CN110482863B - White opaque glaze, white opaque glaze ceramic product and preparation method thereof - Google Patents
White opaque glaze, white opaque glaze ceramic product and preparation method thereof Download PDFInfo
- Publication number
- CN110482863B CN110482863B CN201910864949.9A CN201910864949A CN110482863B CN 110482863 B CN110482863 B CN 110482863B CN 201910864949 A CN201910864949 A CN 201910864949A CN 110482863 B CN110482863 B CN 110482863B
- Authority
- CN
- China
- Prior art keywords
- parts
- glaze
- oxide
- white opaque
- opaque glaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/04—Opaque glass, glaze or enamel
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2205/00—Compositions applicable for the manufacture of vitreous enamels or glazes
- C03C2205/02—Compositions applicable for the manufacture of vitreous enamels or glazes for opaque enamels or glazes
Abstract
The invention discloses a white opaque glaze, a white opaque glaze ceramic product and a preparation method thereof, wherein the white opaque glaze comprises the following raw materials in parts by weight: 20-25 parts of potash feldspar, 22-27 parts of albite, 8-12 parts of calcite, 16-20 parts of quartz, 10-14 parts of talcum powder, 4.5-5.5 parts of bentonite, 6-8 parts of strontium oxide, 5-7 parts of barium oxide, 6-9 parts of magnesium oxide, 5-6 parts of titanium oxide, 2.5-3.5 parts of barium zirconate titanate, 15-20 parts of zirconium silicate and 4-6 parts of yttrium oxide. The white opaque glaze ceramic product prepared by the invention has the advantages of good opacifying effect, smooth and flat glaze surface, good glossiness, delicacy, beauty and the like, and is high in whiteness, good in wear resistance and high in hardness.
Description
Technical Field
The invention relates to the field of ceramic products, in particular to white opaque glaze, a white opaque glaze ceramic product and a preparation method thereof.
Background
The opaque glaze is a common method for decorating ceramics and is widely applied. The opaque glaze is white opaque glaze with luster. The glaze glass has phase 2 or phase 3 matter with refractive index different from that of the matrix glass phase and small volume, and when light passes through the glaze layer, the opaque glaze layer is made to scatter light owing to the opaque particles.
Depending on the aggregation state of the opacifying particles, opacifying glazes can be classified into 3 categories: firstly, a certain amount of tiny crystals exist in the matrix glass, which is called as crystalline phase opaque glaze; secondly, the glaze melt generates liquid-liquid phase separation in the cooling process, and phase 2 glass with small volume and high dispersity is separated from the matrix glass and is called phase-separated emulsion glaze; thirdly, a large amount of micro bubbles exist below the surface layer of the glaze glass, and the glaze is called gas phase opaque glaze. Wherein the crystal phase opacified glaze is divided into 2 types of primary crystal grain opacified glaze and precipitated crystal grain opacified glaze. The former is to emulsify the glaze by adding refractory substances, and the most common glaze is zirconium turbid glaze; the latter is the opacification caused by the spontaneous precipitation of opacified particles from the glazed glass during firing.
The ceramic product is one of the most common appliances in daily life of people, the development history of the ceramic is an important component of the Chinese civilization history, wherein the invention and the development of the ceramic have unique significance, along with the development of modern science and technology, a plurality of new ceramic varieties appear in recent centuries, the ceramic varieties do not use or rarely use traditional ceramic raw materials such as clay, feldspar, quartz and the like, but use other special raw materials, even expand the range of non-silicate and non-oxide, and a plurality of new processes appear, so that the ceramic has various special functions.
Coloring and glazing on the surface of the ceramic product is an effective means for increasing the texture and aesthetic feeling of the ceramic product, and the artistic effect of each glaze color or design color is different, so that various glaze colors, design colors or the combination thereof are on the market at present. There are many types of glazes on the market, such as opaque glazes, but there are some problems: the opacifying effect of the glaze is not good enough, the whiteness is not high enough, and the appearance is not exquisite enough; the glaze has poor wear resistance and low hardness.
