CN109172435A

CN109172435A - A kind of bean curd frost and preparation method thereof

Info

Publication number: CN109172435A
Application number: CN201811236578.1A
Authority: CN
Inventors: 黄彩仪; 王丽辉; 林锦雄
Original assignee: Guangzhou I & B Biological Technology Co Ltd
Current assignee: Guangzhou I & B Biological Technology Co Ltd; Guangzhou Aibei Biological Technology Co Ltd
Priority date: 2018-10-23
Filing date: 2018-10-23
Publication date: 2019-01-11
Anticipated expiration: 2038-10-23
Also published as: CN109172435B

Abstract

The invention discloses a kind of bean curd frosts and preparation method thereof; the bean curd frost includes moisturizer, assistant for emulsifying agent, film forming agent, physical sunscreen agent, rheology control agent, and moisturizer includes the compound being made of dried tremella extract, dipropylene glycol, EDETATE SODIUM, the compound being made of Xylitol-based glucoside, anhydro xylitol and xylitol and Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolyzes the compound that Sodium Hyaluronate forms；Physical sunscreen agent is the compound being made of titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane；Levelling regulator is the compound that polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 form, bean curd frost of the invention has sun-proof and moisture-keeping function, and there is very strong elasticity, appearance is seemed just as bean curd, gives people a kind of completely new vision.

Description

A kind of bean curd frost and preparation method thereof

Technical field

The present invention relates to cosmetic technical field, it is specifically related to a kind of bean curd frost and preparation method thereof.

Background technique

With the development of science and technology with the raising of living standards of the people, cosmetics are in people's lives in occupation of increasingly Important position；In recent years, the kind of cosmetics is increasing, functional also increasingly stronger, and being divided into has moisturizing, whitening, prevents The functions such as solarization, anti-oxidant；It is one of pathomechanism of aged appearance that skin water content, which gradually decreases, when the water content of cuticula is low When 10%, there is crack in dry skin, furfur, imbricate keratinocyte layer arranged in parallel, and skin is easy by extraneous ring The erosion of border physical factor, water, electrolyte in skin are also easy evaporation or are lost.Skin moisture-keeping is the barrier for guaranteeing cuticula The most important basic means of function and cosmetology.Moisturizing Journal of Sex Research is the hot spot of current cosmetics and dermatology research. Environmental pollution, Seasonal conversion so that because of caused by cuticula water shortage dry skin and thus caused by skin itch, furfur Increasingly severe etc. common skin problem, moisturizing is very urgent.Moisturizer is added in cosmetics, it is therefore intended that maintain or increase Add the water content of keratoderma, solves these common skin problems to improve.When skin receives ultraviolet light overexposure Afterwards, epidermal cell can be damaged；Tyrosinase is activated, accelerates pigment synthesis, destroys the moisture-keeping functions of skin, skin is made to become dry It is dry, it makes the elastic fibers in skin corium impaired, generates microgroove, under acute irradiation, also will cause skin inflammation, burn.Have When abnormal case, then it will become pigmentosa cutaneum carcinoma etc..After disposable long period ultraviolet light irradiates skin, through a few hours There is more chronic erythema (sunburn) to more than 10 hours skin, color is scarlet, hydroderma, seriously can all play blister.After solarization Erythema reaction in second day peaks, and subsides through one week or so erythema, there is exfoliation and pigmentation, conscious skin burns pain Bitterly, serious person can be with general reaction, such as fever, headache, out of strength, nauseous and general malaise, or even palpitaition, delirium occurs and stop Gram.Generally reach sun-proof result by smearing suncream.Existing moisturizing or sunscreen product generally only have moisture-keeping functions, or Person's sun-screening function, has a single function, and effect is unobvious.

Summary of the invention

It is an object of the invention to overcome the above problem and provide a kind of bean curd frost and preparation method thereof, which has Anti-sunlight function and lasting moistening effect.

