CN104705297A - Aid suitable for multiple glyphosate salt water agents - Google Patents
Aid suitable for multiple glyphosate salt water agents Download PDFInfo
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- CN104705297A CN104705297A CN201310670072.2A CN201310670072A CN104705297A CN 104705297 A CN104705297 A CN 104705297A CN 201310670072 A CN201310670072 A CN 201310670072A CN 104705297 A CN104705297 A CN 104705297A
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- glyphosate
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Abstract
The invention relates to an aid suitable for multiple glyphosate salt water agents. The aid has a wide application range, and can be used as a synergist for multiple glyphosate salt water agents including ammonium glyphosate, glyphosate isopropylamine, glyphosate dimethylamine, glyphosate ethanol amine, glyphosate triisopropanolamine, glyphosate triethylamine, glyphosphate-trimesium, and glyphosate potassium. The aid is composed of cocamidopropyl betaine, sodium cocoyl sarcosinate, iso-tridecanol polyoxyethylene ether, alkyl glucoside, ammonium sulfate, and water agent. When the weight of the aid accounts for 5 to 20% of various glyphosate water agents, the aid can guarantee the storage stability of water agents and has an excellent synergetic effect on glyphosate.
Description
One, technical field
This patent belongs to agricultural surfactant field, particularly relates to a kind of surface activator composition being applicable to multiple glyphosate salt aqua.
Two, technical background
Glyphosate and N-(phosphonomethyl) glycine are foliar herbicides after a kind of natural disposition seedling that goes out of Uptake and translocation; for weedings such as rubber plantation, tea place, orchard, forest nursery and fire belts, be also widely used in the weeding of the non-agricultural cultivated lands such as railway, highway, airport, oil depot, power station.Glyphosate also can coordinate no-tillage system to use before crops lie fallow phase or sowing, kills the weeds that field covers.Glyphosate decomposes rapidly in soil, does not have the lasting period.
Glyphosate is water-soluble poor, usually utilize alkaline matter to be neutralized into the water soluble salts such as ammonium glyphosate, isopropyl amine salt, dimethylamine salt, ethanolamine salt, triisopropanolamine salt, triethanolamine salt, trimethyl sulfosalt and sylvite, and add corresponding auxiliary agent and water and be mixed with various aqua and use.Tallow amine APEO is the tradition of 41% glyphosate isopropylamine salt water solution and main auxiliary agent, the permeability of preparation is optimized the while that its main feature being and can changing spraying anelasticity, thus improve the activity of weeding of glyphosate, therefore, tallow amine APEO become the mankind use for many years to moderns at widely used glyphosate special assistant.But, tallow amine APEO to skin and eyes irritant, and have comparatively high toxicity to fish, and have potential poisoning risk to glyphosate tolerant crop.In addition, tallow amine APEO is only applicable to glyphosate isopropylamine salt water solution, very poor to the compatibility of the glyphosate salts such as ammonium glyphosate, dimethylamine salt and sylvite, is not suitable as the auxiliary agent of these glyphosate salt aquas.
The present invention is directed to the performance of various glyphosate salt, suitable surfactant is selected to carry out reasonably combined, effectively solve the compatibility of auxiliary agent and various glyphosate salt, and effectively can improve tack and the permeability of glyphosate liquid, strengthen the activity of weeding of various glyphosate salt aqua.In addition, it is strong that the present invention has biological degradability, and the features such as environment compatibility is strong, meet the demand for development of following agricultural surfactant.
Three, summary of the invention
The object of this invention is to provide a kind of auxiliary agent being applicable to multiple gyphosate solution.This auxiliary agent is applied widely, can be used as the synergist of the multiple gyphosate solution comprising ammonium glyphosate, isopropyl amine salt, dimethylamine salt, ethanolamine salt, triisopropanolamine salt, triethylamine salt, trimethyl sulfosalt and sylvite etc.
