CN106967543A - A kind of fruits and vegetables washing salt liquor and its preparation and application - Google Patents

A kind of fruits and vegetables washing salt liquor and its preparation and application Download PDF

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Publication number
CN106967543A
CN106967543A CN201710086103.8A CN201710086103A CN106967543A CN 106967543 A CN106967543 A CN 106967543A CN 201710086103 A CN201710086103 A CN 201710086103A CN 106967543 A CN106967543 A CN 106967543A
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CN
China
Prior art keywords
fruits
liquor
salt
vegetables
washing salt
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Pending
Application number
CN201710086103.8A
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Chinese (zh)
Inventor
杨海波
夏余虎
陶小兵
甄方明
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Middle Salt Changjiang River Salinization Co Ltd
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Middle Salt Changjiang River Salinization Co Ltd
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Priority to CN201710086103.8A priority Critical patent/CN106967543A/en
Publication of CN106967543A publication Critical patent/CN106967543A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39Organic or inorganic per-compounds
    • C11D3/3942Inorganic per-compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of fruits and vegetables washing salt liquor and its preparation and application, belong to detergent applications.The fruits and vegetables washing salt liquor of the present invention includes xanthans 0.15~0.35%, APG 12~20%, sodium carbonate peroxide 6~10%, sodium acid carbonate 14~22%, aloe 3~6%, salt 45~60% according to mass percent;The removal effect of fruits and vegetables washing salt liquor prepared by the present invention not only to remains of pesticide is obvious, it is to avoid the residual in fruit and vegetable surfaces and the injury to human body, simultaneously, also there is certain sterilizing to act on, in addition, being used as base stock using salt, production cost is low, with wider application prospect.

