CN106220331A - A kind of soil pollution renovation agent - Google Patents

A kind of soil pollution renovation agent Download PDF

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Publication number
CN106220331A
CN106220331A CN201610594450.7A CN201610594450A CN106220331A CN 106220331 A CN106220331 A CN 106220331A CN 201610594450 A CN201610594450 A CN 201610594450A CN 106220331 A CN106220331 A CN 106220331A
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CN
China
Prior art keywords
parts
agent
soil
soil pollution
renovation agent
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Pending
Application number
CN201610594450.7A
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Chinese (zh)
Inventor
杜立宇
吴岩
兰西平
梁成华
刘淼
胡悦
赵丽洋
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Shenyang Agricultural University
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Shenyang Agricultural University
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Priority to CN201610594450.7A priority Critical patent/CN106220331A/en
Publication of CN106220331A publication Critical patent/CN106220331A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/10Reclamation of contaminated soil microbiologically, biologically or by using enzymes
    • B09C1/105Reclamation of contaminated soil microbiologically, biologically or by using enzymes using fungi or plants
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Soil Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Mycology (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Botany (AREA)
  • General Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of soil pollution renovation agent, it is prepared from by the raw material of following weight portion: bentonite 25~35 parts, PDDA 17~20 parts, Muscovitum 15~20 parts, nanometer water binding agent 10~15 parts, chitin fiber 6~12 parts, polyethylene glycol acrylate 0.004~1 part, PAMA 24~36 parts, potassium dihydrogen phosphate 12~22 parts, nanometer hydroxyapatite 5~11 parts, culturing pool mud 25~45 parts, bamboo pulp 11~19 parts, sodium iron ethylenediaminetetraacetate 6~14 parts, sugar alcohol magnesium 11~19 parts, enzymatic microorganism 0.8~1.8 parts, 45~65 parts of blue powder end, Mayan, mix bacterium agent 1~3 parts.The renovation agent of the present invention has remediation contaminated soil, soil improvement, degrading pesticide fertilizer residue, improves the functions such as soil nutrient.

