CN109369152A - A kind of high intensity is resistance to fall sky blue glaze ceramic and preparation method thereof - Google Patents
A kind of high intensity is resistance to fall sky blue glaze ceramic and preparation method thereof Download PDFInfo
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- CN109369152A CN109369152A CN201811518261.7A CN201811518261A CN109369152A CN 109369152 A CN109369152 A CN 109369152A CN 201811518261 A CN201811518261 A CN 201811518261A CN 109369152 A CN109369152 A CN 109369152A
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/16—Lean materials, e.g. grog, quartz
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- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
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- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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Abstract
The present invention provides that a kind of high intensity is resistance to fall sky blue glaze ceramic, including tire material and glaze, and the tire material includes following raw material: 40 ~ 45 parts of kaolin, quartzy 18 ~ 20 parts, 25 ~ 30 parts of potassium feldspar, 10 ~ 13 parts of clay, 1 ~ 4 part of talcum；The glaze includes following raw material: 24 ~ 26 parts of nepheline syenite, 15 ~ 18 parts of calcium carbonate, burns 4 ~ 6 parts of talcum, 4 ~ 6 parts of kaolin, 9 ~ 12 parts of barium carbonate, 2 ~ 4 parts of bone ash, 4 ~ 6 parts of copper oxide, 18 ~ 20 parts of line borate at 20 ~ 23 parts of nano zine oxide.The high intensity is resistance to fall sky blue glaze ceramic the production method is as follows: ball milling makes tire slurry and glaze slip；Tire slurry makes green body biscuiting；Glazing；Firing.Using the ceramic of raw material provided by the invention and technique firing, in the translucent sky blue state of milkiness as jade, color is simple and elegant generous, and has very strong crash resistance.
Description
Technical field
The invention belongs to ceramic technology fields, and in particular to a kind of high intensity is resistance to fall sky blue glaze ceramic and its production side
Method.
Background technique
Ceramics development history be Chinese civilization history an important component part, China as four major acids ancient country it
One, brilliant contribution is made that for mankind's social progress and development, wherein the invention and development of ceramics have more unique meaning
Justice, each Chao Gedai has different artistic styles and different technical characteristics on Chinese history." china " in English existing China
The meaning, and have the meaning of ceramics, clearly demonstrate that China is exactly " ceramic native place ".Porcelain, which is grasped, early in European manufactures skill
As soon as before more than thousand years of art, Han nationality has produced very exquisite ceramics.China is one of the country for applying pottery earliest in the world,
And Chinese porcelain due to its high practicability and artistry by the high praise of common people.
Sky blue glaze is a kind of high temperature color glaze, is evolved by " reddish black ", and wound is burnt when clear Kangxu.Glaze colours is shallow and turns blue, like day
Blue, it is therefore named.Amount containing cobalt is 2% hereinafter, the metallic elements such as copper, iron, titanium play photoghraphic coupler in glaze；In colour-stable, shining and clean
Cyanines are refined, can match in excellence or beauty with cowpea red, are that the technology skill of ancient times craftsman's exquisiteness and the perfect of immortal design embody.It is existing
The type of sky blue glaze is few in ceramics, and production technology is complicated, and firing is not easy, and has 70% or so product meeting during firing
It scraps, yield rate is low, therefore huge to the waste of raw material, and cost of manufacture is too high；Simultaneously as the progress of science and technology,
There are many materials that can replace porcelain utensil, such as stainless steel, plastics, compared with the vessel made of these materials, tradition
Pottery the shortcomings that there is also poor mechanical properties, if resistance to the falling property of antidetonation is bad, use process, which accidentally falls off, to be easy to break into pieces,
Therefore it needs to develop a kind of new ceramic, to improve the performance of ceramic.
Summary of the invention
Based on the above prior art, the purpose of the present invention is to provide a kind of high intensity it is resistance to fall sky blue glaze ceramic and its
Production method, glaze colours is like the blue of clear sky, and soft simple and elegant, enamel jade-like stone profit, heavily fortified point are close, and glaze paint opaque is good, and glazing is thicker,
Glaze layer is uniform, has earthworm to walk mud line, and hacking is naturally, feel is sedate, and has very strong resistance to falling property.
