KR20150076477A - Oil-type composition for face washing having continuous moisturizing effect - Google Patents

Abstract

The present invention relates to an oil composition having continuous moisturizing effects for washing a face and, more specifically, to an oil composition comprising oil, hydrophobic hyaluronic acid, a cationic polymer, and glycerin for washing a face. The oil composition for washing a face with excellent stability and with excellent makeup removal power has continuous moisturizing effects as preventing a dry skin caused by removing excessive sebum, and capable of being applied to an oil-type or gel-type product comprising a nonionic surfactant or a viscosity increasing agent.

Description

[0001] Oil-type composition for facial washing having continuous moisturizing effect [

The present invention relates to an oil-in-oil pigment composition having a constant moisturizing effect after cleansing.

Cleansing cosmetics for cleansing the dirt and make-up of the skin include cream, oil, gel, oily, and liquid, and emulsion, oily, and aqueous type according to the formulation classification.

In the case of the aqueous type, a cleansing effect is imparted by mixing a small amount of oil with an ionic and nonionic surfactant in the base using water and a polyol. These aqueous types are advantageous in that the feeling of use is neat, but the drawback .

The cleansing oil representing the oil-based type is a non-water-based formulation using 100% oil or contains a very small amount of water to improve the stability. Korean Patent Laid-Open Publication No. 2012-0084724 discloses a flame-retardant polyolefin composition comprising 1 to 30% by weight of a heavy chain polyglycerol monoalkyl ether, 1 to 30% by weight of a long chain polyglycerol monoalkyl ether, at least one kind of silicone oil, The present invention provides a cleansing oil composition which is easily impregnated with make-up contamination containing an oil component in an amount of 40 to 98% by weight and can be cleanly washed away without oily feeling by washing with water.

This type of oil type has excellent ability to remove makeup, but it causes excessive drying of the skin due to excessive oil removal due to a large amount of oil component, and there is another problem in that the oil remains after the water cleansing or the skin is dried due to excessive sebum removal.

Korean Patent Registration No. 10-0720381 discloses that a cleansing cosmetic composition comprising peanut oil, jujube seed oil, pumpkin seed oil, perilla oil, and walnut oil has excellent skin moisturizing and wrinkle reducing effects and is not irritating and does not cause skin troubles .

On the other hand, hyaluronic acid, which is one of the raw materials for improving the moisturizing power in the cosmetic composition, is widely distributed widely among cells of connective tissues such as dry skin, skin, aorta and joint fluid of mammals and decreases with age.

Since a collagen fiber and a mucopolysaccharide are combined in the dermis to form a matrix containing a large amount of water, synergistic effect of excellent moisturizing can be obtained by combining two kinds of mucopolysaccharide, not solely in cosmetics.

In cosmetics, hyaluronic acid has a high hygroscopicity and a smooth feeling of use under the conditions of low humidity and high humidity, so it is necessary to use cosmetics such as creams, milky lotions, cosmetics, serum, packs and antiperspirants as well as lipstick and foundation , And hair products.

For example, Korean Patent Registration No. 10-0429277 discloses a composition containing an extract of ivy, allantoin, ethanol, L-menthol, hyaluronic acid, glycerin, cocoamphocarboxy glycinate / sodium lauryl sulfate, detergent, Hair softening effect, skin soothing effect and cleaning effect.

In cosmetics, sodium hyaluronate, which is usually a salt of hyaluronic acid, is used. It is a white powder, which is dissolved in water and exhibits various viscous jellies or solutions depending on its molecular weight, concentration, pH and ionic strength.

In addition, a cationic polymer that is artificially synthesized as a kind of protein that makes a human cell membrane has a highly highly biologically stable and highly stable component, has a dermatitis inhibiting effect, has excellent moisturizing effect, and has a stimulant mitigation function through formation of a skin protective film.

However, there is a problem in that hyaluronic acid is difficult to apply to an oil-based pigment composition due to stability within the formulation.

Korean Patent Publication No. 2012-0084724 Korean Patent Registration No. 10-0720381 Korean Patent Registration No. 10-0429277

Accordingly, in order to stably apply hyaluronic acid to an oil-based pigment, an oil, a cationic polymer and glycerin are combined in a specific composition together with a hydrophobic hyaluronic acid, and a non-ionic surfactant or an aging agent is used to prepare an oil formulation and a gel formulation The stability of the obtained oil-based oil composition, the makeup cleansing power, and the moisturizing effect were confirmed, and the present invention was completed.

