CN1093522C - Plant nutriment regulator - Google Patents

Plant nutriment regulator Download PDF

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Publication number
CN1093522C
CN1093522C CN98121840A CN98121840A CN1093522C CN 1093522 C CN1093522 C CN 1093522C CN 98121840 A CN98121840 A CN 98121840A CN 98121840 A CN98121840 A CN 98121840A CN 1093522 C CN1093522 C CN 1093522C
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solution
sulfate
plant
proportion
plant nutriment
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CN1259505A (en
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贺乙峰
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Jiangxi Lian Pu People Agricultural Development Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • C05G5/23Solutions

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Fertilizers (AREA)

Abstract

The present invention relates to a plant nutriment regulator which comprises 12 to 16% of urea, 14 to 24 % of potassium dihydrogen phosphate or potassium sulfate, 7 to 20% of orthoboric acids, 2 to 6% of ammonium molybdate tetrahydrate, 10 to 20 % of zinc sulphate, 5 to 10% of manganese sulphate, 5 to 20 % of cupric sulfate, 10 to 15% of ferrous sulfate heptahydrate, 10 to 24 % of magnesium sulfate and 8 to 16% of amino acids. The plant nutriment regulator is prepared by the following steps: A. complex reaction is carried out for the amino acids, the cupric sulfate and zinc sulphate solutions; chelation reaction is carried out for the ferrous sulfate heptahydrate and EDTA; the manganese sulphate, the orthoboric acids, the magnesium sulfate, and the potassium dihydrogen phosphate are compounded with the acetic acids; B. solutions obtained by the step A are compounded according to proportion; the urea and ammonium molybdate tetrahydrate solutions are added under the condition of stirring according to the proportion, and pH value is finally adjusted to 3.5 to 5, and finished products are obtained. The plant nutriment regulator which is a foliage fertilizer of the plant nutriment regulator has the advantages of comprehensive nutrition and stable solubility; the present invention has the main functions of preventing and treating diseases.