Disclosure of Invention
Based on the above situation, the present invention aims to provide a white opaque glaze, a white opaque glaze ceramic product and a preparation method thereof, which can effectively solve the above problems.
In order to solve the technical problems, the technical scheme provided by the invention is as follows:
the white opaque glaze comprises the following raw materials in parts by weight: 20-25 parts of potash feldspar, 22-27 parts of albite, 8-12 parts of calcite, 16-20 parts of quartz, 10-14 parts of talcum powder, 4.5-5.5 parts of bentonite, 6-8 parts of strontium oxide, 5-7 parts of barium oxide, 6-9 parts of magnesium oxide, 5-6 parts of titanium oxide, 2.5-3.5 parts of barium zirconate titanate, 15-20 parts of zirconium silicate and 4-6 parts of yttrium oxide.
Preferably, the white opaque glaze comprises the following raw materials in parts by weight: 22 parts of potassium feldspar, 24.5 parts of albite, 10.5 parts of calcite, 18.4 parts of quartz, 12 parts of talcum powder, 5 parts of bentonite, 7.5 parts of strontium oxide, 6.2 parts of barium oxide, 7.7 parts of magnesium oxide, 5.5 parts of titanium oxide, 3.1 parts of barium zirconate titanate, 18 parts of zirconium silicate and 5 parts of yttrium oxide.
Preferably, the white opaque glaze also comprises the following raw materials in parts by weight: 4-7 parts of high-boron frit.
Preferably, the white opaque glaze also comprises the following raw materials in parts by weight: 5.8 parts of high-boron frit.
Preferably, the titanium oxide is nano titanium dioxide.
Preferably, the boron content of the high-boron frit is 10-15%, and the lead content is less than 0.01%.
The invention also provides a white opaque glaze ceramic product, which comprises a blank body and a glaze layer covering the surface of the blank body, wherein the glaze layer is the white opaque glaze.
The invention also provides a preparation method of the white opaque glaze ceramic product, which comprises the following steps:
A. weighing the following raw materials in parts by weight: potash feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 20-30 min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2: (0.6-0.7);
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 20-25 min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 60-65%;
D. c, applying the glaze slurry obtained in the step C on the surface of the blank body, wherein the glazing thickness is 0.7-0.8 mm; then heating to 1190-1250 ℃, wherein the heating speed is 3 ℃/min; and (3) carrying out glaze firing for 70-90 min, then cooling to 250 ℃, preserving heat for 2h, and cooling to room temperature to obtain the white opaque glaze ceramic product.
Compared with the prior art, the invention has the following advantages and beneficial effects:
the white opaque glaze disclosed by the invention is prepared by selecting raw materials carefully and reasonably proportioning, and selecting potassium feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit in proper proportion, so that the respective advantages are fully exerted, mutually supplemented and mutually promoted, and the quality stability of a product is improved.
The invention selects titanium oxide, barium zirconate titanate and zirconium silicate as a composite opacifier, potassium feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, yttrium oxide and high-boron frit in proper proportion, prepares the opacified glaze with a composite crystalline phase of titanium oxide and zirconium silicate according to the basic principle of glass chemistry, and finally prepares the white opacified glaze ceramic product.
The preparation method has simple process and simple and convenient operation.
Detailed Description
In order that those skilled in the art will better understand the technical solutions of the present invention, the following description of the preferred embodiments of the present invention is provided in connection with specific examples, which should not be construed as limiting the present patent.
The test methods or test methods described in the following examples are conventional methods unless otherwise specified; the reagents and materials, unless otherwise indicated, are conventionally obtained commercially or prepared by conventional methods.
The blank body can be prepared according to the conventional method in the field, the manufacturing method is not described again, and the shape of the blank body can be any shape; after shaping and air drying, the glaze slurry can be used for glazing by adopting the glaze slurry, and then the next procedure is carried out.
