CN110423005A - A kind of wear-resisting big white glaze and ceramic and preparation method with the glaze - Google Patents
A kind of wear-resisting big white glaze and ceramic and preparation method with the glaze Download PDFInfo
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- CN110423005A CN110423005A CN201910802550.8A CN201910802550A CN110423005A CN 110423005 A CN110423005 A CN 110423005A CN 201910802550 A CN201910802550 A CN 201910802550A CN 110423005 A CN110423005 A CN 110423005A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention discloses a kind of wear-resisting big white glaze and ceramic and preparation method with the glaze, the wear-resisting big white glaze are made of the raw material including following parts by weight: 55~65 parts of silica flour, 13~17 parts of feldspar in powder, 7~10 parts of talcum powder, 8~14 parts of cryolite powder (main component hexafluoro sodium aluminate), 5~8 parts of spodumene powder, 3~5 parts of manganese nitrate, 3~5 parts of barium monoxide, 3~5 parts of magnesia, 4~6 parts of titanium oxide, 2~4 parts of scandium oxide, 5~8 parts of high boron frit.Matrix surface produced by the present invention is formed with wear-resisting big white glaze or the ceramic with the glaze, has the flat and smooth exquisiteness of glaze, glossiness good；It is beautiful in pure, brilliant white；And excellent wear-resisting property, it is more more wear resistant than common white glaze ceramic, it is most important that the small molecule anti-wear agent that the present invention does not add, to body nonhazardous, health is particularly suitable for the domestic ceramicses such as tableware, household appliance.
Description
Technical field
The present invention relates to ceramic fields, and in particular to a kind of wear-resisting big white glaze and ceramic and system with the glaze
Preparation Method.
Background technique
Ceramic is one of most common utensil in people's daily life, and ceramic development history is the one of Chinese civilization history
A important component part, wherein the invention and development of ceramics have more unique meaning, with the development of modern science technology,
Occur many new ceramic kinds again in the last hundred years, they do not use or be rarely employed the tradition pottery such as clay, feldspar, quartz
Porcelain raw material, but other special materials are used, or even be expanded to non-silicate, the range of non-oxidized substance, and there is many
New technique makes ceramics be provided with various specific functions.
Ceramic is fired, and there are many deficiencies for itself, and glazing can make up these deficiencies, and increase for works
Glamour.White glaze is one of porcelain tradition glaze colours, and real white glaze should be milky opaque glaze, and this glaze is just to invent in modern age
's.It is devitrification that ancient Chinese, which only has Yuan Dynasty's pivot mansion glaze, other white glazes are not the glaze of white, but will not containing metal oxide
The glaze of pigmentation element imposes on the pure white implements of tire bone, enters clear frit made of kiln high temperature is fired, glaze colours is because of white and moist porcelain body
It sets off and shows white.
But for tire bone it is not the implements of white, white glaze ceramic cannot then be obtained by applying clear frit, therefore be studied real
The nontransparent glaze of white or necessary, while to guarantee brightness, glossiness and the flatness of ceramic.Application number
It is 201610401747.7, in the patent application of entitled " a kind of high abrasion ceramics with brighten glaze slip and preparation method thereof ", In
It joined brightening agent and anti-wear agent in glaze, both increase cost, especially nearest titanium dioxide price goes up always, and makes to prepare
Process is tedious.
But big white glaze used at present and the ceramic with the glaze there is problems:
1, wear-resisting property is poor, and the small molecule anti-wear agent added is easy exudation, has certain murder by poisoning to body, unhealthy, no
Suitable for domestic ceramicses such as tableware, household appliances；
2, glossiness, whiteness are not high enough, and the integrated appearances such as brightness and flatness performance is not good enough.
Summary of the invention
Based on the above situation, the ceramic the purpose of the present invention is to provide a kind of wear-resisting big white glaze and with the glaze and
Preparation method can effectively solve problem above.
In order to solve the above technical problems, present invention provide the technical scheme that
A kind of wear-resisting big white glaze, is made of the raw material for including following parts by weight: 55~65 parts of silica flour, feldspar in powder 13~
17 parts, 7~10 parts of talcum powder, 8~14 parts of cryolite powder (main component hexafluoro sodium aluminate), 5~8 parts of spodumene powder, manganese nitrate 3
~5 parts, 3~5 parts of barium monoxide, 3~5 parts of magnesia, 4~6 parts of titanium oxide, 2~4 parts of scandium oxide, 5~8 parts of high boron frit.
