CN109169678A - A kind of fungicide and combinations thereof - Google Patents

A kind of fungicide and combinations thereof Download PDF

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Publication number
CN109169678A
CN109169678A CN201810986368.8A CN201810986368A CN109169678A CN 109169678 A CN109169678 A CN 109169678A CN 201810986368 A CN201810986368 A CN 201810986368A CN 109169678 A CN109169678 A CN 109169678A
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Prior art keywords
bacterium
azoles
methyl
fluorine
active component
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CN201810986368.8A
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Chinese (zh)
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CN109169678B (en
Inventor
李科
孙守福
马超
王林
张双应
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Qiaochang Modern Agriculture Co Ltd
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Qiaochang Modern Agriculture Co Ltd
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Priority to CN202011131770.1A priority Critical patent/CN113142235A/en
Priority to CN202011134195.0A priority patent/CN113142225A/en
Priority to CN202011131768.4A priority patent/CN113142223A/en
Priority to CN202011134212.0A priority patent/CN113142229A/en
Priority to CN202011134219.2A priority patent/CN113142231A/en
Priority to CN202011131747.2A priority patent/CN113040156A/en
Priority to CN202011131728.XA priority patent/CN113142218A/en
Priority to CN202011131759.5A priority patent/CN113142222A/en
Priority to CN202011134207.XA priority patent/CN113142228A/en
Priority to CN202011131757.6A priority patent/CN113142221A/en
Priority to CN202011131730.7A priority patent/CN113040155A/en
Priority to CN202011134220.5A priority patent/CN113040157A/en
Application filed by Qiaochang Modern Agriculture Co Ltd filed Critical Qiaochang Modern Agriculture Co Ltd
Priority to CN201810986368.8A priority patent/CN109169678B/en
Priority to CN202011131737.9A priority patent/CN113142219A/en
Priority to CN202011131785.8A priority patent/CN113142224A/en
Priority to CN202011134188.0A priority patent/CN113142236A/en
Priority to CN202011131749.1A priority patent/CN113142220A/en
Priority to CN202011134200.8A priority patent/CN113142227A/en
Priority to CN202011134199.9A priority patent/CN113142226A/en
Priority to CN202011134215.4A priority patent/CN113142230A/en
Publication of CN109169678A publication Critical patent/CN109169678A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines

Abstract

The invention discloses a kind of fungicide and combinations thereof, compound comprising compound A single dose or compound A and other fungicidal activity ingredients, and compound A and other bactericide compounded weight proportions are 1:100-100:1.By the present invention in that two-spot, ternary built are carried out with compound A single dose or compound A and other fungicide, so that obtained single dose or composition all have excellent control efficiency.Meanwhile composition expands fungicidal spectrum, has synergistic effect.The present invention is by being applied to fungicide for compound A and compounding with other fungicidal activity ingredients, controlling disease effect can be improved, germ is made to be not likely to produce drug resistance, it can be used for preventing and treating vegetables such as cucumber, Chinese cabbage, spinach, capsicum, tomato etc., and downy mildew, late blight, epidemic disease, samping off, powdery mildew, rust, anthracnose etc. on the crops such as potato, grape, citrus, banana, there are also root rot, tobacco leaf balck shanks etc..

Description

A kind of fungicide and combinations thereof
Technical field
The invention belongs to disinfectant use in agriculture fields, and in particular to a kind of fungicide and combinations thereof.
Background technique
Downy mildew, powdery mildew and epidemic disease are the common frdquently encountered disease evils of the crops such as melon, fruit tree, vegetables, seriously affect product Yield and quality, usually become destructive disease.
Downy mildew plant disease as caused by the downy mildew in fungi.Downy mildew can be sent out from seedling to each stage is harvested It is raw, it is aggrieved heavier with strain.Main blade of causing harm, is developed from base portion to upper leaf.Early stage forms light yellow close on blade face For circle to polygonal scab, blade back generates the mould layer of white shape when there was dampness in the air, can spread to blade face sometimes.The withered company of later period scab Piece is in yellowish-brown, whole siphonal lobe withered and yellow death when serious.Germ caused harm on seed or Vegetable During Winter-autumn with mycelia it is overwintering, It can be overwintering on invalid body with egg spore.Mainly pass through air-flow, watering, farming and entomochory.Germ spore germination temperature is 6 ~10 DEG C, be suitable for infecting 15~17 DEG C of temperature.Field planting is overstocked, waters that too early, excessive, soil moisture is big, draining after field planting The easy morbidity such as bad.The end of spring and the beginning of summer or autumn continuous rainy weather most easily occur, and 20%~40% can be caused when disease is serious Production loss.
Powdery mildew is the plant disease as caused by the Erysiphaceae (Erysiphacesae) in fungi.Such as: by standing grain white powder Cereal powdery mildew caused by bacterium (Ery-siphegraminis)；Drawn by Siberian cocklebur monofilament shell (Sphaerothecafuliginea) The powdery mildew of the various plants such as the melon, beans, the crudefiber crop that rise；The grape as caused by grape snag shell (Uncinulanecator) Powdery mildew；Mulberry, pears, persimmon, walnut, chestnut, lichee, papaya as caused by hazel ball pin shell (Phyllactiniacorylea) etc. 80 The powdery mildew of a variety of trees；The powdery mildew etc. of the Flowers of Rosa as caused by rose monofilament shell (Sphaerothecapannosa). In the prevention and treatment of powdery mildew, the fungicide such as imidazoles, triazole type, methoxy acrylate class are relied primarily at present.These medicaments because Different degrees of drug resistance is produced to be used for a long time, control efficiency reduces.In addition, triazole type medicament is when dosage is big There is inhibiting effect to the growth of crop, is easy to cause phytotoxicity.
Epidemic disease is primarily referred to as by the fungus-caused a kind of disease of Phytophthora (Phytophthora), mainly cause plant flowers, Fruit, leaf portion tissue it is quick necrosis and it is rotten.High humidity is the principal element for influencing disease and occurring and propagating.Wherein capsicum epidemic disease, Melon epidemic disease and the late blight of potato are important diseases.
Medicament currently used for prevention and treatment downy mildew, powdery mildew and epidemic disease mainly has Propineb, cymoxanil, dimethomorph, fluorine Morpholine, Bravo, metalaxyl, fluazinam, fluopicolide, benzene metsulfovax.
Above-mentioned anti-downy mildew, powdery mildew and epidemic disease medicament have produced different degrees of drug resistance because being used for a long time, and prevent Effect reduction is controlled, it is increasing that dose is administered alone.A large amount of uses of medicament increase pesticide residue simultaneously.Endanger food peace Entirely, environmental pollution is aggravated.Therefore by different role mechanism it is bactericide compounded by be science, the rational use of medicines development need.
By research, the chloro- 2- of compound A, that is, 4- (1,1- dimethyl ethyl) -5- [[[4- (1,1- dimethyl ethyl) is found Phenyl] methyl] sulfenyl] -3 (2H)-pyridazinones are to downy mildew, late blight, the epidemic disease occurred on veterinary antibiotics and field crop Disease, samping off, powdery mildew, rust, anthracnose, root rot, balck shank etc. have good control efficiency.In order to avoid individually making With the defect to develop drug resistance, compound A and the fungicide of different role mechanism are subjected to rational mixture, there is significant synergy Effect improves control efficiency, reduces spraying times and dosage, additionally aids the generation for avoiding germ resistance and delay anti-medicine The generation speed of property, the problems such as can solve the resistance in pesticide single dose application process.
Summary of the invention
Aiming at the problems existing in the prior art, the present invention provides a kind of fungicide and combinations thereof, significantly improves prevention and treatment Effect reduces spraying times and dosage, and the generation speed for additionally aiding the generation for avoiding germ resistance and delaying drug resistance can The problems such as to solve the resistance in pesticide single dose application process.
In order to solve the above technical problems, the invention adopts the following technical scheme:
A kind of fungicide, for the fungicide using compound A as active constituent, the compound A is the chloro- 2- (1,1- of 4- Dimethyl ethyl) -5- [[[4- (1,1- dimethyl ethyl) phenyl] methyl] sulfenyl] -3 (2H)-pyridazinones.
