CN113233765A - Satin matte blue glaze, ceramic product prepared from same and preparation method - Google Patents
Satin matte blue glaze, ceramic product prepared from same and preparation method Download PDFInfo
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- CN113233765A CN113233765A CN202110621465.9A CN202110621465A CN113233765A CN 113233765 A CN113233765 A CN 113233765A CN 202110621465 A CN202110621465 A CN 202110621465A CN 113233765 A CN113233765 A CN 113233765A
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- blue glaze
- flint
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- 239000000919 ceramic Substances 0.000 title claims abstract description 62
- 238000002360 preparation method Methods 0.000 title abstract description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 60
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 45
- 229910052664 nepheline Inorganic materials 0.000 claims abstract description 45
- 239000010434 nepheline Substances 0.000 claims abstract description 45
- 229910052652 orthoclase Inorganic materials 0.000 claims abstract description 45
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 30
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 30
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 30
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 30
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 30
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 30
- 239000010703 silicon Substances 0.000 claims abstract description 30
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 30
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 30
- 239000011787 zinc oxide Substances 0.000 claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 4
- 238000000498 ball milling Methods 0.000 claims description 61
- 238000010438 heat treatment Methods 0.000 claims description 61
- 239000000463 material Substances 0.000 claims description 55
- 238000007873 sieving Methods 0.000 claims description 50
- 238000001354 calcination Methods 0.000 claims description 24
- 238000001816 cooling Methods 0.000 claims description 24
- 238000001035 drying Methods 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 22
- 239000002002 slurry Substances 0.000 claims description 13
- 238000009210 therapy by ultrasound Methods 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000002791 soaking Methods 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims 2
- 230000000694 effects Effects 0.000 description 5
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000036314 physical performance Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses a satin matt blue glaze, which belongs to the technical field of ceramics and comprises the following raw materials in parts by weight: 35-48 parts of nepheline orthoclase, 0.5-1 part of sodium carboxymethylcellulose, 1-5 parts of EPK kaolin, 15-22 parts of flint, 15-25 parts of silicon ore and 15-22 parts of zinc oxide. The invention provides a satin matt blue glaze, a ceramic product prepared from the same and a preparation method of the glaze. The preparation method is simple and safe in process.
Description
Technical Field
The invention belongs to the technical field of ceramics, and particularly relates to a satin matte blue glaze, a ceramic product prepared from the same and a preparation method of the ceramic product.
Background
The glaze is prepared with quartz, feldspar, clay, etc. as material and through grinding, compounding, glazing, sintering and other steps, and has one protecting vitreous layer formed on the surface of ceramic to strengthen the physical performance of ceramic, raise the heat stability, beautify the appearance of ceramic product and facilitate the cleaning of the surface of ceramic product. At present, glaze applied to ceramic products is smooth, has high brightness and has no texture.
Disclosure of Invention
The technical problem to be solved by the invention is as follows: the preparation method is simple, the obtained glaze is satin matt blue, the glaze is applied to the surface of the ceramic product, and the obtained ceramic product is satin matt blue, has moderate brightness and sufficient texture.
The solution of the invention for solving the technical problem is as follows:
a satin matt blue glaze comprises the following raw materials in parts by weight: 35-48 parts of nepheline orthoclase, 0.5-1 part of sodium carboxymethylcellulose, 1-5 parts of EPK kaolin, 15-22 parts of flint, 15-25 parts of silicon ore and 15-22 parts of zinc oxide.
Further, the satin matte blue glaze comprises the following raw materials in parts by weight: 42-48 parts of nepheline orthoclase, 0.8-1 part of sodium carboxymethylcellulose, 2-5 parts of EPK kaolin, 18-22 parts of flint, 20-25 parts of silicon ore and 18-22 parts of zinc oxide.
Further, the satin matte blue glaze comprises the following raw materials in parts by weight: 42 parts of nepheline orthoclase, 0.8 part of sodium carboxymethylcellulose, 2 parts of EPK kaolin, 18 parts of flint, 20 parts of silicon ore and 18 parts of zinc oxide.
