CN110583688A - Synergistic pesticide containing glyphosate - Google Patents
Synergistic pesticide containing glyphosate Download PDFInfo
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- CN110583688A CN110583688A CN201910942880.7A CN201910942880A CN110583688A CN 110583688 A CN110583688 A CN 110583688A CN 201910942880 A CN201910942880 A CN 201910942880A CN 110583688 A CN110583688 A CN 110583688A
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- glyphosate
- synergist
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/08—Magnoliopsida [dicotyledons]
- A01N65/38—Solanaceae [Potato family], e.g. nightshade, tomato, tobacco or chilli pepper
- A01N65/385—Tobacco
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a glyphosate-containing synergistic pesticide, the active ingredients of which are glyphosate-containing compound and synergist; the synergist consists of cembrane diterpene and phytic acid, the mass ratio of the glyphosate-containing compound to the synergist is 100:1-30, and the mass ratio of the cembrane diterpene to the phytic acid is 1-3: 1. The invention compounds the cembrane diterpenoid and phytic acid synergist and the glyphosate-containing compound, so that the herbicide has obvious synergistic effect, the glyphosate effect is enhanced, the acting time is shortened, the use amount of the herbicide is reduced, and the glyphosate pesticide has the advantages of broad spectrum, high efficiency, low toxicity, low pollution, quick response, low cost, simple use and operation after synergism, and the cost performance is obviously improved. And the used synergist is plant extract, is environment-friendly, causes little pollution and reduces the cost.
Description
Technical Field
The invention belongs to the technical field of pesticides, and particularly relates to a synergistic pesticide containing glyphosate.
Background
Glyphosate is a herbicide with the largest use and sale rate all over the world, is famous for strong systemic conductivity in plants, has the advantages of broad spectrum, biocidal property, high efficiency, low toxicity, low residue and environmental friendliness, is widely applied to fields such as farmlands, orchards, woodlands, parks, roads, riverways, factories, warehouses and the like, and prevents and removes various annual, biennial and perennial weeds, shrubs, ferns, algae and the like. With the increasing popularity of glyphosate, the dosage is obviously increased, and the glyphosate is used for many times every year, so that the no-tillage area is enlarged. Over-dependence and long-term use of herbicides with the same action mechanism can lead to the migration and resistance of weed communities, and under the action of selective pressure, the resistance or tolerance of weeds to the weed communities is obviously enhanced.
The pesticide synergist is a compound basically without biological activity, and when the pesticide synergist is mixed with chemical pesticides, the surface tension of the chemical pesticides can be improved, the spreading, dispersion, permeability and the like are improved, the wetting, spreading, permeation and absorption of chemical pesticide liquid on plant leaf surfaces are facilitated, the biological activity of the chemical pesticides can be improved, the effective period of pesticide effect is prolonged, the pesticide utilization rate is improved, the pesticide residue is reduced, the cost is reduced, and the purpose of protecting ecological environment is achieved. Therefore, the synergist is an effective way to enhance the efficacy of glyphosate through research. Although many current researches on synergists are reported, most of the synergists have specificity on pesticides, the current synergists for glyphosate products generally have the defects of unobvious synergistic effect, poor quick-acting performance and the like.
The above background disclosure is only for the purpose of assisting understanding of the inventive concept and technical solutions of the present invention, and does not necessarily belong to the prior art of the present patent application, and should not be used for evaluating the novelty and inventive step of the present application in the case that there is no clear evidence that the above content is disclosed at the filing date of the present patent application.
Disclosure of Invention
The invention aims to provide a synergist which can obviously improve the drug effect of glyphosate and reduce the usage amount of glyphosate.
In order to achieve the above purpose, the technical scheme adopted by the invention is as follows:
a synergistic pesticide containing glyphosate is characterized in that: the active ingredients of the glyphosate-containing compound are glyphosate-containing compound and synergist; the synergist consists of cembrane diterpene and phytic acid, and the mass ratio of the glyphosate-containing compound to the synergist is 100: 1-30.
Further, the mass ratio of the cembrane diterpenoid to the phytic acid is 1-3: 1.
