CN110041124A - A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc - Google Patents

A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc Download PDF

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Publication number
CN110041124A
CN110041124A CN201910328528.4A CN201910328528A CN110041124A CN 110041124 A CN110041124 A CN 110041124A CN 201910328528 A CN201910328528 A CN 201910328528A CN 110041124 A CN110041124 A CN 110041124A
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China
Prior art keywords
zinc
rice
nutrient liquid
rich nutrient
rich
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CN201910328528.4A
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Chinese (zh)
Inventor
陈品儒
翟晚娜
金志敏
陈文豪
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Zhejiang University of Technology ZJUT
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Zhejiang University of Technology ZJUT
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Priority to CN201910328528.4A priority Critical patent/CN110041124A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C21/00Methods of fertilising, sowing or planting
    • A01C21/005Following a specific plan, e.g. pattern
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G22/00Cultivation of specific crops or plants not otherwise provided for
    • A01G22/20Cereals
    • A01G22/22Rice
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C11/00Other nitrogenous fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers

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  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Botany (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Fertilizers (AREA)

Abstract

The invention belongs to crop planting fields, it is related to a kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc, the zinc source of the zinc-rich nutrient liquid is the zinc salt of polysaccharide sulfate, the zinc-rich nutrient liquid is formulated by the raw material of following mass percent: zinc salt, 1.5%-3.0% methionine, 1.5%-3.0% serine, the 5%-8% glycine betaine of 10%-45% polysaccharide sulfate, surplus is water, and raw material summation is 100%.Zn-ef ficiency of the present invention is absorbed by rice leaf, effectively facilitate Rice Photosynthesis, improve the absorptivity of zinc-rich nutrient liquid, keep plant strain growth in great numbers, nutrition and microelement are directly entered in rice body, rice metabolism and organic synthesis are participated in, the nutritional ingredients such as methionine, serine, glycine betaine in formula can promote rice high yield precocious, improve yield;The rice that method of the invention is cultivated is a kind of natural zinc-rich rice, and the absorption of human body utilization rate of this biological zinc is high, and it is 3-5 times of general rice Zn content that the present invention, which can significantly improve the Zn content in rice,.

