CN109208328A - 含水织物柔软组合物 - Google Patents
含水织物柔软组合物 Download PDFInfo
- Publication number
- CN109208328A CN109208328A CN201710552417.2A CN201710552417A CN109208328A CN 109208328 A CN109208328 A CN 109208328A CN 201710552417 A CN201710552417 A CN 201710552417A CN 109208328 A CN109208328 A CN 109208328A
- Authority
- CN
- China
- Prior art keywords
- component
- polyoxyethylene ether
- composition
- acid
- chain
- Prior art date
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- Granted
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- 239000004744 fabric Substances 0.000 title claims abstract description 45
- 150000001875 compounds Chemical class 0.000 title abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 87
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 43
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 43
- -1 polyoxyethylene chain Polymers 0.000 claims abstract description 28
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims description 15
- 150000001412 amines Chemical class 0.000 claims description 15
- 238000002360 preparation method Methods 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 12
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 11
- XIRNKXNNONJFQO-UHFFFAOYSA-N ethyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC XIRNKXNNONJFQO-UHFFFAOYSA-N 0.000 claims description 10
- 239000003760 tallow Substances 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 150000003866 tertiary ammonium salts Chemical class 0.000 claims description 6
- 229940067592 ethyl palmitate Drugs 0.000 claims description 5
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 claims description 5
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 claims description 4
- 230000021736 acetylation Effects 0.000 claims description 4
- 238000006640 acetylation reaction Methods 0.000 claims description 4
- 150000001450 anions Chemical class 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 125000004494 ethyl ester group Chemical group 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- BKPHIEZQGNMZNZ-UHFFFAOYSA-N 2-hydroxyethyl methyl sulfate;methanamine Chemical compound NC.COS(=O)(=O)OCCO BKPHIEZQGNMZNZ-UHFFFAOYSA-N 0.000 claims description 3
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 3
