CN101516195A - Pesticidal mixtures comprising an anthranilamide insecticide and a fungicide - Google Patents

Abstract

Pesticidal mixtures comprising, as active components, 1 ) an anthranilamid compound of the formula I wherein the variables are defined according to the description, and 2) at least one fungicidal compound Il selected from the following groups: strobilurins, carboxamides, heterocylic compounds and other active compounds according to the description, in a synergistically effective amount, methods for controlling pests, and harmful fungi, methods of protecting plants from attack or infestation by insects, acarids or nematodes, methods for treating, controlling, preventing or protecting an animal against infestation or infection by parasites, compositions containing these mixtures, and methods for their preparation.

Description

The pesticide combination that comprises anthranilamide derivatives as insectisides and fungicide

The present invention relates to comprise the ternary pesticide combination of following material as active component with the Synergistic effective dose:

1) anthranilamide of formula I (anthranilamide) compound:

Wherein substituting group is following defines:

B ¹Be hydrogen, cyano group or chlorine;

B ²Be bromine or CF ₃With

R is hydrogen or C ₁-C ₆Alkyl;

With

2) a kind of Fungicidal compounds II that is selected from following group:

A) azole, especially: Bitertanol (bitertanol), bromuconazole (bromuconazole), cyproconazole (cyproconazole) Difenoconazole (difenoconazole), alkene azoles alcohol (diniconazole), IMAZALIL (enilconazole) (imazalil), oxole bacterium (epoxiconazole), Fluquinconazole (fluquinconazole), RH-7592 (fenbuconazole), Flusilazole (flusilazole), Flutriafol (flutriafol), own azoles alcohol (hexaconazole), acid amides azoles (imibenconazole), cycltebuconazole (ipconazole), encircle penta azoles bacterium (metconazole), nitrile bacterium azoles (myclobutanil), penconazole (penconazole), propiconazole (propiconazole), prothioconazoles (prothioconazole), simeconazoles (simeconazole), triazolone (triadimefon), triadimenol (triadimenol), Tebuconazole (tebuconazole), fluorine ether azoles (tetraconazole), triticonazole (triticonazole);

Prochloraz (prochloraz), pefurazoate (pefurazoate), IMAZALIL (imazalil), fluorine bacterium azoles (triflumizole), cyanogen frost azoles (cyazofamid);

Benomyl (benomyl), carbendazim (carbendazim), thiabendazole (thiabendazole), furidazol (fuberidazole);

Guardian (ethaboxam), kobam (etridiazole), hydroxyisoxazole (hymexazole);

B) strobilurins (strobilurins), especially: nitrile Fluoxastrobin (azoxystrobin), ether bacterium amine (dimoxystrobin), Enestroburin (enestroburin), fluoxastrobin (fluoxastrobin), imines bacterium (kresoxim-methyl), fork phenalgin acid amides (metominostrobin), orysastrobin (orysastrobin), ZEN 90160 (picoxystrobin), pyraclostrobin (pyraclostrobin), oxime bacterium ester (trifloxystrobin);

C) carboxylic acid amides, especially: carboxin (carboxin), M 9834 (benalaxyl), Boscalid (boscalid), fenhexamid (fenhexamid), flutolanil (flutolanil), third oxygen goes out and embroiders amine (mepronil), metalaxyl (metalaxyl), Metalaxyl-M (mefenoxam), fenfuram (ofurace) Evil frost spirit (oxadixyl), oxycarboxin (oxycarboxin), pyrrole metsulfovax (penthiopyrad), thifluzamide (thifluzamide), 5-fluoro-1,3-dimethyl-1H-pyrazoles-4-formic acid [2-(1,2-dimethyl-propyl group)-phenyl]-acid amides, dimethomorph (dimethomorph), flumorph (flumorph);

Fluorine pyrrole bacterium amine (fluopicolide) (picobenzamid), zoxamide (zoxamide);

Two chlorine zarilamids (diclocymet), mandipropamid amine (mandipropamid);

D) heterocyclic compound, especially: fluazinam (fluazinam), pyrifenox (pyrifenox);

The phonetic bacterium spirit of sulphur (bupirimate), ring third pyrimidine (cyprodinil), fenarimol (fenarimol), ferimzone (ferimzone), mepanipyrim (mepanipyrim), nuarimol (nuarimol), pyrimethanil (pyrimethanil);

Triforine (triforine), azoles bacterium piperazine (triazoxide);

Fenpiclonil (fenpiclonil), Fu Evil bacterium (fludioxonil);

Dodemorfe (dodemorph), butadiene morpholine (fenpropimorph), tridemorph (tridemorph);

Fenpropidin (fenpropidin), different third fixed (iprodione), the sterilization profit (procymidone), vinclozolin (vinclozolin);

Azolactone bacterium (famoixadone), Fenamidone (fenamidone), probenazole (probenazole);

Indazole flusulfamide (amisulbrom), anilazine (anilazine), diclomezine (diclomezine), pyroquilon (pyroquilon), the third oxygen quinoline (proquinazid), tricyclazole (tricyclazole);

Thiadiazoles element (acibenzolar-S-methyl), difoltan (captafol), captan, folpet, zarilamid (fenoxanil), quinoxyfen (quinoxyfen);

E) Carbamates, especially: mancozeb (mancozeb), maneb, metham-sodium, Carbatene (metiram), ferbam, propineb (propineb), tmtd, zineb, ziram;

The mould prestige of second (diethofencarb), iprovalicarb (iprovalicarb), benzene metsulfovax (flubenthiavalicarb), hundred dimension spirits (propamocarb);

3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate;

With

F) be selected from other following reactive compound:

Guanidine class: dodine, biguanide spicy acid salt (iminoctadine), guazatine (guazatine);

Antibiotic class: spring thunder element (kasugamycin), Polyoxin (polyoxine), jinggangmeisu (validamycin A);

Nitrophenyl derivative: karathane (dinocap),

Sulfur heterocyclic ring based compound: Delan (dithianon), Isoprothiolane (isoprothiolane);

Organo-metallic compound: triphenyltin salt

Organic phosphorus compound: Hinosan (edifenphos), iprobenfos (iprobenfos), ethyl phosphine aluminium (fosetyl-aluminum), Ppyrazophos (pyrazophos), tolelofos-methyl (tolclofos-methyl);

Organochlorine compound: tpn (chlorothalonil), Euparen (dichlofluanid), flusulfamide (flusulfamide), Rabcide (phthalide), Pencycuron (pencycuron), pcnb (q uintozene), tolyfluanid (tolylflu anid);

Inorganic active compound: bordeaux mixture (Bordeaux mixture), Kocide SD, Cupravit, basic copper sulfate, sulphur;

Other: (metrafenone) is with the luxuriant amine of Luo Evil (spiroxamine) for cyflufenamid (cyflufenamid), cymoxanil (cymoxanil), Milcurb (dimethirimol), Milstem (ethirimol), Furalaxyl (furalaxyl), metrafenone;

With

3) a kind ofly be selected from above-mentioned A)-F) and G)-J) the Fungicidal compounds III of group:

G) be selected from following strobilurins (Strobilurins): (2-chloro-5-[1-(3-methyl benzyloxy imino) ethyl] benzyl) methyl carbamate, (2-chloro-5-[1-(6-picoline-2-base methoxyimino) ethyl] benzyl) methyl carbamate and 2-(neighbour-(2,5-dimethyl phenoxy methylene) phenyl)-3-methoxy-methyl acrylate;

H) be selected from following carboxylic acid amides: furan pyrazoles spirit (furametpyr), tiadinil (tiadinil), N-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide; 3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide; N-(2 ', 4 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-3-two-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-3-two-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; 5-fluoro-1, the 3-dimethyl-[2-(1 for 1H-pyrazoles-4-formic acid, 2-dimethyl-propyl group)-phenyl]-acid amides, fluorine biphenyl bacterium (flumetover), carpropamide (carpropamid), and N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-3-methoxyphenyl) ethyl)-2-methanesulfonamido-3-methylbutyryl amine, N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-the 3-methoxyphenyl) ethyl)-2-second sulfonamido-3-methylbutyryl amine;

I) be selected from following heterocyclic compound:

4-dodecyl-2,6-thebaine (aldimorph), different thiophene bacterium ketone (octhilinone), indazole flusulfamide (amisulbrom), diclomezine (diclomezine), 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, 6-(3, the 4-dichlorophenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and 5-trifluoromethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 2-butoxy-6-iodo-3-propyl group chromene-4-ketone; Dazomet (dazomet), 3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazole alkane-3-yl] pyridine;

With

J) be selected from other following reactive compound: metham-sodium, 3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate; Streptomycin (streptomycin), binapacryl (binapacryl), dinobuton (dinobuton);

Fentinacetate (fentin-acetate), fosetyl (fosetyl), phosphorous acid and salt thereof, hexachloro-benzene (hexachlorobenzene), thiophanate methyl (thiophanate-methyl), and Schweinfurt green.

In addition, the present invention relates to a kind of mixture pest control that uses Compound I and reactive compound II and III, the method that comprises animal pest and harmful fungoid, Compound I and reactive compound II and III preparation in such mixture purposes and the composition that comprises this class mixture.

In one embodiment of the invention, the method of control insect, acarid or nematode is provided, and it comprises makes described insect, acarid or nematode or its provand source, habitat, breeding spot or its place contact with the Compound I of insecticidal effective dose and the mixture of two kinds of Compound I I and III.

In addition; in another embodiment; the invention still further relates to the method that a kind of protective plant is avoided insect, acarid or nematosis or infected; it comprises makes plant, or soil or water body that plant grows therein contact with the Compound I of insecticidal effective dose and the mixture of two kinds of Compound I I and III.

The method that the present invention also provides a kind of processing, control, prevented or watch for animals and avoid parasitic infestation or infect, it comprises the mixture of the Compound I of antiparasitic effective dose and two kinds of Compound I I and III is oral, part or parenteral or is applied to animal.

The present invention also provides a kind of preparation to be used to the method for compositions of handling, prevent and treat, prevent or protect warm blooded animal or fish to avoid insect, acarid or nematosis or infect, and said composition comprises the Compound I of insecticidal effective dose and the mixture of two kinds of Compound I I and III.

In addition, the present invention relates to a kind of mixture methods for fighting harmful mushrooms of using Compound I and reactive compound II and III, Compound I and reactive compound II and III preparation in such mixture purposes and the composition that comprises these mixtures.

Be called the Anthranilamide compound, its preparation of the formula I of component 1 above and be that known (WO 2004/67528 the effect of insect and acarid insect; WO 2004/46129; WO2004/33468; WO 2003/24222; WO 2003/15518).

