CN110452044A - A kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof - Google Patents
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof Download PDFInfo
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- CN110452044A CN110452044A CN201910750272.6A CN201910750272A CN110452044A CN 110452044 A CN110452044 A CN 110452044A CN 201910750272 A CN201910750272 A CN 201910750272A CN 110452044 A CN110452044 A CN 110452044A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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Abstract
The invention belongs to crop technical field, a kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof is proposed.The antiviral volume increase Water soluble fertilizer of a kind of Multifucntional proposed by the present invention, it is grouped as by the group of following parts by weight: 15~30 parts of chitosan, 80~120 parts of potassium dihydrogen phosphate, 7~15 parts of four water, eight Boratex, 7~20 parts of microelement, 15~30 parts of compound sugar alcohol, 3~10 parts of vitamin, 3~10 parts of Titanium Citrate, 10~20 parts of chelating agent, 2~18 parts of synergist, 5~20 parts of poloxamer, 3~10 parts of neopelex, 2~5 parts of alkyl glycosides, synergist is the mixture of pearl white, egg-shell meal and folium artemisiae argyi ash mass ratio 3~5:0.5~1:2.Through the above technical solutions, solving the problems, such as to make the crop growth later period lead to crop production reduction because nutrient deficiency causes disease by the water soluble fertilizer of main material of chemical fertilizer in the prior art.
Description
Technical field
The invention belongs to field of agricultural production technologies, it is related to a kind of antiviral volume increase Water soluble fertilizer of Multifucntional and its preparation
Method.
Background technique
Multiple diseases can all occur every year for China crops, cause the underproduction, quality decline.For controlling disease, improve production
Amount, peasant improve Pesticide use amount and Pesticide use number, but result is but run counter to desire, and input cost is caused to increase, farming
Object disease control rate is low, quality decline, while destroys soil aggregate structure, and soil hardening, soil property is easily caused to be hardened.I
The Ministry of Agriculture, state proposes the year two thousand twenty fertilizer and pesticide zero growth rate, and gives implementing direction, according to the characteristics of pest and disease damage occurrence injury and
The reality of prevention and control adheres to comprehensive treatment, treating both manifestation and root cause of disease, works hard on " control, replace, essence, system " four words.Wherein
It a little exactly " controls ", is control disease pest occurrence injury.
Many diseases of plant are all to cause because of nutritional deficiency, therefore the full nutrition water solubility of high concentration is used for crop growth
The organic bio-fertilizer of each phase occurs disease and pest control extremely important.It is existing using chemical fertilizer as the water soluble fertilizer of main material,
Injury and plant growth middle and later periods to soil is the main original of the agriculture underproduction because of the disease caused by organic nutrition element shortage
Cause, therefore, it is necessary to research and develop a kind of full of nutrition to be conducive to crop growth, reduce diseases and pests of agronomic crop incidence and safety collar
The new-type fertilizer of guarantor.
Summary of the invention
The present invention proposes a kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof, solves in the prior art
The crop growth later period is set to lead to crops because nutrient deficiency causes disease by the water soluble fertilizer of main material of chemical fertilizer
The problem of underproduction.
The technical scheme of the present invention is realized as follows:
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
15~30 parts of chitosan, 80~120 parts of potassium dihydrogen phosphate, 7~15 parts of four water, eight Boratex, microelement 7~20
Part, 15~30 parts of compound sugar alcohol, 3~10 parts of vitamin, 3~10 parts of Titanium Citrate, 10~20 parts of chelating agent, synergist 2~18
Part, 5~20 parts of poloxamer, 3~10 parts of neopelex, 2~5 parts of alkyl glycosides,
The synergist is the mixture of pearl white, egg-shell meal and folium artemisiae argyi ash mass ratio 3~5:0.5~1:2.
As further technical solution, it is grouped as by the group of following parts by weight:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, compound sugar alcohol 22
Part, 7 parts of vitamin, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, neopelex 6
Part, 3.5 parts of alkyl glycosides,
The synergist is the mixture of pearl white, egg-shell meal and folium artemisiae argyi ash mass ratio 3~5:0.5~1:2.
As further technical solution, the chelating agent is ethylenediamine tetra-acetic acid and phytic acid mass ratio is 1:1
Mixture.
As further technical solution, the microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid copper mass
Mixture than 3:3:5:5.
As further technical solution, the compound sugar alcohol is lactitol, mannitol, antierythrite mass ratio 3:2:
5 mixture.