Description

A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc
Technical field
The invention belongs to crop planting field, it is related to a kind of dedicated zinc-rich nutrient liquid of rice and for standing grain such as zinc-rich paddy rices The method of graminaceous plant production.
Background technique
Zinc is one of necessary microelement of human body.Zn-ef ficiency is enhanced human immunity to growth in humans's development is promoted, Influencing the physiological functions such as metabolism and the vision of vitamin A has irreplaceable role.
Solving the undesirable strategy of zinc nutrition at present mainly has medicament supplement and food supplement.Medicament supplement lacks rapid improve Zinc human body Zn content significant effect, but there's no such thing as a totally safe medicine, and ideal effect cannot not only be reached by blindly taking zinc supplementation drug, or even be risen To the effect run counter to desire, personal health is influenced.Food supplement is to improve underfed most desirable route, more edible richnesses Zinc food can effectively improve zinc deficiency symptom, especially if the zinc content of staple food rice can be improved, so that it may reach steady in a long-term Offer Zn-ef ficiency, be the optimization to food replenishment strategy.By breeding and Cultural practices, the zinc for improving the edible part of crop contains Amount, is a kind of effective approach.
The zinc content of general rice is 10-15mg/kg.
Current material containing zinc fertilizer mainly has solid fertilizer and liquid fertilizer, but in view of solid fertilizer effect is poor, is easy to run off, and Irreversible change can be generated to soil, so the present invention is to prepare a kind of liquid containing zinc nutrition, not only have zinc supplementation effect to crop, And promotes crop yield, the infringement for resisting crop germ, fixed nitrogen, promotes precocious effect.
Mainly there are inorganic zinc (zinc sulfate, zinc oxide etc.) and coordination zinc (EDTA zinc network in the zinc source of zinc supplementation agent used at present Mixture), but their disadvantages are obvious, and inorganic zinc source difficulty absorbs, and is easy to run off;It is difficult to degrade to be coordinated zinc, residual rate is high, toxic to plant Effect.
Such as Chinese Patent Application No. CN201410037199.5, entitled rice zinc-rich nutrient agent and its preparation and it is used for The method for producing rice rich in zinc, using the mixture of one or more of soluble zinc salt or zinc oxide as zinc source, zinc source Hardly possible is absorbed, is easy to run off, and manufacture is easy to pollute soil at fertiliser granulates as zinc-rich nutrient agent, and utilization rate is low.
Summary of the invention
The deficiencies of present invention is to solve zinc source difficulty absorption in the prior art, be easy to run off, and one kind is provided with small molecule The zinc salt of the polysaccharide sulfate of amount is prepared into the dedicated zinc-rich nutrient liquid of rice as zinc source, and is used for production rice rich in zinc, The Zn content in rice can be dramatically increased, moreover it is possible to promote eary maturity of rice, improve yield.
The technical solution adopted by the present invention to solve the technical problems is:
A kind of dedicated zinc-rich nutrient liquid of rice, the zinc source of the zinc-rich nutrient liquid is the zinc salt of polysaccharide sulfate, described Zinc-rich nutrient liquid is formulated by the raw material of following mass percent:
Zinc salt, 1.5%-3.0% methionine, the 1.5%-3.0% serine, 5%-8% of 10%-45% polysaccharide sulfate Glycine betaine, surplus are water, and raw material summation is 100%.
Preferably, the zinc source is the zinc salt of the polysaccharide sulfate of small-molecular-weight, molecular weight is 400~2500.
Preferably, the polysaccharide sulfated degree of substitution in the zinc source is 0.5~3.
Preferably, the zinc source be the algal polysaccharide zinc sulfate of small-molecular-weight, small-molecular-weight Polysaccharide of Brasenia Schreberi zinc sulfate, In the starch-polysaccharides zinc sulfate of the chondroitin sulfate zinc salt of small-molecular-weight, the heparin zinc salt of small-molecular-weight and small-molecular-weight at least It is a kind of.
A kind of method that the dedicated zinc-rich nutrient liquid of rice is used to produce rice, described method includes following steps:
The configuration of S1, zinc-rich nutrient liquid:
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: the zinc of 10%-45% polysaccharide sulfate Salt, 1.5%-3.0% methionine, 1.5%-3.0% serine, 5%-8% glycine betaine, surplus are water, and raw material summation is 100%;
By the zinc salt of the polysaccharide sulfate of formula ratio, methionine, serine, glycine betaine and water stirring and dissolving to get zinc-rich Nutrient solution;
S2, field spray:
Zinc-rich nutrient liquid is sprayed on to the different plot of paddy field, the field amount of application of zinc-rich nutrient liquid in Grain Filling For 480g~500g per acre;
S3, water and fertilizer management is carried out, to get rice rich in zinc after rice is mature.
Preferably, spraying the zinc-rich nutrient liquid to rice leaf or/and soil.
It is furthermore preferred that spraying the zinc-rich nutrient liquid to rice leaf.
Preferably, in step s 2, the zinc-rich nutrient liquid is sufficiently stirred with 58~60 times of its weight of clear water molten Field is carried out after solution again to spray.
Preferably, spray the zinc-rich nutrient liquid 2~3 times in Grain Filling, every time between be spaced 5~7 days.
The beneficial effects of the present invention are:
