CN113979637A - Transmutation glaze, transmutation glaze laterite ceramic product and preparation method thereof - Google Patents
Transmutation glaze, transmutation glaze laterite ceramic product and preparation method thereof Download PDFInfo
- Publication number
- CN113979637A CN113979637A CN202111411405.0A CN202111411405A CN113979637A CN 113979637 A CN113979637 A CN 113979637A CN 202111411405 A CN202111411405 A CN 202111411405A CN 113979637 A CN113979637 A CN 113979637A
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- transmutation
- transmutation glaze
- red clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009377 nuclear transmutation Methods 0.000 title claims abstract description 77
- 239000000919 ceramic Substances 0.000 title claims abstract description 58
- 229910001710 laterite Inorganic materials 0.000 title claims abstract description 38
- 239000011504 laterite Substances 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000002360 preparation method Methods 0.000 title abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000004927 clay Substances 0.000 claims abstract description 49
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 32
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 32
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 32
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 32
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000011787 zinc oxide Substances 0.000 claims abstract description 32
- 239000002994 raw material Substances 0.000 claims abstract description 31
- 229910007948 ZrB2 Inorganic materials 0.000 claims abstract description 21
- JUZTWRXHHZRLED-UHFFFAOYSA-N [Si].[Cu].[Cu].[Cu].[Cu].[Cu] Chemical compound [Si].[Cu].[Cu].[Cu].[Cu].[Cu] JUZTWRXHHZRLED-UHFFFAOYSA-N 0.000 claims abstract description 21
- VWZIXVXBCBBRGP-UHFFFAOYSA-N boron;zirconium Chemical compound B#[Zr]#B VWZIXVXBCBBRGP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910021360 copper silicide Inorganic materials 0.000 claims abstract description 21
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 claims abstract description 21
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 21
- 229910052656 albite Inorganic materials 0.000 claims abstract description 20
- 239000010453 quartz Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052796 boron Inorganic materials 0.000 claims description 28
- 239000002002 slurry Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 15
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 12
- 238000001816 cooling Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 10
- 239000010433 feldspar Substances 0.000 claims description 10
- 229940072033 potash Drugs 0.000 claims description 10
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 10
- 235000015320 potassium carbonate Nutrition 0.000 claims description 10
- 238000010304 firing Methods 0.000 claims description 7
- 238000000498 ball milling Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000007873 sieving Methods 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000012856 weighed raw material Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 10
- 230000004888 barrier function Effects 0.000 abstract description 6
- 239000007788 liquid Substances 0.000 abstract description 5
- 230000000052 comparative effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000007796 conventional method Methods 0.000 description 3
- 230000006978 adaptation Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000007605 air drying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses transmutation glaze, a transmutation glaze laterite ceramic product and a preparation method thereof, wherein the transmutation glaze comprises the following raw materials in parts by weight: 18-23 parts of albite, 6-8 parts of potassium feldspar, 28-35 parts of quartz, 10-13 parts of red clay, 3-5 parts of calcined kaolin, 7-9.5 parts of copper silicide, 3-4.5 parts of zirconium diboride, 2.6-3.2 parts of niobium carbide, 2-2.5 parts of silicon carbide, 5-7 parts of manganese dioxide, 12-16 parts of zinc oxide and 3-4.5 parts of titanium oxide. The transmutation glaze disclosed by the invention is prepared by selecting raw materials and reasonably proportioning, and the prepared transmutation glaze laterite ceramic product is small in water absorption, good in liquid water barrier property and not easy to absorb moisture; the glossiness is high, and the wear resistance of the glaze surface is good; the glaze surface is smooth and level, the glossiness is good, and the advantages such as pleasing to the eye.
Description
Technical Field
The invention relates to the field of ceramic products, in particular to a transmutation glaze, a transmutation glaze laterite ceramic product and a preparation method thereof.
Background
The fambe glaze, as the name suggests, has an unexpected glaze color effect in the firing process of the ware. Due to the fact that the kiln contains various coloring elements, the porcelain can show unexpected glaze color effects after being taken out of the kiln through oxidation or reduction. The surface of the prepared transmutation glaze has multiple textures and has higher ornamental value.