The present invention's surface active agent composition is wherein selected from the surfactants such as alkyl glycoside, lauroylamidopropyl betaine, Cocoamidopropyl betaine, sodium lauroyl sarcosine, cocoyl propylhomoserin sodium, 13 isomeric alcohol polyethenoxy ether, fatty alcohol-polyoxyethylene ether, DDAO, cocamidopropyl propyl amide sodium oxide molybdena.
The present invention's surface active agent composition is wherein preferably by 4 kinds of surfactants such as Cocoamidopropyl betaine, cocoyl sarcosine sodium, 13 isomeric alcohol polyethenoxy ether and alkyl glycoside, and in addition, inorganic constituents comprises ammonium sulfate and water.
The present invention is formulated according to mass percent by following material:
Composition of the present invention has the following advantages:
1, the invention provides a kind of novel gyphosate solution auxiliary agent, it is not only applicable to glyphosate isopropyl amine salt, and is applicable to various different types of glyphosate salt aquas such as ammonium glyphosate, dimethylamine salt, trimethyl sulfosalt and sylvite.
2, the invention provides a kind of gyphosate solution auxiliary agent, be conducive to the adhesive force and the performance of keeping humidity that improve liquid, be more conducive to interior suction and the conductivity of glyphosate, promote giving full play to of drug effect.
3, the present invention is not containing tallow amine APEO, and is made up of the surfactant having environment compatibility good, and therefore, the present invention has excellent biological degradability, has tight security to environment and biology.
Four, specific implementation method
Embodiment 1
A kind ofly be applicable to each material mass percentage in the auxiliary agent of multiple gyphosate solution: Cocoamidopropyl betaine 10%, alkyl glycoside 30%, cocoyl sarcosine sodium 15%, 13 isomeric alcohol polyethenoxy ether 5%, ammonium sulfate 15%, water supplies 100%, and auxiliary agent mixing and stirring conveniently forms.
Embodiment 2
A kind ofly be applicable to each material mass percentage in the auxiliary agent of multiple gyphosate solution: Cocoamidopropyl betaine 25%, alkyl glycoside 20%, cocoyl sarcosine sodium 5%, 13 isomeric alcohol polyethenoxy ether 10%, ammonium sulfate 10%, water supplies 100%, and auxiliary agent mixing and stirring conveniently forms.
Embodiment 3
A kind ofly be applicable to each material mass percentage in the auxiliary agent of multiple gyphosate solution: Cocoamidopropyl betaine 25%, alkyl glycoside 10%, cocoyl sarcosine sodium 20%, 13 isomeric alcohol polyethenoxy ether 10%, ammonium sulfate 5%, water supplies 100%, and auxiliary agent mixing and stirring conveniently forms.
Embodiment 4
30% ammonium glyphosate aqua, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate 30%, ammoniacal liquor (25%) 24%, auxiliary agent (embodiment 1) 10%, water supplies 100%.
This 30% ammonium glyphosate aqua outward appearance is colourless or pale yellow transparent homogeneous liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 5
30% ammonium glyphosate aqua, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate 30%, ammoniacal liquor (25%) 24%, auxiliary agent (embodiment 2) 12%, water supplies 100%.
This 30% ammonium glyphosate aqua outward appearance is colourless or pale yellow transparent homogeneous liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 6
30% ammonium glyphosate aqua, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate 30%, ammoniacal liquor (25%) 24%, auxiliary agent (embodiment 2) 15%, water supplies 100%.
This 30% ammonium glyphosate aqua outward appearance is colourless or pale yellow transparent homogeneous liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 7
41% glyphosate isopropylamine salt water solution, by following material by mass percentage, and utilizing conventional pesticide preparation processing method formulated: glyphosate isopropyl amine salt 41% (glyphosate 30%), auxiliary agent (embodiment 1) 10%, water supplies 100%.
