CN108558510A - One kind having multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention and preparation method thereof - Google Patents
One kind having multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention and preparation method thereof Download PDFInfo
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- CN108558510A CN108558510A CN201810540991.0A CN201810540991A CN108558510A CN 108558510 A CN108558510 A CN 108558510A CN 201810540991 A CN201810540991 A CN 201810540991A CN 108558510 A CN108558510 A CN 108558510A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/20—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
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Abstract
The invention discloses one kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, and raw material includes by weight：25 35 parts of ammonium nitrate, 10 20 parts of urea, 20 30 parts of potassium dihydrogen phosphate, 15 parts of potassium fulvate, 10 15 parts of sodium humate, 10 15 parts of potassium hydroxide, 24 parts of citric acid, 36 parts of EDTA disodiums, 5 10 parts of KOM, 25 parts of sodium gluconate, 0.5 1.2 parts of copper sulphate, 0.5 1 parts of boric acid, 0.5 1.5 parts of magnesium sulfate, 0.5 1.5 parts of chitosan oligosaccharide, 0 1.5 parts of anticaking agent, 1 30 parts of auxiliary agent, 0.1 1 parts of antifoaming agent, 800 1000 parts of water.The invention also discloses the preparation methods of above-mentioned Water soluble fertilizer.Potassium fulvate and chitosan oligosaccharide form effective compounding in Water soluble fertilizer of the present invention, while enhancing plant disease-proof and anti-adversity, also have volume increase, good function.
Description
Technical field
The present invention relates to technical field of fertilizers, more particularly to one kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention and its preparation side
Method.
Background technology
Agricultural production also faces various distinct issues while increasingly modernized, first, fertilizer and pesticide is a large amount of
Input, although fertilizer and pesticide is constantly updating, the selection resistance of disease pest is also more and more prominent, may finally cause
The use of fertilizer and pesticide larger dose not only increases the planting cost of peasant, also results in serious environmental pollution.2016
Country proposes the fundamental policies of fertilizer and pesticide zero growth rate, usage amount to fertilizer and pesticide and new want not only is proposed using technology
It asks, it was also proposed that new challenge.
In order to realize fertilizer and pesticide zero growth rate it is necessary to set about from the decrement synergy of fertilizer and pesticide, more efficient, ring is worked out
The pesticidal preparations and dosage form of guarantor, and more simple and effective application method.It has now been found that from 1859, Frenchman
After Rouget obtains chitosan first, the biological functionality and compatibility of this natural polymer, blood compatibility, safety,
The excellent performances such as microbic resolvability are just by all trades and professions extensive concern.Chitosan class compound purposes agriculturally also very
Extensively, the NH released is dissolved under weakly acidic condition3+There is very strong inhibiting effect to bacterium, stimulates plant with it, plant can be made
Chitinase activates in object, and when chitin, the germ of constituent of chitosan, pest attack are contained in surface, that has activated is several
Fourth matter enzyme can play corresponding effect to fight invasion.Xanthohumic acid kind compound is a kind of dividing greatly containing various active substance
Sub- colloidal substance agriculturally may be used as plant growth regulator, can promote plant growth, play an important role to drought resisting,
To improve plant stress-resistance ability, volume increase and improving quality effect.Meanwhile plant endoperoxides enzyme also can be improved in fulvic acid,
To which a variety of germs are generated with strong inhibiting effect.By upper it can be found that although the substances such as chitosan and fulvic acid are not belonging to
Synthetic pesticide, but the two can stimulate plant to generate to the resistance of adverse circumstance environment and generate inhibition to germ, objectively but
Play the effect of pesticide, and these substances are without side-effects to environment, will not pollute, be very promising chemical fertilizer,
Pesticide material.
Simultaneously as the influence of the various factors such as weather, water source, soil property, pest and disease damage, artificial to launch to the fertilizer in ground simultaneously
Differ and surely absorbed completely by crop, many diseases of plant are caused because of nutritional deficiency.Water soluble fertilizer is a kind of
It can be dissolved completely in the multielement compound fertilizer of water, it is non-complete water-soluble relative to traditional calcium superphosphate, granulated compound fertilizer etc.
Fertilizer and sustained release kind, due to its with instant, absorptivity is high, it is quick, using the remarkable advantages such as facilitating, thus obtained fast
Violent development.Therefore, in order to obtain fertilizer product more efficiently, environmentally friendly, it is poly- plus shell to develop a kind of full nutrition of high concentration
The Water soluble fertilizer of sugar and fulvic acid formula is used for the organic bio-fertilizer in crop growth each period, for realizing fertilizer and pesticide zero growth rate
It is extremely important.
