CN108041059A - A kind of suspending agent of pyraclostrobin-containing and dimethomorph - Google Patents
A kind of suspending agent of pyraclostrobin-containing and dimethomorph Download PDFInfo
- Publication number
- CN108041059A CN108041059A CN201711320108.9A CN201711320108A CN108041059A CN 108041059 A CN108041059 A CN 108041059A CN 201711320108 A CN201711320108 A CN 201711320108A CN 108041059 A CN108041059 A CN 108041059A
- Authority
- CN
- China
- Prior art keywords
- dimethomorph
- pyraclostrobin
- suspending agent
- agent
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
Abstract
The present invention proposes the suspending agent of a kind of pyraclostrobin-containing and dimethomorph, the suspending agent includes acceptable auxiliary element on active ingredient and pesticide, wherein active ingredient is by pyraclostrobin, dimethomorph compounds, active ingredient accounts for the 12 50% of suspending agent gross mass, the present invention is the suspending agent of water baseization, since its each component is reasonably arranged in pairs or groups, select the active compound of different-grain diameter, the biological effect of preparation and physical stability is made to reach optimal, and pyraclostrobin is not fully exerted with dimethomorph drug effect, the present invention can be used for preventing powdery mildew of cucumber, downy mildew and banana freckle, leaf spot, the diseases such as sclerotiniose, with synergy, it is safe, it is environmentally friendly, the advantages that processing technology is simple and at low cost.
Description
Technical field
The present invention relates to agricultural chemicals suspension agent technical fields, and in particular to a kind of outstanding containing pyraclostrobin and dimethomorph
Floating agent.
Background technology
The distribution space of China's land resource is uneven, and the fertility difference of different zones is apparent.In recent years, with
The development in rural area, China's kind ground area gradually decrease.In the entire production process of crops, numerous prestige such as disease, worm, grass will be faced
The side of body, wherein disease, especially fungal disease, because famine can be found everywhere caused by it.1880, Dogue de Bordeaux area oenin
Mildew occurs, and wine-making industry is caused to be on the verge of bankruptcy；1945~nineteen forty-six, Ireland was because of the serious epidemic disease of its Major Foods potato generation
And have no harvest, die of hunger hundreds of thousands people；Nineteen fifty, the big generation of China's stripe rust of wheat cause 6,000,000,000 kilograms of wheat yield.These examples
Fungoid can be obtained because its species is various, it is rapid to propagate, harm is serious, huge to the yield forming of crops threat.
In plant growing process, in order to reduce caused by fungal disease lose, using highly effective pesticide carry out prevention be at present compared with
For significant means.But with single and highly effective pesticide frequent use so that many pathogens generate one to these medicaments
Fixed resistance, with the increase year by year of resistance, such as the grain and ecological ring of powdery mildew, anthrax, downy mildew, late blight to the mankind
Border brings great threat.Based on this phenomenon, the drug effect of medicament is improved on the basis of existing, reduce usage amount and reduce into
Originally it is the more effective economic means that solves the above problems.
Suspending agent is pesticide original medicine and carrier and dispersant, is had centainly using what wet method progress ultramicro grinding formed
The flowable suspended substance of stickiness.It is the solid active compound by being insoluble or poorly soluble in water and adds the auxiliary agents such as suitable dispersant, passes through
Ultramicro grinding is relatively homogeneously dispersed in water, forms a kind of tiny higher suspension of particle, the liquid solid bodies of flowable stabilization
System.Suspending agent is typically to be made of effective ingredient, dispersant, thickener, antiprecipitant, antifoaming agent, antifreezing agent and water etc..Effectively
The content of composition is generally 5%~50%.Average grain diameter is generally 3 microns.Liquid suspension is spread well in water, can
Spray liquid use is directly prepared into, the dispersiveness and plate-out ability of suspending agent are all relatively good, and suspensibility is high, is adhered to plant surface
Ability is stronger, resistance of rainwater washing against, thus drug effect is significantly and also relatively lasting compared with wettable powder, suspending agent have particle it is small,
Active surface is big, penetration is strong, when making up a prescription without dust, it is at low cost, drug effect is high the features such as and have wettable powder and missible oil concurrently
Advantage can be readily wetted by water, and it is good to be diluted with water rear suspension.