As further technical solution, deacetylating degree of chitosan >=85%.
As further technical solution, the pearl white is Marine fish scale meal.
As further technical solution, the poloxamer molecules amount is 9840~14600.
The invention also provides a kind of preparation methods of the antiviral volume increase Water soluble fertilizer of Multifucntional, comprising the following steps:
S1. according to a kind of formula of the above-mentioned antiviral volume increase Water soluble fertilizer of Multifucntional, it is spare to weigh each component;
S2. dipotassium hydrogen phosphate, four water Boratexes, compound sugar alcohol are mixed to get first and just mix object, first just mixed object and added
In the water for entering its 2 times of quality, 45~55 DEG C are heated to, 30min is reacted, obtains mother liquor;
S3. microelement is added in the mother liquor obtained to step S2, obtains the first mixed liquor;
S4. poloxamer, neopelex, alkyl glycosides are uniformly mixed, obtain second and just mix object, by second
Just mixed object is added in the water of its 5 times of quality, is uniformly mixed and obtains the second mixed liquor;
S5. chitosan, Titanium Citrate, vitamin, synergist, chelating agent are uniformly mixed, obtain third just mixed object, by the
In three the second mixed liquors that just mixed object addition step S4 is obtained, it is heated to 30~35 DEG C and is uniformly mixed, obtain third mixed liquor;
S6. the third mixed liquor that step S5 is obtained is added in the first mixed liquor that step S3 is obtained, heats 65~70 DEG C,
30min is reacted, a kind of antiviral volume increase Water soluble fertilizer of Multifucntional is obtained.
It the working principle of the invention and has the beneficial effect that
1, in the present invention, after the Water soluble fertilizer of preparation is applied to crops, during not only effectively reducing crop growth
Pest and disease damage incidence improves the disease resistance of crops, reduces pesticide amount, meanwhile, accelerate the growth of crops
Speed improves the yield of crops.Potassium dihydrogen phosphate, four water, eight Boratex, microelement, dimension life in Water soluble fertilizer of the invention
It is the growth of crops containing protein, electrolytes and minerals required for a large amount of crop growths in element, synergist etc.
Nutriment is provided, to accelerate the speed of growth of crops, after such as applying Water soluble fertilizer of the invention, the flower of peach is beared fruit
Rate is up to 75.46%, and average single plant peach yield is up to 112.9kg, and average list peach has weighed 220.3g, efficiently solves existing
Having in technology leads the crop growth later period because nutrient deficiency causes disease by the water soluble fertilizer of main material of chemical fertilizer
The problem of causing crop production reduction.
2, in the present invention, synergist is added in the raw material of Water soluble fertilizer, synergist is pearl white, egg-shell meal and folium artemisiae argyi grey matter
For amount than 3~5:0.5~1:2 mixture, pearl white, egg-shell meal contain albumen needed for a large amount of crop growths in folium artemisiae argyi ash
Matter, fatty acid and calcium, iron, zinc, phosphorus etc. are matched with potassium dihydrogen phosphate, four water, eight Boratex, microelement, the vitamin in formula
It closes, provides nutriment for the growth of crops, accelerate the speed of growth of crops, folium artemisiae argyi ash and alkyl glycosides, chitosan phase
Mutual compatibility, synergistic, so that the Water soluble fertilizer of preparation has good bactericidal effect, disease resistance is significantly mentioned after crops application
Height, thus the pest and disease damage incidence during effectively reducing crop growth.
3, in the present invention, it is added to poloxamer, dodecyl sodium sulfate, alkyl glycosides in the raw material of Water soluble fertilizer, moors Lip river
Husky nurse is compounded with dodecyl sodium sulfate, alkyl glycosides, is promoted the dispersion in water such as chitosan, synergist, is improved water
The stability of molten fertilizer, and then bring each component effect in Water soluble fertilizer preferably into play, meanwhile, improve Water soluble fertilizer in water
Dissolubility, the Water soluble fertilizer of preparation is quickly dispersed in water when being diluted with water, promote nutrition in Water soluble fertilizer at
Divide and quickly absorbed by crops, and then supplement various required nutrients comprehensively for crops, promotes crop growth, improve crops
Yield promotes extension of the nutritional ingredient on corps leaf surface, improves the absorption area of blade after foliage-spray Water soluble fertilizer,
Simultaneously avoid due to nutritional ingredient local concentration is excessively high and blade of burning, it is easy to use, it is practical.