Further, the pretreatment is carried out on the flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: performing 30KHz ultrasonic treatment on flint and nepheline orthoclase for 20-30min, soaking in absolute ethanol overnight, taking out, naturally drying, placing into a tubular muffle furnace for anaerobic calcination, heating to 200-phase and 300 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 600-phase and 700 ℃ at 5 ℃/min, keeping the temperature for 2-3h, cooling to room temperature at 10 ℃/min, taking out, performing ball milling in a ball mill for 2h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
Further, it is characterized by comprising the following steps:
s1, adding the silicon ore and zinc oxide into a ball mill according to the weight part ratio for ball milling for 20-25h, and sieving with a 200-mesh sieve to obtain a material 1;
s2, putting the EPK kaolin and the sodium carboxymethyl cellulose into a ball mill for ball milling for 3-4h, and sieving by a 100-mesh sieve to obtain a material 2;
s3, adding water into the material 2, continuing ball milling for 2-3h, adding the material 1, the flint and the nepheline orthoclase, continuing ball milling for 3-5h, and sieving to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 500-550 ℃ at a speed of 10 ℃/min, keeping the temperature for 40-50min, continuing heating to 1100-1200 ℃ at a speed of 15 ℃/min, keeping the temperature for 60-90min, then heating to 1300 ℃ at a speed of 10 ℃/min, keeping the temperature for 10min, and finally cooling to room temperature at a speed of 15 ℃/min to obtain the satin matt blue glaze ceramic.
Further, in step S3, the satin matte blue glaze concentration is 40 ° to 45 ° baume.
A satin matt blue glaze ceramic product prepared by the preparation method of the satin matt blue glaze ceramic product.
The invention has the beneficial effects that: the invention provides a satin matt blue glaze, a ceramic product prepared from the same and a preparation method of the glaze. The preparation method is simple and safe in process.
Detailed Description
The conception, specific structure, and technical effects of the present application will be described clearly and completely with reference to the following embodiments, so that the purpose, features, and effects of the present application can be fully understood. Obviously, the described embodiments are only a part of the embodiments of the present application, and not all embodiments, and other embodiments obtained by those skilled in the art without inventive efforts based on the embodiments of the present application belong to the protection scope of the present application.
In all embodiments of the invention, the flint and nepheline orthoclase are mixed and simultaneously placed into an ultrasonic device for ultrasonic treatment, and taken out and soaked overnight with absolute ethyl alcohol just submerging the materials after ultrasonic treatment.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 200g of silicon ore and 180g of zinc oxide into a ball mill for ball milling for 22h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 20g of EPK kaolin and 8g of sodium carboxymethyl cellulose into a ball mill, carrying out ball milling for 3.5h, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding water into the material 2, continuing ball milling for 2.5 hours, adding the material 1 and the mixture, continuing ball milling for 4 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying at 60 ℃, then placing in a kiln for aerobic calcination, heating to 520 ℃ at 10 ℃/min and keeping the temperature for 45min, continuing heating to 1150 ℃ at 15 ℃/min and keeping the temperature for 75min, then heating to 1300 ℃ at 10 ℃/min and keeping the temperature for 10min, and finally cooling to room temperature at 15 ℃/min to obtain the 42-degree baume-degree satin matt blue glazed ceramic.
Comparative example 1:
a satin matt blue glaze comprises the following raw materials in parts by weight: 42 parts of nepheline orthoclase, 0.8 part of sodium carboxymethylcellulose, 2 parts of EPK kaolin, 18 parts of flint, 20 parts of silicon ore and 18 parts of zinc oxide.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 200g of silicon ore and 180g of zinc oxide into a ball mill for ball milling for 22h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 20g of EPK kaolin and 8g of sodium carboxymethyl cellulose into a ball mill, carrying out ball milling for 3.5h, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 600g of water into the material 2, continuing ball milling for 2.5 hours, adding the material 1, 180g of flint and 420g of nepheline orthoclase, continuing ball milling for 4 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying at 60 ℃, then placing in a kiln for aerobic calcination, heating to 520 ℃ at 10 ℃/min and keeping the temperature for 45min, continuing heating to 1150 ℃ at 15 ℃/min and keeping the temperature for 75min, then heating to 1300 ℃ at 10 ℃/min and keeping the temperature for 10min, and finally cooling to room temperature at 15 ℃/min to obtain the 42-degree baume-degree satin matt blue glazed ceramic.
Example 1:
a satin matt blue glaze comprises the following raw materials in parts by weight: 42 parts of nepheline orthoclase, 0.8 part of sodium carboxymethylcellulose, 2 parts of EPK kaolin, 18 parts of flint, 20 parts of silicon ore and 18 parts of zinc oxide.