But it when developing this full nutrition of high concentration plus the Water soluble fertilizer of chitosan and fulvic acid formula, also faces at present
It challenges below：First, when being introduced into water soluble fertilizer of the organic matters such as fulvic acid, it is easy to which appearance mixing is uneven, and moisture absorption is tight
The problems such as weight, seriously constrain the application development that fulvic acid is applied in Water soluble fertilizer；Second is that unavoidable in the growth course of crop
It is encroached on by disease pest, needs the side effect effect for overcoming traditional pesticide generally existing " toxic "；Third, because current extreme
Weather normalization, natural calamity is more and more frequent, there are such as hot dry wind, arid, flood, the various adverse circumstances of high temperature low temperature to farming
The efficiency of combating a natural disaster of the invasion of object, crops needs to meet requirements at the higher level.
Invention content
Technical problems based on background technology, the present invention propose it is a kind of have the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention and
Preparation method, potassium fulvate and chitosan oligosaccharide form effective compounding in the water-soluble fertilizer, enhance plant disease-proof and anti-adversity
While, also there is volume increase, good function.
Proposed by the present invention a kind of there is the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, raw material to include by weight：Ammonium nitrate 25-
35 parts, 10-20 parts of urea, 20-30 parts of potassium dihydrogen phosphate, 1-5 parts of potassium fulvate, 10-15 parts of sodium humate, potassium hydroxide 10-
15 parts, 2-4 parts of citric acid, 3-6 parts of EDTA- disodiums, 5-10 parts of KOM, 2-5 parts of sodium gluconate, 0.5-1.2 parts of copper sulphate, boron
It is 0.5-1 parts sour, 0.5-1.5 parts of magnesium sulfate, 0.5-1.5 parts of chitosan oligosaccharide, 0-1.5 parts of anticaking agent, 1-30 parts of auxiliary agent, antifoaming agent
0.1-1 parts, 800-1000 parts of water.
Preferably, described to further include with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention：0.3-0.6 parts of ammonium molybdate, manganese sulfate 1-2
Part, 0.2-1 parts of ferrous sulfate.
Preferably, the anticaking agent is by organic phosphate starch paste and methyl naphthalene sulfonic acid sodium by weight ratio 1:3-
5 are mixed to form.
Preferably, the process for preparing the organic phosphate starch paste includes：Be added to the water starch to obtain content be
45-95wt% starch solutions, then microwave treatment is carried out to the starch solution, sodium dihydrogen phosphate is added after being cooled to 50-60 DEG C
Insulation reaction obtains the organic phosphate starch paste after adjusting pH to 4-5.
Organic phosphate starch paste carries out modified phosphorylation reaction appropriate to starch by using microwave action and obtains
It arrives, since microwave action can be with the structure of Effective Regulation starch carrier, disintegrating property, to have adjusted it to fulvic acid and shell
The absorption property of oligosaccharides, phosphorylation reaction can then enhance product solubility property in water, successfully prepare a kind of complete water-soluble
Property phosphorylated starch based aquagel carrier covering material.
Preferably, during preparing the organic phosphate starch paste, when microwave treatment, controls microwave action
Temperature is 100-140 DEG C, and microwave action power is 1000-1400w, and the microwave action time is 60-120min.
Preferably, during preparing the organic phosphate starch paste, be added sodium dihydrogen phosphate insulation reaction when
Between be 1-2h, the addition of sodium dihydrogen phosphate is 0.5-2 times of the starch solution.
Preferably, the auxiliary agent is mixed to form by sodium benzoate, bleeding agent HP-1 and ammonium hydroxide, it is preferable that sodium benzoate,
The weight proportion of bleeding agent HP-1 and ammonium hydroxide is 0.1-1:0.5-1:0.5-30.
The invention also provides the above-mentioned preparation methods with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, include the following steps：
S1, formula is pressed successively by sodium humate, potassium fulvate, potassium hydroxide, auxiliary agent, antifoaming agent, potassium dihydrogen phosphate, nitric acid
Ammonium, urea, chitosan oligosaccharide, which are added to the water, is uniformly mixing to obtain solution A；
S2, formula is pressed by citric acid, potassium hydroxide, EDTA- disodiums, KOM, copper sulphate, magnesium sulfate, sodium gluconate, boron
Acid, anticaking agent are added to the water and are uniformly mixing to obtain solution B；
S3, solution B is added to mixing in solution A under agitation, obtained described multi-functional water-soluble with degeneration-resistant diseases prevention
Fertilizer.
