CN109433810A - A kind of restorative procedure of Farmland Soil Pollution - Google Patents
A kind of restorative procedure of Farmland Soil Pollution Download PDFInfo
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- CN109433810A CN109433810A CN201811532374.2A CN201811532374A CN109433810A CN 109433810 A CN109433810 A CN 109433810A CN 201811532374 A CN201811532374 A CN 201811532374A CN 109433810 A CN109433810 A CN 109433810A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/02—Extraction using liquids, e.g. washing, leaching, flotation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/10—Reclamation of contaminated soil microbiologically, biologically or by using enzymes
- B09C1/105—Reclamation of contaminated soil microbiologically, biologically or by using enzymes using fungi or plants
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C2101/00—In situ
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Soil Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Mycology (AREA)
- Health & Medical Sciences (AREA)
- Botany (AREA)
- Biomedical Technology (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Molecular Biology (AREA)
- Processing Of Solid Wastes (AREA)
- Fertilizers (AREA)
Abstract
The present invention, which relates to, discloses a kind of restorative procedure of Farmland Soil Pollution, raw material including following parts by weight proportion, by 5-10 parts of silica, 1-3 parts of ethyl orthosilicate, 2-4 parts of humic acid ferrous iron, 1-5 parts of Trichoderma, 3-6 parts of zeolite group mineral, 2-7 parts of bacillus subtilis, 1-10 parts of potassium dihydrogen phosphate, 2-10 parts of bentonite, 5-8 parts of chitin fiber, 30-60 parts of water are mixed and made into solution；2) solution obtained in step 1) is added in the soil of heavy metal pollution, turns over the soil of the surface layer thickness 5-15cm of heavy-metal contaminated soil, is sufficiently mixed solution with heavy-metal contaminated soil.Reparation becomes enhanced convenience, have many advantages, such as that repair time is short, institute's expense is few, the fertilizer of plant growth can be provided to a certain extent, repairing effect is stablized, the case where being still able to maintain good repairing effect when temperature is lower, heavy-metal contaminated soil repairing and treating avoided to change in the process and destroy soil texture.
Description
Technical field
The present invention relates to soil pollution technical field, specially a kind of restorative procedure of Farmland Soil Pollution.
Background technique
Soil be not only earth ecology circle important component and important natural resources for the survival of mankind it
One, with the rural activities such as the industrial activities such as exploitation of mineral resources, smelting and sewage irrigation, applying sludge and chemical fertilizer inferior into
Row, the harmful heavy metals such as Cd, Pb constantly enter in soil environment, pollute to normal production and living.Therefore, soil is administered
Heavy metal pollution to conservation culture set and the life of human health is of great significance.
The long-term cropping in contaminated soil, not only will affect plant growth, to reduce crop yield, while can also make
Crop absorbs the ingredient in contaminated soil during the growth process, makes harm of the crop by heavy metal deposition itself, thus human body
Adverse effect can also be generated after eating above-mentioned crop, lead and its compound respectively organize human body toxic, inhale through alimentary canal
It receives, is poisoned into blood circulation.
Heavy metal and many teleorganic nutrients influence each other the Function of both sides, and extra-nutrition element can subtract
The toxic action of heavy metal in light crops, silicon, selenium, nitrogen, phosphorus, potassium, calcium, magnesium and some microelements are the beneficial of crops
Element can not only hinder the accumulation of heavy metal in control crops using foliage-spray, also to a certain extent as physiology barrier
Crop growth, yield can be promoted to increase, quality improving, therefore we have proposed a kind of restorative procedures of Farmland Soil Pollution to come
It solves the above problems.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of restorative procedure of Farmland Soil Pollution, have more square
Just with it is efficient the advantages that, solve the problems, such as that farmland pollution is inconvenient to handle.
(2) technical solution
To realize above-mentioned more convenient and efficient more convenient and efficient purpose, the invention provides the following technical scheme: one
The restorative procedure of kind Farmland Soil Pollution, the raw material including following parts by weight proportion:
1) by 5-10 parts of silica, 1-3 parts of ethyl orthosilicate, 2-4 parts of humic acid ferrous iron, boils by 1-5 parts of Trichoderma
3-6 parts of stone ore object, 2-7 parts of bacillus subtilis, 1-10 parts of potassium dihydrogen phosphate, 2-10 parts of bentonite, chitin fiber 5-
8 parts, 30-60 parts of water are mixed and made into solution；
2) solution obtained in step 1) is added in the soil of heavy metal pollution, turns over the table of heavy-metal contaminated soil
The soil of thickness 5-15cm, is sufficiently mixed solution with heavy-metal contaminated soil, stands 6-8h；
3) soil in step 2) is taken, filtrate is obtained and is precipitated, Na2S9H2O is added in filtrate and stands 80-
120min；
4) solution made from step 3) is added culture medium culture 10-20 days, on heavy-metal contaminated soil surface layer, 5-8cm is thick
Soil in the solution of culture is added, and irrigate, heavy-metal contaminated soil made to keep waterflooding state, stand 20-45 days；
5) part steps 3 are taken) in heavy metal soil carry out 3-5 time elute, then filled out back；
6) plantation of selection cereal is to heavy-metal contaminated soil, by the blade face of the solution spraying in step 1) to plant,
When the Growing season of plant terminates, by plant stalk and root system all removals containing heavy metal；
7) it will be added in the heavy-metal contaminated soil in step 6) containing amino acid-ferrous fertilizer, be uniformly mixed, place 60-
90 days, circulation step 1)-step 7), until the content of heavy metal in soil reaches safety standard.