This 41% glyphosate isopropylamine salt water solution outward appearance is pale yellow transparent homogeneous liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 8
51% glyphosate isopropylamine salt water solution, by following material by mass percentage, and utilizing conventional pesticide preparation processing method formulated: glyphosate isopropyl amine salt 51% (glyphosate 37.5%), auxiliary agent (embodiment 2) 12%, water supplies 100%.
This 41% glyphosate isopropylamine salt water solution outward appearance is pale yellow transparent homogeneous liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 9
41% glyphosate isopropylamine salt water solution, by following material by mass percentage, and utilizing conventional pesticide preparation processing method formulated: glyphosate isopropyl amine salt 41% (glyphosate 30%), auxiliary agent (embodiment 3) 15%, water supplies 100%.
This 41% glyphosate isopropylamine salt water solution outward appearance is pale yellow transparent homogeneous liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 10
38% glyphosate dimethylamine salt aqua, by following material by mass percentage, and utilizing conventional pesticide preparation processing method formulated: glyphosate dimethylamine salt 38% (glyphosate 30%), auxiliary agent (embodiment 1) 10%, water supplies 100%.
This 38% glyphosate dimethylamine salt aqua outward appearance is rufous transparency liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 11
41% glyphosate dimethylamine salt aqua, by following material by mass percentage, and utilizing conventional pesticide preparation processing method formulated: glyphosate dimethylamine salt 36% (glyphosate 32.5%), auxiliary agent (embodiment 2) 12%, water supplies 100%.
This 41% glyphosate dimethylamine salt aqua outward appearance is for being rufous transparency liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 12
50.5% glyphosate dimethylamine salt aqua, by following material by mass percentage, and utilizing conventional pesticide preparation processing method formulated: glyphosate dimethylamine salt 50.5% (glyphosate 40%), auxiliary agent (embodiment 3) 15%, water supplies 100%.
This 50.5% glyphosate dimethylamine salt aqua outward appearance is rufous clear viscous liquids, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 13
36.8% sylvine aqua with glyphosate, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate potassium 36.8% (glyphosate 30%), auxiliary agent (embodiment 1) 10%, water supplies 100%.
This 36.8% sylvine aqua with glyphosate outward appearance is colourless transparent liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 14
42% sylvine aqua with glyphosate, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate potassium 42% (glyphosate 34.3%), auxiliary agent (embodiment 2) 12%, water supplies 100%.
This 42% sylvine aqua with glyphosate outward appearance is colourless transparent liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 15
49% sylvine aqua with glyphosate, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate potassium 49% (glyphosate 40%), auxiliary agent (embodiment 3) 15%, water supplies 100%.
This 49% sylvine aqua with glyphosate outward appearance is water white transparency thick liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 16
41% glyphosate ethanolamine salt aqua, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate ethanolamine salt 41%, auxiliary agent (embodiment 1) 10%, water supplies 100%.
This 41% glyphosate ethanolamine salt aqua outward appearance is water white transparency thick liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 17
51% glyphosate triethylamine salt aqua, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate triethylamine salt 51%, auxiliary agent (embodiment 2) 10%, water supplies 100%.
This 51% glyphosate triethylamine salt aqua outward appearance is water white transparency thick liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 18
51% glyphosate triisopropanolamine salt aqua, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate triisopropanolamine salt 51%, auxiliary agent (embodiment 3) 10%, water supplies 100%.
This 51% glyphosate triisopropanolamine salt aqua outward appearance is water white transparency thick liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 19
48% glyphosate trimethyl sulfosalt aqua, by following material by mass percentage, and utilize conventional pesticide preparation processing method formulated: glyphosate trimethyl sulfosalt 48%, auxiliary agent (embodiment 1) 10%, water supplies 100%.
This 48% glyphosate triisopropanolamine salt aqua outward appearance is rufous transparency liquid, and hot and cold storage has good stability, and dilution stability is qualified.
Embodiment 20
Field control effectiveness test:
Reagent agent:
4 kinds of gyphosate solutions such as embodiment 4,7,10 and 13.
Contrast medicament:
41% glyphosate-isopropylammonium aqua (commercially available).