Description

A kind of fruits and vegetables washing salt liquor and its preparation and application
Technical field
The present invention relates to detergent applications, more particularly to a kind of fruits and vegetables washing salt liquor and its preparation and application.
Background technology
Residues of pesticides are largely enriched in the surface of melon fruits and vegetables, at present can be by following several before edible fruits and vegetables Method removes pollutant:(1) running water is cleaned, and this is the most frequently used cleaning way, mainly for bulky grains such as the sludge on surface Material has obvious removal effect, it is impossible to wash the material that water-insoluble such as agricultural chemicals adheres to surface off;(2) starch cleaning, leads to The remains of pesticide of part can be dissolved by a small amount of surfactant in rice washing water by crossing the long-time immersion of rice washing water, but extremely Soak 30 minutes less, long soaking time and bacteria-eliminating efficacy is poor;(3) liquid detergent is cleaned, composition all being of most of liquid detergent Length of schooling agent, not only the liquid detergent on fruit and vegetable surfaces is difficult to rinse out completely, and readily permeable causes two to fruits and vegetables cell interior Secondary pollution.Liquid detergent component residue is difficult thorough removal in fruit and vegetable surfaces simultaneously, and harmful substance can cause accumulation, danger in human body Evil health;(4) fruit peeler, although vegetables and melon and fruit to stem class have an extraordinary effect, but the abundant battalion on pericarp Form and point be dropped;(5) boiling water scalds, and boiling water can play a part of sterilization, and have more preferable clean result compared with normal-temperature water, but It is that boiling water still can not preferably remove purpose to water-insoluble residual play of agriculture, and easily causes fruit and vegetable surfaces nutritional ingredient stream Lose.
More than remove pollutant method all can not be effective to pollutant removal, in recent years many companies develop fruits and vegetables Special purpose detergent, fruits and vegetables detergent usually contains salt and surfactant and pH adjusting agent composition, therefore is often referred to as fruits and vegetables washing Salt.It is residual that fruits and vegetables washing salt can effectively dissolve agriculture;It is dissolved in the water the special electrolyte solution to be formed can by gap compared with Many, surface irregularity fruit and vegetable surfaces are cleaned up, while removing the artificial wax of fruit surface, and do not destroy the nutrition of fruits and vegetables Composition;The osmotic pressure of salting liquid formation can kill the harmful microorganisms such as worm's ovum and bacterium, and therefore, fruits and vegetables personal cleansing salt is mesh Preceding maximally efficient and healthy fruits and vegetables cleaning agent.
The content of the invention
Object of the present invention is to provide a kind of fruits and vegetables washing salt liquor and its preparation and application.The present invention is from washing Wash technique and detergent compositions set out, the fruits and vegetables washing salt liquor of development is using salt as base stock, with Natural surfactant Agent and pH adjusting agent compounding, play synergy, can not only strengthen the removal effect to remains of pesticide, and avoid in fruit The residual on vegetable surface and the injury to human body, meanwhile, fruits and vegetables washing salt liquor of the invention also there is certain sterilizing to make With there is development prospect in fields such as articless for washing.
To achieve the above object, the invention discloses a kind of fruits and vegetables washing salt liquor, according to mass percent, comprising following Component:Xanthans 0.15~0.35%, APG 12~20%, sodium carbonate peroxide 6~10%, sodium acid carbonate 14~22%, Aloe 3~6%, salt 45~65%.
It is preferred as the technology of the present invention, according to mass percent, include following components:Xanthans 0.25%, alkyl sugar Glycosides 12%, sodium carbonate peroxide 8%, sodium acid carbonate 18%, aloe 5%, salt 56.75%.
To realize the purpose of the present invention, the invention also discloses a kind of preparation method of fruits and vegetables washing salt liquor, including such as Lower step:
(1) xanthans is fully dissolved into water, adds aloe, preparation forms liquid portion;
(2) it will be mixed according to the APG of corresponding proportion, sodium acid carbonate, sodium carbonate peroxide and salt, form solid portion;
(3) liquid portion that the solid portion for preparing the step (2) is prepared with the step (1) is according to quality volume Than the ratio mixing for 20~30%, it is uniformly dissolved, prepares liquor washing salt.
Further, in the step (3), the liquid portion that the step (1) is prepared is according to mass volume ratio 25% ratio mixing, is uniformly dissolved, prepares liquor washing salt.
Present invention also offers a kind of technical scheme of the application method of fruits and vegetables washing salt liquor, i.e., fruits and vegetables are washed into saline solution Agent is 1 according to mass ratio:150~250 ratio, is dissolved in clear water, forms solution, 3~7s fruits and vegetables will be soaked through agricultural chemicals Sample is placed in soak in solution and 1~5min and washed by rubbing with the hands, then soaks 30~90s with clear water and wash by rubbing with the hands, finally 1 is rinsed with flowing water~ 3min。
Beneficial effect:
1st, the present invention is from washing process and detergent compositions, using salt as base stock, with Natural surfactant Agent and pH adjusting agent compounding, prepare fruits and vegetables washing salt liquor, preserve and easy to use;
2nd, removal effect of the fruits and vegetables washing salt liquor for preparing of the present invention not only to remains of pesticide is obvious, it is to avoid in fruits and vegetables The residual on surface and the injury to human body, meanwhile, also acted on certain sterilizing, in addition, using salt as basic Raw material, production cost is low, with wider application prospect.
Embodiment
In order to preferably explain the present invention, below in conjunction with specific embodiment and the experimental data master that the present invention is furture elucidated Content is wanted, but present disclosure is not limited solely to following examples.
The present invention uses each component of different formulations, wherein, xanthans is fully dissolved into water, aloe is added, matched somebody with somebody System forms liquid portion;It will be mixed according to the APG of corresponding proportion, sodium acid carbonate, sodium carbonate peroxide and salt, form solid Part;Solid portion and liquid portion are mixed according to mass volume ratio for 25% ratio again, are uniformly dissolved, prepare as Embodiment in each component such as Tables 1 and 2 of liquor washing salt in Tables 1 and 2 shown in embodiment 1~9, wherein different formulations Shown in 1~embodiment 9.