To achieve the above object, the technical solution adopted by the present invention is that a kind of bean curd is white, the bean curd frost include moisturizer, Assistant for emulsifying agent, film forming agent, physical sunscreen agent, rheology control agent, the moisturizer include by dried tremella extract, dipropylene glycol, The compound of EDETATE SODIUM composition, the compound being made of Xylitol-based glucoside, anhydro xylitol and xylitol and hyalomitome The compound that sour sodium cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form, it is described to help Emulsifier includes the compound and laruyl alcohol phosphate that polyacrylamide, C13-14 isoparaffin and laureth -7 form Potassium；The film forming agent is polyester -7 and the compound that two enanthic acid neopentyl glycol ester form；The physical sunscreen agent is by titanium dioxide Titanium, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane group At compound；The levelling regulator is that polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 form Compound.

The compound that moisturizer dried tremella extract, dipropylene glycol, the EDETATE SODIUM of selection form is rich in carotenoid, Huang Ketone compounds and polysaccharide (iso- glucan, beta glucan and phlorose) isoreactivity ingredient, can promote AQP-3 and hyalomitome The expression of acid enzyme has moisturizing, anti-oxidant and promotion wound healing and other effects；In addition, the beta glucan wherein contained is also Have effects that improve cutaneous immunisation power and resistant to pollution.Xylitol-based glucoside, anhydro xylitol and xylitol form compound Object is the active constituent of natural botanical source, can moisturizing and rebuild skin texture system, promote GAGs (hyaluronic acid and sulfuric acid Chondroitin) content increase, improves the moisture content of epidermis and corium, promotes ceramide synthesis, reinforce skin barrier and act on, change Kind skin texture, reduces water loss, can be used in various moisturizing formulas.Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, The compound Hymagic-4D of acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition uses 4 heavy water science and technology living, building Three-dimensional water storage spongy layer, the different levels of precise positioning skin, outer layer moisturizing, internal layer water lock, layer by layer moisturizing；It uses very It is convenient, break the application method of traditional Sodium Hyaluronate, three kinds of moisturizing ingredients of the invention are compounded, in moistening effect Aspect has synergistic function；

The physical sunscreen agent that the present invention adds is by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, suddenly The compound (Solaveil XT-40W) of bar seed oil, stearic acid, alum scholar, glycerol caprylate and saualane composition suddenly, mostly Inorganic dispersion liquid is all oil dispersed, will affect the final skin sense of product, and Solaveil XT-40W is the system of water dispersion, It can prepare in water phase, greatly increase the flexibility of o/w formula, spreadability and reduction whiting, Solaveil XT- 40W is green natural, largely reduces the irritation of formula, it has both while with excellent uv blocking A Outstanding uv blocking B, and its TiO 2 particles are by particularly handling, and hydrophobic coating makes particle become the same of waterproof When more smooth feeling is provided, increase persistence and graceful skin sense；Physical sunscreen agent and moisturizer are combined, so that product With anti-sunlight function and lasting moistening effect, then add -7 group of polyacrylamide, C13-14 isoparaffin and laureth At compound, laruyl alcohol phosphate potassium, polyester -7 and two enanthic acid neopentyl glycol ester composition compound, by titanium dioxide, water, What -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane formed answers The compound that conjunction object and polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 form is in certain proportion Composition, so that product has very strong elasticity, appearance is seemed just as bean curd, gives people a kind of completely new vision.

Preferably, moisturizer, assistant for emulsifying agent, film forming agent, physical sunscreen agent, rheology control agent each ingredient in entire beans The content of rotten frost, based on following mass percent: the compound 1 that the dried tremella extract, dipropylene glycol, EDETATE SODIUM form~ 8%, the compound 1~5% that is made of Xylitol-based glucoside, anhydro xylitol and xylitol, be crosslinked by Sodium Hyaluronate it is poly- Close the compound 2~10% of object, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition；Polyacrylamide Amine, laruyl alcohol phosphate potassium 0.3~1%, gathers the compound 0.3~1% of C13-14 isoparaffin and the composition of laureth -7 The compound 1~5%, hard by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose of ester -7 and two enanthic acid neopentyl glycol ester composition Resin acid ester, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane composition compound 5~20%, polyethylene glycol- The compound 1~8% that 240/HDI copolymer and double-decyl alkanol polyethers -20 form.