Accordingly, an object of the present invention is to provide an oil-based antioxidant composition having excellent stability, excellent make-up cleansing power, and preventing skin dry due to excessive sebum removal and having a constant moisturizing effect.

In order to achieve the above object, the present invention provides an oil-based pigment composition comprising an oil, a hydrophobic hyaluronic acid, a cationic polymer, and glycerin.

Wherein the oil-retentive pigment composition comprises, within a total of 100% by weight,

80 to 95 wt% of oil, 0.1 to 5.0 wt% of hydrophobic hyaluronic acid, 0.1 to 5.0 wt% of cationic polymer, and 0.5 to 10 wt% of glycerin.

The oil-retentive pigment composition may be prepared in an oil or gel formulation containing 2 to 10% by weight of non-ionic surfactant or 2 to 10% by weight of nonionic surfactant in the total composition.

In addition, the oil-retentive composition may further comprise 0.1 to 2.0% by weight of water.

The oil-retentive composition according to the present invention is excellent in stability, excellent in make-up cleansing power, prevents skin dry due to excessive sebum removal, has a constant moisturizing effect, and can be applied as an oil-type or gel-type product.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a graph showing changes in skin moisture loss of the oil-based pigment compositions of Examples 1 and 2 and Comparative Examples 1 to 6. FIG.
2 is a graph showing the composition of the oil-based pigment composition of Examples 1 and 2, the composition of Comparative Example 1, and the skin surface capacitance after skin application.

Hereinafter, the present invention will be described in more detail.

The oil-retentive pigment composition according to the present invention simultaneously maintains excellent moisturizing effect by the hyaluronic acid and the cationic polymer together with excellent make-up removal effect according to the oil formulation.

Specifically, the oil-retentive composition comprises an oil, hydrophobic hyaluronic acid, a cationic polymer, and glycerin, and a non-ionic surfactant or thickener is used for the formulation.

The oil is not particularly limited as long as it is used in cosmetics and can be selected in consideration of makeup removing power and stability. Typically, the oil is selected from the group consisting of hydrocarbon-based oils, ester based synthetic oils, silicone oils, mineral oils, vegetable oils, alkyl ester oils, lipids, C10-C40 fatty alcohols, caprylic / Frictigo triglyceride oil may be used. Typically, hydrocarbon-based oils including squalane, polydecene and paraffin oil; Cetyl ethylhexanoate, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, isononyl isononanoate, C12-15 alkyl benzoate, glyceryl trioctanoate, octyldodecyl myristate, octyl palmate, Ester-based synthetic oils containing tate; Silicone oils including cyclomethicone, dimethicone, phenyl trimethicone, trisiloxane / dimethicone; Mineral oil; Vegetable oils including sunflower seed oil, olive oil, mango butter, shea butter, copoic acid seed butter, macadamia seed oil; Ethoxylated alkyl ester oils; Lipids such as cholesterol, cholesteryl sulfate, phytosphingosine, sphingonoids; One selected from the group consisting of C10-C40 fatty alcohols such as butyl alcohol, behenyl alcohol, cetostearyl alcohol, cetyl alcohol and stearyl alcohol, caprylic / capric triglyceride, and mixtures thereof can be used. Preferably, the oil cleansing composition of the present invention is a mixture of ester synthetic oil, mineral oil, vegetable oil and caprylic / capric triglyceride.

The oil contains 80 to 95% by weight, preferably 85 to 95% by weight, based on the total weight of the total composition for oil cleansing. If the content is less than the above range, the makeup detergency and the stability of the oil or gel formulation deteriorate. On the contrary, if the content exceeds the above range, the content of the other composition is relatively small, The phenomenon can not be prevented.

Hyaluronic acid is used for moisturizing and hydrophobic hyaluronic acid is used to dissolve in oil formulations. Hydrophobic hyaluronic acid is hydrophobicized by reacting hyaluronic acid with an organic substance. Glyceryl-hyaluronic acid (Glyceryl-HA) is preferably used, and a commercially available one is purchased and used. It was confirmed that the hydrophilic hyaluronic acid and hydrophilic hyaluronic acid were superior to the hydrophilic hyaluronic acid and ceramide in the experimental example of the present invention in stability of the formulation and moisturizing ability after cleansing.

The hydrophobic hyaluronic acid is contained in an amount of 0.1 to 5.0% by weight, preferably 0.1 to 3.0% by weight, based on the total weight of the composition for cleaning the entire oil. If the content is less than the above range, a sufficient moisturizing effect can not be ensured. On the other hand, if the content is in excess of the above range, the stability of the oil or gel formulation may deteriorate.

