CN103210915A - Agricultural thickening synergist and application thereof - Google Patents
Agricultural thickening synergist and application thereof Download PDFInfo
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- CN103210915A CN103210915A CN2013101535644A CN201310153564A CN103210915A CN 103210915 A CN103210915 A CN 103210915A CN 2013101535644 A CN2013101535644 A CN 2013101535644A CN 201310153564 A CN201310153564 A CN 201310153564A CN 103210915 A CN103210915 A CN 103210915A
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Abstract
The invention discloses an agricultural thickening synergist. The agricultural thickening synergist comprises the following components by mass percent: 1-40% of fatty alcohol polyoxyethylene ether sulfate, 0-30% of alkyl glycoside, 5-15% of sodium lauroyl sarcosinate, 5-10% of sodium alkyl benzene sulfonate, 5-15% of ammonium sulfate and the balance of water. The invention also discloses an application of the agricultural thickening synergist in a glyphosate isopropamide salt water agent and a glyphosate salt water agent. The agricultural thickening synergist has the characteristics of better wetting synergy effect, more stable performance and better thickening synergy effect; by using the glyphosate salt water agent, the agricultural thickening synergist has high viscosity, the adhesive force and moisture property of the liquid medicine are improved, the internal absorption and conductivity of the glyphosate are realized, and the pharmacological function can be fully realized. Besides, the agricultural thickening synergist has excellent biological degradability, has high safety to the environment and organisms, and meets the development requirement of the agricultural surface active agent in the future.
Description
Technical field
The present invention relates to a kind of thickening builder, especially relate to a kind of special-purpose thickening builder of glyphosate isopropyl amine salt aqua, belong to the agricultural surfactant technical field.
Background technology
Fatty alcohol polyoxyethylene ether sulfate is a kind of typical anion surfactant, has simultaneously the performance of non-ionic surface active agent again, it is soluble in water, it is all extremely strong to have favorable biological degradability, detergency, foaming characteristic, emulsifiability and resistance to hard water etc., therefore is widely used in shampoo, cosmetics, family and the industrial detergent.
Fatty alcohol polyoxyethylene ether sulfate is as a kind of green auxiliary agent, begun on the farming product, to use in a large number, for example utilize its main body auxiliary agent as careless ammonium phosphine aqua, not only has synergistic effect preferably, and can significantly improve the viscosity of phosphine oxamate aqua, and then improve the adhesive force of preparation.But, directly utilize fatty alcohol polyoxyethylene ether sulfate on application technology, also to have certain limitation as the synergist of gyphosate solution, mainly be because glyphosate and salt thereof are incompatible in water with fatty alcohol polyoxyethylene ether sulfate, to such an extent as to fatty alcohol polyoxyethylene ether sulfate can't be as the synergist of gyphosate solution or a component in the synergist.
Summary of the invention
Be to solve the deficiencies in the prior art, the object of the present invention is to provide that a kind of thickening synergistic effect is good, environment compatibility and strong agricultural thickening builder and the application thereof of biological degradability.
For achieving the above object, the present invention is achieved by the following technical solutions:
A kind of agricultural thickening builder is characterized in that, comprises that the quality percentage composition of following component and each component is:
Fatty alcohol polyoxyethylene ether sulfate 1-40%;
Alkyl glycoside 10-30%;
Sodium N-lauroyl sarcosinate 5-15%;
Neopelex 5-10%;
Ammonium sulfate 5-15%;
Water surplus.
Further, the quality percentage composition of described fatty alcohol polyoxyethylene ether sulfate is preferably 5-25%.
And described fatty alcohol polyoxyethylene ether sulfate is sodium sulfate of polyethenoxy ether of fatty alcohol (AES) or AESA (AESA).
Above-mentioned agricultural thickening builder is applied to glyphosate isopropyl ammonium salt aqua.
Above-mentioned agricultural thickening builder is applied to the ammonium glyphosate aqua.
The invention has the beneficial effects as follows: the present invention is owing to contain fatty alcohol polyoxyethylene ether sulfate, it is better to make auxiliary agent itself have wetting synergy, the characteristics that performance is more stable, and the thickening synergistic effect is better, utilize the glyphosate class aqua of its preparation to have higher viscosity, help improving the adhesive force and the performance of keeping humidity of soup, more help the interior suction and the conductivity of glyphosate, can promote giving full play to of drug effect; And owing to also contain alkyl glycoside, sodium N-lauroyl sarcosinate and neopelex; make fatty alcohol polyoxyethylene ether sulfate and glyphosate class aqua have good environmental compatible; make auxiliary agent itself have excellent biological degradability simultaneously; environment and biology are had tight security, meet very much the demand for development of following agricultural surfactant.