The pretreatment method of the flint and nepheline orthoclase comprises the following steps: carrying out 30KHz ultrasonic treatment on 180g of flint and 420g of nepheline orthoclase for 25min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing in a tubular muffle furnace for anaerobic calcination, heating to 250 ℃ at the speed of 10 ℃/min, keeping the temperature for 1h, heating to 650 ℃ at the speed of 5 ℃/min, keeping the temperature for 2.5h, cooling to room temperature at the speed of 10 ℃/min, taking out, carrying out ball milling in a ball mill for 2h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 200g of silicon ore and 180g of zinc oxide into a ball mill for ball milling for 22h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 20g of EPK kaolin and 8g of sodium carboxymethyl cellulose into a ball mill, carrying out ball milling for 3.5h, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 600g of water into the material 2, continuing ball milling for 2.5 hours, adding the material 1 and the mixture, continuing ball milling for 4 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying at 60 ℃, then placing in a kiln for aerobic calcination, heating to 520 ℃ at 10 ℃/min and keeping the temperature for 45min, continuing heating to 1150 ℃ at 15 ℃/min and keeping the temperature for 75min, then heating to 1300 ℃ at 10 ℃/min and keeping the temperature for 10min, and finally cooling to room temperature at 15 ℃/min to obtain the 42-degree baume-degree satin matt blue glazed ceramic.
Example 2:
a satin matt blue glaze comprises the following raw materials in parts by weight: 35 parts of nepheline orthoclase, 0.5 part of sodium carboxymethylcellulose, 1 part of EPK kaolin, 15 parts of flint, 15 parts of silicon ore and 15 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: carrying out 30KHz ultrasonic treatment on 150g of flint and 350g of nepheline orthoclase for 20min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing in a tubular muffle furnace for anaerobic calcination, heating to 200 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 600 ℃ at 5 ℃/min, keeping the temperature for 2h, cooling to room temperature at 10 ℃/min, taking out, carrying out ball milling in a ball mill for 2h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 150g of silicon ore and 150g of zinc oxide into a ball mill for ball milling for 20h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 10g of EPK kaolin and 5g of sodium carboxymethylcellulose into a ball mill for ball milling for 3h, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 400g of water into the material 2, continuing ball milling for 2 hours, adding the material 1 and the mixture, continuing ball milling for 3 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying at 60 ℃, then placing in a kiln for aerobic calcination, heating to 500 ℃ at 10 ℃/min and preserving heat for 40min, continuing heating to 1100 ℃ at 15 ℃/min and preserving heat for 60min, then heating to 1300 ℃ at 10 ℃/min and preserving heat for 10min, and finally cooling to room temperature at 15 ℃/min to obtain the 40-DEG baume-degree satin surface matt blue glazed ceramic.
Example 3:
a satin matt blue glaze comprises the following raw materials in parts by weight: 40 parts of nepheline orthoclase, 0.7 part of sodium carboxymethylcellulose, 3 parts of EPK kaolin, 17 parts of flint, 18 parts of silicon ore and 17 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: the method comprises the steps of firstly performing 30KHz ultrasonic treatment on 170g of flint and 400g of nepheline orthoclase for 20min, then soaking in absolute ethyl alcohol overnight, taking out, naturally drying, then placing in a tubular muffle furnace for anaerobic calcination, heating to 200 ℃ at the speed of 10 ℃/min, keeping the temperature for 1h, heating to 600 ℃ at the speed of 5 ℃/min, keeping the temperature for 2h, then cooling to room temperature at the speed of 10 ℃/min, taking out, performing ball milling in a ball mill for 2h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 180g of silicon ore and 170g of zinc oxide into a ball mill, carrying out ball milling for 20h, and sieving with a 200-mesh sieve to obtain a material 1;
s2, putting 30g of EPK kaolin and 7g of sodium carboxymethylcellulose into a ball mill for ball milling for 3h, and sieving with a 100-mesh sieve and a 200-mesh sieve to obtain a material 2;
s3, adding 580g of water into the material 2, continuing ball milling for 2 hours, and adding the material 1 and the mixture into the mixture, continuing ball milling for 3 hours to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying at 60 ℃, then placing in a kiln for aerobic calcination, heating to 500 ℃ at 10 ℃/min and preserving heat for 40min, continuing heating to 1100 ℃ at 15 ℃/min and preserving heat for 60min, then heating to 1300 ℃ at 10 ℃/min and preserving heat for 10min, and finally cooling to room temperature at 15 ℃/min to obtain the 41-DEG baume-degree satin matt blue glazed ceramic.