In order to further examine fruits and vegetables washing salt liquor to remove the residual effect of agriculture, by fruits and vegetables washing salt liquor according to quality Than for 1:200 ratio, is dissolved in clear water, forms solution, and the fruits and vegetables sample that 5s is soaked through agricultural chemicals is placed in solution and soaked 4min is simultaneously washed by rubbing with the hands, then is soaked 60s with clear water and washed by rubbing with the hands, is finally rinsed 3min with flowing water, has been obtained the fruits and vegetables shown in Tables 1 and 2 Washing salt liquor removes the residual the effect list of agriculture.
Wherein, the fruits and vegetables sample used is commercially available Brassica rapa L and pear, and processing procedure is with clearly by Brassica rapa L and pear Drained after water cleaning, be then immersed in certain density DDVP solution after certain time to take out and drain stand-by, then made Salt powder cleaning is washed with the fruits and vegetables of above-mentioned preparation.
The residual detection method of agriculture is gas chromatography, and the instrument used is Trace-1300 gas chromatograph.
The fruits and vegetables washing salt liquor of the different formulations of table 1 removes the residual the effect list of Brassica rapa L agriculture
The fruits and vegetables washing salt liquor of the different formulations of table 2 removes the residual the effect list of pear agriculture
From Tables 1 and 2, the optimum formula of fruits and vegetables washing salt liquor of the invention is xanthans 0.25%, alkyl sugar Glycosides 12%, sodium carbonate peroxide 8%, sodium acid carbonate 18%, aloe 5%, salt 56.75%, now, the residual clearance rate of agriculture reach most Greatly, i.e. the clearance rate residual to Brassica rapa L agriculture reaches 92.95%, and the clearance rate residual to pear agriculture reaches 91.80%.
Fruit vegetables storing experimental result after the cleaning of fruits and vegetables washing salt liquor is as shown in Table 3 and Table 4.
Storage experiment result after the fruits and vegetables washing salt liquor processing Brassica rapa L of the different formulations of table 3
Understood with reference to table 3, control group is the storage experiment result after being handled using clear water, the Brassica rapa L cleaned using clear water , there is slight glossiness and declines in not storage endurance at normal temperatures after 3 days, and dish leaf occur it is obvious turn yellow, no longer newly It is fresh.The Brassica rapa L handled using liquor is in the normal temperature storage of 3 days without the obvious yellowing of appearance.
Storage experiment result after the fruits and vegetables washing salt liquor processing pear of the different formulations of table 4
Understood with reference to table 4, control group is the storage experiment result after being handled using clear water, the pear cleaned using clear water is existed Stored 3 days under normal temperature, glossiness significantly declines, and obvious brown stain occur, and used after liquor processing, glossiness is kept It is preferable, Skin brown is significantly suppressed.
Table 5 and table 6 are the liquor washing salt using optimum formula, i.e. xanthans 0.25%, APG 12%, peroxide carbon Sour sodium 8%, sodium acid carbonate 18%, aloe 5%, salt 56.75%, the fruits and vegetables after cleaning are sent to Ministry of Agriculture's food quality inspection test Analyze the list of persticide residue in center (Wuhan).
The censorship result of the residual removal effect of Brassica rapa L agriculture of table 5
In table 5, after the cleaning of washing salt liquor, 100% is equally reached to the clearance of DDVP and Acetamiprid.It is right The clearance of cypermethrin is respectively 45%.According to《NY/T393-2013 pollution-free food Pesticide use criterions》Regulation, Chinese cabbage The maximum residue limit standard of middle cypermethrin and Acetamiprid is respectively 2mg/kg and 12mg/kg, and chlorine cyanogen in Brassica rapa L after cleaning The residual quantity of chrysanthemum ester is respectively 0.238mg/kg.Illustrate after the cleaning of liquor washing salt the residual of cypermethrin and Acetamiprid in Brassica rapa L Allowance meets green food standard well below correlation standard.
The censorship result of the residual removal effect of pear agriculture of table 6
In table 6, DDVP residues of pesticides are contained in pear control sample, are had after the cleaning of liquor washing salt to DDVP There is same removal effect, clearance reaches 100%.
In order to better illustrate the using effect of fruits and vegetables washing salt liquor prepared by the present invention, the present invention is also washed to fruits and vegetables The bactericidal effect of salt liquor is tested, and has obtained the fruits and vegetables washing salt of table 7 and the different formulations of embodiment 1~9 shown in table 8 The bactericidal effect list of liquor.
The examination criteria of wherein total plate count is《GB4789.2-2010 food microbiological examinations total plate count is determined》Rule Fixed method.
The examination criteria of coliform is《GB789.3-2010 food microbiological examinations coliform number is counted》It is defined Method.
Bactericidal effect list of the fruits and vegetables washing salt liquor of the different formulations of table 7 to Brassica rapa L
Bactericidal effect list of the fruits and vegetables washing salt liquor of the different formulations of table 8 to pear
Control group in table 7 and table 8 is the antibacterial detection carried out after being washed using clear water, is understood with reference to table 7, table 8, this The washing salt of invention formula has preferable removal ability to Escherichia coli, clear using the washing salt of formula in terms of total plate count After washing, total plate count is significantly reduced, and is below 100CFU/g, in safer scope.
It follows that removal effect of the fruits and vegetables washing salt liquor not only to remains of pesticide of the present invention is obvious, it is to avoid The residual of fruit and vegetable surfaces and the injury to human body, meanwhile, also acted on certain sterilizing, in addition, using salt conduct Base stock, production cost is low, with wider application prospect.
Above example is only optimal citing, and is not the restriction to embodiments of the present invention.Except above-described embodiment Outside, the present invention also has other embodiment.All use equivalent substitutions or the technical scheme of equivalent transformation formation, all fall within the present invention It is required that protection domain.