- 239000002979 fabric softener Substances 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 3
- 238000005984 hydrogenation reaction Methods 0.000 claims description 3
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 claims description 2
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 claims description 2
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 claims description 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 2
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 235000009508 confectionery Nutrition 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- 229940100242 glycol stearate Drugs 0.000 claims description 2
- 238000009940 knitting Methods 0.000 claims description 2
- 229920000059 polyethylene glycol stearate Polymers 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 18
- 230000008859 change Effects 0.000 abstract description 5
- 238000010276 construction Methods 0.000 abstract description 3
- 238000003860 storage Methods 0.000 abstract description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 32
- 239000000796 flavoring agent Substances 0.000 description 16
- 235000013355 food flavoring agent Nutrition 0.000 description 16
- 239000002585 base Substances 0.000 description 11
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 239000010445 mica Substances 0.000 description 10
- 229910052618 mica group Inorganic materials 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 235000019441 ethanol Nutrition 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 239000003086 colorant Substances 0.000 description 8
- 239000000049 pigment Substances 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 7
- CDOSHBSSFJOMGT-UHFFFAOYSA-N beta-linalool Natural products CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 7
- 150000001721 carbon Chemical group 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- BANXPJUEBPWEOT-UHFFFAOYSA-N 2-methyl-Pentadecane Chemical compound CCCCCCCCCCCCCC(C)C BANXPJUEBPWEOT-UHFFFAOYSA-N 0.000 description 6
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 229910044991 metal oxide Inorganic materials 0.000 description 6
- 150000004706 metal oxides Chemical class 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 6
- 230000002335 preservative effect Effects 0.000 description 6
