty acid condensates thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/90Betaines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/92Sulfobetaines ; Sulfitobetaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention provides a kind of natural fruit and vegetables detergent, the fruits and vegetables detergent includes the component of following weight percentage: the amino acid surfactant of 10%-20%, the mineral salt of 1%-5% and solvent.The effect of fruits and vegetables detergent of the invention passes through the collocation of amino acid surfactant and mineral salt, and fruits and vegetables detergent of the invention is enabled effectively to remove pesticide, and has mild cleaning, emulsification foam, and exquisiteness is not hurt hands.

Description

A kind of natural fruit and vegetables detergent
Technical field
The invention belongs to detergent technical fields, and in particular to a kind of natural fruit and vegetables detergent.
Background technique
In the growth course of fruits and vegetables, people can add Multiple Pesticides and plant hormone, for improving the disease resistance of fruits and vegetables With eliminate various insect pests, and improve the fruit-setting rate of fruits and vegetables and the commodity rate of fruit.Part pesticide and hormone are inevitably Fruit and vegetable surfaces can be remained in.If the remains of pesticide in fruit and vegetable is taken in for a long time by human body, can cause damages to human health, seriously Will cause pesticide poisoning.
The fruit-vegetable clear washing article such as fruit-vegetable clear desalinization of soil by flooding or leaching at present, main component sodium chloride, fruits and vegetables cleaning agent main component are divided into Three kinds of surfactant-based, enzyme preparation class, alkaline species.The salt moisture absorption in air is cleaned, is not easy to store;It is surfactant-based to adopt more With from chemical synthesis, such as fatty acid sulfates, irritation is larger;Enzyme preparation fermentoid has specificity, just for a small number of agricultures Medicine has preferable effect;Strong basicity class is larger to skin irritation.
Summary of the invention
A kind of natural fruit and vegetables detergent is provided it is an object of the invention to overcome the shortcomings of the prior art place.
To achieve the above object, the technical scheme adopted by the invention is as follows: a kind of fruits and vegetables detergent, the fruits and vegetables detergent packet Include the component of following weight percent content: the amino acid surfactant of 10%-20%, the mineral salt of 1%-5% and conduct The water of solvent.
Preferably, the mineral salt is selected from one of sea salt, lake salt and deep-well salt or a variety of.
The mineral elements such as the magnesium, potassium, calcium, sodium, zinc and the chloride that contain in the mineral salt.
Preferably, the amino acid surfactant is selected from N- acyl amino acid surfactant.
It is highly preferred that the amino acid surfactant is selected from N- sodium lauroyl glutamate, N- lauroyl Sodium L-alaninate, N- Sodium lauroyl sarcosine.
Preferably, the fruits and vegetables detergent further includes the amophoteric surface active for accounting for the fruits and vegetables detergent weight 5%-15% Agent.
Preferably, the fruits and vegetables detergent further includes the non-ionic surface work for accounting for the fruits and vegetables detergent weight 1%-5% Property agent.
Preferably, N- acyl amino acid surfactant accounts for the fruits and vegetables detergent weight in the fruits and vegetables detergent 12%-18%.
Preferably, the fruits and vegetables detergent Minerals salt accounts for the 2%-4% of the fruits and vegetables detergent weight.
Preferably, the fruits and vegetables detergent includes pH adjusting agent, and the pH value of the fruits and vegetables detergent is 6-7.
Under the conditions of the pH, the closer skin with human body of the pH of fruits and vegetables detergent.
It is highly preferred that the pH adjusting agent is citric acid.
Preferably, the amphoteric surfactant is selected from carboxylic acid group's glycine betaine, sulphonic acid betaine and phosphate ester glycine betaine.
