CN105994347A - Suspension seed-coating agent containing cyantraniliprole, silthiopham and pyraclostrobin - Google Patents

Suspension seed-coating agent containing cyantraniliprole, silthiopham and pyraclostrobin Download PDF

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Publication number
CN105994347A
CN105994347A CN201610365288.1A CN201610365288A CN105994347A CN 105994347 A CN105994347 A CN 105994347A CN 201610365288 A CN201610365288 A CN 201610365288A CN 105994347 A CN105994347 A CN 105994347A
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CN
China
Prior art keywords
agent
suspension seed
silthiopham
pyraclostrobin
coating agent
Prior art date
Application number
CN201610365288.1A
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Chinese (zh)
Inventor
王磊
赵晓伟
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洛阳市嘉创农业开发有限公司
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Priority to CN201610365288.1A priority Critical patent/CN105994347A/en
Publication of CN105994347A publication Critical patent/CN105994347A/en

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur

Abstract

The invention relates to a suspension seed-coating agent containing cyantraniliprole, silthiopham and pyraclostrobin. The suspension seed-coating agent comprises 1-5% of cyantraniliprole, 1-5% of pyraclostrobin, 2-6% of silthiopham, 15-20% of pearl powder, 1-3% of a defoamer, 3-9% of a film forming agent, 1-3% of a warning color, 1-2% of a thickening agent, 2-3% of an emulsifier, 1-3% of an anti-freezing agent, 1-2% of a preservative, 0.2-1% of a colorant and the balance of water. The suspension seed-coating agent can effectively prevent and treat wheat sharp eyespot, full rot, wireworms and grubs, slows down drug resistance of plant diseases and insect pests, prolongs the service life of pesticides, can treat both pests and diseases, reduces the consumption of pesticides, lowers the cost, reduces the investment, and also reduces pollution and harm to the environment.

Description

Suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin

Technical field

The present invention relates to pesticide field, especially relate to a kind of seed coat agent, particularly a kind of containing bromine cyanogen worm acyl The suspension seed-coating agent of amine, Silthiopham and pyraclostrobin.

Background technology

Bromine cyanogen insect amide is also cyanogen insect amide, can effectively prevent and treat Lepidoptera, Semiptera and coleopteran pest, tool Have more efficient, applicable crops widely advantage.Bromine cyanogen insect amide is subject to by activating the ryania of target pest Body and pest control.The calcium ion of storage in the releasable striped muscle of activation of ryanodine receptor and smooth muscle cell, Cause insect muscular movement to regulate impaired, paralysis, ultimately result in insect dead.Bromine cyanogen insect amide has wider The insecticidal activity of spectrum, has the preventive effect of excellence to sucking pest.

Pyraclostrobin is a kind of wide-spectrum bactericide, can suppress the growth of fungal mycelium, ultimately result in pathogenic bacteria Death, is respectively provided with prevention and therapeutic effect, its former medicine low toxicity well, acts on fast multiple fungal disease Speed, lasting medicine, it is recommended that to crop safety under dosage, and it is latent to induce plant performance to a certain extent Resistance against diseases.

Silthiopham chemical name N-pi-allyl-4,5-dimethyl-2-(TMS) thiophene-3-formyl Amine, has good protection activity, and the lasting period is long.Mainly make seed treatment, strong inhibition Semen Tritici aestivi total eclipse of dressing seed Sick.

Wheat sharp eyespot, the important soil-borne disease in full rot Shi Mai district, because of kind, cropping system, rich water bar The reasons such as part, the sickness rate at Mai Qu adds recurrence year by year.Mixed in most of Mai Qu, banded sclerotial blight and full rot Closing and occur or alternately occur, its pathogen is soil invader, and host range is wide, can be at multiple weeds, standing grain Breed on undergraduate course crop, it is possible to survived the winter on invalid body by mycelium, just because of this, banded sclerotial blight and total eclipse Sick being difficult to is prevented and treated, and causes the Semen Tritici aestivi percentage of earbearing tiller low, causes crop failure, total crop failure.

In modern agricultural production, utilizing seed coat agent that seed carries out chemicals treatment is to prevent subterranean pest-insect and agriculture Crop soil passes, one of the method for economical and convenient of seed-borne disease.Seed coat agent be a kind of for crop or other plant Thing seed treatment, the pesticidal preparations with film forming characteristics, it can solidify to form at the surface of the seed and referred to as plant The film of clothing.Seed coat agent in soil imbibition and be not dissolved, it is allowed to seed normally germinates required moisture Passing through with air, the material such as contained pesticide and seed manure slowly discharges, it is possible to kill subterranean pest-insect, evil in seedling stage Worm, has preventing and treating sprout term disease and systematicness disease, improves percentage of seedgermination, promotion seedling healthy growth etc. Effect.