Ceramic products are one of the most common appliances in people's daily life.
The red clay ceramic product is a daily life appliance such as a jar, a pot, a bowl, a pot, a bottle and the like. The laterite ceramic product has a porous structure, is easy to absorb water and even leak, has poor barrier property, and is easy to absorb moisture and increase weight; the wear resistance of the glaze is poor; the surface is rough and uneven, the glossiness is low, and the like.
Disclosure of Invention
Based on the situation, the invention aims to provide a transmutation glaze, a transmutation glaze laterite ceramic product and a preparation method thereof, which can effectively solve the problems. According to the invention, the transmutation glaze is prepared by selecting raw materials, reasonably proportioning and selecting raw materials such as albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide, high-boron frit and the like in proper proportion, so that the prepared transmutation glaze laterite ceramic product has the advantages of low water absorption rate, good liquid water barrier property and low moisture absorption tendency; the glossiness is high, and the wear resistance of the glaze surface is good; the glaze surface is flat and smooth, the glossiness is good, and the appearance is beautiful;
in addition, the transmutation glaze disclosed by the invention has better comprehensive performance than that of a common transmutation glaze laterite ceramic product.
In order to solve the technical problems, the technical scheme provided by the invention is as follows:
the transmutation glaze comprises the following raw materials in parts by weight:
18-23 parts of albite,
6-8 parts of potassium feldspar,
28-35 parts of quartz,
10-13 parts of red clay,
3-5 parts of calcined kaolin,
7 to 9.5 parts of copper silicide,
3 to 4.5 parts of zirconium diboride,
2.6 to 3.2 parts of niobium carbide,
2-2.5 parts of silicon carbide,
5-7 parts of manganese dioxide,
12-16 parts of zinc oxide,
3-4.5 parts of titanium oxide.
According to the invention, the transmutation glaze is prepared by selecting raw materials, reasonably proportioning and selecting raw materials such as albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide, high-boron frit and the like in proper proportion, so that the prepared transmutation glaze laterite ceramic product has the advantages of low water absorption rate, good liquid water barrier property and low moisture absorption tendency; the glossiness is high, and the wear resistance of the glaze surface is good; the glaze surface is flat and smooth, the glossiness is good, and the appearance is beautiful;
in addition, the transmutation glaze disclosed by the invention has better comprehensive performance than that of a common transmutation glaze laterite ceramic product.
Preferably, the transmutation glaze comprises the following raw materials in parts by weight:
20.5 parts of albite,
7 parts of potassium feldspar,
31.5 parts of quartz,
11.5 parts of red clay,
4 parts of calcined kaolin,
8.3 parts of copper silicide,
3.7 parts of zirconium diboride,
2.9 parts of niobium carbide,
2.25 parts of silicon carbide,
6 parts of manganese dioxide,
14 parts of zinc oxide,
3.8 parts of titanium oxide.
Preferably, the red clay is calcined red clay with the granularity of 3000-4000 meshes.
Preferably, the kaolin is calcined kaolin, and the particle size is 4000-5000 meshes.
Preferably, the zinc oxide is nano zinc oxide.
Preferably, the titanium oxide is nano titanium oxide.
Preferably, the transmutation glaze further comprises the following raw materials in parts by weight: 4-6 parts of high-boron frit.
Preferably, the boron content of the high-boron frit is 10-13%, and the lead content is less than 0.01%.
Meanwhile, the invention also provides a transmutation glaze laterite ceramic product, which comprises a laterite ceramic body and a glaze layer covering the surface of the laterite ceramic body, wherein the glaze layer is the transmutation glaze.
Meanwhile, the invention also provides a preparation method of the transmutation glaze laterite ceramic product, which comprises the following steps:
A. weighing the following raw materials in parts by weight: albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide and high boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling the mixture for 40-60 min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2.3: (0.65-0.7);
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 25-30 min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 62.5-64.5%;
D. c, applying the glaze slurry obtained in the step C to the surface of the red clay ceramic body, wherein the glazing thickness is 0.6-1 mm; then heating to 1140-1180 ℃, wherein the heating speed is 5-6 ℃/min; and (4) carrying out glaze firing for 60-80 min, then cooling to 370 ℃, preserving heat for 2h, and cooling to room temperature to obtain the transmutation glaze laterite ceramic product.