A kind of microbicide compositions, the microbicide compositions be using synergistic effective quantity include following compound as Active component:
1) the chloro- 2- of compound A:4- (1,1- dimethyl ethyl) -5- [[[4- (1,1- dimethyl ethyl) phenyl] methyl] sulphur Base] -3 (2H)-pyridazinones；With 2) at least one reactive compound B selected from the group below:
N-butylamine (butylamine)；Cymoxanil (cymoxanil)；Cymoxanil (cymoxanil)；Dodine (dodine)；Guanoctine (guazatine)；Biguanide spicy acid salt (iminoctadine)；M 9834 (benalaxyl)；Refining benzene White spirit (Benalaxyl-M)；Benodanil (benodanil)；Benzohydroxamic acid (benzohydroxamic acid)；N-(3′, 4 '-two chloro- 5- fluorine hexichol -2- bases) -3- (difluoromethyl) -1- methylpyrazole -4- formamide (bixafen)；Carboxin (carboxin)；Ring propionyl bacterium amine (carpropamid)；Imugan (chloraniformethan)；Ring bacterium amine (cyclafuramid)；Cyflufenamid (cyflufenamid)；Benzene flusulfamide (dichlofluanid)；Double chlorine zarilamid (diclocymet)；Dimethomorph (dimethomorph)；Fenfuram (fenfuram)；Fenhexamid (fenhexamid)； Fenoxanil (fenoxanil)；(3S, 6S, 7R, 8R) -8- benzyl -3- { 3- [(isobutyryl oxygen) methoxyl group] -4- methoxyl group pyrrole Pyridine -2- formamido } -6- methyl -4,9- dioxo -1,5- dioxy nonyl ring -7- base isobutyrate (fenpicoxamid)；Cough up bacterium Nitrile (fludioxonil)；Fluorine biphenyl bacterium (flumetover)；Flumorph (flumorph)；Fluopicolide (fluopicolide)； Fluorine pyrrole bacterium ester (fluopicolpkd)；Fluorine ether bacterium amide (fluopimomide)；Fluopyram (fluopyram)；Flusulfamide (flusulfamide)；Flutolanil (flutolanil)；Furalaxyl (furalaxyl)；Furan pyrazoles is clever (furametpyr)；Diformazan Ofurace (furcarbanil)；It dresses seed amine (furmecyclox)；N- [1,1- dimethyl -2- (4- isopropoxy-neighbour's toluene Base) -2- oxoethyl] -3 methyl thiophene -2- formamide (isofetamid)；(RS) -2- methoxy-. N-methyl -2- [α-(2, 5- xylyloxy)-o- tolyl] acetamide (mandestrobin)；Mandipropamid (mandipropamid)；Mebenil (mebenil)；Third oxygen, which goes out, embroiders amine (mepronil)；Metalaxyl (metalaxyl)；Metalaxyl-M (metalaxyl-M)；Methuroxam (methfuroxam)；Fenfuram (ofurace)；Oxycarboxin (oxycarboxin)；Fluorine azoles bacterium aniline (penflufen)；Pyrrole metsulfovax (penthiopyrad)；Pyracarbolin (pyracarbolid)；(Z)-N- { 2- [chloro- 5- (ring of 3- Propylacetylene base) -2- pyridyl group] -2- (isopropoxy imino group) ethyl } -3- (difluoromethyl) -1- methyl-1 H- pyrazoles -4- Formamide (pyrapropoyne)；[N- (3 ', 4 '-DfBP -2- base) -3- (trifluoromethyl) pyrazine -2- formamide] (pyraziflumid)；Quinazamid (quinazamid)；Salicylanilide (salicylanilide)；Fluorine azoles ring bacterium amine (sedaxane)；Silthiopham (silthiofam)；Tecloftalam (tecloftalam)；Thifluzamide (thifluzamide)；Thiophene Acyl bacterium amine (tiadinil)；Sulphur benzonitrile formamide (tioxymid)；First flusulfamide (tolnifanide)；Toluene flusulfamide (tolylfluanid)；Trichlamide (trichlamide)；Triforine (triforine)；Downy mildew goes out (valifenalate)； Vangard (vangard)；Zarilamid (zarilamid)；Zoxamide (zoxamide)；Aureofungin (aureofungin)； Blasticidin-S (blasticidin S)；Cycloheximide (cycloheximide)；Griseofulvin (griseofulvin)；Kasugarnycin (kasugamycin)；Moroxydine (moroxydine)；Viscous thiazole (myxothiazol)；Natamycin (natamycin)；It is mostly anti- Mycin (polyoxin)；Polyoxin (polyoxorim)；Streptomysin (streptomycin)；Valida (validamycin)；Biphenyl (biphenyl)；Chlorine nitre naphthalene (chlorodinitronaphthalenes)；Chloroneb (chloroneb)；Bravo (chlorothalonil)；Guaiacol (cresol)；Botran (dicloran)；Phenol bacterium ketone (fenjuntong)；Hexachloro-benzene (hexachlorobenzene)；Pentachlorophenol (pentachlorophenol)；Pentachloronitrobenzene (quintozene)；Penta sodium pentachlorophenate (sodium pentachlorophenate)；Tecnazene (tecnazene)；Thiocyanogen Dinitrobenzene (thiocyanatodinitrobenzenes)；Pyrimidone (pyriofenone)；Metrafenone (metrafenone)； Thiophanate-methyl (thiophanate-methyl)；Thiophanate methyl (thiophanate-methyl)；Furan first thiophanate (furophanate)；Benzene metsulfovax (benthiavalicarb-isopropyl)；Pest of going out azoles (chlobenthiazone)；Two Discrimination bacillus (dichlobentiazox)；Probenazole (probenazole)；Benzene metsulfovax (benthiavalicarb- isopropyl)；Pest of going out azoles (chlobenthiazone)；Two discrimination bacillus (dichlobentiazox)；Furan first thiophanate (furophanate)；Probenazole (probenazole)；Thiophanate-methyl (thiophanate-methyl)；Diethofencarb (diethofencarb)；Butylamino formic acid iodopropynyl ester (iodocarb)；Iprovalicarb or iprovalicarb (iprovalicarb)；(6- { [(Z)-(methyl-1 H-5- tetrazole radical) (phenyl) methylene] aminooxymethyl } -2- pyridine Base) carbamic acid spy butyl ester (picarbutrazox)；Propamocarb (propamocarb)；Prothiocarb (prothiocarb)；2,2, 2- trifluoroethyl (S)-[2- methyl-1-(p- toluoyl aminomethyl) propyl] carbamate (tolprocarb)；Maneb (maneb)；Carbatene (metiram)；Polycarbamate (polycarbamate)；Zineb (zineb)；Ambam (amobam)；Azithiram (azithiram)；Carbamorph (carbamorph)；Dazomet (dazomet)；Disulfiram (disulfiram)；Ethisul (etem)；Fervam (ferbam)；Mancozeb (mancozeb)；Metham-sodium (metam)；Generation Gloomy ring (milneb)；Dithane A40 (nabam)；Propineb (propineb)；Aateck (tecoram)；Thiram (thiram)；Suppression Mould azoles (imazalil)；It dislikes imidazoles (oxpoconazole)；Efficient imazalil (S-imazalil)；Fluorine bacterium azoles (triflumizole)；Climbazole (climbazole)；Clotrimazole (clotrimazole)；Fenamidone (fenamidone)；Fenapanil (fenapanil)；Furidazol (fuberidazole)；Glyodin (glyodin)；Pefurazoate (pefurazoate)；Prochloraz (prochloraz)；Apl-Luster (thiabendazole)；Triazoxide (triazoxide)；Ah Parbendazole (albendazole)；Benomyl (benomyl)；Carbendazim (carbendazim)；2- (2- chlorphenyl) -1H- benzo Imidazoles -2 (chlorfenazole)；Cypendazole (cypendazole)；Debacarb (debacarb)；N- [methyl 1- (2- methyl sulphur Base ethylaminocarbonyl) benzimidazolyl-2 radicals-yl) methyl carbamate (mecarbinzid)；Pyrrole imidazoles (rabenzazole)； Azoles mepanipyrim (ametoctradin)；Amisulbrom (amisulbrom)；Bitertanol (bitertanol)；Bromuconazole (bromuconazole)；Cyproconazole (cyproconazole)；Difenoconazole (difenoconazole)；Olefin conversion (diniconazole)；Epoxiconazole (epoxiconazole)；Etaconazole (etaconazole)；Benzoxazole (fenbuconazole)；Fluotrimazole (fluotrimazole)；Fluquinconazole (fluquinconazole)；Flusilazole (flusilazole)；Flutriafol (flutriafol)；Furconazole (furconazole)；Furconazole_cis (furconazole-cis)； Hexaconazole (hexaconazole)；Glyoxalin (imibenconazole)；Kind bacterium azoles (ipconazole)；Different Fluconazole (ipfentrifluconazole)；Cresol Fluconazole (mefentrifluconazole)；Metconazole (metconazole)；Nitrile Bacterium azoles (myclobutanil)；Penconazole (penconazole)；Propiconazole (propiconazole)；Prothioconazoles (prothioconazole)；Simeconazoles (simeconazole)；Tebuconazole (tebuconazole)；Tetraconazole (tetraconazole)；Triazolone (triadimefon)；Triadimenol (triadimenol)；Butrizol (triazbutil)；It goes out Bacterium azoles (triticonazole)；Uniconazole P (uniconazole)；High uniconazole P (uniconazole-P)；Famoxate (famoxadone)；Hymexazol (hymexazol)；Cyazofamid (cyazofamid)；Wakil (oxadixyl)；Oxazole (acetoxazole)；Drazoxolon (drazoxolon)；Hydrazine pitches oxazolone (metazoxolon)；Fluorine thiazole pyrrole ethyl ketone (oxathiapiprolin)；Vinclozolin (vinclozolin)；Pungent capric acid copper (acypetacs-copper)；Basic carbonate Copper (basic copper carbonate)；Basic copper sulfate (basic copper sulfate)；Bordeaux mixture (bordeaux mixture)；Burgundy mixture (burgundy mixture)；Cheshunt mixture (cheshunt mixture)；Acetic acid Copper (copper acetate)；Kocide SD (copper hydroxide)；Copper naphthenate (copper naphthenate)；Oil Sour copper (copper oleate)；Copper oxychloride (copper oxychloride)；Cupric silicate (copper silicate)；Sulfuric acid Copper (copper sulphate)；Copper zinc chromate (copper zinc chromate)；Nonylphenolsulfonate copper (cuppric nonyl phenolsulfonate)；Cuprobam (cuprobam)；Cuprous oxide (cuprous oxide)；Mancopper (mancopper)；Copper 8-hydroxyquinolinate (oxine-copper)；Difoltan (captafol)；Captan (captan)；Chlozolinate (chlozolinate)；Sclex (dichlozoline)；Dimethachlon (dimethachlon)；Folpet (folpet)；Different bacterium Urea (iprodione)；Chlorobenzene Climbazole (isovaledione)；Myclozolin (myclozolin)；Procymidone (procymidone)；Sulphur chlorobenzene imines (thiochlorfenphim)；Binapacryl (binapacryl)；Dinobuton (dinobuton)；Dinocap (dinocap)；Dinocton (dinocton)；Dinopenton (dinopenton)；Dinosulfon (dinosulfon)；Dinoterbon (dinoterbon)；Chemox PE (DNOC)；The mite that disappears is more (meptyldinocap)；Carbon disulfide (carbon disulfide)；Dimethyl disulfide (dimethyl disulfide)；Bromomethane (methyl bromide)；First Base iodine (methyl iodide)；Sodium thiocarbonate (sodium tetrathiocarbonate)；Benquinox (benquinox)； Sulphur (sulfur)；4- dodecyl -2,6- thebaine (aldimorph)；Antibacterial quinoline (benzamorf)；12 rings Quinoline (dodemorph)；Butadiene morpholine (fenpropimorph)；Tridemorph (tridemorph)；The third phosphoric acid of ammonia (ampropylfos)；Plondrel (ditalimfos)；Kitazine (EBP)；Hinosan (edifenphos)；Fosetyl (fosetyl)；Fosetyl