Preferably, the dosage of water is respectively to be formulated 80-85%, 15-20% of dosage in S1, S2；Potassium hydroxide in S1, S2
Dosage be respectively be formulated dosage 90-95%, 5-10%.
In Water soluble fertilizer of the present invention, substances (chitosan oligosaccharide, the Huangs such as chitosan oligosaccharide, the potassium fulvate with degeneration-resistant diseases prevention effectiveness are selected
Rotten acid potassium is belonging respectively to water-soluble chitosan class and xanthohumic acid kind compound) it is carried out with each substance for providing nutrition needed for plant
Rationally compounding is produced by using degeneration-resistant, immune and nutrition the effect of these substances with the homologous product of medicine fertilizer.Example
Such as, the organic matter of potassium fulvate, sodium humate, chitosan oligosaccharide of addition etc. not only can in Water soluble fertilizer elemental nitrogen, phosphorus, potassium,
The effective organic mineralization of the progress such as copper, iron, molybdenum, manganese, magnesium, and soil vitality is had activated in use, promote soil
Earth recycles, and improves fertilizer efficiency, compensates nutritional deficiency, coordinates nutrient balance, improves rhizosphere cycle, then reduce chemical fertilizer to the pollution of soil and
To the pressure of microorganism.Trace copper, boron, the magnesium contained in Water soluble fertilizer, can overcome lack of trace elements in crops after
Disease so that the nutritional ingredient of crop balances, and can effectively improve the physicochemical character of the soil after application, and promotes crop to nitrogenous fertilizer
Utilization, improve utilization rate of fertilizer, achieve the effect that volume increase and improve crop quality.Further, the organic matters such as humic acid
Compounding can also be formed with KOM, can not only supply crop nutrition content but also physiological function of plants can be adjusted, and improve crop resistance, from
And the anti-adversities such as the resistant to lodging of crops, premature senescence resistance, drought-resistant, hot-dry wind tolerance, high temperature resistance low temperature are remarkably reinforced；Also, phase
To general fertilizer, the dosage of N P and K is significantly less in Water soluble fertilizer of the present invention, pollution by chemical fertilizer is alleviated, more since the present invention is providing
While nutrition, moreover it is possible to stimulate crop itself to enhance defending performance, prevent the generation of some diseases, therefore product of the present invention uses
After the light worm of crop disease can be made few, reduce formulation rate and times for spraying, though there is pesticidal effects, but pesticide side effect be not present.
The present invention in order to enable the water-soluble fertilizer can form effective compounding with potassium fulvate and chitosan oligosaccharide, be added to by
The anticaking agent of organic phosphate starch paste and methyl naphthalene sulfonic acid sodium composition, the anticaking agent can form one in fertilizer surface
Layer film effectively coats fertilizer surface, has blocked the generation of fertilizer salt bridge and the diffusion of saturated solution, effectively prevent fertilizer
While material caking, moreover it is possible to increase the instant performance of fertilizer.
Specific implementation mode
In the following, technical scheme of the present invention is described in detail by specific embodiment.
Embodiment 1
One kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, and raw material includes by weight：25 parts of ammonium nitrate, 20 parts of urea,
20 parts of potassium dihydrogen phosphate, 5 parts of potassium fulvate, 10 parts of sodium humate, 15 parts of potassium hydroxide, 2 parts of citric acid, 6 parts of EDTA- disodiums,
5 parts of KOM, 5 parts of sodium gluconate, 0.5 part of copper sulphate, 1 part of boric acid, 0.5 part of magnesium sulfate, 1.5 parts of chitosan oligosaccharide, 30 parts of auxiliary agent disappear
0.1 part of infusion, 1000 parts of water.
The above-mentioned preparation method with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, includes the following steps：
S1, by weight successively by 10 parts of sodium humates, 5 parts of potassium fulvates, 13.5 parts of potassium hydroxide, 30 parts of auxiliary agents, 0.1
Part antifoaming agent, 20 parts of potassium dihydrogen phosphates, 25 parts of ammonium nitrate, 20 parts of urea, 1.5 parts of chitosan oligosaccharides are added in 800 parts of water and stir
It is even to obtain solution A；
S2, by weight by 2 parts of citric acids, 1.5 parts of potassium hydroxide, 6 parts of EDTA- disodiums, 5 parts of KOM, 0.5 part of copper sulphate,
0.5 part of magnesium sulfate, 5 parts of sodium gluconates, 1 part of boric acid, which are added in 200 parts of water, is uniformly mixing to obtain solution B；
S3, solution B is added to mixing in solution A under agitation, obtained described multi-functional water-soluble with degeneration-resistant diseases prevention
Fertilizer.