- 239000011049 pearl Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 4
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 4
- 239000006184 cosolvent Substances 0.000 description 4
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 235000013399 edible fruits Nutrition 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000006081 fluorescent whitening agent Substances 0.000 description 4
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 4
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 4
- 229930007744 linalool Natural products 0.000 description 4
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 3
- 229940043268 2,2,4,4,6,8,8-heptamethylnonane Drugs 0.000 description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical class COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
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- KUVMKLCGXIYSNH-UHFFFAOYSA-N isopentadecane Natural products CCCCCCCCCCCCC(C)C KUVMKLCGXIYSNH-UHFFFAOYSA-N 0.000 description 3
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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Abstract
本发明涉及一种含水织物柔软组合物，该组合物同时具有良好的柔软效果、存储稳定性、抗静电效果、分散性和易用性。本发明组合物中使用的乳化剂脂肪胺聚氧乙烯醚是一种特殊结构的可生物降解的表面活性剂，调节其中烷基链和聚氧乙烯链的长度可以改变脂肪胺聚氧乙烯醚的表面活性特性。本发明中加入的脂肪胺聚氧乙烯醚可以明显改善组合物的稳定性；并且相对于脂肪醇乙氧基化物，改善稳定性的效率更高，效果更好。此外，本发明使用非离子柔软剂可以明显提高组合物的柔软性能。
Description
技术领域
本发明涉及一种含水织物柔软组合物，该组合物同时具有良好的柔软效果、存储稳定性、抗静电效果、分散性和易用性。
背景技术
柔软剂组合物的粘度需要保持在一个合适的范围内。粘度偏高，产品不易倾倒；粘度偏低，产品不易计量，容易倒多。因此粘度偏低或者偏高都会影响产品的使用便利性。
CN 1258313A记载了织物柔软剂组合物，其包含1％-20％(重量)的季铵二酯织物软化剂以及共用的单硬脂酸甘油酯，以及作为乳化剂的脂肪醇乙氧基化物非离子表面活性剂，该乳化剂的HLB值高于7.5。
CN 102869757A记载了非离子柔软助剂与仅仅具有一个长链烃基的阳离子表面活性剂组合物。其中组分A阳离子表面活性剂是单长链的叔胺盐或者季铵盐，组分B非离子柔软剂仅仅具有一个键合到具有至少一个游离羟基的极性基团上的长链烃基，不包括脂肪醇烷氧基化物或者脂肪酸烷氧基化物，并且如果组分A和组分B的摩尔比是2:1至1:3，则表现出良好的柔软作用和形成存储稳定的分散体。但该专利中更关注的是组合物的柔软性能，并没有关注所述组合物的粘度大小以及粘度的变化情况。
从现有技术来看，开发保持现有产品优异柔软性能的前提下具有进一步提高的稳定性的产品仍是十分必要的。
发明内容
本发明的目的是提供一种织物柔软组合物，该组合物不仅具有良好的柔软性能，而且加入特定结构的乳化剂使组合物的稳定性进一步得到了改善。
本发明提供了一种织物柔软组合物，其包括如下组分：
1)组分A是如下式(1)所示的脂肪酯季铵盐或者叔胺盐：
其中，R1为含有9-21个碳原子的脂肪族烃基；
R2、R3可以相同或者不同，彼此独立地选自-C(O)OR、-ZC(O)R、苄基、苯基、OH或者H，其中R选自C10-22支链或直链烷基；
R4选自OH或者H；
b选自1-3的整数；
当R2、R3、R4为H时，c、d和e可以相同或者不同，彼此独立地选自0-3的整数；当R2、R3、R4不为H时，c、d和e可以相同或者不同，彼此独立地选自1-3的整数；
X是化合价为a的阴离子，例如X-a可以为Br-、Cl-、CH3SO4 -或CH3CH2SO4 -；
2)组分B为乳化剂，选自脂肪胺聚氧乙烯醚中的一种或者多种；和
3)溶剂。
根据本发明，组分A的用量可以为2.5％-25％(重量)，组分B的用量可以为0.2％-5％(重量)，余量为溶剂。
