CN1608436A - Nutritious rice with rich organic selenium and zinc and its production process - Google Patents
Nutritious rice with rich organic selenium and zinc and its production process Download PDFInfo
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Abstract
The nutritious rice with rich organic selenium and zinc is produced through diluting organic selenium and zinc chelating agent solution containing selenium in 3.56-7.12 g/kg and zinc in 45.30-67-94 g/kg in the amount of 200 g/mu with water in 150-300 times, spraying the diluted solution to rice leaf in the tillering period, booting period and grain filling period of rice for rice to absorb and convert, and other steps. The nutritious rice has selenium and zinc content of 0.070-0.270 ppm and 12-25 mg ppm separately, 2-10 times and 2-5 times higher than common rice product separately. The nutritious rice of the present invention may be used in producing public food for human body to replenish selenium and zinc.
Description
Technical field
The present invention relates to the food improvement, particularly a kind of nutritious rice and production method thereof that is rich in organic selenium, zinc.
Background technology
The whole world has more than 40 countries and regions to belong to scarce selenium area, China is a scarce selenium big country, disclose according to " People's Republic of China's localized disease and environmental factor atlas ", tiltedly wear to the Yunnan-Guizhou Plateau from three provinces in the northeast of China, there is a low selenium area in 72% area that accounts for China's area, wherein, 30% is the serious selenium area that lacks, and natural food Se contents such as grain are lower.Big and medium-sized cities such as North China, northeast and northwest all belong to and lack the selenium area.Some areas of 22 provinces and cities of China, about 700,000,000 people live in low selenium area.Se content is below 0.02mg/kg, far below the minimum of the United Nations's health organization regulation in most of regional food.Still do not reach the above standard of everyone 40 micrograms every day at present in the population of China food and mend the selenium level, especially lack selenium area crowd, the more difficult purpose of mending selenium that from food, reaches.Selenium is the important component of the glutathione peroxidase of human body, and WHO classifies selenium as micro elements needed by human.Result of study shows that 17 class diseases such as cancer, angiocardiopathy, hepatopathy, diabetes, cataract and asthma are relevant with low selenium.The white muscle disease of livestock and poultry is exactly the typical selenium disease that lacks, and hangs down the selenium area with China and matches.Zinc be arranged in the human body confirmed of WHO and animal, the plant essential trace element top a kind of, participated in the metabolism of big nutriment in vivo, be the part of 300 plurality of enzymes or functional protein, human body is had important physical function, trophism and clinic diagnosis meaning.When human body lacked zinc, immunologic function degression, apocleisis, growth retardation, depauperation and intelligence degradation symptom down can appear.Chinese Soclety of Nutrition points out that national resident generally lacks zinc, especially Chinese children and teenager.As everyone knows, 20th century, the human subject matter that faces was to improve the output of agricultural product, solved human problem of food and clothing.And 21 century this problem be converted into output and quality and carry, focus on quality, exploitation health-nutrition food improves the human physique and the general level of the health.Have more than 600 medicine expert jointly to give a warning in the world, present human 90% disease, be since in the daily food the improper or content of microelement match can not satisfy due to the health needs.The Chinese food that 13 ministries and commissions of the Ministry of Public Health of State Council on the 10th etc. July in 2000 hold in Beijing is strengthened in the seminar, the relevant ministries and commissions representative of expert, professor and central authorities at home and abroad is consistent thinks that the shortage of trace element can not be ignored the harm of health and social development, and it directly influences the quality of human resources.The trace element insufficiency of intake makes 4,300 hundred million yuan of the annual losses of China.The approach that humans and animals is taken in selenium zinc mainly guarantees by the food that contains selenium zinc.Grain is the primary food that China resident takes in amino acid, cellulose, sugar, vitamin and trace element, macroelement every day.Grain contains selenium, zinc amount usually respectively less than 0.01mg/kg and 5mg/kg under the scarce selenium zinc ecotope.
Summary of the invention
The present invention makes selenium in the rice, zinc content reach the requirement that replenishes human body selenium, zinc by a kind of nutritious rice and production method thereof that is rich in organic selenium, zinc is provided, to reach the purpose that control lacks selenium, lacks the zinc synthetic disease.