4, in the present invention, compound sugar alcohol, chelating agent, Titanium Citrate are added in the raw material of Water soluble fertilizer, chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1, compound sugar alcohol and ethylenediamine tetra-acetic acid, phytic acid are mutual
The effects of potassium dihydrogen phosphate in compatibility, with formula, four water, eight Boratex, vitamin, microelement, generates stable compound
Body, avoid potassium dihydrogen phosphate, four water, eight Boratex, vitamin, microelement lose activity after entering soil and can not be by agriculture
The defect that crop absorbs, is delivered to position needed for crops for such nutritional ingredient, promotes suction of the crops to nitrogen, phosphorus, potassium
It receives and operating, compound sugar alcohol and ethylenediamine tetra-acetic acid, phytic acid, Titanium Citrate acts synergistically, improve nutritional ingredient
Utilization rate, and then crops are effectively prevented because nutritional deficiency, which causes disease, makes crop production reduction the phenomenon that, it effectively increases
The yield of crops.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
15 parts of chitosan, 80 parts of potassium dihydrogen phosphate, 7 parts of four water, eight Boratex, 7 parts of microelement, 15 parts of compound sugar alcohol, dimension
Raw 3 parts of element, 3 parts of Titanium Citrate, 10 parts of chelating agent, 2 parts of synergist, 5 parts of poloxamer, 3 parts of neopelex, alkyl
2 parts of glucosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 3:0.5:2;Chelating agent is second
The mixture that ethylenediamine tetraacetic acid (EDTA) and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulphur
The mixture of sour copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Poloxamer selects poloxamer188, point
Son amount is 9840~14600;
Preparation method, comprising the following steps:
S1. according to above-mentioned formula, it is spare to weigh each component;
S2. dipotassium hydrogen phosphate, four water Boratexes, compound sugar alcohol are mixed to get first and just mix object, first just mixed object and added
In the water for entering its 2 times of quality, 45~55 DEG C are heated to, 30min is reacted, obtains mother liquor;
S3. microelement is added in the mother liquor obtained to step S2, obtains the first mixed liquor;
S4. poloxamer, neopelex, alkyl glycosides are uniformly mixed, obtain second and just mix object, by second
Just mixed object is added in the water of its 5 times of quality, is uniformly mixed and obtains the second mixed liquor;
S5. chitosan, Titanium Citrate, vitamin, synergist, chelating agent are uniformly mixed, obtain third just mixed object, by the
In three the second mixed liquors that just mixed object addition step S4 is obtained, it is heated to 30~35 DEG C and is uniformly mixed, obtain third mixed liquor;
S6. the third mixed liquor that step S5 is obtained is added in the first mixed liquor that step S3 is obtained, is heated to 65~70
DEG C, 30min is reacted, a kind of antiviral volume increase Water soluble fertilizer of Multifucntional is obtained.
Embodiment 2
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
30 parts of chitosan, 120 parts of potassium dihydrogen phosphate, 15 parts of four water, eight Boratex, 20 parts of microelement, compound sugar alcohol 30
Part, 10 parts of vitamin, 10 parts of Titanium Citrate, 20 parts of chelating agent, 18 parts of synergist, 20 parts of poloxamer, dodecyl benzene sulfonic acid
10 parts of sodium, 5 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 5:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%, Marine fish scale meal are perch pearl white;Poloxamer selects poloxamer188,
Molecular weight is 9840~14600;
Preparation method is the same as embodiment 1.
Embodiment 3
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
16 parts of chitosan, 120 parts of potassium dihydrogen phosphate, 13 parts of four water, eight Boratex, 10 parts of microelement, compound sugar alcohol 20
Part, 3 parts of vitamin, 3 parts of Titanium Citrate, 10 parts of chelating agent, 6 parts of synergist, 8 parts of poloxamer, neopelex 5
Part, 2 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 3:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is butterfish scale;Poloxamer selects poloxamer188, point
Son amount is 9840~14600;
Preparation method is the same as embodiment 1.
Embodiment 4
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
18 parts of chitosan, 90 parts of potassium dihydrogen phosphate, 10 parts of four water, eight Boratex, 10 parts of microelement, 18 parts of compound sugar alcohol,
4 parts of vitamin, 5 parts of Titanium Citrate, 12 parts of chelating agent, 8 parts of synergist, 10 parts of poloxamer, 5 parts of neopelex,
4 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 5:0.5:2;Chelating agent is second
The mixture that ethylenediamine tetraacetic acid (EDTA) and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulphur
The mixture of sour copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Poloxamer selects poloxamer188, point
Son amount is 9840~14600;
Preparation method is the same as embodiment 1.