In order to achieve the goal above, the technical solution adopted by the present invention are as follows: a kind of high intensity is resistance to fall sky blue glaze ceramic,
Including tire material and glaze, which is characterized in that the tire material includes following raw material: 40~45 parts of kaolin, quartz 18~
20 parts, 25~30 parts of potassium feldspar, 10~13 parts of clay, 1~4 part of talcum；The glaze includes following raw material: nepheline is just
24~26 parts of feldspar, 15~18 parts of calcium carbonate, burns 4~6 parts of talcum, 4~6 parts of kaolin, carbonic acid at 20~23 parts of nano zine oxide
9~12 parts of barium, 2~4 parts of bone ash, 4~6 parts of copper oxide, 18~20 parts of line borate.
In order to preferably realize the present invention, further, the tire material includes the raw material of following parts by weight: kaolin 43
Part, quartzy 19 parts, 28 parts of potassium feldspar, 12 parts of clay, 2 parts of talcum；The glaze includes following raw material: nepheline syenite
25 parts, 22 parts of nano zine oxide, 16 parts of calcium carbonate, burning 5 parts of talcum, 5 parts of kaolin, 10 parts of barium carbonate, 3 parts of bone ash, copper oxide 5
Part, 19 parts of line borate.
Make the high-intensitive resistance to method for falling sky blue glaze ceramic the present invention also provides a kind of, which is characterized in that including with
Lower step:
Step 1, weighed respectively according to weight ratio tire feed powder it is broken after be put into ball mill carry out ball milling, addition account for tire material total weight
The water of 33%-36% carries out wet-milling 8-12h, and the slurry by wet-milling is spare by 250 meshes；
Blank is made by moulding in the mud of step 1 by step 2, is modified, is bonded after blank is half-dried, carved etc. and is made
Smart base；
Step 3 enters kiln kiln discharge after 900-1000 DEG C of biscuiting 2-4h, cooling after drying smart base, obtain plain tire；
Step 4 is put into ball mill progress ball milling after weighing glaze crushing respectively according to weight ratio, and addition accounts for glaze total weight
The water of 38%-43% carries out wet-milling 8-12h, and the slurry by wet-milling is spare by 250 meshes；
Element tire obtained in step 3 is dipped into glaze slip obtained in step 4 by step 5, the glaze for waiting its surface to adhere to
Bubble and uneven part on biscuit surface glaze layer are modified in taking-up when reaching 1.5~2.0mm thickness；
Step 6, the biscuit for trimming glaze layer is put into kiln firing, 1250-1280 DEG C of firing temperature.
In order to preferably realize the present invention, further, firing process described in the step 6 specifically includes following step
It is rapid:
1. the biscuit after glazing is put into kiln, heats up under oxidizing atmosphere, temperature is made to be ramped up 1000 in 4~8h
℃；
2. temperature under reducing atmosphere, is made to be ramped up 1250~1280 DEG C in 6~10h；
3. under reducing atmosphere, heat preservation 2~4h after annealing is rapidly cooled to room temperature, it is made.