aluminium (fosetyl-Aluminum)；Hexamethylene sulphur phosphorus (hexylthiofos)；Inezin (inezin)；It is different Kitazine (iprobenfos)；Izopamfos (izopamfos)；Phosdiphen (phosdiphen)；Phosphorous acid (Phosphorous ) and its salt acid；Ppyrazophos (pyrazophos)；Tolelofos-methyl (tolclofos-methyl)；Triamiphos (triamiphos)；Decafentin (decafentin)；Fentinacetate (fentin-acetate)；Fentin (fentin)；Tributyl Tin oxide (tributyltin oxide)；Solbar (barium polysulfide)；Lime sulfur (calcium polysulfide)；Potassium polysulfide (potassium polysulfide)；Sodium polysulfide (sodium polysulphide)；Benzene And alkene fluorine bacterium azoles (benzovindiflupyr)；Amine benzene pyrrole bacterium ketone (fenpyrazamine)；Fluorobenzene pyrrole bacterium amine (fluxapyroxad)；3- (difluoromethyl)-N- [(R) -2,3- dihydro -1,1,3- trimethyl -1H- indenes -4- base] -1- methyl pyrrole Azoles -4- formamide (inpyrfluxam)；The fluoro- 1- of N- (5- chloro-2-isopropyl benzyl)-N- cyclopropyl -3- (difluoromethyl) -5- Methyl-1 H- pyrazole-4-carboxamide (isoflucypram)；Isopyrazam (isopyrazam)；Fluorine azoles bacterium acyl azanol (pydiflumetofen)；Pyraoxystrobin (pyraoxystrobin)；The chloro- 4- of 3- (2,6- difluorophenyl) -6- methyl -5- phenyl is rattled away Piperazine (pyridachlometyl)；4- phenoxy benzyl 2- amino -6- methylnicotinic acid ester (aminopyrifen)；Boscalid (boscalid)；The phonetic bacterium of sulphur is clever (bupirimate)；Buthiobate (buthiobate)；Dipyrithione (dipyrithione)； Fluazinam (fluazinam)；Pyridine bacterium amine (peip)；Pyrrole bacterium benzene prestige (pyribencarb)；Pyridinitril (pyridinitril)；Pyridine Spot oxime (pyrifenox)；Oxazole (pyrisoxazole)；Pyrrole chlorine is clever (pyroxychlor)；Chlorine pyrrole furan ether (pyroxyfur)；Cyprodinil (cyprodinil)；Fluorine mepanipyrim (diflumetorim)；Milcurb (dimethirimol)； Milstem (ethirimol)；Fenarimol (fenarimol)；Ferimzone (ferimzone)；Mepanipyrim (mepanipyrim)； Nuarimol (nuarimol)；Pyrimethanil (pyrimethanil)；Triarimol (triarimol)；Fenpiclonil (fenpiclonil)；Fluoromide (fluoroimide)；8-hydroxyquinoline (8-hydroxyquinoline sulfate)； Spergon (chloranil)；Dichlone (dichlone)；Dithianon (dithianon)；Ethoxyquin (ethoxyquin)；Halacrinate (halacrinate)；2 [2- (the fluoro- 2- methylquinoline -3- oxygroup of 7-8- bis-) -6- fluorine Phenyl] propyl alcohol -2- alcohol (ipflufenoquin)；The third oxygen quinoline (proquinazid)；1- (8- hydroxyl -5- quinoline) ethyl ketone (quinacetol)；The fluoro- 3,3- dimethyl -1- quinoline -3- isoquinolin (quinofumelin) of 4,4- bis-；Quinoxyfen (quinoxyfen)；Isobutyl ethoxyquin (tebufloquin)；Oxolinic acide (chinomethionat)；Lucel (chlorquinox)；Eradex (thioquinox)；The gloomy copper of thiophene (saisentong)；Thiodiazole-copper (thiodiazole- copper)；Zinc thiazole (zinc thiazole)；Benthiozole (benthiazole)；Yekuzuo (bismerthiazol)；Thiophene Azoles bacterium amine (ethaboxam)；Grandox fumigant (etridiazole)；Isotianil (isotianil)；Metsulfovax (metsulfovax)；Octhilinone (octhilinone)；Third azoles grass is grand (bentaluron)；Pencycuron (pencycuron)；Second Acetylcholinesterase-zinc (acypetacs-zinc)；Cufraneb (cufraneb)；Polyoxin D zinc salt (polyoxorim- zinc)；Naphthalene acid zinc (zinc naphthenate)；Zinc trichlorophenate (zinc trichlorophenate)；Ziram (ziram)； Bithionol (bithionol)；Antiphen (dichlorophen)；Diphenylamines (diphenylamine)；Hexachlorophene (hexachlorophene)；Felodipine (parinol)；First fragrant bacterium ester (coumethoxystrobin)；Coumoxystrobin (coumoxystrobin)；Dimoxystrobin (dimoxystrobin)；Enestroburin (enestroburin)；Alkene oxime amine (fenaminstrobin)；Fluorine bacterium mite ester (flufenoxystrobin)；Fluoxastrobin (fluoxastrobin)；Kresoxim-methyl (kresoxim-methyl)；SSF 126 (metominostrobin)；Orysastrobin (orysastrobin)；ZEN 90160 (picoxystrobin)；Pyraclostrobin (pyraclostrobin)；Azoles amine bacterium ester (pyrametostrobin)；Chlorine nalidixic bacterium ester (triclopyricarb)；Trifloxystrobin (trifloxystrobin)；Thiophene bacterium is luxuriant (saijunmao)；Isoprothiolane (isoprothiolane)；Two furan of thiophene (thiadifluor)；Fluorine thiazole bacterium nitrile (flutianil)；Allicin (allicin)；It is small Bark of a cork tree alkali (berberine)；Carvacrol (carvacrol)；Carvol (carvone)；Osthole (osthol)；Sanguinarine (sanguinarine)；Fennel artemisin (santonin)；N- (4 '-bromo biphenyl -2- base) -4- difluoromethyl -2- methylthiazol -5- first Amide；N- (4 '-trifluoromethyl-biphenyl -2- base) -4- difluoromethyl -2- methylthiazol -5- formamide；N- (4 '-chloro- 3 '-fluorine connection Benzene -2- base) -4- difluoromethyl -2- methylthiazol -5- formamide；N- (3 ', 4 '-two chloro- 4- fluorine biphenyl -2- base) -3- difluoro first Base -1- methylpyrazole -4- formamide；N- (the chloro- 5- fluorine biphenyl -2- base of 3', 4'- bis-) -3- difluoromethyl -1- methylpyrazole -4- Formamide；3,4- bis- chloro- N- (2- cyano-phenyl) isothiazole -5- formamide；N- (2- { 4- [3- (4- chlorphenyl) propyl- 2- alkynes oxygen Base] -3- anisyl } ethyl) -2- methanesulfonamido -3- methylbutyryl amine；N- (2- { 4- [3- (4- chlorphenyl) -propyl- 2- alkynes Oxygroup] -3- anisyl } ethyl) -2- second sulfonamido -3- methylbutyryl amine；Thiadiazoles element (acibenzolar-S- methyl)；Astromicin (astromicin)；Benziothiazolinone (benziothiazolinone)；Brassin lactones (brassinolide)；Cycocel (chlormequat)；Gibberellin (gibberellin)；Three octyl benzene sulfonate of biguanides (iminoctadine trialbesilate)；Oxolinic acid (oxolinic acid)；Adjust naphthenic acid (prohexadione) and its Salt；2- butylamine (sec-Butylamine)；O- phenylphenol sodium (sodium o-phenylphenoxide)；TrinexAN_SNacethyl (trinexapac-ethyl)；Triforine (triforine)；
The active component 1) and active component 2) quality proportioning be 1:100-100:1.
The single dose content of the compound A is 0.1-95.
Preferably, the active component 2) be at least one reactive compound B selected from the group below:
Bitertanol (bitertanol)；Bromuconazole (bromuconazole)；Difenoconazole (difenoconazole)；Olefin conversion (diniconazole)；Flusilazole (flusilazole)；Flutriafol (flutriafol)； Hexaconazole (hexaconazole)；Nitrile bacterium azoles (myclobutanil)；Penconazole (penconazole)；Propiconazole (propiconazole)；Prothioconazoles (prothioconazole)；Simeconazoles (simeconazole)；Tebuconazole (tebuconazole)；Fluorine ether azoles (tetraconazole)；Fluorine bacterium azoles (triflumizole)；Cyproconazole (cyproconazole)；Epoxiconazole (epoxiconazole)；Fluquinconazole (fluquinconazole)；Triadimenol (triadimenol)；Imazalil (imazalil)；It dislikes imidazoles (oxpoconazole)；Famoxate (famoxadone)；Fluorine pyridine Amine (fluazinam)；Oxazole (Acetoxazole)；Chinomethionat (chinomethionat)；The third oxygen quinoline (proquinazid)；Quinoxyfen (quinoxyfen)；Azoles mepanipyrim (ametoctradin)；Cyproconazole (cyproconazole)；Oxole bacterium (epoxiconazole)；Fluquinconazole (fluquinconazole)；Cycltebuconazole (ipconazole)；Penta azoles bacterium (metconazole) of ring；Triazolone (triadimefon)；Triadimenol (triadimenol)；Penta It pitches bacterium azoles (triticonazole)；Prochloraz (prochloraz)；Enzyme (imazalil)；Benomyl (benomyl)；It is more Bacterium spirit (carbendazim)；Apl-Luster (thiabendazole)；Furidazol (fuberidazole)；Kobam (etridiazole)；Hydroxyisoxazole (hymexazole)；Oxygen ring azoles (azaconazole)；Efficient olefin conversion (diniconazole)；Benzoxazole (fenbuconazole)；Kind bacterium azoles (ipconazole)；Metconazole (metconazole)； Tetraconazole (tetraconazole)；Triticonazole (triticonazole)；Efficient imazalil (imazalil)；Pefurazoate (pefurazoate)；Hymexazol (hymexazol)；Grandox fumigant (etridiazole)；Octhilinone (octhilinone)；Benzene thiophene Sulphur cyanogen (benthiazole)；Dithianon (dithianon)；Ethoxyquin (ethoxyquin)；Oxyquinoline (hydroxyquinoline sulfate)；Viscous thiazole (myxothiazol)；Yekuzuo (bismerthiazol)；Phenyl allyloxy thiophene Azoles (probenazole)；High uniconazole P (uniconazole-P)；Uniconazole P (uniconazole)；Furconazole_cis (furconazole-cis)；Furconazole (furconazole)；Etaconazole (etaconazole)；Butrizol (triazbutil)； Fluotrimazole (fluotrimazole)；Climbazole (climbazole)；Clotrimazole (clotrimazole)；Different Fluconazole (ipfentrifluconazole)；Cresol Fluconazole (mefentrifluconazole)；Flumorph (flumorph)；Alkene acyl Quinoline (dimethomorph)；Bravo (chlorothalonil)；Mancozeb (mancozeb)；Cymoxanil (cymoxanil)； Cyazofamid (cyazofamid)；Fluopicolide (picobenzamid)；Propamocarb (propamocarb)；Metalaxyl (metalaxyl)；Famoxate (famoxadone)；Benziothiazolinone (benziothiazolinone)；Zoxamide (zoxamide)；Pyraclostrobin (pyraclostrobin)；Fluoxastrobin (azoxystrobin)；Fluorine thiazole pyrrole ethyl ketone (oxathiapiprolin)；Aliette (fosetyl aluminum)；Nonylphenolsulfonate copper；Propineb (propineb)；Zineb (zineb)；Enestroburin (enestroburin)；Bupirimate (enestroburin)；Ethirimol (ethirimol)； Kresoxim-methyl (kresoxim-methyl)；Isopyrazam (isopyrazam)；Fluxapyroxad (fluxapyroxad)；Pyridine acyl Bacterium amine (boscalid)；Three octyl benzene sulfonate of biguanides (iminoctadine trialbesilate)；Polyoxin (polyoxin)；Astromicin (astromicin)；Jamaicin (berberine)；Thiophanate-methyl (thiophanate methyl)；Mandipropamid (mandipropamid).