Pyraclostrobin, alias pyraclostrobin, hectogram are quick, chemical name：N- { 2- [1- (4- chlorphenyls) -1H- pyrazoles -3-
Yloxymethyl] phenyl } (N- methoxyl groups) methyl carbamate is new-type wide-spectrum bactericide, by being hindered in being synthesized in cytochromes
Only electronics shifts to inhibit mitochondrial respiratory.With protection, treatment, blade infiltration conduction.It is mainly used for cucumber white powder
The prevention of disease, downy mildew and banana freckle, leaf spot, sclerotiniose etc. has good control effect and security.
Dimethomorph, alias peace gram, excellent profit, green victory etc., chemical name：(E, Z) -4- [3- (4- chlorphenyls) 3- (3,4- bis-
Methoxyphenyl) acryloyl] morpholine is a kind of new interior therapeutic special less toxic fungicide of suction, mechanism of action is to destroy disease
The formation of bacterium cell envelope, causes the decomposition of spore cyst wall, and makes germ dead.Except zoospore formation and spore swarm stage
Outside, there is effect to each stage of the oomycetes history of life, it is especially more sensitive to the formation stages of sporangiophore and egg spore, if
Sporangium and egg spore form preceding medication, then can completely inhibit the generation of spore.The medicine absorbability is strong, and root application can pass through
Root enters each position of plant；Blade sprays, and can enter blade interior.Dimethomorph belongs to single-minded prevention Oomycete fungal
Disease medicament, to lower funguses venereal diseases such as downy mildew, peronospora tabacina, late blight, epidemic disease (mould) disease, phytophthora rot, rotten mildew, balck shanks
Evil is respectively provided with good control effect.It can be applied to grape, lichee, cucumber, muskmelon, balsam pear, tomato, capsicum, potato, cross
Flower section vegetables.
In order to improve resistivity of the crops to fungal disease, pyraclostrobin, the non-building preparation of dimethomorph are hanged
Floating agent has good researching value.
The content of the invention
In view of the above problems, the present invention proposes a kind of suspending agent containing pyraclostrobin and dimethomorph,
Pass through the Bactericidal composite of two kinds of active ingredient of pyraclostrobin and dimethomorph, it is therefore intended that overcome single formulation dosing
Greatly, the shortcomings of drug resistance is big, under optimum proportioning, composition has synergy, reduces dosage, reduces cost, reduces ring
Border is polluted, the advantages that delaying drug resistance.
In order to realize above-mentioned purpose, the present invention uses following technical solution：
A kind of suspending agent of pyraclostrobin-containing and dimethomorph, including in active ingredient and pesticide it is acceptable auxiliary into
Point, wherein active ingredient is compounded by pyraclostrobin, dimethomorph, and active ingredient accounts for the 12-50% of suspending agent gross mass.
Preferably, auxiliary element includes dispersant, wetting agent, antifoaming agent, thickener, carrier and solvent.
Preferably, the suspending agent of pyraclostrobin-containing and dimethomorph includes following percentage composition component：Pyraclostrobin 2
~10%, dimethomorph 10~40%, dispersant 1%~5%, wetting agent 2%~5%, antifoaming agent 0.5%~1%, thickener
0.25%~0.5%, carrier 0.5%~1%, balance of solvent.
Preferably, dispersant SP-SC3, SP-SC29, ENV1-Pol 871, Emulson AG/TRN/105,7289,
One or several kinds in 602#.
Preferably, wetting agent SP-SC3265, SP-SC3200LQ, one kind in AG/TRSS LV, AG/TRST HA or
Person is several.
Preferably, the one or several kinds in antifoaming agent B-385, B-386, B-387, AFE-3168.
Preferably, carrier is the one or several kinds in kaolin, white carbon, diatomite, bentonite, clay.
Preferably, thickener for xanthans, methylcellulose, carboxymethyl cellulose, sodium alginate, one kind in sucrose or
Person is several.
Preferably, the suspending agent of pyraclostrobin-containing and dimethomorph, preparation process are：Dispensing by weight percentage is put
It after being stirred evenly in container, then is crushed with high speed dispersion agent, control grain size D90 is less than 5 μm.
Preferably, the suspending agent of pyraclostrobin-containing and dimethomorph obtained is for cultural control powdery mildew of cucumber, frost
Mildew and banana freckle, leaf spot, sclerotiniose.
Due to using above-mentioned technical solution, the beneficial effects of the invention are as follows：
1) present invention is made of two kinds of different active ingredients of mechanism of action, has apparent synergy after combination
Effect, expands fungicidal spectrum, exacerbates the death of germ, delay the resistance to the action of a drug of germ.