Description

A kind of preparation method of plant nutriment regulator
The present invention relates to a kind of foliage fertilizer, particularly a kind of plant nutriment regulator that contains abundant nutritive element.
In the process of growth of plant, Chang Yin lacks nutritive element and causes nutritional deficiency disease, influenced growth and development of plant, cause plant physiology imbalance, reduce resistibility, bring out and increased the weight of the disease that the spreading venereal diseases original causes and take place, crop can not be increased production, this situation just need be different according to plant breeding time, replenish various nutritive elements with a definite target in view, to keep balance.Replenishing of nutritive element sprays foliage fertilizer and is one of a kind of the most direct valid approach.Existing foliage fertilizer mainly is divided into three major types: the common foliage fertilizer that only contains the simple substance compound, contain the multi-element leaf fertilizer of various nutrient elements and contain organic foliage fertilizer,, above-mentioned no matter which kind of foliage fertilizer, or nutritive element is few, or effective constituent is low, or it is poorly soluble, or dissolved poor stability, such as CN1123266A disclosed " a kind of liquid plant-foliage fertilizer and preparation method thereof ", its product comprises the compounded amino acid mother liquor of 80-85% (weight), the CuSO of 3-8% (weight) 45H 2O, the ZnSO of 1-3% (weight) 47H 2O, the Na of 2-5% (weight) 2B 4O 710H 2O, the MnSO of 2-4% (weight) 45H 2O, the blade face infiltration wetting agent of the plant-growth regulator of 1-3% (weight) and 0.5-1% (weight).The principal feature for preparing the method for this foliar nutrient is to adopt hydrochloric acid hydrolysis and ammoniacal liquor neutral method to send out with the people who cleans and/or pig hair and/or waste leather and/or animal blood prepare rare compounded amino acid mother liquor, with the method that reduces pressure it is condensed into dense compounded amino acid mother liquor then.This foliage fertilizer has only solved solubility problem owing to be that each component is mixed simply, but it can not be settled out, and it can finally be given to spray to use and cause difficulty along with variation of temperature produces salting-out phenomenon; Moreover its nutritive element is not comprehensive, and such as lacking very important molybdenum, iron, magnesium elements for plant, and each element proportioning is unreasonable, has produced antagonism, can not be attracted fully by plant.
The object of the present invention is to provide a kind of comprehensive nutrition, solvability is stable, based on fertile diseases prevention, disease-resistant, the foliage fertilizer-plant nutriment regulator of curing the disease.
The foliage fertilizer of excellent property should be that each dropping liquid fertilizer all contains consistent various nutritive elements and other effective constituent, these various nutritive elements that just require foliage fertilizer are that full dissolubility and solvability are stable, simultaneously, proportion relation between each nutritive element is also very important, if collocation is unreasonable, produced antagonistic action between component, unfavorable plant absorbing does not reach the effect of science with fertilizer.So the solvability of the various nutritive elements of foliage fertilizer, dissolved stability, and the proportion relation of each nutritive element be the place of technician's the key of researching and solving.
The present invention is achieved in that a kind of preparation method of plant nutriment regulator, it contains urea 12-16%, potassium primary phosphate or vitriolate of tartar 14-24%, boric acid 7-20%, ammonium molybdate 2-6%, zinc sulfate 10-20%, manganous sulfate 5-10%, copper sulfate 5-10%, ferrous sulfate 10-15%, sal epsom 10-24%, amino acid 8-16%, adopt the following step preparation: A. is mixed in proportion amino acid solution, copper-bath, solution of zinc sulfate and carries out complex reaction; Copperas solution and EDTA solution carry out chelatropic reaction; Manganese sulfate solution, boric acid solution, Adlerika, potassium dihydrogen phosphate and acetic acid are compound; B. the three class solution that the A step is obtained are compound in proportion, add urea, ammonium molybdate solution under whipped state in proportion, and finally adjusting pH value is that 3.5-5 gets finished product; The add-on of wherein said EDTA solution adds with the 5-10% of copperas solution amount; The add-on of described acetic acid adds with the 1-2% of manganese sulfate solution, boric acid solution, Adlerika, potassium dihydrogen phosphate total amount.
In order to quicken the dissolution rate of manganous sulfate and boric acid, the available hot water that is not less than 50 ℃ dissolves.
The present invention has following characteristics:
1. the present invention is a kind of big or middle, micro-foliage fertilizer such as nitrogen, phosphorus, potassium, molybdenum, sulphur, copper, iron, zinc, boron, manganese that contains, it is considered that the peasant is passed through and executes nitrogen, phosphorus, potash fertilizer, in not noting, the trace element use, destroyed the ratio equilibrium relationship between each element, make plant produce serious nutritional deficiency disease, therefore in proportion of raw materials, have a mind to reduce the consumption of nitrogen, phosphorus, potassium, and with moderate-element, trace element makes its nutrition more comprehensive for leading and be equipped with organic matters such as amino acid and organic acid.Use this plant nutriment regulator, it can supply the required various nutritive ingredients of plant, improves the undesirable condition of hunger sign in plant as early as possible, reaches diseases prevention, the effect of curing the disease.
2. after nutritive element is determined,, can produce precipitation or generate emulsion if simply that these materials mixing are soluble in water, plant leaf surface can not be absorbed fully, so make full use of complexing agent in the present invention, sequestrant, buffer reagent, making prescription reach molten entirely after the mixing, steady quality can be along with salting-out phenomenon appear in variation of temperature, its equalization of concentration, be convenient to plant and fast, fully absorb, also be convenient to spray.The multiple amino acids of introducing in the prescription, acetic acid also play a driving role to the various nutrients of plant absorbing except that effects such as complexing, chelating, common-ion effcet, buffer reagent, sequestering agent are arranged; Amino acid complex can also kill the multiple germ of all kinds of plants, promotes growth and development of plants; Acetic acid can resist willow soil to infect disease as low-molecular-weight fatty acid.
3. well-known, if enough phenolic compounds, protein and starch thing are arranged, help strengthening the resistance against diseases of plant in the plant materials.Application of potash fertilizer can increase the phenol amount that contains in the blade, reduce the shape bacterium harm of wriggling, and the nitrogenous fertilizer of too high levels can reduce the phenol amount that contains, and it is light that the present invention just heavily keeps away, and choose reasonable nitrogenous fertilizer content is to promote the formation of phenolic compound in the plant materials; An amount of potassium element and many trace elements such as boron, zinc, copper, manganese etc. all can promote protein synthesis, reduce vivo acid content, and this is the major reason that improves crop disease-resistant; Phosphorus potash fertilizer can promote photosynthesis and starch to form, and trace elements iron, manganese, zinc, copper etc. normally also are absolutely necessary to photosynthetic, and the formation of polymeric carbohydrate also be unable to do without trace element; The present invention takes all factors into consideration above factor, and choose reasonable nutritive element and proportioning thereof finally reach and have stronger resistance against diseases.Simultaneously, it also has and strengthens the disease-resistant bacterium infection ability of host crop, can promote Mierocrystalline cellulose and xylogen to form as wherein potash fertilizer, make in the more difficult intrusive body of germ, an amount of boron, zinc can make the epidermic cell membrane stability improve, and can reduce the nutritive substance to excessiveization, thereby alleviate infection process.
4. nutritive element of the present invention is complete, with inorganic fertilizer and organic rational proportion, through spraying to all kinds of farm crop of mu up to ten thousand, proved: use the present invention and can impel the various nutrition of plant materials to keep balance, strengthen the resistance against diseases of plant, pest control reaches about all kinds of increasing crop yield 10-35%, improves the effect of crops quality.Under lift a detailed example explanation:
The inventor did field test once on August 6th, 1 at north of the city vegetables base, ancient piece of jade, round, flat and with a hole in its centre cities and towns, Bishan County one peasant household place, and experimental cultivar is a pumpkin, and administration of drugs is this plant nutriment regulator, with 100 times of liquid foliage-sprays.Before spraying, 6 nest pumpkins of this peasant household's plantation, the blossom disease viral disease all takes place in totally 11 strains, and it is withered and yellow that its symptom shows as lower blade, and it is variegated that the middle part blade presents yellowish green alternate spot, the leaf of fainting on a small quantity, the distortion deformity, the heterogeneous look of leaf color spot, stem is thin, a little less than the growing way.After August 6 sprayed, investigation on August 18: 4 strains of control group 2 nests, upper, middle and lower portion blade no change is newly extracted 4 in blade out and still is the leaf distorted shape of fainting, and blade is narrow, and the leaf look aged; 7 strains of test group 4 nests, green, yellow area minimizing that lower blade no change, middle part blade have begun to change, it is green that upper blade leaf look all changes, the leaf of fainting, and twisted state improves significantly, 7 of new leaf development sheets are all normal, the leaf look glossy dark green, and immaculate does not have the leaf deformity of fainting, growing way is vigorous, comparison is according to the climing long 17.5cm that increases, and leaf length increases 2.8cm, the wide increase of leaf 2.6cm.From last example as can be seen: 1. this plant nutriment regulator not only can be regulated plant nutrition and physiological function effectively, can also strengthen the resistance against diseases of plant; 2. the preventive and therapeutic effect that virus disease is had demonstration, to the due to illness malicious plant dwarfing that causes, leaf curling deformity and the yellow of leaf look have notable therapeutic effect.