Embodiment 2
One kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, and raw material includes by weight：35 parts of ammonium nitrate, 10 parts of urea,
30 parts of potassium dihydrogen phosphate, 1 part of potassium fulvate, 15 parts of sodium humate, 10 parts of potassium hydroxide, 4 parts of citric acid, 3 parts of EDTA- disodiums,
10 parts of KOM, 2 parts of sodium gluconate, 1.2 parts of copper sulphate, 0.5 part of boric acid, 1.5 parts of magnesium sulfate, 0.5 part of chitosan oligosaccharide, anticaking agent
1.5 parts, 1 part of auxiliary agent, 1 part of antifoaming agent, 800 parts of water；
The anticaking agent is by organic phosphate starch paste and methyl naphthalene sulfonic acid sodium by weight ratio 1:5 mixing shapes
At；The preparation process of the wherein described organic phosphate starch paste includes：Starch is added to the water to obtain content for the shallow lakes 45wt%
Powder solution, then microwave treatment is carried out to the starch solution, control microwave action temperature is 140 DEG C when microwave treatment, and microwave is made
It is 1000w with power, the microwave action time is 120min, and sodium dihydrogen phosphate insulation reaction 2h, phosphoric acid are added after being cooled to 50 DEG C
The addition of sodium dihydrogen is 0.5 times of the starch solution, and the organic phosphate starch paste is obtained after adjusting pH to 5；
The auxiliary agent is mixed to form by sodium benzoate, bleeding agent HP-1 and ammonium hydroxide, sodium benzoate, bleeding agent HP-1 and ammonia
The weight proportion of water is 0.1:1:0.5；
The above-mentioned preparation method with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, includes the following steps：
S1,15 parts of sodium humates, 1 part of potassium fulvate, 9.5 parts of potassium hydroxide, 1 part of auxiliary agent, 1 part are disappeared successively by weight
Infusion, 30 parts of potassium dihydrogen phosphates, 35 parts of ammonium nitrate, 10 parts of urea, 0.5 part of chitosan oligosaccharide are added in 680 parts of water and stir evenly
To solution A；
S2, by weight by 4 parts of citric acids, 0.5 part of potassium hydroxide, 3 parts of EDTA- disodiums, 10 parts of KOM, 1.2 parts of sulfuric acid
Copper, 1.5 parts of magnesium sulfate, 2 parts of sodium gluconates, 0.5 part of boric acid, 1.5 parts of anticaking agents are added in 120 parts of water and stir evenly
To solution B；
S3, solution B is added to mixing in solution A under agitation, obtained described multi-functional water-soluble with degeneration-resistant diseases prevention
Fertilizer.
Embodiment 3
One kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, and raw material includes by weight：30 parts of ammonium nitrate, 15 parts of urea,
25 parts of potassium dihydrogen phosphate, 3 parts of potassium fulvate, 12 parts of sodium humate, 13 parts of potassium hydroxide, 3 parts of citric acid, 5 parts of EDTA- disodiums,
8 parts of KOM, 3 parts of sodium gluconate, 0.8 part of copper sulphate, 0.7 part of boric acid, 1 part of magnesium sulfate, 0.3 part of ammonium molybdate, 2 parts of manganese sulfate,
1 part of ferrous sulfate, 1 part of chitosan oligosaccharide, 0.7 part of anticaking agent, 15 parts of auxiliary agent, 0.6 part of antifoaming agent, 900 parts of water；
The anticaking agent is by organic phosphate starch paste and methyl naphthalene sulfonic acid sodium by weight ratio 1:3 mixing shapes
At；The preparation process of the wherein described organic phosphate starch paste includes：Starch is added to the water to obtain content for the shallow lakes 95wt%
Powder solution, then microwave treatment is carried out to the starch solution, control microwave action temperature is 100 DEG C when microwave treatment, and microwave is made
It is 1400w with power, the microwave action time is 60min, and sodium dihydrogen phosphate insulation reaction 1h, di(2-ethylhexyl)phosphate are added after being cooled to 60 DEG C
The addition of hydrogen sodium is 2 times of the starch solution, and the organic phosphate starch paste is obtained after adjusting pH to 4；