Example 1:
the white opaque glaze comprises the following raw materials in parts by weight: 20-25 parts of potash feldspar, 22-27 parts of albite, 8-12 parts of calcite, 16-20 parts of quartz, 10-14 parts of talcum powder, 4.5-5.5 parts of bentonite, 6-8 parts of strontium oxide, 5-7 parts of barium oxide, 6-9 parts of magnesium oxide, 5-6 parts of titanium oxide, 2.5-3.5 parts of barium zirconate titanate, 15-20 parts of zirconium silicate and 4-6 parts of yttrium oxide.
Preferably, the white opaque glaze comprises the following raw materials in parts by weight: 22 parts of potassium feldspar, 24.5 parts of albite, 10.5 parts of calcite, 18.4 parts of quartz, 12 parts of talcum powder, 5 parts of bentonite, 7.5 parts of strontium oxide, 6.2 parts of barium oxide, 7.7 parts of magnesium oxide, 5.5 parts of titanium oxide, 3.1 parts of barium zirconate titanate, 18 parts of zirconium silicate and 5 parts of yttrium oxide.
Preferably, the white opaque glaze also comprises the following raw materials in parts by weight: 4-7 parts of high-boron frit.
Preferably, the white opaque glaze also comprises the following raw materials in parts by weight: 5.8 parts of high-boron frit.
Preferably, the titanium oxide is nano titanium dioxide.
Preferably, the boron content of the high-boron frit is 10-15%, and the lead content is less than 0.01%.
The embodiment also provides a white opaque glaze ceramic product, which comprises a blank body and a glaze layer covering the surface of the blank body, wherein the glaze layer is the white opaque glaze.
The embodiment also provides a preparation method of the white opaque glaze ceramic product, which comprises the following steps:
A. weighing the following raw materials in parts by weight: potash feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 20-30 min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2: (0.6-0.7);
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 20-25 min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 60-65%;
D. c, applying the glaze slurry obtained in the step C on the surface of the blank body, wherein the glazing thickness is 0.7-0.8 mm; then heating to 1190-1250 ℃, wherein the heating speed is 3 ℃/min; and (3) carrying out glaze firing for 70-90 min, then cooling to 250 ℃, preserving heat for 2h, and cooling to room temperature to obtain the white opaque glaze ceramic product.
Example 2:
the white opaque glaze comprises the following raw materials in parts by weight: 20 parts of potassium feldspar, 22 parts of albite, 8 parts of calcite, 16 parts of quartz, 10 parts of talcum powder, 4.5 parts of bentonite, 6 parts of strontium oxide, 5 parts of barium oxide, 6 parts of magnesium oxide, 5 parts of titanium oxide, 2.5 parts of barium zirconate titanate, 15 parts of zirconium silicate and 4 parts of yttrium oxide.
In this embodiment, the white opaque glaze further includes the following raw materials in parts by weight: 4 parts of high-boron frit.
In this embodiment, the titanium oxide is nano titanium dioxide.
In this embodiment, the boron content of the high-boron frit is 10% and the lead content is less than 0.01%.
The invention also provides a white opaque glaze ceramic product, which comprises a blank body and a glaze layer covering the surface of the blank body, wherein the glaze layer is the white opaque glaze.
In this embodiment, the method for preparing a white opaque glazed ceramic product includes the following steps:
A. weighing the following raw materials in parts by weight: potash feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 20min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2: 0.6;
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 20min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 60%;
D. c, applying the glaze slurry obtained in the step C to the surface of the blank body, wherein the glazing thickness is 0.8 mm; then heating to 1190 ℃, wherein the heating speed is 3 ℃/min; glaze firing is carried out for 70min, then the temperature is reduced to 250 ℃, the temperature is kept for 2h, and the white opaque glaze ceramic product is obtained after cooling to the room temperature.
Example 3:
the white opaque glaze comprises the following raw materials in parts by weight: 25 parts of potassium feldspar, 27 parts of albite, 12 parts of calcite, 20 parts of quartz, 14 parts of talcum powder, 5.5 parts of bentonite, 8 parts of strontium oxide, 7 parts of barium oxide, 9 parts of magnesium oxide, 6 parts of titanium oxide, 3.5 parts of barium zirconate titanate, 20 parts of zirconium silicate and 6 parts of yttrium oxide.
