CN108101671A - A kind of functional form foliar fertilizer and preparation method thereof - Google Patents
A kind of functional form foliar fertilizer and preparation method thereof Download PDFInfo
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- CN108101671A CN108101671A CN201810165048.6A CN201810165048A CN108101671A CN 108101671 A CN108101671 A CN 108101671A CN 201810165048 A CN201810165048 A CN 201810165048A CN 108101671 A CN108101671 A CN 108101671A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Pest Control & Pesticides (AREA)
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Abstract
The invention discloses a kind of functional form foliar fertilizers and preparation method thereof, are as made from urea, sodium selenite, four water, eight Boratex, potassium dihydrogen phosphate, fulvic acid, trace element, garlic polysaccharide, pulullan polysaccharide, polyglutamic acid, disodium ethylene diamine tetraacetate, methyl α-naphthyl acetate, zinc ion porphyrin nano complex compound and water.The functional form foliar fertilizer of the present invention has efficient, environmental protection, strong sprout, the excellent properties of degeneration-resistant, anti-evil, with can be penetrated into after plant contact in plant rapidly, cell is promoted to increase, division, the synthesis of nucleic acid and protein, organ is delayed to come off and crop aging and Chlorophyll synthesis, improve photosynthetic rate and enhancing resistance, break apical dominance, plant growth is promoted to be good for without prosperous, both the synthesis of total nutrient had been added, coordinate the relations of distribution of nutrition and reproductive growth again, increase substantially crop yield and quality.
Description
Technical field
The present invention relates to foliar fertilizer technical fields, and in particular to a kind of functional form foliar fertilizer and preparation method thereof.
Background technology
The major function of blade is to carry out photosynthesis synthesis organic matter using solar energy, and synthetic product is carried out centainly
Biochemical transformation is simultaneously transported to other organs.The blade of high terrestrial plant is generally by epidermis, mesophyll, vein three parts group
Into.The epidermis of leaf is divided into the palisade cell of epicuticle and the sponge cell of lower epidermis.Also have in the upper lower epidermis of blade and safeguard
The aperture of plastidogenetic lens-shaped is known as stomata, is air and water vapour in the gaseous metabolisms such as carbon assimilation, transpiration
Access.Research show blade with it is extraneous carry out mass exchange be mainly pass through blade surface stomata and cuticula it is hydrophilic small
Hole.There is one layer of cuticula outside plant leaf blade epidermal cell, by a kind of long-chain fat acid polymer group with hydroxyl and carboxyl
Into hydroxyl, carboxylated hydrophilic group on the molecular gap and molecule of this polymer can allow aqueous solution to penetrate into leaf.Separately
Nutriment can be transported to blade interior by the matter ectodesma of outer leafs cell by active absorption.
Foliar fertilizer refers to for the purpose of Foliage Absorption, and nutrient needed for crop is directly applied to the fertilizer on blade face.Foliar fertilizer is
Nutrient is applied to crops blade surface, and a kind of fertilizer type of base function is played by the absorption of blade, plant
Blade has two layers of table seed up and down, is made of table seed cell, there is cuticula and wax on table on the outside of cell, can protect table seed group
Mesophyll cell under knitting exercises the functions such as photosynthetic, breathing, and from the influence of extraneous unfavorable conditions variation, there are many more blade performances
Small stomata exercises the function that gas is replaced.Foliar fertilizer can be penetrated by micropore in blade after being applied to leaf surfaces.
Foliage dressing has the advantages that soil application is incomparable.It is not required to through soil, can live to avoid some mineral elements and physiology
Sex factor is fixed in the soil and decomposes, therefore foliage dressing is compared with soil application, for foliage dressing fertilizer amount only
For the 1/10-1/5 of soil application, it is possible to reduce substantial amounts of soil application.In addition foliage-spray can be directed to the difference life of crop
Long-term and special growing environment, spray the nutrient that plant growth is lacked, especially micro-, can rectify in time
Just or improve crop nutritional deficiency symptom.Using crop can be met after foliar fertilizer to the needs in relation to nutrient, inhibit to be harmful to micro- life
Object promotes the activity of urase, phosphatase, arginase etc. in the breeding of blade surface, and it is antibacterial to reach diseases prevention, promotes plant growth
The effect of.