Formula I compound and other insecticide to the useful mixture of insect usually by WO2004/67528; WO 2004/46129; WO 2004/33468; WO 2003/24222; WO 2003/15518 is known.WO 2006/055922 discloses the Anthranilamide compound derivative as independent compound and mixture.The binary mixture of formula I compound and fungicide is described among the WO 2006/108552.

Above reactive compound II that mentions as component 2 and 3 and III, its preparation and to the effect of harmful fungoid normally known (referring to Http:// www.hclrss.demon.co.uk/index.html); They can be commercial.

Hinosan, phosphonodithioic acid O-ethyl S, S-diphenyl; Iprobenfos, phosphonothiolic acid S-benzyl O, O-diisopropyl ester (Jpn.Pesticide Inf., the 2nd phase, the 11st page (1970)); Fosetyl, ethyl phosphine aluminium, phosphinic acid ethyl ester (aluminium) (FR 22 54 276); Ppyrazophos, 2-diethoxy sulfo-phosphonato-5-methylpyrazole be [1,5-a] pyrimidine-6-Ethyl formate (DE 15 45 790) also; Tolelofos-methyl, phosphonothiolic acid O-2,6-dichloro-p-toluene base O, O-dimethyl esters (GB 14 67 561); Tpn, 2,4,5,6-termil (US 3 290 353); Euparen, N-dichloro one fluorine methyl mercapto-N ', N '-dimethyl-N-phenyl-sulfamide (DE 11 93 498); Flusulfamide, 2 ', 4-two chloro-α, α, α-three fluoro-4 '-nitro between toluol sulfonanilide (EP-A 199 433); Hexachloro-benzene (C.R.Seances Acad.Agric.Fr., the 31st volume, the 24th page (1945)); Rabcide (DE 16 43 347); Pencycuron, 1-(4-benzyl chloride base)-1-cyclopenta-3-phenylurea (DE 27 32 257); Pcnb, pentachloro-nitrobenzene (DE 682 048); Thiophanate methyl, 1,2-phenylene two (imino group thiocarbonyl) two (carbamic acid dimethyl esters) (DE-OS 19 30540); Tolyfluanid, N-dichloro one fluorine methyl mercapto-N, N-dimethyl-N-p-methylphenyl sulfonamide (DE11 93 498); Bordeaux mixture, the mixture of slaked lime and copper sulphate (II); Kocide SD, Cu (OH) ₂Cupravit, Cu ₂Cl (OH) ₃Cyflufenamid, (Z)-N-[α-(cyclopropyl methoxyimino)-2,3-two fluoro-6-(trifluoromethyl) benzyls]-2-phenyl-acetamides (WO 96/19442); Cymoxanil, 1-(2-cyano group-2-methoxyimino acetyl group)-3-ethyl carbamide (US 3 957 847); Milcurb, 5-butyl-2-dimethylamino-6-methylpyrimidine-4-alcohol (GB 11 82 584); Milstem, 5-butyl-2-ethylamino-6-methylpyrimidine-4-alcohol (GB11 82 584); Furalaxyl, N-(2-furoyl base)-N-(2, the 6-xylyl)-DL-methyl lactamine (GB14 48 810); Metrafenone, 3 '-bromo-2,3,4,6 '-tetramethoxy-2 ', 6-dimethyl benzophenone (US 5 945567); The luxuriant amine of Luo Evil, (the 8-tert-butyl group-1,4-dioxo spiro [4.5] last of the ten Heavenly stems-2-yl) diethylamide (EP-A 281842).

Compound, its preparation and fungicidal action thereof according to the IUPAC name are known equally: (2-chloro-5-[1-(3-methyl benzyloxy imino group) ethyl] benzyl) methyl carbamate, (2-chloro-5-[1-(6-picoline-2-base methoxyimino) ethyl] benzyl) methyl carbamate (EP-A 12 01 648); 2-(neighbour-((2,5-dimethyl phenoxy methylene) phenyl)-3-methoxy-methyl acrylate (EP-A 226 917); 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazol [1,5-a] pyrimidine (WO98/46608), 3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide (WO 99/24413), N-(2-{4-[3-(4-chlorphenyl) third-2-alkynyloxy group]-the 3-anisyl } ethyl)-2-methanesulfonamido-3-methylbutyryl amine, N-(2-{4-[3-(4-chlorphenyl) third-2-alkynyloxy group]-the 3-anisyl } ethyl)-2-second sulfonamido-3-methylbutyryl amine (WO 2004/049804), N-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide (WO 2003/066609), N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide (WO2003/053145); 2-butoxy-6-iodo-3-propyl group chromene-4-ketone (WO 03/14103); 3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazole alkane-3-yl] pyridine (EP-A 1035122); The indazole flusulfamide, N, N-dimethyl-3-(3-bromo-6-fluoro-2 methyl indole-1-sulfonyl)-[1,2,4] triazole-1-sulfonamide (WO03/053145); 3-(4-chlorphenyl)-3-(2-isopropoxy carbonyl amino-3-methylbutyryl amino) methyl propionate (EP-A 1028125); 6-(3, the 4-dichlorophenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and 5-trifluoromethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine is known in EP-A 71 792; EP-A 141 317; WO2003/009687; WO 05/087771; WO 2005/087772; WO 2005/087773; WO2006/087325; And/or WO 2006/092428;

N-(2 ', 4 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide;

N-(3 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide;

N-(3 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-3--difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group)-phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide,

N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; 4-formic acid-N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; And N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide is known in WO 2006/087343, WO 2001/42223, WO 2005/34628, WO 2005/123689, WO 2005/123690, WO 2006/120219, WO 2007/017450 and/or EP application number 06123463.9.

For the rate of application that reduces known compound and widen its activity profile, the purpose of this invention is to provide under total amount of application of reactive compound reduces insect had and improve active mixture.

Appear at an interior typical problem of field of pest control and reduce the dose rate of active component when still allowing effective control of insect, to reduce or to avoid hostile environment or toxicology to influence for needing.

About the present invention, the term insect comprises animal pest and harmful fungoid.

Another problem that runs into relates to need be to the effective pest control agent of wide region insect.

Also exist and knock down (knock down) activity and prevent and treat for a long time combining, be i.e. the snap action and the needs of the pest control agent of continuous action for a long time.

About another difficulty of using agricultural chemicals be, cause insect fast selective to occur under many circumstances with the independent agricultural chemical compound of single administration repeatedly, mean that promptly described reactive compound is had chemical sproof insect and harmful fungoid natural or that adapt to.For this reason, exist helping to prevent or overcome the needs of chemical sproof pest control agent.

For this reason, purpose of the present invention has solved the depressant dose rate and/or has strengthened activity profile and/or combined the pesticide combination of the problem of knocking down active and long-term control and/or drug resistance management for providing.

We find that this purpose is partly or entirely realized by the combination of the defined reactive compound of beginning.In addition, we find to compare with the possible control rate of unification compound, and simultaneously, promptly associating or separate administration Compound I and two or more Compound I I or III can strengthen to insect the i.e. control of animal pest and harmful fungoid (Synergistic mixture).

In definition, use the following substituent collectivity term of representative usually to formula symbol that I gives:

Alkyl: have 1-6, the preferred saturated straight chain or the branched hydrocarbyl radical of 4 carbon atoms, for example C at the most ₁-C ₄Alkyl is as methyl, ethyl, propyl group, 1-Methylethyl, butyl, 1-methyl-propyl, 2-methyl-propyl, 1,1-dimethyl ethyl.

Formula I especially represents wherein, and R is the compound of methyl, ethyl, n-pro-pyl, isopropyl, normal-butyl, sec-butyl or the tert-butyl group.

Formula I especially represents wherein B ¹Compound for chlorine and cyano group.

Formula I especially represents wherein B ²Compound for bromine.

An embodiment is represented wherein, and R is the formula I compound of hydrogen.Another embodiment is represented wherein, and R is C ₁-C ₄The formula I compound of alkyl.

Especially consider their purposes in mixture of the present invention, preferably collect in the Compound I in the following table:

Table I

Sequence number	B 1	B 2	R
				I-1	H	Br	H
I-2	CN	Br	H
				I-3	Cl	Br	H
I-4	H	CF 3	H
				I-5	CN	CF 3	H
I-6	Cl	CF 3	H
				I-7	H	Br	CH 3
I-8	CN	Br	CH 3
				I-9	Cl	Br	CH 3
I-10	H	CF 3	CH 3
				I-11	CN	CF 3	CH 3
I-12	Cl	CF 3	CH 3
				I-13	H	Br	CH 2CH 3
I-14	CN	Br	CH 2CH 3
				I-15	Cl	Br	CH 2CH 3
I-16	H	CF 3	CH 2CH 3
				I-17	CN	CF 3	CH 2CH 3
I-18	Cl	CF 3	CH 2CH 3
				I-19	H	Br	CH 2CH 2CH 3
I-20	CN	Br	CH 2CH 2CH 3
				I-21	Cl	Br	CH 2CH 2CH 3
I-22	H	CF 3	CH 2CH 2CH 3
				I-23	CN	CF 3	CH 2CH 2CH 3
I-24	Cl	CF 3	CH 2CH 2CH 3
				I-25	H	Br	CH(CH 3) 2
I-26	CN	Br	CH(CH 3) 2
				I-27	Cl	Br	CH(CH 3) 2
I-28	H	CF 3	CH(CH 3) 2
				I-29	CN	CF 3	CH(CH 3) 2
I-30	Cl	CF 3	CH(CH 3) 2

Among special preferred compound I-2 and the I-3 any with the Compound I I of beginning definition and III in any combination.Special preferred compound I-3,3-bromo-4 '-chloro-1-(3-chloro-2-pyridine radicals)-2 '-methyl-6 '-(methylamino formoxyl) pyrazoles-5-formailide (carboxanilide), its temporary transient ISO is called chlorine insect amide (chlorantraniliprole).

The preferred embodiments of the invention provide Compound I, especially any and the ternary mixture that is selected from following Compound I I among Compound I-2 and the I-3:

Azole, especially: cyanogen frost azoles, IMAZALIL, pefurazoate, Prochloraz, fluorine bacterium azoles;

Strobilurins, especially: nitrile Fluoxastrobin, ether bacterium amine, Enestroburin, fork phenalgin acid amides, orysastrobin;

Carboxylic acid amides, especially: carpropamide, two chlorine zarilamid, flutolanil, the spirit of furan pyrazoles, mandipropamid amine, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, the spirit of fenfuram, Evil frost, oxycarboxin, pyrrole metsulfovax, thifluzamide, tiadinil;

Heterocyclic compound, especially: indazole flusulfamide, anilazine, diclomezine, azolactone bacterium, Fenamidone, different thiophene bacterium ketone, probenazole, pyroquilon, the third oxygen quinoline, tricyclazole.