Beneficial effect
Beneficial effects of the present invention are as follows:
(1) high intensity provided by the invention is resistance to falls sky blue glaze ceramic, using kaolin, quartz, potassium feldspar, clay and
For talcum as tire material at base, kaolin is mainly at base raw material, and whiteness is high, viscosity is big, plasticity is strong, three oxidations contained
Two iron directly affect tire color and glaze quality；The addition of quartz makes blank raw material be easier to be formed, and the green body after also making sizing has
It certain dry tenacity and do not influence and deforms vulnerable to external force, crack；Potassium feldspar can play non-plastic raw material before firing, subtract
The dry contraction and deformation of few green body, improve drying property, shorten drying time, can be used as flux reduction firing temperature in firing
Degree promotes quartz and kaolin melting, and diffuses into one another the formation for permeating and accelerating mullite in the liquid phase, generates in melting
Feldspar vitreum is filled between the mullite grains of green body, is kept green body fine and close and is reduced gap, to improve its mechanical strength
And dielectric properties, increase its high-intensitive resistance to falling property, furthermore the generation of feldspar glass can also improve the translucency of green body；Clay is promoted
The plasticity of blank raw material, green density after making sizing is high, viscosity is high, can make after being combined with quartz after being formed with a thickness of
The green body of 0.3~0.5mm is indeformable, cracks, arrisdefect；Talcum promotes the whiteness and consistency of green body, after Low fire ceramic product, gently
The clear of its surface is hit, when the thickness after green body sizing is small, the ceramic of firing can be made to have certain transparency,
To promote the quality of Low fire ceramic product.
(2) high intensity provided by the invention is resistance to falls sky blue glaze ceramic, uses nepheline syenite, nano zine oxide, carbon
Sour calcium burns talcum, kaolin, barium carbonate, bone ash, copper oxide, line borate as glaze layer raw material, and nepheline syenite main component is
Di-iron trioxide cooperation in silicate, and kaolin generates sky blue glaze, while being furnished with bone ash, introduces phosphorus pentoxide, increases
Add the opaque of glaze colours, be in opalescence state, nano zine oxide can reduce sintering temperature, improve gloss as glaze and fluxing agent
Degree and flexibility, there is excellent performance；It is unified that copper oxide and barium carbonate can further improve glaze face color；Calcium carbonate and boric acid
Calcium can reduce firing temperature, improve the success rate of product, while increase the intensity of ceramic, and each raw material makes to be burnt into after combining
Ceramic have the blue of fine day sky, glaze colours is soft simple and elegant, and enamel jade-like stone profit, hard close, glaze paint opaque is good, glazing compared with
Thickness, glaze layer is uniform, has earthworm to walk mud line, and hacking is naturally, feel is sedate, to be made, high intensity is resistance to fall sky blue glaze ceramic.
(3) high intensity provided by the invention is resistance to falls sky blue glaze ceramic, and blank raw material is from glaze layer raw material using different
Raw material and proportion, blank raw material is mixed and finely ground Hou Jiashui and is made green body pug, then obtains green body through sizing, by high temperature element
It burns, is conducive to tire and porcelain and guarantees at high temperature without porcelain body at glaze in sesame dark reddish brown.Glazing after biscuiting, glazing is than general glaze layer
Make glaze colours thick and heavy after thickness, then high temperature firing, tone burnt hair, glaze mobility can be generated if too high or too low for temperature in sky blue
Greatly, gloss is bright.Glaze thickness is helpful for forming earthworm Zou mud line and hacking simultaneously, and the quartz especially wherein contained is shadow
Ring the key factor of hacking size compactness extent.By adjusting the proportion of green body and glaze layer raw material, can make in high temperature sintering procedure
Green body and glaze layer have the thermal expansivity of relative synchronization, thus keep the ceramic glaze layer opaque of firing good, distinctive earthworm
Walk the lines of mud line, also make the ceramic water resistant of firing it is resistance to fall, intensity it is high, be fired using reducing atmosphere after initial oxidation,
Its glaze colours one integrated mass, whole in colour-stable, tone is soft simple and elegant uniform, and making one for sight is pleasing.
Specific embodiment
Invention is further described in detail combined with specific embodiments below.
Embodiment 1
Sky blue glaze ceramic, including tire material and glaze are fallen the present embodiment provides a kind of high intensity is resistance to, the tire material includes
Following raw material: 40 parts of kaolin, quartzy 18 parts, 25 parts of potassium feldspar, 10 parts of clay, 1 part of talcum；The glaze include with
Lower raw material: 24 parts of nepheline syenite, 15 parts of calcium carbonate, burns 4 parts of talcum, 4 parts of kaolin, carbon at 20 parts of nano zine oxide
9 parts of sour barium, 2 parts of bone ash, 4 parts of copper oxide, 18 parts of line borate.