Zn-ef ficiency of the invention is absorbed by rice leaf, effectively facilitates Rice Photosynthesis, improves zinc-rich nutrient liquid Absorptivity keeps plant strain growth in great numbers, is directly entered nutrition and microelement in rice body, participate in rice metabolism with it is organic Synthesis, methionine, serine, glycine betaine etc. in formula, which are formed, point can promote rice high yield precocious, raising yield;Of the invention The rice that method is cultivated is a kind of natural zinc-rich rice, and the absorption of human body utilization rate of this biological zinc is high, and the present invention can be mentioned obviously Zn content in high rice is 3-5 times of general rice Zn content, and zinc content reaches 30.6-53.5mg/kg.
Specific embodiment
Below by embodiment, explanation is further described to technical solution of the present invention.
Embodiment 1:
Selecting molecular weight is 1000, the algal polysaccharide sulphur that the algal polysaccharide sulfate that sulphation degree of substitution is 1.53 is prepared into Sour zinc, the zinc source as the present embodiment.
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: 30% algal polysaccharide zinc sulfate, 2.5% methionine, 2.0% serine, 7% glycine betaine, surplus are water, and raw material is agitated to be dissolved into zinc-rich nutrient liquid, are labeled as 1 Number nutrient solution.
Embodiment 2:
Selecting molecular weight is 800, the Polysaccharide of Brasenia Schreberi sulphur that the Polysaccharide of Brasenia Schreberi sulfuric ester that sulphation degree of substitution is 1.46 is prepared into Sour zinc, the zinc source as the present embodiment.
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: 20% Polysaccharide of Brasenia Schreberi zinc sulfate, 1.5% methionine, 1.5% serine, 5% glycine betaine, surplus are water, and raw material is agitated to be dissolved into zinc-rich nutrient liquid, are labeled as 2 Number nutrient solution.
Embodiment 3:
Selecting molecular weight is 2000, the zinc salt that the chondroitin sulfate that sulphation degree of substitution is 1.37 is prepared into, as this reality Apply the zinc source of example.
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: 30% chondroitin sulfate zinc salt, 2.0% methionine, 3.0% serine, 7% glycine betaine, surplus are water, and raw material is agitated to be dissolved into zinc-rich nutrient liquid, are labeled as 3 Number nutrient solution.
Embodiment 4:
Selecting molecular weight is 1500, the zinc salt that the heparin that sulphation degree of substitution is 1.24 is prepared into, as the present embodiment Zinc source.
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: 45% heparin zinc salt, 3.0% egg ammonia Acid, 2.5% serine, 8% glycine betaine, surplus are water, and raw material is agitated to be dissolved into zinc-rich nutrient liquid, are labeled as No. 4 nutrient solutions.
Embodiment 5:
Selecting molecular weight is 500, the starch-polysaccharides sulphur that the starch-polysaccharides sulfuric ester that sulphation degree of substitution is 0.98 is prepared into Sour zinc, the zinc source as the present embodiment.
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: 20% starch-polysaccharides zinc sulfate, 1.5% Methionine, 1.5% serine, 5% glycine betaine, surplus are water, and raw material is agitated to be dissolved into zinc-rich nutrient liquid, labeled as No. 5 battalion Nutrient solution.
Embodiment 6:
Selecting molecular weight is 4000, the algal polysaccharide sulphur that the algal polysaccharide sulfate that sulphation degree of substitution is 1.53 is prepared into Sour zinc, the zinc source as the present embodiment.
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: 10% algal polysaccharide zinc sulfate, 1.5% Methionine, 1.5% serine, 5% glycine betaine, surplus are water, and raw material is agitated to be dissolved into zinc-rich nutrient liquid, labeled as No. 6 battalion Nutrient solution.
Comparative example:
Clear water is labeled as No. 0 nutrient solution.
Different Nutrition liquid obtained above is sprayed on to the same a piece of experimental plot in Zhejiang county, the rice of field planting is Zhejiang Excellent 18 kind, the total amount that nutrient solution is applied in field is that 500g, zinc-rich nutrient liquid spray again after adding clear water 30kg to dilute per acre, Grain Filling is sprayed on the rice leaf in experimental plot difference plot, continuous spraying 2-3 times, is sprayed every 7 days primary.To water After rice is mature, rice zinc content is measured, following table is summarized in:
Embodiment Nutrient solution number Rice zinc content mg/kg Per mu yield (kilogram)
Comparative example 0 12.4 932
1 1 38.7 984
2 2 53.5 964
3 3 40.5 973
4 4 36.8 987
5 5 32.8 964
6 6 30.6 950
From above example it can be seen that the rice produced using method provided by the invention, Zn content reach 30.6- 53.5mg/kg is 3-5 times of general rice Zn content, and the zinc salt of the polysaccharide sulfate of macromolecule can also improve rice and contain Zinc amount, but it is weak compared to the polysaccharide sulfate zinc salt effect of small-molecular-weight.The rice cultivated in this way it be exactly a kind of day The absorption of human body utilization rate of right rice rich in zinc, this biological zinc is high, and by the way that various nutrients are added, so that rice yield obtains It improves, and passes through foliage-spray but also the utilization rate of zinc is more much higher than the utilization rate for spreading fertilizer over the fields solid zinc fertilizer in nutrient solution, thus Rice rich in zinc this new function rice is developed by this approach will a boundless application prospect, and to improving people The zinc nutrition deficiency of the people has the meaning of reality.
Embodiment described above is preferred version of the invention, is not intended to limit the present invention in any form, There are also other variants and remodeling on the premise of not exceeding the technical scheme recorded in the claims.