Preferably, the active component 2) be at least one reactive compound B selected from the group below:
Flusilazole (flusilazole)；Flutriafol (flutriafol)；Nitrile bacterium azoles (myclobutanil)；Propiconazole (propiconazole)；Tebuconazole (tebuconazole)；Epoxiconazole (epoxiconazole)；Triazolone (triadimefon)；Carbendazim (carbendazim)；Hymexazol (hymexazol)；Flumorph (flumorph)；Dimethomorph (dimethomorph)；Bravo (chlorothalonil)；Mancozeb (mancozeb)；Cymoxanil (cymoxanil)；Cyanogen White azoles (cyazofamid)；Fluopicolide (picobenzamid)；Propamocarb (propamocarb)；Metalaxyl (metalaxyl)；Famoxate (famoxadone)；Benziothiazolinone (benziothiazolinone)；Zoxamide (zoxamide)；Fluazinam (fluazinam)；Pyraclostrobin (pyraclostrobin)；Fluoxastrobin (azoxystrobin)； Fluorine thiazole pyrrole ethyl ketone (oxathiapiprolin)；Aliette (fosetyl aluminum)；Nonylphenolsulfonate copper；Propineb (propineb)；Zineb (zineb)；Enestroburin (enestroburin)；Bupirimate (enestroburin)；Second Phonetic phenol (ethirimol)；Kresoxim-methyl (kresoxim-methyl)；Isopyrazam (isopyrazam)；Fluxapyroxad (fluxapyroxad)；Difenoconazole (difenoconazole)；Boscalid (boscalid)；Three octyl benzene sulphur of biguanides Hydrochlorate (iminoctadine trialbesilate)；Polyoxin (polyoxin)；Astromicin (astromicin)；Barberry Alkali (berberine)；Thiophanate-methyl (thiophanate methyl)；Mandipropamid (mandipropamid).
The active component 1) and active component 2) quality proportioning be 1:50-50:1.
The active component 1) and active component 2) quality proportioning be 1:25-25:1.
Active component 1) and active component 2) quality proportioning be 1:10-10:1.
Active component 1) and active component 2) quality proportioning be 1:5-5:1.
The bactericidal composition also includes surfactant and/or filler.
The active component 1) and active component 2) content account for the 5%-90% of bactericidal composition.
Describedization active component 1) and active component 2) content account for the 10%-80% of bactericidal composition.
The active component 1) and active component 2) content account for the 20%-60% of bactericidal composition.
Downy mildew of the fungicide for occurring on veterinary antibiotics and field crop, late blight, epidemic disease, samping off, The prevention and treatment of powdery mildew, rust, anthracnose, root rot, balck shank.
The prevention and treatment of downy mildew, powdery mildew, epidemic disease that the fungicide occurs on veterinary antibiotics and field crop.
Downy mildew of the microbicide compositions for occurring on veterinary antibiotics and field crop, late blight, epidemic disease, The prevention and treatment of samping off, powdery mildew, rust, anthracnose, root rot, balck shank.
Downy mildew of the microbicide compositions for occurring on veterinary antibiotics and field crop, epidemic disease powdery mildew Prevention and treatment.
The dosage form of bactericidal composition of the present invention is missible oil, aqueous suspension agent, oil-suspending agent, wettable powder, water dispersible granular Agent, microemulsion, aqueous emulsion, microcapsules, dry suspending agent or suspoemulsion.The preparation of the invention can will be described by known way Reactive compound is mixed with conventional additives and is prepared.The conventional additives such as routine extender and solvent or diluent, Emulsifier, dispersing agent, and/or adhesive or fixative, wetting agent, waterproofing agent, if it is desired, can also comprising drier and Toner, stabilizer, pigment, defoaming agent, preservative, thickener, water and other processing aids.
Composition of the invention has good plant tolerance under concentration needed for controlling plant diseases, this is allowed for can To the aerial part of plant, breeds strain (propagationstock), seed and soil in vitro and handle.Group of the invention Close object can also foliage applying or be used for seed pelleting.The present invention also provides the seeds being coated with composition of the invention.
Composition of the invention, which has, effectively kills microbial activity, and can be used in crop protection or material protection Undesired microorganism is prevented and treated, such as fungi and bacterium.We have found that compared with single compound, meanwhile, i.e., it jointly or separately applies With compound A and reactive compound B or successively application compound A and reactive compound B can preferably prevent and treat harmful fungoid, thin Bacterium (synergistic mixture).Meanwhile increasing sterilization with jointly or separately applying compound A and reactive compound B ultrasound adduction Activity.
The mixture of compound A and reactive compound B, or simultaneously, i.e., jointly or separately use compound A and active ingredient Object B is especially selected from Ascomycetes (Ascomycetes), deuteromycetes to the plant pathogenic fungi of wide scope (Deuteromycetes), the fungi of Oomycete (Oomycetes) and Basidiomycetes (Basidiomycetes) has excellent Activity.
The mixture of compound A and reactive compound B, or simultaneously, i.e., jointly or separately use compound A and active ingredient Object B can be used for preventing and treating phytopathogenic bacteria.As pseudomonad (Psedomonadaceae), rhizobium (Rhizobiaceae), Enterobacteria (Enterbacteriaceae), bar bacterium (Cornebacteriaceae) and streptomycete (Streptomycetaceae)。
Lead to fungal disease and bacteriosis as what example can propose to be included into above-mentioned generic name below in a non-limiting manner Pathogen: Flavobacterium strain, such as rice bacterial leaf spot are yellow single (Xanthomonascampestrispv.oryzae)；It is false single Born of the same parents' Pseudomonas strain, such as Bacterial leaf spot cucumber pvs oryzae and oryzicola (Pseudomonas syringaepv.Lachrymans)； Erwinia strain, such as pears water epidemic disease Irving (family name) bacterium (Erwiniaamylovora)；Rotten mould (Pythium) strain, example Such as Pythium ultimum (Pythium ultimum)；Phytophthora (Phytophthora) strain, such as phytophthora infestans (Phytophthorainfestans)；False downy mildew (Pseudoperonospora) strain, such as the false downy mildew of grass (Pseudoperonospora humuli) or Pseudoperonospora cubensis (Pseudoperonosporacubensis)；Axis downy mildew (Plasmopara) strain, such as grape are raw axis downy mildew (Plasmoparaviticola)；Disk downy mildew (Bremia) strain, such as Lettuce disk downy mildew (Bremia lactucae)；Downy mildew (Peronospora) strain, such as pea downy mildew (Peronospora ) or Cruciferae downy mildew (P.brassicae) pisi；Powdery mildew (Erysiphe) strain, such as Erysiphe graminis (Erysiphe graminis)；Sphaerotheca (Sphaerotheca) kind, such as balsamine list softgel shell (Sphaerothecafuliginea)；Fork Silk Sphaerotheca (Podosphaera) strain, such as white cross hair list softgel shell (Podosphaera-leucotricha)；Black star bacterium Belong to (Venturia) strain, such as apple black star bacteria (Venturiainaequalis)；Pyrenophora (Pyrenophora) bacterium Kind, such as round nuclear cavity bacteria (Pyrenophorateres) or wheat nuclear cavity bacteria (P.graminea) (conidial form: Drechslera, Syn:Helminthosporium)；Cochliobolus category (Cochliobolus) strain, such as standing grain cochliobolus (Cochliobolussativus) (conidial form: Drechslera, Syn:Helminthosporium)；Uromyce Belong to (Uromyces) strain, such as wart top uromyce (Uromyces-appendiculatus)；Handle rest fungus (Puccinia) bacterium Kind, such as Puccinia recondita (Puccinia recondita)；Sclerotinia (Sclerotinia) strain, such as rape sclerotium Germ (Sclerotiniasclerotiorum)；Tilletia (Tilletia) strain, such as Tilletia caries (Tilletiacaries)；Smut (Ustilago) strain, such as naked smut (Ustilago nuda) or oat smut (Ustilago avenae)；Film lead fungi category (Pellicularia) strain, such as assistant help the wooden film lead fungi (Pelliculariasasakii)；Pears spore (Pyricularia) strain, such as Magnaporthe grisea (Pyricularia oryzae)；Sickle Spore category (Fusarium) strain, such as yellow fusarium (Fusarium culmorum)；Botrytis (Botrytis) strain, example Such as Botrytis cinerea (Botrytis cinerea)；Septoria (Septoria) strain, such as phaeosphaeria nodorum (Septoria nodorum)；Leptosphaeria (Leptosphaeria) strain, such as Leptosphaeria nodorum；Cercospora (Cercospora) strain, such as graying tail spore (Cercosporacanescens)；Alternaria (Alternaria) strain, Such as rape rod method (Alternariabrassicae)；False Cercosporalla (Pseudocercosporella) strain, such as Wheat Phyllostachys pubescens (Pseudocercosporella herpotrichoides)；Phakopsora (Phakopsora) strain, example Such as Phakopsora pachyrhizi (Phakopsorapachyrhizi) and mountain horseleech layer rest fungus (Phakopsora meibomiae)；And silk Pyrenomycetes category (Rhizoctonia) strain, such as Rhizoctonia solani Kuhn (Rhizoctoniasolani).Composition of the invention is especially Suitable for preventing and treating following plant disease:
Rod method (AIternaria) on vegetables, oilseed rape, sugar beet and fruit and rice belongs to, sugar beet and vegetable Silk capsule mould (Aphanomyces) on dish belongs to, and the Bipolaris (Bipolaris) in corn, Cereal, rice and lawn belongs to and interior The compacted spore of navel (Drechslera) belongs to, the standing grain powdery mildew (Blumeria graminis) (powdery mildew) on Cereal, strawberry, vegetables, Botrytis cinerea (Botrytis cinerea) (gray mold) on flowers and grapevine, the lettuce disk on lettuce obstruct mould (Bremia Lactucae), tail spore (Cercospora) on corn and soybean, rice and sugar beet belongs to, corn, Cereal, the rotation spore on rice Chamber bacterium (Cochliobolus) belongs to (such as the standing grain cochliobolus (Cochlio bolus sativus) on Cereal, the palace on rice Portion's cochliobolus (Cochlio bolusmiyabeanus), the thorn disk spore (Colletotricum) on soybean and cotton belong to, standing grain The compacted spore of interior navel (Drechslera) in cereal and corn belongs to, and the compacted spore of prominent navel (Exserohilum) on corn belongs to, on cucumber Two spore powdery mildews (Erysiphe cichoracearum) and monofilament shell powdery mildew (Sphaerotheca fuliginea), it is various Fusarium (Fusarium) on plant belongs to and wheel branch spore (Verticillium) belongs to, the gaeumannomyce on Cereal (Gaeumanomyces graminis) belongs to, and red mould (Gibberella) on Cereal and rice belongs to that (such as the rattan storehouse on rice is red Mould (Gibberella fujikuroi)), the Gram's staining complex (Grain staining complex) on rice, corn Belong to the compacted spore of length (Helminthosporium) on rice, the Michrodochium nivale on Cereal, Cereal, banana Belong to the spherical cavity bacterium (Mycosphaerella) on peanut, the Phakopsora pachyrhizi (Phakopsora pachyrhizi) on soybean With mountain horse sulphur layer rest fungus (Phakopsara meibomiae), the Phomopsis (Phomopsis) on soybean and sunflower belongs to, soil Phytophthora infestans (Phytophthora infestans) on beans and tomato, the grape on grapevine are raw uniaxial mould (Plasmopara viticola), the apple mildew bacterium (Podosphaera leucotricha) on apple, on Cereal Wheat Phyllostachys pubescens (Pseudocercosporella herpotrichoides), the false downy mildew on hops and cucurbit (Pseudoperonospora) belong to, the handle rest fungus (Puccinia) on Cereal and corn belongs to, the nuclear cavity bacteria on Cereal (Pyrenophora) belong to, Pyricularia oryzae (the 0 η zae), Bamboo grass wood photovoltaicing leather bacteria (Corticium of Pyricularia on rice Sasakii), broom obstructs Cylindrocarpon (Sarocladium oryzae), sheath rot of rice plant (S.attenuatum), rice leaf smut (Entyloma oryzae), the piricularia oryzae (Pyricularia grisea) on lawn and Cereal, lawn, rice, corn, Rotten mould (Pythium) on cotton, oilseed rape, sunflower, sugar beet, vegetables and other plant belongs to, cotton, rice, potato, Rhizoctonia (Rhizoctonia) on lawn, corn, oilseed rape, potato, sugar beet, vegetables and other plant belongs to, oilseeds Sclerotinite (Sclerotinia) on rape and sunflower belongs to, wheat septoria (Septoria tritici) on wheat and Many spores of clever withered shell (Stagonospora nodorum), the grape snag shell (Erysiphe) on grapevine, on corn and lawn Setospaeria belong to, the silk axis smut (Sphacelotheca reilinia) on corn, the root string on soybean and cotton Pearl mould (Thievaliopsis) belongs to, and the Tilletia foetida (Tilletia) on Cereal belongs to, on Cereal, corn and sugar beet Smut (Ustilago) belong to, the black star bacterium (Venturia) on apple and pears belongs to (scab).