Description

A kind of soil pollution renovation agent
Technical field
The present invention relates to soil remediation field, be specifically related to a kind of soil pollution renovation agent.
Background technology
Along with expanding economy, environmental pollution is day by day serious, and soil pollution is different from other and pollutes, and mainly shows as hidden Contact scar, has certain hysteresis quality and the most directly perceived.Particularly heavy metal pollution, typically could can only be found by detection, Therefore administer relatively difficult and waste time and energy.Additionally using in a large number along with chemical fertilizer and pesticide, soil show harden tight Weight, pesticide residue increase, the problem such as eutrophication, workability of soil reduction occur;Along with the development of poultry large-scale cultivation, tradition Poultry fertilizer occur in that a series of potential risks such as antibiotic remains, this all brings serious impact to agricultural production, with Time affect agricultural product quality and safety and food safety.
Soil remediation is the technical measures making to suffer contaminated soil to recover normal function, the most conventional soil remediation side Method has physics, chemistry and microbial process, although physics and chemical method effect are directly, and quick result, but vitality is poor, And method or consumption used the most at that time, did not only reach repairing effect, and can bring new pollution, complex method Then comprehensively, comprehensive, lasts power is strong, also can provide nutrition, it is to avoid the impoverishment of soil while repairing, will not be with appointing What ill effect.Wherein microbial process is because of advantages such as its character are gentle and soil affinity is strong, effect is thorough, itself and other Method be used in combination the research direction becoming comprehensive soil remediation.
Summary of the invention
For solving the problems referred to above, the invention provides a kind of soil pollution renovation agent, there is remediation contaminated soil, soil changes The functions such as good, degrading pesticide fertilizer residue, raising soil nutrient.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of soil pollution renovation agent, is prepared from by the raw material of following weight portion:
Bentonite 25~35 parts, PDDA 17~20 parts, Muscovitum 15~20 parts, nanometer water glue Mixture 10~15 parts, chitin fiber 6~12 parts, polyethylene glycol acrylate 0.004~1 part, PAMA 24 ~36 parts, potassium dihydrogen phosphate 12~22 parts, nanometer hydroxyapatite 5~11 parts, culturing pool mud 25~45 parts, bamboo pulp 11~ 19 parts, sodium iron ethylenediaminetetraacetate 6~14 parts, sugar alcohol magnesium 11~19 parts, enzymatic microorganism 0.8~1.8 parts, Mayan blue powder end 45~65 Part, mix bacterium agent 1~3 parts.
Preferably, described culturing pool mud is the mud in fish, shrimp, Eriocheir sinensis seawater aquaculturing pond, and water content is 15~25% After, particle diameter is 1~4 millimeter.
Preferably, described mix bacterium agent is by gel-shaped bacillus, Lactobacillus bulgaricus, enterobacteria YC105C, lactic acid Streptococcus, the Corynebacterium glutamicum mixing gained of 1:1:1:1:1 in mass ratio.
Preferably, the raw material of following weight portion it is prepared from:
Bentonite 25 parts, PDDA 17 parts, 15 parts of Muscovitum, nanometer water binding agent 10 parts, shell Polysaccharide fiber 6 parts, polyethylene glycol acrylate 0.004 part, PAMA 24 parts, potassium dihydrogen phosphate 12 parts, nanometer Hydroxyapatite 5 parts, 25 parts of culturing pool mud, bamboo pulp 11 parts, sodium iron ethylenediaminetetraacetate 6 parts, sugar alcohol magnesium 11 parts, enzymatic microorganism 0.8 part, Mayan blue powder end 45 parts, mix bacterium agent 1 part.
Preferably, the raw material of following weight portion it is prepared from:
Bentonite 35 parts, PDDA 20 parts, 20 parts of Muscovitum, nanometer water binding agent 15 parts, shell Polysaccharide fiber 12 parts, polyethylene glycol acrylate 1 part, PAMA 36 parts, potassium dihydrogen phosphate 22 parts, nano-hydroxy 11 parts of apatite, 45 parts of culturing pool mud, bamboo pulp 19 parts, sodium iron ethylenediaminetetraacetate 14 parts, sugar alcohol magnesium 19 parts, enzymatic microorganism 1.8 Part, Mayan blue powder end 65 parts, mix bacterium agent 3 parts.
Preferably, the raw material of following weight portion it is prepared from:
Bentonite 30 parts, PDDA 18.5 parts, 17.5 parts of Muscovitum, nanometer water binding agent 12.5 Part, chitin fiber 9 parts, polyethylene glycol acrylate 0.502 part, PAMA 30 parts, potassium dihydrogen phosphate 17 parts, Nanometer hydroxyapatite 8 parts, 35 parts of culturing pool mud, bamboo pulp 15 parts, sodium iron ethylenediaminetetraacetate 10 parts, sugar alcohol magnesium 15 parts, Enzymatic microorganism 1.3 parts, Mayan blue powder end 55 parts, mix bacterium agent 2 parts.
The method have the advantages that
The polymerizable crosslinkings such as PAMA, polyethylene glycol acrylate, PDDA Form cation, anion, the network structure of non-ionic group, blue powder end, collaborative Mayan, can carry out in soil metal from The absorption of son;Then the removal of metal ion is carried out by Muscovitum etc.;Nanometer water binding agent is mainly composed of polylactic acid and gathers Ester, rich in great amount of hydroxy group and carboxy functional group, after being applied in soil, its functional group is by electrostatic adsorption, can reunite With adhered soil microgranule, form the big particle diameter soil particle with crumb structure, effectively improve Soil structure, strengthen the anti-of soil particle and invade Erosion, anti-disintegrate and water stability ability, moreover it is possible to effectively regulation soil hydro-thermal and nutritional condition, promote vegetation growth;Microorganism is multiple Close flora in the metabolism of self because to absorb the nutrient meeting self-demand, active absorption heavy metal ion, And it is enriched in cell interior, also can carry out heavy metal ion by the various physicochemical properties of outside and cell surface Absorption and precipitation, it to other are organic or mineral decomposes, thus can improve the nutrient of soil simultaneously;Bamboo pulp exists Sustainable under sodium iron ethylenediaminetetraacetate, sugar alcohol magnesium effect become humic acid, constantly improve soil aggregate.
Detailed description of the invention
In order to make objects and advantages of the present invention clearer, below in conjunction with embodiment, the present invention is carried out further Describe in detail.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to limit this Bright.
In the embodiment of the present invention 1~3, the culturing pool mud used is the mud in fish, shrimp, Eriocheir sinensis seawater aquaculturing pond, After water content is 15~25%, particle diameter is 1~4 millimeter;The mix bacterium agent used is by gel-shaped bacillus, bulgarian milk Bacillus, enterobacteria YC105C, streptococcus acidi lactici, the Corynebacterium glutamicum mixing gained of 1:1:1:1:1 in mass ratio.
Embodiment 1
A kind of soil pollution renovation agent, is prepared from by the raw material of following weight portion:
Bentonite 25 parts, PDDA 17 parts, 15 parts of Muscovitum, nanometer water binding agent 10 parts, shell Polysaccharide fiber 6 parts, polyethylene glycol acrylate 0.004 part, PAMA 24 parts, potassium dihydrogen phosphate 12 parts, nanometer Hydroxyapatite 5 parts, 25 parts of culturing pool mud, bamboo pulp 11 parts, sodium iron ethylenediaminetetraacetate 6 parts, sugar alcohol magnesium 11 parts, enzymatic microorganism 0.8 part, Mayan blue powder end 45 parts, mix bacterium agent 1 part.
Embodiment 2
A kind of soil pollution renovation agent, is prepared from by the raw material of following weight portion:
Bentonite 35 parts, PDDA 20 parts, 20 parts of Muscovitum, nanometer water binding agent 15 parts, shell Polysaccharide fiber 12 parts, polyethylene glycol acrylate 1 part, PAMA 36 parts, potassium dihydrogen phosphate 22 parts, nano-hydroxy 11 parts of apatite, 45 parts of culturing pool mud, bamboo pulp 19 parts, sodium iron ethylenediaminetetraacetate 14 parts, sugar alcohol magnesium 19 parts, enzymatic microorganism 1.8 Part, Mayan blue powder end 65 parts, mix bacterium agent 3 parts.
Embodiment 3
A kind of soil pollution renovation agent, is prepared from by the raw material of following weight portion:
Bentonite 30 parts, PDDA 18.5 parts, 17.5 parts of Muscovitum, nanometer water binding agent 12.5 Part, chitin fiber 9 parts, polyethylene glycol acrylate 0.502 part, PAMA 30 parts, potassium dihydrogen phosphate 17 parts, Nanometer hydroxyapatite 8 parts, 35 parts of culturing pool mud, bamboo pulp 15 parts, sodium iron ethylenediaminetetraacetate 10 parts, sugar alcohol magnesium 15 parts, Enzymatic microorganism 1.3 parts, Mayan blue powder end 55 parts, mix bacterium agent 2 parts.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (6)