Another preferred embodiment of the present invention provides nitrile Fluoxastrobin and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides carpropamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides two chlorine zarilamids and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides spirit of furan pyrazoles and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides orysastrobin and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides probenazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides tiadinil and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides thifluzamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides tricyclazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides fluorine bacterium azoles and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides pyroquilon and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides ether bacterium amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides fluoxastrobin and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides ZEN 90160 and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides pyraclostrobin and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides oxime bacterium ester and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Bitertanol and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides cyproconazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides oxole bacterium and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Fluquinconazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Flutriafol and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides the mixture that encircles penta azoles bacterium and collect in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides cycltebuconazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides prothioconazoles and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Prochloraz and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides triadimenol and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Tebuconazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment Ti Gong Difenoconazole of the present invention and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides thiabendazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides propiconazole and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides IMAZALIL and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Fu Evil bacterium and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides the mixture that encircles third pyrimidine and collect in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides pyrimethanil and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides guazatine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides dimethomorph and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides butadiene morpholine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides fenpropidin and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides tmtd and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides captan and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides metalaxyl and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Metalaxyl-M and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides thiophanate methyl and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides tpn and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides carboxin and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Boscalid and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides Guardian and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provide N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide with collect in the mixture of the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provide N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide with collect in the mixture of the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provide N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide with collect in the mixture of the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provide N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide with collect in the mixture of the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group)-phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-fluoro-1,3-dimethyl-1H-pyrazoles-4-formic acid [2-(1,2-dimethyl-propyl group)-phenyl]-acid amides and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 6-(3,4-two chloro-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-methyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4] triazols [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-ethyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4] triazols [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides 5-trifluoromethyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4] triazols [1,5-a] pyrimidin-7-yl amine and the mixture that collects in the arbitrary formula I compound in the Table I.

Another preferred embodiment of the present invention provides azoles bacterium piperazine and the mixture that collects in the arbitrary formula I compound in the Table I.

Comprising formula I compound collects in the following table as component 2 and another fungicide preferred ternary mixture as component 3 as component 1, fungicide II.

Following combination, wherein component 1 is a Compound I-2, and the combination of component 2 and 3 for the delegation of each triple combination corresponding to Table A.

Following combination, wherein component 1 is a Compound I-3, and the combination of component 2 and 3 for the delegation of each triple combination corresponding to Table A.

Following abbreviation is used in the Table A:

B1:N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide,

B2:N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide;

B3:3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide;

B4:N-(3 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide;

B5:N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide;

B6:N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide;

B7:N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide;

B8:N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide;

B9:N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group)-phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide,

B10:N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide;

B11:N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide;

B12:N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide;

B13:5-fluoro-1,3-dimethyl-1H-pyrazoles-4-formic acid [2-(1, the 2-dimethyl propyl)-phenyl]-acid amides;

B14:5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazols [1,5-a] pyrimidine;

B15:6-(3,4-two chloro-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B16:6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B17:5-methyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4] triazols [1,5-a] pyrimidin-7-yl amine;

B18:5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B19:6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B20:6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B21:5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B22:5-ethyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4] triazols [1,5-a] pyrimidin-7-yl amine;

B23:6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B24:5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B25:6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine;

B26:5-trifluoromethyl-6-(3,5,5-trimethyl-hexyl)-[1,2,4] triazols [1,5-a] pyrimidin-7-yl amine.

Table A

Sequence number	Component 2	Component 3
			A-1	Difenoconazole	Cyproconazole
A-2	Difenoconazole	Cycltebuconazole
			A-3	Difenoconazole	Encircle penta azoles bacterium
A-4	Difenoconazole	Azoles bacterium piperazine
			A-5	Difenoconazole	Triticonazole
A-6	Difenoconazole	The nitrile Fluoxastrobin
			A-7	Difenoconazole	Ether bacterium amine
A-8	Difenoconazole	Fluoxastrobin
			A-9	Difenoconazole	The imines bacterium
A-10	Difenoconazole	Fork phenalgin acid amides
			A-11	Difenoconazole	Orysastrobin
A-12	Difenoconazole	ZEN 90160
			A-13	Difenoconazole	Pyraclostrobin
A-14	Difenoconazole	Oxime bacterium ester
			A-15	Difenoconazole	Carboxin
A-16	Difenoconazole	Boscalid
			A-17	Difenoconazole	B1
A-18	Difenoconazole	B2
			A-19	Difenoconazole	B3
A-20	Difenoconazole	B4
			A-21	Difenoconazole	B5
A-22	Difenoconazole	B6
			A-23	Difenoconazole	B7
A-24	Difenoconazole	B8
			A-25	Difenoconazole	B9
A-26	Difenoconazole	B10
			A-27	Difenoconazole	B11
A-28	Difenoconazole	B12
			A-29	Difenoconazole	B13
A-30	Difenoconazole	Metalaxyl-M

Sequence number	Component 2	Component 3
			A-31	Difenoconazole	Mancozeb
A-32	Difenoconazole	Maneb
			A-33	Difenoconazole	Carbatene
A-34	Difenoconazole	Propineb
			A-35	Difenoconazole	Tmtd
A-36	Difenoconazole	Zineb
			A-37	Difenoconazole	Ziram
A-38	Oxole bacterium	Different third is fixed
			A-39	Oxole bacterium	Prochloraz
A-40	Oxole bacterium	Pyrimethanil
			A-41	Oxole bacterium	Azoles bacterium piperazine
A-42	Oxole bacterium	The nitrile Fluoxastrobin
			A-43	Oxole bacterium	Ether bacterium amine
A-44	Oxole bacterium	Fluoxastrobin
			A-45	Oxole bacterium	The imines bacterium
A-46	Oxole bacterium	Fork phenalgin acid amides
			A-47	Oxole bacterium	Orysastrobin
A-48	Oxole bacterium	ZEN 90160
			A-49	Oxole bacterium	Pyraclostrobin
A-50	Oxole bacterium	Oxime bacterium ester
			A-51	Oxole bacterium	Boscalid
A-52	Oxole bacterium	B1
			A-53	Oxole bacterium	B2
A-54	Oxole bacterium	B3
			A-55	Oxole bacterium	B4
A-56	Oxole bacterium	B5
			A-57	Oxole bacterium	B6
A-58	Oxole bacterium	B7
			A-59	Oxole bacterium	B8
A-60	Oxole bacterium	B9
			A-61	Oxole bacterium	B10
A-62	Oxole bacterium	B11
			A-63	Oxole bacterium	B12
A-64	Oxole bacterium	B13
			A-65	Oxole bacterium	B14
A-66	Oxole bacterium	B15

Sequence number	Component 2	Component 3
			A-67	Oxole bacterium	B16
A-68	Oxole bacterium	B17
			A-69	Oxole bacterium	B18
A-70	Oxole bacterium	B19
			A-71	Oxole bacterium	B20
A-72	Oxole bacterium	B21
			A-73	Oxole bacterium	B22
A-74	Oxole bacterium	B23
			A-75	Oxole bacterium	B24
A-76	Oxole bacterium	B25
			A-77	Oxole bacterium	B26
A-78	Oxole bacterium	Mancozeb
			A-79	Oxole bacterium	Maneb
A-80	Oxole bacterium	Carbatene
			A-81	Oxole bacterium	Propineb
A-82	Oxole bacterium	Tmtd
			A-83	Oxole bacterium	Zineb
A-84	Oxole bacterium	Ziram
			A-85	Fluquinconazole	The nitrile Fluoxastrobin
A-86	Fluquinconazole	Ether bacterium amine
			A-87	Fluquinconazole	Fluoxastrobin
A-88	Fluquinconazole	The imines bacterium
			A-89	Fluquinconazole	Fork phenalgin acid amides
A-90	Fluquinconazole	Orysastrobin
			A-91	Fluquinconazole	ZEN 90160
A-92	Fluquinconazole	Pyraclostrobin
			A-93	Fluquinconazole	Oxime bacterium ester
A-94	Fluquinconazole	Prochloraz
			A-95	Fluquinconazole	Azoles bacterium piperazine
A-96	Fluquinconazole	Boscalid
			A-97	Fluquinconazole	B1
A-98	Fluquinconazole	B2
			A-99	Fluquinconazole	B3
A-100	Fluquinconazole	B4
			A-101	Fluquinconazole	B5
A-102	Fluquinconazole	B6

Sequence number	Component 2	Component 3
			A-103	Fluquinconazole	B7
A-104	Fluquinconazole	B8
			A-105	Fluquinconazole	B9
A-106	Fluquinconazole	B10
			A-107	Fluquinconazole	B11
A-108	Fluquinconazole	B12
			A-109	Fluquinconazole	B13
A-110	Fluquinconazole	B14
			A-111	Fluquinconazole	B15
A-112	Fluquinconazole	B16
			A-113	Fluquinconazole	B17
A-114	Fluquinconazole	B18
			A-115	Fluquinconazole	B19
A-116	Fluquinconazole	B20
			A-117	Fluquinconazole	B21
A-118	Fluquinconazole	B22
			A-119	Fluquinconazole	B23
A-120	Fluquinconazole	B24
			A-121	Fluquinconazole	B25
A-122	Fluquinconazole	B26
			A-123	Encircle penta azoles bacterium	Boscalid
A-124	Encircle penta azoles bacterium	B1
			A-125	Encircle penta azoles bacterium	B2
A-126	Encircle penta azoles bacterium	B3
			A-127	Encircle penta azoles bacterium	B4
A-128	Encircle penta azoles bacterium	B5
			A-129	Encircle penta azoles bacterium	B6
A-130	Encircle penta azoles bacterium	B7
			A-131	Encircle penta azoles bacterium	B8
A-132	Encircle penta azoles bacterium	B9
			A-133	Encircle penta azoles bacterium	B10
A-134	Encircle penta azoles bacterium	B11
			A-135	Encircle penta azoles bacterium	B12
A-136	Encircle penta azoles bacterium	B13
			A-137	Encircle penta azoles bacterium	B14
A-138	Prochloraz	Metalaxyl