Example 4:
a satin matt blue glaze comprises the following raw materials in parts by weight: 46 parts of nepheline orthoclase, 0.9 part of sodium carboxymethylcellulose, 4 parts of EPK kaolin, 20 parts of flint, 24 parts of silicon ore and 20 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: carrying out 30KHz ultrasonic treatment on 200g of flint and 460g of nepheline orthoclase for 28min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing in a tubular muffle furnace for anaerobic calcination, heating to 280 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 680 ℃ at 5 ℃/min, keeping the temperature for 2.8h, cooling to room temperature at 10 ℃/min, taking out, carrying out ball milling in a ball mill for 2h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 240g of silicon ore and 200g of zinc oxide into a ball mill for ball milling for 23h, and sieving with a 200-mesh sieve to obtain a material 1;
s2, putting 40g of EPK kaolin and 9g of sodium carboxymethyl cellulose into a ball mill, carrying out ball milling for 3.8h, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 700g of water into the material 2, continuing ball milling for 2.8 hours, adding the material 1 and the mixture, continuing ball milling for 4 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 540 ℃ at a speed of 10 ℃/min, keeping the temperature for 48min, continuing heating to 1180 ℃ at a speed of 15 ℃/min, keeping the temperature for 80min, then heating to 1300 ℃ at a speed of 10 ℃/min, keeping the temperature for 10min, and finally cooling to room temperature at a speed of 15 ℃/min to obtain the 44-DEG baume-degree satin matt blue glazed ceramic glaze.
Example 5:
a satin matt blue glaze comprises the following raw materials in parts by weight: 48 parts of nepheline orthoclase, 1 part of sodium carboxymethylcellulose, 5 parts of EPK kaolin, 22 parts of flint, 25 parts of silicon ore and 22 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: carrying out 30KHz ultrasonic treatment on 220g flint and 480g nepheline orthoclase for 28min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing in a tubular muffle furnace for anaerobic calcination, heating to 280 ℃ at a rate of 10 ℃/min, keeping the temperature for 1h, heating to 680 ℃ at a rate of 5 ℃/min, keeping the temperature for 2.8h, cooling to room temperature at a rate of 10 ℃/min, taking out, carrying out ball milling in a ball mill for 2h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 250g of silicon ore and 220g of zinc oxide into a ball mill for ball milling for 23h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 50g of EPK kaolin and 10g of sodium carboxymethylcellulose into a ball mill, carrying out ball milling for 3.8h, sieving with a 100-mesh sieve, and sieving with a 200-mesh sieve to obtain a material 2;
s3, adding 750g of water into the material 2, continuing ball milling for 2.8 hours, adding the material 1 and the mixture, continuing ball milling for 4 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 540 ℃ at a speed of 10 ℃/min, keeping the temperature for 48min, continuing heating to 1180 ℃ at a speed of 15 ℃/min, keeping the temperature for 80min, then heating to 1300 ℃ at a speed of 10 ℃/min, keeping the temperature for 10min, and finally cooling to room temperature at a speed of 15 ℃/min to obtain the 45-DEG baume-degree satin matt blue glazed ceramic glaze.
Example 6:
a satin matt blue glaze comprises the following raw materials in parts by weight: 48 parts of nepheline orthoclase, 1 part of sodium carboxymethylcellulose, 5 parts of EPK kaolin, 22 parts of flint, 25 parts of silicon ore and 22 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: performing 30KHz ultrasonic treatment on 220g flint and 480g nepheline orthoclase for 30min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing into a tubular muffle furnace for anaerobic calcination, heating to 300 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 700 ℃ at 5 ℃/min, keeping the temperature for 2.8h, cooling to room temperature at 10 ℃/min, taking out, performing ball milling in a ball mill for 3h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 250g of silicon ore and 220g of zinc oxide into a ball mill for ball milling for 23h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 50g of EPK kaolin and 10g of sodium carboxymethyl cellulose into a ball mill, carrying out ball milling for 3.8h, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 750g of water into the material 2, continuing ball milling for 2.8 hours, adding the material 1 and the mixture, continuing ball milling for 4 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 540 ℃ at a speed of 10 ℃/min, keeping the temperature for 48min, continuing heating to 1180 ℃ at a speed of 15 ℃/min, keeping the temperature for 80min, then heating to 1300 ℃ at a speed of 10 ℃/min, keeping the temperature for 10min, and finally cooling to room temperature at a speed of 15 ℃/min to obtain the 45-DEG baume-degree satin matt blue glazed ceramic glaze.