2) present composition medicament reduces dosage, reduces poisoning, improves the security to crop；It reduces simultaneously
Residual in crop and soil alleviates the pollution to environment.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention
(all pesticides meet the standard of pesticide industry in embodiment, can be bought from market), to the technology in the embodiment of the present invention
Scheme is clearly and completely described.Based on the embodiment of the present invention, those of ordinary skill in the art are not making creativeness
All other embodiments obtained under the premise of work, belong to the scope of protection of the invention.
Embodiment 1：
Formula such as following table：
| Component | Material name | Dosage (mass percent %) |
| Effective constituents A | Pyraclostrobin | 5 |
| Active ingredient B | Dimethomorph | 20 |
| Dispersant | SP-SC3 | 3 |
| Wetting agent | SP-SC3200LQ | 3 |
| Antifoaming agent | B-386 | 0.5 |
| Thickener | Xanthans | 0.3 |
| Carrier | White carbon | 1 |
| Solvent | Water | 67.2 |
It weighs each component by the formula in above table, is then placed in container for stirring and is uniformly mixed, use high speed dispersor
It crushes, control grain size D90 is less than 5 microns.
Embodiment 2：
Formula such as following table：
| Component | Material name | Dosage (mass percent %) |
| Effective constituents A | Pyraclostrobin | 8 |
| Active ingredient B | Dimethomorph | 35 |
| Dispersant | SP-SC3 | 3 |
| Wetting agent | SP-SC3200LQ | 3 |
| Antifoaming agent | B-386 | 0.5 |
| Thickener | Xanthans | 0.3 |
| Carrier | White carbon | 1 |
| Solvent | Water | 49.2 |
It weighs each component by the formula in above table, is then placed in container for stirring and is uniformly mixed, use high speed dispersor
It crushes, control grain size D90 is less than 5 microns.
Embodiment 3：
Formula such as following table：
It weighs each component by the formula in above table, is then placed in container for stirring and is uniformly mixed, use high speed dispersor
It crushes, control grain size D90 is less than 5 microns.
Embodiment 4：
Formula such as following table：
| Component | Material name | Dosage (mass percent %) |
| Effective constituents A | Pyraclostrobin | 15 |
| Active ingredient B | Dimethomorph | 15 |
| Dispersant | SP-SC3 | 3 |
| Wetting agent | SP-SC3200LQ | 3 |
| Antifoaming agent | B-386 | 0.5 |
| Thickener | Xanthans | 0.3 |
| Carrier | White carbon | 1 |
| Solvent | Water | 62.2 |
It weighs each component by the formula in above table, is then placed in container for stirring and is uniformly mixed, use high speed dispersor
It crushes, control grain size D90 is less than 5 microns.
Embodiment 5：
Formula such as following table：
It weighs each component by the formula in above table, is then placed in container for stirring and is uniformly mixed, use high speed dispersor
It crushes, control grain size D90 is less than 5 microns.
Embodiment 6：
Formula such as following table：
| Component | Material name | Dosage (mass percent %) |
| Effective constituents A | Pyraclostrobin | 20 |
| Active ingredient B | Dimethomorph | 20 |
| Dispersant | SP-SC3 | 3 |
| Wetting agent | SP-SC3200LQ | 3 |
| Antifoaming agent | B-386 | 0.5 |
| Thickener | Xanthans | 0.3 |
| Carrier | White carbon | 1 |
| Solvent | Water | 52.2 |
It weighs each component by the formula in above table, is then placed in container for stirring and is uniformly mixed, use high speed dispersor
It crushes, control grain size D90 is less than 5 microns.
Every internal control index of suspending agent prepared by Examples 1 to 6 is as shown in table 1, and heat stabilization test result is such as
Shown in table 2.
Every internal control index of 16 embodiment suspending agents of table
26 embodiment suspending agent heat storage stability result of the tests of table
The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although with reference to the foregoing embodiments
The present invention is described in detail, it will be understood by those of ordinary skill in the art that：It still can be to foregoing each implementation
Technical solution recorded in example modifies or carries out equivalent substitution to which part technical characteristic；And these modification or
It replaces, the essence of appropriate technical solution is not made to depart from the spirit and scope of various embodiments of the present invention technical solution.
Claims (10)
1. a kind of suspending agent of pyraclostrobin-containing and dimethomorph, it is characterised in that：Including that can be connect in active ingredient and pesticide
The auxiliary element received, wherein active ingredient are compounded by pyraclostrobin, dimethomorph, and active ingredient accounts for suspending agent gross mass
12-50%.