For above-mentioned pest and disease damage and Semen Tritici aestivi disease, the most common solution is typically only capable to reach parasite killing or anti- Sick purpose, it is impossible to integrated control, big to the consumption of pesticide, application cost is high;Even if by different medicaments Mixing, is also individually to use repeatedly hydrojet, not only wastes time and energy, and operate complexity.

Summary of the invention

It is an object of the invention to provide a kind of hanging containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin Floating seed coat agent, is used for preventing and treating wheat sharp eyespot, full rot, wireworm, Holotrichia diomphalia Bates, and drug effect is notable, can reduce Dosing, parasitosis is double to be controlled, and reduces cost, and non-environmental-pollution.

The object of the invention to solve the technical problems realizes by the following technical solutions.

A kind of suspension kind containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin proposed according to the present invention Clothing agent, wherein, including bromine cyanogen insect amide, pyraclostrobin, Silthiopham, pearl essence, defoamer, one-tenth Membrane, warning coloration, thickening agent, emulsifying agent, antifreezing agent, preservative, coloring agent and water.

The object of the invention to solve the technical problems also can be applied to the following technical measures to achieve further.

Aforesaid a kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin, wherein, The weight content of each composition is: bromine cyanogen insect amide 1-5%, pyraclostrobin 1-5%, Silthiopham 2-6%, pearl Light powder 15-20%, defoamer 1-3%, film former 3-9%, warning coloration 1-3%, thickening agent 1-2%, emulsifying agent 2-3%, antifreezing agent 1-3%, preservative 1-2%, coloring agent 0.2-1%, remaining is water.

Aforesaid a kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin, wherein, The weight content of each composition is: bromine cyanogen insect amide 5%, pyraclostrobin 3%, Silthiopham 4%, pearl essence 20%, defoamer 1%, film former 5%, warning coloration 2%, thickening agent 1%, emulsifying agent 2%, antifreezing agent 1%, Preservative 2%, coloring agent 1%, remaining is water.

Aforesaid a kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin, wherein, Described warning coloration is azarin color.

Aforesaid a kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin, wherein, Described thickening agent is xanthan gum.

Aforesaid a kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin, wherein, Described defoamer is dimethicone.

Aforesaid a kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin, wherein, Described film former is polyvinyl alcohol 1788 or acrylic resin.

The preparation of aforesaid a kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin Method is: is mixed by described each composition, stirs, then put in grinder and be ground, be milled to thing The mean diameter of material is less than 4um, and milling time is 4-8h, ground after, filter.

The present invention compared with prior art has clear advantage and beneficial effect, by technique scheme, A kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin of the present invention can reach quite Technological progress and practicality, and there is the extensive value in industry, it at least has the advantage that

(1) present invention is by pyraclostrobin, bromine cyanogen insect amide and Silthiopham ternary built, has significantly Synergistic function, and raw material is easy to get, preparation method is easy, slow down the drug-fast generation of pest and disease damage, prolongs Grown the service life of pesticide, can preventing and treating wheat sharp eyespot, full rot, wireworm, Holotrichia diomphalia Bates, worm Disease is double to be controlled, and simplifies agricultural production process.

(2) the seed coat agent good film-forming property of the present invention, it is possible to stable preservation and use, drug effect is notable, decreases The usage amount of pesticide, cost-effective, reduce investment, reduce the pollution to environment and harm.

In sum, a kind of suspension kind containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin of the present invention Clothing agent has significantly progressive technically, and has obvious good effect, is really one novel, progressive, real New design.

Described above is only the general introduction of technical solution of the present invention, in order to better understand the technology of the present invention Means, and can being practiced according to the content of description, and in order to allow the present invention above and other purpose, Feature and advantage can become apparent, and below especially exemplified by preferred embodiment, describes in detail as follows.

Accompanying drawing explanation

Nothing

Detailed description of the invention

By further illustrating the technological means and effect that the present invention taked by reaching predetermined goal of the invention, with Lower combination preferred embodiment, contains bromine cyanogen insect amide, Silthiopham and pyrrole to the one proposed according to the present invention The suspension seed-coating agent of azoles kresoxim-methyl, its detailed description of the invention, structure, feature and effect thereof, describe in detail such as After.

A kind of suspension seed-coating agent containing bromine cyanogen insect amide, Silthiopham and pyraclostrobin, by following component Form according to percentage by weight: bromine cyanogen insect amide 1-5%, pyraclostrobin 1-5%, Silthiopham 2-6%, pearl Light powder 15-20%, defoamer 1-3%, film former 3-9%, warning coloration 1-3%, thickening agent 1-2%, emulsifying agent 2-3%, antifreezing agent 1-3%, preservative 1-2%, coloring agent 0.2-1%, remaining is water.