Embodiment
Below in conjunction with specific embodiment the present invention is carried out concrete introduction.
Embodiment 1
A kind of agricultural thickening builder comprises that the quality percentage composition of following component and each component is: AES5%, alkyl glycoside 10%; sodium N-lauroyl sarcosinate 15%, neopelex 10%, ammonium sulfate 10%; water 50% forms according to the auxiliary agent mixing and stirring of routine.
Embodiment 2
A kind of agricultural thickening builder comprises that the quality percentage composition of following component and each component is: AES10%, alkyl glycoside 20%; sodium N-lauroyl sarcosinate 10%, neopelex 10%, ammonium sulfate 5%; water 45% forms according to the auxiliary agent mixing and stirring of routine.
Embodiment 3
A kind of agricultural thickening builder comprises that the quality percentage composition of following component and each component is: AES15%, alkyl glycoside 20%; sodium N-lauroyl sarcosinate 15%, neopelex 5%, ammonium sulfate 10%; water supplies 35%, forms according to the auxiliary agent mixing and stirring of routine.
Embodiment 4
A kind of agricultural thickening builder comprises that the quality percentage composition of following component and each component is: AESA20%, alkyl glycoside 25%; sodium N-lauroyl sarcosinate 5%, neopelex 5%, ammonium sulfate 5%; water 40% forms according to the auxiliary agent mixing and stirring of routine.
Embodiment 5
A kind of agricultural thickening builder comprises that the quality percentage composition of following component and each component is: AESA25%, alkyl glycoside 30%; sodium N-lauroyl sarcosinate 5%, neopelex 5%, ammonium sulfate 5%; water 30% forms according to the auxiliary agent mixing and stirring of routine.
Embodiment 6
Glyphosate isopropyl ammonium salt aqua
41% glyphosate isopropyl amine salt aqua, glyphosate isopropyl amine salt 41%(glyphosate 30%), embodiment 1 described agricultural thickening builder 10%, water 49% the quality percentage composition that comprises following component and each component is:, and utilize conventional pesticide preparation processing method formulated.
This 41% glyphosate isopropyl amine salt aqua outward appearance is faint yellow transparent thick liquid, and viscosity (25 ℃) is 270mPa.s, and cold and hot storage has good stability.
Embodiment 7
41% glyphosate isopropyl amine salt aqua, glyphosate isopropyl amine salt 41%(glyphosate 30%), embodiment 2 described agricultural thickening builders 10%, water 49% the quality percentage composition that comprises following component and each component is:, and utilize conventional pesticide preparation processing method formulated.
This 41% glyphosate isopropyl amine salt aqua outward appearance is faint yellow transparent thick liquid, and viscosity (25 ℃) is 280mPa.s, and cold and hot storage has good stability.
Embodiment 8
41% glyphosate isopropyl amine salt aqua, glyphosate isopropyl amine salt 41%(glyphosate 30%), embodiment 3 described agricultural thickening builders 10%, water 49% the quality percentage composition that comprises following component and each component is:, and utilize conventional pesticide preparation processing method formulated.
This 41% glyphosate isopropyl amine salt aqua outward appearance is faint yellow transparent thick liquid, and viscosity (25 ℃) is 310mPa.s, and cold and hot storage has good stability.
Embodiment 9
36% ammonium glyphosate aqua comprises that the quality percentage composition of following component and each component is: ammonium glyphosate 36%(glyphosate 30%), and embodiment 4 described agricultural thickening builders 10%, water 54%, and utilize conventional pesticide preparation processing method formulated.
This 36% ammonium glyphosate aqua outward appearance is the water white transparency thick liquid, and viscosity (25 ℃) is 240mPa.s, and cold and hot storage has good stability.
Embodiment 10
36% glyphosate isopropyl amine salt aqua, the quality percentage composition that comprises following component and each component is: ammonium glyphosate 36%(glyphosate 30%), embodiment 5 described agricultural thickening builders 10%, water 54%, and utilize conventional pesticide preparation processing method formulated.
This 36% ammonium glyphosate aqua outward appearance is the water white transparency thick liquid, and viscosity (25 ℃) is 270mPa.s, and cold and hot storage has good stability.
Embodiment 11
The biologicall test experiment
Field control effectiveness test:
Reagent agent:
5 kinds of gyphosate solutions among the embodiment 6～10.
The contrast medicament:
41% glyphosate isopropyl ammonium salt aqua (commercially available).
Prevent and kill off object:
Wasteland weeds such as annual fleabane herb, little lamb's-quarters, green foxtail, eleusine indica.