The auxiliary agent is mixed to form by sodium benzoate, bleeding agent HP-1 and ammonium hydroxide, sodium benzoate, bleeding agent HP-1 and ammonia
The weight proportion of water is 1:0.5:30；
The above-mentioned preparation method with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, includes the following steps：
S1, by weight successively by 12 parts of sodium humates, 3 parts of potassium fulvates, 11.9 parts of potassium hydroxide, 15 parts of auxiliary agents, 0.6
Part antifoaming agent, 25 parts of potassium dihydrogen phosphates, 30 parts of ammonium nitrate, 15 parts of urea, 1 part of chitosan oligosaccharide are added in 728 parts of water and stir evenly
Obtain solution A；
S2, by weight by 3 parts of citric acids, 1.1 parts of potassium hydroxide, 5 parts of EDTA- disodiums, 8 parts of KOM, 0.8 part of copper sulphate,
1 part of magnesium sulfate, 3 parts of sodium gluconates, 0.7 part of boric acid, 0.3 part of ammonium molybdate, 2 parts of manganese sulfates, 1 part of ferrous sulfate, 0.7 part of anti-caking
Block agent is added in 172 parts of water and is uniformly mixing to obtain solution B；
S3, solution B is added to mixing in solution A under agitation, obtained described multi-functional water-soluble with degeneration-resistant diseases prevention
Fertilizer.
Embodiment 4
One kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, and raw material includes by weight：32 parts of ammonium nitrate, 13 parts of urea,
26 parts of potassium dihydrogen phosphate, 1.5 parts of potassium fulvate, 12 parts of sodium humate, 12 parts of potassium hydroxide, 2.5 parts of citric acid, EDTA- disodiums 4
Part, 7 parts of KOM, 4 parts of sodium gluconate, 0.9 part of copper sulphate, 0.8 part of boric acid, 1.2 parts of magnesium sulfate, 0.6 part of ammonium molybdate, manganese sulfate
1 part, 0.2 part of ferrous sulfate, 0.9 part of chitosan oligosaccharide, 0.8 part of anticaking agent, 16 parts of auxiliary agent, 0.5 part of antifoaming agent, 900 parts of water；
The anticaking agent is by organic phosphate starch paste and methyl naphthalene sulfonic acid sodium by weight ratio 1:4 mixing shapes
At；The preparation process of the wherein described organic phosphate starch paste includes：Starch is added to the water to obtain content for the shallow lakes 75wt%
Powder solution, then microwave treatment is carried out to the starch solution, control microwave action temperature is 120 DEG C when microwave treatment, and microwave is made
It is 1200w with power, the microwave action time is 90min, and sodium dihydrogen phosphate insulation reaction 1.5h, phosphoric acid are added after being cooled to 55 DEG C
The addition of sodium dihydrogen is 1 times of the starch solution, and the organic phosphate starch paste is obtained after adjusting pH to 5；
The auxiliary agent is mixed to form by sodium benzoate, bleeding agent HP-1 and ammonium hydroxide, sodium benzoate, bleeding agent HP-1 and ammonia
The weight proportion of water is 0.5:0.7:10；
The above-mentioned preparation method with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, includes the following steps：
S1, by weight successively by 12 parts of sodium humates, 1.5 parts of potassium fulvates, 11 parts of potassium hydroxide, 16 parts of auxiliary agents, 0.5
Part antifoaming agent, 26 parts of potassium dihydrogen phosphates, 32 parts of ammonium nitrate, 13 parts of urea, 0.9 part of chitosan oligosaccharide are added in 720 parts of water and stir
It is even to obtain solution A；
S2, by weight by 2.5 parts of citric acids, 1 part of potassium hydroxide, 4 parts of EDTA- disodiums, 7 parts of KOM, 0.9 part of copper sulphate,
1.2 parts of magnesium sulfate, 4 parts of sodium gluconates, 0.8 part of boric acid, 0.6 part of ammonium molybdate, 1 part of manganese sulfate, 0.2 part of ferrous sulfate, 0.8 part
Anticaking agent is added in 180 parts of water and is uniformly mixing to obtain solution B；
S3, solution B is added to mixing in solution A under agitation, obtained described multi-functional water-soluble with degeneration-resistant diseases prevention
Fertilizer.