Preferably, the solution of each elution is filtrate after last elution after heavy metal precipitation is handled
It is obtained by filtration.
Preferably, the heavy metal precipitation process is the filtrate NaOH tune pH value to 8-10 after eluting.
Preferably, the cereal is rice, wheat or barley.
Preferably, 40-60ml liquid solution is sprayed in the soil of every weight per square meter metallic pollution in the step 4).
Preferably, the fertilizer conduct containing N, P, K is added after all removing in the plant stalk in the step 6) and root system
Top dressing.
(3) beneficial effect
Compared with prior art, the present invention provides a kind of restorative procedures of Farmland Soil Pollution, have following beneficial to effect
Fruit:
The restorative procedure of the Farmland Soil Pollution, reparation become enhanced convenience, have that repair time is short, institute's expense is few
The advantages that, cost has been saved, the fertilizer of plant growth can be provided to a certain extent, repairing effect is stablized, lower in temperature
When be still able to maintain good repairing effect, avoid changing and destroying soil texture during heavy-metal contaminated soil repairing and treating
Situation.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched
It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention
In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts
Example, shall fall within the protection scope of the present invention.
A kind of restorative procedure of Farmland Soil Pollution, the raw material including following parts by weight proportion:
1) by 5-10 parts of silica, 1-3 parts of ethyl orthosilicate, 2-4 parts of humic acid ferrous iron, boils by 1-5 parts of Trichoderma
3-6 parts of stone ore object, 2-7 parts of bacillus subtilis, 1-10 parts of potassium dihydrogen phosphate, 2-10 parts of bentonite, chitin fiber 5-
8 parts, 30-60 parts of water are mixed and made into solution；
2) solution obtained in step 1) is added in the soil of heavy metal pollution, turns over the table of heavy-metal contaminated soil
The soil of thickness 5-15cm, is sufficiently mixed solution with heavy-metal contaminated soil, stands 6-8h；
3) soil in step 2) is taken, filtrate is obtained and is precipitated, heavy metal precipitation process is that the filtrate after eluting is used
NaOH tune pH value is added Na2S9H2O in filtrate and stands 80-120min to 8-10；
4) solution made from step 3) is added culture medium culture 10-20 days, on heavy-metal contaminated soil surface layer, 5-8cm is thick
Soil in the solution of culture is added, spray 40-60ml liquid solution in the soil of every weight per square meter metallic pollution, and irrigate,
So that heavy-metal contaminated soil is kept waterflooding state, stands 20-45 days；
5) part steps 3 are taken) in heavy metal soil carry out 3-5 time elution, the solution of each elution be last time
What the filtrate after elution was obtained by filtration after heavy metal precipitation is handled, then filled out back；
6) plantation of selection cereal is to heavy-metal contaminated soil, and cereal is rice, wheat or barley, by step 1)
In solution spraying to the blade face of plant, when the Growing season of plant terminates, by containing heavy metal plant stalk and root system all move
It removes, plant stalk and root system all remove and the fertilizer containing N, P, K are added later as top dressing；
7) it will be added in the heavy-metal contaminated soil in step 6) containing amino acid-ferrous fertilizer, be uniformly mixed, place 60-
90 days, circulation step 1)-step 7), until the content of heavy metal in soil reaches safety standard.