Sequence number	Component 2	Component 3
			A-139	Prochloraz	Triticonazole
A-140	Prochloraz	Cycltebuconazole
			A-141	Prochloraz	Encircle penta azoles bacterium
A-142	Prothioconazoles	The nitrile Fluoxastrobin
			A-143	Prothioconazoles	Ether bacterium amine
A-144	Prothioconazoles	Fluoxastrobin
			A-145	Prothioconazoles	The imines bacterium
A-146	Prothioconazoles	Fork phenalgin acid amides
			A-147	Prothioconazoles	Orysastrobin
A-148	Prothioconazoles	ZEN 90160
			A-149	Prothioconazoles	Pyraclostrobin
A-150	Prothioconazoles	Oxime bacterium ester
			A-151	Prothioconazoles	Cycltebuconazole
A-152	Prothioconazoles	Encircle penta azoles bacterium
			A-153	Prothioconazoles	Prochloraz
A-154	Prothioconazoles	Tebuconazole
			A-155	Prothioconazoles	Azoles bacterium piperazine
A-156	Prothioconazoles	Triticonazole
			A-157	Prothioconazoles	Metalaxyl
A-158	Prothioconazoles	Mancozeb
			A-159	Prothioconazoles	Maneb
A-160	Prothioconazoles	Carbatene
			A-161	Prothioconazoles	Propineb
A-162	Prothioconazoles	Tmtd
			A-163	Prothioconazoles	Zineb
A-164	Prothioconazoles	Ziram
			A-165	Prothioconazoles	Boscalid
A-166	Prothioconazoles	B1
			A-167	Prothioconazoles	B2
A-168	Prothioconazoles	B3
			A-169	Prothioconazoles	B4
A-170	Prothioconazoles	B5
			A-171	Prothioconazoles	B6
A-172	Prothioconazoles	B7
			A-173	Prothioconazoles	B8
A-174	Prothioconazoles	B9

Sequence number	Component 2	Component 3
			A-175	Prothioconazoles	B10
A-176	Prothioconazoles	B11
			A-177	Prothioconazoles	B12
A-178	Prothioconazoles	B13
			A-179	Tebuconazole	The nitrile Fluoxastrobin
A-180	Tebuconazole	Ether bacterium amine
			A-181	Tebuconazole	Fluoxastrobin
A-182	Tebuconazole	The imines bacterium
			A-183	Tebuconazole	Fork phenalgin acid amides
A-184	Tebuconazole	Orysastrobin
			A-185	Tebuconazole	ZEN 90160
A-186	Tebuconazole	Pyraclostrobin
			A-187	Tebuconazole	Oxime bacterium ester
A-188	Tebuconazole	Prochloraz
			A-189	Tebuconazole	Azoles bacterium piperazine
A-190	Tebuconazole	Mancozeb
			A-191	Tebuconazole	Maneb
A-192	Tebuconazole	Carbatene
			A-193	Tebuconazole	Propineb
A-194	Tebuconazole	Tmtd
			A-195	Tebuconazole	Zineb
A-196	Tebuconazole	Ziram
			A-197	Triticonazole	Oxole bacterium
A-198	Triticonazole	Prochloraz
			A-199	Triticonazole	Azoles bacterium piperazine
A-200	Triticonazole	Different third is fixed
			A-201	Triticonazole	Pyrimethanil
A-202	Triticonazole	The nitrile Fluoxastrobin
			A-203	Triticonazole	Ether bacterium amine
A-204	Triticonazole	Fluoxastrobin
			A-205	Triticonazole	The imines bacterium
A-206	Triticonazole	Fork phenalgin acid amides
			A-207	Triticonazole	Orysastrobin
A-208	Triticonazole	ZEN 90160
			A-209	Triticonazole	Pyraclostrobin
A-210	Triticonazole	Oxime bacterium ester

Sequence number	Component 2	Component 3
			A-211	Triticonazole	Metalaxyl
A-212	Triticonazole	Mancozeb
			A-213	Triticonazole	Maneb
A-214	Triticonazole	Carbatene
			A-215	Triticonazole	Propineb
A-216	Triticonazole	Tmtd
			A-217	Triticonazole	Zineb
A-218	Triticonazole	Ziram
			A-219	Triticonazole	Boscalid
A-220	Triticonazole	B1
			A-221	Triticonazole	B2
A-222	Triticonazole	B3
			A-223	Triticonazole	B4
A-224	Triticonazole	B5
			A-225	Triticonazole	B6
A-226	Triticonazole	B7
			A-227	Triticonazole	B8
A-228	Triticonazole	B9
			A-229	Triticonazole	B10
A-230	Triticonazole	B11
			A-231	Triticonazole	B12
A-232	Triticonazole	B13
			A-233	Triticonazole	B14
A-234	Triticonazole	B15
			A-235	Triticonazole	B16
A-236	Triticonazole	B17
			A-237	Triticonazole	B18
A-238	Triticonazole	B19
			A-239	Triticonazole	B20
A-240	Triticonazole	B21
			A-241	Triticonazole	B22
A-242	Triticonazole	B23
			A-243	Triticonazole	B24
A-244	Triticonazole	B25
			A-245	Triticonazole	B26
A-246	Azoles bacterium piperazine	B1

Sequence number	Component 2	Component 3
			A-247	Azoles bacterium piperazine	B2
A-248	Azoles bacterium piperazine	B3
			A-249	The nitrile Fluoxastrobin	Boscalid
A-250	Ether bacterium amine	Boscalid
			A-251	Fluoxastrobin	Boscalid
A-252	The imines bacterium	Boscalid
			A-253	Fork phenalgin acid amides	Boscalid
A-254	Orysastrobin	Boscalid
			A-255	ZEN 90160	Boscalid
A-256	Pyraclostrobin	Boscalid
			A-257	Oxime bacterium ester	Boscalid
A-258	The nitrile Fluoxastrobin	B1
			A-259	Ether bacterium amine	B1
A-260	Fluoxastrobin	B1
			A-261	The imines bacterium	B1
A-262	Fork phenalgin acid amides	B1
			A-263	Orysastrobin	B1
A-264	ZEN 90160	B1
			A-265	Pyraclostrobin	B1
A-266	Oxime bacterium ester	B1
			A-267	The nitrile Fluoxastrobin	B2
A-268	Ether bacterium amine	B2
			A-269	Fluoxastrobin	B2
A-270	The imines bacterium	B2
			A-271	Fork phenalgin acid amides	B2
A-272	Orysastrobin	B2
			A-273	ZEN 90160	B2
A-274	Pyraclostrobin	B2
			A-275	Oxime bacterium ester	B2
A-276	The nitrile Fluoxastrobin	B3
			A-277	Ether bacterium amine	B3
A-278	Fluoxastrobin	B3
			A-279	The imines bacterium	B3
A-280	Fork phenalgin acid amides	B3
			A-281	Orysastrobin	B3
A-282	ZEN 90160	B3

Sequence number	Component 2	Component 3
			A-283	Pyraclostrobin	B3
A-284	Oxime bacterium ester	B3
			A-285	The nitrile Fluoxastrobin	B4
A-286	Ether bacterium amine	B4
			A-287	Fluoxastrobin	B4
A-288	The imines bacterium	B4
			A-289	Fork phenalgin acid amides	B4
A-290	Orysastrobin	B4
			A-291	ZEN 90160	B4
A-292	Pyraclostrobin	B4
			A-293	Oxime bacterium ester	B4
A-294	The nitrile Fluoxastrobin	B5
			A-295	Ether bacterium amine	B5
A-296	Fluoxastrobin	B5
			A-297	The imines bacterium	B5
A-298	Fork phenalgin acid amides	B5
			A-299	Orysastrobin	B5
A-300	ZEN 90160	B5
			A-301	Pyraclostrobin	B5
A-302	Oxime bacterium ester	B5
			A-303	The nitrile Fluoxastrobin	B6
A-304	Ether bacterium amine	B6
			A-305	Fluoxastrobin	B6
A-306	The imines bacterium	B6
			A-307	Fork phenalgin acid amides	B6
A-308	Orysastrobin	B6
			A-309	ZEN 90160	B6
A-310	Pyraclostrobin	B6
			A-311	Oxime bacterium ester	B6
A-312	The nitrile Fluoxastrobin	B7
			A-313	Ether bacterium amine	B7
A-314	Fluoxastrobin	B7
			A-315	The imines bacterium	B7
A-316	Fork phenalgin acid amides	B7
			A-317	Orysastrobin	B7
A-318	ZEN 90160	B7

Sequence number	Component 2	Component 3
			A-319	Pyraclostrobin	B7
A-320	Oxime bacterium ester	B7
			A-321	The nitrile Fluoxastrobin	B8
A-322	Ether bacterium amine	B8
			A-323	Fluoxastrobin	B8
A-324	The imines bacterium	B8
			A-325	Fork phenalgin acid amides	B8
A-326	Orysastrobin	B8
			A-327	ZEN 90160	B8
A-328	Pyraclostrobin	B8
			A-329	Oxime bacterium ester	B8
A-330	The nitrile Fluoxastrobin	B9
			A-331	Ether bacterium amine	B9
A-332	Fluoxastrobin	B9
			A-333	The imines bacterium	B9
A-334	Fork phenalgin acid amides	B9
			A-335	Orysastrobin	B9
A-336	ZEN 90160	B9
			A-337	Pyraclostrobin	B9
A-338	Oxime bacterium ester	B9
			A-339	The nitrile Fluoxastrobin	B10
A-340	Ether bacterium amine	B10
			A-341	Fluoxastrobin	B10
A-342	The imines bacterium	B10
			A-343	Fork phenalgin acid amides	B10
A-344	Orysastrobin	B10
			A-345	ZEN 90160	B10
A-346	Pyraclostrobin	B10
			A-347	Oxime bacterium ester	B10
A-348	The nitrile Fluoxastrobin	B11
			A-349	Ether bacterium amine	B11
A-350	Fluoxastrobin	B11
			A-351	The imines bacterium	B11
A-352	Fork phenalgin acid amides	B11
			A-353	Orysastrobin	B11
A-354	ZEN 90160	B11

Sequence number	Component 2	Component 3
			A-355	Pyraclostrobin	B11
A-356	Oxime bacterium ester	B11
			A-357	The nitrile Fluoxastrobin	B12
A-358	Ether bacterium amine	B12
			A-359	Fluoxastrobin	B12
A-360	The imines bacterium	B12
			A-361	Fork phenalgin acid amides	B12
A-362	Orysastrobin	B12
			A-363	ZEN 90160	B12
A-364	Pyraclostrobin	B12
			A-365	Oxime bacterium ester	B12
A-366	The nitrile Fluoxastrobin	B13
			A-367	Ether bacterium amine	B13
A-368	Fluoxastrobin	B13
			A-369	The imines bacterium	B13
A-370	Fork phenalgin acid amides	B13
			A-371	Orysastrobin	B13
A-372	ZEN 90160	B13
			A-373	Pyraclostrobin	B13
A-374	Oxime bacterium ester	B13
			A-375	The nitrile Fluoxastrobin	B14
A-376	Ether bacterium amine	B14
			A-377	Fluoxastrobin	B14
A-378	The imines bacterium	B14
			A-379	Fork phenalgin acid amides	B14
A-380	Orysastrobin	B14
			A-381	ZEN 90160	B14
A-382	Pyraclostrobin	B14
			A-383	Oxime bacterium ester	B14
A-384	The nitrile Fluoxastrobin	B15
			A-385	Ether bacterium amine	B15
A-386	Fluoxastrobin	B15
			A-387	The imines bacterium	B15
A-388	Fork phenalgin acid amides	B15
			A-389	Orysastrobin	B15
A-390	ZEN 90160	B15