Test method:
According to the area of experimental plot, the accurate good various medicaments of weighing, and after converting the water dilution, utilize knapsack sprayer, and carrying out even spraying, shower nozzle is selected the Fan spray head of weed killer herbicide special use for use.During spraying, note soup is evenly sprayed application in the experimental plot, accomplish not leak the phenomenon of spray, many sprays.
After the test respectively behind medicine 15d, 30d observe the weeds death condition, and the activity of weeding of more various medicaments.
Table 1: embodiments of the invention preparation weeding test effect see the following form (15d behind the medicine)
Table 2: embodiments of the invention preparation weeding test effect see the following form (30d behind the medicine)
Show by the field control effectiveness test result shown in table 1 and the table 2, utilize the herbicidal effect of the gyphosate solution that the present invention prepares remarkable, illustrate that the present invention is remarkable to the gyphosate solution synergistic effect.
The present invention is illustrated according to the foregoing description, should be appreciated that the foregoing description does not limit the present invention in any form, and all employings are equal to replaces or technical scheme that the equivalent transformation mode is obtained, all drops within protection scope of the present invention.
Claims (5)
1. an agricultural thickening builder is characterized in that, comprises that the quality percentage composition of following component and each component is:
Fatty alcohol polyoxyethylene ether sulfate 1-40%;
Alkyl glycoside 10-30%;
Sodium N-lauroyl sarcosinate 5-15%;
Neopelex 5-10%;
Ammonium sulfate 5-15%;
Water surplus.
2. a kind of agricultural thickening builder according to claim 1 is characterized in that the quality percentage composition of described fatty alcohol polyoxyethylene ether sulfate is 5-25%.
3. a kind of agricultural thickening builder according to claim 1 and 2 is characterized in that described fatty alcohol polyoxyethylene ether sulfate is sodium sulfate of polyethenoxy ether of fatty alcohol or AESA.
4. the described agricultural thickening builder of claim 1 is applied to glyphosate isopropyl ammonium salt aqua.
5. the described agricultural thickening builder of claim 1 is applied to the ammonium glyphosate aqua.
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| CN201310153564.4A CN103210915B (en) | 2013-04-28 | 2013-04-28 | Agricultural thickening synergist and application thereof |
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| CN201310153564.4A CN103210915B (en) | 2013-04-28 | 2013-04-28 | Agricultural thickening synergist and application thereof |
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| CN103210915B CN103210915B (en) | 2015-05-27 |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104068048A (en) * | 2014-05-27 | 2014-10-01 | 安徽省益农化工有限公司 | Glyphosate synergist |
| CN104403674A (en) * | 2014-12-15 | 2015-03-11 | 成都新朝阳作物科学有限公司 | Soil conditioner for adjusting soil physical and chemical properties, and preparation method of soil conditioner |
| CN104705297A (en) * | 2013-12-11 | 2015-06-17 | 南京科翼新材料有限公司 | Aid suitable for multiple glyphosate salt water agents |
| CN104705293A (en) * | 2013-12-11 | 2015-06-17 | 南京科翼新材料有限公司 | Suspending agent aid for pesticide with high concentration of electrolyte |
| CN104814008A (en) * | 2015-03-25 | 2015-08-05 | 深圳市长园嘉彩环境材料有限公司 | Special thickening and efficiency-improving aid for ammonium glyphosate |
| CN107568216A (en) * | 2017-08-02 | 2018-01-12 | 湖北泰盛化工有限公司 | A kind of glyphosate isopropylamine salt water solution auxiliary agent |
| CN108402040A (en) * | 2018-04-12 | 2018-08-17 | 南京科翼新材料有限公司 | A kind of auxiliary agent suitable for glufosinate-ammonium sylvine aqua |
| CN108432799A (en) * | 2018-04-12 | 2018-08-24 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and 2,4 drops |
| CN108477153A (en) * | 2018-04-12 | 2018-09-04 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and Mediben |
| CN108542796A (en) * | 2018-07-20 | 2018-09-18 | 广州天赐高新材料股份有限公司 | A kind of amino acid is from thickened systems |