The present embodiment, which also provides, a kind of makes the high-intensitive resistance to method for falling sky blue glaze ceramic, comprising the following steps:
Step 1, weighed respectively according to weight ratio tire feed powder it is broken after be put into ball mill carry out ball milling, addition account for tire material total weight
33% water carries out wet-milling 12h, and the slurry by wet-milling is spare by 250 meshes；
Blank is made by moulding in the mud of step 1 by step 2, is modified, is bonded after blank is half-dried, carved etc. and is made
Smart base；
Step 3 enters kiln kiln discharge after 900 DEG C of biscuiting 4h, cooling after drying smart base, obtain plain tire；
Step 4 is put into ball mill progress ball milling after weighing glaze crushing respectively according to weight ratio, and addition accounts for glaze total weight
38% water carries out wet-milling 12h, and the slurry by wet-milling is spare by 250 meshes；
Element tire obtained in step 3 is dipped into glaze slip obtained in step 4 by step 5, the glaze for waiting its surface to adhere to
Bubble and uneven part on biscuit surface glaze layer are modified in taking-up when reaching 1.5 thickness；
The biscuit for trimming glaze layer is put into kiln by step 6, is heated up under oxidizing atmosphere, is ramped up temperature 8h
1000℃；Then turn fire under reducing atmosphere, temperature 10h is made to be ramped up 1250 DEG C；Continue under reducing atmosphere, in firing temperature
Heat preservation 4h after annealing is rapidly cooled to room temperature at 1250 DEG C of degree, is made.
Embodiment 2
Sky blue glaze ceramic, including tire material and glaze are fallen the present embodiment provides a kind of high intensity is resistance to, the tire material includes
Following raw material: 41 parts of kaolin, quartzy 19 parts, 26 parts of potassium feldspar, 11 parts of clay, 2 parts of talcum；The glaze include with
Lower raw material: 25 parts of nepheline syenite, 16 parts of calcium carbonate, burns 5 parts of talcum, 5 parts of kaolin, carbon at 21 parts of nano zine oxide
10 parts of sour barium, 3 parts of bone ash, 5 parts of copper oxide, 19 parts of line borate.
The present embodiment, which also provides, a kind of makes the high-intensitive resistance to method for falling sky blue glaze ceramic, comprising the following steps:
Step 1, weighed respectively according to weight ratio tire feed powder it is broken after be put into ball mill carry out ball milling, addition account for tire material total weight
34% water carries out wet-milling 11h, and the slurry by wet-milling is spare by 250 meshes；
Blank is made by moulding in the mud of step 1 by step 2, is modified, is bonded after blank is half-dried, carved etc. and is made
Smart base；
Step 3 enters kiln kiln discharge after 920 DEG C of biscuiting 3.5h, cooling after drying smart base, obtain plain tire；
Step 4 is put into ball mill progress ball milling after weighing glaze crushing respectively according to weight ratio, and addition accounts for glaze total weight
39% water carries out wet-milling 11h, and the slurry by wet-milling is spare by 250 meshes；
Element tire obtained in step 3 is dipped into glaze slip obtained in step 4 by step 5, the glaze for waiting its surface to adhere to
Bubble and uneven part on biscuit surface glaze layer are modified in taking-up when reaching 1.6mm thickness；
The biscuit for trimming glaze layer is put into kiln by step 6, is heated up under oxidizing atmosphere, is ramped up temperature 7h
1000℃；Then turn fire under reducing atmosphere, temperature is made to be ramped up 1260 DEG C in 9h；Continue under reducing atmosphere, be burnt into
3h after annealing is kept the temperature at 1260 DEG C of temperature to be rapidly cooled to room temperature, and is made.