It is preferred that the consisting of of this suspension seed-coating agent: bromine cyanogen insect amide 5%, pyraclostrobin 3%, silicon thiophene bacterium Amine 4%, pearl essence 20%, defoamer 1%, film former 5%, warning coloration 2%, thickening agent 1%, emulsifying agent 2%, Antifreezing agent 1%, preservative 2%, coloring agent 1%, water 53%.

So-called warning coloration is exactly the color of seed coat agent, it is simple to whether coating is dressed seed to distinguish seed, more intuitively, General seed coat agent color is redness, yellow, blueness, green etc..

It is preferred that described warning coloration is azarin color;Described water is distilled water.

Described defoamer is used for preventing from producing a large amount of bubble when using, and defoamer can be selected for dimethicone.

Described thickening agent is for improving the viscosity of suspension, thus reduces the sedimentation velocity of particle, improves and suspends The stability of liquid, thickening agent can use xanthan gum.Xanthan gum is the one of thickening agent, film forming have aqueous, Breathability, such as macrogol.

Described film former can make active component concentrate on the surface of the seed, reduces pesticide diffusion in the environment, from And reducing the infringement to environment, described film former can be selected for polyvinyl alcohol or acrylic resin.

Pearl essence can change the outward appearance of seed, increase the brightness of seed, makes seed glossy, increases seed Commodity.

The preparation method of above-mentioned seed coat agent is: is mixed by the above each composition, stirs, then put into Being ground in grinder, milling time is 4-8h, and the mean diameter being milled to material is less than 4um, filters, Collect filtrate.

The bromine cyanogen insect amide pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 1:5%

Each constituent content is: bromine cyanogen insect amide 2%, pyraclostrobin 1%, Silthiopham 2%, pearl essence 20%, Defoamer 1%, film former 3%, warning coloration 2%, thickening agent 2%, emulsifying agent 2%, antifreezing agent 1%, preservative 1%, coloring agent 1%, water 62%.

Grinding 6h after being mixed by above composition, mean diameter is less than 4um.

The bromine cyanogen insect amide pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 2:9%

Each constituent content is: bromine cyanogen insect amide 1%, pyraclostrobin 5%, Silthiopham 3%, pearl essence 15%, Defoamer 3%, film former 9%, warning coloration 3%, thickening agent 1%, emulsifying agent 3%, antifreezing agent 2%, preservative 2%, coloring agent 1%, water 52%.

Grinding 6h after being mixed by above composition, mean diameter is less than 4um.

The bromine cyanogen insect amide pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 3:12%

Each constituent content is: bromine cyanogen insect amide 5%, pyraclostrobin 3%, Silthiopham 4%, pearl essence 20%, Defoamer 1%, film former 5%, warning coloration 2%, thickening agent 1%, emulsifying agent 2%, antifreezing agent 1%, preservative 2%, coloring agent 1%, water 53%.

Grinding 6h after being mixed by above composition, mean diameter is less than 4um.

The bromine cyanogen insect amide pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 4:15%

Each constituent content is: bromine cyanogen insect amide 4%, pyraclostrobin 5%, Silthiopham 6%, pearl essence 18%, Defoamer 2%, film former 5%, warning coloration 1%, thickening agent 1%, emulsifying agent 2%, antifreezing agent 3%, preservative 1%, coloring agent 0.2%, water 51.8%.

Grinding 6h after being mixed by above composition, mean diameter is less than 4um.

Above-described embodiment products obtained therefrom is carried out indoor germination rate and germinating energy detection and field efficacy investigation, step Rapid as follows:

(1) first, seed is dressed seed, selected full seed, each processes according to pesticide-seeds ratio is 1:50, Put into after weighing up in culture dish, close the lid, fully shake, make seed pelleting uniform, dry.

(2) indoor germination rate and germinating energy investigation, process every time and choose 200 full seeds, in indoor Test.

(3) field efficacy investigation, choosing Semen Tritici aestivi is experimental subject, investigates vermins-proof effect and sees whether occur Banded sclerotial blight, full rot, wireworm, Holotrichia diomphalia Bates.

Result is as follows:

The seed coat agent of table 1. heterogeneity is on wheat germination rate and the impact of germinating energy

Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Blank Germination percentage (%) 94 95 98 97 92 Germinating energy (%) 90 91 94 93 88

As it can be seen from table 1 after the seed coat agent of the present invention is to seed pelleting, equal to its germination percentage and germinating energy Have no adverse effects.