Preferably, the bean curd frost further includes the ingredient of following mass percent: C20-22 alcohol phosphide and C20-22 alcohol group At compound 0.5~4%, dimethyl silicone polymer 1~10%, Australia's state macadamia nut oil 1~10%, polyacrylate cross-linked polymeric Object -6 0.1~1%, glycine betaine 1~5%, methyl hydroxybenzoate 0.1~0.3%, glycerin polyether -261~5%, triethanolamine 0.1~ 0.3%, glycerol 1~10%, 1,3 butylene glycol 1~10%, double-polyethylene glycol -15- methyl ether dimethyl siloxane 0.1~ 1%, the deionization of the compound 0.2~1%, essence 0.02~0.1% and surplus that are made of Phenoxyethanol, Sensiva SC50 Water.

Preferably, the moisturizer is based on following mass percent: the dried tremella extract, dipropylene glycol, EDETATE SODIUM The compound 2.5~6% of composition, the compound 2~4% being made of Xylitol-based glucoside, anhydro xylitol and xylitol, by The compound 4 that Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form ~8%.The proportion of moisturizer of the present invention, component will affect effect, the study found that in the preferred mass percent range Interior, moistening effect of the present invention is more preferably.

Preferably, the moisturizer is based on following mass percent: the dried tremella extract, dipropylene glycol, EDETATE SODIUM The compound 4% of composition, the compound 3% being made of Xylitol-based glucoside, anhydro xylitol and xylitol, by hyaluronic acid The compound 5% that sodium cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form.This Shen Please inventor have been surprisingly found that under the specific quality proportioning, moistening effect of the present invention reaches best in many experiments.

Preferably, the moisturizer, assistant for emulsifying agent, film forming agent, physical sunscreen agent, rheology control agent each ingredient whole The content of a bean curd frost, based on following mass percent: the dried tremella extract, dipropylene glycol, EDETATE SODIUM form compound Object 4%, the compound 3% being made of Xylitol-based glucoside, anhydro xylitol and xylitol, by Sodium Hyaluronate cross-linked polymeric The compound 5% that object, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form；Polyacrylamide, C13- Compound 0.6%, laruyl alcohol phosphate potassium 0.6%, polyester -7 and two enanthic acid that 14 isoparaffins and laureth -7 form Neopentyl glycol ester composition compound 3%, by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, Jojoba seed Oil, stearic acid, alum scholar, glycerol caprylate and saualane composition compound 8%, polyethylene glycol -240/HDI copolymer and double - The compound 4% that decyl alkanol polyethers -20 forms.Present inventor has been surprisingly found that in many experiments, specific at this Quality proportioning under, moisturizing of the present invention, sun-proof, elasticity reaches best.

Preferably, the ingredient including following mass percent: the compound of C20-22 alcohol phosphide and C20-22 alcohol composition 2%, dimethyl silicone polymer 2%, Australia's state macadamia nut oil 3%, polyester -7 and two enanthic acid neopentyl glycol ester composition compound 3%, By titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and It is the compound 8% of saualane composition, polyacrylate cross-linked polymer -6 0.4%, glycine betaine 3%, methyl hydroxybenzoate 0.2%, sweet Oily polyethers -26 3%, triethanolamine 0.2%, by polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 The compound 4% of composition, glycerol 6%, 1,3-BDO 6%, double-polyethylene glycol -15- methyl ether dimethyl siloxane 0.6%, Compound 0.6%, the laruyl alcohol phosphate potassium being made of polyacrylamide, C13-14 isoparaffin and laureth -7 0.6%, the compound 0.6% that is made of Phenoxyethanol, Sensiva SC50, by dried tremella extract, dipropylene glycol, EDETATE SODIUM The compound 4% of composition, the compound 3% being made of Xylitol-based glucoside, anhydro xylitol and xylitol, by hyaluronic acid Compound 5%, the essence that sodium cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form 0.05% and surplus deionized water.

Preferably, the compound being made of dried tremella extract, dipropylene glycol, EDETATE SODIUM is handed over by Sodium Hyaluronate The mass ratio for the compound that linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form is 4: 5.The compound that is made of dried tremella extract, dipropylene glycol, EDETATE SODIUM with by Sodium Hyaluronate cross-linked polymer, hyaluronic acid The mass ratio of the compound of sodium, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition is 4:5, the guarantor of the present composition Wet effect is more preferable.