Foliar fertilizer have amount of application it is few, effect is apparent rapidly, improves the utilization rate of fertilizer, be a kind of not only economy, effect but also
Good measures of fertilizer, obtains liking for consumers in general.But although existing foliar fertilizer can improve grain yield, still
It needs to can be only achieved preferable effect of increasing production using substantial amounts of foliar fertilizer.Foliar fertilizer is applied to after corps leaf surface, due to
The effect of foliar fertilizer is limited, it is necessary to which the long period can just be absorbed by crops and play a role, and be easy to cause foliar fertilizer utilizes effect
Rate is low.
The content of the invention
The present invention provides it is a kind of efficiently, environmental protection, strong sprout, degeneration-resistant, anti-evil functional form foliar fertilizer.
The present invention also provides the preparation methods of the functional form foliar fertilizer.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of functional form foliar fertilizer is as made from the raw material of following parts by weight:20 parts of urea, 2-4 parts of sodium selenite,
10-15 parts of four water, eight Boratex, 10-15 parts of potassium dihydrogen phosphate, 8-12 parts of fulvic acid, 10-15 parts of trace element, garlic polysaccharide 5-
9 parts, 4-6 parts of pulullan polysaccharide, 6-8 parts of polyglutamic acid, 0.4-0.6 parts of disodium ethylene diamine tetraacetate, 0.1-0.3 parts of methyl α-naphthyl acetate,
Zinc ion -0.2-0.4 parts of porphyrin nano complex compound, 50-70 parts of water.
Described, zinc ion-porphyrin nano complex compound is prepared using following methods:By 10ml acetic acid zinc solutions
It is added to together with the acetum of four pyridylporphyrins of 1.5ml0.05mmol/L in reaction bulb, 20-30 DEG C is stirred to react 10-
20h obtains zinc ion-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 0.5-1.5mol/L.
Described, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.05-0.1:0.1-0.2:0.1-0.3:The weight ratio composition of 0.8-1.2.
Preferably, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.08:0.15:0.2:1 weight ratio composition.
Described, the molecular weight of polyglutamic acid is ten thousand dalton of 5-10.
A kind of preparation method of functional form foliar fertilizer, is as made from following steps:
1) urea, sodium selenite, four water, eight Boratex, potassium dihydrogen phosphate, fulvic acid and trace element are added in water, mixed
It closes uniformly, must expect A;
2) garlic polysaccharide, pulullan polysaccharide, polyglutamic acid, disodium ethylene diamine tetraacetate and methyl α-naphthyl acetate are added in material A, risen
Temperature stirs 0.5-1.5h, is cooled to room temperature, must expect B to 30-50 DEG C;
3) zinc ion-porphyrin nano complex compound is added in material B, stirs 20-40min, obtain functional form foliar fertilizer.
Beneficial effects of the present invention:The functional form foliar fertilizer of the present invention have efficiently, environmental protection, strong sprout, degeneration-resistant, anti-evil
It can be penetrated into after excellent properties, with plant contact in plant rapidly, cell be promoted to increase, division, the conjunction of nucleic acid and protein
Into, organ is delayed to come off and crop aging and Chlorophyll synthesis, improve photosynthetic rate and enhancing resistance, it is excellent to break top
Gesture promotes plant growth to be good for without prosperous, has not only added the synthesis of total nutrient, but also has coordinated nutrition and the distribution of reproductive growth pass
System, increases substantially crop yield and quality.Zinc ion-porphyrin nano complex compound of the present invention can enhance suction of the blade to fertilizer
It is attached, improve the utilization rate of functional form foliar fertilizer.Garlic polysaccharide, pulullan polysaccharide and polyglutamic acid synergistic effect, on the one hand have
There is preferable antibacterial activity, on the other hand optionally combine a variety of fertilizer molecules or ion, form Host-guest inclusion complex, with
After plant contact, object fertilizer is discharged rapidly, enhances the using effect of foliar fertilizer.Fulvic acid can promote crop to nutrient
It absorbs, promotes the activity raising of enzyme, promote photosynthesis and respiration.The preparation method of the present invention is simple and practicable, is produced into
This is low, it can be achieved that the clean manufacturing of no pollution discharge, is suitble to scale industrialization production.