Sequence number	Component 2	Component 3
			A-391	Pyraclostrobin	B15
A-392	Oxime bacterium ester	B15
			A-393	The nitrile Fluoxastrobin	B16
A-394	Ether bacterium amine	B16
			A-395	Fluoxastrobin	B16
A-396	The imines bacterium	B16
			A-397	Fork phenalgin acid amides	B16
A-398	Orysastrobin	B16
			A-399	ZEN 90160	B16
A-400	Pyraclostrobin	B16
			A-401	Oxime bacterium ester	B16
A-402	The nitrile Fluoxastrobin	B17
			A-403	Ether bacterium amine	B17
A-404	Fluoxastrobin	B17
			A-405	The imines bacterium	B17
A-406	Orysastrobin	B17
			A-407	Fork phenalgin acid amides	B17
A-408	ZEN 90160	B17
			A-409	Pyraclostrobin	B17
A-410	Oxime bacterium ester	B17
			A-411	The nitrile Fluoxastrobin	B18
A-412	Ether bacterium amine	B18
			A-413	Fluoxastrobin	B18
A-414	The imines bacterium	B18
			A-415	Fork phenalgin acid amides	B18
A-416	Orysastrobin	B18
			A-417	ZEN 90160	B18
A-418	Pyraclostrobin	B18
			A-419	Oxime bacterium ester	B18
A-420	The nitrile Fluoxastrobin	B19
			A-421	Ether bacterium amine	B19
A-422	Fluoxastrobin	B19
			A-423	The imines bacterium	B19
A-424	Fork phenalgin acid amides	B19
			A-425	Orysastrobin	B19
A-426	ZEN 90160	B19

Sequence number	Component 2	Component 3
			A-427	Pyraclostrobin	B19
A-428	Oxime bacterium ester	B19
			A-429	The nitrile Fluoxastrobin	B20
A-430	Ether bacterium amine	B20
			A-431	Fluoxastrobin	B20
A-432	The imines bacterium	B20
			A-433	Fork phenalgin acid amides	B20
A-434	Orysastrobin	B20
			A-435	ZEN 90160	B20
A-436	Pyraclostrobin	B20
			A-437	Oxime bacterium ester	B20
A-438	The nitrile Fluoxastrobin	B21
			A-439	Ether bacterium amine	B21
A-440	Fluoxastrobin	B21
			A-441	The imines bacterium	B21
A-442	Fork phenalgin acid amides	B21
			A-443	Orysastrobin	B21
A-444	ZEN 90160	B21
			A-445	Pyraclostrobin	B21
A-446	Oxime bacterium ester	B21
			A-447	The nitrile Fluoxastrobin	B22
A-448	Ether bacterium amine	B22
			A-449	Fluoxastrobin	B22
A-450	The imines bacterium	B22
			A-451	Fork phenalgin acid amides	B22
A-452	Orysastrobin	B22
			A-453	ZEN 90160	B22
A-454	Pyraclostrobin	B22
			A-455	Oxime bacterium ester	B22
A-456	The nitrile Fluoxastrobin	B23
			A-457	Ether bacterium amine	B23
A-458	Fluoxastrobin	B23
			A-459	The imines bacterium	B23
A-460	Fork phenalgin acid amides	B23
			A-461	Orysastrobin	B23
A-462	ZEN 90160	B23

Sequence number	Component 2	Component 3
			A-463	Pyraclostrobin	B23
A-464	Oxime bacterium ester	B23
			A-465	The nitrile Fluoxastrobin	B24
A-466	Ether bacterium amine	B24
			A-467	Fluoxastrobin	B24
A-468	The imines bacterium	B24
			A-469	Fork phenalgin acid amides	B24
A-470	Orysastrobin	B24
			A-471	ZEN 90160	B24
A-472	Pyraclostrobin	B24
			A-473	Oxime bacterium ester	B24
A-474	The nitrile Fluoxastrobin	B25
			A-475	Ether bacterium amine	B25
A-476	Fluoxastrobin	B25
			A-477	The imines bacterium	B25
A-478	Fork phenalgin acid amides	B25
			A-479	Orysastrobin	B25
A-480	ZEN 90160	B25
			A-481	Pyraclostrobin	B25
A-482	Oxime bacterium ester	B25
			A-483	The nitrile Fluoxastrobin	B26
A-484	Ether bacterium amine	B26
			A-485	Fluoxastrobin	B26
A-486	The imines bacterium	B26
			A-487	Fork phenalgin acid amides	B26
A-488	Orysastrobin	B26
			A-489	ZEN 90160	B26
A-490	Pyraclostrobin	B26
			A-491	Oxime bacterium ester	B26
A-492	The nitrile Fluoxastrobin	Captan
			A-493	Ether bacterium amine	Captan
A-494	Fluoxastrobin	Captan
			A-495	The imines bacterium	Captan
A-496	Fork phenalgin acid amides	Captan
			A-497	Orysastrobin	Captan
A-498	ZEN 90160	Captan

Sequence number	Component 2	Component 3
			A-499	Pyraclostrobin	Captan
A-500	Oxime bacterium ester	Captan
			A-501	The nitrile Fluoxastrobin	Folpet
A-502	Ether bacterium amine	Folpet
			A-503	Fluoxastrobin	Folpet
A-504	The imines bacterium	Folpet
			A-505	Fork phenalgin acid amides	Folpet
A-506	Orysastrobin	Folpet
			A-507	ZEN 90160	Folpet
A-508	Pyraclostrobin	Folpet
			A-509	Oxime bacterium ester	Folpet
A-510	The nitrile Fluoxastrobin	Metalaxyl
			A-511	Ether bacterium amine	Metalaxyl
A-512	Fluoxastrobin	Metalaxyl
			A-513	The imines bacterium	Metalaxyl
A-514	Fork phenalgin acid amides	Metalaxyl
			A-515	Orysastrobin	Metalaxyl
A-516	ZEN 90160	Metalaxyl
			A-517	Pyraclostrobin	Metalaxyl
A-518	Oxime bacterium ester	Metalaxyl
			A-519	The nitrile Fluoxastrobin	Metalaxyl-M
A-520	Ether bacterium amine	Metalaxyl-M
			A-521	Fluoxastrobin	Metalaxyl-M
A-522	The imines bacterium	Metalaxyl-M
			A-523	Fork phenalgin acid amides	Metalaxyl-M
A-524	Orysastrobin	Metalaxyl-M
			A-525	ZEN 90160	Metalaxyl-M
A-526	Pyraclostrobin	Metalaxyl-M
			A-527	Oxime bacterium ester	Metalaxyl-M
A-528	The nitrile Fluoxastrobin	Dimethomorph
			A-529	Ether bacterium amine	Dimethomorph
A-530	Fluoxastrobin	Dimethomorph
			A-531	The imines bacterium	Dimethomorph
A-532	Fork phenalgin acid amides	Dimethomorph
			A-533	Orysastrobin	Dimethomorph
A-534	ZEN 90160	Dimethomorph

Sequence number	Component 2	Component 3
			A-535	Pyraclostrobin	Dimethomorph
A-536	Oxime bacterium ester	Dimethomorph
			A-537	The nitrile Fluoxastrobin	Thiophanate methyl
A-538	Ether bacterium amine	Thiophanate methyl
			A-539	Fluoxastrobin	Thiophanate methyl
A-540	The imines bacterium	Thiophanate methyl
			A-541	Fork phenalgin acid amides	Thiophanate methyl
A-542	Orysastrobin	Thiophanate methyl
			A-543	ZEN 90160	Thiophanate methyl
A-544	Pyraclostrobin	Thiophanate methyl
			A-545	Oxime bacterium ester	Thiophanate methyl
A-546	Metalaxyl	Boscalid
			A-547	Metalaxyl	B1
A-548	Metalaxyl	B2
			A-549	Metalaxyl	B3
A-550	Metalaxyl	B4
			A-551	Metalaxyl	B5
A-552	Metalaxyl	B6
			A-553	Metalaxyl	B7
A-554	Metalaxyl	B8
			A-555	Metalaxyl	B9
A-556	Metalaxyl	B10
			A-557	Metalaxyl	B11
A-558	Metalaxyl	B12
			A-559	Metalaxyl	B13
A-560	Metalaxyl	B14
			A-561	Metalaxyl-M	Boscalid
A-562	Metalaxyl-M	B1
			A-563	Metalaxyl-M	B2
A-564	Metalaxyl-M	B3
			A-565	Metalaxyl-M	B4
A-566	Metalaxyl-M	B5
			A-567	Metalaxyl-M	B6
A-568	Metalaxyl-M	B7
			A-569	Metalaxyl-M	B8
A-570	Metalaxyl-M	B9

Sequence number	Component 2	Component 3
			A-571	Metalaxyl-M	B10
A-572	Metalaxyl-M	B11
			A-573	Metalaxyl-M	B12
A-574	Metalaxyl-M	B13
			A-575	Guazatine	Oxole bacterium
A-576	Guazatine	Difenoconazole
			A-577	Guazatine	Encircle penta azoles bacterium
A-578	Guazatine	Tebuconazole
			A-579	Guazatine	Triticonazole
A-580	Guazatine	Carboxin
			A-581	Thiophanate methyl	Oxole bacterium
A-582	Thiophanate methyl	Difenoconazole
			A-583	Thiophanate methyl	Encircle penta azoles bacterium
A-584	Thiophanate methyl	Tebuconazole
			A-585	Thiophanate methyl	Triticonazole
A-586	Thiophanate methyl	Carboxin
			A-587	Captan	Oxole bacterium
A-588	Captan	Difenoconazole
			A-589	Captan	Encircle penta azoles bacterium
A-590	Captan	Tebuconazole
			A-591	Captan	Triticonazole
A-592	Captan	Carboxin
			A-593	Folpet	Oxole bacterium
A-594	Folpet	Difenoconazole
			A-595	Folpet	Encircle penta azoles bacterium
A-596	Folpet	Tebuconazole
			A-597	Folpet	Triticonazole
A-598	Folpet	Carboxin
			A-599	Fu Evil bacterium	Difenoconazole
A-600	Fu Evil bacterium	Flutriafol
			A-601	Fu Evil bacterium	Cycltebuconazole
A-602	Fu Evil bacterium	Encircle penta azoles bacterium
			A-603	Fu Evil bacterium	Tebuconazole
A-604	Fu Evil bacterium	Triticonazole
			A-605	Fu Evil bacterium	The nitrile Fluoxastrobin
A-606	Fu Evil bacterium	Ether bacterium amine