根据本发明，式(1)中，R2和R3中至少有一个选自-C(O)OR或-OC(O)R，其中R为C10-22支链或直链烷基。优选地，R1为含有15-21个碳原子的脂肪族烃基；R2和R3中一个选自-C(O)OR或-OC(O)R，其中R为C16-22支链或直链烷基，另一个选自OH；R4选自H。
还优选地，R1为含有15-21个碳原子的脂肪族烃基，b＝2；R2选自-OC(O)R，其中R为C16-22支链或直链烷基，c＝2；R3选自OH，d选自1-3的整数；R4选自H，e选自1-3的整数。
进一步优选地，组分A为双C16-22脂肪酸乙酯基羟乙基甲基硫酸甲酯铵，还进一步优选地，组分A为双棕榈酸乙酯基羟乙基甲基硫酸甲酯铵。
根据本发明，所述组分B选自C8-22烷基胺聚氧乙烯醚(EO＝5-50)中的一种或多种，其中所述烷基链可以含有双键，优选双键的数目不大于3。
例如，组分B选自辛胺聚氧乙烯醚(EO＝10-40)、癸胺聚氧乙烯醚(EO＝10-40)、十二胺聚氧乙烯醚(EO＝10-40)、十四胺聚氧乙烯醚(EO＝10-40)、十六胺聚氧乙烯醚(EO＝10-40)、十八胺聚氧乙烯醚(EO＝10-40)、油胺聚氧乙烯醚(EO＝10-40)、二十胺聚氧乙烯醚(EO＝10-40)、二十二胺聚氧乙烯醚(EO＝10-40)、牛脂胺聚氧乙烯醚(EO＝10-40)、双氢化牛脂胺聚氧乙烯醚(EO＝10-40)中的一种或多种。更优选地，组分B选自牛脂胺聚氧乙烯醚(EO＝10-40)或十四胺聚氧乙烯醚(EO＝10-40)中的一种或多种。
根据本发明，组分B脂肪胺聚氧乙烯醚是一种特殊结构的可生物降解的表面活性剂，调节烷基链和聚氧乙烯链的长度可以改变脂肪胺聚氧乙烯醚的表面活性。
根据本发明，所述溶剂可以为水。
根据本发明，所述织物柔软组合物中还可以包括组分C，组分C为非离子柔软剂。
根据本发明，所述组分C选自脂肪酸与C2-6二醇或者C3-9多元醇反应生成的单酯或双酯、C2-10一元、二元、三元脂肪酸或C2-10脂肪酸的酸酐与C14-22烷基酸单甘酯反应得到的有机酸单甘酯、C14-22长链脂肪醇中的一种或多种。优选地，组分C选自烷基酸甘油酯、烷基酸乙二醇酯、失水山梨醇脂肪酸酯、乙酰化单甘酯、琥珀酸单甘酯、柠檬酸单甘酯、十六醇、十八醇中的一种或多种。更优选地，组分C选自硬脂酸甘油酯、油酸甘油酯、硬脂酸乙二醇酯、失水山梨醇硬脂酸酯、乙酰化单甘油硬脂酸酯、琥珀酸单甘油硬脂酸酯、柠檬酸单甘油硬脂酸酯、十六醇、十八醇中的一种或多种。
根据本发明，所述组分的用量为0.1％-8％(重量)。
根据本发明，所述织物柔软组合物中还可以包括助溶剂。
根据本发明，所述助溶剂选自短碳链的醇如乙醇、异丙醇、乙二醇、丙二醇、甘油，或醇醚如二丙二醇甲醚、三丙二醇甲醚、三丙二醇丁醚、二乙二醇丁醚中的一种或多种。进一步优选地，所述助溶剂为乙醇、异丙醇、乙二醇、甘油中的一种或多种，更进一步优选为甘油。
根据本发明，所述助溶剂的用量为0.05％-10％(重量)。
根据本发明，所述织物柔软组合物还可以包括香味剂。
根据本发明，所述香味剂选自香精、具有香味的物质、具有特殊气味的物质中的一种或多种。
根据本发明，所述香味剂可以为微胶囊。
根据本发明，所述香味剂的用量可以为0.01％-3％(重量)。
根据本发明，所述织物柔软组合物还可以包括常用于织物柔软组合物中的其他组分，以便于增加本发明含水织物柔软组合物的外观或者其他性能。
根据本发明，所述其他组分包括但不限于如下中的一种或多种：着色剂例如染料或者颜料，防腐剂，杀菌剂，抗氧化剂，荧光增白剂，流变改性剂，珠光剂，pH调节剂。
根据本发明，所述其他组分的用量可以为0.001-1.5％(重量)。
根据本发明，无论最终产品是浓缩型或者普通型，均应是在最终应用时易于倾倒的、粘度稳定的。通常的，本发明所述织物柔软组合物的粘度为400cP以下，优选为150cP-300cP。
本发明还提供如上所述织物柔软组合物的制备方法，包括如下步骤：将组分A和组分B加入到溶剂中，搅拌后冷却即得到本发明的组合物。
根据本发明，所述组分A、B、溶剂具有如上所述的定义。
根据本发明，所述溶剂在加入组分A和组分B前需加热到50-70摄氏度，例如加热到62摄氏度。
根据本发明，加入组分A和组分B后可以搅拌1-100min，例如搅拌15min。
当本发明的织物柔软组合物中还包含如上所述组分C时，所述制备方法中包括将组分C与组分A和组分B同时加入溶剂中的步骤。
当本发明的织物柔软组合物中还包括如上所述香味剂和/或其他组分时，如上所述制备方法中还包括加入香味剂和/或其他组分继续搅拌得到本发明组合物的步骤。
根据本发明，加入香味剂和/或其他组分时反应液的温度可以为30-50摄氏度，例如40摄氏度。
根据本发明，加入香味剂和/或其他组分后可继续搅拌1-100min，例如搅拌10min。
根据本发明，所述香味剂可以微胶囊形式加入。
本发明还提供如上所述织物柔软组合物的用途，其用于织物柔软处理。具体的，所述组合物为液体的织物柔软剂，用于织物柔软处理。
本发明的有益效果：
1)本发明中使用的组分B，即脂肪胺聚氧乙烯醚是一种特殊结构的可生物降解的表面活性剂，调节其中烷基链和聚氧乙烯链的长度可以改变脂肪胺聚氧乙烯醚的表面活性特性。本发明中加入的脂肪胺聚氧乙烯醚可以明显改善组合物的稳定性；并且相对于脂肪醇乙氧基化物，改善稳定性的效率更高，效果更好。
2)当本发明的织物柔软组合物中使用组分C非离子柔软剂时，组分C可以明显提高组合物的柔软性能。
具体实施方式
[组分A]