Preferably, the wear-resisting big white glaze is by including that the raw material of following parts by weight is made: 60 parts of silica flour, feldspar in powder
15.2 parts, 8.5 parts of talcum powder, 11.5 parts of cryolite powder, 7.5 parts of spodumene powder, 4.2 parts of manganese nitrate, 3.3 parts of barium monoxide, oxidation
3 parts of magnesium, 5.1 parts of titanium oxide, 3 parts of scandium oxide, 6.5 parts of high boron frit.
It preferably, include alpha-quartz and β-quartz in the quartz.
Preferably, alpha-quartz and β-quartz mass ratio are 100:(6~8 in the quartz).
Preferably, the manganese nitrate is four water manganese nitrate (Mn (NO3)2·4H2O)。
Preferably, the titanium oxide is nano-titanium dioxide.
Preferably, the boron content of the high boron frit is 10~15%, and lead content is less than 0.01%.
The present invention also provides a kind of ceramics, including green body and the glaze layer for being covered in the billet surface, the glaze layer
For wear-resisting big white glaze above-mentioned.
The present invention also provides a kind of preparation methods of foregoing ceramic, including the following steps:
(1) following raw material: silica flour, feldspar in powder, talcum powder, cryolite powder, spodumene powder, nitre is weighed by weight
Sour manganese, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron frit；
(2) mixture will be obtained after weighed each raw material mixes, 30~50min of ball milling, wherein when ball milling, mixture, ball
With the weight ratio of water are as follows: 1:2.3:(0.6~0.65)；
(3) 200 meshes are crossed, 20~30min of froth in vacuum is then carried out and obtains glaze slip, continue 20~30min of stirring, and adjust
Saving glaze slip solid content is 62~65%；
(4) billet surface is imposed on using glaze slip, is being warming up to 1280~1330 DEG C, is carrying out 100~140min of glaze firing, then drop
Temperature is to 250 DEG C of 100~140min of heat preservation to get the ceramic.
Compared with prior art, the present invention have the following advantages that and the utility model has the advantages that
Wear-resisting big white glaze of the invention is made up of selected raw material, and rational proportion, selected appropriate proportion silica flour,
Feldspar in powder, talcum powder, cryolite powder, spodumene powder, manganese nitrate, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron are molten
Block, matrix surface obtained are formed with wear-resisting big white glaze or ceramic, have the flat and smooth exquisiteness of glaze, glossiness good；It is in
Pure, brilliant white is beautiful；And excellent wear-resisting property, it is more more wear resistant than common white glaze ceramic, it is most important that the present invention does not add
The small molecule anti-wear agent added, but by having selected silica flour, feldspar in powder, talcum powder, cryolite powder, the lithium brightness of appropriate proportion
Mountain flour, manganese nitrate, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron frit fire integral (glaze), also without lead cadmium etc.
Heavy metal, it is not easy to ooze out poisonous metal (ingredient), to body nonhazardous, health is particularly suitable for the days such as tableware, household appliance
With ceramics.
Preparation method simple process of the invention, it is easy to operate.
Specific embodiment
It is right combined with specific embodiments below in order to make those skilled in the art more fully understand technical solution of the present invention
The preferred embodiments of the invention are described, but should not be understood as the limitation to this patent.
Test method described in following embodiments or test method are unless otherwise specified conventional method；The reagent
And material is obtained from routine business approach, or prepare in conventional manner unless otherwise specified.
Green body of the present invention can be made according to conventional method in that art, repeat no more its production method, and shape can be with
It is arbitrary shape；It can be used to carry out glazing using glaze slip of the invention, subsequently into lower one of work after sizing, air-drying
Sequence.
Embodiment 1:
A kind of wear-resisting big white glaze, is made of the raw material for including following parts by weight: 55~65 parts of silica flour, feldspar in powder 13~
17 parts, 7~10 parts of talcum powder, 8~14 parts of cryolite powder, 5~8 parts of spodumene powder, 3~5 parts of manganese nitrate, 3~5 parts of barium monoxide,
3~5 parts of magnesia, 4~6 parts of titanium oxide, 2~4 parts of scandium oxide, 5~8 parts of high boron frit.