The invention will be further described below in conjunction with drawings and Examples:
Fig. 1. process flow sheet of the present invention.
Embodiment 1: the processing step referring to Fig. 1 prepares plant nutriment regulator:
1. with in the double centner multiple amino acids addingization batch can, add 400 kg water dissolution filters, standby;
2. with 25 kilo sulfuric acid copper, in the 50 kilo sulfuric acid zinc addingization batch cans, and add the double centner water dissolution;
3. the 1st step was filtered good amino acid and put into the complexing jar, go on foot the copper sulfate that makes with the 2nd again, solution of zinc sulfate slowly adds complexing under whipped state;
4. with in the ferrous adding batch can of 50 kilo sulfuric acid, add 0.5 kilogram of EDTA, 50 kg water are carried out chelating;
5. with 25 kilo sulfuric acid manganese, 50 kilograms of boric acid add 95 kg water and carry out mixed dissolution, (for accelerating dissolving, available 50 ℃ of hot water carry out mixed dissolution);
6. with 60 kilo sulfuric acid magnesium, 70 kilograms of potassium primary phosphates add water and dissolve in changing batch can for 250 kilograms;
7. will dissolve good manganous sulfate, boric acid, sal epsom, potassium primary phosphate and put into composite tanks, adding 10 kilograms of acetic acid carries out compound;
8. with above-mentioned complexing cupric ammine, zinc, chelated iron, sulfate composite manganese etc. is put into composite tanks, adds 60 kg urea, and 10 kilograms of ammonium molybdate solutions that dissolving is good under agitation slowly add compound;
9. above-mentioned mixing solutions compound good after, put into the finished product jar, adjusting pH value with sodium hydroxide solution is 3.5-5, is made into 1000 liters of solution and gets plant nutriment regulator.
Embodiment 2: implementation step is with reference to embodiment 1, and different is proportion of raw materials (weight percent):
Urea 15%, potassium primary phosphate 15%, boric acid 10%, ammonium molybdate 2%, zinc sulfate 10%, sulphur
Acid manganese 5%, copper sulfate 5%, ferrous sulfate 10%, sal epsom 12%, amino acid/11 6%.
This foliage fertilizer is applicable to south rice, greengrocery.
Embodiment 3: implementation step is with reference to embodiment 1, and different is proportion of raw materials (weight percent):
Urea 12%, potassium primary phosphate 18%, boric acid 13%, ammonium molybdate 6%, zinc sulfate 13%,
Manganous sulfate 5%, copper sulfate 5%, ferrous sulfate 10%, sal epsom 10%, amino acid 8%.
This foliage fertilizer is applicable to northern apple, cotton class.
Embodiment 4: implementation step is with reference to embodiment 1, and different is proportion of raw materials (weight percent):
Urea 12%, potassium primary phosphate 16%, boric acid 10%, ammonium molybdate 3%, zinc sulfate 10%,
Manganous sulfate 7%, copper sulfate 7%, ferrous sulfate 12%, sal epsom 10%, amino acid/11 3%.
This foliage fertilizer has comprehensive, and is applied widely than the foliage fertilizer of embodiment 2,3.
Embodiment 5: implementation step is with reference to embodiment 1, and different is proportion of raw materials (weight percent):
Urea 14%, potassium primary phosphate 14%, boric acid 7%, ammonium molybdate 3%, zinc sulfate 11%,
Manganous sulfate 7%, copper sulfate 7%, ferrous sulfate 12%, sal epsom 14%, amino acid/11 1%.
Embodiment 6: once with regard to urea 50 grams, potassium primary phosphate 50 restrained in the present invention, amino acid 40 grams, copper sulfate 25 grams, ferrous sulfate 40 grams, zinc sulfate 40 grams, manganous sulfate 25 grams, boric acid 30 grams, ammonium molybdate 15 grams, sal epsom 50 grams, acetic acid 6ml, the plant nutrition poiser censorship of EDTA1.5g preparation records total nitrogen (comprising amino acid) 〉=17.34%, potassium (K 2O), phosphorus (P 2O 5) 〉=8.09%, copper 〉=1.21%, boron 〉=1.61%, zinc 〉=1.41%, manganese 〉=1.80%, molybdenum 〉=2.57%, iron 〉=2.41%.
The present invention also can provide following actual weight per distribution ratio (add-on of acetic acid is a manganous sulfate, boric acid, sal epsom, the 1-2% of potassium dihydrogen phosphate total amount, the add-on of EDTA is the 5-10% of copperas solution amount):
Embodiment 789 10
Urea 12 16 13 14
Potassium primary phosphate 14 17 16 15
Boric acid 10 11 97
Ammonium molybdate 2534
Zinc sulfate 14 12 10 11
Manganous sulfate 6578
Copper sulfate 5568
Ferrous sulfate 10 11 12 11
Sal epsom 12 10 11 13
Amino acid/11 58 13 9