Embodiment 5
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
20 parts of chitosan, 110 parts of potassium dihydrogen phosphate, 13 parts of four water, eight Boratex, 10 parts of microelement, compound sugar alcohol 20
Part, 6 parts of vitamin, 5 parts of Titanium Citrate, 13 parts of chelating agent, 12 parts of synergist, 10 parts of poloxamer, neopelex 5
Part, 3 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 3~5:0.5~1:2;Chelating
The mixture that agent is ethylenediamine tetra-acetic acid and phytic acid mass ratio is 1:1;Microelement is ferrous sulfate, manganese sulfate, sulphur
The mixture of sour zinc, copper sulphate mass ratio 3:3:5:5;Compound sugar alcohol is lactitol, mannitol, antierythrite mass ratio 3:2:
5 mixture;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Poloxamer selects poloxamer188, point
Son amount is 9840~14600;
Preparation method is the same as embodiment 1.
Embodiment 6
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
26 parts of chitosan, 115 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 18 parts of microelement, compound sugar alcohol 26
Part, 8 parts of vitamin, 8 parts of Titanium Citrate, 18 parts of chelating agent, 15 parts of synergist, 16 parts of poloxamer, neopelex 5
Part, 4 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 4:0.5:2;Chelating agent is second
The mixture that ethylenediamine tetraacetic acid (EDTA) and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulphur
The mixture of sour copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Poloxamer selects poloxamer188, point
Son amount is 9840~14600;
Preparation method is the same as embodiment 1.
Embodiment 7
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, compound sugar alcohol 22
Part, 7 parts of vitamin, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, neopelex 6
Part, 3.5 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 4:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Poloxamer selects poloxamer188, point
Son amount is 9840~14600;
Preparation method is the same as embodiment 1.
Comparative example 1
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, compound sugar alcohol 22
Part, 7 parts of vitamin, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, neopelex 6
Part, 3.5 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 4:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Egg-shell meal smashes it through 200 meshes by egg shell
It obtains, folium artemisiae argyi ash is burned after drying by folium artemisiae argyi and obtained;Poloxamer select poloxamer188, molecular weight be 9840~
14600;
Preparation method is corresponding to delete synergist in step S5, remaining step is the same as embodiment 1.
Comparative example 2
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, compound sugar alcohol 22
Part, 7 parts of vitamin, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, neopelex 6
Part, 3.5 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 4:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Egg-shell meal smashes it through 200 meshes by egg shell
It obtains, folium artemisiae argyi ash is burned after drying by folium artemisiae argyi and obtained;Poloxamer select poloxamer188, molecular weight be 9840~
14600;
Preparation method is the same as embodiment 1.
Comparative example 3
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, compound sugar alcohol 22
Part, 7 parts of vitamin, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, neopelex 6
Part, 3.5 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 4:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Egg-shell meal smashes it through 200 meshes by egg shell
It obtains, folium artemisiae argyi ash is burned after drying by folium artemisiae argyi and obtained;Poloxamer select poloxamer188, molecular weight be 9840~
14600;
Preparation method is the same as embodiment 1.
Comparative example 4
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, compound sugar alcohol 22
Part, 7 parts of vitamin, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, neopelex 6
Part, 3.5 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 4:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Egg-shell meal smashes it through 200 meshes by egg shell
It obtains, folium artemisiae argyi ash is burned after drying by folium artemisiae argyi and obtained;Poloxamer select poloxamer188, molecular weight be 9840~
14600;
Preparation method is corresponding to delete chelating agent in step S5, remaining step is the same as embodiment 1.