Embodiment 3
Sky blue glaze ceramic, including tire material and glaze are fallen the present embodiment provides a kind of high intensity is resistance to, the tire material includes
Following raw material: 43 parts of kaolin, quartzy 19 parts, 28 parts of potassium feldspar, 12 parts of clay, 2 parts of talcum；The glaze include with
Lower raw material: 25 parts of nepheline syenite, 16 parts of calcium carbonate, burns 5 parts of talcum, 5 parts of kaolin, carbon at 22 parts of nano zine oxide
10 parts of sour barium, 3 parts of bone ash, 5 parts of copper oxide, 19 parts of line borate.
The present embodiment, which also provides, a kind of makes the high-intensitive resistance to method for falling sky blue glaze ceramic, comprising the following steps:
Step 1, weighed respectively according to weight ratio tire feed powder it is broken after be put into ball mill carry out ball milling, addition account for tire material total weight
34% water carries out wet-milling 10h, and the slurry by wet-milling is spare by 250 meshes；
Blank is made by moulding in the mud of step 1 by step 2, is modified, is bonded after blank is half-dried, carved etc. and is made
Smart base；
Step 3 enters kiln kiln discharge after 950 DEG C of biscuiting 2h, cooling after drying smart base, obtain plain tire；
Step 4 is put into ball mill progress ball milling after weighing glaze crushing respectively according to weight ratio, and addition accounts for glaze total weight
40% water carries out wet-milling 10h, and the slurry by wet-milling is spare by 250 meshes；
Element tire obtained in step 3 is dipped into glaze slip obtained in step 4 by step 5, the glaze for waiting its surface to adhere to
Bubble and uneven part on biscuit surface glaze layer are modified in taking-up when reaching 1.8mm thickness；
The biscuit for trimming glaze layer is put into kiln by step 6, is heated up under oxidizing atmosphere, is risen temperature uniformly in 6h
To 1000 DEG C；Then turn fire under reducing atmosphere, temperature is made to be ramped up 1265 DEG C in 8h；Continue under reducing atmosphere, burning
It is rapidly cooled to room temperature, is made at 2h after annealing is kept the temperature at 1265 DEG C of temperature.
Embodiment 4
Sky blue glaze ceramic, including tire material and glaze are fallen the present embodiment provides a kind of high intensity is resistance to, the tire material includes
Following raw material: 43 parts of kaolin, quartzy 20 parts, 29 parts of potassium feldspar, 12 parts of clay, 3 parts of talcum；The glaze include with
Lower raw material: 26 parts of nepheline syenite, 17 parts of calcium carbonate, burns 5 parts of talcum, 6 parts of kaolin, carbon at 22 parts of nano zine oxide
11 parts of sour barium, 4 parts of bone ash, 5 parts of copper oxide, 19 parts of line borate.
The present embodiment, which also provides, a kind of makes the high-intensitive resistance to method for falling sky blue glaze ceramic, comprising the following steps:
Step 1, weighed respectively according to weight ratio tire feed powder it is broken after be put into ball mill carry out ball milling, addition account for tire material total weight
35% water carries out wet-milling 9h, and the slurry by wet-milling is spare by 250 meshes；
Blank is made by moulding in the mud of step 1 by step 2, is modified, is bonded after blank is half-dried, carved etc. and is made
Smart base；
Step 3 enters kiln kiln discharge after 980 DEG C of biscuiting 3h, cooling after drying smart base, obtain plain tire；
Step 4 is put into ball mill progress ball milling after weighing glaze crushing respectively according to weight ratio, and addition accounts for glaze total weight
41% water carries out wet-milling 9h, and the slurry by wet-milling is spare by 250 meshes；
Element tire obtained in step 3 is dipped into glaze slip obtained in step 4 by step 5, the glaze for waiting its surface to adhere to
Bubble and uneven part on biscuit surface glaze layer are modified in taking-up when reaching 1.9mm thickness；
The biscuit for trimming glaze layer is put into kiln by step 6, is heated up under oxidizing atmosphere, is risen temperature uniformly in 5h
To 1000 DEG C；Then turn fire under reducing atmosphere, temperature is made to be ramped up 1270 DEG C in 7h；Continue under reducing atmosphere, burning
It is rapidly cooled to room temperature, is made at 3h after annealing is kept the temperature at 1270 DEG C of temperature.