Compared with the prior art, the invention has the following advantages and beneficial effects:
according to the invention, the transmutation glaze is prepared by selecting raw materials, reasonably proportioning and selecting raw materials such as albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide, high-boron frit and the like in proper proportion, so that the prepared transmutation glaze laterite ceramic product has the advantages of low water absorption rate, good liquid water barrier property and low moisture absorption tendency; the glossiness is high, and the wear resistance of the glaze surface is good; the glaze surface is flat and smooth, the glossiness is good, and the appearance is beautiful;
in addition, the transmutation glaze disclosed by the invention has better comprehensive performance than that of a common transmutation glaze laterite ceramic product.
The preparation method has simple process and simple and convenient operation.
Detailed Description
In order that those skilled in the art will better understand the technical solutions of the present invention, the following description of the preferred embodiments of the present invention is provided in connection with specific examples, which should not be construed as limiting the present patent.
The test methods or test methods described in the following examples are conventional methods unless otherwise specified; the reagents and materials, unless otherwise indicated, are conventionally obtained commercially or prepared by conventional methods.
The blank body can be prepared according to the conventional method in the field, the manufacturing method is not described again, and the shape of the blank body can be any shape; after shaping and air drying, the glaze slurry can be used for glazing by adopting the glaze slurry, and then the next procedure is carried out.
Example 1:
the transmutation glaze comprises the following raw materials in parts by weight:
18-23 parts of albite,
6-8 parts of potassium feldspar,
28-35 parts of quartz,
10-13 parts of red clay,
3-5 parts of calcined kaolin,
7 to 9.5 parts of copper silicide,
3 to 4.5 parts of zirconium diboride,
2.6 to 3.2 parts of niobium carbide,
2-2.5 parts of silicon carbide,
5-7 parts of manganese dioxide,
12-16 parts of zinc oxide,
3-4.5 parts of titanium oxide.
In the embodiment, the transmutation glaze preferably, but not limited to, comprises the following raw materials in parts by weight:
20.5 parts of albite,
7 parts of potassium feldspar,
31.5 parts of quartz,
11.5 parts of red clay,
4 parts of calcined kaolin,
8.3 parts of copper silicide,
3.7 parts of zirconium diboride,
2.9 parts of niobium carbide,
2.25 parts of silicon carbide,
6 parts of manganese dioxide,
14 parts of zinc oxide,
3.8 parts of titanium oxide.
In the present embodiment, the red clay is preferably, but not limited to, calcined red clay, and the particle size is preferably, but not limited to, 3000-4000 mesh.
In the present embodiment, the kaolin is preferably, but not limited to, calcined kaolin, and the particle size is preferably, but not limited to, 4000 to 5000 mesh.
In the present embodiment, the zinc oxide is preferably, but not limited to, nano zinc oxide.
In the present embodiment, the titanium oxide is preferably, but not limited to, nano titanium oxide.
In this embodiment, the transmutation glaze preferably, but not limited to, further comprises the following raw materials in parts by weight: 4-6 parts of high-boron frit.
In this embodiment, the boron content of the high-boron frit is preferably, but not limited to, 10 to 13%, and the lead content is preferably, but not limited to, less than 0.01%.
Meanwhile, the invention also provides a transmutation glaze laterite ceramic product, which comprises a laterite ceramic body and a glaze layer covering the surface of the laterite ceramic body, wherein the glaze layer is the transmutation glaze.