作为实例，本发明式(1)所示的脂肪酯季铵盐或者叔胺盐结构中R2、R3不同时为-C(O)OR或-OC(O)R，其中R选自C10-22支链或直链烷基，即式(1)可以具有如下所示的结构：
其中，R1为含有9-21个碳原子的脂肪族烃基；
R2、R3其中一个基团选自苄基、苯基、OH或者H；
R4选自OH或者H；
b选自1-3的整数；
当R4、R2和R3其中一个为H时，c、d和e可以相同或者不同，彼此独立地选自0-3的整数；当R2、R3、R4不为H时，c、d和e可以相同或者不同，彼此独立地选自1-3的整数；
X是化合价为a的阴离子，例如X-a可以为Br-、Cl-、CH3SO4 -或CH3CH2SO4 -。
例如，式(1)中，R2和R3中至少有一个选自-C(O)OR或-OC(O)R，其中R选自C10-22支链或直链烷基。优选地，R1为含有15-21个碳原子的脂肪族烃基；R2和R3中一个选自-C(O)OR或-OC(O)R，其中R选自C16-22支链或直链烷基，另一个选自OH；R4选自H。
还优选地，R1为含有15-21个碳原子的脂肪族烃基，b＝2；R2选自-OC(O)R，其中R选自C16-22支链或直链烷基，c＝2；R3选自OH，d选自1-3的整数；R4选自H，e选自1-3的整数。
进一步优选地，组分A为双C16-22脂肪酸乙酯基羟乙基甲基硫酸甲酯铵，还进一步优选地，组分A为双棕榈酸乙酯基羟乙基甲基硫酸甲酯铵。
作为另一个实例，本发明式(1)所示的脂肪酯季铵盐或者叔胺盐结构中R2、R3同时为-C(O)OR或-OC(O)R，其中R选自C10-22支链或直链烷基，即式(1)可以具有如下所示的结构：
其中，R1为含有9-21个碳原子的脂肪族烃基；
R4选自OH或者H；
b、c、d可以相同或者不同，彼此独立地选自1-3的整数；当R4为OH时，e可以选自1-3的整数；当R4为H时，e可以选自0-3的整数；
X是化合价为a的阴离子，例如X-a可以为Br-、Cl-、CH3SO4 -或CH3CH2SO4 -。[香味剂]
本发明的香味剂包括但不限于：草本香剂，如薄荷香、留兰香、迷迭香、百里香、鼠尾草和原子松树、云杉和其他具有森林气味的树木；水果香剂，如苹果、杏仁、葡萄、樱桃、菠萝、梨、水蜜桃、芒果、橘子、草莓、蓝莓、柑橘；花香剂，如玫瑰样、薰衣草样、康乃馨样；以及香草、栀子、山楂、素心兰、金银花、仙客来、风信子、蕨菜、丁香、茉莉、百合、含羞草、木兰花、兰花、水仙花、橙花、甘草、木犀草绿、车轴草、紫罗兰、甜豌豆、桂竹香等等(“PerfumesCosmetics and Soaps”第二版，1959年由W.A.Poucher出版)、香叶醇乙酸酯、里哪醇乙酸酯、香芹酚、乙酸异冰片酯、四氢月桂烯醇、衣兰烯、乙酸香根酯、西藏麝香、粉檀麝香、麝香茚满酮、α-檀香醇、苯基庚醇、苯甲酸苯乙基酯、苯乙酸苯乙基酯、10-氧杂十六内酯、11-氧杂十六内酯、1-(1,1-二甲基乙基)-3,4,5-三甲氧基-2,6-二硝基苯、g-n-紫罗兰酮、甲基二氢茉莉酮、沉香基苯甲酸酯、α-鸢尾酮、水杨酸己酯、水杨酸环己酯、水杨酸己烯酯、己基肉桂醛、十六烷内酯、苯乙酸香叶酯、邻氨基苯甲酸香叶酯、十一烯酸乙酯、十二内酯、巴亚基酸次乙酯、二苯醚、二苯基甲烷、仙客来醛、肉桂酸肉桂酯、甲酸柏木酯、乙酸柏木酯、乙酸乙酯、乙酰乙酸乙酯、甲位己基桂醛、丙酸苄酯、雪松醇、杜松烯、β-石竹烯、异丁基喹啉、对-叔丁基环己基乙酸酯、水杨酸苄酯、水杨酸异戊酯、戊基肉桂醛、戊基肉桂醛二甲缩醛、肉桂酸戊酯、苯甲酸戊酯、麝香梨内酯、环己烷丙酸烯丙酯、香豆素、香兰素、丁子香酚、异丁子香酚、肉桂酸甲酯、β-甲基-萘基酮、d-十一烷酸内酯、香草醛、二氢茉莉酮酸甲酯、二氢月桂烯醇、香叶醇、左旋香茅醇、右旋香茅醇、消旋香茅醇、羟基香茅醛、铃兰醛、芳樟醇、乙酸苄酯、苯甲醛、左旋香芹酮、橙花醇、里哪醇、苯乙醇、苯基己醇、α-萜品醇、肉豆蔻醚、麝香酮等等。
优选地，所述香味剂可以选自苯乙醇、己基肉桂醛、左旋香茅醇、右旋香茅醇、松油醇、羟基香茅醛、铃兰醛、芳樟醇、香叶醇、香兰素、乙酸乙酯、乙酰乙酸乙酯、乙酸苄酯、二氢月桂烯醇、甲位己基桂醛、丙酸苄酯、g-n-紫罗兰酮中的一种或多种。
上述优选地香味剂，具有较好的挥发性能，作为主香剂使用时，可以提供良好的香料效果和香味体验。所述香味剂的加入量可以为0.01％-3％(重量)。
如上所述香味剂可以根据组合物的制备需要做成不同剂型，例如制成微胶囊。
[常用于织物柔软组合物中的其他组分]
本发明中着色剂例如染料或者颜料选自直接染料或者直接颜料，所述直接染料或者直接颜料的含量足以提供着色，适宜的染料或者颜料包括但不限于：各种颜色的酸性染料、各种颜色的碱性染料、以及4-硝基邻苯二胺、2-硝基对苯二胺、4-氨基-3-硝基苯酚、2-氨基-6-氯-4-硝基苯酚、4-硝基苯基氨基乙酸脲、6-硝基-2,5-吡啶二胺、喹酞酮或2-茚二酮的一磺酸和二磺酸混合物的钠盐、2-羟基-1,4-萘醌、指甲花红、靛蓝、胭脂虫红以及它们的混合物。所述着色剂的加入量可以为0.001％-0.1％(重量)。
本发明中所述防腐剂选自尼泊金甲酯、尼泊金乙酯、尼泊金丙酯、尼泊金异丙酯、尼泊金丁酯、尼泊金异丁酯、卡松、2-甲基-4-异噻唑啉-3-酮、3-碘-2-丙炔基丁基氨基甲酸酯、二羟甲基海因、布罗波尔中的一种或多种的混合物。所述防腐剂的加入量可以为0.001％-0.5％(重量)。