Preferably, the weight ratio of the N- acyl amino acid surfactant and amphoteric surfactant is 1:2-5:1.
It is highly preferred that the weight ratio of the N- acyl amino acid surfactant and amphoteric surfactant is 1:1-3:1.
Preferably, the fruits and vegetables detergent further includes the moisturizer for accounting for the fruits and vegetables detergent weight 1%-10%, accounts for institute State the essence of fruits and vegetables detergent weight 0.1%-0.2%, the ethylenediamine tetraacetic of Zhan Suoshu fruits and vegetables detergent weight 0.05%-0.1% Acetic acid disodium (EDTA), Zhan Suoshu fruits and vegetables detergent weight 0.2%-0.5% antibacterial agent.
Preferably, the fruits and vegetables detergent includes the component of following weight percentage: 15% amino acid surface activity Agent, 3% mineral salt, 7.5% amphoteric surfactant, 3% nonionic surfactant, 5% moisturizer, 0.2% Essence, 0.1% disodium ethylene diamine tetraacetate, 0.5% antibacterial agent and citric acid, surplus are the water as solvent;
The pH value of the fruits and vegetables detergent is 6, and the content by changing citric acid is adjusted;
Wherein, the amino acid surfactant is selected from N- sodium lauroyl glutamate, N- lauroyl Sodium L-alaninate, N- laurel Acylsarcosine sodium.
When pH is 6, the anti-microbial property of the fruits and vegetables detergent is preferable.
The beneficial effects of the present invention are: the present invention provides a kind of fruits and vegetables detergent, fruits and vegetables detergent of the invention is logical The collocation for crossing amino acid surfactant and mineral salt enables fruits and vegetables detergent of the invention effectively to remove pesticide, and With the effect of mild cleaning, emulsification foam, exquisiteness is not hurt hands.
Specific embodiment
To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention It is described further.
Embodiment 1
As a kind of fruits and vegetables detergent of the embodiment of the present invention, the fruits and vegetables detergent includes following weight percent content Component:
15% amino acid surfactant, 3% mineral salt, 7.5% amphoteric surfactant, 3% nonionic Surfactant, 5% moisturizer, 0.2% essence, 0.1% disodium ethylene diamine tetraacetate, 0.5% antibacterial agent and As the citric acid of pH adjusting agent, surplus is the water as solvent;
The pH value of the fruits and vegetables detergent is 6, and the content by changing citric acid is adjusted;
Wherein, the amino acid surfactant is N- sodium lauroyl sarcosine;
The amphoteric surfactant is carboxylic acid group's glycine betaine.
Embodiment 2-5
As the fruits and vegetables detergent of the embodiment of the present invention, embodiment 2-5, comparative example 1 fruits and vegetables detergent formula such as table 1 It is shown.
1 embodiment 2-5 of table, comparative example 1 fruits and vegetables detergent formula
Ingredient/content % Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Comparative example 1
N- sodium lauroyl sarcosine 10 12 18 20 0
Mineral salt 3 3 3 3 3
Carboxylic acid group's glycine betaine 7.5 7.5 7.5 7.5 7.5
Nonionic surfactant 3 3 3 3 3
Moisturizer 5 5 5 5 5
Essence 0.2 0.2 0.2 0.2 0.2
EDTA 0.1 0.1 0.1 0.1 0.1
Antibacterial agent 0.5 0.5 0.5 0.5 0.5
Citric acid In right amount In right amount In right amount In right amount In right amount
Water Surplus Surplus Surplus Surplus Surplus
Experimental example 1
The performance of the fruits and vegetables detergent of embodiment 1-5, comparative example 1 is measured.
1, foaming properties
With reference to GB/T 13173-91, measured using Ross-Miles method.10g embodiment 1-5,1 sample of comparative example are weighed, Use 150mgkg-1Hard water dissolve and be settled in the volumetric flask of 1000mL, the solution prepared is placed in 40 DEG C of waters bath with thermostatic control 0.5h.At 40 DEG C, by 200mL test solution from 90cm height flow to the surface of the identical test solution of measuring graduates bottom 50mL after, liquid It collides and generates foam, open stopwatch immediately and record system corresponding foam height in 30s and 5min.It is corresponding with 30s Foam height (H0) characterization foamability, to balance corresponding foam height (H after 5min5) and H0Ratio (H5/H0) characterization bubble The stability of foam.