Embodiment one:
A kind of restorative procedure of Farmland Soil Pollution, the raw material including following parts by weight proportion:
1) by 5 parts of silica, 1 part of ethyl orthosilicate, humic acid is 2 parts ferrous, 1 part of Trichoderma, 3 parts of zeolite group mineral, withered
2 parts of careless bacillus, 1 part of potassium dihydrogen phosphate, 2 parts of bentonite, 5 parts of chitin fiber, 30 parts of water are mixed and made into solution；
2) solution obtained in step 1) is added in the soil of heavy metal pollution, turns over the table of heavy-metal contaminated soil
The soil of thickness 5cm, is sufficiently mixed solution with heavy-metal contaminated soil, stands 6h；
3) soil in step 2) is taken, filtrate is obtained and is precipitated, heavy metal precipitation process is that the filtrate after eluting is used
NaOH tune pH value is added Na2S9H2O in filtrate and stands 80min to 8；
4) solution made from step 3) is added culture medium culture 10 days, in the soil of heavy-metal contaminated soil surface layer 5cm thickness
The solution of culture is added in earth, sprays 40ml liquid solution in the soil of every weight per square meter metallic pollution, and irrigate, makes heavy metal
Contaminated soil keeps waterflooding state, stands 20 days；
5) part steps 3 are taken) in heavy metal soil carry out 3 times elution, the solution of each elution is last leaching
What the filtrate after washing was obtained by filtration after heavy metal precipitation is handled, then filled out back；
6) plantation of selection cereal is to heavy-metal contaminated soil, and cereal is rice, wheat or barley, by step 1)
In solution spraying to the blade face of plant, when the Growing season of plant terminates, by containing heavy metal plant stalk and root system all move
It removes, plant stalk and root system all remove and the fertilizer containing N, P, K are added later as top dressing；
7) it will be added in the heavy-metal contaminated soil in step 6) containing amino acid-ferrous fertilizer, be uniformly mixed, place 60
It, circulation step 1)-step 7), until the content of heavy metal in soil reaches safety standard.
Embodiment two:
A kind of restorative procedure of Farmland Soil Pollution, the raw material including following parts by weight proportion:
1) by 0 part of silica 1,3 parts of ethyl orthosilicate, humic acid is 4 parts ferrous, 5 parts of Trichoderma, 6 parts of zeolite group mineral, withered
7 parts of careless bacillus, 10 parts of potassium dihydrogen phosphate, 10 parts of bentonite, 8 parts of chitin fiber, 60 parts of water are mixed and made into solution；
2) solution obtained in step 1) is added in the soil of heavy metal pollution, turns over the table of heavy-metal contaminated soil
The soil of thickness 15cm, is sufficiently mixed solution with heavy-metal contaminated soil, stands 8h；
3) soil in step 2) is taken, filtrate is obtained and is precipitated, heavy metal precipitation process is that the filtrate after eluting is used
NaOH tune pH value is added Na2S9H2O in filtrate and stands 120min to 10；
4) solution made from step 3) is added culture medium culture 20 days, in the soil of heavy-metal contaminated soil surface layer 8cm thickness
The solution of culture is added in earth, sprays 60ml liquid solution in the soil of every weight per square meter metallic pollution, and irrigate, makes heavy metal
Contaminated soil keeps waterflooding state, stands 45 days；
5) part steps 3 are taken) in heavy metal soil carry out 5 times elution, the solution of each elution is last leaching
What the filtrate after washing was obtained by filtration after heavy metal precipitation is handled, then filled out back；
6) plantation of selection cereal is to heavy-metal contaminated soil, and cereal is rice, wheat or barley, by step 1)
In solution spraying to the blade face of plant, when the Growing season of plant terminates, by containing heavy metal plant stalk and root system all move
It removes, plant stalk and root system all remove and the fertilizer containing N, P, K are added later as top dressing；
7) it will be added in the heavy-metal contaminated soil in step 6) containing amino acid-ferrous fertilizer, be uniformly mixed, place 90
It, circulation step 1)-step 7), until the content of heavy metal in soil reaches safety standard.
The beneficial effects of the present invention are: the restorative procedure of the Farmland Soil Pollution, reparation becomes enhanced convenience, when reparation
Between short, institute's expense it is few the advantages that, saved cost, the fertilizer of plant growth, repairing effect can be provided to a certain extent
Stablize, good repairing effect is still able to maintain when temperature is lower, avoids changing during heavy-metal contaminated soil repairing and treating
The case where with soil texture is destroyed.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention is defined by the appended.
Claims (6)
1. a kind of restorative procedure of Farmland Soil Pollution, which is characterized in that the raw material including following parts by weight proportion:
1) by 5-10 parts of silica, 1-3 parts of ethyl orthosilicate, 2-4 parts of humic acid ferrous iron, 1-5 parts of Trichoderma, Zeolite mineral
3-6 parts of object, 2-7 parts of bacillus subtilis, 1-10 parts of potassium dihydrogen phosphate, 2-10 parts of bentonite, 5-8 parts of chitin fiber,
30-60 parts of water are mixed and made into solution；
2) solution obtained in step 1) is added in the soil of heavy metal pollution, the surface layer for turning over heavy-metal contaminated soil is thick
The soil of 5-15cm, is sufficiently mixed solution with heavy-metal contaminated soil, stands 6-8h；
3) soil in step 2) is taken, filtrate is obtained and is precipitated, Na2S9H2O is added in filtrate and stands 80-120min；
4) solution made from step 3) is added culture medium culture 10-20 days, in the soil of heavy-metal contaminated soil surface layer 5-8cm thickness
The solution of culture is added in earth, and irrigates, heavy-metal contaminated soil is made to keep waterflooding state, stands 20-45 days；
5) part steps 3 are taken) in heavy metal soil carry out 3-5 time elute, then filled out back；
6) plant is worked as to heavy-metal contaminated soil in the blade face of the solution spraying in step 1) to plant by the plantation of selection cereal
The Growing season of object terminates, by plant stalk and root system all removals containing heavy metal；
7) it will be added in the heavy-metal contaminated soil in step 6) containing amino acid-ferrous fertilizer, be uniformly mixed, place 60-90
It, circulation step 1)-step 7), until the content of heavy metal in soil reaches safety standard.