The technical solution adopted for the present invention to solve the technical problems is: a kind of nutritious rice that is rich in organic selenium, zinc being provided, containing selenium in this nutritious rice and the zinc amount is respectively 0.070-0.270mg/kg and 12-25mg/kg, is respectively in the same old way 2-10 doubly and 2-5 times; Be by by every mu of rice field with 200 gram selenium, the organic chelated agent solution thin up of zinc 150-300 doubly after, spray once on aspire to the blade face or respectively spray once on aspire to the blade face or respectively spray once on aspire to the blade face in the booting of paddy rice, treat to gather in the crops after the paddy rice maturation and make in tillering stage, booting stage and the grouting of paddy rice in booting stage of paddy rice and grouting.This organic selenium that is rich in, the production method of the nutritious rice of zinc is: at first use selenium dioxide, zinc sulphate, methionine, fulvic acid and water are made and are contained selenium 3.56-7.12g/kg, the selenium that contains zinc 45.30-67.94g/kg, the organic chelated agent solution of zinc, then in use, restrain selenium by every mu of rice field with 200, the organic chelated agent solution of zinc, with 150-300 times of water dilution, spray once in the booting of paddy rice aspire to the blade face, or respectively spray once on aspire to the blade face in booting stage of paddy rice and grouting, or in tillering stage of paddy rice, booting stage and grouting are aspire to respectively spraying once on the blade face, after treating the paddy rice maturation, results are and are rich in organic selenium, the nutritious rice of zinc; Its concrete production method is: the preparation of a. selenium, the organic chelated agent solution of zinc: the selenium dioxide that will account for material gross weight 0.5-1% adds in the entry, after the stirring and dissolving, the methionine that adds 1-1.5% again, mixed dissolution, add successively then 20-30% with the zinc sulphate of 7 water of crystallization and 2% fulvic acid, stirring and dissolving, chelatropic reaction 24 hours forms the organic chelated agent solution that contains selenium methionine, zinc methionine and fulvic acid selenium, fulvic acid zinc; B. be rich in the production of organic selenium zinc nutritious rice: respectively tillering stage of paddy rice, booting stage or/and the pustulation period is got 200 gram selenium, zinc organic sequestering agent solution with water dilution 150-300 doubly, spray rice leaf in 1 mu of rice field with the droplet shape; C. other growth conditionss of paddy rice with to identical in the same old way, treat that ripe back results are the nutritious rice that is rich in organic selenium, zinc.Wherein, with the organic chelated agent solution of selenium, zinc that descends surface compositions to make, the nutritious rice of organic selenium, zinc is rich in production, both cheap, can reach the purpose of rich selenium zinc again: the water of the fulvic acid and 76.5% (weight) of the methionine, 2% (weight) of the zinc sulphate with 7 water of crystallization of the selenium dioxide, 20% (weight) of 0.5% (weight), 1% (weight) is mixed stirring and dissolving, and that makes contains selenium 3.56g/kg, the selenium that contains zinc 45.30g/kg, the organic chelated agent solution of zinc.In selenium of the present invention, the organic chelated agent solution of zinc, because selenium, zinc are in water miscible organic chelated state, than traditional inorganic additive, be that plant institute absorbs easily more, the selenium, the zinc organic sequestering agent that particularly utilize methionine and fulvic acid to make, similar or close to the composition that plant is contained, according to the principle of similar compatibility, the availability of selenium, zinc is higher, more obvious, better effects if.In addition, containing selenium, zinc amount in organic selenium, the zinc nutrition rice increases with selenium, zinc content in selenium, the organic chelated agent solution of zinc and the increase that sprays number of times.