Composition of the invention to various crops such as cotton, vegetable variety (such as cucumber, beans, tomato, potato and Cucurbitaceous plant), barley, dogstail, oat, banana, coffee, corn, fruit variety, rice, rye, soybean, grapevine, wheat, A large amount of fungies are prevented and treated in ornamental plant, peanut, rape, sugarcane and various seeds to be even more important.
Composition of the invention is particularly suitable for preventing and treating following plants pathogenic epiphyte: the standing grain powdery mildew in Cereal (Blumeria graminis) (powdery mildew), the two spore powdery mildews (Erysiphe cichoracearum) in cucurbitaceous plant With monofilament shell (Sphaerotheca fuliginea), apple mildew bacterium (Podosphaera in apple Leucotricha), the grape snag shell mildew (Uncinula necator) in grapevine, the handle rest fungus in Cereal (Puccinia) belong to, the rhizoctonia (Rhizoctonia) in cotton, rice and lawn belongs to, the smut in Cereal and sugarcane (Ustilago) belong to, the venturia inaequalis (Venturia inaequalis) (scab) in apple, the compacted spore of length in Cereal (Helminthosporium) belong to, the wheat glume blotch bacterium (Septorianodorum) in wheat, strawberry, vegetables, ornamental plant With the Botrytis cinerea (Botrytiscinerea) (gray mold) in grapevine, Cercosporaarachidicola (Cercospora in peanut Arachidicola), the eye spot bacterium in wheat and barley (Pseudocercosporella Herpotrichoides), rice In Pyricularia oryzae (Pyriculariaoryzae), the phytophthora infestans (Phytophthora in potato and tomato Infestans), the grape single shaft in grapevine is mould (Plasmopara viticola), the false downy mildew in hops and cucumber (Pseudoperonospora) belong to, the spherical cavity bacterium in rod method (Alternaria) category, banana in vegetables and fruit (Mycosphaerella) category and Neurospora (Fusarium) and wheel branch spore (Verticillium).
Composition of the invention is particularly suitable for preventing and treating downy mildew, powdery mildew, epidemic disease, samping off, rust, anthracnose.
Composition of the present invention shows low toxicity and excellent plant tolerance.All plants and plant portion Position can be handled according to the present invention.The meaning of plant should be understood all plant and plant population in the present invention, such as Wild plant need and unwanted or crop plants (crop plants including naturally occurring).Crop plants, which can be, to be passed through Conventional plant breeding and optimum seeking method are obtained by biotechnology and genetic engineering method or by the combination of the method Plant, including genetically modified plants also include the plant variety being weighed protection by plant seedling or not being protected by it.Plant parts contain Justice should be understood all grounds of plant and underground position and plant organ, such as bud, leaf, Hua Hegen, specifiable example There are leaf, needle, stem, dry, flower, fructification, fruit, seed, root, stem tuber and rhizome.Plant parts further include harvested material, and Asexual and sexual plant propagation material, such as rice shoot, stem tuber, rhizome, cutting and seed.
According to plant variety or plant cultivars, its planting site and growth conditions (soil, weather, vegetation period, battalion Support), processing of the invention also can produce superadditivity (collaboration) effect.Thus the following effect more than actual desired can be obtained Fruit, such as the amount of application of the present composition can be reduced and/or widen its action spectrum and/or improve its activity, improve plant life Long situation, improve high temperature or cold tolerance, raising to arid or to the tolerance of salt content in water or in soil, improve and bloom Quality makes simpler harvesting, hasting of maturity, improves yield, improving the quality of harvested products and/or improve its nutritive value, change The Storage property and/or its processing performance of kind harvested products.
According to the present invention, processing plant and plant parts carried out using compound according to conventional treatment method directly into Row, or realized by handling its local environment, habitat or storage space, the conventional treatment method such as immersion liquid, spraying, steaming Hair atomizing, is broadcasted sowing, is smeared；For propagation material, especially seed, one or more layers coating can be also carried out.
Preferred method of administration is to be administered to aboveground vegetation part, especially foliage applying；Application times and application rate Biology and weather life condition depending on objective microbe.However, active constituent can also pass through root system via soil or water Reach in plant, thus can pour location with liquid preparation or the substance is mixed in soil in solid form.This hair Bright composition can also be administered on seed-grain in seed treatment, and thus the liquid of every kind of active constituent can be used in stem tuber or cereal Preparation successively impregnates, or is wrapped up with the wet or dry preparation mixed.
Effective component mix plant site, such as in the form of granules mix soil in (soil application), effectively at Inside plants (systemic action) can also be entered by root system by dividing.The described plant when being implemented application method of the invention Soil or cultivation medium be the supporter for referring to make crops take root, grow, such as: soil, water etc., specific raw material It can be used such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, sawdust, bark.
When preparing mixture, it is preferable to use pure reactive compound ,if needed can be by them and confrontation harmful fungoid Other pests such as insect, spider or nematode other reactive compounds or weeding or growth regulating as other active components Reactive compound or fertilizer mixing.
In a preferred embodiment of the invention, using the mixture of compound A and reactive compound B.In certain conditions Under, it can be advantageous that it combines compound A with two or more reactive compounds B.
Compound A and reactive compound B is excellent usually with 100:1-1:100, preferably 50:1-1:50, preferably 25:1-1:25 The weight ratio of 10:1-1:10, especially 5:1-1:5 is selected to use.
Depending on the type and required effect of compound, the rate of application of inventive mixture is 5-2000g/ha, preferably 50- 900g/ha, especially 50-750g/ha.Correspondingly, the rate of application of compound A is usually 1-1000g/ha, preferably 10-900g/ Ha, especially 20-750g/ha.
In the seed treatment for example by dusting, coating or immersion seed, the rate of application of mixture is usually 1- 1000g/100kg seed, preferably 1-750g/100kg, especially 5-500g/100kg.
Prevent and treat harmful fungoid method by before or after plant seeding or before or after plant emergence to seed, Plant or soil are sprayed or dusting is to separate or be administered in combination compound A and reactive compound B or compound A and reactive compound The mixture of B and carry out.
Mixture of the invention or compound A and reactive compound II can be converted to general configuration agent, such as solution, Lotion, suspension, pulvis, powder, paste and particle.Use form depends on specifically being intended to purpose, in each case should be true It protects the compounds of this invention finely and is evenly distributed.
Preparaton is prepared in known manner, such as is prepared and mixing reactive compound with solvent and/or carrier, Emulsifier and dispersing agent are used if needing.Solvent/auxiliary agent suitable to the purpose is main are as follows:
Water, arsol (such as Solvesso product, dimethylbenzene), paraffin (such as mineral oil fractions), alcohols (such as methanol, fourth Alcohol, amylalcohol, benzylalcohol), ketone (such as cyclohexanone, gamma-butyrolacton), pyrrolidones (NMP, NOP), acetic acid esters (ethylene glycol oxalic acid Ester), dihydric alcohol, fatty acid dimethylamides, fatty acid and aliphatic ester.Solvent mixture can also be used in principle.
The natural minerals (such as kaolin, clay, talcum, chalk) and synthetic mineral (such as height ground that carrier is such as ground Silica, the silicate of dispersion)；Emulsifier such as nonionic and anion emulsifier (such as polyoxyethylene aliphatic alcohol ether, alkylsulfonate And arylsulphonate) and dispersing agent such as lignin sulfite waste liquor and methylcellulose.
Suitable surfactant used is the alkali metal of lignosulphonic acid, naphthalene sulfonic acids, phenolsulfonic acid, dibutyl naphthalenesulfonic acid Salt, alkali salt and ammonium salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, aliphatic alcohol sulfate, fatty acid With sulphated fatty alcohol glycol ether, there are also the condensation product of sulfonated naphthalene and naphthalene derivatives and formaldehyde, naphthalene or naphthalene sulfonic acids and phenol and The condensation product of formaldehyde, NONIN HS 240, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol, the poly- second two of alkyl phenyl Alcohol ether, tributyl phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, pure and mild fatty alcohol/oxygen Change ethylene condensation product, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether Acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.
Suitable for prepare can Direct spraying solution, lotion, paste or oil dispersion substance be mid-boiling point to high boiling mineral Oil distillate, such as kerosene or diesel oil, in addition there are coal tar and plant or the oil of animal origin, aliphatic series, cyclic annular and aromatic hydrocarbon, such as Toluene, dimethylbenzene, paraffin, tetrahydronaphthalene, alkylated naphthalene or derivatives thereof, methanol, ethyl alcohol, propyl alcohol, butanol, cyclohexanol, hexamethylene Ketone, isophorone, intensive polar solvent, such as dimethyl sulfoxide, N-Methyl pyrrolidone and water.
Powder, broadcast sowing with material and can dusting product can be by the way that active material be mixed or simultaneous grinding with solid carrier And it prepares.
Particle such as coated particle, impregnated granules and homogeneous particle can be and adhering to reactive compound and solid carrier Preparation.The example of solid carrier be mine soil for example silica gel, silicate, talcum, kaolin, activated clay (attaclay), lime stone, Lime, chalk, bole, loess, clay, dolomite, diatomite, calcium sulfate, magnesium sulfate, magnesia；The synthesis material ground Material；Fertilizer such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea；The product of plant origin such as flour, bark powder, wood powder and shuck Powder, cellulose powder and other solid carriers.
Formulation for seed treatment can additional comprising adhesive and/or gelling agent and properly colorant.
Preparaton generally comprises 0.01-95 weight %, the preferably reactive compound of 0.1-90 weight %.Reactive compound with The purity of 90-100%, preferably 95-100% use.