The cationic polymer imparts a moisturizing effect to the skin, imparts a softening effect to the anionic skin due to its cationic nature, and allows the user to feel a moist feeling after use. The cationic polymer may be a polyquaternium-based polymer. Specific examples of the cationic polymer include polyquaternium-4, polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium- 16, polyquaternium-39, polyquaternium-51, and combinations thereof. Preferably, polyquaternium-51 is used for moisturizing and thickening effect. The use of such a cationic polymer makes it possible to produce oil or gel formulations having a predetermined viscosity without any additional thickening agent.

The cationic polymer is contained in an amount of 0.1 to 5.0% by weight, preferably 0.1 to 3.0% by weight, based on the total weight of the composition for cleaning the entire oil. If the content is less than the above range, a sufficient moisturizing effect can not be ensured. On the other hand, if the content is in excess of the above range, the content of the other composition may be reduced and oil formulations can not be produced.

Glycerin is used for the dissolution of hydrophobic hyaluronic acid and cationic polymer and is used less than the amount of conventional moisturizing agent used.

The glycerin is contained in an amount of 0.5 to 10 wt%, preferably 0.5 to 5 wt%, based on the total weight of the composition for cleaning the entire oil. If the content is less than the above range, the hydrophobic hyaluronic acid and the cationic polymer can not be sufficiently dissolved to lower the stability of the oil formulation. On the contrary, if the content exceeds the above range, the content of the other composition is decreased to make oil or gel formulations , And is appropriately used within the above range. It was confirmed that the stability of the formulation was excellent when glycerin was used as compared with the other polyols (diglycerin, butylene glycol, etc.) instead of glycerin in the experimental examples of the present invention.

The oil-retentive composition having the above-described composition can be prepared in an oil-form, and the composition can be prepared into a gel-form by changing the composition.

To prepare the gel formulation, a nonionic surfactant is used in addition to the above composition.

The nonionic surfactant is used for enhancing the dispersion stability of the composition for oil cleansing. As the hydrophobic group, a nonionic surfactant containing a hydrocarbon group of C10-54 carbon atoms or hydrocarbon silicon can be used. Examples of the nonionic surfactant include glucosides such as lauryl glucoside and decyl glucoside, phage-20 glyceryl triisostearate, phage-15 glyceryl isostearate, phage-8 isostearate Polyglyceryl-3-diisostearate, polyglyceryl-10 diallylate, polyglyceryl 10-tallowate, and other nonionic surfactants such as polyethylene glycols, .

The nonionic surfactant is contained in an amount of 2 to 10% by weight, preferably 5 to 10% by weight, based on the total weight of the total composition for oil cleansing. If the content is less than the above range, the makeup detergency and the stability of the oil formulation deteriorate. On the contrary, if the content exceeds the above range, the skin dryness is caused and the unit price rises.

In order to prepare the gel formulation, an aging agent is used in addition to the above composition. It is possible to use one kind selected from the group consisting of xanthan gum, carbomer, magnesium aluminum silicate, cellulose gum, dextrin palmitate, dextrin palmitate / ethylhexanoate, and combinations thereof, preferably dextrin palmitate or Dextrin palmitate / ethyl hexanoate is used.

The above-mentioned thickener is contained in an amount of 2 to 10% by weight, preferably 5 to 10% by weight, based on the total weight of the total composition for oil cleansing. If the content is less than the above range, it is difficult to prepare into a gel formulation. On the other hand, if the content exceeds the above range, it is difficult to use due to an excessive viscosity increase.

According to a preferred embodiment, the oil-retentive composition according to the present invention comprises 80 to 95% by weight of oil, 0.1 to 5.0% by weight of hydrophobic hyaluronic acid, 0.1 to 5.0% by weight of cationic polymer, 0.5 to 10% by weight of glycerin, and 2 to 10% by weight of a nonionic surfactant.

In the case of the gel formulation, the oil-retentive composition may contain 30 to 95% by weight of oil, 0.1 to 5.0% by weight of hydrophobic hyaluronic acid, 0.1 to 5.0% by weight of cationic polymer, 0.5 to 10% by weight of glycerin %, And an increment of 2 to 10 wt%.