Preferably, the wear-resisting big white glaze is by including that the raw material of following parts by weight is made: 60 parts of silica flour, feldspar in powder
15.2 parts, 8.5 parts of talcum powder, 11.5 parts of cryolite powder, 7.5 parts of spodumene powder, 4.2 parts of manganese nitrate, 3.3 parts of barium monoxide, oxidation
3 parts of magnesium, 5.1 parts of titanium oxide, 3 parts of scandium oxide, 6.5 parts of high boron frit.
It preferably, include alpha-quartz and β-quartz in the quartz.
Preferably, alpha-quartz and β-quartz mass ratio are 100:(6~8 in the quartz).
Preferably, the manganese nitrate is four water manganese nitrate (Mn (NO3)2·4H2O)。
Preferably, the titanium oxide is nano-titanium dioxide.
Preferably, the boron content of the high boron frit is 10~15%, and lead content is less than 0.01%.
The present embodiment also provides a kind of ceramic, including green body and the glaze layer for being covered in the billet surface, the glaze
Layer is wear-resisting big white glaze above-mentioned.
The present embodiment also provides a kind of preparation method of foregoing ceramic, including the following steps:
(1) following raw material: silica flour, feldspar in powder, talcum powder, cryolite powder, spodumene powder, nitre is weighed by weight
Sour manganese, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron frit；
(2) mixture will be obtained after weighed each raw material mixes, 30~50min of ball milling, wherein when ball milling, mixture, ball
With the weight ratio of water are as follows: 1:2.3:(0.6~0.65)；
(3) 200 meshes are crossed, 20~30min of froth in vacuum is then carried out and obtains glaze slip, continue 20~30min of stirring, and adjust
Saving glaze slip solid content is 62~65%；
(4) billet surface is imposed on using glaze slip, is being warming up to 1280~1330 DEG C, is carrying out 100~140min of glaze firing, then drop
Temperature is to 250 DEG C of 100~140min of heat preservation to get the ceramic.
Embodiment 2:
A kind of wear-resisting big white glaze, is made of the raw material for including following parts by weight: 55 parts of silica flour, is slided 13 parts of feldspar in powder
7 parts of mountain flour, 8 parts of cryolite powder, 5 parts of spodumene powder, 3 parts of manganese nitrate, 3 parts of barium monoxide, 3 parts of magnesia, 4 parts of titanium oxide, oxidation
2 parts of scandium, 5 parts of high boron frit.
It in the present embodiment, include alpha-quartz and β-quartz in the quartz.
In the present embodiment, alpha-quartz and β-quartz mass ratio are 100:6 in the quartz.
In the present embodiment, the manganese nitrate is four water manganese nitrate (Mn (NO3)2·4H2O)。
In the present embodiment, the titanium oxide is nano-titanium dioxide.
In the present embodiment, the boron content of the high boron frit is 10%, and lead content is less than 0.01%.
In the present embodiment, a kind of ceramic is also provided, including green body and the glaze layer for being covered in the billet surface, institute
Stating glaze layer is wear-resisting big white glaze above-mentioned.
In the present embodiment, a kind of preparation method of foregoing ceramic is also provided, including the following steps:
(1) following raw material: silica flour, feldspar in powder, talcum powder, cryolite powder, spodumene powder, nitre is weighed by weight
Sour manganese, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron frit；
(2) mixture will be obtained after weighed each raw material mixes, ball milling 30min, wherein when ball milling, mixture, ball and water
Weight ratio are as follows: 1:2.3:0.6；
(3) 200 meshes are crossed, froth in vacuum 20min is then carried out and obtains glaze slip, continue to stir 20min, and it is solid to adjust glaze slip
Content is 62%；
(4) billet surface is imposed on using glaze slip, is being warming up to 1280 DEG C, is carrying out glaze firing 140min, then is being cooled to 250 DEG C of guarantors
Warm 100min is to get the ceramic.
Embodiment 3:
A kind of wear-resisting big white glaze, is made of the raw material for including following parts by weight: 65 parts of silica flour, is slided 17 parts of feldspar in powder
10 parts of mountain flour, 14 parts of cryolite powder, 8 parts of spodumene powder, 5 parts of manganese nitrate, 5 parts of barium monoxide, 5 parts of magnesia, 6 parts of titanium oxide, oxygen
Change 4 parts of scandium, 8 parts of high boron frit.
It in the present embodiment, include alpha-quartz and β-quartz in the quartz.