Claims (5)

1. a kind of fruits and vegetables washing salt liquor, it is characterised in that:According to mass percent, following components is included:Xanthans 0.15~ 0.35%, APG 12~20%, sodium carbonate peroxide 6~10%, sodium acid carbonate 14~22%, aloe 3~6%, salt 45~ 65%.
2. fruits and vegetables washing salt liquor according to claim 1, it is characterised in that:According to mass percent, comprising with the following group Point:Xanthans 0.25%, APG 12%, sodium carbonate peroxide 8%, sodium acid carbonate 18%, aloe 5%, salt 56.75%.
3. the preparation method of fruits and vegetables washing salt liquor according to claim 1 or 2, it is characterised in that:Comprise the following steps:
(1) xanthans is fully dissolved into water, adds aloe, preparation forms liquid portion;
(2) it will be mixed according to the APG of corresponding proportion, sodium acid carbonate, sodium carbonate peroxide and salt, form solid portion;
(3) liquid portion that the solid portion for preparing the step (2) is prepared with the step (1) is according to mass volume ratio 20~30% ratio mixing, is uniformly dissolved, prepares liquor washing salt.
4. the preparation method of fruits and vegetables washing salt liquor according to claim 3, it is characterised in that:, will in the step (3) The liquid portion that the step (1) is prepared is mixed according to mass volume ratio for 25% ratio, is uniformly dissolved, is prepared liquor Washing salt.
5. the application method of fruits and vegetables washing salt liquor according to claim 1 or 2, it is characterised in that:By fruits and vegetables washing salt Liquor is 1 according to mass ratio:150~250 ratio, is dissolved in clear water, forms solution, 3~7s fruit will be soaked through agricultural chemicals Vegetable sample is placed in soak in solution and 1~5min and washed by rubbing with the hands, then soaks 30~90s with clear water and wash by rubbing with the hands, finally 1 is rinsed with flowing water~ 3min。
CN201710086103.8A 2017-02-17 2017-02-17 A kind of fruits and vegetables washing salt liquor and its preparation and application Pending CN106967543A (en)

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Application Number Priority Date Filing Date Title
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107653071A (en) * 2017-09-04 2018-02-02 江西富达盐化有限公司 A kind of paste melon, fruit and vegetable cleaning salt and its preparation and application
CN109593614A (en) * 2018-11-28 2019-04-09 山东海天生物化工有限公司 A kind of fruits and vegetables cleaning agent
CN110343577A (en) * 2019-03-27 2019-10-18 四川金中誉科技有限公司 A kind of fruits and vegetables washing salt and preparation method thereof
CN110754648A (en) * 2018-07-25 2020-02-07 广东美味鲜调味食品有限公司 Bacteriostatic agent, preparation and use method of bacteriostatic agent and soy sauce production process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105647711A (en) * 2016-02-04 2016-06-08 王玉成 Fruit washing salt and preparation method
CN105733823A (en) * 2016-02-04 2016-07-06 王玉成 Fruit-and-vegetable washing salt and preparing method
CN106010827A (en) * 2016-05-24 2016-10-12 长沙华晨生物科技有限公司 Fruit and vegetable washing mineral salt

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105647711A (en) * 2016-02-04 2016-06-08 王玉成 Fruit washing salt and preparation method
CN105733823A (en) * 2016-02-04 2016-07-06 王玉成 Fruit-and-vegetable washing salt and preparing method
CN106010827A (en) * 2016-05-24 2016-10-12 长沙华晨生物科技有限公司 Fruit and vegetable washing mineral salt

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107653071A (en) * 2017-09-04 2018-02-02 江西富达盐化有限公司 A kind of paste melon, fruit and vegetable cleaning salt and its preparation and application
CN110754648A (en) * 2018-07-25 2020-02-07 广东美味鲜调味食品有限公司 Bacteriostatic agent, preparation and use method of bacteriostatic agent and soy sauce production process
CN109593614A (en) * 2018-11-28 2019-04-09 山东海天生物化工有限公司 A kind of fruits and vegetables cleaning agent
CN110343577A (en) * 2019-03-27 2019-10-18 四川金中誉科技有限公司 A kind of fruits and vegetables washing salt and preparation method thereof

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Inventor after: Yang Haibo

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Inventor after: Tao Xiaobing

Inventor after: Zhen Fangming

Inventor before: Yang Haibo

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