For seed treatment, the preparaton after 2-10 times of dilution shortly with providing 0.01-40 weight % in preparation, it is excellent Select the activity compound concentration of 0.1-30 weight %.
When handling soil, the rate of application of active constituent is usually 0.1 to 10000g/ha, preferably 1 to 5000g/ha.
Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to practical feelings when reality is applied Condition and needs adjust rate of application especially in accordance with the seriousness of the property and germ of plant to be processed or crop.
Composition of the invention can also be applied with other active ingredient combinations, such as expanding activity profile or preventing shape At resistance.Other active constituents for example fungicide, bactericide, attractant, insecticide, acaricide, nematicide, Growth regulator, herbicide, safener, fertilizer or semiochemical etc..
Beneficial effects of the present invention: by research, the chloro- 2- of compound A, that is, 4- (1,1- dimethyl ethyl) -5- is found [[[4- (1,1- dimethyl ethyl) phenyl] methyl] sulfenyl] -3 (2H)-pyridazinones on veterinary antibiotics and field crop to sending out Raw downy mildew, late blight, epidemic disease, samping off, powdery mildew, rust, anthracnose, root rot, balck shank etc. have anti-well Control effect.In order to avoid the defect to develop drug resistance is used alone, compound A and the fungicide of different role mechanism are closed Reason mixture, has significant synergies, and improves control efficiency, reduces spraying times and dosage, additionally aids and avoid disease The generation of bacterium resistance and the generation speed for delaying drug resistance, the problems such as can solve the resistance in pesticide single dose application process.
Specific embodiment
Combined with specific embodiments below, the present invention will be further described.It should be understood that following embodiment is merely to illustrate this The person skilled in the art of the range of invention and is not intended to limit the present invention, the field can make one according to the content of foregoing invention A little nonessential modifications and adaptations.
1. the product being diluted with water
A) water-soluble concentrate (SL, LS, GW, PA)
10 parts by weight inventive mixtures are dissolved in 90 parts by weight water or water-soluble solvent.Alternatively, be added wetting agent or Other auxiliary agents.Reactive compound is diluted through water and is dissolved.The preparaton that active compound content is 10 weight % is obtained by this method.
B) dispersed concentrate (DC)
20 parts by weight inventive mixtures are dissolved in 70 parts by weight cyclohexanone and for example poly- second of 10 parts per weight dispersing agents is added Vinyl pyrrolidone.It is diluted with water to obtain dispersion.Active compound content is 20 weight %.
C) missible oil (EC)
15 parts by weight inventive mixtures are dissolved in 75 parts by weight of xylene and calcium dodecyl benzene sulfonate and castor is added Sesame oil ethoxylate (being in each case 5 parts by weight).It is diluted with water to obtain lotion.The reactive compound of the preparaton contains Amount is 15 weight %.
D) lotion (EW, EO, ES, ME)
25 parts by weight inventive mixtures are dissolved in 35 parts by weight of xylene and calcium dodecyl benzene sulfonate and castor is added Sesame oil ethoxylate (being in each case 5 parts by weight).The mixture is introduced 30 by mulser (Ultraturrax) In parts by weight water and equal phase emulsion is made.It is diluted with water to obtain lotion.The active compound content of the preparaton is 25 weight %.
E) suspension (SC, OD, FS, CS, SE, ZC, ZW, ZE)
In the ball mill of stirring, 20 parts by weight inventive mixtures are crushed to and are added 10 parts per weight dispersing agents and are moistened Agent and 70 parts by weight water or organic solvent, obtain reactive compound suspension fine crushing.It is diluted with water to obtain stable activation Close object suspension.Active compound content in the preparaton is 20 weight %.
F) water-dispersible granule and water-soluble granular (WG, SG, EG, ST, EP, WT, GE, DF)
By the grinding fine crushing of 50 parts by weight inventive mixtures and 50 parts per weight dispersing agents and wetting agent is added, is filled by industry It sets (such as pelletizer, spray tower, fluidized bed) and is made into water dispersible or water-soluble granular.It is diluted with water to obtain stable activity Compound dispersion or solution.The active compound content of the preparaton is 50 weight %.
G) water dispersible pow-ders and water-soluble powder (WP, SP, SS, WS)
By 75 parts by weight inventive mixtures crush and be added in airslide disintegrating mill 25 parts per weight dispersing agents, wetting agent and Silica gel.It is diluted with water to obtain stable active compound dispersion or solution.The active compound content of the preparaton is 75 weights Measure %.
H) gel formulation
In the ball mill by 20 parts by weight inventive mixtures, 10 parts per weight dispersing agents, 1 parts by weight gelling agent and 70 weight Part water or organic solvent grind to obtain delicate suspensions.It is outstanding to be diluted with water to obtain the stabilization that active compound content is 20 weight % Supernatant liquid.
2. the product applied without dilution
It I) can dusting powder (DP, DS)
It is sufficiently mixed the grinding fine crushing of 5 parts by weight inventive mixtures and with 95 parts by weight kaolin fine crushing.This is lived Property compounds content be 5 weight % can dusting product.
J) particle (GR, FG, GG, MG)
By the grinding fine crushing of 0.5 parts by weight inventive mixture and combine 99.5 parts by weight carriers.Current methods are to squeeze out, spray Mist drying or bed process.This obtains the particle applied without dilution that active compound content is 0.5 weight %.
K) ULV solution (UL)
10 parts by weight inventive mixtures are dissolved in 90 weight parts organic solvents such as dimethylbenzene.This obtains reactive compound Content is the product of 10 weight % applied without dilution.
For seed treatment, usually using water-soluble concentrate (LS), suspension (FS), can dusting powder (DS), moisture Dissipate property and water-soluble powder (WS, SS), lotion (ES), missible oil (EC) and gel formulation (GF).These preparatons can be without Dilution or preferably diluted form are applied on seed.Application can carry out prior to seeding.
It is preferable to use seed treatment FS preparatons.Such preparaton generally comprises 1-800g reactive compound/L, 1- 200g surfactant/L, 0-200g antifreezing agent/L, 0-400g adhesive/L, 0-200g colorant/L and solvent, preferably water.
The similar preparaton A-K of compound A or reactive compound B includes each reactive compound of corresponding amount.They are usually Directly (tank mix) is mixed during being diluted to i.e. with activity compound concentration before administration.
Reactive compound uses the concentration in preparation that can change in a wider range shortly.They are usually 0.0001- 10%, preferably 0.01-1%.
Reactive compound can directly, in the form of its preparaton or use form prepared therefrom (such as can Direct spraying it is molten Liquid, powder, suspension or dispersion, lotion, oil dispersion, paste, can dusting product, broadcast sowing with material or particle), by spray Mist, dusting, is broadcasted sowing or is poured to use at atomization.Use form depends entirely on desired purpose；It is intended in each case really Breaking even the best of invention reactive compound may distribution.
Aqueous use form can be by being added water by emulsion concentrates, paste or wettable powder (sprayable powder, oil dispersed Body) preparation.It, can be straight by the substance by wetting agent, tackifier, dispersing agent or emulsifier for preparation lotion, paste or oil dispersion It connects or is homogenized in water after being dissolved in oil or solvent.However, it is also possible to prepare by active material, wetting agent, tackifier, dispersing agent Or emulsifier and properly solvent or oil composition concentrate and the concentrate be suitable for be diluted with water.
Reactive compound can also be used successfully to ultra-low volume method (ULV), live wherein can apply and comprise more than 95 weight % Property compound preparaton, or even application be free of additive reactive compound.
Can be added into reactive compound various types of oil, wetting agent, adjuvant, herbicide, fungicide, other Pesticide or fungicide ,if needed (tank mix) tightly only is being added just before use.These reagents usually and the present composition with The weight ratio of 1:100-100:1, preferably 1:10-10:1 mix.
Compound A and B or mixture or corresponding preparation, by the mixture with effective fungicidal amount or in separate administration feelings Compound A and B under condition handle harmful fungoid, bacterium, and administration time can choose before harmful fungoid, bacterial invasion or it After carry out.
Application Example
The fungicidal effect of compound and mixture is confirmed by following test:
The present composition can be described further the synergistic function of harmful fungoid by the following example, but this Invention is only limitted to absolutely not this.Wherein the active component is the compound A in bactericidal composition of the invention and its homicide Microbial inoculum active constituent B.
Test method and evaluation method is as follows:
The predictive role of the specific combination of two kinds of reactive compounds can be used so-called " Colby formula " (referring to S.R.Colby, " CalculatingSynergisticandAntagonisticResponsesof HerbicideCombinations ", Weeds1967,15,20-22)
It is following to calculate: if
X is the activity when the use of dosage being α g/ha or reactive compound A that concentration is α ppm；
Y is the activity when the use of dosage being β g/ha or reactive compound B that concentration is β ppm, is expressed as accounting for untreated The percentage of control；
E is the activity when the use of dosage being α and β g/ha or reactive compound A and B that concentration is α and β ppm；So
If the activity of actual observation is greater than expection activity, the super adduction of the composition has synergistic effect.
Embodiment 1 prevents and treats cucumber downy mildew test
By the aqueous solution for two leaf phase of the potting cucumber seedling active component that kind is " the close thorn in Shandong " (concentration is as described below) After 24 hours, cucumber downy mildew spore suspension is seeded on cucumber leaves for spraying treatment, and being subsequently placed in temperature is 18 ± 1 DEG C and relative humidity be 90 ± 5% climatic chamber in cultivate, the development degree that infects of germ on blade is measured after 3 days.It is each independent Active component and the activity data of present composition cucumber downy mildew the results are shown in Table 1 and table 2.
The results show that the practical control efficiency value of composition is all larger than theoretical control efficiency value, composition is matched in test Synergistic effect is shown as in range.
Preventive effect of the independent active component of table 1 to cucumber downy mildew
2 present composition of table is to cucumber downy mildew
Embodiment 2 prevents and treats powdery mildew of cucumber test
Selection growth neat and consistent, the identical cucumber potting seedling of leaf age (kind: the close thorn in Xintai City), are being made by design dosage Foliar spray processing is carried out on composition spray, separately sets the blank control of not adding medicine.Pathogen is inoculated with after 24 hours, inoculation moves back To greenhouse normal management, and condition of culture (temperature: 23-28 DEG C of daytime, 18-20 DEG C of night) result investigation is carried out after culture 8 days.Investigation is every Open the development degree that blade germ is infected.The active number of each individual active component and present composition prevention and treatment powdery mildew of cucumber According to the results are shown in Table 3 tables 4.
The results show that the practical preventive effect of composition is all larger than theoretical preventive effect, composition is shown as in test ratio range Synergistic effect.
The independent active component of table 3 is to powdery mildew of cucumber preventive effect
The activity of 4 present composition of table
By a large number of experiments research A and a variety of different component B such as dimethomorph, flumorph, fluopicolide, benzoyl bacterium Amine, cyazofamid, Bravo, Mancozeb, benziothiazolinone, aliette, nonylphenolsulfonate copper, cymoxanil, pyraclostrobin, fluorine thiazole pyrrole ethyl ketone Deng at 1:10 to 10:1 ratio, tomato late blight is controlled, there is synergistic effect.Equally have to the prevention and treatment of the late blight of potato There is good synergistic effect.