Prevent and kill off object:
Broad leaved weed: knotweed, little lamb's-quarters and artemisia annua etc., grassy weed: green foxtail, wild oat and eleusine indica etc.
Test method:
According to the area of experimental plot, the good various medicament of precise, and after being watered dilution, utilize knapsack sprayer, carry out even spraying, the Fan spray head that sprinkler selection weed killer herbicide is special.During spraying, liquid be noted evenly to spray application in experimental plot, accomplish the phenomenon not having drain spray, many sprays.
After test, after medicine, 15d, 30d observe weeds death condition respectively, and the activity of weeding of more various medicament.
Embodiments of the invention preparation Herbicidal Testing Trials effect sees the following form (after medicine 15d)
Embodiments of the invention preparation Herbicidal Testing Trials effect sees the following form (after medicine 30d)
Field control effectiveness test result shows, under the condition that glyphosate content is identical, the herbicidal effect of the gyphosate solution utilizing the present invention to prepare is remarkable, illustrates that the present invention is remarkable to gyphosate solution synergistic effect.
Claims (8)
1. one kind is applicable to multiple glyphosate salt aqua auxiliary agent, it is characterized in that this auxiliary agent is applied widely, can be used as the synergist of the multiple gyphosate solution comprising ammonium glyphosate, isopropyl amine salt, dimethylamine salt, ethanolamine salt, triisopropanolamine salt, triethylamine salt, trimethyl sulfosalt and sylvite etc.
2. be applicable to multiple glyphosate salt aqua auxiliary agent according to the one described in claim 1, the surface active agent composition that it is characterized in that wherein is selected from 3 to 5 kinds in the surfactants such as alkyl glycoside, lauroylamidopropyl betaine, Cocoamidopropyl betaine, sodium lauroyl sarcosine, cocoyl propylhomoserin sodium, 13 isomeric alcohol polyethenoxy ether, fatty alcohol-polyoxyethylene ether, DDAO, cocamidopropyl propyl amide sodium oxide molybdena.
3. be applicable to multiple glyphosate salt aqua auxiliary agent according to the one described in claim 1-2, it is characterized in that described auxiliary agent is preferably made up of 4 kinds of surfactants such as Cocoamidopropyl betaine, cocoyl sarcosine sodium, 13 isomeric alcohol polyethenoxy ether and alkyl glycoside.
4. be applicable to multiple glyphosate salt aqua auxiliary agent according to the one described in claim 1-3, it is characterized in that except containing except 4 kinds of surfactants such as Cocoamidopropyl betaine, cocoyl sarcosine sodium, 13 isomeric alcohol polyethenoxy ether and alkyl glycoside, also containing a certain amount of ammonium sulfate and water.
5. be applicable to multiple glyphosate salt aqua auxiliary agent according to the one described in claim 1-4, wherein various material component calculates according to mass percent and is:
。
6. be applicable to multiple glyphosate salt aqua auxiliary agent according to the one described in claim 1-5, it is characterized in that being applicable to the consumption of described auxiliary agent in gyphosate solution is 5-20%.
7. be applicable to multiple glyphosate salt aqua auxiliary agent according to the one described in claim 1-6, it is characterized in that the storage-stable of the gyphosate solution of all size utilizing described auxiliary agent to prepare is better.