Claims (9)

1. a kind of dedicated zinc-rich nutrient liquid of rice, which is characterized in that the zinc source of the zinc-rich nutrient liquid is polysaccharide sulfate Zinc salt, the zinc-rich nutrient liquid are formulated by the raw material of following mass percent:
Zinc salt, 1.5%-3.0% methionine, 1.5%-3.0% serine, the 5%-8% beet of 10%-45% polysaccharide sulfate Alkali, surplus are water, and raw material summation is 100%.
2. the dedicated zinc-rich nutrient liquid of rice as described in claim 1, which is characterized in that the zinc source is the more of small-molecular-weight The zinc salt of sugar sulfate, molecular weight 400-2500.
3. the dedicated zinc-rich nutrient liquid of rice as claimed in claim 2, which is characterized in that the zinc source it is polysaccharide sulfated Degree of substitution is 0.5~3.
4. the dedicated zinc-rich nutrient liquid of rice as described in claims 1 to 3 any one, which is characterized in that the zinc source is In algal polysaccharide zinc sulfate, Polysaccharide of Brasenia Schreberi zinc sulfate, chondroitin sulfate zinc salt, heparin zinc salt and starch-polysaccharides zinc sulfate at least It is a kind of.
5. the side that a kind of dedicated zinc-rich nutrient liquid of rice described in Claims 1 to 4 any one is used to produce rice rich in zinc Method, which is characterized in that described method includes following steps:
The configuration of S1, zinc-rich nutrient liquid:
The zinc-rich nutrient liquid is formulated by the raw material of following mass percent: the zinc salt of 10%-45% polysaccharide sulfate, 1.5%-3.0% methionine, 1.5%-3.0% serine, 5%-8% glycine betaine, surplus are water, and raw material summation is 100%;
By the zinc salt of the polysaccharide sulfate of formula ratio, methionine, serine, glycine betaine and water stirring and dissolving to get zinc-rich nutrient Liquid;
S2, field spray:
The zinc-rich nutrient liquid is sprayed in Grain Filling, the field amount of application of zinc-rich nutrient liquid is 480g~500g per acre;
S3, water and fertilizer management is carried out, to get rice rich in zinc after rice is mature.
6. zinc-rich nutrient liquid as claimed in claim 5 be used for produce rice method, which is characterized in that rice leaf or/ The zinc-rich nutrient liquid is sprayed with soil.
7. the method that zinc-rich nutrient liquid as claimed in claim 6 is used to produce rice, which is characterized in that sprayed to rice leaf The zinc-rich nutrient liquid.
8. the method that zinc-rich nutrient liquid as claimed in claim 5 is used to produce rice, which is characterized in that in step s 2, will The zinc-rich nutrient liquid is sufficiently stirred with 58~60 times of its weight of clear water to carry out field after dissolution again and sprays.
9. the method that zinc-rich nutrient liquid as claimed in claim 5 is used to produce rice, which is characterized in that sprayed in Grain Filling Apply the zinc-rich nutrient liquid 2~3 times, every time between be spaced 5~7 days.
CN201910328528.4A 2019-04-23 2019-04-23 A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc Pending CN110041124A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
CN111393208A (en) * 2020-04-28 2020-07-10 合肥绿农肥业有限责任公司 Zinc-rich rice liquid fertilizer and application method thereof

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