Example 7:
a satin matt blue glaze comprises the following raw materials in parts by weight: 48 parts of nepheline orthoclase, 1 part of sodium carboxymethylcellulose, 5 parts of EPK kaolin, 22 parts of flint, 25 parts of silicon ore and 22 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: performing 30KHz ultrasonic treatment on 220g flint and 480g nepheline orthoclase for 30min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing into a tubular muffle furnace for anaerobic calcination, heating to 300 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 700 ℃ at 5 ℃/min, keeping the temperature for 2.8h, cooling to room temperature at 10 ℃/min, taking out, performing ball milling in a ball mill for 3h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 250g of silicon ore and 220g of zinc oxide into a ball mill for ball milling for 25h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 50g of EPK kaolin and 10g of sodium carboxymethylcellulose into a ball mill for ball milling for 4 hours, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 750g of water into the material 2, continuing ball milling for 3 hours, adding the material 1 and the mixture, continuing ball milling for 5 hours, and sieving by using a 200-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 550 ℃ at a rate of 10 ℃/min, keeping the temperature for 50min, continuing heating to 1200 ℃ at a rate of 15 ℃/min, keeping the temperature for 80min, then heating to 1300 ℃ at a rate of 10 ℃/min, keeping the temperature for 10min, and finally cooling to room temperature at a rate of 15 ℃/min to obtain the 45-degree baume-degree satin surface matt blue glaze ceramic.
Example 8:
a satin matt blue glaze comprises the following raw materials in parts by weight: 48 parts of nepheline orthoclase, 1 part of sodium carboxymethylcellulose, 5 parts of EPK kaolin, 22 parts of flint, 25 parts of silicon ore and 22 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: performing 30KHz ultrasonic treatment on 220g flint and 480g nepheline orthoclase for 30min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing into a tubular muffle furnace for anaerobic calcination, heating to 300 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 700 ℃ at 5 ℃/min, keeping the temperature for 2.8h, cooling to room temperature at 10 ℃/min, taking out, performing ball milling in a ball mill for 3h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 250g of silicon ore and 220g of zinc oxide into a ball mill for ball milling for 25h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 50g of EPK kaolin and 10g of sodium carboxymethylcellulose into a ball mill for ball milling for 4 hours, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 750g of water into the material 2, continuing ball milling for 3 hours, adding the material 1 and the mixture, continuing ball milling for 5 hours, and sieving by using a 100-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 550 ℃ at a rate of 10 ℃/min, keeping the temperature for 50min, continuing heating to 1200 ℃ at a rate of 15 ℃/min, keeping the temperature for 80min, then heating to 1300 ℃ at a rate of 10 ℃/min, keeping the temperature for 10min, and finally cooling to room temperature at a rate of 15 ℃/min to obtain the 45-degree baume-degree satin surface matt blue glaze ceramic.
Example 9:
a satin matt blue glaze comprises the following raw materials in parts by weight: 48 parts of nepheline orthoclase, 1 part of sodium carboxymethylcellulose, 5 parts of EPK kaolin, 22 parts of flint, 25 parts of silicon ore and 22 parts of zinc oxide.
Pretreatment is carried out on flint and nepheline orthoclase, and the pretreatment specifically comprises the following steps: performing 30KHz ultrasonic treatment on 220g flint and 480g nepheline orthoclase for 30min, soaking in absolute ethyl alcohol overnight, taking out, naturally drying, placing into a tubular muffle furnace for anaerobic calcination, heating to 300 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 700 ℃ at 5 ℃/min, keeping the temperature for 2.8h, cooling to room temperature at 10 ℃/min, taking out, performing ball milling in a ball mill for 3h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
A preparation method of a satin matt blue glaze ceramic product comprises the following steps:
s1, adding 250g of silicon ore and 220g of zinc oxide into a ball mill for ball milling for 25h, and sieving by using a 200-mesh sieve to obtain a material 1;
s2, putting 50g of EPK kaolin and 10g of sodium carboxymethylcellulose into a ball mill for ball milling for 4 hours, and sieving by using a 100-mesh sieve to obtain a material 2;
s3, adding 750g of water into the material 2, continuing ball milling for 3 hours, adding the material 1 and the mixture, continuing ball milling for 5 hours, and sieving through a 300-mesh sieve to obtain a satin matt blue glaze;
s4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 550 ℃ at a rate of 10 ℃/min, keeping the temperature for 50min, continuing heating to 1200 ℃ at a rate of 15 ℃/min, keeping the temperature for 80min, then heating to 1300 ℃ at a rate of 10 ℃/min, keeping the temperature for 10min, and finally cooling to room temperature at a rate of 15 ℃/min to obtain the 45-degree baume-degree satin surface matt blue glaze ceramic.