Specific embodiment
The present invention is described in further details with reference to specific embodiment.
Embodiment 1
A kind of functional form foliar fertilizer is as made from the raw material of following parts by weight:20 parts of urea, 4 parts of sodium selenite, four
15 parts of eight Boratex of water, 10 parts of potassium dihydrogen phosphate, 12 parts of fulvic acid, 10 parts of trace element, 9 parts of garlic polysaccharide, pulullan polysaccharide 6
Part, 8 parts of polyglutamic acid, 0.4 part of disodium ethylene diamine tetraacetate, 0.1 part of methyl α-naphthyl acetate, zinc ion -0.4 part of porphyrin nano complex compound,
70 parts of water.
Described, zinc ion-porphyrin nano complex compound is prepared using following methods:By 10ml acetic acid zinc solutions
It is added to together with the acetum of four pyridylporphyrins of 1.5ml0.05mmol/L in reaction bulb, 20 DEG C are stirred to react 20h, obtain
Zinc ion-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 0.5mol/L.
Described, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.1:0.2:0.1:0.8 weight ratio composition.
Preferably, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.08:0.15:0.2:1 weight ratio composition.
Described, the molecular weight of polyglutamic acid is ten thousand dalton of 5-10.
A kind of preparation method of functional form foliar fertilizer, is as made from following steps:
1) urea, sodium selenite, four water, eight Boratex, potassium dihydrogen phosphate, fulvic acid and trace element are added in water, mixed
It closes uniformly, must expect A;
2) garlic polysaccharide, pulullan polysaccharide, polyglutamic acid, disodium ethylene diamine tetraacetate and methyl α-naphthyl acetate are added in material A, risen
Temperature stirs 1.5h, is cooled to room temperature, must expect B to 50 DEG C;
3) zinc ion-porphyrin nano complex compound is added in material B, stirs 20min, obtain functional form foliar fertilizer.
Embodiment 2
A kind of functional form foliar fertilizer is as made from the raw material of following parts by weight:20 parts of urea, 3 parts of sodium selenite, four
13 parts of eight Boratex of water, 12 parts of potassium dihydrogen phosphate, 10 parts of fulvic acid, 13 parts of trace element, 7 parts of garlic polysaccharide, pulullan polysaccharide 5
Part, 7 parts of polyglutamic acid, 0.5 part of disodium ethylene diamine tetraacetate, 0.2 part of methyl α-naphthyl acetate, zinc ion -0.3 part of porphyrin nano complex compound,
60 parts of water.
Described, zinc ion-porphyrin nano complex compound is prepared using following methods:By 10ml acetic acid zinc solutions
It is added to together with the acetum of four pyridylporphyrins of 1.5ml0.05mmol/L in reaction bulb, 25 DEG C are stirred to react 15h, obtain
Zinc ion-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 1mol/L.
Described, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.08:0.15:0.2:1 weight ratio composition.
Preferably, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.08:0.15:0.2:1 weight ratio composition.
Described, the molecular weight of polyglutamic acid is ten thousand dalton of 5-10.
A kind of preparation method of functional form foliar fertilizer, is as made from following steps:
1) urea, sodium selenite, four water, eight Boratex, potassium dihydrogen phosphate, fulvic acid and trace element are added in water, mixed
It closes uniformly, must expect A;
2) garlic polysaccharide, pulullan polysaccharide, polyglutamic acid, disodium ethylene diamine tetraacetate and methyl α-naphthyl acetate are added in material A, risen
Temperature stirs 1h, is cooled to room temperature, must expect B to 40 DEG C;
3) zinc ion-porphyrin nano complex compound is added in material B, stirs 30min, obtain functional form foliar fertilizer.
Embodiment 3
A kind of functional form foliar fertilizer is as made from the raw material of following parts by weight:20 parts of urea, 2 parts of sodium selenite, four
10 parts of eight Boratex of water, 15 parts of potassium dihydrogen phosphate, 8 parts of fulvic acid, 15 parts of trace element, 5 parts of garlic polysaccharide, pulullan polysaccharide 4
Part, 6 parts of polyglutamic acid, 0.6 part of disodium ethylene diamine tetraacetate, 0.3 part of methyl α-naphthyl acetate, zinc ion -0.2 part of porphyrin nano complex compound,
50 parts of water.