Meanwhile, the invention also provides a preparation method of the transmutation glaze laterite ceramic product, which comprises the following steps:
A. weighing the following raw materials in parts by weight: albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide and high boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling the mixture for 40-60 min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2.3: (0.65-0.7);
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 25-30 min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 62.5-64.5%;
D. c, applying the glaze slurry obtained in the step C to the surface of the red clay ceramic body, wherein the glazing thickness is 0.6-1 mm; then heating to 1140-1180 ℃, wherein the heating speed is 5-6 ℃/min; and (4) carrying out glaze firing for 60-80 min, then cooling to 370 ℃, preserving heat for 2h, and cooling to room temperature to obtain the transmutation glaze laterite ceramic product.
Example 2:
the transmutation glaze comprises the following raw materials in parts by weight:
18 parts of albite,
6 parts of potassium feldspar,
28 parts of quartz,
10 portions of red clay,
3 parts of calcined kaolin,
7 parts of copper silicide,
3 parts of zirconium diboride,
2.6 parts of niobium carbide,
2 portions of silicon carbide,
5 parts of manganese dioxide,
12 portions of zinc oxide,
3 parts of titanium oxide.
In this embodiment, the red clay is calcined red clay with a particle size of 3000 mesh.
In this example, the kaolin was calcined kaolin having a particle size of 4000 mesh.
In this embodiment, the zinc oxide is nano zinc oxide.
In this embodiment, the titanium oxide is nano titanium oxide.
In this embodiment, the transmutation glaze further comprises the following raw materials in parts by weight: 4 parts of high-boron frit.
In this embodiment, the boron content of the high-boron frit is 10% and the lead content is less than 0.01%.
In this embodiment, the transmutation glaze laterite ceramic product comprises a laterite ceramic body and a glaze layer covering the surface of the laterite ceramic body, wherein the glaze layer is the transmutation glaze.
In this embodiment, the method for preparing a transmutation glazed red clay ceramic product comprises the following steps:
A. weighing the following raw materials in parts by weight: albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide and high boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 40min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2.3: 0.65;
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 25-30 min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 62.5%;
D. c, applying the glaze slurry obtained in the step C to the surface of the red clay ceramic body, wherein the glazing thickness is 1 mm; then heating to 1140 ℃ at the heating speed of 5 ℃/min; and (4) carrying out glaze firing for 80min, then cooling to 370 ℃, preserving heat for 2h, and cooling to room temperature to obtain the transmutation glaze laterite ceramic product.
Example 3:
the transmutation glaze comprises the following raw materials in parts by weight:
23 parts of albite,
8 parts of potassium feldspar,
35 parts of quartz,
13 portions of red clay,
5 parts of calcined kaolin,
9.5 parts of copper silicide,
4.5 parts of zirconium diboride,
3.2 parts of niobium carbide,
2.5 parts of silicon carbide,
7 parts of manganese dioxide,
16 portions of zinc oxide,
4.5 parts of titanium oxide.
In this embodiment, the red clay is calcined red clay with a particle size of 4000 meshes.
In this example, the kaolin was calcined kaolin having a particle size of 5000 mesh.
In this embodiment, the zinc oxide is nano zinc oxide.
In this embodiment, the titanium oxide is nano titanium oxide.
In this embodiment, the transmutation glaze further comprises the following raw materials in parts by weight: 6 parts of high-boron frit.
In this embodiment, the boron content of the high-boron frit is 13% and the lead content is less than 0.01%.
In this embodiment, the transmutation glaze laterite ceramic product comprises a laterite ceramic body and a glaze layer covering the surface of the laterite ceramic body, wherein the glaze layer is the transmutation glaze.
In this embodiment, the method for preparing a transmutation glazed red clay ceramic product comprises the following steps:
A. weighing the following raw materials in parts by weight: albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide and high boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 60min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2.3: 0.7;
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 30min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 64.5%;
D. c, applying the glaze slurry obtained in the step C to the surface of the red clay ceramic body, wherein the glazing thickness is 0.6 mm; then heating to 1180 ℃ at the heating speed of 6 ℃/min; and (4) carrying out glaze firing for 60min, then cooling to 370 ℃, preserving heat for 2h, and cooling to room temperature to obtain the transmutation glaze laterite ceramic product.