The effect of frit size on frit properties is shown in table 1.
Table 1 effect of glaze particle size on glaze properties
The impact of pretreatment of flint and nepheline orthoclase on ceramic product performance is shown in table 2.
Table 2 impact of pretreatment of flint and nepheline orthoclase on ceramic product performance
The effect of glaze raw material amount on the properties of the ceramic article is shown in table 3.
TABLE 3 influence of glaze raw material dosage on ceramic product properties
While the preferred embodiments of the present invention have been described in detail, it will be understood by those skilled in the art that the invention is not limited to the details of the embodiments, but is capable of various modifications and substitutions without departing from the spirit of the invention.
Claims (7)
1. The satin matt blue glaze is characterized by comprising the following raw materials in parts by weight: 35-48 parts of nepheline orthoclase, 0.5-1 part of sodium carboxymethylcellulose, 1-5 parts of EPK kaolin, 15-22 parts of flint, 15-25 parts of silicon ore and 15-22 parts of zinc oxide.
2. The satin matte blue glaze according to claim 1, which comprises the following raw materials in parts by weight: 42-48 parts of nepheline orthoclase, 0.8-1 part of sodium carboxymethylcellulose, 2-5 parts of EPK kaolin, 18-22 parts of flint, 20-25 parts of silicon ore and 18-22 parts of zinc oxide.
3. The satin matte blue glaze according to claim 2, which comprises the following raw materials in parts by weight: 42 parts of nepheline orthoclase, 0.8 part of sodium carboxymethylcellulose, 2 parts of EPK kaolin, 18 parts of flint, 20 parts of silicon ore and 18 parts of zinc oxide.
4. The satin matte blue glaze of claim 3, wherein the flint and nepheline orthoclase are pretreated first, specifically: performing 30KHz ultrasonic treatment on flint and nepheline orthoclase for 20-30min, soaking in absolute ethanol overnight, taking out, naturally drying, placing into a tubular muffle furnace for anaerobic calcination, heating to 200-phase and 300 ℃ at 10 ℃/min, keeping the temperature for 1h, heating to 600-phase and 700 ℃ at 5 ℃/min, keeping the temperature for 2-3h, cooling to room temperature at 10 ℃/min, taking out, performing ball milling in a ball mill for 2h, taking out, and sieving with a 200-mesh sieve to obtain a mixture for later use.
5. A method of making a satin matte blue glaze ceramic article using the satin matte blue glaze of claim 1, comprising the steps of:
s1, adding the silicon ore and the zinc oxide into a ball mill according to the weight part ratio for ball milling for 20-25h, and sieving with a 200-mesh sieve to obtain a material 1;
s2, putting the EPK kaolin and the sodium carboxymethyl cellulose into a ball mill for ball milling for 3-4h, and sieving with a 100-mesh sieve to obtain a material 2;
s3, adding water into the material 2, continuing to ball mill for 2-3h, adding the material 1, the flint and the nepheline orthoclase, continuing to ball mill for 3-5h, and sieving to obtain a satin matt blue glaze material;
and S4, immersing the fired ceramic body into the glaze slurry for glazing, drying, placing in a kiln for aerobic calcination, heating to 500-550 ℃ at a speed of 10 ℃/min, preserving heat for 40-50min, continuously heating to 1100-1200 ℃ at a speed of 15 ℃/min, preserving heat for 60-90min, heating to 1300 ℃ at a speed of 10 ℃/min, preserving heat for 10min, and finally cooling to room temperature at a speed of 15 ℃/min to obtain the satin-surface blue-blue glaze ceramic.
6. The method of manufacturing a satin matte blue glaze ceramic product according to claim 5, wherein in step S3, the satin matte blue glaze concentration is 40 ° to 45 ° baume.
7. A satin matte blue glaze ceramic product produced by the method of producing a satin matte blue glaze ceramic product according to claim 5.
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| CN115572068A (en) * | 2022-10-24 | 2023-01-06 | 福建省德化县哈维陶瓷有限公司 | Low-temperature fast-firing matt glaze and manufacturing process thereof |
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