In the present embodiment, alpha-quartz and β-quartz mass ratio are 100:8 in the quartz.
In the present embodiment, the manganese nitrate is four water manganese nitrate (Mn (NO3)2·4H2O)。
In the present embodiment, the titanium oxide is nano-titanium dioxide.
In the present embodiment, the boron content of the high boron frit is 15%, and lead content is less than 0.01%.
In the present embodiment, a kind of ceramic is also provided, including green body and the glaze layer for being covered in the billet surface, institute
Stating glaze layer is wear-resisting big white glaze above-mentioned.
In the present embodiment, a kind of preparation method of foregoing ceramic is also provided, including the following steps:
(1) following raw material: silica flour, feldspar in powder, talcum powder, cryolite powder, spodumene powder, nitre is weighed by weight
Sour manganese, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron frit；
(2) mixture will be obtained after weighed each raw material mixes, ball milling 50min, wherein when ball milling, mixture, ball and water
Weight ratio are as follows: 1:2.3:0.65；
(3) 200 meshes are crossed, froth in vacuum 30min is then carried out and obtains glaze slip, continue to stir 30min, and it is solid to adjust glaze slip
Content is 65%；
(4) billet surface is imposed on using glaze slip, is being warming up to 1330 DEG C, is carrying out glaze firing 100min, then is being cooled to 250 DEG C of guarantors
Warm 100min is to get the ceramic.
Embodiment 4:
A kind of wear-resisting big white glaze, is made of the raw material for including following parts by weight: 60 parts of silica flour, 15.2 parts of feldspar in powder,
8.5 parts of talcum powder, 11.5 parts of cryolite powder, 7.5 parts of spodumene powder, 4.2 parts of manganese nitrate, 3.3 parts of barium monoxide, 3 parts of magnesia, oxygen
Change 5.1 parts of titanium, 3 parts of scandium oxide, 6.5 parts of high boron frit.
It in the present embodiment, include alpha-quartz and β-quartz in the quartz.
In the present embodiment, alpha-quartz and β-quartz mass ratio are 100:7 in the quartz.
In the present embodiment, the manganese nitrate is four water manganese nitrate (Mn (NO3)2·4H2O)。
In the present embodiment, the titanium oxide is nano-titanium dioxide.
In the present embodiment, the boron content of the high boron frit is 13%, and lead content is less than 0.01%.
In the present embodiment, a kind of ceramic is also provided, including green body and the glaze layer for being covered in the billet surface, institute
Stating glaze layer is wear-resisting big white glaze above-mentioned.
In the present embodiment, a kind of preparation method of foregoing ceramic is also provided, including the following steps:
(1) following raw material: silica flour, feldspar in powder, talcum powder, cryolite powder, spodumene powder, nitre is weighed by weight
Sour manganese, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron frit；
(2) mixture will be obtained after weighed each raw material mixes, ball milling 40min, wherein when ball milling, mixture, ball and water
Weight ratio are as follows: 1:2.3:0.62；
(3) 200 meshes are crossed, froth in vacuum 25min is then carried out and obtains glaze slip, continue to stir 25min, and it is solid to adjust glaze slip
Content is 63%；
(4) billet surface is imposed on using glaze slip, is being warming up to 1320 DEG C, is carrying out glaze firing 120min, then is being cooled to 250 DEG C of guarantors
Warm 120min is to get the ceramic.
Comparative example 1:
Difference with embodiment 4 is that, without cryolite powder, other are same as Example 4.
Comparative example 2:
Difference with embodiment 4 is that, without manganese nitrate, other are same as Example 4.
Comparative example 3:
Difference with embodiment 4 is that, without scandium oxide, other are same as Example 4.
Comparative example 4:
Difference with embodiment 4 is, is 45 parts by weight without silica flour, other are same as Example 4.
Comparative example 5:
Difference with embodiment 4 is that, without titanium oxide, other are same as Example 4.
Performance survey is carried out to the ceramic that the embodiment of the present invention 2 to embodiment 4, comparative example 1 to comparative example 5 obtain below
Examination, test result are as shown in table 1:
In table, the test result of appearance is the consistent qualification result of expert in 5 ceramic fields.