Example 4:
the transmutation glaze comprises the following raw materials in parts by weight:
20.5 parts of albite,
7 parts of potassium feldspar,
31.5 parts of quartz,
11.5 parts of red clay,
4 parts of calcined kaolin,
8.3 parts of copper silicide,
3.7 parts of zirconium diboride,
2.9 parts of niobium carbide,
2.25 parts of silicon carbide,
6 parts of manganese dioxide,
14 parts of zinc oxide,
3.8 parts of titanium oxide.
In this embodiment, the red clay is calcined red clay with a particle size of 3500 meshes.
In this example, the kaolin was calcined kaolin having a particle size of 4500 mesh.
In this embodiment, the zinc oxide is nano zinc oxide.
In this embodiment, the titanium oxide is nano titanium oxide.
In this embodiment, the transmutation glaze further comprises the following raw materials in parts by weight: 5 parts of high-boron frit.
In this example, the boron content of the high-boron frit was 11.5% and the lead content was less than 0.01%.
In this embodiment, the transmutation glaze laterite ceramic product comprises a laterite ceramic body and a glaze layer covering the surface of the laterite ceramic body, wherein the glaze layer is the transmutation glaze.
In this embodiment, the method for preparing a transmutation glazed red clay ceramic product comprises the following steps:
A. weighing the following raw materials in parts by weight: albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide and high boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 50min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2.3: 0.68;
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 28min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 63.5%;
D. c, applying the glaze slurry obtained in the step C to the surface of the red clay ceramic body, wherein the glazing thickness is 0.8 mm; then heating to 1160 ℃, wherein the heating speed is 5.5 ℃/min; and (4) carrying out glaze firing for 70min, then cooling to 370 ℃, preserving heat for 2h, and cooling to room temperature to obtain the transmutation glaze laterite ceramic product.
Comparative example 1:
the difference from example 4 is that there is no red clay, and the other is the same as example 4.
Comparative example 2:
the difference from example 4 is that copper silicide is not present, and the other is the same as example 4.
Comparative example 3:
the difference from example 4 is that there is no zirconium diboride, otherwise the same as example 4.
Comparative example 4:
the difference from example 4 is that no niobium carbide is present, and the other is the same as example 4.
Comparative example 5:
the difference from example 4 is that silicon carbide is not contained, and the other is the same as example 4.
The following tests were performed on the transmutation glazes red clay ceramic products obtained in examples 2 to 4 of the present invention and the transmutation glazes red clay ceramic products obtained in the comparative example, and the test results are shown in table 1.
In the table, the water absorption is measured after "the kiln-transmutation glazes red clay ceramic product" is placed in water and soaked for 24 hours, and the water absorption is (mass after soaking-mass before soaking)/mass before soaking.
The test results of the appearance are the identification results consistent with 5 experts in the field of ceramic products.
TABLE 1
As can be seen from the above table, the transmutation glaze disclosed by the invention is prepared by selecting raw materials, reasonably proportioning and selecting raw materials such as albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide, high-boron frit and the like in proper proportion, so that the prepared transmutation glaze laterite ceramic product is small in water absorption rate, good in liquid water barrier property and not easy to absorb moisture; the glossiness is high, and the wear resistance of the glaze surface is good; the glaze surface is flat and smooth, the glossiness is good, and the appearance is beautiful;
in addition, the transmutation glaze disclosed by the invention has better comprehensive performance than that of a common transmutation glaze laterite ceramic product.
The above is only a preferred embodiment of the present invention, and it should be noted that the above preferred embodiment should not be considered as limiting the present invention, and the protection scope of the present invention should be subject to the scope defined by the claims. It will be apparent to those skilled in the art that various modifications and adaptations can be made without departing from the spirit and scope of the invention, and these modifications and adaptations should be considered within the scope of the invention.
Claims (10)
1. The transmutation glaze is characterized by comprising the following raw materials in parts by weight:
18-23 parts of albite,
6-8 parts of potassium feldspar,
28-35 parts of quartz,
10-13 parts of red clay,
3-5 parts of calcined kaolin,
7 to 9.5 parts of copper silicide,
3 to 4.5 parts of zirconium diboride,
2.6 to 3.2 parts of niobium carbide,
2-2.5 parts of silicon carbide,
5-7 parts of manganese dioxide,
12-16 parts of zinc oxide,
3-4.5 parts of titanium oxide.