Claims (2)

1. the preparation method of a plant nutriment regulator, it contains urea 12-16%, potassium primary phosphate or vitriolate of tartar 14-24%, boric acid 7-20%, ammonium molybdate 2-6%, zinc sulfate 10-20%, manganous sulfate 5-10%, copper sulfate 5-10%, ferrous sulfate 10-15%, sal epsom 10-24%, amino acid 8-16% adopts the following step preparation: A. that amino acid solution, copper-bath, solution of zinc sulfate are mixed and carries out complex reaction; Copperas solution and EDTA solution carry out chelatropic reaction; Manganese sulfate solution, boric acid solution, Adlerika, potassium dihydrogen phosphate and acetic acid are compound; B. the three class solution that the A step is obtained are compound in proportion, add urea, ammonium molybdate solution under whipped state in proportion, and finally adjusting pH value is that 3.5-5 gets finished product; The add-on of wherein said EDTA solution adds with the 5-10% of copperas solution amount; The add-on of described acetic acid adds with the 1-2% of manganese sulfate solution, boric acid solution, Adlerika, potassium dihydrogen phosphate total amount; The hot water that is not less than 50 ℃ is adopted in the dissolving of described manganous sulfate and boric acid.
2. the preparation method of plant nutriment regulator as claimed in claim 1 is characterized in that: the adjustment employing sodium hydroxide solution of described pH value.
CN98121840A 1998-11-09 1998-11-09 Plant nutriment regulator Expired - Lifetime CN1093522C (en)

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Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003042128A2 (en) * 2001-11-14 2003-05-22 Akzo Nobel N.V. Aqueous iron chelate composition
CN1580006B (en) * 2003-08-15 2012-07-25 唐祯 Foliage fertilizer
CN100363312C (en) * 2005-08-11 2008-01-23 徐平 Fertilizer and pesticide composition
CN101353281B (en) * 2008-08-28 2012-10-10 吴成祥 Functional urea and preparation thereof
CN101891520B (en) * 2010-07-12 2012-08-29 重庆东方农药有限公司 Amino acid foliar fertilizer
CN102336605B (en) * 2011-06-29 2013-08-14 湖南农业大学 Amino acid foliar fertilizer for ramie and preparation method thereof
CN103360176A (en) * 2013-07-30 2013-10-23 重庆蓝苗生物科技开发有限公司 Water-soluble leaf fertilizer for konjak, and application thereof
CN103553725B (en) * 2013-09-18 2016-02-03 句容市植保植检站 A kind of foliage fertilizer preventing and treating pear tree iron deficiency disease disease
CN103755423B (en) * 2014-01-28 2015-08-12 华中农业大学 A kind of Amino acid liquid fertilizer and preparation method
CN104628478A (en) * 2015-02-09 2015-05-20 安徽省皖江蔬菜产业技术研究院有限责任公司 Special organic fertilizer for four-season fruit mulberry and preparation method thereof
CN104628492A (en) * 2015-02-09 2015-05-20 安徽省皖江蔬菜产业技术研究院有限责任公司 Low-cost meinong muskmelon controlled release fertilizer and preparation method thereof
CN105503396B (en) * 2015-12-23 2019-01-15 金广彦 A kind of production method of edible mushroom base-material pH value conditioner
CN105859421A (en) * 2016-05-06 2016-08-17 广西壮族自治区农业科学院农业资源与环境研究所 Rice functional foliage fertilizer formulation and preparation method and application thereof
CN110229033A (en) * 2019-06-26 2019-09-13 大农(苏州)农业科技有限公司 The high concentration fruits and vegetables mill water culture nutrient solution of zinc salt containing single amino acid, manganese salt chelate
CN111039709A (en) * 2020-01-19 2020-04-21 信阳农林学院 Foliar fertilizer for improving yield of radix scrophulariae

Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1121061A (en) * 1994-10-16 1996-04-24 唐祯 Proportioning and preparation process of liquid fertilizer containing amino acid
CN1123261A (en) * 1994-11-15 1996-05-29 四川银山化工集团股份有限公司 Method for production of amino-acid plant tonic liquor and product thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1121061A (en) * 1994-10-16 1996-04-24 唐祯 Proportioning and preparation process of liquid fertilizer containing amino acid
CN1123261A (en) * 1994-11-15 1996-05-29 四川银山化工集团股份有限公司 Method for production of amino-acid plant tonic liquor and product thereof

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