In addition, the oil-in-oil pigment composition according to the present invention may further comprise a very small amount of water. The water is used for stability and is contained in an amount of 0.1 to 2.0% by weight, preferably 0.1 to 1.0% by weight, based on the total weight of the composition for cleaning the entire oil. If the content is less than the above range, the transparency and stability are lowered. On the other hand, if the content exceeds the above range, oil or gel formulations can not be produced.

The preparation of the oil-retentive pigment composition according to the present invention is not particularly limited in the present invention, and can be produced by a known method.

For example, water and a polyol solvent are mixed with a cationic polymer, hydrophobic hyaluronic acid is added thereto to completely dissolve, and then oil and a nonionic surfactant are added.

In addition, the oil-retentive composition may further include known additives such as a flavor, a pigment, an antioxidant, a preservative, a pH adjuster, and the like.

Such an oil-based pigment composition gives excellent detergency when applied to the skin without using a separate moisturizing agent, and is a combination of a moisturizing factor and a cationic polymer added in the formulation after cleansing to remove skin sebum due to excessive sebum removal after using conventional cleansing oil Can be minimized.

Hereinafter, preferred embodiments of the present invention will be described in order to facilitate understanding of the present invention. However, the following examples are provided to further understand the present invention, and the present invention is not limited by the examples.

Examples and Comparative Example : oil Three pigments  Preparation of composition

An oil-retentive pigment composition having the compositions shown in Tables 1 and 2 below was prepared. Specifically, the cationic polymer was heated to 70 DEG C in water and a polyol solvent, and a humectant was added thereto to completely dissolve the cationic polymer. The temperature was then lowered to 45 DEG C and then oil and non-ionic surfactant were added and stored in a 25 DEG C chamber for 24 hours.

Composition (% by weight) Example Comparative Example One 2 One 2 3 4 5 6 oil Cetyl ethyl hexanoate 24.7 26.7 26.5 25.0 25.0 25.0 25.0 25.0 Mineral oil 30.00 30.00 30.00 30.00 30.00 30.00 30.00 30.00 Sunflower seed oil 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Caprylic / capric triglyceride 30.00 30.00 30.00 30.00 30.00 30.00 30.00 30.00 Nonionic surfactant Phage-20 glyceryl triisostearate 6.00 - 6.00 6.00 6.00 6.00 6.00 6.00 Polyglyceryl-10 triturate 2.00 - 2.00 2.00 2.00 2.00 2.00 2.00 Incrementer Dextrin palmitate - 1.00 - - - - - - Dextrin palmitate / ethyl hexanoate - 5.00 - - - - - - Moisturizer

Glyceryl-hyaluronic acid 0.50 0.50 - 0.50 - - - - Sodium-Hyaluronic Acid (Hydrophilic) - - - - 0.50 - - - Ceramide - - - - - 0.50 - - Cationic polymer Polyquaternium-51 0.30 0.30 - - - - 0.50 - PP / PE-17/6 Copolymer - - - - - - - 0.5 Polyol solvent

glycerin 1.00 1.00 - 1.00 1.00 1.00 1.00 1.00 Diglycerin - - - - - - - - Butylene glycol - - - - - - - - Propylene glycol - - - - - - - - Dipropylene glycol - - - - - - - - Sorbitol - - - - - - - - Purified water 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Formulation oil Gel oil oil oil oil oil oil

Composition (% by weight)
Comparative Example 7 8 9 10 11 12 13 14 oil Cetyl ethyl hexanoate 24.7 25.5 25.5 25.5 25.5 25.7 26.0 24.5 Mineral oil 30.00 30.00 30.00 30.00 30.00 30.00 30.00 30.00 Sunflower seed oil 5.00 5.00 5.00 5.00 5.00 5.00 5.00 5.00 Caprylic / capric triglyceride 30.00 30.00 30.00 30.00 30.00 30.00 30.00 30.00 Nonionic surfactant Phage-20 glyceryl triisostearate 6.00 6.00 6.00 6.00 6.00 6.00 6.00 6.00 Polyglyceryl-10 triturate 2.00 2.00 2.00 2.00 2.00 2.00 2.00 2.00 Incrementer Dextrin palmitate - - - - - - - - Dextrin palmitate / ethyl hexanoate - - - - - - - - Moisturizer

Glyceryl-hyaluronic acid 0.50 - - - - 0.50 - - Sodium-Hyaluronic Acid (Hydrophilic) - - - - - - - - Ceramide - - - - - - - - Cationic polymer Polyquaternium-51 0.30 - - - - 0.30 - - PP / PE-17/6 Copolymer - - - - - - - - Polyol solvent


glycerin - - - - - 0.00 0.50 2.00 Diglycerin 1.00 - - - - - - - Butylene glycol - 1.00 - - - - - - Propylene glycol - - 1.00 - - - - - Dipropylene glycol - - - 1.00 - - - - Sorbitol - - - 1.00 - - - Purified water 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Formulation oil oil oil oil oil oil oil oil