2. The transmutation glaze according to claim 1, wherein the transmutation glaze comprises the following raw materials in parts by weight:
20.5 parts of albite,
7 parts of potassium feldspar,
31.5 parts of quartz,
11.5 parts of red clay,
4 parts of calcined kaolin,
8.3 parts of copper silicide,
3.7 parts of zirconium diboride,
2.9 parts of niobium carbide,
2.25 parts of silicon carbide,
6 parts of manganese dioxide,
14 parts of zinc oxide,
3.8 parts of titanium oxide.
3. The transmutation glaze according to claim 1, wherein the red clay is calcined red clay with a particle size of 3000-4000 meshes.
4. The transmutation glaze according to claim 1, wherein the kaolin is calcined kaolin and has a particle size of 4000-5000 meshes.
5. The transmutation glaze according to claim 1, wherein the zinc oxide is nano zinc oxide.
6. The transmutation glaze according to claim 1, wherein the titanium oxide is nano titanium oxide.
7. The transmutation glaze according to claim 1, further comprising the following raw materials in parts by weight: 4-6 parts of high-boron frit.
8. The transmutation glaze according to claim 1, wherein the high-boron frit has a boron content of 10-13% and a lead content of less than 0.01%.
9. A transmutation glazed red clay ceramic product, which is characterized by comprising a red clay ceramic body and a glazed layer covering the surface of the red clay ceramic body, wherein the glazed layer is the transmutation glaze according to any one of claims 7 to 8.
10. A method of making a transmutated glazed red earth ceramic article according to claim 9, comprising the steps of:
A. weighing the following raw materials in parts by weight: albite, potash feldspar, quartz, red clay, calcined kaolin, copper silicide, zirconium diboride, niobium carbide, silicon carbide, manganese dioxide, zinc oxide, titanium oxide and high boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling the mixture for 40-60 min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2.3: (0.65-0.7);
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 25-30 min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 62.5-64.5%;
D. c, applying the glaze slurry obtained in the step C to the surface of the red clay ceramic body, wherein the glazing thickness is 0.6-1 mm; then heating to 1140-1180 ℃, wherein the heating speed is 5-6 ℃/min; and (4) carrying out glaze firing for 60-80 min, then cooling to 370 ℃, preserving heat for 2h, and cooling to room temperature to obtain the transmutation glaze laterite ceramic product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111411405.0A CN113979637A (en) | 2021-11-25 | 2021-11-25 | Transmutation glaze, transmutation glaze laterite ceramic product and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202111411405.0A CN113979637A (en) | 2021-11-25 | 2021-11-25 | Transmutation glaze, transmutation glaze laterite ceramic product and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN113979637A true CN113979637A (en) | 2022-01-28 |
Family
ID=79731780
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202111411405.0A Pending CN113979637A (en) | 2021-11-25 | 2021-11-25 | Transmutation glaze, transmutation glaze laterite ceramic product and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113979637A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116606121A (en) * | 2023-05-08 | 2023-08-18 | 山东崯基新材料科技发展有限公司 | Porcelain material prepared from inferior gangue and preparation method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6379751A (en) * | 1986-09-20 | 1988-04-09 | 株式会社イナックス | Spray-form burn glazed body and manufacture |
| CN102718471A (en) * | 2012-05-31 | 2012-10-10 | 福建省德化县锦福陶瓷有限公司 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
| CN105924231A (en) * | 2016-05-03 | 2016-09-07 | 武汉工程大学 | Wear-resistant electric porcelain glaze and preparation method thereof |
| CN107216038A (en) * | 2016-03-21 | 2017-09-29 | 郑成全 | A kind of furnace transmutation glaze and be soaked with the glaze ceramic body method for cooking and application |