1. a soil pollution renovation agent, it is characterised in that be prepared from by the raw material of following weight portion:
Bentonite 25~35 parts, PDDA 17~20 parts, Muscovitum 15~20 parts, nanometer water binding agent 10~15 parts, chitin fiber 6~12 parts, polyethylene glycol acrylate 0.004~1 part, PAMA 24~36 Part, potassium dihydrogen phosphate 12~22 parts, nanometer hydroxyapatite 5~11 parts, culturing pool mud 25~45 parts, bamboo pulp 11~19 Part, sodium iron ethylenediaminetetraacetate 6~14 parts, sugar alcohol magnesium 11~19 parts, enzymatic microorganism 0.8~1.8 parts, Mayan blue powder end 45~65 Part, mix bacterium agent 1~3 parts.
A kind of soil pollution renovation agent the most according to claim 1, it is characterised in that described culturing pool mud be fish, shrimp, Mud in Eriocheir sinensis seawater aquaculturing pond, after water content is 15~25%, particle diameter is 1~4 millimeter.
A kind of soil pollution renovation agent the most according to claim 1, it is characterised in that described mix bacterium agent is by gel-shaped bud Born of the same parents bacillus, Lactobacillus bulgaricus, enterobacteria YC105C, streptococcus acidi lactici, Corynebacterium glutamicum 1:1:1:1:1 in mass ratio mix Close gained.
A kind of soil pollution renovation agent the most according to claim 1, it is characterised in that prepared by the raw material of following weight portion Form:
Bentonite 25 parts, PDDA 17 parts, 15 parts of Muscovitum, nanometer water binding agent 10 parts, chitosan Fiber 6 parts, polyethylene glycol acrylate 0.004 part, PAMA 24 parts, potassium dihydrogen phosphate 12 parts, nano-hydroxy 5 parts of apatite, 25 parts of culturing pool mud, bamboo pulp 11 parts, sodium iron ethylenediaminetetraacetate 6 parts, sugar alcohol magnesium 11 parts, enzymatic microorganism 0.8 Part, Mayan blue powder end 45 parts, mix bacterium agent 1 part.
A kind of soil pollution renovation agent the most according to claim 1, it is characterised in that prepared by the raw material of following weight portion Form:
Bentonite 35 parts, PDDA 20 parts, 20 parts of Muscovitum, nanometer water binding agent 15 parts, chitosan Fiber 12 parts, polyethylene glycol acrylate 1 part, PAMA 36 parts, potassium dihydrogen phosphate 22 parts, nano-hydroxy-apatite 11 parts of stone, 45 parts of culturing pool mud, bamboo pulp 19 parts, sodium iron ethylenediaminetetraacetate 14 parts, sugar alcohol magnesium 19 parts, enzymatic microorganism 1.8 parts, agate Refined blue powder end 65 parts, mix bacterium agent 3 parts.
A kind of soil pollution renovation agent the most according to claim 1, it is characterised in that prepared by the raw material of following weight portion Form:
Bentonite 30 parts, PDDA 18.5 parts, 17.5 parts of Muscovitum, nanometer water binding agent 12.5 parts, Chitin fiber 9 parts, polyethylene glycol acrylate 0.502 part, PAMA 30 parts, potassium dihydrogen phosphate 17 parts, receive Rice hydroxyapatite 8 parts, 35 parts of culturing pool mud, bamboo pulp 15 parts, sodium iron ethylenediaminetetraacetate 10 parts, sugar alcohol magnesium 15 parts, ferment Element bacterium 1.3 parts, Mayan blue powder end 55 parts, mix bacterium agent 2 parts.
CN201610594450.7A 2016-07-26 2016-07-26 A kind of soil pollution renovation agent Pending CN106220331A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106748328A (en) * 2017-03-08 2017-05-31 商洛学院 A kind of soil pollution renovation agent
CN106922737A (en) * 2017-03-19 2017-07-07 佳木斯大学 A kind of microbial pesticide improved the ecological environment
CN107285700A (en) * 2017-07-25 2017-10-24 内蒙古科技大学 A kind of superhigh tenacity concrete and preparation method thereof
CN107540307A (en) * 2017-08-30 2018-01-05 商洛学院 A kind of four grading grinding coagulation soil for being applicable water power hydraulic engineering and preparation method thereof
CN107593816A (en) * 2017-10-09 2018-01-19 河北省农林科学院石家庄果树研究所 A kind of composite pesticide for apple tree cultivation
CN107652442A (en) * 2017-10-16 2018-02-02 王欣 A kind of production method of the high water-retaining resin of bentonite base both sexes of fertilizer slow release carrier
CN109433810A (en) * 2018-12-14 2019-03-08 佛山市铁人环保科技有限公司 A kind of restorative procedure of Farmland Soil Pollution
CN110452044A (en) * 2019-08-14 2019-11-15 河北标驰农业科技有限公司 A kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof
CN111849491A (en) * 2020-07-30 2020-10-30 乐昌市住宅建筑工程有限公司 High-standard farmland construction method
CN115247066A (en) * 2022-07-12 2022-10-28 生态环境部南京环境科学研究所 Remediation agent for pesticide chemical polluted site and preparation method thereof