Described, zinc ion-porphyrin nano complex compound is prepared using following methods:By 10ml acetic acid zinc solutions
It is added to together with the acetum of four pyridylporphyrins of 1.5ml0.05mmol/L in reaction bulb, 30 DEG C are stirred to react 10h, obtain
Zinc ion-porphyrin nano complex compound.
Described, the concentration of acetic acid zinc solution is 1.5mol/L.
Described, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.05:0.1:0.3:1.2 weight ratio composition.
Preferably, trace element is by zinc-amino acid chelate, chelating amino acids molybdenum, chelating amino acids manganese, chelating amino acids
Iron and chelating amino acids boron are according to 1:0.08:0.15:0.2:1 weight ratio composition.
Described, the molecular weight of polyglutamic acid is ten thousand dalton of 5-10.
A kind of preparation method of functional form foliar fertilizer, is as made from following steps:
1) urea, sodium selenite, four water, eight Boratex, potassium dihydrogen phosphate, fulvic acid and trace element are added in water, mixed
It closes uniformly, must expect A;
2) garlic polysaccharide, pulullan polysaccharide, polyglutamic acid, disodium ethylene diamine tetraacetate and methyl α-naphthyl acetate are added in material A, risen
Temperature stirs 0.5h, is cooled to room temperature, must expect B to 30 DEG C;
3) zinc ion-porphyrin nano complex compound is added in material B, stirs 40min, obtain functional form foliar fertilizer.
Comparative example 1
A kind of functional form foliar fertilizer is as made from the raw material of following parts by weight:20 parts of urea, 3 parts of sodium selenite, four
13 parts of eight Boratex of water, 12 parts of potassium dihydrogen phosphate, 10 parts of fulvic acid, 13 parts of trace element, 7 parts of garlic polysaccharide, pulullan polysaccharide 5
Part, 7 parts of polyglutamic acid, 0.5 part of disodium ethylene diamine tetraacetate, 0.2 part of methyl α-naphthyl acetate, 60 parts of water.
Remaining is the same as embodiment 2.
Comparative example 2
A kind of functional form foliar fertilizer is as made from the raw material of following parts by weight:20 parts of urea, 3 parts of sodium selenite, four
13 parts of eight Boratex of water, 12 parts of potassium dihydrogen phosphate, 10 parts of fulvic acid, trace element 13 parts, 0.5 part of disodium ethylene diamine tetraacetate,
0.2 part of methyl α-naphthyl acetate, zinc ion -0.3 part of porphyrin nano complex compound, 60 parts of water.
Remaining is the same as embodiment 2.
Cucumber test
Experimental cultivar:Excellent No. 3 cucumber in Tianjin.
Test site:Tangshan, Hebei Province.
Test period:In November, 2016 in April, 2017.
Experiment work sets 7 processing, is divided into blank control group, control group, embodiment 1-3 and comparative example 1-2.Wherein:
Blank control group uses conventional fertilizer application, does not spray clear water or foliar fertilizer.
Control group sprays 3 clear water using conventional root fertilising+spray clear water, growth animated period, at intervals of 7 days, every time
The amount of spraying is 45kg/ mus.
Embodiment 1-3 and comparative example 1-2 apply fertilizer+sprays embodiment 1-3 and comparative example 1-2 using conventional root and prepares respectively
Functional form foliar fertilizer, growth animated period spray 3 times, at intervals of 7 days, every time the amount of spraying be 100g/ mus, first by work(when spraying
Can type foliar fertilizer and water by 1: 450 proportional arrangement into aqueous solution.
Plant height, fruiting rate, yield and the rate of growth of each group cucumber are counted respectively, and result of the test is as shown in table 1.
1 functional form foliar fertilizer cucumber test result of table
It is found during experiment, the functional form foliar fertilizer cucumber plant growing way for spraying 1-3 of embodiment of the present invention preparations is fast
And it is strong, blade thickens, and leaf dark green is shinny, and the enhancing of plant disease resistance, cucumber bearing pumpkin rate is high, and cucumber melon type is uniformly neat,
Cucumber is in good taste.