Comparative example 5
A kind of antiviral volume increase Water soluble fertilizer of Multifucntional, is grouped as by the group of following parts by weight:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, compound sugar alcohol 22
Part, 7 parts of vitamin, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, neopelex 6
Part, 3.5 parts of alkyl glycosides,
Wherein, synergist is the mixture of Marine fish scale meal, egg-shell meal and folium artemisiae argyi ash mass ratio 4:1:2;Chelating agent is second two
The mixture that amine tetraacethyl and phytic acid mass ratio are 1:1;Microelement is ferrous sulfate, manganese sulfate, zinc sulfate, sulfuric acid
The mixture of copper mass ratio 3:3:5:5;Compound sugar alcohol is the mixing of lactitol, mannitol, antierythrite mass ratio 3:2:5
Object;
Deacetylating degree of chitosan >=85%;Marine fish scale meal is yellow croaker scale;Egg-shell meal smashes it through 200 meshes by egg shell
It obtains;Folium artemisiae argyi ash is burned after drying by folium artemisiae argyi and is obtained;
Preparation method is corresponding to delete step S4, remaining step is the same as embodiment 1.
Field trial: in order to prove a kind of effect of the antiviral volume increase Water soluble fertilizer of Multifucntional of the present invention in practical applications
Water soluble fertilizer prepared by the embodiment of the present invention 1~7 and comparative example 1~5 is used for the field trial of crops, specifically tests feelings by fruit
Condition is as follows:
Test one: Chinese cabbage
13 pieces of experimental plots are chosen in the Zhuozhou City peach garden street village Xi Gao village and carry out Chinese cabbage sowing, and every piece of experimental plot area is
1m2, every piece of experimental plot is one group, is divided into 1~13 group.25 seeds are sowed in every piece of experimental plot, after planting experimental plot management method
Referring to local Chinese cabbage planting technology.The growth period of Chinese cabbage is 50~60 days, and after sowing 15 days, 1~7 group of experimental plot is sprayed respectively
The Water soluble fertilizer of Examples 1 to 7 preparation is applied, 8~12 groups of experimental plot sprays the Water soluble fertilizer of the preparation of comparative example 1~5 respectively, 13 pairs
Experimental plot is blank control group, sprays clear water, and before spraying, Water soluble fertilizer prepared by Examples 1 to 7 and comparative example 1~5 is first watered
1000 times of dilution, spraying method is foliage-spray, sprayed once, sprays altogether 3 times every 10 days.Record the Chinese cabbage in each experimental plot
Pest and disease damage situation measures the Chinese cabbage plant height and each experimental plot total output of each experimental plot harvest.
Test result see the table below:
The influence of Water soluble fertilizer prepared by 1 Examples 1 to 7 of table and comparative example 1~5 to Chinese cabbage growth and development
Experimental plot group | Pest and disease damage incidence (%) | Chinese cabbage is averaged plant height (cm) | Chinese cabbage total output (kg) |
1 | 6.15 | 36.8 | 16.12 |
2 | 6.21 | 35.3 | 15.95 |
3 | 5.73 | 35.9 | 16.24 |
4 | 4.39 | 36.2 | 16.08 |
5 | 4.52 | 36.7 | 15.90 |
6 | 2.91 | 37.3 | 16.46 |
7 | 2.46 | 36.5 | 16.75 |
8 | 35.75 | 29.2 | 14.07 |
9 | 31.09 | 33.6 | 14.91 |
10 | 12.16 | 30.7 | 14.26 |
11 | 11.81 | 28.3 | 13.83 |
12 | 19.37 | 34.8 | 15.08 |
13 | 42.65 | 26.9 | 13.27 |
Data can be seen that compared with 8~13 groups of Chinese cabbage from upper table, 1~7 group of Chinese cabbage growth period pest and disease damage hair
Raw rate significantly reduces, and Chinese cabbage is averaged plant height and Chinese cabbage total output is significantly increased, the disease of especially 7 groups of Chinese cabbage growth period
Insect pest incidence is down to 2.46%, and the Chinese cabbage plant height that is averaged is up to 37.3cm, and Chinese cabbage total output is up to 16.75kg, illustrates the present invention
The Water soluble fertilizer of Examples 1 to 7 preparation not only significantly reduces Chinese cabbage growth period pest and disease damage incidence, improves the disease-resistant of Chinese cabbage
Ability, and the speed of growth of Chinese cabbage has been dramatically speeded up, to improve the plant height and yield of Chinese cabbage, play unexpected
Effect.
Compared with 1~7 group, 8 groups, 9 groups, 12 groups of Chinese cabbage growth period pest and disease damage incidence it is relatively high, 8 groups water-soluble
It is not added with synergist in fertilizer, folium artemisiae argyi ash is not added in 9 groups of Water soluble fertilizer, is not added with poloxamer, 12 in 12 groups of Water soluble fertilizer
Sodium alkyl sulfonate, alkyl glycosides illustrate the addition of synergist, significantly improve the disease resistance of Chinese cabbage and then greatly reduce white
The pest and disease damage incidence of dish, the addition of poloxamer, dodecyl sodium sulfate, alkyl glycosides cooperate with components other in formula,
It has been significantly reduced pest and disease damage incidence.