The present invention is by foliage-spray selenium, zinc organic sequestering agent, in the paddy rice body, carry out biochemical pathway, make rice contain selenium, the zinc amount reaches 0.070-0.270mg/kg and 12-25mg/kg respectively, be common 2-10 in the same old way doubly and 2-5 times, and meet the sanitary standard (GB1305-91 that limits the quantity of of selenium in the food, zinc again, " every day of recommendation is nutrient allowance in the meals " 1306-91) and among the GB15740-1997 " the health food universal standard " of country promulgation is so be referred to as organic selenium, zinc nutrition rice.Selenium, zinc element mainly are organic selenium, the organic zincs that human body easily absorbs and utilizes in this meter, and long term storage in vivo to keep higher blood selenium, Blood Zinc Concentration, is slowly brought into play diseases prevention, disease-resistant effect, improves the immunologic function of human body etc.The selenium, zinc organic sequestering agent and using method and the dosage that help the paddy rice absorption that utilize the present invention to develop, build foundation farm, three rivers in the Heilongjiang Province and carried out small size industrialization trial production, both met food standard, be rich in the interworking type rice of organic selenium and organic zinc again.With 400 kilograms of organic selenium, the every per mu yields of zinc nutrition rice, 3.00 yuan/kilogram of costs, 4.00 yuan of/kilogram calculating of price, 10000 mu of organic selenium, zinc nutrition rice can be made a profit 4,000,000 yuan.
The present invention will be further described below in conjunction with embodiment.
Embodiment
The preparation of embodiment 1.a. selenium, the organic chelated agent solution of zinc: the selenium dioxide that will account for material gross weight 0.5% joins in 76.5% water, after the stirring and dissolving, add 1% methionine again, mixed dissolution, add successively then 20% with the zinc sulphate of 7 water of crystallization and 2% fulvic acid, stirring and dissolving, chelatropic reaction 24 hours, formation contains selenium 3.56g/kg, contains selenium methionine, zinc methionine and the fulvic acid selenium of zinc 45.30g/kg, the organic chelated agent solution of fulvic acid zinc; B. be rich in the production of organic selenium zinc nutritious rice: get 200 gram selenium, zinc organic sequestering agent solution with water dilution 150-300 doubly by 1 mu of rice field, spray rice leaf with the droplet shape and spray by three kinds of situations: (1) sprayed once in the booting stage of paddy rice; (2) spray secondary in booting stage and the pustulation period of paddy rice; (3) spray three times in tillering stage, booting stage and the pustulation period of paddy rice; C. other growth conditionss of paddy rice with to identical in the same old way, contain inorganic selenium (as selenium dioxide) to adopt respectively in the same old way, zinc (as the zinc sulphate with 7 water of crystallization) solution sprays and do not spray any selenium zinc solution (as water spray) that contains, treat that ripe back results are the nutritious rice that is rich in organic selenium, zinc.Selenium, zinc content results of comparison such as table 1 in the product:
Table 1
The preparation of embodiment 2.a. selenium, the organic chelated agent solution of zinc: the selenium dioxide that will account for material gross weight 0.75% joins in 71% water, after the stirring and dissolving, add 1.25% methionine again, mixed dissolution, add successively then 25% with the zinc sulphate of 7 water of crystallization and 2% fulvic acid, stirring and dissolving, chelatropic reaction 24 hours forms the organic chelated agent solution that contains selenium methionine, zinc methionine and fulvic acid selenium, fulvic acid zinc that contains selenium 5.34g/kg, contains zinc 56.23g/kg; B. be rich in the production of organic selenium zinc nutritious rice: get 200 gram selenium, zinc organic sequestering agent solution with water dilution 150-300 doubly by 1 mu of rice field, spray rice leaf with the droplet shape, spray by three kinds of situations: (1) sprayed once in the booting stage of paddy rice; (2) spray secondary in booting stage and the pustulation period of paddy rice; (3) spray three times in tillering stage, booting stage and the pustulation period of paddy rice; C. other growth conditionss of paddy rice with to identical in the same old way, spray and do not spray any selenium zinc solution that contains to adopt the solution contain inorganic selenium, zinc respectively in the same old way, treat that ripe back results are the nutritious rice that is rich in organic selenium, zinc.Selenium, zinc content results of comparison such as table 2 in the product:
Table 2
The preparation of embodiment 3.a. selenium, the organic chelated agent solution of zinc: the selenium dioxide that will account for material gross weight 1.00% joins in 65.5% water, after the stirring and dissolving, add 1.50% methionine again, mixed dissolution, add successively then 30% with the zinc sulphate of 7 water of crystallization and 2% fulvic acid, stirring and dissolving, chelatropic reaction 24 hours, formation contains selenium 7.12g/kg, contains selenium methionine, zinc methionine and the fulvic acid selenium of zinc 67.94g/kg, the organic chelated agent solution of fulvic acid zinc; B. be rich in the production of organic selenium zinc nutritious rice: get 200 gram selenium, zinc organic sequestering agent solution with water dilution 150-300 doubly by 1 mu of rice field, spray rice leaf with the droplet shape and spray by three kinds of situations: (1) sprayed once in the booting stage of paddy rice; (2) spray secondary in booting stage and the pustulation period of paddy rice; (3) spray three times in tillering stage, booting stage and the pustulation period of paddy rice; C. other growth conditionss of paddy rice with to identical in the same old way, contain the inorganic solution that contains selenium, zinc and spray and do not spray any selenium zinc solution that contains adopt respectively in the same old way, treat that ripe back results are the nutritious rice that is rich in organic selenium, zinc.Selenium, zinc content results of comparison such as table 3 in the product:
Table 3
Detection data among the embodiment 1,2 and 3 are provided by cereal monitoring center of the Ministry of Agriculture.