Embodiment 5
Sky blue glaze ceramic, including tire material and glaze are fallen the present embodiment provides a kind of high intensity is resistance to, the tire material includes
Following raw material: 45 parts of kaolin, 30 parts of potassium feldspar, 13 parts of clay, slides 4 parts at 20 parts of quartz；The glaze includes following
Raw material: 26 parts of nepheline syenite, 18 parts of calcium carbonate, burns 6 parts of talcum, 6 parts of kaolin, carbonic acid at 23 parts of nano zine oxide
12 parts of barium, 4 parts of bone ash, 6 parts of copper oxide, 20 parts of line borate.
The present embodiment, which also provides, a kind of makes the high-intensitive resistance to method for falling sky blue glaze ceramic, comprising the following steps:
Step 1, weighed respectively according to weight ratio tire feed powder it is broken after be put into ball mill carry out ball milling, addition account for tire material total weight
36% water carries out wet-milling 8h, and the slurry by wet-milling is spare by 250 meshes；
Blank is made by moulding in the mud of step 1 by step 2, is modified, is bonded after blank is half-dried, carved etc. and is made
Smart base；
Step 3 enters kiln kiln discharge after 1000 DEG C of biscuiting 2h, cooling after drying smart base, obtain plain tire；
Step 4 is put into ball mill progress ball milling after weighing glaze crushing respectively according to weight ratio, and addition accounts for glaze total weight
43% water carries out wet-milling 8h, and the slurry by wet-milling is spare by 250 meshes；
Element tire obtained in step 3 is dipped into glaze slip obtained in step 4 by step 5, the glaze for waiting its surface to adhere to
Bubble and uneven part on biscuit surface glaze layer are modified in taking-up when reaching 2.0mm thickness；
The biscuit for trimming glaze layer is put into kiln by step 6, is heated up under oxidizing atmosphere, is risen temperature uniformly in 4h
To 1000 DEG C；Then turn fire under reducing atmosphere, temperature is made to be ramped up 1280 DEG C in 6h；Continue under reducing atmosphere, burning
It is rapidly cooled to room temperature, is made at 2h after annealing is kept the temperature at 1280 DEG C of temperature.
The high intensity provided in above-described embodiment 1 to 5 is resistance to fall such as the following table 1 institute of raw material used by sky blue glaze ceramic
Show:
1 raw material of table and parts by weight
The sky blue glaze ceramic that falls resistance to high intensity obtained in above-described embodiment 1 to 5 carries out hardness and strength test, surveys
Method for testing is as follows:
Hardness test: loading plunging using diamond penetrator, tests Vickers hardness, i.e., the Buddha's warrior attendant for being 136 ° with diagonal plane
The tetragonous centrum of stone is cooked pressure head, under the load effect of 9.807~490.3 (1~50kgf), is pressed into ceramic surface, is kept a timing
Between after load removal, material surface just leaves an impression, and the cornerwise length of measurement impression and the area of indentation find out unit plane
The load born in product --- stress, i.e. vickers hardness hv, numerical value is higher, and hardness is bigger.
Bending strength test: generally divide three-point bending and four-point bending intensity, wherein four-point bending is pure bending, is obtained
As a result more accurate, we are tested using four-point bending.
It is resistance to high intensity obtained in above-described embodiment 1 to 5 to fall sky blue glaze ceramic and as the ordinary porcelain of reference examples
Product carries out hardness and strength, and test result is as follows shown in table 2:
2 test result of table
| Test result | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Reference examples |
| Vickers hardness hv | 3980 | 4050 | 4100 | 4070 | 4010 | 1750 |
| Bending strength N | 2790 | 2822 | 2846 | 2835 | 2829 | 1540 |
The high intensity being burnt into above-described embodiment 1 to 5 is resistance to fall sky blue glaze ceramic, Vickers hardness and strength test
Common ceramic products can be better than, wherein the properties of the ceramic to be burnt into embodiment 3 are best, it is most preferred embodiment.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention,
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used
To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features.