8. be applicable to multiple glyphosate salt aqua auxiliary agent according to the one described in claim 1-7, the various gyphosate solutions utilizing it to prepare are excellent to the preventive effect of weeds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310670072.2A CN104705297A (en) | 2013-12-11 | 2013-12-11 | Aid suitable for multiple glyphosate salt water agents |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310670072.2A CN104705297A (en) | 2013-12-11 | 2013-12-11 | Aid suitable for multiple glyphosate salt water agents |
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| CN104705297A true CN104705297A (en) | 2015-06-17 |
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| CN201310670072.2A Pending CN104705297A (en) | 2013-12-11 | 2013-12-11 | Aid suitable for multiple glyphosate salt water agents |
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Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106172391A (en) * | 2016-07-05 | 2016-12-07 | 南京科翼新材料有限公司 | A kind of agricultural builder containing sodium cocoyl glutamate |
| CN106172390A (en) * | 2016-07-05 | 2016-12-07 | 南京科翼新材料有限公司 | A kind of gyphosate solution builder containing methyl gluceth |
| CN106212453A (en) * | 2016-07-05 | 2016-12-14 | 南京科翼新材料有限公司 | A kind of glufosinate-ammoniumaqua aqua builder containing trimethylamino acid |
| CN108308180A (en) * | 2018-04-12 | 2018-07-24 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and glufosinate-ammonium |
| CN108402040A (en) * | 2018-04-12 | 2018-08-17 | 南京科翼新材料有限公司 | A kind of auxiliary agent suitable for glufosinate-ammonium sylvine aqua |
| CN108477153A (en) * | 2018-04-12 | 2018-09-04 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and Mediben |
| CN108684704A (en) * | 2018-07-09 | 2018-10-23 | 南开大学 | A kind of ammonium glyphosate builder composition and its application |
| CN109221131A (en) * | 2018-10-31 | 2019-01-18 | 安徽省锦江农化有限公司 | A kind of aqua containing amino-oligosaccharide and kasugarnycin and its application |
| CN110547294A (en) * | 2019-08-19 | 2019-12-10 | 南京拓际生物科技有限公司 | Preparation research method of special auxiliary agent for glyphosate granules |
| CN110583688A (en) * | 2019-09-30 | 2019-12-20 | 广西拜科生物科技有限公司 | Synergistic pesticide containing glyphosate |
| CN110800735A (en) * | 2019-10-12 | 2020-02-18 | 惠州市银农科技股份有限公司 | Microemulsion with emamectin benzoate as effective component and preparation method thereof |
| CN111466377A (en) * | 2020-05-29 | 2020-07-31 | 广东省科学院产业技术育成中心 | Herbicide adjuvant and preparation method thereof |
| CN112087949A (en) * | 2018-03-09 | 2020-12-15 | 欧罗分奥切米卡公司 | High-load glyphosate herbicidal compositions, ready-to-use formulations obtained therefrom and methods for controlling various weed species in crops |
| CN112772672A (en) * | 2021-01-22 | 2021-05-11 | 济南天邦化工有限公司 | Environment-friendly glyphosate aqueous solution and preparation method thereof |
| CN114423287A (en) * | 2019-09-20 | 2022-04-29 | 罗地亚经营管理公司 | Stable herbicide composition comprising amine oxide and tertiary amine |
| CN114431226A (en) * | 2022-02-21 | 2022-05-06 | 广东粤港澳大湾区国家纳米科技创新研究院 | Thickening aid suitable for high-salt water aqua |
| CN114557340A (en) * | 2022-03-15 | 2022-05-31 | 浙江新安化工集团股份有限公司 | Low-foam anti-crystallization pesticide aqueous solution and preparation process thereof |
| CN114680130A (en) * | 2020-12-25 | 2022-07-01 | 南通泰禾化工股份有限公司 | Glyphosate isopropylamine soluble agent and preparation method thereof |
| CN115281187A (en) * | 2022-08-11 | 2022-11-04 | 北京广源益农化学有限责任公司 | Stable pesticide synergist and preparation method thereof |