Further, the Cembranoid diterpenes (Cembranoid diterpenes) are macrocyclic diterpenes formed by connecting 4 isoprenes end to end, and are natural products of which the parent frameworks are provided with fourteen-membered rings and 3 symmetrically distributed methyl groups and 1 isopropyl group. Can be extracted from Corallium japonicum Kishinouye, tobacco, sea fan, Sargassum, and Colophonium. Preferably, the cembrane diterpene is extracted from tobacco.
Further, the glyphosate-containing compound is glyphosate acid and/or a glyphosate acid active derivative.
Further, the active glyphosate derivative is one or more of glyphosate ammonium salt, glyphosate isopropylamine salt, glyphosate potassium salt, glyphosate sodium salt, glyphosate dimethylammonium salt, glyphosate trimethylsulfonium salt and other salts.
On the other hand, the invention also provides a preparation formulation prepared from the glyphosate-containing synergistic pesticide, and the pesticide is prepared into an aqueous solution, an aqueous emulsion, a wettable powder, a soluble granule, a water dispersible granule, a suspending agent, an oil suspending agent, a tablet or an effervescent granule by adding an auxiliary agent besides the glyphosate-containing compound and the synergistic agent. The glyphosate compound and the synergist account for 30-90% of the dosage form by weight.
In a third aspect, the invention also provides a glyphosate-containing aqueous pesticide, which comprises 30-35% of glyphosate compound, 10-15% of synergist, 5-10% of emulsifier, 3-5% of penetrant, 0.5-2% of defoamer and 1-3% of antifreeze according to percentage; the balance being water.
Preferably, the emulsifier comprises one or more of alkylphenol ethoxylates, cocamidopropyl betaine, sodium dodecyl sulfate, acrylic rosin polyoxyethylene sucrose ester and polyoxyethylene fatty amide.
Preferably, the penetrant comprises one or more of organosilicon penetrant, sodium butyl ricinoleate sulfate, N-methyl pyrrolidone, N-dodecyl pyrrolidone and azone penetrant.
Preferably, the defoaming agent comprises one or more of emulsified silicone oil, polyoxyethylene polyoxypropylene pentaerythritol ether and polydimethylsiloxane.
Preferably, the antifreeze agent comprises one or more of glycerol, ethylene glycol, triethanolamine and triisopropanolamine.
Compared with the prior art, the invention has the advantages and beneficial effects that:
the invention compounds the cembrane diterpenoid and phytic acid synergist and the glyphosate-containing compound, so that the herbicide has obvious synergistic effect, the glyphosate effect is enhanced, the acting time is shortened, the use amount of the herbicide is reduced, and the glyphosate pesticide has the advantages of broad spectrum, high efficiency, low toxicity, low pollution, quick response, low cost, simple use and operation after synergism, and the cost performance is obviously improved. And the used synergist is plant extract, is environment-friendly, causes little pollution and reduces the cost.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments. It should be emphasized that the following description is merely exemplary in nature and is not intended to limit the scope of the invention or its application.
Example 1
Mixing glyphosate and a synergist according to the proportion shown in table 1 to prepare an aqueous pesticide, wherein the mass percentage of the glyphosate and the synergist in the aqueous pesticide is 40%, and on the basis of the original pesticide, 10% of alkylphenol polyoxyethylene ether emulsifier, 3% of organic silicon penetrant, 1% of silicone emulsion defoamer, 0.5% of glycol antifreeze and the balance of water are added. The preparation method comprises stirring the above components uniformly.
Table 1: mixing glyphosate and synergist according to different proportions
| Serial number | Glyphosate | Cedarane diterpene | Phytic acid |
| A | 30％ | A | A |
| B | 30％ | 10％ | A |
| C | 30％ | A | 10％ |
| D | 30％ | 5％ | 5％ |
The A, B, C, D groups of glyphosate aqueous products were subjected to field tests according to the following method, and the test results are shown in table 2.
The test method comprises the following steps: selecting the land with abundant growth and leaving a plurality of weed types (the weeds are mainly green bristlegrass herb, bermudagrass, ageratum conyzoides, cyperus rotundus and the like) after the sugarcane is harvested in the last year, carrying out a pesticide effect test, and spraying the water stem leaves with the amount of 300 ml/mu to prevent and control the field weeds.