All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention
Within protection scope.
Claims (4)
1. a kind of high intensity is resistance to fall sky blue glaze ceramic, including tire material and glaze, which is characterized in that the tire material includes following
Raw material: 40 ~ 45 parts of kaolin, quartzy 18 ~ 20 parts, 25 ~ 30 parts of potassium feldspar, 10 ~ 13 parts of clay, 1 ~ 4 part of talcum；It is described
Glaze includes following raw material: 24 ~ 26 parts of nepheline syenite, 15 ~ 18 parts of calcium carbonate, burns and slides 20 ~ 23 parts of nano zine oxide
4 ~ 6 parts of stone, 4 ~ 6 parts of kaolin, 9 ~ 12 parts of barium carbonate, 2 ~ 4 parts of bone ash, 4 ~ 6 parts of copper oxide, 18 ~ 20 parts of line borate.
2. a kind of high intensity according to claim 1 is resistance to fall sky blue glaze ceramic, which is characterized in that the tire material includes
The raw material of following parts by weight: 43 parts of kaolin, quartzy 19 parts, 28 parts of potassium feldspar, 12 parts of clay, 2 parts of talcum；The glaze includes
Following raw material: 25 parts of nepheline syenite, 22 parts of nano zine oxide, 16 parts of calcium carbonate, burn 5 parts of talcum, 5 parts of kaolin,
10 parts of barium carbonate, 3 parts of bone ash, 5 parts of copper oxide, 19 parts of line borate.
3. a kind of make the resistance to method for falling sky blue glaze ceramic of high intensity of any of claims 1 or 2, which is characterized in that packet
Include following steps:
Step 1, weighed respectively according to weight ratio tire feed powder it is broken after be put into ball mill carry out ball milling, addition account for tire material total weight 33%-
36% water carries out wet-milling 8-12h, and the slurry by wet-milling obtains mud by 250 meshes, spare；
Blank is made by moulding in the mud of step 1 by step 2, is modified, is bonded after blank is half-dried, carved etc. smart base is made；
Step 3 enters kiln kiln discharge after 900 ~ 1000 DEG C of biscuiting 2-4h, cooling after drying smart base, obtain plain tire；
Step 4 is put into ball mill progress ball milling after weighing glaze crushing respectively according to weight ratio, and addition accounts for glaze total weight 38%-
43% water carries out wet-milling 8-12h, and the slurry by wet-milling is spare by 250 meshes；
Element tire obtained in step 3 is dipped into glaze slip obtained in step 4 by step 5, and the glaze for waiting its surface to adhere to reaches
It is taken out when 1.5 ~ 2.0mm thickness, modifies bubble and uneven part on biscuit surface glaze layer；
Step 6, the biscuit for trimming glaze layer is put into kiln firing, 1250-1280 DEG C of firing temperature.
4. the high-intensitive resistance to method for falling sky blue glaze ceramic of production according to claim 3, which is characterized in that the step
Firing process described in rapid 6 specifically includes the following steps:
1. the biscuit after glazing is put into kiln, heat up under oxidizing atmosphere, temperature is made to be ramped up 1000 DEG C in 4 ~ 8h；
2. temperature under reducing atmosphere, is made to be ramped up 1250 ~ 1280 DEG C in 6 ~ 10h；
3. under reducing atmosphere, heat preservation 2 ~ 4h after annealing is rapidly cooled to room temperature, it is made.
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| CN113233765A (en) * | 2021-06-03 | 2021-08-10 | 福建省德化县信良陶瓷有限公司 | Satin matte blue glaze, ceramic product prepared from same and preparation method |
| CN113666713A (en) * | 2021-08-20 | 2021-11-19 | 德化县顺尔美工艺品有限公司 | Soda-fired molten glaze ceramic and preparation method thereof |
| CN114773033A (en) * | 2022-05-07 | 2022-07-22 | 福建省德化县宝瑞陶瓷有限公司 | Domestic ceramic product of transparent glaze and preparation method thereof |
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