The above is only the preferred embodiment of the present invention, it should be pointed out that:For the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (7)
1. a kind of functional form foliar fertilizer, which is characterized in that be as made from the raw material of following parts by weight:20 parts of urea, sub- selenium
Sour sodium 2-4 parts, 10-15 parts of four water, eight Boratex, 10-15 parts of potassium dihydrogen phosphate, 8-12 parts of fulvic acid, 10-15 parts of trace element,
5-9 parts of garlic polysaccharide, 4-6 parts of pulullan polysaccharide, 6-8 parts of polyglutamic acid, 0.4-0.6 parts of disodium ethylene diamine tetraacetate, methyl α-naphthyl acetate
0.1-0.3 parts, zinc ion -0.2-0.4 parts of porphyrin nano complex compound, 50-70 parts of water.
2. functional form foliar fertilizer according to claim 1, which is characterized in that the zinc ion-porphyrin nano complex compound is
It is prepared using following methods:10ml acetic acid zinc solutions and the acetic acid of four pyridylporphyrins of 1.5ml 0.05mmol/L is molten
Liquid is added in reaction bulb together, and 20-30 DEG C is stirred to react 10-20h, obtains zinc ion-porphyrin nano complex compound.
3. functional form foliar fertilizer according to claim 2, which is characterized in that the concentration of the acetic acid zinc solution is 0.5-
1.5mol/L。
4. functional form foliar fertilizer according to claim 1, which is characterized in that the trace element is by chelating amino acids
Zinc, chelating amino acids molybdenum, chelating amino acids manganese, amino acid chelated iron and chelating amino acids boron are according to 1:0.05-0.1:0.1-
0.2:0.1-0.3:The weight ratio composition of 0.8-1.2.
5. functional form foliar fertilizer according to claim 4, which is characterized in that the trace element is by chelating amino acids
Zinc, chelating amino acids molybdenum, chelating amino acids manganese, amino acid chelated iron and chelating amino acids boron are according to 1:0.08:0.15:0.2:1
Weight ratio composition.
6. functional form foliar fertilizer according to claim 1, which is characterized in that the molecular weight of the polyglutamic acid is 5-10 ten thousand
Dalton.
7. the preparation method of functional form foliar fertilizer any one of a kind of claim 1-6, which is characterized in that be by following
Made from step:
1) urea, sodium selenite, four water, eight Boratex, potassium dihydrogen phosphate, fulvic acid and trace element are added in water, mixing is equal
It is even, it must expect A;
2) garlic polysaccharide, pulullan polysaccharide, polyglutamic acid, disodium ethylene diamine tetraacetate and methyl α-naphthyl acetate are added in material A, are warming up to
30-50 DEG C, 0.5-1.5h is stirred, room temperature is cooled to, must expect B;
3) zinc ion-porphyrin nano complex compound is added in material B, stirs 20-40min, obtain functional form foliar fertilizer.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109336665A (en) * | 2018-12-05 | 2019-02-15 | 新乡博凯生物技术有限公司 | A kind of foliar fertilizer promoting potato production promoting |
CN109329019A (en) * | 2018-10-10 | 2019-02-15 | 广西壮族自治区林业科学研究院 | A kind of method of water planting Moringa vegetables |
CN109734521A (en) * | 2019-03-18 | 2019-05-10 | 赤峰学院 | A kind of fertilizing method for vegetables mineral nutrition balance |
CN110041124A (en) * | 2019-04-23 | 2019-07-23 | 浙江工业大学 | A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc |
CN112640744A (en) * | 2020-12-04 | 2021-04-13 | 常德市农林科学研究院 | Cultivation method for preventing freeze injury of brassica chinensis bolts |
CN112679264A (en) * | 2021-01-14 | 2021-04-20 | 安徽卓砺环保科技有限公司 | Fertilizer function synergist and application thereof |
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CN110041124A (en) * | 2019-04-23 | 2019-07-23 | 浙江工业大学 | A kind of dedicated zinc-rich nutrient liquid of rice and its method for producing rice rich in zinc |
CN112640744A (en) * | 2020-12-04 | 2021-04-13 | 常德市农林科学研究院 | Cultivation method for preventing freeze injury of brassica chinensis bolts |
CN112679264A (en) * | 2021-01-14 | 2021-04-20 | 安徽卓砺环保科技有限公司 | Fertilizer function synergist and application thereof |
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