本发明中所述杀菌剂选自苯甲酸钠、山梨酸钾、银离子杀菌剂、烷基吡啶盐酸盐、苯并三氮唑或硝基吡啶中的一种或多种。所述杀菌剂的加入量可以为0.1％-1.2％(重量)。
本发明中所述抗氧化剂选自抗坏血酸、2,6-二叔丁基-4-甲基酚(BHT)、丁基羟基苯甲醚(BHA)、生育酚和没食子酸丙酯中的一种或多种。所述抗氧化剂的加入量可以为0.1％-1.0％(重量)。
本发明中所述荧光增白剂选自二苯乙烯联苯型，三嗪基氨基均二苯代乙烯型，二(1,2,3-三唑-2-基)均二苯代乙烯型，二(苯并呋喃-2-基)联苯，1,3-二苯基-2-吡唑啉和香豆素型的一种或多种。所述的荧光增白剂均为磺化产物，以其碱金属盐形式存在，优选包含但不限于二苯乙烯基型化合物，如4,4’-双(2-磺酸钠苯乙烯基)联苯、双三嗪基二苯乙烯衍生物中的一种或多种。所述荧光增白剂的加入量可以为0.001％-0.5％(重量)。
本发明中所述流变改性剂用来增加组合物的亲和性，并且还可用作成膜剂，包括但不限于如下中的一种或多种：丙烯酰胺/丙烯酸铵共聚物(和)聚异丁烯(和)聚山梨酸酯20；丙烯酰胺/丙烯酰牛磺酸钠共聚物/异十六烷/聚山梨酸酯80；丙烯酸酯共聚物；丙烯酸酯/山嵛醇聚醚-25甲基丙烯酸酯共聚物；丙烯酸酯/丙烯酸C10-C30烷基酯交联聚合物；丙烯酸酯/硬脂基聚氧乙烯醚-20衣康酸酯共聚物；聚丙烯酸铵/异十六烷/PEG-40蓖麻油；C12-16烷基PEG-2羟丙基羟乙基乙基纤维素(HM-EHEC)；卡波姆；交联的聚乙烯吡咯烷酮(PVP)；二亚苄基山梨醇；羟乙基乙基纤维素(EHEC)；羟丙基甲基纤维素(HPMC)；羟丙基甲基纤维素(HPMC)；羟丙基纤维素(HPC)；甲基纤维素(MC)；甲基羟乙基纤维素(MEHEC)；PEG-150/癸醇/SMDI共聚物；PEG-150/硬脂醇/SMDI共聚物；聚丙烯酰胺/C13-14异链烷烃/月桂基聚氧乙烯醚-7；聚丙烯酸酯13/聚异丁烯/聚山梨酸酯20；聚丙烯酸酯交联聚合物-6；聚酰胺-3；聚季铵盐-37(和)氢化的聚癸烯(和)十三烷基聚氧乙烯醚-6；聚氨酯-39；丙烯酸钠/丙烯酰二甲基牛磺酸盐/二甲基丙烯酰胺；交联聚合物(和)异十六烷(和)聚山梨酸酯60；聚丙烯酸钠。所述流变改性剂的加入量可以为0.01％-1.5％(重量)。
本发明中所述珠光剂为结晶的或玻璃质固体，能够反射和折射光线以产生珠光效果的透明或半透明化合物。通常，珠光剂为结晶的颗粒，在掺入了它们的组合物中是不溶解的。优选地，珠光剂具有薄片或球体的形状。根据本发明，球体被理解为一般的球形。粒度跨过球体的最大直径测量。片状颗粒是指颗粒的两个尺寸(长度和宽度)为第三个尺寸(深度或厚度)的至少5倍。其它晶形，如立方体或针状体或其它晶形，不显示珠光效果。许多珠光剂如云母是具有单斜结晶的天然矿物。形状似乎影响试剂的稳定性。球形，甚至更优选地片状试剂，是最成功地稳定化的。
所述珠光剂优选具有小于50μm的D0.99(有时称为D99)体积粒度。更优选地，所述珠光剂具有小于40μm，最优选小于30μm的D0.99。最优选地，颗粒具有大于1μm的体积粒度。最优选地，所述珠光剂具有0.1μm至50μm，更优选0.5μm至25μm，并且最优选1μm至20μm的粒度分布。所述D0.99为粒度相对于粒度分布的量度，并且在这种情况下是指99％的所述颗粒具有小于50μm的体积粒度。使用可得自Malvern Instruments Ltd.的Hydro2000G设备来测量体积粒度和粒度分布。粒度具有稳定所述试剂的作用。粒度和分布越小，它们将越容易被悬浮。然而，减小珠光剂的粒度也将降低试剂的功效。
不受理论的约束，申请人相信在珠光剂和其所悬浮的液体介质的界面处的光线的传输取决于受Fresnel公式支配的物理定律。被珠光剂反射的光线的比例随着在珠光剂和液体介质之间的折射指数差异的增加而增加。其余的光线将根据能量守恒而折射，并且穿过液体介质传输直至其遇到另一个珠光剂表面。因此，为了使包含珠光剂的组合物赋予可见的珠光，据信在折射指数方面的差异必须足够高，以使充足的光线的反射与被折射的光线的量成比例。
包含较少水和较多有机溶剂的液体组合物与包含更多水的组合物相比通常将具有更高的折射指数。因此申请人已发现，在此类具有高折射率的组合物中，折射率不够高的珠光剂不会赋予足够的可见珠光，即使在所述组合物中以高含量被引入(通常超过3％)。因此，优选使用具有高折射率的珠光颜料，以便将所述制剂中的颜料含量保持在相当低的水平。因此，优选选择珠光剂，使其具有超过1.41，更优选超过1.8，甚至更优选超过2.0的折射指数。优选地，在珠光剂和然后添加了珠光剂的组合物或介质之间的折射指数的差异为至少0.02。优选地，在珠光剂和组合物之间的折射指数的差异为至少0.2，更优选至少0.6。申请人已发现，试剂的折射指数越高，试剂在产生珠光效果方面将越有效。然而，该效果还取决于试剂和组合物折射指数上的差异。差异越大，感觉到的效果就越大。
所述珠光剂可以是有机或者无机的。所述无机珠光剂包括选自由下列组成的组的那些：云母、金属氧化物涂层的云母、二氧化硅涂层的云母、氯氧化铋涂层的云母、氯氧化铋、肉豆蔻酸十四烷基酯、玻璃、金属氧化物涂层的玻璃、鸟嘌呤、闪光剂(聚酯或金属)、以及它们的混合物。合适的云母包括白云母或氟羟钾铝。云母片优选地用薄的金属氧化物层涂层。优选的金属氧化物选自由下列组成的组：金红石、二氧化钛、氧化铁、氧化锡、氧化铝、以及它们的混合物。结晶的珠光层通过在约732℃煅烧用金属氧化物涂层的云母形成。所述热量产生不溶于树脂的惰性颜料，具有稳定的颜色，并能够经受后续加工的热应力。这些珠光剂中的颜色通过在金属氧化物层的顶部和底部表面以镜面反射角反射的光线之间的干涉作用而显现。当视角转换到非镜面反射角时，试剂损失颜色强度并提供珠光外观。