In this embodiment, the white opaque glaze further includes the following raw materials in parts by weight: 7 parts of high-boron frit.
In this embodiment, the titanium oxide is nano titanium dioxide.
In this embodiment, the boron content of the high-boron frit is 15% and the lead content is less than 0.01%.
The invention also provides a white opaque glaze ceramic product, which comprises a blank body and a glaze layer covering the surface of the blank body, wherein the glaze layer is the white opaque glaze.
In this embodiment, the method for preparing a white opaque glazed ceramic product includes the following steps:
A. weighing the following raw materials in parts by weight: potash feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 30min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2: 0.7;
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 25min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 65%;
D. c, applying the glaze slurry obtained in the step C to the surface of the blank body, wherein the glazing thickness is 0.7 mm; then heating to 1250 ℃, wherein the heating speed is 3 ℃/min; glaze firing is carried out for 90min, then the temperature is reduced to 250 ℃, the temperature is kept for 2h, and the white opaque glaze ceramic product is obtained after cooling to the room temperature.
Example 4:
the white opaque glaze comprises the following raw materials in parts by weight: 22 parts of potassium feldspar, 24.5 parts of albite, 10.5 parts of calcite, 18.4 parts of quartz, 12 parts of talcum powder, 5 parts of bentonite, 7.5 parts of strontium oxide, 6.2 parts of barium oxide, 7.7 parts of magnesium oxide, 5.5 parts of titanium oxide, 3.1 parts of barium zirconate titanate, 18 parts of zirconium silicate and 5 parts of yttrium oxide.
In this embodiment, the white opaque glaze further includes the following raw materials in parts by weight: 5.8 parts of high-boron frit.
In this embodiment, the titanium oxide is nano titanium dioxide.
In this embodiment, the boron content of the high-boron frit is 13% and the lead content is less than 0.01%.
The invention also provides a white opaque glaze ceramic product, which comprises a blank body and a glaze layer covering the surface of the blank body, wherein the glaze layer is the white opaque glaze.
In this embodiment, the method for preparing a white opaque glazed ceramic product includes the following steps:
A. weighing the following raw materials in parts by weight: potash feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling the mixture for 25min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2: 0.67;
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 22min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 63%;
D. c, applying the glaze slurry obtained in the step C to the surface of the blank body, wherein the glazing thickness is 0.75 mm; then the temperature is increased to 1230 ℃, and the temperature increasing speed is 3 ℃/min; glaze firing is carried out for 80min, then the temperature is reduced to 250 ℃, the temperature is kept for 2h, and the white opaque glaze ceramic product is obtained after cooling to the room temperature.
The white opaque glaze ceramic products obtained in examples 2 to 4 of the present invention and the common opaque glaze ceramic products were subjected to the following performance tests, and the test results are shown in table 1:
in the table, the test results of fluidity, crystallization property and appearance are all the identification results consistent with 5 experts in the field of ceramic products.
TABLE 1
As can be seen from the above table, the white opaque glaze of the invention is prepared by selecting the raw materials carefully and reasonably proportioning potassium feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit in proper proportion, and the prepared white opaque glaze ceramic product has the advantages of good opacifying effect, flat and smooth glaze surface, good glossiness, delicate and attractive appearance and the like, and has high whiteness, good wear resistance and high hardness; the comprehensive performance of the product is superior to that of the common opaque glaze ceramic product.
The above is only a preferred embodiment of the present invention, and it should be noted that the above preferred embodiment should not be considered as limiting the present invention, and the protection scope of the present invention should be subject to the scope defined by the claims. It will be apparent to those skilled in the art that various modifications and adaptations can be made without departing from the spirit and scope of the invention, and these modifications and adaptations should be considered within the scope of the invention.