Sequence number	Component 2	Component 3
			A-607	Fu Evil bacterium	Fluoxastrobin
A-608	Fu Evil bacterium	The imines bacterium
			A-609	Fu Evil bacterium	Fork phenalgin acid amides
A-610	Fu Evil bacterium	Orysastrobin
			A-611	Fu Evil bacterium	ZEN 90160
A-612	Fu Evil bacterium	Pyraclostrobin
			A-613	Fu Evil bacterium	Oxime bacterium ester
A-614	Fu Evil bacterium	Carboxin
			A-615	Fu Evil bacterium	Encircle third pyrimidine
A-616	Fu Evil bacterium	Metalaxyl-M
			A-617	Fu Evil bacterium	Boscalid
A-618	Fu Evil bacterium	B1
			A-619	Fu Evil bacterium	B2
A-620	Fu Evil bacterium	B3
			A-621	Fu Evil bacterium	B4
A-622	Fu Evil bacterium	B5
			A-623	Fu Evil bacterium	B6
A-624	Fu Evil bacterium	B7
			A-625	Fu Evil bacterium	B8
A-626	Fu Evil bacterium	B9
			A-627	Fu Evil bacterium	B10
A-628	Fu Evil bacterium	B11
			A-629	Fu Evil bacterium	B12
A-630	Fu Evil bacterium	B13

For purposes of the present invention, mixture of the present invention or Compound I and reactive compound II and III can be changed into conventional preparaton, for example solution, emulsion, suspension, pulvis, powder, paste and particle.Type of service depends on the specific purpose that is intended to; Should guarantee the meticulous and distribution equably of The compounds of this invention in each case.

Preparaton prepares in known manner, for example prepares by reactive compound is mixed with solvent and/or carrier, and the words that need are used emulsifier and dispersant.Suitable solvent/auxiliary agent is mainly:

-water, arsol (as Solvesso product, dimethylbenzene), paraffin (as mineral oil fractions), alcohols (as methyl alcohol, butanols, amylalcohol, benzylalcohol), ketone (as cyclohexanone, gamma-butyrolacton), pyrrolidones (NMP, NOP), acetic acid esters (ethylene acetate), dihydroxylic alcohols, fatty acid dimethylformamide, fatty acid and fatty acid ester.Can also use solvent mixture in principle.

-carrier is as natural minerals (as kaolin, clay, talcum, chalk) that grinds and the synthetic mineral (as silica, the silicate of high degree of dispersion) that grinds; Emulsifier such as nonionic and anion emulsifier (as polyoxyethylene aliphatic alcohol ether, alkylsulfonate and arylsulphonate) and dispersant such as lignin sulfite waste liquor and methylcellulose.

Suitable surfactant is a lignosulphonic acid, naphthalene sulfonic acids, phenolsulfonic acid, the alkali metal salt of dibutyl naphthalene sulfonic acids, alkali salt and ammonium salt, alkylaryl sulfonates, alkyl sulfate, alkylsulfonate, aliphatic alcohol sulfate, fatty acid and sulphated fatty alcohol glycol ether, the condensation product of sulfonated naphthalene and naphthalene derivatives and formaldehyde in addition, the condensation product of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde, polyoxyethylene octylphenol ether, the ethoxylation isooctylphenol, octyl phenol, nonyl phenol, alkyl phenol polyglycol ether, tributyl phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, pure and mild fatty alcohol/ethylene oxide condensation product, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorbitol ester, lignin sulfite waste liquor and methylcellulose.

Being suitable for preparing directly, the material of spray solution, emulsion, paste or oil dispersion is that mid-boiling point arrives high boiling mineral oil fractions, as kerosene or diesel oil, the oil that also has coal tar and plant or animal origin in addition, aliphatic series, ring-type and aromatic hydrocarbon, for example toluene, dimethylbenzene, paraffin, tetrahydronaphthalene, alkylated naphthalene or derivatives thereof, methyl alcohol, ethanol, propyl alcohol, butanols, cyclohexanol, cyclohexanone, isophorone, intensive polar solvent, for example methyl-sulfoxide, N-Methyl pyrrolidone and water.

Antifreezing agent such as glycerine, ethylene glycol, propane diols and bactericide also can add preparaton.

Suitable defoamer for example is the defoamer based on polysiloxanes or dolomol.

Suitable preservative for example is antiphen (Dichlorophen) and phenmethylol hemiformal (enzylalkoholhemiformal).

The seed treatment preparaton can additionally comprise adhesive and optional colorants.

Add adhesive to improve active material adhesion for seed after processing.Proper adhesive is a block copolymer EO/PO surfactant, and polyvinyl alcohol, polyvinylpyrrolidone, polyacrylate, polymethacrylates, polybutene, polyisobutene, polystyrene, polyvinylamine, polyvinyl lactam, polymine

Polyethers, polyurethane, polyvinyl acetate, tylose and derived from the copolymer of these polymer.

Choose wantonly and in preparaton, also comprise colouring agent.The colouring agent or the dyestuff that are applicable to the seed treatment preparaton are rhodamine B, C.I. pigment red 112, C.I. solvent red 1, pigment blue 15: 4, pigment blue 15: 3, pigment blue 15: 2, pigment blue 15: 1, alizarol saphirol 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 4 8:2, pigment red 4 8:1, paratonere 57:1, paratonere 53:1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment Green 7, Pigment white 6, pigment brown 25, alkaline purple 10, alkalescence purple 49, acid red 51, acid red 52, azogeramine 4, acid blue 9, acid yellow 23, alkali red 1:1 0, alkali red 1:1 08.

The example of gelling agent is a carrageenan

But powder, broadcast sowing with material and dusting product and can prepare by active substance is mixed with solid carrier or grinds simultaneously.

Particle such as coated particle, impregnated granules and homogeneous particle can be by preparing reactive compound and solid carrier adhesion.The example of solid carrier is that ore deposit soil is as silica gel, silicate, talcum, kaolin, activated clay (attaclay), lime stone, lime, chalk, bole, loess, clay, dolomite, diatomite, calcium sulphate, magnesium sulfate, magnesia, the synthetic material that grinds, fertilizer such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, and the product of plant origin such as flour, bark powder, wood powder and shuck powder, cellulose powder and other solid carrier.

Preparaton comprises 0.01-95 weight % usually, the reactive compound of preferred 0.1-90 weight %.Reactive compound is with 90-100%, and the purity of preferred 95-100% (according to the NMR spectrum) is used.

For seed treatment, various preparatons can obtain reactive compound after doubly at dilution 2-10 and use 0.01-60 weight % in the preparation, the concentration of preferred 0.1-40 weight % shortly.

Under classify the preparaton example as:

1. the product of dilute with water

For seed treatment, these products can dilute or be applied to seed without dilution.

A water-soluble concentrate (SL, LS)

10 weight portion reactive compounds are dissolved in 90 weight parts waters or the water-soluble solvent.Perhaps, add wetting agent or other auxiliary agent.Reactive compound is through water dilution dissolving.Obtain the preparaton that reactive compound content is 10 weight % in this way.

The dispersed concentrate (DC) of B

Be dissolved in 20 weight portion reactive compounds in the 70 weight portion cyclohexanone and add 10 weight portion dispersant such as PVP(polyvinyl pyrrolidone).Dilute with water obtains dispersion.Reactive compound content is 20 weight %.

C missible oil (EC)

Be dissolved in 15 weight portion reactive compounds in the 75 weight portion dimethylbenzene and add calcium dodecyl benzene sulfonate and castor oil ethoxylate (being 5 weight portions in each case).Dilute with water obtains emulsion.The reactive compound content of this preparaton is 15 weight %.

D emulsion (EW, EO, ES)

Be dissolved in 25 weight portion reactive compounds in the 35 weight portion dimethylbenzene and add calcium dodecyl benzene sulfonate and castor oil ethoxylate (being 5 weight portions in each case).Add this mixture in 30 weight parts waters and make equal phase emulsion by mulser (as Ultraturrax).Dilute with water obtains emulsion.The reactive compound content of preparaton is 25 weight %.

E suspension (SC, OD, FS)

In the ball mill that stirs, 20 weight portion reactive compounds are pulverized and added 10 weight portion dispersants and wetting agent and 70 weight parts waters or organic solvent, obtain reactive compound suspension in small, broken bits.Dilute with water obtains stable reactive compound suspension.Reactive compound content is 20 weight % in the preparaton.

F water-dispersible granule and water-soluble granular (WG, SG)

With the grinding in small, broken bits of 50 weight portion reactive compounds and add 50 weight portion dispersant and wetting agents, be made into water dispersible or water-soluble granular by commercial plant (as extruder, spray tower, fluid bed).Dilute with water obtains stable active compound dispersion or solution.The reactive compound content of this preparaton is 50 weight %.

G water dispersible pow-ders and water-soluble powder (WP, SP, SS, WS)

75 weight portion reactive compounds are ground in the rotor-stator grinding machine and add 25 weight portion dispersants, wetting agent and silica gel.Dilute with water obtains stable active compound dispersion or solution.The reactive compound content of this preparaton is 75 weight %.

H gel formulation (GF)

In ball mill, with 20 weight portion reactive compounds, 10 weight portion dispersants, 1 weight portion gelling agent and 70 weight parts waters or organic solvent grind, and obtain suspension in small, broken bits.Dilute with water obtains the steady suspension that reactive compound content is 20 weight %.

2. the product of using without dilution

But I dusting powder (DP, DS)

Fully mix with the grinding in small, broken bits of 5 weight portion reactive compounds and with 95 weight portions kaolin in small, broken bits.But this obtains the dusting product that reactive compound content is 5 weight %.

J particle (GR, FG, GG, MG)

With the grinding in small, broken bits of 0.5 weight portion reactive compound and in conjunction with 99.5 weight portion carriers.Current methods be extrude, atomized drying or bed process.The reactive compound content that this obtains using without dilution is the particle of 0.5 weight %.

K ULV solution (UL)

10 weight portion reactive compounds are dissolved in 90 weight portion organic solvents such as the dimethylbenzene.The reactive compound content that this obtains using without dilution is the product of 10 weight %.