The present invention also provides a kind of preparation methods of bean curd frost, and the preparation method comprises the following steps 1) C20-22 Compound, dimethyl silicone polymer, Australia's state macadamia nut oil, polyester -7 and the two enanthic acid neopentyl glycols of alcohol phosphide and C20-22 alcohol composition Ester composition compound, by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum The compound of scholar, glycerol caprylate and saualane composition, which are uniformly mixed, is heated to 75 DEG C -85 DEG C；

2) deionized water, polyacrylate cross-linked polymer -6, glycine betaine, methyl hydroxybenzoate, glycerin polyether -26, three second Hydramine, compound, the glycerol, 1,3- fourth being made of polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 Glycol, double-polyethylene glycol -15- methyl ether dimethyl siloxane, which are uniformly mixed, is heated to 75 DEG C -85 DEG C；

3) mixture in step 2) is poured into the mixture that step 1) obtains, homogeneous 2-4min is added by poly- third Compound, the laruyl alcohol phosphate potassium of acrylamide, C13-14 isoparaffin and the composition of laureth -7, then homogeneous 2-4min, Then stirring cooling；When temperature drops to 40 DEG C -50 DEG C, Phenoxyethanol/Sensiva SC50, by dried tremella extract, double third sweet Alcohol, EDETATE SODIUM composition compound, be made of Xylitol-based glucoside, anhydro xylitol and xylitol compound 3%, by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition compound, Essence sequentially adds, and stirs evenly.

Beneficial effects of the present invention: bean curd frost of the invention has good assimilation effect to moisture, and can be permanent Ground keeps skin wet, and has good sun-proof result simultaneously, simultaneously because being added to the different alkane of polyacrylamide, C13-14 Compound, laruyl alcohol phosphate potassium, polyester -7 and the two enanthic acid neopentyl glycol ester composition that hydrocarbon and laureth -7 form are answered Close object, by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, caprylic The compound and polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 of acid esters and saualane composition form Compound form in certain proportion so that product has very strong elasticity, appearance seemed just as bean curd, gives people A kind of completely new vision.

Specific embodiment

To better illustrate the object, technical solutions and advantages of the present invention, below in conjunction with specific embodiment to the present invention It is described further.Each raw material manufacturer involved by following embodiment is as shown in table 1:

Table 1

Embodiment 1

A kind of embodiment of the preparation method of bean curd frost of the invention, the constituent such as table 2 of the bean curd frost of the present embodiment It is shown.

The preparation method of the frost of bean curd described in the present embodiment: A is mixed and is uniformly heated to 75 DEG C -85 DEG C, B is mixed 75 DEG C -85 DEG C are uniformly heated to, A phase is poured into B phase, homogeneous 2-4min is added to C, then homogeneous 2-4min, then stirs Cooling；When temperature drops to 40 DEG C -50 DEG C, the raw material in E phase is sequentially added, is stirred evenly.

Embodiment 2~7

The constituent and mass percentage content of the frost of bean curd described in embodiment 2~7 are as shown in table 2, and embodiment 2~ The preparation method of 7 bean curd frost is such as embodiment 1.

Table 2

Comparative example 1

The difference of this comparative example and embodiment 1 is only that, wherein being made of polyester -7, two enanthic acid neopentyl glycol ester compound The mass percent of object is 0.5%.

Comparative example 2

The difference of this comparative example and embodiment 1 is only that, wherein hard by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose Resin acid ester, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane composition the mass percent of compound be 3%.

Comparative example 3

The difference of this comparative example and embodiment 1 is only that, by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate The mass percent for the compound that ester, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane form is 3%, gathers Ethylene glycol -240/HDI copolymer pair-decyl alkanol polyethers -20 mass percent is 3%.

Comparative example 4

The difference of this comparative example and embodiment 1 is only that, by polyacrylamide, C13-14 isoparaffin, laureth- The mass percent of the compound of 7 compositions is 0.2%, and the mass percent of laruyl alcohol phosphate potassium is 0.5%.

Comparative example 5

The difference of this comparative example and embodiment 1 is only that, by polyacrylamide, C13-14 isoparaffin, laureth- The mass percent of the compound of 7 compositions is 0.5%, and the mass percent of laruyl alcohol phosphate potassium is 0.2%, is extracted by tremella The mass percent for the compound that object, dipropylene glycol, EDETATE SODIUM form is 1%.