It repeats the above experiment, obtains result of the error between at least 3 test results within 5%.
2, cleaning ability
Referring to the test method of GB/T 24691-2009 " fruits and vegetables cleaning agent ", the pesticide residue of fruits and vegetables detergent is removed Rate is tested.
3, testing result
To testing result such as 2 institute of table of the foaming properties of the fruits and vegetables detergent of embodiment 1-5, comparative example 1, cleaning ability Show.
The testing result of 2 embodiment 1-5 of table, the foaming properties of the fruits and vegetables detergent of comparative example 1, cleaning ability.
Embodiment 6-9
As the fruits and vegetables detergent of the embodiment of the present invention, embodiment 6-9, comparative example 2 fruits and vegetables detergent formula such as table 3 It is shown.
3 embodiment 6-9 of table, comparative example 2 fruits and vegetables detergent formula
Experimental example 2
The performance of fruits and vegetables detergent of embodiment 1, embodiment 6-9, comparative example 2 is measured.Detection method is the same as experiment Example 1.
Embodiment 1, embodiment 6-9, the foaming properties of the fruits and vegetables detergent of comparative example 2, cleaning ability testing result such as Shown in table 4.
4 embodiment 1 of table, embodiment 6-9, comparative example 2 fruits and vegetables detergent foaming properties, cleaning ability.
Embodiment 10-13
As the fruits and vegetables detergent of the embodiment of the present invention, embodiment 10-13, comparative example 3 fruits and vegetables detergent formula such as Shown in table 5.
5 embodiment 10-13 of table, comparative example 3 fruits and vegetables detergent formula
Experimental example 3
The performance of fruits and vegetables detergent of embodiment 1, embodiment 10-14, comparative example 3 is measured.Detection method is the same as real Test example 1.
The testing result of embodiment 1, embodiment 10-14, the foaming properties of the fruits and vegetables detergent of comparative example 3, cleaning ability As shown in table 6.
6 embodiment 1 of table, embodiment 10-14, comparative example 3 fruits and vegetables detergent foaming properties, cleaning ability.
Embodiment 15
As the fruits and vegetables detergent of the embodiment of the present invention, the fruits and vegetables detergent of the present embodiment and the fruits and vegetables of embodiment 1 are washed The difference of agent are as follows: the amino acid surfactant is N- sodium lauroyl glutamate.
Embodiment 16
As the fruits and vegetables detergent of the embodiment of the present invention, the fruits and vegetables detergent of the present embodiment and the fruits and vegetables of embodiment 1 are washed The difference of agent are as follows: the amino acid surfactant is N- lauroyl Sodium L-alaninate.
Embodiment 17
As the fruits and vegetables detergent of the embodiment of the present invention, the fruits and vegetables detergent of the present embodiment and the fruits and vegetables of embodiment 1 are washed The difference of agent are as follows: the amphoteric surfactant is phosphate ester glycine betaine.
Embodiment 18
As the fruits and vegetables detergent of the embodiment of the present invention, the fruits and vegetables detergent of the present embodiment and the fruits and vegetables of embodiment 1 are washed The difference of agent are as follows: the amphoteric surfactant is sulphonic acid betaine.
Experimental example 4
The performance of the fruits and vegetables detergent of embodiment 15-18 is measured.Detection method is the same as experimental example 1.
The foaming properties of the fruits and vegetables detergent of embodiment 15-18, the testing result of cleaning ability are as shown in table 7.
Foaming properties, the cleaning ability of the fruits and vegetables detergent of 7 embodiment 15-18 of table.
Finally, it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention rather than protects to the present invention The limitation of range is protected, although the invention is described in detail with reference to the preferred embodiments, those skilled in the art should Understand, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the essence of technical solution of the present invention And range.