更优选的无机珠光剂选自由下列组成的组：云母和氯氧化铋以及它们的混合物。最优选的无机珠光剂是云母。
所述有机珠光剂，如乙二醇一硬脂酸酯和乙二醇二硬脂酸酯，仅当所述组合物在运动时提供珠光。
因此，仅当所述组合物被倾倒时，所述组合物才表现出珠光。由于提供动态和静态珠光，因此无机珠光材料是优选的。所谓动态珠光是指当所述组合物在运动时组合物表现出珠光效果。所谓静态珠光是指当所述组合物为静态时组合物表现出珠光。所述珠光剂的加入量可以为0.001％-0.2％(重量)。
本发明中所述pH调节剂可以使用任何已知的pH调节剂，包括无机类型或有机类型的碱度来源以及酸化试剂。
无机碱度来源包括但不限于：水溶性碱金属氢氧化物、氧化物、碳酸盐、碳酸氢盐、硼酸盐、硅酸盐、偏硅酸盐、以及它们的混合物；水溶性碱土金属氢氧化物、氧化物、碳酸盐、碳酸氢盐、硼酸盐、硅酸盐、偏硅酸盐、以及它们的混合物；水溶性硼族金属氢氧化物、氧化物、碳酸盐、碳酸氢盐、硼酸盐、硅酸盐、偏硅酸盐、以及它们的混合物；以及它们的混合物。优选的无机碱度来源为氢氧化钠、和氢氧化钾以及它们的混合物，最优选地无机碱度来源为氢氧化钠。虽然因为生态学原因是不优选的，但可使用水溶性磷酸盐作为碱度来源，包括焦磷酸盐、正磷酸盐、聚磷酸盐、膦酸盐、以及它们的混合物。
有机碱度来源包括但不限于：伯胺、仲胺、叔胺、以及它们的混合物。
其它有机碱度来源为链烷醇胺、或链烷醇胺的混合物。合适的链烷醇胺可选自低级链烷醇一链烷醇胺、二链烷醇胺和三链烷醇胺，诸如单乙醇胺；二乙醇胺或三乙醇胺。高级链烷醇胺具有更高的分子量，并且就本发明目的而言，可能质量效率更低。因为质量效率原因，优选一链烷醇胺和二链烷醇胺。尤其优选单乙醇胺，然而在某些实施例中，可使用另外的链烷醇胺诸如三乙醇胺作为缓冲剂。本文所用的最优选的链烷醇胺为单乙醇胺。
无机酸化剂包括但不限于：HF、HCl、HBr、HI、硼酸、磷酸、膦酸、硫酸、磺酸、以及它们的混合物。优选的无机酸化剂是硼酸。
有机酸化剂包括但不限于：柠檬酸、取代和取代的、支链、直链和/或环状的C1至C30的羧酸、以及它们的混合物。
下文将结合具体实施例对本发明的通式化合物及其制备方法和应用做更进一步的详细说明。下列实施例仅为示例性地说明和解释本发明，而不应被解释为对本发明保护范围的限制。凡基于本发明上述内容所实现的技术均涵盖在本发明旨在保护的范围内。
除非另有说明，以下实施例中使用的原料和试剂均为市售商品，或者可以通过已知方法制备。
在本发明中，除非特别指出，所有粘度值均是在20-25℃下采用Brookfield RVTD数字粘度计，2号转子在转速为30rpm条件下测定的。
实施例2-7和对比例1-4中的“二酯季铵盐”是指双棕榈酸乙酯基羟乙基甲基硫酸甲酯铵，“叔胺盐”是指双棕榈酸乙酯基羟乙基叔胺硫酸盐，“适量”是指参考实施例1的用量及在上述给出的各组分的用量范围内适量添加。
实施例1
本实施例按照如下表1的组分制备含水织物柔软组合物。
将水加热至62℃，加入二酯季铵盐、牛脂胺聚氧乙烯醚(EO＝15)、失水山梨醇硬脂酸酯，持续搅拌15min。加入部分常温水(约20％(重量))，继续搅拌降温至40℃，加入香味剂、着色剂、防腐剂，补充剩余水，10min后停止搅拌得到产品。
表1
| 组分 | 重量百分比(％) |
| 二酯季铵盐 | 8.6 |
| 失水山梨醇硬脂酸酯 | 1.2 |
| 牛脂胺聚氧乙烯醚(EO＝15) | 0.5 |
| 香味剂 | 0.5 |
| 着色剂 | 0.002 |
| 防腐剂 | 0.2 |
| 水 | 加至100 |
实施例2-6
参考实施例1的制备方法，实施例2-6按照如下表2的组分制备含水织物柔软组合物。
表2
实施例7-11
参考实施例1的制备方法，实施例7-11按照如下表3的组分制备含水织物柔软组合物。
表3
对比例1
参考实施例1的制备方法，本对比例中的含水织物柔软组合物的制备使用12％重量份的二酯季铵盐、0.4％重量份的牛脂胺聚氧乙烯醚(EO＝15)、适量香精、适量着色剂、适量防腐剂及余量水加到100％。
对比例2-7
参考实施例1的制备方法，对比例2-7按照如下表4的组分制备含水织物柔软组合物。
表4
柔软性能测试例
织物材质：针织纯棉白色毛巾，尺寸24×24cm，每块毛巾重约30g。
前处理：用于柔软性能测试的毛巾需要经过前处理去除出厂时附带的整理剂。前处理方法为将针织毛巾放入标准洗衣机中，使用20％(重量)十二烷基醇醚硫酸钠(氢氧化钠调整pH原液至8.5左右)基础洗涤剂按洗衣机标准洗涤程序进行洗涤，洗涤3次，再按照漂洗-脱水模式进行漂洗，重复漂洗直至无泡沫，甩干后取出，室温下悬挂晾干。
样品处理：在2L烧杯中加入1.5L自来水，分别称取0.5g如下表2中的织物柔软组合物组分加到烧杯中并搅拌均匀，制成约0.3g/L的织物柔软组合物溶液；向织物柔软组合物溶液放入2块纯棉白色毛巾，持续搅拌5min，取出后在漂洗器中脱水，自然晾干。
柔软性能评价：选8位经过培训的评价人员做手感评测。柔软性得分从0至5分评分，8位评价人员分别评价2次，16次的评分取平均值，得分越高代表柔软性能越好，测试结果如表5所示。
表5
由表5的结果可知，实施例2-4、实施例5-6加入非离子柔软剂分别相对于没有添加非离子柔软剂的对比例1和对比例5可以明显提高组合物的柔软性能。