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| CN106172391B (en) * | 2016-07-05 | 2020-04-07 | 南京科翼新材料有限公司 | Agricultural synergistic additive containing sodium cocoyl glutamate |
| CN106172390A (en) * | 2016-07-05 | 2016-12-07 | 南京科翼新材料有限公司 | A kind of gyphosate solution builder containing methyl gluceth |
| CN106212453A (en) * | 2016-07-05 | 2016-12-14 | 南京科翼新材料有限公司 | A kind of glufosinate-ammoniumaqua aqua builder containing trimethylamino acid |
| CN106172391A (en) * | 2016-07-05 | 2016-12-07 | 南京科翼新材料有限公司 | A kind of agricultural builder containing sodium cocoyl glutamate |
| CN106212453B (en) * | 2016-07-05 | 2019-09-20 | 南京科翼新材料有限公司 | A kind of glufosinate-ammoniumaqua aqua builder of the acid containing trimethylamino |
| CN112087949A (en) * | 2018-03-09 | 2020-12-15 | 欧罗分奥切米卡公司 | High-load glyphosate herbicidal compositions, ready-to-use formulations obtained therefrom and methods for controlling various weed species in crops |
| CN108308180A (en) * | 2018-04-12 | 2018-07-24 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and glufosinate-ammonium |
| CN108402040A (en) * | 2018-04-12 | 2018-08-17 | 南京科翼新材料有限公司 | A kind of auxiliary agent suitable for glufosinate-ammonium sylvine aqua |
| CN108477153A (en) * | 2018-04-12 | 2018-09-04 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and Mediben |
| CN108684704A (en) * | 2018-07-09 | 2018-10-23 | 南开大学 | A kind of ammonium glyphosate builder composition and its application |
| CN109221131A (en) * | 2018-10-31 | 2019-01-18 | 安徽省锦江农化有限公司 | A kind of aqua containing amino-oligosaccharide and kasugarnycin and its application |
| CN110547294A (en) * | 2019-08-19 | 2019-12-10 | 南京拓际生物科技有限公司 | Preparation research method of special auxiliary agent for glyphosate granules |
| CN114423287A (en) * | 2019-09-20 | 2022-04-29 | 罗地亚经营管理公司 | Stable herbicide composition comprising amine oxide and tertiary amine |
| CN110583688A (en) * | 2019-09-30 | 2019-12-20 | 广西拜科生物科技有限公司 | Synergistic pesticide containing glyphosate |
| CN110800735A (en) * | 2019-10-12 | 2020-02-18 | 惠州市银农科技股份有限公司 | Microemulsion with emamectin benzoate as effective component and preparation method thereof |
| CN110800735B (en) * | 2019-10-12 | 2020-12-11 | 惠州市银农科技股份有限公司 | Microemulsion with emamectin benzoate as effective component and preparation method thereof |
| CN111466377A (en) * | 2020-05-29 | 2020-07-31 | 广东省科学院产业技术育成中心 | Herbicide adjuvant and preparation method thereof |
| CN114680130A (en) * | 2020-12-25 | 2022-07-01 | 南通泰禾化工股份有限公司 | Glyphosate isopropylamine soluble agent and preparation method thereof |
| CN114680130B (en) * | 2020-12-25 | 2023-12-22 | 南通泰禾化工股份有限公司 | Glyphosate isopropylamine salt soluble solution and preparation method thereof |
| CN112772672A (en) * | 2021-01-22 | 2021-05-11 | 济南天邦化工有限公司 | Environment-friendly glyphosate aqueous solution and preparation method thereof |
| CN112772672B (en) * | 2021-01-22 | 2022-05-24 | 济南天邦化工有限公司 | Environment-friendly glyphosate aqueous solution and preparation method thereof |
| CN114431226A (en) * | 2022-02-21 | 2022-05-06 | 广东粤港澳大湾区国家纳米科技创新研究院 | Thickening aid suitable for high-salt water aqua |
| CN114557340A (en) * | 2022-03-15 | 2022-05-31 | 浙江新安化工集团股份有限公司 | Low-foam anti-crystallization pesticide aqueous solution and preparation process thereof |
| CN115281187A (en) * | 2022-08-11 | 2022-11-04 | 北京广源益农化学有限责任公司 | Stable pesticide synergist and preparation method thereof |
| CN115281187B (en) * | 2022-08-11 | 2023-11-24 | 北京广源益农化学有限责任公司 | Stable pesticide synergist and preparation method thereof |
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