Comparative example 6

The difference of this comparative example and embodiment 1 is only that, is made of Xylitol-based glucoside, anhydro xylitol and xylitol Compound mass percent be 0.1%.

Comparative example 7

The difference of this comparative example and embodiment 1 is only that, described by Sodium Hyaluronate cross-linked polymer, hyaluronic acid The mass percent of the compound of sodium, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition is 0.5%.

Comparative example 8

The difference of this comparative example and embodiment 1 is only that, does not include by dried tremella extract, dipropylene glycol and EDETATE SODIUM group At complex components.

Comparative example 9

This comparative example is only that with the difference of embodiment 1, does not include by Xylitol-based glucoside, anhydro xylitol and xylitol The compound of composition.

Comparative example 10

The difference of this comparative example and embodiment 1 is only that, do not include by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, The compound of acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition.

Embodiment 10 tests the white moisturizing of the embodiment of the present invention 2 to 10 and comparative example 1 to 7

Method: choosing 160 areals, women white collar that age bracket is 18-35 one full year of life dry skin is as subject, 16 groups are equally divided into, number 1-17.Every group of subject carries out moisture of skin survey after cleaning face, to every group of subject respectively It tries, after average treatment, records every group of the initial moisture value of skin；And the usage amount of every group of trial target is all the same.Smear 3h, When 6h, 12h, the skin moisture content that every group of subject mutually exists together is tested respectively, after average treatment, carry out recording every group respectively Skin moisture content, and analyze；Test result is as shown in table 2:

The moistening effect test result of the invention of table 2

As shown in Table 1, the frost that prepared by embodiment 2 to 9 using after 3h, 6h, 9h even 12h, skin moisture content according to It is so higher by much than the initial moisture value of skin, illustrates that test sample embodiment 2-9 has good absorption effect, and can grow Skin wet is kept long；Wherein preferable with the effect of embodiment 2, embodiment 7~9, especially the moistening effect of embodiment 2 is most Good, the effect of comparative example 1 to 4 is not much different with effect of the present invention, shows to be made of polyester -7, two enanthic acid neopentyl glycol ester Compound, by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol The compound of caprylate and saualane composition, polyethylene glycol -240/HDI copolymer pair-decyl alkanol polyethers -20, laurel The changes of contents of alcohol phosphate potassium influences less moistening effect, and comparative example 5~10 is after using 3h, 6h, 9h, 12h, skin water Although point content moisture value more initial than skin is high, be not obvious, especially 7,10, illustrate test sample comparative example 5~10 have compared with Good assimilation effect, but long-acting moistening effect is poor.The main reason for above-mentioned phenomenon occur is: by dried tremella extract, double third sweet Alcohol, EDETATE SODIUM composition compound, by Xylitol-based glucoside, anhydro xylitol and xylitol compound, by hyaluronic acid Sodium cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition compound, especially by The compound that Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form There is tremendous influence to the moisturizing of skin.And comparative example 8~10 is respectively to lack by dried tremella extract, dipropylene glycol, EDTA The compound of disodium composition gathers by Xylitol-based glucoside, anhydro xylitol and xylitol compound, by Sodium Hyaluronate crosslinking The one such ingredient of compound of object, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate composition is closed, and As can be known from the results, and significant effect reduces, and shows that of the invention is that can just play good length under three kinds of ingredient collective effects Imitate moisture-keeping function.