Embodiment 5
One kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, and raw material includes by weight：30 parts of ammonium nitrate, 15 parts of urea,
20 parts of potassium dihydrogen phosphate, 3 parts of potassium fulvate, 15 parts of sodium humate, 13 parts of potassium hydroxide, 2 parts of citric acid, 5 parts of EDTA- disodiums,
5 parts of KOM, 2.5 parts of sodium gluconate, 1 part of copper sulphate, 0.9 part of boric acid, 1.5 parts of magnesium sulfate, 1 part of chitosan oligosaccharide, anticaking agent 1.1
Part, 25 parts of auxiliary agent, 0.5 part of antifoaming agent, 830 parts of water；
The anticaking agent is by organic phosphate starch paste and methyl naphthalene sulfonic acid sodium by weight ratio 1:3.5 mixing shapes
At；The preparation process of the wherein described organic phosphate starch paste includes：Starch is added to the water to obtain content for the shallow lakes 60wt%
Powder solution, then microwave treatment is carried out to the starch solution, control microwave action temperature is 130 DEG C when microwave treatment, and microwave is made
It is 1100w with power, the microwave action time is 100min, and sodium dihydrogen phosphate insulation reaction 1.6h, phosphorus are added after being cooled to 56 DEG C
The addition of acid dihydride sodium is 1.5 times of the starch solution, and the organic phosphate starch paste is obtained after adjusting pH to 4；
The auxiliary agent is mixed to form by sodium benzoate, bleeding agent HP-1 and ammonium hydroxide, sodium benzoate, bleeding agent HP-1 and ammonia
The weight proportion of water is 0.6:0.7:5；
The above-mentioned preparation method with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, includes the following steps：
S1, by weight successively by 15 parts of sodium humates, 3 parts of potassium fulvates, 12 parts of potassium hydroxide, 25 parts of auxiliary agents, 0.5 part
Antifoaming agent, 20 parts of potassium dihydrogen phosphates, 30 parts of ammonium nitrate, 15 parts of urea, 1 part of chitosan oligosaccharide are added in 700 parts of water and stir evenly
To solution A；
S2, by weight by 2 parts of citric acids, 1 part of potassium hydroxide, 5 parts of EDTA- disodiums, 5 parts of KOM, 1 part of copper sulphate, 1.5
Part magnesium sulfate, 2.5 parts of sodium gluconates, 0.9 part of boric acid, 1.1 parts of anticaking agents be added in 150 parts of water be uniformly mixing to obtain it is molten
Liquid B；
S3, solution B is added to mixing in solution A under agitation, obtained described multi-functional water-soluble with degeneration-resistant diseases prevention
Fertilizer.
The present invention tests wheat crop, and it is as follows to generate sample reports：
1, experiment material
1.1 test sites and field：Select the positive Yanguan Pass farm uniform field of growing way as experimental plot
1.2 for trying fertilizer：There is the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention in embodiment 5
1.3 experimental design：Experiment sets two processing, is indicated respectively with A, CK, A：Have degeneration-resistant diseases prevention more in embodiment 5
Function Water soluble fertilizer, CK：Fresh water spraying
1.4 experimental plot：Two processing are set in crop field, each handle 250m2(25m*10m)
2, field management：
2.1 the sowing time：On October 10th, 2017
2.2 fertilising situations：It is sprayed respectively once in the boot stage of wheat growth, flowering to Early filling stage, A handles product mu
With 60mL, 30 kilograms of foliar sprays are watered, other field management are the same as general Production of Large Fields.
3, test result and analysis：
3.1 property determination：In the method that wheat ripe harvest time is sampled using big 5 points production (each cell circle is surveyed come species test
Sample 1m2, 5 sampling points, the whole harvests of difference), measure its lower wheat yield, mass of 1000 kernel, hardness and protein content, expelling parasite is prevented
The indexs such as sick, degeneration-resistant
3.2 data analysis：Data analysis is carried out with softwares such as EXCELL, SAS, it was therefore concluded that, test result is arranged
Table 1, table 2
The lower wheat aging time yield of 1 two processing of table and correlated traits phenotypic data
| Processing | Per mu yield (jin) | Mass of 1000 kernel (g) | Hardness (kilogram/cm2) | Crude protein content (g) |
| A | 1053.4 | 44.5 | 11.9 | 13.8 |
| CK | 864.0 | 41.9 | 11.3 | 12.1 |
The lower wheat aging time diseases prevention anti-adversity comparison of 2 two processing of table
As can be seen from Table 1, the wheat yield obtained with the multi-functional Water soluble fertilizer processing of degeneration-resistant diseases prevention is substantially better than control；
And the size of thousand grain weight of wheat is one of the important indicator of wheat grade, and thousand grain weight of wheat is bigger, and wheat higher grade, by table
1 as can be seen that be significantly improved effect to thousand grain weight of wheat with the processing of degeneration-resistant diseases prevention multi-functional Water soluble fertilizer；Wheat hardness and egg
White matter content as can be seen from Table 1, has degeneration-resistant diseases prevention to having decisive role to food processing quality and nutritional quality
The processing of multi-functional Water soluble fertilizer is compared with control treatment, the trend that the hardness and crude protein content of wheat are improved, with hardness
With the raising of crude protein content, the processing quality and nutritional quality of wheat are also corresponding therewith to be improved.