Claims (10)

1. a kind of fruits and vegetables detergent, which is characterized in that the fruits and vegetables detergent includes the component of following weight percent content: The amino acid surfactant of 10%-20%, the mineral salt of 1%-5% and the water as solvent.
2. fruits and vegetables detergent according to claim 1, which is characterized in that the amino acid surfactant is N- acyl group ammonia Base acid surfaces activating agent.
3. fruits and vegetables detergent according to claim 2, which is characterized in that the fruits and vegetables detergent further includes accounting for the fruits and vegetables The amphoteric surfactant of detergent weight 5%-15%.
4. fruits and vegetables detergent according to claim 3, which is characterized in that the fruits and vegetables detergent further includes accounting for the fruits and vegetables The nonionic surfactant of detergent weight 1%-5%.
5. according to any fruits and vegetables detergent of claim 2-4, which is characterized in that N- acyl group ammonia in the fruits and vegetables detergent Base acid surfaces activating agent accounts for the 12%-18% of the fruits and vegetables detergent weight, and the fruits and vegetables detergent Minerals salt accounts for the fruit The 2%-4% of vegetable detergent weight.
6. fruits and vegetables detergent according to claim 5, which is characterized in that the fruits and vegetables detergent includes pH adjusting agent, institute The pH value for stating fruits and vegetables detergent is 6-7.
7. fruits and vegetables detergent according to claim 5, which is characterized in that the amphoteric surfactant is selected from carboxylic acid group's sweet tea Dish alkali, sulphonic acid betaine and phosphate ester glycine betaine, the weight of the N- acyl amino acid surfactant and amphoteric surfactant Amount is than being 1:2-5:1.
8. fruits and vegetables detergent according to claim 7, which is characterized in that the N- acyl amino acid surfactant and two Property surfactant weight ratio be 1:1-3:1.
9. fruits and vegetables detergent according to claim 7, which is characterized in that the fruits and vegetables detergent further includes accounting for the fruits and vegetables The moisturizer of detergent weight 1%-10%, essence, the Zhan Suoshu fruits and vegetables of Zhan Suoshu fruits and vegetables detergent weight 0.1%-0.2% are washed Wash disodium ethylene diamine tetraacetate, the Zhan Suoshu fruits and vegetables detergent weight 0.2%-0.5% antibacterial agent of agent weight 0.05%-0.1%.
10. fruits and vegetables detergent according to claim 7, which is characterized in that the fruits and vegetables detergent includes following weight hundred Divide the component of content:
15% amino acid surfactant, 3% mineral salt, 7.5% amphoteric surfactant, 3% non-ionic surface Activating agent, 5% moisturizer, 0.2% essence, 0.1% disodium ethylene diamine tetraacetate, 0.5% antibacterial agent and conduct The citric acid of pH adjusting agent, surplus are the water as solvent;
The pH value of the fruits and vegetables detergent is 6, and the content by changing citric acid is adjusted;
Wherein, the amino acid surfactant is selected from N- sodium lauroyl glutamate, N- lauroyl Sodium L-alaninate, N- lauroyl flesh Propylhomoserin sodium.
CN201811478255.3A 2018-12-04 2018-12-04 A kind of natural fruit and vegetables detergent Pending CN109456856A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201811478255.3A CN109456856A (en) 2018-12-04 2018-12-04 A kind of natural fruit and vegetables detergent

Publications (1)

Publication Number Publication Date
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109797055A (en) * 2019-03-21 2019-05-24 冠道(广州)科技有限公司 A kind of multifunctional detergent and preparation method thereof that addition amino acid table is living
CN111778116A (en) * 2020-07-10 2020-10-16 广州市加茜亚化妆品有限公司 Fruit and vegetable tableware detergent and preparation method thereof
CN111961542A (en) * 2020-09-03 2020-11-20 上海伟虹科技发展有限公司 Multifunctional cleaning agent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047506A (en) * 2016-06-04 2016-10-26 湖南省轻工盐业集团技术中心有限公司 Fruit and vegetable washing salt
CN106047505A (en) * 2016-05-30 2016-10-26 江苏雪豹日化有限公司 Natural-formulation multi-effect cleaning composition and application thereof
CN106190594A (en) * 2016-07-08 2016-12-07 张健 A kind of aminoacid kitchen is clean
CN107629892A (en) * 2017-08-17 2018-01-26 深圳市科霖洁生物科技有限公司 A kind of fruits and vegetables cleaning powder and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106047505A (en) * 2016-05-30 2016-10-26 江苏雪豹日化有限公司 Natural-formulation multi-effect cleaning composition and application thereof
CN106047506A (en) * 2016-06-04 2016-10-26 湖南省轻工盐业集团技术中心有限公司 Fruit and vegetable washing salt
CN106190594A (en) * 2016-07-08 2016-12-07 张健 A kind of aminoacid kitchen is clean
CN107629892A (en) * 2017-08-17 2018-01-26 深圳市科霖洁生物科技有限公司 A kind of fruits and vegetables cleaning powder and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109797055A (en) * 2019-03-21 2019-05-24 冠道(广州)科技有限公司 A kind of multifunctional detergent and preparation method thereof that addition amino acid table is living
CN109797055B (en) * 2019-03-21 2021-06-08 广东站成研创科技有限公司 Multifunctional detergent added with amino acid surfactant and preparation method thereof
CN111778116A (en) * 2020-07-10 2020-10-16 广州市加茜亚化妆品有限公司 Fruit and vegetable tableware detergent and preparation method thereof
CN111961542A (en) * 2020-09-03 2020-11-20 上海伟虹科技发展有限公司 Multifunctional cleaning agent and preparation method thereof

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Application publication date: 20190312

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