Embodiment 11

Bean curd of the present invention frost, the shadow of the mass ratio of the dried tremella extract and Hymagic-4D to moistening effect It rings.In order to investigate the influence, we are prepared for different test group bean curd frosts, the beans of each experimental group according to the method for embodiment 1 Rotten frost is grouped as by the group of following weight percentage: compound 0.5~4% that C20-22 alcohol phosphide and C20-22 alcohol forms gathers Dimethyl siloxane 1~10%, Australia's state macadamia nut oil 1~10%, two enanthic acid neopentyl glycol ester 1~5% of polyester -7&, by titanium dioxide Titanium, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane group At compound 5~20%, polyacrylate cross-linked polymer -6 0.1~1%, glycine betaine 1~5%, methyl hydroxybenzoate 0.1~ 0.3%, glycerin polyether -261~5%, triethanolamine 0.1~0.3%, by polyethylene glycol -240/HDI copolymer and double-decyl Compound 1~8%, the glycerol 1~10%, 1,3 butylene glycol 1~10%, double-polyethylene glycol-of the composition of tetradecanol polyethers -20 15- methyl ether dimethyl siloxane 0.1~1% is made of polyacrylamide, C13-14 isoparaffin and laureth -7 Compound 0.3~1%, laruyl alcohol phosphate potassium 0.3~1%, the compound 0.2 being made of Phenoxyethanol, Sensiva SC50 ~1%, the compound 1~5% that is made of dried tremella extract, dipropylene glycol, EDETATE SODIUM, by Xylitol-based glucoside, dehydration The compound 1~5%, transparent by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation of xylitol and xylitol composition The deionized water of the compound 2~10% of matter acid sodium and hydrolysis Sodium Hyaluronate composition, essence 0.02~0.1% and surplus.

Wherein, the compound (dried tremella extract) that is made of dried tremella extract, dipropylene glycol, EDETATE SODIUM with by hyalomitome The compound that sour sodium cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form (Hymagic-4D) mass ratio is as shown in table 3.

Table 3

Group	Dried tremella extract and Hymagic-4D mass ratio
		Experimental group 1	4:3
Experimental group 2	4:4
		Experimental group 3	4:5
Experimental group 4	4:6
		Experimental group 5	4:8
Experimental group 6	4:10

The moisture content of skin for the bean curd frost that test experiments group 1 to 5 is prepared respectively, test method such as 10 phase of embodiment Together, the results are shown in Table 4:

Table 4

By table 4 as it can be seen that the visible frost of experimental group 1~6 is after using 3h, 6h, 9h even 12h, skin moisture content is still It is higher by much than the initial moisture value of skin, wherein good absorption effect is preferably provided with the moistening effect of experimental group 3, and Skin wet can muchly be kept, show when the compound that be made of dried tremella extract, dipropylene glycol, EDETATE SODIUM with by saturating The compound substance that bright matter acid sodium cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate form When amount is than being 4:5, performance of keeping humidity is best.

The test of 13 sun-proof result of embodiment

Method: choosing the volunteer of areal 18-35 age bracket, wherein 30 are women, 30 are male, Nv Xingping 3 groups, group number 1-3 are divided into, male is also equally divided into 3 groups, group number 4-6, observes whether every group of volunteer has erythema.Every group Volunteer takes same amount of trial target to be applied to full face after having cleaned face, and experimental group 6 is using the test agent for implementing 2；It is real Group 7 is tested as using the test agent of comparative example 1；Experimental group 8 is the test agent using comparative example 2；Experimental group 9 is to use comparative example 3 For test agent；Experimental group 10 is the test agent using comparative example 4；Experimental group 11 is the test agent using comparative example 5.Every group of will Hope person is after having smeared test agent, and be exposed to the sun 1h, 2h, 3h in sunlight, observes whether skin has respectively in each period Erythema.Experimental result is as shown in table 5:

Table 5

As shown in Table 5, occur experimental group 1,2,5,6 is exposed to the sun after 3h even if in sunlight without erythema, and experimental group group 3,4 Just have erythema appearance after the 1h that is exposed to the sun, reason be by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, flash The compound of bar seed oil, stearic acid and alum scholar, glycerol caprylate and saualane composition have sun-proof well in effective range Effect.

12 flexibility test of embodiment

Method: choose commercially available a common white shape product as a control group with implement the test agent of 2, comparative example 1 to 7 into Row comparison.Method is that the test agent of control group and implementation 2, comparative example 1 to 7 is stirred into appearance very out-of-flatness from flat appearance Appearance, whether the appearance that the test agent of control group and comparative example 1 to 7 is observed after 10-20min revert to smooth appearance.It is real Test that the results are shown in Table 6:

Table 6

As shown in Table 6, embodiment 2, comparative example 2, comparative example 6, comparative example 7 test agent can restore originally to be smooth outer It sees, and comparative example 1, comparative example 3, comparative example 4, the test agent of comparative example 5 and control group can not all restore smooth appearance, mainly The reason is that the compound, the polyethylene glycol -240/HDI copolymer pair-decyl that are made of polyester -7, two enanthic acid neopentyl glycol ester Alkanol polyethers -20, compound, the laruyl alcohol phosphoric acid being made of polyacrylamide, C13-14 isoparaffin and laureth -7 The content range of ester potassium outside the scope of the present invention, shows to have to the ratio in effective range and just has good elasticity.