2. a kind of restorative procedure of Farmland Soil Pollution according to claim 1, which is characterized in that each elution is used
Solution be that filtrate after last elution is obtained by filtration after heavy metal precipitation is handled.
3. a kind of restorative procedure of Farmland Soil Pollution according to claim 1, which is characterized in that the heavy metal precipitation
Process is the filtrate NaOH tune pH value to 8-10 after eluting.
4. a kind of restorative procedure of Farmland Soil Pollution according to claim 1, which is characterized in that the cereal is
Rice, wheat or barley.
5. a kind of restorative procedure of Farmland Soil Pollution according to claim 1, which is characterized in that every in the step 4)
40-60ml liquid solution is sprayed in the soil of weight per square meter metallic pollution.
6. a kind of restorative procedure of Farmland Soil Pollution according to claim 1, which is characterized in that in the step 6)
The fertilizer containing N, P, K is added as top dressing in plant stalk and root system after all removing.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811532374.2A CN109433810B (en) | 2018-12-14 | 2018-12-14 | Farmland soil pollution remediation method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811532374.2A CN109433810B (en) | 2018-12-14 | 2018-12-14 | Farmland soil pollution remediation method |
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| CN109433810A true CN109433810A (en) | 2019-03-08 |
| CN109433810B CN109433810B (en) | 2020-11-24 |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104789227A (en) * | 2015-03-19 | 2015-07-22 | 浙江省农业科学院 | Soil heavy metal passivation agent applicable to water-flooding environment and application thereof |
| CN104891670A (en) * | 2015-05-07 | 2015-09-09 | 戴祺又 | Environment-friendly type high-efficiency house refuse covering agent and preparation method thereof |
| CN105170641A (en) * | 2015-09-30 | 2015-12-23 | 河南行知专利服务有限公司 | Combined remediation method for heavy metal contaminated soil |
| CN105344708A (en) * | 2015-09-30 | 2016-02-24 | 河南行知专利服务有限公司 | Remediation method for heavy metal contaminated soil of saline and alkaline land |
| CN106147778A (en) * | 2016-07-04 | 2016-11-23 | 河北省农林科学院农业资源环境研究所 | Passivator, preparation method and applications for repairing heavy metal in soil combined pollution |
| CN106220331A (en) * | 2016-07-26 | 2016-12-14 | 沈阳农业大学 | A kind of soil pollution renovation agent |
| CN108405598A (en) * | 2018-03-14 | 2018-08-17 | 上海立昌环境工程股份有限公司 | A kind of heavy metal polluted soil of farmland renovation agent and its application |
-
2018
- 2018-12-14 CN CN201811532374.2A patent/CN109433810B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104789227A (en) * | 2015-03-19 | 2015-07-22 | 浙江省农业科学院 | Soil heavy metal passivation agent applicable to water-flooding environment and application thereof |
| CN104891670A (en) * | 2015-05-07 | 2015-09-09 | 戴祺又 | Environment-friendly type high-efficiency house refuse covering agent and preparation method thereof |
| CN105170641A (en) * | 2015-09-30 | 2015-12-23 | 河南行知专利服务有限公司 | Combined remediation method for heavy metal contaminated soil |
| CN105344708A (en) * | 2015-09-30 | 2016-02-24 | 河南行知专利服务有限公司 | Remediation method for heavy metal contaminated soil of saline and alkaline land |
| CN106147778A (en) * | 2016-07-04 | 2016-11-23 | 河北省农林科学院农业资源环境研究所 | Passivator, preparation method and applications for repairing heavy metal in soil combined pollution |
| CN106220331A (en) * | 2016-07-26 | 2016-12-14 | 沈阳农业大学 | A kind of soil pollution renovation agent |
| CN108405598A (en) * | 2018-03-14 | 2018-08-17 | 上海立昌环境工程股份有限公司 | A kind of heavy metal polluted soil of farmland renovation agent and its application |
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