Claims (3)
1. The preparation method of the white opaque glaze ceramic product is characterized by comprising a blank body and a glaze layer covering the surface of the blank body, wherein the glaze layer is white opaque glaze, and the white opaque glaze comprises the following raw materials in parts by weight: 20-25 parts of potash feldspar, 22-27 parts of albite, 8-12 parts of calcite, 16-20 parts of quartz, 10-14 parts of talcum powder, 4.5-5.5 parts of bentonite, 6-8 parts of strontium oxide, 5-7 parts of barium oxide, 6-9 parts of magnesium oxide, 5-6 parts of titanium oxide, 2.5-3.5 parts of barium zirconate titanate, 15-20 parts of zirconium silicate, 4-6 parts of yttrium oxide and 4-7 parts of high-boron frit; the titanium oxide is nano titanium dioxide; the boron content of the high-boron frit is 10-15%, and the lead content is less than 0.01%; the preparation method comprises the following steps:
A. weighing the following raw materials in parts by weight: potash feldspar, albite, calcite, quartz, talcum powder, bentonite, strontium oxide, barium oxide, magnesium oxide, titanium oxide, barium zirconate titanate, zirconium silicate, yttrium oxide and high-boron frit;
B. mixing the weighed raw materials to obtain a mixture, and ball-milling for 20-30 min by using a ball mill, wherein the weight ratio of the mixture to balls to water is as follows: 1: 2: (0.6-0.7);
C. sieving with a 200-mesh sieve, removing bubbles in vacuum for 20-25 min to obtain glaze slurry, continuously stirring, and adjusting the solid content of the glaze slurry to 60-65%;
D. c, applying the glaze slurry obtained in the step C on the surface of the blank body, wherein the glazing thickness is 0.7-0.8 mm; then heating to 1190-1250 ℃, wherein the heating speed is 3 ℃/min; and (3) carrying out glaze firing for 70-90 min, then cooling to 250 ℃, preserving heat for 2h, and cooling to room temperature to obtain the white opaque glaze ceramic product.
2. The preparation method of the white opaque glaze ceramic product according to claim 1, wherein the white opaque glaze comprises the following raw materials in parts by weight: 22 parts of potassium feldspar, 24.5 parts of albite, 10.5 parts of calcite, 18.4 parts of quartz, 12 parts of talcum powder, 5 parts of bentonite, 7.5 parts of strontium oxide, 6.2 parts of barium oxide, 7.7 parts of magnesium oxide, 5.5 parts of titanium oxide, 3.1 parts of barium zirconate titanate, 18 parts of zirconium silicate, 5 parts of yttrium oxide and 5.8 parts of high-boron frit.
3. A white opaque glazed ceramic article produced by the process of claim 1 or 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910864949.9A CN110482863B (en) | 2019-09-12 | 2019-09-12 | White opaque glaze, white opaque glaze ceramic product and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910864949.9A CN110482863B (en) | 2019-09-12 | 2019-09-12 | White opaque glaze, white opaque glaze ceramic product and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110482863A CN110482863A (en) | 2019-11-22 |
| CN110482863B true CN110482863B (en) | 2022-04-05 |
Family
ID=68557802
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910864949.9A Active CN110482863B (en) | 2019-09-12 | 2019-09-12 | White opaque glaze, white opaque glaze ceramic product and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110482863B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110818260B (en) * | 2019-12-16 | 2022-05-13 | 湖南华联瓷业股份有限公司 | Grass-like wood ash glaze and preparation method thereof |
| CN116854373B (en) * | 2023-07-25 | 2024-02-23 | 景德镇乐华陶瓷洁具有限公司 | Low-zirconium ceramic sanitary ware opacifying glaze, ceramic sanitary ware and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103332966A (en) * | 2013-07-02 | 2013-10-02 | 泉州欧米克生态建材科技有限公司 | Preparation method of composite opaque glaze |
| CN106630622A (en) * | 2016-12-29 | 2017-05-10 | 成都旭光电子股份有限公司 | Opaque glaze, and preparation method and application of opaque glaze |