Compared with 1~7 group, 8 groups, 10 groups, the average plant height of 11 groups of Chinese cabbage and yield are relatively low, 8 groups of Water soluble fertilizer
In be not added with synergist, egg-shell meal, pearl white are not added in 9 groups of Water soluble fertilizer, chelating agent is not added in 11 groups of Water soluble fertilizer, says
The addition of bright synergist can not only reduce pest and disease damage incidence, additionally it is possible to remarkably promote the growth of Chinese cabbage, chelating agent adds
Enter, in formula other components cooperate, significantly improve the speed of growth of Chinese cabbage, thus substantially increase Chinese cabbage plant height and
Yield.
Test two: peach
13 pieces of experimental plots are chosen in Zhuozhou City peach garden street peace village village, every piece of experimental plot area is 10m2, every piece of test
Tian Weiyi group is divided into 1~13 group, and the peach transplantation of seedlings for growing into 4~5 true leaves is carried out earth culture into each experimental plot, for examination
Soil is brunisolic soil, before earth culture, the Water soluble fertilizer of 1~7 group of experimental plot application Examples 1 to 7 preparation, and 8~12 groups of experimental plot
Apply Water soluble fertilizer prepared by comparative example 1~5, " the eastern regions of the Yunnan Province gold good fortune " refined organic fertilizer of 13 groups of experimental plot application on the market.From flower
The phase of thanking start carry out foliage-spray Water soluble fertilizer, wherein 1~7 group of peach seedling spray Examples 1 to 7 preparation Water soluble fertilizer, 8~12
The peach seedling of group sprays the Water soluble fertilizer of the preparation of comparative example 1~5, and 13 groups of experimental plot is blank control group, sprays clear water, sprays
Before, Water soluble fertilizer prepared by Examples 1 to 7 and comparative example 1~5 is first watered 1000 times of dilution, primary, spray altogether was sprayed every 7 days
It applies 8 times.Other way to manages are referring to local peach cultivation technique.Record the insect pest incidence of peach growth period, flower is beared fruit
Rate, average single plant peach yield and average Dan Taochong, test result see the table below:
The influence of Water soluble fertilizer prepared by 2 Examples 1 to 7 of table and comparative example 1~5 to peach growth and development
Experimental plot group | Pest and disease damage incidence (%) | Flower fruit-setting rate (%) | Average single plant peach yield (kg) | Average Dan Taochong (g) |
1 | 9.32 | 73.57 | 103.5 | 219.4 |
2 | 8.83 | 72.91 | 105.8 | 221.5 |
3 | 6.41 | 73.28 | 103.7 | 217.9 |
4 | 6.76 | 74.54 | 104.2 | 215.6 |
5 | 5.19 | 73.85 | 110.1 | 216.4 |
6 | 4.62 | 74.71 | 108.5 | 221.2 |
7 | 4.28 | 75.46 | 112.9 | 220.3 |
8 | 34.85 | 51.73 | 76.28 | 200.5 |
9 | 32.18 | 63.26 | 89.83 | 201.7 |
10 | 13.24 | 55.19 | 77.35 | 198.2 |
11 | 13.47 | 52.65 | 78.46 | 204.8 |
12 | 25.61 | 58.43 | 72.17 | 196.4 |
13 | 52.34 | 50.16 | 68.33 | 197.5 |
Data can be seen that compared with 8~13 groups of peach from upper table, 1~7 group of peach growth period pest and disease damage hair
Raw rate significantly reduces, flower fruit-setting rate, average single plant peach yield and average Dan Taochong are significantly increased, and especially 7 groups
Peach, for growth period pest and disease damage incidence down to 4.28%, flower fruit-setting rate is up to 75.46%, and average single plant peach yield is high
Up to 112.9kg, average list peach has weighed 220.3g, and the Water soluble fertilizer for illustrating prepared by the embodiment of the present invention 1~7 not only significantly reduces
The pest and disease damage incidence of peach growth period, improves the anti-virus ability of peach, and dramatically speeded up the growth of peach
Speed plays unexpected effect to improve the fruit-setting rate and yield of peach.