粘度稳定性测试例
为了证明脂肪胺聚氧乙烯醚可以维持体系的粘度稳定性，对10种织物柔软组合物进行了高低温老化试验，测试结果如表6所示：
表6
由表6的结果可知，新制备得到添加十四/牛脂胺聚氧乙烯醚的实施例7、8、9、10、11织物柔软组合物分别相对于没有添加乳化剂的对比例2、3、4、6、7产品粘度明显要低。此外，本发明实施例7、8、9、10、11织物柔软组合物在高温或者低温放置后，其粘度变化相较于对比例2、3、4、6、7产品变化不大，因此可以说明烷基胺聚氧乙烯醚具有明显维持体系粘度稳定性的效果，使组合物的稳定性进一步得到了改善。
以上，对本发明的实施方式进行了说明。但是，本发明不限定于上述实施方式。凡在本发明的精神和原则之内，所做的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (10)
1.一种织物柔软组合物，其特征在于，所述组合物包括如下组分：
1)组分A是如下式(1)所示的脂肪酯季铵盐或者叔胺盐：
其中，R1为含有9-21个碳原子的脂肪族烃基；
R2、R3可以相同或者不同，彼此独立地选自-C(O)OR、-OC(O)R、苄基、苯基、OH或者H，其中R选自C10-22支链或直链烷基；
R4选自OH或者H；
b选自1-3的整数；
当R2、R3、R4为H时，c、d和e可以相同或者不同，彼此独立地选自0-3的整数；当R2、R3、R4不为H时，c、d和e可以相同或者不同，彼此独立地选自1-3的整数；
X是化合价为a的阴离子，例如X-a为Br-、Cl-、CH3SO4 -或CH3CH2SO4 -；
2)组分B为乳化剂，选自脂肪胺聚氧乙烯醚中的一种或者多种；和
3)溶剂。
2.如权利要求1所述的织物柔软组合物，其特征在于，组分A的用量为2.5％-25％(重量)，组分B的用量为0.2％-5％(重量)，余量为溶剂。
3.如权利要求1或2所述的织物柔软组合物，其特征在于，式(1)中，R2和R3中至少有一个选自-C(O)OR或-OC(O)R，其中R选自C10-22支链或直链烷基。
4.如权利要求1-3任一项所述的织物柔软组合物，其特征在于，R1为含有15-21个碳原子的脂肪族烃基；R2和R3中一个选自-C(O)OR或-OC(O)R，其中R选自C16-22支链或直链烷基，另一个选自OH；R4选自H。还优选地，R1为含有15-21个碳原子的脂肪族烃基，b＝2；R2选自-OC(O)R，其中R选自C16-22支链或直链烷基，c＝2；R3选自OH，d选自1-3的整数；R4选自H，e选自1-3的整数。进一步优选地，组分A为双C16-22脂肪酸乙酯基羟乙基甲基硫酸甲酯铵，还进一步优选地，组分A为双棕榈酸乙酯基羟乙基甲基硫酸甲酯铵。
5.如权利要求1-4任一项所述的织物柔软组合物，其特征在于，所述组分B选自C8-22烷基胺聚氧乙烯醚(EO＝5-50)中的一种或多种，其中烷基链可以含有双键，优选双键的数目不大于3。
优选地，所述组分B选自辛胺聚氧乙烯醚(EO＝10-40)、癸胺聚氧乙烯醚(EO＝10-40)、十二胺聚氧乙烯醚(EO＝10-40)、十四胺聚氧乙烯醚(EO＝10-40)、十六胺聚氧乙烯醚(EO＝10-40)、十八胺聚氧乙烯醚(EO＝10-40)、油胺聚氧乙烯醚(EO＝10-40)、二十胺聚氧乙烯醚(EO＝10-40)、二十二胺聚氧乙烯醚(EO＝10-40)、牛脂胺聚氧乙烯醚(EO＝10-40)、双氢化牛脂胺聚氧乙烯醚(EO＝10-40)中的一种或多种。
更优选地，组分B选自牛脂胺聚氧乙烯醚(EO＝10-40)或十四胺聚氧乙烯醚(EO＝10-40)中的一种或多种。
6.如权利要求1-5任一项所述的织物柔软组合物，其特征在于，所述溶剂为水。
7.如权利要求1-6任一项所述的织物柔软组合物，其特征在于，所述织物柔软组合物中还包括组分C，所述组分C为非离子柔软剂。
优选地，所述组分C选自脂肪酸与C2-6二醇或者C3-9多元醇反应生成的单酯或双酯、C2-10一元、二元、三元脂肪酸或C2-10脂肪酸的酸酐与C14-22烷基酸单甘酯反应得到的有机酸单甘酯、C14-22长链醇中的一种或多种。更优选地，组分C选自烷基酸甘油酯、烷基酸乙二醇酯、失水山梨醇脂肪酸酯、乙酰化单甘酯、琥珀酸单甘酯、柠檬酸单甘酯、十六醇、十八醇中的一种或多种。进一步优选地，组分C选自硬脂酸甘油酯、油酸甘油酯、硬脂酸乙二醇酯、失水山梨醇硬脂酸酯、乙酰化单甘油硬脂酸酯、琥珀酸单甘油硬脂酸酯、柠檬酸单甘油硬脂酸酯、十六醇、十八醇中的一种或多种。
优选地，所述组分C的用量为0.1％-8％(重量)。
8.权利要求1-7任一项所述的织物柔软组合物的制备方法，其特征在于，所述方法包括如下步骤：将组分A和组分B加入到溶剂中，搅拌后冷却即得到所述组合物。
9.根据权利要求8所述的制备方法，其特征在于，所述溶剂在加入组分A和组分B前需加热到50-70摄氏度，例如加热到62摄氏度。
优选地，加入组分A和组分B后搅拌1-100min，例如搅拌15min。
优选地，当本发明的织物柔软组合物中包含组分C时，所述制备方法中包括将组分C与组分A和组分B同时加入溶剂中的步骤。
10.权利要求1-7任一项所述织物柔软组合物的用途，其特征在于，所述组合物用于织物柔软处理。具体的，所述组合物为液体的织物柔软剂，用于织物柔软处理。
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