| CN106698949A (en) * | 2017-01-25 | 2017-05-24 | 武汉理工大学 | Opacified glaze and preparation method thereof |
| CN107601880A (en) * | 2017-11-09 | 2018-01-19 | 四川金辉卫浴洁具有限公司 | A kind of ceramic opaque glaze and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8110035B2 (en) * | 2008-05-30 | 2012-02-07 | Dentsply International Inc. | Integrated porcelain system for a dental prosthesis |
-
2019
- 2019-09-12 CN CN201910864949.9A patent/CN110482863B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103332966A (en) * | 2013-07-02 | 2013-10-02 | 泉州欧米克生态建材科技有限公司 | Preparation method of composite opaque glaze |
| CN106630622A (en) * | 2016-12-29 | 2017-05-10 | 成都旭光电子股份有限公司 | Opaque glaze, and preparation method and application of opaque glaze |
| CN106698949A (en) * | 2017-01-25 | 2017-05-24 | 武汉理工大学 | Opacified glaze and preparation method thereof |
| CN107601880A (en) * | 2017-11-09 | 2018-01-19 | 四川金辉卫浴洁具有限公司 | A kind of ceramic opaque glaze and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110482863A (en) | 2019-11-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN114671610B (en) | Low-temperature transparent glaze ceramic product and preparation method thereof | |
| CN104529553B (en) | The surface of manufacturing with ceramic refuse is as glazed tile and the preparation of broken brill sand flicker starlight | |
| CN107226691B (en) | Green fambe flowing glaze ceramic product and manufacturing process thereof | |
| CN107216127B (en) | Dehua pearl white porcelain and its preparation process | |
| CN110423006B (en) | High-performance transparent glaze, ceramic product with glaze and preparation method | |
| CN112794707B (en) | High-whiteness and high-strength light-transmitting ceramic tile and preparation method thereof | |
| CN110482863B (en) | White opaque glaze, white opaque glaze ceramic product and preparation method thereof | |
| CN110818264A (en) | High-temperature all-ceramic crack glaze and preparation method thereof | |
| CN111320458A (en) | Preparation method of tea dust glaze light porcelain | |
| CN110451804A (en) | Blue Sub-shine glaze, blue Sub-shine glaze ceramic and preparation method thereof | |
| CN112374762A (en) | Moon white glaze for jun porcelain and preparation method thereof | |
| CN107572792A (en) | A kind of pottery celeste glaze and preparation method thereof | |
| CN1071658A (en) | Self-releasing enamel low-temp ceramics | |
| CN112830816B (en) | Black-substrate silver light net grain glaze, preparation method thereof and porcelain body with black-substrate silver light net grain glaze | |
| CN107619268B (en) | Porcelain formula and production process | |
| CN106517779A (en) | Red glaze and preparation method thereof | |
| CN106007663A (en) | Unglazed high-density bright crystal ceramic and preparation method thereof | |
| CN104291799B (en) | The beautiful porcelain of magnesium and production method thereof | |
| CN109400211A (en) | A kind of celeste glaze and preparation method thereof | |
| CN112142327B (en) | Glaze composition, glaze and preparation method thereof, and ceramic tile and preparation method thereof | |
| CN114262218A (en) | High-performance ceramic rock plate and preparation method thereof | |
| CN109336397B (en) | Daily glass ceramic with smooth surface and preparation method thereof | |
| CN111410425A (en) | Medium-temperature bright red glaze and preparation method thereof | |
| CN106477888B (en) | A kind of copper oxide pink potassium feldspar glaze and preparation method thereof | |
| CN109133645A (en) | A kind of yellow glaze pottery and its preparation process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221205 Address after: 362500 Chengdong Industrial Zone, Xun Zhong town, Dehua County, Quanzhou, Fujian Patentee after: FUJIAN PROVINCE DEHUA TONGXIN CERAMIC CO.,LTD. Address before: Xun Zhong Zhen Feng Yang Cun, Dehua County, Quanzhou City, Fujian Province Patentee before: FUJIAN DEHUA HUIYUAN CERAMIC CO.,LTD. |