Compared with 1~7 group, 8 groups, 9 groups, 12 groups of peach growth period pest and disease damage incidence it is relatively high, 8 groups water-soluble
It is not added with synergist in fertilizer, folium artemisiae argyi ash is not added in 9 groups of Water soluble fertilizer, is not added with poloxamer, 12 in 12 groups of Water soluble fertilizer
Sodium alkyl sulfonate, alkyl glycosides illustrate the addition of synergist, significantly improve the disease resistance of peach and then greatly reduce white
The pest and disease damage incidence of dish, the addition of poloxamer, dodecyl sodium sulfate, alkyl glycosides cooperate with components other in formula,
It has been significantly reduced pest and disease damage incidence.
Compared with 1~7 group, 8 groups, 10 groups, the flower fruit-setting rate of 11 groups of Chinese cabbage, average single plant peach yield and average
Dan Taochong is relatively low, and synergist is not added in 8 groups of Water soluble fertilizer, egg-shell meal, pearl white are not added in 9 groups of Water soluble fertilizer,
It is not added with chelating agent in 11 groups of Water soluble fertilizer, illustrates the addition of synergist, pest and disease damage incidence can not only be reduced, additionally it is possible to is aobvious
The growth for promoting Chinese cabbage is write, the addition of chelating agent cooperates with other components in formula, significantly improves the growth speed of peach
Degree, to substantially increase the fruit-setting rate and yield of peach.
The above is merely preferred embodiments of the present invention, be not intended to limit the invention, it is all in spirit of the invention and
Within principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (9)
1. a kind of antiviral volume increase Water soluble fertilizer of Multifucntional, which is characterized in that be grouped as by the group of following parts by weight:
15~30 parts of chitosan, 80~120 parts of potassium dihydrogen phosphate, 7~15 parts of four water, eight Boratex is 7~20 parts of microelement, multiple
15~30 parts of sugar alcohol are closed, 3~10 parts of vitamin, 3~10 parts of Titanium Citrate, 10~20 parts of chelating agent, 2~18 parts of synergist, is moored
5~20 parts of Luo Shamu, 3~10 parts of neopelex, 2~5 parts of alkyl glycosides,
The synergist is the mixture of pearl white, egg-shell meal and folium artemisiae argyi ash mass ratio 3~5:0.5~1:2.
2. the antiviral volume increase Water soluble fertilizer of a kind of Multifucntional according to claim 1, which is characterized in that by following weight
The group of part is grouped as:
23 parts of chitosan, 100 parts of potassium dihydrogen phosphate, 12 parts of four water, eight Boratex, 13 parts of microelement, 22 parts of compound sugar alcohol, dimension
Raw 7 parts of element, 6 parts of Titanium Citrate, 15 parts of chelating agent, 10 parts of synergist, 14 parts of poloxamer, 6 parts of neopelex, alkane
3.5 parts of base glucosides,
The synergist is the mixture of pearl white, egg-shell meal and folium artemisiae argyi ash mass ratio 3~5:0.5~1:2.
3. the antiviral volume increase Water soluble fertilizer of a kind of Multifucntional according to claim 1 or 2, which is characterized in that the chela
The mixture that mixture is ethylenediamine tetra-acetic acid and phytic acid mass ratio is 1:1.
4. the antiviral volume increase Water soluble fertilizer of a kind of Multifucntional according to claim 3, which is characterized in that the micro member
Element is the mixture of ferrous sulfate, manganese sulfate, zinc sulfate, copper sulphate mass ratio 3:3:5:5.
5. the antiviral volume increase Water soluble fertilizer of a kind of Multifucntional according to claim 3, which is characterized in that the glycoconjugate
Alcohol is the mixture of lactitol, mannitol, antierythrite mass ratio 3:2:5.
6. the antiviral volume increase Water soluble fertilizer of a kind of Multifucntional according to claim 3, which is characterized in that the chitosan
Deacetylation >=85%.
7. the antiviral volume increase Water soluble fertilizer of a kind of Multifucntional according to claim 3, which is characterized in that the pearl white
For Marine fish scale meal.
8. the antiviral volume increase Water soluble fertilizer of a kind of Multifucntional according to claim 3, which is characterized in that the pool Lip river is husky
Nurse molecular weight is 9840~14600.