| CN109179999A (en) * | 2018-11-20 | 2019-01-11 | 禹州市锦丰源瓷业有限公司 | A kind of magnesium-based blue mat glaze |
| CN112125521A (en) * | 2020-09-24 | 2020-12-25 | 德化县嘉祥陶瓷有限公司 | Clay glaze and preparation method of domestic ceramic with same |
-
2021
- 2021-11-25 CN CN202111411405.0A patent/CN113979637A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6379751A (en) * | 1986-09-20 | 1988-04-09 | 株式会社イナックス | Spray-form burn glazed body and manufacture |
| CN102718471A (en) * | 2012-05-31 | 2012-10-10 | 福建省德化县锦福陶瓷有限公司 | Green body of red soil ceramic and formula of transmutation glaze of red soil ceramic |
| CN107216038A (en) * | 2016-03-21 | 2017-09-29 | 郑成全 | A kind of furnace transmutation glaze and be soaked with the glaze ceramic body method for cooking and application |
| CN105924231A (en) * | 2016-05-03 | 2016-09-07 | 武汉工程大学 | Wear-resistant electric porcelain glaze and preparation method thereof |
| CN109179999A (en) * | 2018-11-20 | 2019-01-11 | 禹州市锦丰源瓷业有限公司 | A kind of magnesium-based blue mat glaze |
| CN112125521A (en) * | 2020-09-24 | 2020-12-25 | 德化县嘉祥陶瓷有限公司 | Clay glaze and preparation method of domestic ceramic with same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116606121A (en) * | 2023-05-08 | 2023-08-18 | 山东崯基新材料科技发展有限公司 | Porcelain material prepared from inferior gangue and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110407469B (en) | Low-temperature transparent glaze, ceramic product with glaze and preparation method | |
| CN108358602B (en) | Shadow celadon ceramic product and manufacturing process thereof | |
| CN112079570B (en) | Blue composite transmutation glaze material and method for preparing transmutation glaze ceramic by adopting same | |
| CN105731799A (en) | Copper red reduction transmutation glaze, copper red reduction transmutation glaze ceramic product and preparation method thereof | |
| CN112125521B (en) | Clay glaze and preparation method of domestic ceramic with same | |
| CN109095775A (en) | A kind of clear frit and preparation method thereof suitable for high-strength ceramic whiteware | |
| CN110451804A (en) | Blue Sub-shine glaze, blue Sub-shine glaze ceramic and preparation method thereof | |
| CN110818264A (en) | High-temperature all-ceramic crack glaze and preparation method thereof | |
| CN113979637A (en) | Transmutation glaze, transmutation glaze laterite ceramic product and preparation method thereof | |
| CN108530022A (en) | Available white jade ceramic whiteware of open fire and preparation method thereof | |
| CN105601110A (en) | Black silver drop reduced transmutation glaze, black silver drop reduced transmutation glaze ceramic product prepared using same and preparation method | |
| CN106316127B (en) | Medium-temperature golden plum crystal glaze and preparation method thereof | |
| CN112408791B (en) | Firing method for high-temperature firing of bone china for daily use | |
| CN110482863B (en) | White opaque glaze, white opaque glaze ceramic product and preparation method thereof | |
| CN109179999A (en) | A kind of magnesium-based blue mat glaze | |
| CN113233765A (en) | Satin matte blue glaze, ceramic product prepared from same and preparation method | |
| CN112679091A (en) | Formula and method of vanadium yellow matte decorative glaze for ceramic wine bottles | |
| CN110342823B (en) | Fertilizer Bai Youtao porcelain and preparation method thereof | |
| CN110423005A (en) | A kind of wear-resisting big white glaze and ceramic and preparation method with the glaze | |
| CN109942273A (en) | Shi porcelain and preparation method thereof | |
| CN103030366A (en) | Red porcelain and method for producing same | |
| CN107352803B (en) | Ceramic glaze, preparation method and application method thereof | |
| CN111620564B (en) | Luminous glaze with humidity adjusting function | |
| CN112552019A (en) | Formula of slip glaze for high-temperature firing of bone domestic porcelain | |
| CN114573232A (en) | Tile-splitting glaze for ceramic tiles and method for preparing ceramic tiles |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20220128 |