The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention Within mind and principle, any modification, equivalent substitution, improvement and etc. done be should be included within the scope of the present invention.

Claims

1. a kind of bean curd frost, which is characterized in that the bean curd frost include moisturizer, assistant for emulsifying agent, film forming agent, physical sunscreen agent, Rheology control agent, the moisturizer include the compound being made of dried tremella extract, dipropylene glycol, EDETATE SODIUM, by xylitol Base glucoside, anhydro xylitol and xylitol composition compound and by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, second Acylated Sodium Hyaluronate and the compound for hydrolyzing Sodium Hyaluronate composition, the assistant for emulsifying agent includes polyacrylamide, by C13- The compound and laruyl alcohol phosphate potassium that 14 isoparaffins, laureth -7 form；The film forming agent is polyester -7 and two heptan The compound of sour neopentyl glycol ester composition；The physical sunscreen agent is hard by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose The compound that resin acid ester, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane form；The levelling regulator is The compound that polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 form.

2. bean curd according to claim 1 frost, which is characterized in that moisturizer, assistant for emulsifying agent, film forming agent, physical sunscreen agent, Each ingredient of rheology control agent entire bean curd frost content, based on following mass percent: the dried tremella extract, double third Glycol, EDETATE SODIUM composition compound 1~8%, be made of Xylitol-based glucoside, anhydro xylitol and xylitol it is compound Object 1~5%, by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate group At compound 2~10%；The compound 0.3 that polyacrylamide, C13-14 isoparaffin and laureth -7 form~ 1%, laruyl alcohol phosphate potassium 0.3~1%, polyester -7 and two enanthic acid neopentyl glycol ester composition compound 1~5%, by dioxy Change titanium, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane Compound 5~20%, polyethylene glycol -240/HDI copolymer and the double-decyl alkanol polyethers -20 of composition form compound Object 1~8%.

3. bean curd frost according to claim 2, which is characterized in that further include the ingredient of following mass percent: C20-22 Alcohol phosphide and C20-22 alcohol composition compound 0.5~4%, dimethyl silicone polymer 1~10%, Australia's state macadamia nut oil 1~10%, Polyacrylate cross-linked polymer -6 0.1~1%, glycine betaine 1~5%, methyl hydroxybenzoate 0.1~0.3%, glycerin polyether -26 1 ~5%, triethanolamine 0.1~0.3%, glycerol 1~10%, 1,3 butylene glycol 1~10%, double-polyethylene glycol -15- methyl ether Dimethyl siloxane 0.1~1%, the compound 0.2~1% being made of Phenoxyethanol, Sensiva SC50, essence 0.02~ 0.1% and surplus deionized water.

4. bean curd frost according to claim 2, which is characterized in that the moisturizer is based on following mass percent: described Dried tremella extract, dipropylene glycol, EDETATE SODIUM composition compound 2.5~6%, by Xylitol-based glucoside, anhydro xylitol With the compound 2~4% of xylitol composition, by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate With the compound 4~8% of hydrolysis Sodium Hyaluronate composition.

5. bean curd frost according to claim 4, which is characterized in that the moisturizer is based on following mass percent: described Dried tremella extract, dipropylene glycol, EDETATE SODIUM composition compound 4%, by Xylitol-based glucoside, anhydro xylitol and xylose It is the compound 3% of alcohol composition, saturating by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis The compound 5% of bright matter acid sodium composition.