Usually, with water-soluble concentrate (LS), suspension (FS) but dusting powder (DS), water dispersible and water-soluble powder (WS, SS), emulsion (ES), missible oil (EC) and gel formulation (GF) are used for seed treatment.These preparatons can not diluted forms or preferably are applied to seed with diluted form.Use and before sowing, to carry out.

In preferred embodiments, the FS preparaton is used for seed treatment.The FS preparaton can comprise 1-800g/l active component, 1-200g/l surfactant, 0-200g/l antifreezing agent, 0-400g/l adhesive, 0-200g/l pigment and 1 liter of solvent at the most, preferred water usually.

Reactive compound can be directly, with its preparaton form or type of service prepared therefrom, but as directly spray solution, powder, suspension or dispersion, emulsion, oil dispersion, paste dusting product, broadcast sowing, by spraying, atomizing, dusting, broadcast sowing or water and use with material or particle.Type of service depends on the purpose that is intended to fully; Be intended to guarantee in each case that the best of reactive compound of the present invention may distribute.

Moisture type of service can be prepared by emulsion concentrates, paste or wettable powder (sprayable powder, oil dispersion) by adding entry.Be preparation emulsion, paste or oil dispersion, can be with this material directly or be dissolved in back homogenizing in water in oil or the solvent by wetting agent, tackifier, dispersant or emulsifier.Perhaps can also prepare concentrate and this concentrate formed by active substance, wetting agent, tackifier, dispersant or emulsifier and suitable solvent or oil and be suitable for dilute with water.

Promptly can in relative broad range, change with the activity compound concentration in the preparation.It typically is 0.0001-10%, preferred 0.01-1%.

Reactive compound also can successfully use with ultra low volume method (ULV), wherein can use to comprise the preparaton that surpasses 95 weight % reactive compounds or even can not have to use reactive compound under the situation of additive.

Various types of oil, wetting agent, adjuvant, weed killer herbicide, fungicide, other agricultural chemicals or bactericide can be added in the reactive compound just (bucket mixes) adding before being close to use of suitable words.These reagent usually can 1: 100-100: 1, preferred 1: 10-10: 1 weight ratio and reagent mix of the present invention.

Composition of the present invention can also contain other active components, other agricultural chemicals for example, weed killer herbicide, fertilizer such as ammonium nitrate, urea, potash and superphosphate, phytotoxin and plant growth regulator and safener.These extra compositions can with above-mentioned composition successively or be used in combination, suitable words also add (bucket mixing) before using being close to.For example can be before or after handling with other active components with the present composition plant of spraying.

The mixture of Compound I and Compound I I and III, or simultaneously, i.e. associating or separately use Compound I and Compound I I and III plant pathogenic fungi to wide region, especially be selected from Ascomycetes (Ascomycetes), deuteromycetes (Deuteromycetes), Peronosporomycetes (synonym: Oomycete (Oomycetes)) and the fungi of Basidiomycetes (Basidiomycetes) have the activity of excellence.The interior suction of in them some is effective and can be used as blade face fungicide, seed dressing is used for crop protection with fungicide and soil fungicide.

They are even more important to a large amount of fungies of control in various cultivated plants such as banana, cotton, vegetables (as cucumber, beans and cucurbitaceous plant), barley, dogstail, oat, coffee, potato, corn, fruit, rice, rye, soybean, tomato, grape vine, wheat, ornamental plants, sugarcane and multiple seed.

Compound I and Compound I I and III can be simultaneously, i.e. associating or separate administration, or use successively, under the situation of separate administration, order of administration usually to the result of prophylactico-therapeutic measures without any influence.

They are even more important to a large amount of fungies of control in the seed of various cultivated plants such as wheat, rye, barley, oat, rice, corn, dogstail, banana, cotton, soybean, coffee, sugarcane, grape vine, fruit and ornamental plants and vegetables such as cucumber, beans, tomato, potato and cucurbitaceous plant and these plants.It also can be used for, and the invasion and attack to insect or fungi have in the crop of resistance owing to the cultivation that comprises gene engineering.In addition, it is applicable to that also control especially attacks the grape seat chamber Pseudomonas (Botryosphaeria) of timber or grape vine root, Cylindrocarpon (Cylindrocarpon), grape apical dieback germ (Eutypa lata), Chinese tulip tree new clump red shell bacterium (Neonectria liriodendri) and hair Boreostereum vibrans (Stereum hirsutum).

They are particularly suitable for preventing and treating following various plant disease:

Chain lattice spore (Alternaria) on vegetables, rape seed, sugar beet, fruit, rice and soybean and the potato belongs to (for example early epidemic disease chain lattice spores (A.solani) or alternaria (A.alternata)), with (for example early epidemic disease chain lattice spores (A.solani) or alternaria (A.alternata)) on the tomato, belong to (black points (black head mold)) with the chain lattice spore (Alternaria) on the wheat

Silk capsule mould (Aphanomyces) on sugar beet and the vegetables belongs to,

Shell two spores (Ascochyta) on cereal class and the vegetables belong to, and for example the wheat full front of a Chinese gown leaf on the wheat is dazzled bacterium (Ascochyta tritici) (leaf spot),

Flat navel in corn, cereal class, rice and the lawn wriggles that spore (Bipolaris) belongs to and interior navel is wriggled spore (Drechslera) genus (for example southern corn leaf blight on the corn (D.maydis)),

Standing grain powdery mildew (Blumeria graminis) (powdery mildew) in the cereal class (for example wheat or barley),

Botrytis cinerea on strawberry, vegetables, flowers, grape vine and the wheat (Botrytis cinerea) (head mold disease) (head mold),

Lettuce dish stalk mould (Bremia lactucae) on the lettuce,

Tail spore (Cercospora) on corn, rice, the sugar beet belongs to, for example soybean tail spore (Cercospora sojina) (leaf spot) on the soybean or Kikuchi tail spore (Cercospora kikuchii) (leaf spot),

French beans branch spore (Cladosporium herbarum) on the wheat (dry rot (ear rot)),

Cochliobolus (Cochliobolus) on corn, cereal class and the rice belongs to (for example palace portion cochliobolus (Cochliobolusmiyabeanus) on standing grain cochliobolus on the cereal class (Cochliobolus sativus) and the rice),

Perverse dish spore (Colletotricum) on the cotton belongs to and the green soy bean anthrax bacteria (Colletotrichum truncatum) (anthracnose) on the soybean for example,

Corynespora cassicola on the soybean (Corynespora cassiicola) (leaf spot)

Lineae ablicantes plumage synnema bacterium (Dematophora necatrix) (root/neck rot) on the soybean

Seat shell (Diaporthe phaseolorum) between the Kidney bean on the soybean (stem disease evil)

On corn, cereal class, rice and the lawn, the interior navel of (for example D.tritci-repentis) is wriggled on (for example in the barley filigree navel wriggle spore (D.teres)) or the wheat on the barley, and spore (Drechslera) belongs to, nuclear cavity bacteria (Pyrenophora) belongs to,

Eschka (Esca) on the grape vine that causes by Phaeoacremonium chlamydosporium, Ph.Aleophilum and Formitipora punctata (synonym spot hole Phellinus (Phellinus punctatus));

Elsinochrome on the grape vine (Elsinoe empelina),

Epicoccum on the wheat (Epicoccum) (black points)

Prominent navel on the corn spore (Exserohilum) of wriggling belongs to,

Two spore powdery mildews (Erysiphe cichoracearum) on the cucumber and monofilament shell powdery mildew (Sphaerotheca fuliginea),

Fusarium on each plant species (Fusarium) belongs to and wheel branch spore (Verticillium) belongs to, for example Fusarium graminearum (F.graminearum) on the cereal class (for example wheat or barley) or the sharp sickle spore (F.oxysporum) on machete sickle spore (F.culmorum) (root rot) or the tomato and the Zhen Mate fusarium solanae (Fusarium Solani) on the soybean (stem disease evil)

Gaeumannomyce (Gaeumanomyces graminis) on the cereal class (for example wheat or barley) belongs to (head mold disease (root black)),

Red mould (Gibberella) on cereal class and the rice belongs to (for example gibberella fujikuroi on the rice (Gibberellafujikuroi)),

Enclose small cluster shell (Glomerella cingulata) on grape vine and other plant,

Gram complex on the rice (Grainstaining complex),

Grape Guignardia on the grape vine (Guignardia budwelli),

Length on corn and the rice spore (Helminthosporium) of wriggling belongs to,

Foxiness on the grape vine is intended Isaria (Isariopsis clavispora),

Kidney bean lattice spore (Macrophomina phaseolina) (root/stem rot) on the soybean,

Michrodochium nivale (snow mold) on the cereal class (for example wheat and barley),

Microsphaera diffusa (powdery mildew) on the soybean,

Ball chamber bacterium (Mycosphaerella) on cereal class, banana and the peanut belongs to, for example standing grain green-ball chamber bacterium (M.graminicola) on the wheat or the M.fijiesis on the banana,

Downy mildew on the wild cabbage (Peronospora) belongs to (for example rape downy mildew (P.brassicae)), (for example P.destructor) on the onion and for example northeast downy mildew (Peronosporamanshurica) (downy mildew) on the soybean,

Yam bean layer rest fungus (Phakopsora pachyrhizi) (soybean rust) on the soybean and mountain horseleech layer rest fungus (Phakopsara meibomiae) (soybean rust),

Phialophora gregata on the soybean (stem disease evil),

Phomopsis on sunflower, grape vine and the soybean (Phomopsis) belongs to (as the grape Phomopsis (P.viticola) on the grape vine and the Phomopsis phaseoli on the soybean),

Phytophthora on each plant species (Phytophthora), the Phytophthora capsici on the green pepper (P.capsici) for example, big male epidemic disease on the soybean mould (Phytophthora megasperma) (leaf/stem rot), the phytophthora infestans on potato and the tomato (Phytophthora infestans)

Grape on the grape vine is given birth to single shaft mould (Plasmopara viticola),

Apple mildew bacterium on the apple (Podosphaera leucotricha),

The rotten germ (Pseudocercosporellaherpotrichoides) (eye spot) of the wheat-based of (wheat or barley) on the cereal class,

False downy mildew (Pseudoperonospora) on each plant species belongs to, the humulus grass false downy mildew (P.humili) on false downy mildew (P.cubenis) of the Cuba on the cucumber or the lupulus for example,

Pseudopezicula tracheiphilai on the grape vine,

Handle rest fungus (Puccinia) on each plant species belongs to, the wheat rust bacterium (P.triticina) on the cereal class (for example barley and wheat) for example, yellow rust bacterium (P.striformis), on barley aecidium (P.hordei) or puccinia graminis (P.graminis) or the asparagus (asparagus aecidium (P.asparagi))