Table 1
As can be seen from the above table, wear-resisting big white glaze of the invention is made up of selected raw material, and rational proportion, has been selected suitable
When the silica flour of proportion, feldspar in powder, talcum powder, cryolite powder, spodumene powder, manganese nitrate, barium monoxide, magnesia, titanium oxide,
Scandium oxide, high boron frit, matrix surface obtained are formed with wear-resisting big white glaze or ceramic, have glaze flat and smooth thin
It is greasy, glossiness is good；It is beautiful in pure, brilliant white；And excellent wear-resisting property, it is more more wear resistant than common white glaze ceramic.
The above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred embodiment is not construed as pair
Limitation of the invention, protection scope of the present invention should be defined by the scope defined by the claims..For the art
For those of ordinary skill, without departing from the spirit and scope of the present invention, several improvements and modifications can also be made, these change
It also should be regarded as protection scope of the present invention into retouching.
Claims (9)
1. a kind of wear-resisting big white glaze, which is characterized in that be made of the raw material for including following parts by weight: 55~65 parts of silica flour, potassium
13~17 parts of feldspar powder, 7~10 parts of talcum powder, 8~14 parts of cryolite powder, 5~8 parts of spodumene powder, 3~5 parts of manganese nitrate, oxidation
3~5 parts of barium, 3~5 parts of magnesia, 4~6 parts of titanium oxide, 2~4 parts of scandium oxide, 5~8 parts of high boron frit.
2. wear-resisting big white glaze according to claim 1, which is characterized in that the wear-resisting big white glaze is by including following parts by weight
Raw material be made: 60 parts of silica flour, 15.2 parts of feldspar in powder, 8.5 parts of talcum powder, 11.5 parts of cryolite powder, spodumene powder 7.5
Part, 4.2 parts of manganese nitrate, 3.3 parts of barium monoxide, 3 parts of magnesia, 5.1 parts of titanium oxide, 3 parts of scandium oxide, 6.5 parts of high boron frit.
3. wear-resisting big white glaze according to claim 1, which is characterized in that include alpha-quartz and β-quartz in the quartz.
4. wear-resisting big white glaze according to claim 1, which is characterized in that alpha-quartz and β-quartz quality in the quartz
The ratio between be 100:(6~8).
5. wear-resisting big white glaze according to claim 1, which is characterized in that the manganese nitrate is four water manganese nitrates.
6. wear-resisting big white glaze according to claim 1, which is characterized in that the titanium oxide is nano-titanium dioxide.
7. wear-resisting big white glaze according to claim 1, which is characterized in that the boron content of the high boron frit is 10~15%,
Lead content is less than 0.01%.
8. a kind of ceramic, which is characterized in that including green body and the glaze layer for being covered in the billet surface, the glaze layer is power
Benefit requires 1 to 7 described in any item wear-resisting big white glazes.
9. a kind of preparation method of ceramic as claimed in claim 8, characterized in that it comprises the following steps:
(1) following raw material: silica flour, feldspar in powder, talcum powder, cryolite powder, spodumene powder, nitric acid is weighed by weight
Manganese, barium monoxide, magnesia, titanium oxide, scandium oxide, high boron frit；
(2) mixture will be obtained after weighed each raw material mixes, 30~50min of ball milling, wherein when ball milling, mixture, ball and
The weight ratio of water are as follows: 1:2.3:(0.6~0.65)；
(3) 200 meshes are crossed, 20~30min of froth in vacuum is then carried out and obtains glaze slip, continue 20~30min of stirring, and adjust
Glaze slip solid content is 62~65%；
Billet surface is imposed on using glaze slip, 1280~1330 DEG C is being warming up to, is carrying out 100~140min of glaze firing, then be cooled to 250
DEG C heat preservation 100~140min to get the ceramic.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN111410424A (en) * | 2020-04-25 | 2020-07-14 | 福建省德化县合和陶瓷技术开发有限公司 | Domestic ceramic product not prone to being stained and preparation method thereof |
| CN112194371A (en) * | 2020-09-16 | 2021-01-08 | 德化县吉元瓷业有限责任公司 | High-temperature-resistant ceramic glaze water and preparation method thereof |
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| CN111410424A (en) * | 2020-04-25 | 2020-07-14 | 福建省德化县合和陶瓷技术开发有限公司 | Domestic ceramic product not prone to being stained and preparation method thereof |
| CN112194371A (en) * | 2020-09-16 | 2021-01-08 | 德化县吉元瓷业有限责任公司 | High-temperature-resistant ceramic glaze water and preparation method thereof |
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