Basic principles and main features and advantages of the present invention of the invention have been shown and described above.The skill of the industry Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and Its equivalent thereof.

Claims (18)

1. a kind of fungicide, for the fungicide using compound A as active component, the compound A is the chloro- 2- of 4- (1,1- bis- Methylethyl) -5- [[[4- (1,1- dimethyl ethyl) phenyl] methyl] sulfenyl] -3 (2H)-pyridazinones.
2. a kind of microbicide compositions, it includes following compound as work that the microbicide compositions, which are using synergistic effective quantity, Property component:
1) the chloro- 2- of compound A:4- (1,1- dimethyl ethyl) -5- [[[4- (1,1- dimethyl ethyl) phenyl] methyl] sulfenyl] - 3 (2H)-pyridazinones；
With 2) at least one reactive compound B selected from the group below:
N-butylamine；Cymoxanil；Cymoxanil；Dodine；Guanoctine；Biguanide spicy acid salt；M 9834；Smart M 9834；Benodanil；Benzene Base hydroxamic acid；N- (3 ', 4 '-two chloro- 5- fluorine hexichol -2- base) -3- (difluoromethyl) -1- methylpyrazole -4- formamide；Wither rust Spirit；Ring propionyl bacterium amine；Imugan；Ring bacterium amine；Cyflufenamid；Benzene flusulfamide；Double chlorine zarilamid；Dimethomorph；Fenfuram；Ring Acyl bacterium amine；Fenoxanil；(3S, 6S, 7R, 8R) -8- benzyl -3- { 3- [(isobutyryl oxygen) methoxyl group] -4-methoxypyridine - 2- formamido } -6- methyl -4,9- dioxo -1,5- dioxy nonyl ring -7- base isobutyrate；Fludioxonil；Fluorine biphenyl bacterium；Fluorine Quinoline；Fluopicolide；Fluorine pyrrole bacterium ester；Fluorine ether bacterium amide；Fluopyram；Flusulfamide；Flutolanil；Furalaxyl；Furan pyrazoles spirit；Diformazan Ofurace；Seed dressing amine；N- [1,1- dimethyl -2- (4- isopropoxy-o-tolyl) -2- oxoethyl] -3 methyl thiophene -2- Formamide；(RS) -2- methoxy-. N-methyl -2- [α-(2,5- xylyloxy)-o- tolyl] acetamide；Mandipropamid； Mebenil；Third oxygen, which goes out, embroiders amine；Metalaxyl；Metalaxyl-M；Methuroxam；Fenfuram；Oxycarboxin；Fluorine azoles bacterium aniline；Pyrrole thiophene Bacterium amine；Pyracarbolin；(Z)-N- { 2- [the chloro- 5- of 3- (cyclopropyl acethlene base) -2- pyridyl group] -2- (isopropoxy imino group) second Base } -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamide；[N- (3 ', 4 '-DfBP -2- base) -3- (fluoroform Base) pyrazine -2- formamide]；Quinazamid；Salicylanilide；Fluorine azoles ring bacterium amine；Silthiopham；Tecloftalam；Thifluzamide；Thiophene acyl Bacterium amine；Sulphur benzonitrile formamide；First flusulfamide；Toluene flusulfamide；Trichlamide；Triforine；Downy mildew goes out；Vangard；Zarilamid；Benzene Acyl bacterium amine；Aureofungin；Blasticidin-S；Cycloheximide；Griseofulvin；Kasugarnycin；Moroxydine；Viscous thiazole；Natamycin；It is more Antimycin；Polyoxin；Streptomysin；Valida；Biphenyl；Chlorine nitre naphthalene；Chloroneb；Bravo；Guaiacol；Botran；Phenol Bacterium ketone；Hexachloro-benzene；Pentachlorophenol；Pentachloronitrobenzene；Penta sodium pentachlorophenate；Tecnazene；Thiocyanogen dinitrobenzene；Pyrimidone；Benzene bacterium Ketone；Thiophanate-methyl；Thiophanate methyl；Furan first thiophanate；Benzene metsulfovax；Pest of going out azoles；Two discrimination bacillus；Probenazole；Benzene thiophene Bacterium amine；Pest of going out azoles；Two discrimination bacillus；Furan first thiophanate；Probenazole；Thiophanate-methyl；Diethofencarb；Butylamino formic acid iodo Propynyl ester；Iprovalicarb or iprovalicarb；(6- { [(Z)-(methyl-1 H-5- tetrazole radical) (phenyl) methylene] amino oxygroup first Base } -2- pyridyl group) carbamic acid spy's butyl ester；Propamocarb；Prothiocarb；2,2,2- trifluoroethyls (S)-[2- methyl-1-(p- toluene Acyl aminomethyl) propyl] carbamate；Maneb；Carbatene；Polycarbamate；Zineb；Ambam；Azithiram；? Bacterium prestige；Dazomet；Disulfiram；Ethisul；Fervam；Mancozeb；Metham-sodium；Milneb；Dithane A40；Propineb；Aateck；Good fortune It is U.S. double；Imazalil；Dislike imidazoles；Efficient imazalil；Fluorine bacterium azoles；Climbazole；Clotrimazole；Fenamidone；Fenapanil；Furidazol； Glyodin；Pefurazoate；Prochloraz；Apl-Luster；Triazoxide；Albendazole；Benomyl；Carbendazim；2- (2- chlorphenyl) -1H- benzene And imidazoles -2；Cypendazole；Debacarb；N- [methyl 1- (2- methylsulfanylethyl carbamoyl) benzimidazolyl-2 radicals-yl) amino Methyl formate；Pyrrole imidazoles；Azoles mepanipyrim；Amisulbrom；Bitertanol；Bromuconazole；Cyproconazole；Difenoconazole；Alkene azoles Alcohol；Epoxiconazole；Etaconazole；Benzoxazole；Fluotrimazole；Fluquinconazole；Flusilazole；Flutriafol；Furconazole；Furconazole_cis；Hexaconazole；It is sub- Amine azoles；Kind bacterium azoles；Different Fluconazole；Cresol Fluconazole；Metconazole；Nitrile bacterium azoles；Penconazole；Propiconazole；Prothioconazoles；Simeconazoles； Tebuconazole；Tetraconazole；Triazolone；Triadimenol；Butrizol；Triticonazole；Uniconazole P；High uniconazole P；Famoxate；Hymexazol； Cyazofamid；Wakil；Oxazole；Drazoxolon；Hydrazine pitches oxazolone；Fluorine thiazole pyrrole ethyl ketone；Vinclozolin；Pungent capric acid copper；Alkali Formula copper carbonate；Basic copper sulfate；Bordeaux mixture；Burgundy mixture；Cheshunt mixture；Copper acetate；Kocide SD；Cycloalkanes Sour copper；Copper oleate；Copper oxychloride；Cupric silicate；Copper sulphate；Copper zinc chromate；Nonylphenolsulfonate copper；Cuprobam；Cuprous oxide；Maneb Copper；Copper 8-hydroxyquinolinate；Difoltan；Captan；Chlozolinate；Sclex；Dimethachlon；Folpet；Iprodione；Chlorobenzene Climbazole；Myclozolin； Procymidone；Sulphur chlorobenzene imines；Binapacryl；Dinobuton；Dinocap；Dinocton；Dinopenton；Dinosulfon；Dinoterbon；Dinitro Phenol；The mite that disappears is more；Carbon disulfide dimethyl disulfide；Bromomethane；Methyl iodide；Sodium thiocarbonate；Benquinox；Sulphur；4- dodecane Base -2,6- thebaine；Antibacterial quinoline；Dodemorph；Butadiene morpholine；Tridemorph；The third phosphoric acid of ammonia；Plondrel；Kitazine； Hinosan；Fosetyl；Fosetyl aluminium；Hexamethylene sulphur phosphorus；Inezin；Different rice blast net；Izopamfos；Phosdiphen；Phosphorous acid and its salt；It is fixed Bacterium phosphorus；Tolelofos-methyl；Triamiphos；Decafentin；Fentinacetate；Fentin；Tributyltin oxide；Solbar；Lime sulfur；It is more Potassium sulfide；Sodium polysulfide；Benzo alkene fluorine bacterium azoles；Amine benzene pyrrole bacterium ketone；Fluorobenzene pyrrole bacterium amine；3- (difluoromethyl)-N- [(R) -2,3- two Hydrogen -1,1,3- trimethyl -1H- indenes -4- base] -1- methylpyrazole -4- formamide；N- (5- chloro-2-isopropyl benzyl)-N- cyclopropyl The fluoro- 1- methyl-1 H- pyrazole-4-carboxamide of base -3- (difluoromethyl) -5-；Isopyrazam；Fluorine azoles bacterium acyl azanol；Pyraoxystrobin； The chloro- 4- of 3- (2,6- difluorophenyl) -6- methyl -5- phenyl pyridazine；4- phenoxy benzyl 2- amino -6- methylnicotinic acid ester；Pyridine acyl Bacterium amine；The phonetic bacterium spirit of sulphur；Buthiobate；Dipyrithione；Fluazinam；Pyridine bacterium amine；Pyrrole bacterium benzene prestige；Pyridinitril；Pyrifenox；Pyridine bacterium is disliked Azoles；Pyrrole chlorine spirit；Chlorine pyrrole furan ether；Cyprodinil；Fluorine mepanipyrim；Milcurb；Milstem；Fenarimol；Ferimzone；Mepanipyrim；Fluorine Benzene ancymidol；Pyrimethanil；Triarimol；Fenpiclonil；Fluoromide；8-hydroxyquinoline；Spergon；Dichlone；Two Cyanogen anthraquinone；Ethoxyquin；Halacrinate；2 [2-(the fluoro- 2- methylquinoline-3- oxygroup of 7- 8- bis-)-6- fluorophenyls] third Alcohol -2- alcohol；The third oxygen quinoline；1- (8- hydroxyl -5- quinoline) ethyl ketone；The fluoro- 3,3- dimethyl -1- quinoline -3- isoquinolin of 4,4- bis-；Benzene Oxygen quinoline；Isobutyl ethoxyquin；Oxolinic acide；Lucel；Eradex；The gloomy copper of thiophene；Thiodiazole-copper；Zinc thiazole；Benthiozole；Leaf Withered azoles；Guardian；Grandox fumigant；Isotianil；Metsulfovax；Octhilinone；Third azoles grass is grand；Pencycuron；Acetylcholinesterase-zinc； Cufraneb；Polyoxin D zinc salt；Naphthalene acid zinc；Zinc trichlorophenate；Ziram；Bithionol；Antiphen；Diphenylamines；Hexachlorophene；Chlorobenzene Pyridine；First fragrant bacterium ester；Coumoxystrobin；Dimoxystrobin；Enestroburin；Alkene oxime amine；Fluorine bacterium mite ester；Fluoxastrobin；Kresoxim-methyl；Benzene oxygen Bacterium amine；Orysastrobin；ZEN 90160；Pyraclostrobin；Azoles amine bacterium ester；Chlorine nalidixic bacterium ester；Trifloxystrobin；Thiophene bacterium cyclopentadienyl；Isoprothiolane；Thiophene two Furan；Fluorine thiazole bacterium nitrile；Allicin；Jamaicin；Carvacrol；Carvol；Osthole；Sanguinarine；Fennel artemisin；N- (4 '-bromines connection Benzene -2- base) -4- difluoromethyl -2- methylthiazol -5- formamide；N- (4 '-trifluoromethyl-biphenyl -2- base) -4- difluoromethyl - 2- methylthiazol -5- formamide；N- (4 '-chloro- 3 '-fluorine biphenyl -2- base) -4- difluoromethyl -2- methylthiazol -5- formamide； N- (3 ', 4 '-two chloro- 4- fluorine biphenyl -2- base) -3- difluoromethyl -1- methylpyrazole -4- formamide；N- (the chloro- 5- of 3', 4'- bis- Fluorine biphenyl -2- base) -3- difluoromethyl -1- methylpyrazole -4- formamide；3,4- bis- chloro- N- (2- cyano-phenyl) isothiazole -5- Formamide；N- (2- { 4- [3- (4- chlorphenyl) propyl- 2- alkynyloxy group] -3- anisyl } ethyl) -2- methanesulfonamido -3- methyl Butyramide；N- (2- { 4- [3- (4- chlorphenyl) -propyl- 2- alkynyloxy group] -3- anisyl } ethyl) -2- second sulfonamido -3- first Base butyramide；Thiadiazoles element；Astromicin；Benziothiazolinone；Brassin lactones；Cycocel；Gibberellin；Three octyl benzene sulfonic acid of biguanides Salt；Oxolinic acid；Adjust naphthenic acid and its salt；2- butylamine；O- phenylphenol sodium；TrinexAN_SNacethyl；Triforine；
The active component 1) and active component 2) quality proportioning be 1:100-100:1.