Experimental Example  1: Phase stability evaluation

The stability of the oil-retentive composition prepared in the above Examples and Comparative Examples was tested. The stability of each composition was visually observed at 25 ° C, 5 ° C, and 45 ° C oven for 4 weeks immediately after the preparation of each composition to confirm whether layer separation and precipitation occurred. In this case, the 'cycle' means a cycle of circulating at 25 ° C, 5 ° C, and 45 ° C for 6 hours, respectively. The results are shown in Table 3.

<Evaluation method>

○: When there is no phenomenon such as layer separation or sinking at the time of observation

△: When layer separation phenomenon is seen or sinking occurs

X: Immediately after production, when impurities are floating or separated

Example Comparative Example One 2 One 2 3 4 5 6 7 8 9 10 11 12 13 14 Immediately after manufacture ○ ○ ○ ○ ○ ○ ○ ○ ○ ○ × × × × ○ × 25 ℃ ○ ○ ○ ○ △ △ ○ △ ○ ○ × × × × ○ × 40 ℃ ○ ○ ○ △ × × △ × ○ △ × × × × ○ × 5 ℃ ○ ○ ○ △ × × △ × ○ ○ × × × × ○ × cycle ○ ○ ○ △ × × △ × △ △ × × × × △ ×

Referring to Table 3, the oil-in-oil pigment compositions according to the present invention exhibited high stability in both oil formulations and gel formulations, but in Comparative Examples 9 to 12 and Comparative Example 14, phase separation was observed immediately after preparation.

In Comparative Examples 2 to 6, 7, 8 and 13, the phase stability was excellent immediately after the production, but the layer separation phenomenon occurred in the cycle test.

Experimental Example  2: Usability evaluation

The feeling of use of the oil-retentive composition prepared in the above Examples and Comparative Examples was measured. The sensation of feeling was evaluated by the following evaluation criteria for the applicability, the washability, the cleansing power, and the moisturizing power after cleansing. The results are shown in Table 4.

<Evaluation Criteria> 5 points (very good), 4 points (good), 3 points (normal), 2 points (poor), 1 point (very bad)

Example Comparative Example One 2 One 2 3 4 5 6 Application property 4.0 4.0 4.0 4.0 3.0 3.0 3.5 3.5 Washability 4.5 4.5 4.0 4.0 3.0 3.0 3.0 3.0 Cleansing power 4.5 4.8 4.2 4.2 3.0 3.0 4.0 4.0 Moisturizing power after cleansing 4.5 4.5 3.5 3.2 3.0 3.0 3.5 3.0

Referring to Table 4, the compositions of Examples 1 and 2 according to the present invention showed a high score of 4.5 or more, confirming that the compositions of Examples 1 to 6 had better feeling than the compositions of Comparative Examples 1 to 6.

Experimental Example  3: Assessment of improving skin moisture retention

Trans-epidermal water loss (TEWL) of the oil-based oil composition prepared in the above Examples and Comparative Examples was measured to confirm whether or not the skin had barrier strengthening effect.

Twenty women aged 32 to 42 years (mean age 36 ± 3 years) with healthy skin were performed in an incubation room capable of temperature and humidity control at 25 ° C / 40RH%. The measurement was performed before and after the use of each composition, and the TWEL was measured three times at each test site using a TEWL meter, and the obtained results are shown in FIG.

BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a graph showing changes in skin moisture loss of the oil-based pigment compositions of Examples 1 and 2 and Comparative Examples 1 to 6. FIG.

Referring to FIG. 1, the oil-in-oil pigment compositions of Examples 1 and 2 according to the present invention showed a skin moisture loss of 30% or less immediately after use, showing superior results to those of Comparative Examples 1 to 6. In particular, in the case of Comparative Example 1, the results of Experimental Examples 1 and 2 showed excellent stability, but the moisture content was as low as about 2.7 times.

Experimental Example  4: Evaluation of skin moisture improvement after cleansing

The skin oil content after cleansing of the oil-based oil compositions prepared in the above Examples and Comparative Examples was measured.