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CN103641635A (en) * 2013-12-20 2014-03-19 张仁亮 Bio-compound water-retaining fertilizer
CN104230589A (en) * 2014-08-22 2014-12-24 合肥四方磷复肥有限责任公司 Soil improvement biofertilizer and preparation method of soil improvement biofertilizer
CN104817413A (en) * 2015-04-14 2015-08-05 中山大学 Environment-friendly water-soil conserving soil modifier formula
CN105062496A (en) * 2015-08-24 2015-11-18 杭州市园林绿化股份有限公司 Soil conditioner
CN105110909A (en) * 2015-08-05 2015-12-02 国家海洋局第一海洋研究所 Preparation method for marine biological calcium magnesium fertilizer

Patent Citations (5)

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Publication number Priority date Publication date Assignee Title
CN103641635A (en) * 2013-12-20 2014-03-19 张仁亮 Bio-compound water-retaining fertilizer
CN104230589A (en) * 2014-08-22 2014-12-24 合肥四方磷复肥有限责任公司 Soil improvement biofertilizer and preparation method of soil improvement biofertilizer
CN104817413A (en) * 2015-04-14 2015-08-05 中山大学 Environment-friendly water-soil conserving soil modifier formula
CN105110909A (en) * 2015-08-05 2015-12-02 国家海洋局第一海洋研究所 Preparation method for marine biological calcium magnesium fertilizer
CN105062496A (en) * 2015-08-24 2015-11-18 杭州市园林绿化股份有限公司 Soil conditioner

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106748328A (en) * 2017-03-08 2017-05-31 商洛学院 A kind of soil pollution renovation agent
CN106922737A (en) * 2017-03-19 2017-07-07 佳木斯大学 A kind of microbial pesticide improved the ecological environment
CN107285700A (en) * 2017-07-25 2017-10-24 内蒙古科技大学 A kind of superhigh tenacity concrete and preparation method thereof
CN107540307A (en) * 2017-08-30 2018-01-05 商洛学院 A kind of four grading grinding coagulation soil for being applicable water power hydraulic engineering and preparation method thereof
CN107593816A (en) * 2017-10-09 2018-01-19 河北省农林科学院石家庄果树研究所 A kind of composite pesticide for apple tree cultivation
CN107652442A (en) * 2017-10-16 2018-02-02 王欣 A kind of production method of the high water-retaining resin of bentonite base both sexes of fertilizer slow release carrier
CN109433810A (en) * 2018-12-14 2019-03-08 佛山市铁人环保科技有限公司 A kind of restorative procedure of Farmland Soil Pollution
CN110452044A (en) * 2019-08-14 2019-11-15 河北标驰农业科技有限公司 A kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof
CN111849491A (en) * 2020-07-30 2020-10-30 乐昌市住宅建筑工程有限公司 High-standard farmland construction method
CN115247066A (en) * 2022-07-12 2022-10-28 生态环境部南京环境科学研究所 Remediation agent for pesticide chemical polluted site and preparation method thereof

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Application publication date: 20161214