| CN110547294A (en) * | 2019-08-19 | 2019-12-10 | 南京拓际生物科技有限公司 | Preparation research method of special auxiliary agent for glyphosate granules |
| CN110663687A (en) * | 2019-10-23 | 2020-01-10 | 河北天发生物科技有限公司 | Emulsifier and application of auxiliary agent containing emulsifier in pesticide preparation processing |
| CN111869663A (en) * | 2020-08-20 | 2020-11-03 | 南京拓凯新材料科技有限公司 | Synergistic low-foam type triflumuron water agent auxiliary agent and preparation process thereof |
| CN112075450A (en) * | 2020-09-25 | 2020-12-15 | 河南豫松环保科技有限公司 | Novel herbicide and preparation method thereof |
| CN112640894A (en) * | 2020-12-14 | 2021-04-13 | 剑胜作物科技(江苏盐城)有限责任公司 | Preparation method of agricultural synergistic additive containing lecithin |
| CN113207874A (en) * | 2021-03-25 | 2021-08-06 | 安徽瑞然生物药肥科技有限公司 | Glyphosate isopropylamine salt aqueous solution and production method thereof |
| CN114431226A (en) * | 2022-02-21 | 2022-05-06 | 广东粤港澳大湾区国家纳米科技创新研究院 | Thickening aid suitable for high-salt water aqua |
| CN115868487A (en) * | 2022-12-29 | 2023-03-31 | 南京科翼新材料有限公司 | Thickening synergistic additive suitable for refined glufosinate-ammonium and 2,4-drop compound aqueous solution |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104705297A (en) * | 2013-12-11 | 2015-06-17 | 南京科翼新材料有限公司 | Aid suitable for multiple glyphosate salt water agents |
| CN104705293A (en) * | 2013-12-11 | 2015-06-17 | 南京科翼新材料有限公司 | Suspending agent aid for pesticide with high concentration of electrolyte |
| CN104068048A (en) * | 2014-05-27 | 2014-10-01 | 安徽省益农化工有限公司 | Glyphosate synergist |
| CN104403674A (en) * | 2014-12-15 | 2015-03-11 | 成都新朝阳作物科学有限公司 | Soil conditioner for adjusting soil physical and chemical properties, and preparation method of soil conditioner |
| CN104403674B (en) * | 2014-12-15 | 2017-11-14 | 成都新朝阳作物科学有限公司 | Soil conditioner for adjusting soil physical and chemical property and preparation method thereof |
| CN104814008A (en) * | 2015-03-25 | 2015-08-05 | 深圳市长园嘉彩环境材料有限公司 | Special thickening and efficiency-improving aid for ammonium glyphosate |
| CN107568216A (en) * | 2017-08-02 | 2018-01-12 | 湖北泰盛化工有限公司 | A kind of glyphosate isopropylamine salt water solution auxiliary agent |
| CN108402040A (en) * | 2018-04-12 | 2018-08-17 | 南京科翼新材料有限公司 | A kind of auxiliary agent suitable for glufosinate-ammonium sylvine aqua |
| CN108432799A (en) * | 2018-04-12 | 2018-08-24 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and 2,4 drops |
| CN108477153A (en) * | 2018-04-12 | 2018-09-04 | 南京科翼新材料有限公司 | A kind of thickening aids compound aqueous suitable for glyphosate and Mediben |
| CN108542796A (en) * | 2018-07-20 | 2018-09-18 | 广州天赐高新材料股份有限公司 | A kind of amino acid is from thickened systems |
| CN108542796B (en) * | 2018-07-20 | 2020-06-30 | 广州天赐高新材料股份有限公司 | Amino acid self-thickening system |
| CN110547294A (en) * | 2019-08-19 | 2019-12-10 | 南京拓际生物科技有限公司 | Preparation research method of special auxiliary agent for glyphosate granules |
| CN110663687A (en) * | 2019-10-23 | 2020-01-10 | 河北天发生物科技有限公司 | Emulsifier and application of auxiliary agent containing emulsifier in pesticide preparation processing |
| CN110663687B (en) * | 2019-10-23 | 2021-06-29 | 河北天发生物科技有限公司 | Emulsifier and application of auxiliary agent containing emulsifier in pesticide preparation processing |
| CN111869663A (en) * | 2020-08-20 | 2020-11-03 | 南京拓凯新材料科技有限公司 | Synergistic low-foam type triflumuron water agent auxiliary agent and preparation process thereof |
| CN112075450A (en) * | 2020-09-25 | 2020-12-15 | 河南豫松环保科技有限公司 | Novel herbicide and preparation method thereof |
| CN112640894A (en) * | 2020-12-14 | 2021-04-13 | 剑胜作物科技(江苏盐城)有限责任公司 | Preparation method of agricultural synergistic additive containing lecithin |
| CN113207874A (en) * | 2021-03-25 | 2021-08-06 | 安徽瑞然生物药肥科技有限公司 | Glyphosate isopropylamine salt aqueous solution and production method thereof |
| CN114431226A (en) * | 2022-02-21 | 2022-05-06 | 广东粤港澳大湾区国家纳米科技创新研究院 | Thickening aid suitable for high-salt water aqua |
| CN115868487A (en) * | 2022-12-29 | 2023-03-31 | 南京科翼新材料有限公司 | Thickening synergistic additive suitable for refined glufosinate-ammonium and 2,4-drop compound aqueous solution |
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