9. a kind of preparation method of the antiviral volume increase Water soluble fertilizer of Multifucntional, which comprises the following steps:
S1. according to a kind of formula of the antiviral volume increase Water soluble fertilizer of Multifucntional described in claim 1~8 any one, claim
Take each component spare;
S2. dipotassium hydrogen phosphate, four water Boratexes, compound sugar alcohol are mixed to get the first just mixed object, will first just mixed object be added its 2
In the water of times quality, 45~55 DEG C are heated to, 30min is reacted, obtains mother liquor;
S3. microelement is added in the mother liquor obtained to step S2, obtains the first mixed liquor;
S4. poloxamer, neopelex, alkyl glycosides are uniformly mixed, obtain second and just mixes object, will mixed at the beginning of second
Object is added in the water of its 5 times of quality, is uniformly mixed and obtains the second mixed liquor;
S5. chitosan, Titanium Citrate, vitamin, synergist, chelating agent are uniformly mixed, obtain third just mixed object, it will be at the beginning of third
Mixed object is added in the second mixed liquor that step S4 is obtained, and is heated to 30~35 DEG C and is uniformly mixed, obtains third mixed liquor;
S6. the third mixed liquor that step S5 is obtained is added in the first mixed liquor that step S3 is obtained, heats 65~70 DEG C, reaction
30min obtains a kind of antiviral volume increase Water soluble fertilizer of Multifucntional.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113105288A (en) * | 2021-04-13 | 2021-07-13 | 湖南文理学院 | Green economic plant leaf preparation and preparation method thereof |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090044581A1 (en) * | 2004-09-13 | 2009-02-19 | Torfinn Johnsen | Stabilizing membrane for water and nutrient |
CN104892208A (en) * | 2015-06-11 | 2015-09-09 | 中化化肥有限公司烟台作物营养与植物保护研究中心 | Liquid compound trace element fertilizer and preparation method thereof |
CN106220331A (en) * | 2016-07-26 | 2016-12-14 | 沈阳农业大学 | A kind of soil pollution renovation agent |
CN106380323A (en) * | 2016-09-23 | 2017-02-08 | 山东省农业科学院农业资源与环境研究所 | Disease-resistant macroelement liquid water-soluble fertilizer and preparation method thereof |
CN106518361A (en) * | 2016-10-28 | 2017-03-22 | 青岛海之源智能技术有限公司 | Microcapsule fertilizer with desinsectization effect and preparation method thereof |
CN107602195A (en) * | 2017-10-30 | 2018-01-19 | 桐梓县茅石乡龙会村蔬菜种植场 | A kind of fertilizer of strawberry cultivating |
CN108558510A (en) * | 2018-05-30 | 2018-09-21 | 安徽省神农农业技术开发有限公司 | One kind having multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention and preparation method thereof |
WO2019033124A1 (en) * | 2017-08-11 | 2019-02-14 | California Safe Soil, LLC | Agricultural admixtures |
-
2019
- 2019-08-14 CN CN201910750272.6A patent/CN110452044A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090044581A1 (en) * | 2004-09-13 | 2009-02-19 | Torfinn Johnsen | Stabilizing membrane for water and nutrient |
CN104892208A (en) * | 2015-06-11 | 2015-09-09 | 中化化肥有限公司烟台作物营养与植物保护研究中心 | Liquid compound trace element fertilizer and preparation method thereof |
CN106220331A (en) * | 2016-07-26 | 2016-12-14 | 沈阳农业大学 | A kind of soil pollution renovation agent |
CN106380323A (en) * | 2016-09-23 | 2017-02-08 | 山东省农业科学院农业资源与环境研究所 | Disease-resistant macroelement liquid water-soluble fertilizer and preparation method thereof |
CN106518361A (en) * | 2016-10-28 | 2017-03-22 | 青岛海之源智能技术有限公司 | Microcapsule fertilizer with desinsectization effect and preparation method thereof |
WO2019033124A1 (en) * | 2017-08-11 | 2019-02-14 | California Safe Soil, LLC | Agricultural admixtures |
CN107602195A (en) * | 2017-10-30 | 2018-01-19 | 桐梓县茅石乡龙会村蔬菜种植场 | A kind of fertilizer of strawberry cultivating |
CN108558510A (en) * | 2018-05-30 | 2018-09-21 | 安徽省神农农业技术开发有限公司 | One kind having multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
王福刚等: "《环境水文地质调查实习指导书》", 30 June 2017 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113105288A (en) * | 2021-04-13 | 2021-07-13 | 湖南文理学院 | Green economic plant leaf preparation and preparation method thereof |
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