Twenty women aged 32 to 42 years (mean age 36 ± 3 years) with healthy skin were performed in an incubation room capable of temperature and humidity control at 25 ° C / 40RH%. The measurement was conducted after using the compositions of Examples 1 and 2, and the composition of Comparative Example 1 was measured after use and after skin application. At this time, the skin surface capacitance was repeatedly measured three times using a corneometer (CM825) after cleansing, and the obtained results are shown in FIG.

2 is a graph showing the composition of the oil-based pigment composition of Examples 1 and 2, the composition of Comparative Example 1, and the skin surface capacitance after skin application. At this time, the higher the value, the greater the amount of water present in the skin.

2, it can be seen that the oil-in-oil pigment compositions of Examples 1 and 2 according to the present invention have a higher skin moisture content than the composition of Comparative Example 1 and the skin.

Claims (13)

An oil, a hydrophobic hyaluronic acid, a cationic polymer, and glycerin. 2. The composition of claim 1, wherein the oil-in-oil pigment composition comprises, within a total of 100%
Wherein the composition comprises 80 to 95% by weight of oil, 0.1 to 5.0% by weight of hydrophobic hyaluronic acid, 0.1 to 5.0% by weight of a cationic polymer, and 0.5 to 10% by weight of glycerin. The composition according to claim 1, wherein the oil is selected from the group consisting of hydrocarbon-based oils, ester-based synthetic oils, silicone oils, mineral oils, vegetable oils, alkyl ester oils, lipids, C10-C40 fatty alcohols, caprylic / capric triglycerides, And mixtures thereof. &Lt; RTI ID = 0.0 &gt; 11. &lt; / RTI &gt; The composition of claim 1 wherein said oil is selected from the group consisting of squalane, polydecene, paraffin oil, cetyl ethylhexanoate, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, isononyl isononanoate, Octyldodecyl myristate, octyl palmitate, cyclomethicone, dimethicone, phenyltrimethicone, trisiloxane / dimethicone, mineral oil, sunflower seed oil, olive oil, mango butter, But are not limited to, cholesterol, cholesterol, cholesterol, cholesteryl sulfate, phytosphingosine, sphingonoid, butyl alcohol, behenyl alcohol, cetostearyl alcohol, cetyl alcohol, stearoyl alcohol, Allyl alcohol, caprylic / capric triglyceride, and mixtures thereof. By weight based on the total weight of the composition. The oil-based pigment composition according to claim 1, wherein the hydrophobic hyaluronic acid is glyceryl-hyaluronic acid. The composition of claim 1 wherein said cationic polymer is selected from the group consisting of polyquaternium-4, polyquaternium-6, polyquaternium-7, polyquaternium-10, polyquaternium-11, polyquaternium- -39, polyquaternium-51, and a combination thereof. The oil-based antimicrobial composition according to claim 1, wherein the oil-retentive pigment composition comprises a non-ionic surfactant or a thickener in the overall composition. 8. The composition of claim 7, wherein the nonionic surfactant is selected from the group consisting of: phage-20 glyceryl triisostearate, phage-15 glyceryl isostearate, phage-8 isostearate, polyglyceryl-3 diisostearate Polyglyceryl-10 diallylate, polyglyceryl 10-trilaurate, and combinations thereof. The oil-and-oil pigment composition according to claim 1, 8. The composition of claim 7, wherein the thickener comprises one selected from the group consisting of xanthan gum, carbomer, magnesium aluminum silicate, cellulose gum, dextrin palmitate, dextrin palmitate / ethylhexanoate, &Lt; / RTI &gt; The three-pigment composition of claim 1, wherein the oil-in-oil pigment composition is an oil or gel formulation. The oil-retentive composition according to any one of claims 1, 2, 7, and 10,
Characterized in that it is an oil formulation comprising 80 to 95 wt% of oil, 0.1 to 5.0 wt% of hydrophobic hyaluronic acid, 0.1 to 5.0 wt% of cationic polymer, 0.5 to 10 wt% of glycerin and 2 to 10 wt% of nonionic surfactant Lt; / RTI &gt; The oil-retentive composition according to any one of claims 1, 2, 7, and 10,
Characterized in that it is a gel formulation comprising 80 to 95% by weight of oil, 0.1 to 5.0% by weight of hydrophobic hyaluronic acid, 0.1 to 5.0% by weight of cationic polymer, 0.5 to 10% by weight of glycerin and 2 to 10% A three-pigment composition. 2. The oil-reticulated pigment composition of claim 1, wherein the oil-retentive composition further comprises from 0.1 to 2.0% by weight of water within 100% by weight of the total composition.

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