3. microbicide compositions according to claim 2, it is characterised in that: the single dose content of the compound A is 0.1- 95。
4. microbicide compositions according to claim 2, it is characterised in that: the active component 2) it is selected from least one The reactive compound B of the following group:
Bitertanol；Bromuconazole；Difenoconazole；Olefin conversion；Flusilazole；Flutriafol；Hexaconazole；Nitrile bacterium azoles；Penconazole；Third Ring azoles；Prothioconazoles；Simeconazoles；Tebuconazole；Fluorine ether azoles；Fluorine bacterium azoles；Cyproconazole；Epoxiconazole；Fluquinconazole；Triadimenol；Press down mould Azoles；Dislike imidazoles；Famoxate；Fluazinam；Oxazole；Chinomethionat；The third oxygen quinoline；Quinoxyfen；Azoles mepanipyrim；Cyproconazole； Oxole bacterium；Fluquinconazole；Cycltebuconazole；Penta azoles bacterium of ring；Triazolone；Triadimenol；Pentylidene bacterium azoles；Prochloraz；Enzyme；Benzene bacterium Spirit；Carbendazim；Apl-Luster；Furidazol；Kobam；Hydroxyisoxazole；Oxygen ring azoles；Efficient olefin conversion；Benzoxazole；Kind bacterium azoles；Metconazole； Tetraconazole；Triticonazole；Efficient imazalil；Pefurazoate；Hymexazol；Grandox fumigant；Octhilinone；Benthiozole；Dithianon；Ethoxy Quinoline；Oxyquinoline；Viscous thiazole；Yekuzuo；Probenazole；High uniconazole P；Uniconazole P；Furconazole_cis；Furconazole；Etaconazole； Butrizol；Fluotrimazole；Climbazole；Clotrimazole；Different Fluconazole；Cresol Fluconazole；Flumorph；Dimethomorph；Bravo；Generation Gloomy MnZn；Cymoxanil；Cyazofamid；Fluopicolide；Propamocarb；Metalaxyl；Famoxate；Benziothiazolinone；Zoxamide；Pyrazoles ether bacterium Ester；Fluoxastrobin；Fluorine thiazole pyrrole ethyl ketone；Aliette；Nonylphenolsulfonate copper；Propineb；Zineb；Enestroburin；Bupirimate；Second is phonetic Phenol；Kresoxim-methyl；Isopyrazam；Fluxapyroxad；Boscalid；Three octyl benzene sulfonate of biguanides；Polyoxin；Wuyi is mould Element；Jamaicin；Thiophanate-methyl；Mandipropamid.
5. microbicide compositions according to claim 2, it is characterised in that: the active component 2) it is selected from least one The reactive compound B of the following group:
Flusilazole；Flutriafol；Nitrile bacterium azoles；Propiconazole；Tebuconazole；Epoxiconazole；Triazolone；Carbendazim；Hymexazol；Flumorph；Alkene Morpholide；Bravo；Mancozeb；Cymoxanil；Cyazofamid；Fluopicolide；Propamocarb；Metalaxyl；Famoxate；Benziothiazolinone； Zoxamide；Fluazinam；Pyraclostrobin；Fluoxastrobin；Fluorine thiazole pyrrole ethyl ketone；Aliette；Nonylphenolsulfonate copper；Propineb；Zineb；Alkene Trifloxystrobin；Bupirimate；Ethirimol；Kresoxim-methyl；Isopyrazam；Fluxapyroxad；Difenoconazole；Boscalid； Three octyl benzene sulfonate of biguanides；Polyoxin；Astromicin；Jamaicin；Thiophanate-methyl；Mandipropamid.
6. microbicide compositions according to claim 2, it is characterised in that: the active component 1) and active component 2) Quality proportioning is 1:50-50:1.
7. microbicide compositions according to claim 2, it is characterised in that: the active component 1) and active component 2) Quality proportioning is 1:25-25:1.
8. microbicide compositions according to claim 2, it is characterised in that: active component 1) and active component 2) quality Proportion is 1:10-10:1.
9. microbicide compositions according to claim 2, it is characterised in that: active component 1) and active component 2) quality Proportion is 1:5-5:1.
10. microbicide compositions according to claim 2, it is characterised in that: the bactericidal composition also includes that surface is living Property agent and/or filler.
11. microbicide compositions according to claim 10, it is characterised in that: the active component 1) and active component 2) Content account for the 5%-90% of bactericidal composition.
12. microbicide compositions according to claim 9, it is characterised in that: describedization active component 1) and active component 2) content accounts for the 10%-80% of bactericidal composition.
13. microbicide compositions according to claim 9, it is characterised in that: the active component 1) and active component 2) Content account for the 20%-60% of bactericidal composition.
14. the application of fungicide according to claim 1, it is characterised in that: the fungicide for veterinary antibiotics and The downy mildew that occurs on field crop, late blight, epidemic disease, samping off, powdery mildew, rust, anthracnose, root rot, balck shank Prevention and treatment.
15. the application of fungicide according to claim 1, it is characterised in that: the fungicide for veterinary antibiotics and The prevention and treatment of the downy mildew, powdery mildew, epidemic disease that occur on field crop.
16. according to the application of any microbicide compositions of claim 2-13, it is characterised in that: the antimicrobial combination Downy mildew, late blight, epidemic disease, samping off, powdery mildew, rust, the anthrax that object occurs on veterinary antibiotics and field crop The prevention and treatment of disease, root rot, balck shank.
17. according to the application of any microbicide compositions of claim 2-13, it is characterised in that: the antimicrobial combination The prevention and treatment of downy mildew, epidemic disease powdery mildew that object occurs on veterinary antibiotics and field crop.
18. the application of -13 any microbicide compositions according to claim 1, it is characterised in that: the bactericidal composition Dosage form be missible oil, aqueous suspension agent, oil-suspending agent, wettable powder, water dispersion granule, microemulsion, aqueous emulsion, microcapsules, Dry suspending agent or suspoemulsion.
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CN113100233A (en) * 2021-04-19 2021-07-13 中国农业科学院植物保护研究所 Application of arylhydroxamic acid and derivatives thereof as chitin deacetylase inhibitor and plant antifungal agent
CN113349002A (en) * 2021-06-15 2021-09-07 广西安农农业集团有限公司 Sweet potato dry-planting film-mulching ridging-free water-fertilizer integrated planting method
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CN111848295A (en) * 2019-04-04 2020-10-30 宁波三江益农化学有限公司 Bactericidal composition containing potassium phosphite and application thereof
CN110093210A (en) * 2019-05-15 2019-08-06 中国农业科学院烟草研究所 A kind of dewaxing matter garlic volatile spirits and its extracting method and application
CN112088889A (en) * 2019-06-18 2020-12-18 东莞市东阳光菌阳氢专利农药有限公司 Composition containing pyridachlorometyl and zinc thiazole
CN112088889B (en) * 2019-06-18 2023-08-04 东莞市东阳光菌阳氢专利农药有限公司 Composition containing Pyridachlorometyl and zinc thiazole
CN110250190A (en) * 2019-07-22 2019-09-20 东莞东阳光科研发有限公司 A kind of composition, preparation and its application, preparation method
CN110301436A (en) * 2019-08-13 2019-10-08 福建拓烯新材料科技有限公司 A kind of microcapsule formulations composition and preparation method thereof
CN110506747A (en) * 2019-08-28 2019-11-29 浙江海正化工股份有限公司 Using cyproconazole and copper 8-hydroxyquinolinate as the composition pesticide of active constituent and its preparation and application
CN110692628A (en) * 2019-11-08 2020-01-17 广西壮族自治区农业科学院 Downy mildew prevention and treatment method for downy mildew of downy grapes, prevention and treatment agent and preparation method of prevention and treatment agent
CN110692628B (en) * 2019-11-08 2021-06-25 广西壮族自治区农业科学院 Downy mildew prevention and treatment method for downy mildew of downy grapes, prevention and treatment agent and preparation method of prevention and treatment agent
CN110859189A (en) * 2019-11-22 2020-03-06 东莞市东阳光菌阳氢专利农药有限公司 Composition, preparation, application and preparation method of composition
CN110859189B (en) * 2019-11-22 2024-01-16 东莞市东阳光菌阳氢专利农药有限公司 Composition, preparation, application and preparation method thereof
CN113100233A (en) * 2021-04-19 2021-07-13 中国农业科学院植物保护研究所 Application of arylhydroxamic acid and derivatives thereof as chitin deacetylase inhibitor and plant antifungal agent
CN113349002A (en) * 2021-06-15 2021-09-07 广西安农农业集团有限公司 Sweet potato dry-planting film-mulching ridging-free water-fertilizer integrated planting method
CN114755326A (en) * 2022-03-30 2022-07-15 浙江省化工产品质量检验站有限公司 Detection method of dicyclopentadienyl in hypromellose
CN114755326B (en) * 2022-03-30 2024-02-02 浙江省化工产品质量检验站有限公司 Detection method of difenoconazole in hydroxypropyl methylcellulose
WO2024046311A1 (en) * 2022-08-29 2024-03-07 江苏中旗科技股份有限公司 Composition used for killing fungi and method for applying composition

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