The result of field experiment is as follows:

The seed coat agent field diseases prevention vermins-proof effect experimental result of table 2. heterogeneity

Implementation sequence number Banded sclerotial blight preventive effect (%) Full rot preventive effect (%) Wireworm preventive effect (%) Holotrichia diomphalia Bates preventive effect (%) Embodiment 1 90.5 91.5 92.2 90.6 Embodiment 2 92.6 91.3 93.7 92.9 Embodiment 3 99.3 99.8 95.8 97.3 Embodiment 4 96.1 96.9 94.3 96.7

Upper table shows, after the seed coat agent of the present invention is to seed pelleting, through field test it has been observed that to Semen Tritici aestivi The prevention effect highly significant of pest and disease damage, its insect protected protection effect, up to more than 95%, effectively inhibits Semen Tritici aestivi complete Erosion disease, banded sclerotial blight, wireworm and the generation of Holotrichia diomphalia Bates.Wherein example 3,4 effect is obvious, and prevention effect is optimal.

The above, be only presently preferred embodiments of the present invention, not makees the present invention any pro forma Limit, although the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any Those skilled in the art, in the range of without departing from technical solution of the present invention, when available the disclosure above Technology contents make a little change or be modified to the Equivalent embodiments of equivalent variations, as long as being without departing from this The content of bright technical scheme, any simple modification above example made according to the technical spirit of the present invention, Equivalent variations and modification, all still fall within the range of technical solution of the present invention.

Claims (9)

1., containing bromine cyanogen insect amide, Silthiopham and a suspension seed-coating agent for pyraclostrobin, its feature exists Bromine cyanogen insect amide, pyraclostrobin, Silthiopham, pearl essence, defoamer, film former, police is included in it Guard against color, thickening agent, emulsifying agent, antifreezing agent, preservative, coloring agent and water.
2. suspension seed-coating agent as claimed in claim 1, it is characterised in that the weight content of each composition is: bromine Cyanogen insect amide 1-5%, pyraclostrobin 1-5%, Silthiopham 2-6%, pearl essence 15-20%, defoamer 1-3%, Film former 3-9%, warning coloration 1-3%, thickening agent 1-2%, emulsifying agent 2-3%, antifreezing agent 1-3%, preservative 1-2%, coloring agent 0.2-1%, remaining is water.
3. suspension seed-coating agent as claimed in claim 1, it is characterised in that the weight content of each composition is: bromine Cyanogen insect amide 5%, pyraclostrobin 3%, Silthiopham 4%, pearl essence 20%, defoamer 1%, film former 5%, warning coloration 2%, thickening agent 1%, emulsifying agent 2%, antifreezing agent 1%, preservative 2%, coloring agent 1%, its Yu Weishui.
4. suspension seed-coating agent as claimed in claim 1, it is characterised in that described warning coloration is azarin color.
5. suspension seed-coating agent as claimed in claim 1, it is characterised in that described thickening agent is xanthan gum.
6. suspension seed-coating agent as claimed in claim 1, it is characterised in that described defoamer is dimethicone.
7. suspension seed-coating agent as claimed in claim 1, it is characterised in that described film former be polyvinyl alcohol or Acrylic resin.
8. suspension seed-coating agent as claimed in claim 1, it is characterised in that its preparation method is as follows: by described Each composition mixes, and stirs, then puts in grinder and be ground, and the mean diameter being milled to material is little In 4um, filter.
9. the preparation method of suspension seed-coating agent as claimed in claim 4, it is characterised in that milling time is 4-8h。
CN201610365288.1A 2016-05-26 2016-05-26 Suspension seed-coating agent containing cyantraniliprole, silthiopham and pyraclostrobin CN105994347A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101516195A (en) * 2006-09-18 2009-08-26 巴斯夫欧洲公司 Pesticidal mixtures comprising an anthranilamide insecticide and a fungicide
CN102428953A (en) * 2012-01-14 2012-05-02 陕西美邦农药有限公司 Bactericidal composition containing silthiopham and methoxy acrylate compound
CN103210938A (en) * 2013-04-26 2013-07-24 北京燕化永乐农药有限公司 Pesticide composition
WO2015028376A1 (en) * 2013-08-28 2015-03-05 Basf Se Use of a mixture comprising at least one strobilurine and at least one dithiocarbamate for increasing the health of silvicultural plants
CN105272604A (en) * 2015-10-26 2016-01-27 唐睿 Pest-killing and disease-resistant suspended seed coating agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101516195A (en) * 2006-09-18 2009-08-26 巴斯夫欧洲公司 Pesticidal mixtures comprising an anthranilamide insecticide and a fungicide
CN102428953A (en) * 2012-01-14 2012-05-02 陕西美邦农药有限公司 Bactericidal composition containing silthiopham and methoxy acrylate compound
CN103210938A (en) * 2013-04-26 2013-07-24 北京燕化永乐农药有限公司 Pesticide composition
WO2015028376A1 (en) * 2013-08-28 2015-03-05 Basf Se Use of a mixture comprising at least one strobilurine and at least one dithiocarbamate for increasing the health of silvicultural plants
CN105272604A (en) * 2015-10-26 2016-01-27 唐睿 Pest-killing and disease-resistant suspended seed coating agent

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