6. bean curd frost according to claim 1, which is characterized in that the moisturizer, assistant for emulsifying agent, film forming agent, physics are anti- Shine agent, rheology control agent each ingredient entire bean curd frost content, based on following mass percent: tremella extraction Object, dipropylene glycol, EDETATE SODIUM composition compound 4%, be made of Xylitol-based glucoside, anhydro xylitol and xylitol Compound 3%, by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate The compound 5% of composition；Polyacrylamide, the compound 0.6% of C13-14 isoparaffin and the composition of laureth -7, laurel Alcohol phosphate potassium 0.6%, polyester -7 and two enanthic acid neopentyl glycol ester composition compound 3%, by titanium dioxide, water, polyglycereol - The compound that 2 certain herbaceous plants with big flowers acid esters, sucrose stearate, jojoba seed oil, stearic acid, alum scholar, glycerol caprylate and saualane form 8%, the compound 4% that polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20 form.

7. bean curd frost according to claim 1, which is characterized in that the ingredient including following mass percent: C20-22 alcohol Compound 2%, dimethyl silicone polymer 2%, Australia's state macadamia nut oil 3%, polyester -7 and two enanthic acid of phosphide and C20-22 alcohol composition Neopentyl glycol ester composition compound 3%, by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, Jojoba seed Oil, stearic acid, alum scholar, glycerol caprylate and saualane composition compound 8%, polyacrylate cross-linked polymer -6 0.4%, glycine betaine 3%, methyl hydroxybenzoate 0.2%, glycerin polyether -26 3%, triethanolamine 0.2%, by polyethylene glycol -240/ HDI copolymer and double-compound 4% that decyl alkanol polyethers -20 forms, glycerol 6%, 1,3-BDO 6%, double-is poly- Ethylene glycol -15- methyl ether dimethyl siloxane 0.6%, by -7 group of polyacrylamide, C13-14 isoparaffin and laureth At compound 0.6%, laruyl alcohol phosphate potassium 0.6%, the compound 0.6% being made of Phenoxyethanol, Sensiva SC50, The compound 4% that is made of dried tremella extract, dipropylene glycol, EDETATE SODIUM, by Xylitol-based glucoside, anhydro xylitol and wood Sugar alcohol composition compound 3%, by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis The deionized water of compound 5%, essence 0.05% and surplus that Sodium Hyaluronate forms.

8. bean curd frost according to claim 1, which is characterized in that described by dried tremella extract, dipropylene glycol, EDTA bis- Sodium composition compound with by Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolyze it is transparent The mass ratio of the compound of matter acid sodium composition is 4:5.

9. a kind of preparation method of the bean curd frost as described in claim 3 or 7, which is characterized in that the preparation method include with Compound, the dimethyl silicone polymer, Australia's state macadamia nut oil, polyester -7 that lower step 1) forms C20-22 alcohol phosphide and C20-22 alcohol With two enanthic acid neopentyl glycol ester composition compound, by titanium dioxide, water, -2 certain herbaceous plants with big flowers acid esters of polyglycereol, sucrose stearate, flash Bar seed oil, stearic acid, alum scholar, glycerol caprylate and saualane composition compound be uniformly mixed and be heated to 75 DEG C -85 DEG C；

2) deionized water, polyacrylate cross-linked polymer -6, glycine betaine, methyl hydroxybenzoate, glycerin polyether -26, triethanolamine, The compound that is made of polyethylene glycol -240/HDI copolymer and double-decyl alkanol polyethers -20, glycerol, 1,3-BDO, Double-polyethylene glycol -15- methyl ether dimethyl siloxane is uniformly mixed and is heated to 75 DEG C -85 DEG C；

3) mixture in step 2) is poured into the mixture that step 1) obtains, homogeneous 2-4min is added by polyacrylamide Compound, the laruyl alcohol phosphate potassium of amine, C13-14 isoparaffin and the composition of laureth -7, then homogeneous 2-4min, then Stirring cooling；When temperature drops to 40 DEG C -50 DEG C, extracted the compound being made of Phenoxyethanol, Sensiva SC50, by tremella Object, dipropylene glycol, EDETATE SODIUM composition compound, answered by what Xylitol-based glucoside, anhydro xylitol and xylitol formed It closes object, be made of Sodium Hyaluronate cross-linked polymer, Sodium Hyaluronate, acetylation Sodium Hyaluronate and hydrolysis Sodium Hyaluronate Compound, essence sequentially add, and stir evenly.