CN109456057B - 锆钛酸钡钙基无铅压电陶瓷及其制备方法 - Google Patents
锆钛酸钡钙基无铅压电陶瓷及其制备方法 Download PDFInfo
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- CN109456057B CN109456057B CN201811296384.0A CN201811296384A CN109456057B CN 109456057 B CN109456057 B CN 109456057B CN 201811296384 A CN201811296384 A CN 201811296384A CN 109456057 B CN109456057 B CN 109456057B
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- 239000000919 ceramic Substances 0.000 title claims abstract description 61
- 239000011575 calcium Substances 0.000 title claims abstract description 28
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title abstract description 8
- 229910021523 barium zirconate Inorganic materials 0.000 title abstract description 8
- DQBAOWPVHRWLJC-UHFFFAOYSA-N barium(2+);dioxido(oxo)zirconium Chemical compound [Ba+2].[O-][Zr]([O-])=O DQBAOWPVHRWLJC-UHFFFAOYSA-N 0.000 title abstract description 8
- 229910052791 calcium Inorganic materials 0.000 title abstract description 8
- FQNGWRSKYZLJDK-UHFFFAOYSA-N [Ca].[Ba] Chemical compound [Ca].[Ba] FQNGWRSKYZLJDK-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 238000000227 grinding Methods 0.000 claims description 33
- 239000002994 raw material Substances 0.000 claims description 33
- 238000005245 sintering Methods 0.000 claims description 26
- 239000000843 powder Substances 0.000 claims description 19
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 15
- 229910052709 silver Inorganic materials 0.000 claims description 15
- 239000004332 silver Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 230000010287 polarization Effects 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 238000003825 pressing Methods 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 6
- 239000012071 phase Substances 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- 238000003746 solid phase reaction Methods 0.000 claims description 6
- 239000007858 starting material Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 229910052808 lithium carbonate Inorganic materials 0.000 claims description 3
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 claims description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 3
- 229910052721 tungsten Inorganic materials 0.000 claims description 3
- 239000010937 tungsten Substances 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 239000004677 Nylon Substances 0.000 description 3
- 229920001778 nylon Polymers 0.000 description 3
- 238000004321 preservation Methods 0.000 description 3
- 230000002269 spontaneous effect Effects 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 2
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 150000001553 barium compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000028161 membrane depolarization Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000005501 phase interface Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
- C04B35/49—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates containing also titanium oxides or titanates
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
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Abstract
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Claims (9)
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CN201811296384.0A CN109456057B (zh) | 2018-11-01 | 2018-11-01 | 锆钛酸钡钙基无铅压电陶瓷及其制备方法 |
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CN109456057B true CN109456057B (zh) | 2021-10-08 |
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JP7168914B2 (ja) * | 2019-03-22 | 2022-11-10 | Tdk株式会社 | 誘電体組成物および電子部品 |
CN112876240B (zh) * | 2021-02-10 | 2022-03-08 | 同济大学 | 一种陶瓷材料及其制备方法和用途 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101786880A (zh) * | 2010-02-11 | 2010-07-28 | 中国科学院上海硅酸盐研究所 | 一种铌酸钾钠-铌酸钾锂压电陶瓷及其制备方法 |
CN101885607A (zh) * | 2010-07-08 | 2010-11-17 | 桂林理工大学 | 锆钛酸钡-铌酸钾钠基压电陶瓷及其制备方法 |
CN101935212A (zh) * | 2010-09-09 | 2011-01-05 | 西北工业大学 | 一种锆钛酸钡钙无铅压电陶瓷及其制备方法 |
CN102515761A (zh) * | 2011-12-22 | 2012-06-27 | 四川师范大学 | 铌酸钠锆钛酸钡钙系无铅压电陶瓷组合物 |
CN103373849A (zh) * | 2013-07-09 | 2013-10-30 | 贵州大学 | 一种氧化铌掺杂的锆钛酸钡钙无铅压电陶瓷粉体材料 |
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- 2018-11-01 CN CN201811296384.0A patent/CN109456057B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN101786880A (zh) * | 2010-02-11 | 2010-07-28 | 中国科学院上海硅酸盐研究所 | 一种铌酸钾钠-铌酸钾锂压电陶瓷及其制备方法 |
CN101885607A (zh) * | 2010-07-08 | 2010-11-17 | 桂林理工大学 | 锆钛酸钡-铌酸钾钠基压电陶瓷及其制备方法 |
CN101935212A (zh) * | 2010-09-09 | 2011-01-05 | 西北工业大学 | 一种锆钛酸钡钙无铅压电陶瓷及其制备方法 |
CN102515761A (zh) * | 2011-12-22 | 2012-06-27 | 四川师范大学 | 铌酸钠锆钛酸钡钙系无铅压电陶瓷组合物 |
CN103373849A (zh) * | 2013-07-09 | 2013-10-30 | 贵州大学 | 一种氧化铌掺杂的锆钛酸钡钙无铅压电陶瓷粉体材料 |
Non-Patent Citations (2)
Title |
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(Ba,Ca)(Zr,Ti)O3与(K,Na)NbO3基无铅压电陶瓷的制备及电性能研究;燕小斌;《中国博士学位论文全文数据库工程科技I辑》;20170115;第B015-15页 * |
BCZT-KNN无铅压电陶瓷的制备及其介电性能研究;李 伟等;《聊城大学学报》;20110630;第24卷(第2期);第43-45页 * |
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