As can be seen from Table 2, have the multi-functional Water soluble fertilizer processing of degeneration-resistant diseases prevention compared with control treatment, diseases prevention and degeneration-resistant effect
The trend that fruit is improved.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. one kind having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, which is characterized in that its raw material includes by weight：Ammonium nitrate 25-35
Part, 10-20 parts of urea, 20-30 parts of potassium dihydrogen phosphate, 1-5 parts of potassium fulvate, 10-15 parts of sodium humate, potassium hydroxide 10-15
Part, 2-4 parts of citric acid, 3-6 parts of EDTA- disodiums, 5-10 parts of KOM, 2-5 parts of sodium gluconate, 0.5-1.2 parts of copper sulphate, boric acid
0.5-1 parts, 0.5-1.5 parts of magnesium sulfate, 0.5-1.5 parts of chitosan oligosaccharide, 0-1.5 parts of anticaking agent, 1-30 parts of auxiliary agent, antifoaming agent 0.1-
1 part, 800-1000 parts of water.
2. having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention according to claim 1, which is characterized in that described to have degeneration-resistant diseases prevention more
Function Water soluble fertilizer further includes：0.3-0.6 parts of ammonium molybdate, 1-2 parts of manganese sulfate, 0.2-1 parts of ferrous sulfate.
3. according to claim 1 or claim 2 have the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, which is characterized in that the anticaking agent is
By organic phosphate starch paste and methyl naphthalene sulfonic acid sodium by weight ratio 1:3-5 is mixed to form.
4. having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention according to claim 3, which is characterized in that prepare the Phosphation and form sediment
The process of powder paste includes：Starch is added to the water to obtain content to be 45-95wt% starch solutions, then to the starch solution
Microwave treatment is carried out, sodium dihydrogen phosphate insulation reaction is added after being cooled to 50-60 DEG C, the phosphoric acid is obtained after adjusting pH to 4-5
Esterification starch paste.
5. having the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention according to claim 4, which is characterized in that prepare the Phosphation and form sediment
During powder paste, control microwave action temperature is 100-140 DEG C when the microwave treatment, and microwave action power is
1000-1400w, microwave action time are 60-120min.
6. described according to claim 4 or 5 have the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention, which is characterized in that prepare the phosphate
During changing starch paste object, the time that sodium dihydrogen phosphate insulation reaction is added is 1-2h, and the addition of sodium dihydrogen phosphate is
0.5-2 times of the starch solution.
7. there is the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention according to any one of claim 1-6, which is characterized in that the auxiliary agent is by benzene
Sodium formate, bleeding agent HP-1 and ammonium hydroxide are mixed to form, it is preferable that the weight proportion of sodium benzoate, bleeding agent HP-1 and ammonium hydroxide is
0.1-1:0.5-1:0.5-30。
8. a kind of preparation method according to the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention described in claim any one of 1-7, feature
It is, includes the following steps：
S1, by formula successively by sodium humate, potassium fulvate, potassium hydroxide, auxiliary agent, antifoaming agent, potassium dihydrogen phosphate, ammonium nitrate,
Urea, chitosan oligosaccharide, which are added to the water, is uniformly mixing to obtain solution A；
S2, by formula by citric acid, potassium hydroxide, EDTA- disodiums, KOM, copper sulphate, magnesium sulfate, sodium gluconate, boric acid, anti-
Agglomeration agent, which is added to the water, is uniformly mixing to obtain solution B；
S3, solution B is added to mixing in solution A under agitation, obtained described with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention.