Control effect (%) < 100% (weight of weeds in treated area/fresh weight of weeds before test)%
The investigation method comprises the following steps: the part above the ground is cut by scissors, and the fresh weight is weighed, and the sampling time is 3 days, 7 days and 15 days.
The embodiment is applied to the control effect of weeds in sugarcane fields
From the field test results, the invention has the advantages that after the cembrane diterpenoid and the phytic acid are added into the glyphosate raw pesticide for compounding, the effect is fast, and the weeding effect is better. (B, C test results should be interchanged)
Example 2
In order to investigate that glyphosate and a synergist are prepared into an aqueous pesticide according to different proportions, the mass percent of glyphosate in the aqueous pesticide is 30%, wherein the synergist consists of cembrane diterpene and phytic acid in a mass ratio of 1: 1. Based on the original medicine, 10 percent of alkylphenol polyoxyethylene ether emulsifier, 3 percent of organic silicon penetrating agent, 1 percent of emulsified silicone oil defoamer, 0.5 percent of glycol antifreeze and the balance of water are added. The results of the field test were carried out in the same manner as in example 1, and the results are shown in Table 3.
Table 3: investigating the control effect of different proportions of glyphosate and synergist on weeds in sugarcane fields
From the above test results, it is known that when glyphosate: the synergistic effect is gradually enhanced when the ratio of the synergist is 100:1-30, the enhanced effect is optimal when the ratio is 100:30, and the enhanced effect is weakened when the ratio is more than 100:50, and the ratio of the synergist to the synergist is 100:1-30 because the cost problem is considered.
Example 3
Investigating the synergistic effect of different proportions of cembrane diterpene and phytic acid in the synergist, and preparing an aqueous pesticide according to the different proportions of the cembrane diterpene and the phytic acid, wherein the mass percentage of the glyphosate in the aqueous pesticide is 30%, and the mass percentage of the synergist is 10%. Based on the original medicine, 10 percent of alkylphenol polyoxyethylene ether emulsifier, 3 percent of organic silicon penetrating agent, 1 percent of emulsified silicone oil defoamer, 0.5 percent of glycol antifreeze and the balance of water are added. The results of the field test were carried out in the same manner as in example 1, and the results are shown in Table 4.
TABLE 4 controlling effect of different proportions of synergist on weeds in sugarcane field
From the above results, it is found that the cembrane-type diterpene in the potentiator of the present invention: the phytic acid has better synergistic effect when the ratio is 1-3: 1.
Example 4
An aqueous pesticide containing glyphosate, which comprises 30 percent of glyphosate, 10 percent of synergist, 8 percent of cocamidopropyl betaine emulsifier, 4 percent of ricinoleic acid butyl ester sodium sulfate penetrant, 1.5 percent of polyoxyethylene polyoxypropylene pentaerythritol ether defoamer and 2 percent of triethanolamine antifreeze; the balance being water. The synergist is prepared from 2:1 of cembrane diterpene: phytic acid.
Example 5
An aqueous pesticide containing glyphosate, which comprises 35 percent of glyphosate ammonium salt, 12 percent of synergist, 5 percent of acrylic rosin polyoxyethylene sucrose ester emulsifier, 5 percent of N-methyl pyrrolidone penetrant, 2 percent of polydimethylsiloxane defoamer and 1.5 percent of triisopropanolamine antifreeze agent; the balance being water. The synergist is prepared from 3:1 of cembrane diterpene: phytic acid.
Example 6
An aqueous pesticide containing glyphosate, which comprises 33 percent of glyphosate dimethyl ammonium salt, 15 percent of synergist, 5 percent of acrylic rosin polyoxyethylene sucrose ester emulsifier, 5 percent of N-methyl pyrrolidone penetrant, 2 percent of polydimethylsiloxane defoamer and 1 percent of N-dodecyl pyrrolidone antifreeze; the balance being water. The synergist is prepared from 1:1 of cembrane diterpene: phytic acid.
Example 7
An aqueous pesticide containing glyphosate, which comprises 30 percent of glyphosate potassium salt, 10 percent of synergist, 10 percent of polyoxyethylene fatty amide emulsifier, 3 percent of azone penetrant, 1.5 percent of polydimethylsiloxane defoamer and 2 percent of N-dodecyl pyrrolidone antifreeze; the balance being water. The synergist is prepared from 1:1 of cembrane diterpene: phytic acid.