Claims (3)
1. nutritious rice that is rich in organic selenium, zinc is characterized in that containing selenium in the nutritious rice and the zinc amount is respectively 0.070-0.270mg/kg and 12-25mg/kg, is respectively in the same old way 2-10 doubly and 2-5 times; This nutritious rice be by by every mu of rice field with 200 gram selenium, the organic chelated agent solution thin up of zinc 150-300 doubly after, spray once on aspire to the blade face or respectively spray once on aspire to the blade face or respectively spray once on aspire to the blade face in the booting of paddy rice in tillering stage, booting stage and the grouting of paddy rice in booting stage of paddy rice and grouting, after treating the paddy rice maturation, results make.
2. one kind is rich in organic selenium, the production method of the nutritious rice of zinc, it is characterized in that at first using selenium dioxide, zinc sulphate, methionine, fulvic acid and water are made and are contained selenium 3.56-7.12g/kg, the selenium that contains zinc 45.30-67.94g/kg, the organic chelated agent solution of zinc, then in use, restrain selenium by every mu of rice field with 200, the organic chelated agent solution of zinc, with 150-300 times of water dilution, spray once in the booting of paddy rice aspire to the blade face, or respectively spray once on aspire to the blade face in booting stage of paddy rice and grouting, or in tillering stage of paddy rice, booting stage and grouting are aspire to respectively spraying once on the blade face, after treating the paddy rice maturation, results are and are rich in organic selenium, the nutritious rice of zinc; Its concrete production method is: the preparation of a. selenium, the organic chelated agent solution of zinc: the selenium dioxide that will account for material gross weight 0.5-1% adds in the entry, after the stirring and dissolving, the methionine that adds 1-1.5% again, mixed dissolution, add successively then 20-30% with the zinc sulphate of 7 water of crystallization and 2% fulvic acid, stirring and dissolving, chelatropic reaction 24 hours forms the organic chelated agent solution that contains selenium methionine, zinc methionine and fulvic acid selenium, fulvic acid zinc; B. be rich in the production of organic selenium zinc nutritious rice: respectively tillering stage of paddy rice, booting stage or/and the pustulation period is got 200 gram selenium, zinc organic sequestering agent solution with water dilution 150-300 doubly, spray rice leaf in 1 mu of rice field with the droplet shape; C. other growth conditionss of paddy rice with to identical in the same old way, treat that ripe back results are the nutritious rice that is rich in organic selenium, zinc.
3. according to claim 1 or 2 described nutritious rice and the production methods thereof that are rich in organic selenium, zinc, it is characterized in that selenium, the organic chelated agent solution of zinc water, contain selenium 3.56g/kg, the selenium that contains zinc 45.30g/kg, the organic chelated agent solution of zinc through what stirring and dissolving formed by the fulvic acid and 76.5% (weight) of the methionine, 2% (weight) of the zinc sulphate with 7 water of crystallization of the selenium dioxide, 20% (weight) of 0.5% (weight), 1% (weight).
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| CN109997631A (en) * | 2019-03-14 | 2019-07-12 | 深圳市芭田生态工程股份有限公司 | The implantation methods and rice rich in zinc of rice rich in zinc |
| CN110041124A (en) * | 2019-04-23 | 2019-07-23 | 浙江工业大学 | A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc |
| CN113575329A (en) * | 2021-08-11 | 2021-11-02 | 广东美雅臻生物科技有限公司 | Planting method of organic selenium-rich rice |
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