2. the suspending agent of pyraclostrobin-containing according to claim 1 and dimethomorph, it is characterised in that：It is described auxiliary into
Dividing includes dispersant, wetting agent, antifoaming agent, thickener, carrier and solvent.
3. the suspending agent of pyraclostrobin-containing according to claim 2 and dimethomorph, which is characterized in that the suspending agent
Including following percentage composition component：Pyraclostrobin 2~10%, dimethomorph 10~40%, dispersant 1%~5%, wetting agent
2%~5%, antifoaming agent 0.5%~1%, thickener 0.25%~0.5%, carrier 0.5%~1%, balance of solvent.
4. the suspending agent of pyraclostrobin-containing according to claim 3 and dimethomorph, it is characterised in that：Described is scattered
Agent is the one or several kinds in SP-SC3, SP-SC29, ENV1-Pol 871, EmulsonAG/TRN/105,7289,602#.
5. the suspending agent of pyraclostrobin-containing according to claim 3 and dimethomorph, it is characterised in that：The wetting
Agent is SP-SC3265, SP-SC3200LQ, the one or several kinds in AG/TRSS LV, AG/TRST HA.
6. the suspending agent of pyraclostrobin-containing according to claim 3 and dimethomorph, it is characterised in that：The defoaming
Agent is the one or several kinds in B-385, B-386, B-387, AFE-3168.
7. the suspending agent of pyraclostrobin-containing according to claim 3 and dimethomorph, it is characterised in that：The carrier
For the one or several kinds in kaolin, white carbon, diatomite, bentonite, clay.
8. the suspending agent of pyraclostrobin-containing according to claim 3 and dimethomorph, it is characterised in that：The thickening
Agent is xanthans, the one or several kinds in methylcellulose, carboxymethyl cellulose, sodium alginate, sucrose.
9. according to claim 4-8 any one of them pyraclostrobin-containing and the suspending agent of dimethomorph, which is characterized in that system
It is for step：Dispensing by weight percentage is placed in container after stirring evenly, then is crushed with high speed dispersion agent, control grain size D90
Less than 5 μm.
10. the application of the suspending agent of the pyraclostrobin-containing as made from claim 9 and dimethomorph：For cultural control cucumber
Powdery mildew, downy mildew and banana freckle, leaf spot, sclerotiniose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711320108.9A CN108041059A (en) | 2017-12-12 | 2017-12-12 | A kind of suspending agent of pyraclostrobin-containing and dimethomorph |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711320108.9A CN108041059A (en) | 2017-12-12 | 2017-12-12 | A kind of suspending agent of pyraclostrobin-containing and dimethomorph |
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| CN108041059A true CN108041059A (en) | 2018-05-18 |
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| CN201711320108.9A Pending CN108041059A (en) | 2017-12-12 | 2017-12-12 | A kind of suspending agent of pyraclostrobin-containing and dimethomorph |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113142236A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN114732009A (en) * | 2022-06-13 | 2022-07-12 | 山东百农思达生物科技有限公司 | Preparation method of water dispersible granules containing pyraclostrobin and dimethomorph |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102239864A (en) * | 2010-05-16 | 2011-11-16 | 青岛奥迪斯生物科技有限公司 | Bactericidal composition containing pyraclostrobin and dimethomorph |
| CN105123727A (en) * | 2015-09-25 | 2015-12-09 | 安徽美兰农业发展股份有限公司 | Dimethomorph and pyraclostrobin compound suspending agent as well as preparation method thereof |
-
2017
- 2017-12-12 CN CN201711320108.9A patent/CN108041059A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102239864A (en) * | 2010-05-16 | 2011-11-16 | 青岛奥迪斯生物科技有限公司 | Bactericidal composition containing pyraclostrobin and dimethomorph |
| CN105123727A (en) * | 2015-09-25 | 2015-12-09 | 安徽美兰农业发展股份有限公司 | Dimethomorph and pyraclostrobin compound suspending agent as well as preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 刘程等: "《表面活性剂性质理论与应用》", 30 June 2003, 北京工业大学出版社 * |
| 崔维: "《园林植物杀菌剂应用技术》", 31 October 2016, 河南科学技术出版社 * |
| 杨军玉: "《蔬菜病虫害防治彩色图鉴》", 29 February 2016, 金盾出版社 * |
| 沈晋良: "《农药加工与管理》", 30 June 2002, 中国农业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113142236A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN114732009A (en) * | 2022-06-13 | 2022-07-12 | 山东百农思达生物科技有限公司 | Preparation method of water dispersible granules containing pyraclostrobin and dimethomorph |
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