Example 8
An aqueous pesticide containing glyphosate, which comprises 35 percent of glyphosate potassium salt, 13 percent of synergist, 10 percent of polyoxyethylene fatty amide emulsifier, 3 percent of azone penetrant, 1.5 percent of polydimethylsiloxane defoamer and 2 percent of N-dodecyl pyrrolidone antifreeze; the balance being water. The synergist is prepared from 2:1 of cembrane diterpene: phytic acid.
The aqueous glyphosate pesticides prepared in examples 4 to 8 were subjected to field tests in the same manner as in example 1, and the test results are shown in table 5.
Table 5: the glyphosate-containing aqueous pesticide has the effect of preventing and treating weeds in sugarcane fields
In conclusion, the invention compounds the cembrane diterpenoid and phytic acid synergist and the glyphosate-containing compound, so that the herbicide has obvious synergistic action, the glyphosate efficacy is enhanced, the onset time is shortened, the use amount of the herbicide is reduced, and the glyphosate pesticide has the advantages of broad spectrum, high efficiency, low toxicity, low pollution, quick effect, low cost, simple use and operation after synergism, and the cost performance is obviously improved.
The foregoing is a more detailed description of the invention in connection with specific/preferred embodiments and is not intended to limit the practice of the invention to those descriptions. It will be apparent to those skilled in the art that various substitutions and modifications can be made to the described embodiments without departing from the spirit of the invention, and such substitutions and modifications are to be considered as within the scope of the invention.
Claims (10)
1. A synergistic pesticide containing glyphosate is characterized in that: the active ingredients of the glyphosate-containing compound are glyphosate-containing compound and synergist; the synergist consists of cembrane diterpene and phytic acid, and the mass ratio of the glyphosate-containing compound to the synergist is 100: 1-30.
2. The glyphosate-containing synergistic pesticide of claim 1, wherein: the mass ratio of the cembrane diterpenoid to the phytic acid is 1-3: 1.
3. The glyphosate-containing synergistic pesticide of claim 1, wherein: the cembrane diterpene is an extract obtained by separating tobacco.
4. The glyphosate-containing synergistic pesticide of claim 1, wherein: the glyphosate-containing compound is glyphosate acid and/or an active derivative of the glyphosate acid.
5. The glyphosate-containing synergistic pesticide of claim 4, wherein: the active glyphosate derivative is one or more of glyphosate ammonium salt, glyphosate isopropylamine salt, glyphosate potassium salt, glyphosate sodium salt, glyphosate dimethylammonium salt, glyphosate trimethylsulfonium salt and other salts.
6. The glyphosate-containing synergistic pesticide of claim 1, wherein: the pesticide contains the glyphosate compound and the synergist, and is also added with an auxiliary agent to prepare an aqueous solution, an aqueous emulsion, a wettable powder, a soluble granule, a water dispersible granule, a suspending agent, an oil suspending agent, a tablet or an effervescent granule; the glyphosate compound and the synergist account for 30-90% of the dosage form by weight.
7. The aqueous glyphosate-containing pesticide as set forth in claim 6, characterized in that: the aqueous pesticide comprises 30-35% of glyphosate compound, 10-15% of synergist, 5-10% of emulsifier, 3-5% of penetrant, 0.5-2% of defoaming agent and 1-3% of antifreezing agent by percentage; the balance being water.
8. An aqueous glyphosate containing pesticide according to claim 7, characterized in that: the emulsifier comprises one or more of alkylphenol polyoxyethylene, cocamidopropyl betaine, sodium dodecyl sulfate, acrylic rosin polyoxyethylene sucrose ester and polyoxyethylene fatty amide.
9. An aqueous glyphosate containing pesticide according to claim 7, characterized in that: the penetrating agent comprises one or more of organic silicon penetrating agent, ricinoleic acid butyl ester sodium sulfate, N-methyl pyrrolidone, N-dodecyl pyrrolidone and azone penetrating agent.