9. the preparation method with the multi-functional Water soluble fertilizer of degeneration-resistant diseases prevention according to claim 8, which is characterized in that in S1, S2
The dosage of water is respectively to be formulated 80-85%, 15-20% of dosage；The dosage of potassium hydroxide is respectively to be formulated dosage in S1, S2
90-95%, 5-10%.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110452044A (en) * | 2019-08-14 | 2019-11-15 | 河北标驰农业科技有限公司 | A kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof |
| CN111825492A (en) * | 2019-04-15 | 2020-10-27 | 中国科学院微生物研究所 | Water-soluble fertilizer synergistic additive and preparation method thereof |
| CN113651649A (en) * | 2021-09-17 | 2021-11-16 | 青岛科光生物技术有限公司 | Fertilizer with stress-resistant and disease-resistant functions and preparation method thereof |
| EP4188074A4 (en) * | 2020-07-29 | 2024-09-11 | Solugen Inc | Methods and compositions for use in agricultural processes |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105145630A (en) * | 2015-08-02 | 2015-12-16 | 海南正业中农高科股份有限公司 | Composition containing humic acid and chitosan oligosaccharide/chitosan |
| CN105669297A (en) * | 2015-12-30 | 2016-06-15 | 湖南泰谷生物科技股份有限公司 | Humic acid-containing complete-element water soluble fertilizer, and preparation method and application thereof |
| CN105669299A (en) * | 2016-01-05 | 2016-06-15 | 湖南泰谷生物科技股份有限公司 | Macroelement water soluble fertilizer having effect of improving crop growth environment and application thereof |
| CN106278601A (en) * | 2016-08-12 | 2017-01-04 | 董向波 | A kind of biostimulant is containing the preparation method of humic acid water-soluble fertilizer |
| CN106748306A (en) * | 2017-02-21 | 2017-05-31 | 山东康德源农业科技有限公司 | A kind of Multifunctional pesticide fertilizer and preparation method and application |
| CN107285892A (en) * | 2017-07-27 | 2017-10-24 | 云南润杰农业科技股份有限公司 | A kind of multi-functional alkaline water-soluble fertilizer and preparation method thereof, application method and application |
| CN107540470A (en) * | 2017-10-30 | 2018-01-05 | 成都云图控股股份有限公司 | A kind of water-soluble fertilizer containing fulvic acid and preparation method thereof |
-
2018
- 2018-05-30 CN CN201810540991.0A patent/CN108558510A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105145630A (en) * | 2015-08-02 | 2015-12-16 | 海南正业中农高科股份有限公司 | Composition containing humic acid and chitosan oligosaccharide/chitosan |
| CN105669297A (en) * | 2015-12-30 | 2016-06-15 | 湖南泰谷生物科技股份有限公司 | Humic acid-containing complete-element water soluble fertilizer, and preparation method and application thereof |
| CN105669299A (en) * | 2016-01-05 | 2016-06-15 | 湖南泰谷生物科技股份有限公司 | Macroelement water soluble fertilizer having effect of improving crop growth environment and application thereof |
| CN106278601A (en) * | 2016-08-12 | 2017-01-04 | 董向波 | A kind of biostimulant is containing the preparation method of humic acid water-soluble fertilizer |
| CN106748306A (en) * | 2017-02-21 | 2017-05-31 | 山东康德源农业科技有限公司 | A kind of Multifunctional pesticide fertilizer and preparation method and application |
| CN107285892A (en) * | 2017-07-27 | 2017-10-24 | 云南润杰农业科技股份有限公司 | A kind of multi-functional alkaline water-soluble fertilizer and preparation method thereof, application method and application |
| CN107540470A (en) * | 2017-10-30 | 2018-01-05 | 成都云图控股股份有限公司 | A kind of water-soluble fertilizer containing fulvic acid and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111825492A (en) * | 2019-04-15 | 2020-10-27 | 中国科学院微生物研究所 | Water-soluble fertilizer synergistic additive and preparation method thereof |
| CN110452044A (en) * | 2019-08-14 | 2019-11-15 | 河北标驰农业科技有限公司 | A kind of antiviral volume increase Water soluble fertilizer of Multifucntional and preparation method thereof |
| EP4188074A4 (en) * | 2020-07-29 | 2024-09-11 | Solugen Inc | Methods and compositions for use in agricultural processes |
| CN113651649A (en) * | 2021-09-17 | 2021-11-16 | 青岛科光生物技术有限公司 | Fertilizer with stress-resistant and disease-resistant functions and preparation method thereof |
| CN113651649B (en) * | 2021-09-17 | 2022-06-24 | 青岛科光生物技术有限公司 | Fertilizer with stress-resistant and disease-resistant functions and preparation method thereof |
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