10. An aqueous glyphosate containing pesticide according to claim 7, characterized in that: the defoaming agent comprises one or more of emulsified silicone oil, polyoxyethylene polyoxypropylene pentaerythritol ether and polydimethylsiloxane; the antifreezing agent comprises one or more of glycerol, ethylene glycol, triethanolamine and triisopropanolamine.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201910942880.7A CN110583688A (en) | 2019-09-30 | 2019-09-30 | Synergistic pesticide containing glyphosate |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910942880.7A CN110583688A (en) | 2019-09-30 | 2019-09-30 | Synergistic pesticide containing glyphosate |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111771879A (en) * | 2020-07-15 | 2020-10-16 | 南京拓呗新材料科技有限公司 | Special efficient synergist for dimethylglyphosate aqueous solution and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1545881A (en) * | 2003-12-04 | 2004-11-17 | 吴云清 | Synergy auxiliary agent of glyphosate isopropyl amine brine agent |
| CN1715281A (en) * | 2004-06-14 | 2006-01-04 | 中国科学院南海海洋研究所 | Cembranoid |
| CN1948302A (en) * | 2006-06-13 | 2007-04-18 | 中国科学院南海海洋研究所 | Cesong alkyl type diterpine, its preparation method and use |
| CN102165959A (en) * | 2011-03-16 | 2011-08-31 | 天津市艾普伦生物科技有限公司 | Glyphosate environment-friendly aqueous agent using biodiesel as synergist |
| CN102432384A (en) * | 2011-09-22 | 2012-05-02 | 南通派斯第农药化工有限公司 | 41% glyphosate and preparation method thereof |
| CN102640750A (en) * | 2012-04-25 | 2012-08-22 | 南京太化化工有限公司 | Special adjuvant of glyphosate potassium salt aqueous solution and salt aqueous solution using same |
| CN103238625A (en) * | 2012-02-10 | 2013-08-14 | 李庆晨 | Glyphosate isopropamide salt water agent environment-friendly synergist and preparation method thereof |
| CN104705297A (en) * | 2013-12-11 | 2015-06-17 | 南京科翼新材料有限公司 | Aid suitable for multiple glyphosate salt water agents |
-
2019
- 2019-09-30 CN CN201910942880.7A patent/CN110583688A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1545881A (en) * | 2003-12-04 | 2004-11-17 | 吴云清 | Synergy auxiliary agent of glyphosate isopropyl amine brine agent |
| CN1715281A (en) * | 2004-06-14 | 2006-01-04 | 中国科学院南海海洋研究所 | Cembranoid |
| CN1948302A (en) * | 2006-06-13 | 2007-04-18 | 中国科学院南海海洋研究所 | Cesong alkyl type diterpine, its preparation method and use |
| CN102165959A (en) * | 2011-03-16 | 2011-08-31 | 天津市艾普伦生物科技有限公司 | Glyphosate environment-friendly aqueous agent using biodiesel as synergist |
| CN102432384A (en) * | 2011-09-22 | 2012-05-02 | 南通派斯第农药化工有限公司 | 41% glyphosate and preparation method thereof |
| CN103238625A (en) * | 2012-02-10 | 2013-08-14 | 李庆晨 | Glyphosate isopropamide salt water agent environment-friendly synergist and preparation method thereof |
| CN102640750A (en) * | 2012-04-25 | 2012-08-22 | 南京太化化工有限公司 | Special adjuvant of glyphosate potassium salt aqueous solution and salt aqueous solution using same |
| CN104705297A (en) * | 2013-12-11 | 2015-06-17 | 南京科翼新材料有限公司 | Aid suitable for multiple glyphosate salt water agents |
Non-Patent Citations (3)
| Title |
|---|
| 任晋等: "西松烷型大环二萜类化合物研究进展", 《中草药》 * |
| 李国强等: "西松烷二萜类海洋活性成分研究进展", 《中国海洋大学学报(自然科学版)》 * |
| 龙康侯等: "《萜类化学》", 30 June 1984, 高等教育出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111771879A (en) * | 2020-07-15 | 2020-10-16 | 南京拓呗新材料科技有限公司 | Special efficient synergist for dimethylglyphosate aqueous solution and preparation method thereof |
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Application publication date: 20191220 |