Pyricularia oryzae on the wheat (the Pyrenophora teres (net blotch) on Pyricularia oryzae), Bamboo grass wood photovoltaicing leather bacteria (Corticiumsasakii), broom stalk Cylindrocarpon (Sarocladium oryzae), sheath rot of rice plant (S.attenuatum), Pyrenophora tritici-repentis (leaf spot) or the barley

Rice leaf smut (Entyloma oryzae) on the rice,

Piricularia oryzae on lawn and the cereal class (Pyricularia grisea),

Rotten mould (Pythium) on lawn, rice, corn, wheat, cotton, rape seed, sunflower, sugar beet, vegetables and the other plant belongs to, and (for example ultimate corruption mould (P.ultimum) or melon and fruit corruption mould (P.aphanidermatum)),

Ramularia collo-cygni on the barley (Ramularia/ sunburn (sunburn) compound/physiology leaf spot),

Rhizoctonia (Rhizoctonia) on cotton, rice, potato, lawn, corn, rape seed, potato, sugar beet, vegetables and the various other plant belongs to, the cereal rhizoctonia (Rhizoctoniacerealis) on the miliary damping-off germ on the soybean (Rhizoctonia solani) (root/stem rot) or wheat or the barley (maculopathy (sharp eyspot)) for example

Rye beak spore (Rhynchosporium secalis) on barley (leaf spot), rye and the triticale,

Sclerotinite on rape seed, sunflower and the soybean (Sclerotinia) belongs to, for example sclerotinite on the soybean (Sclerotinia sclerotiorum) (stem disease evil) or Sclerotinia rolfsii (stem disease evil),

Soybean septoria musiva on the soybean (Septoria glycines) (leaf spot),

Wheat septoria on the wheat (Septoria tritici) (leaf blight (leaf septoria)) and the many spores of clever withered shell (Stagonospora nodorum),

Grape snag shell on the grape vine (Erysiphe (synonym Uncinula neeator),

Setospaeria on corn and the lawn belongs to,

Silk axle smut (Sphacelotheca reilinia) on the corn,

The many spores of clever withered shell (Stagonospora nodorum) on the wheat (glume blight (ear septoria)),

Thielaviopsis sp on soybean and the cotton (Thievaliopsis) belongs to,

Tilletia foetida on the cereal class (Tilletia) belongs to,

Meat spore nuclear coral bacterium (Typhula incarnate) (snow mold) on wheat or the barley,

Smut on cereal class, corn and the sugarcane (Ustilago) belongs to (for example Ustilago maydis on the corn (U.maydis)),

Black star bacterium (Venturia) on apple and the pears belongs to (scab) (for example apple scab on the apple (V.in aequalis)).

Target crop can be the crop of conventional plant or the crop of genetically modified plant (" GM plant " or " GMO ").

For this reason, the present composition also is suitable for useful plant, especially cereal class, cotton, soybean, sugar beet, sugarcane, kind plant (for example citrus fruit, coffee, banana), rape, maize and the antiweed of rice, anti-insect and/or antimycotic genetically modified crops.

The antiweed crop is understood to include by conventional breeding or gene engineering method and tolerates those crops of multiple weed killer herbicide or multiclass weed killer herbicide (for example ALS, GS, EPSPS, PPO and HPPD inhibitor).The example that tolerates the crop of imidazolone for example such as imazamox (imazamox) by the conventional breeding method is

Summer rape ((canola) drawn in the Kano).The example of the crop of herbicide-tolerant is the corn variety of anti-for example glyphosate (glyphosate) or careless ammonium phosphine (glufosinate) by gene engineering method, and it respectively can trade (brand) name

With

Buy.

For the purpose of the present invention, anti-insect and/or antimycotic transgenosis useful plant should clearly be interpreted as and comprise those useful plants that also have herbicide tolerant except that having pest resistance and/or antifungal activity.According to the present invention, in the herbicide tolerant useful plant, preferably have glyphosate, careless ammonium phosphine (glufosinate-ammonium), ALS (acetolactate synthestase) inhibitor, sulfonylureas for example, as primisulfuronmethyl (primisulfuron), fluorine third yellow grand (prosulfuron) and trifluoro pyridine yellow grand (trifloxysulfuron)) or the useful plant of the tolerance of Brominal (bromoxynil), for example the Bt11 maize or

Maize.

For the purpose of the present invention, anti-insect genetically modified crops plant is interpreted as making it can synthesize one or more selectively acting toxin by using recombinant DNA technology to transform, for example by toxigenic bacterium, the plant of the known toxin of those bacillus (Bacillus) bacterium particularly.

Can for example comprise insecticidal proteins by the toxin that these genetically modified plants are expressed, as insecticidal proteins from Bacillus cercus (Bacillus cereus) or Japanese beetle bacillus (Bacillus popilliae); Or from the insecticidal proteins of bacillus thuringiensis (Bacillus thuringiensis), α-endotoxin for example, as CryIA (b), CryIA (c), CryIF, CryIF (a2), CryIIA (b), CryIIIA, CryIIIB (bi) or Cry9c, or plant insecticide albumen (VIP), as VIP1, VIP2, VIP3 or VIP3A; Or colonize in bacterium on the nematode, Photobacterium (Photorhabdus spp.) for example, Xenorhabdus belongs to (Xenorhabdus spp.), as luminous bacillus (Photorhabdus luminescens), Xenorhabdus nematophilus (Xenorhabdus nematophilus)) insecticidal proteins; By the toxin of animal generation, as scorpion toxin, spider animal toxin, wasp toxin and other insect-specific neurotoxin; By mycetogenetic toxin, streptomycete (Streptomycetes) toxin for example; Lectins, for example pea haemoglutinin, barley haemoglutinin or snowdrop haemoglutinin; Agglutinin; Protease inhibitors, for example trypsin inhibitor, serpin, potato tubers storage protein (patatin), serum NAC protease (cystatin) inhibitor, antipain; Ribosome inactivating protein (RIP), for example ricin, maize RIP, abrin, sponge gourd seed toxalbumin (luffin), sapotoxin albumen (saporin) or cucurbit toxalbumin (bryodin); The steroid metabolism enzyme, as blocking agent, juvenile hormone esterase, the diuretic hormone acceptor, 1 of 3-hydroxy steroid oxidase, ecdysteroid-UDP-glycosyl transferase, cholesterol oxidase, moulting hormone inhibitor, HMG-COA reductase, ion channel blocking agent such as sodium or calcium channel, 2-benzene divinyl synzyme, bibenzyl synzyme, chitinase and dextranase.

For the purpose of the present invention, should understand and comprise following material: the d-endotoxin, for example CryIA (b), CryIA (c), CryIF, CryIF (a2), CryIIA (b), CryIIIA, CryIIIB (bi) or Cry9c, or plant insecticide albumen (VIP), for example VIP1, VIP2, VIP3 or VIP3A also clearly comprise hybridization toxin, truncated toxins (truncated toxin) and modify toxin.The hybridization toxin is by the different structure territory that reconfigures those albumen generation (for example referring to WO 02/15701) of recombinating.The example of truncated toxins is brachymemma CryIA (b), and it is to express in the Bt11 maize of Syngenta Seeds SAS as mentioned below.Modifying under the situation of toxin, naturally existing the one or more amino acid in the toxin to be replaced.In this seed amino acid was replaced, preferably the protease recognition sequence that non-natural is existed inserted in the toxin, for example under the situation of CryIIIA055, cathepsin-D-recognition sequence was inserted in the CryIIIA toxin (referring to WO 03/018810).

The example that these toxin maybe can synthesize the genetically modified plants of these toxin for example is disclosed among EP-A374 753, WO 93/07278, WO 95/34656, EP-A 427 529, EP-A 451 878 and the WO 03/052073.

Normally those skilled in the art are known to produce the methods of these genetically modified plants, and for example are described in the publication mentioned above.CryI type DNA (deoxyribonucleic acid) and preparation example thereof are as known by WO95/34656, EP-A 367 474, EP-A 401 979 and WO 90/13651.

Contained toxin provides tolerance to harmful insect for plant in the genetically modified plants.These insects can belong to any classification of insect, but especially are common in beetle (coleoptera (Coleoptera)), dipteran (diptera (Diptera)) and the butterfly (Lepidoptera (Lepidoptera)).

The harmful insect of following different classification is especially common in the maize crop:

Ostrinia nubilalis, European corn borer,

Agrotis ipsilon, black cutworm,

Helicoverpa zea, corn earworm,

Spodoptera frugiperda, fall army worm,

Diatraea grandiosella, southwestern corn straw crambid,

Elasmopalpus lignosellus, South America maize seedling phycitid,

Diatraea saccharalis, little sugarcane borer,

Diabrotica virgifera virgifera, western corn root leaf A,

Diabrotica longicornis barberi, northern northern corn root-worm,

Diabrotica undecimpunctata howardi, the southern corn root is chrysomelid,

Melanotus spp., the acupuncture needle Eimeria

Cyclocephala borealis, northern round end rhinoceros cockchafer (grub),

Cyclocephala immaculata, southern round end rhinoceros cockchafer (grub),

Popillia japonica, Japanese beetle,

Chaetocnema pulicaria, the corn flea beetle,

Sphenophorus maidis, the latent beak of corn resembles,

Rhopalosiphum maidis, corn leaf aphids,

Anuraphis maidiradicis, corn tail aphid,

Blissus leucopterus leucopterus, the corn chinch bug,

Melanoplus femurrubrum, red foot is deceived locust,

Melanoplus sanguinipes, the black locust that migrates,

Hylemya platura plants fly,

Agromyza parvicornis, the corn liriomyza bryoniae,

Anaphothrips obscurus, yellow slow-witted thrips,

Solenopsis milesta, the theft ant,

Tetranychus urticae, T.urticae Koch.

The genetically modified plants that contain one or more coded insect-killing agent resistances and express the gene of one or more toxin are known, and some of them can be buied.The example of these plants is:

(expressing the maize kind of CryIA (b) toxin); YieldGard (expressing the maize kind of CryIIIB (bi) toxin); YieldGard

(expressing the maize kind of CryIA (b) and CryIIIB (bi) toxin);

(expressing the maize kind of Cry9 (c) toxin); Herculex (expressing CryIF (a2) toxin and phosphine oxamate (phosphinothricin) N-acetyl group-transferase (PAT)) to obtain maize kind to the tolerance of weed killer herbicide grass ammonium phosphine; NuCOTN

(expressing the cotton variety of CryIA (c) toxin); Bollgard

(expressing the cotton variety of CryIA (c) toxin); Bollgard

(expressing the cotton variety of CryIA (c) and CryIIA (b) toxin);

(expressing the cotton variety of VIP toxin);

(expressing the potato kind of CryIIIA toxin);

Know

Other example of these genetically modified crops is:

1. from Syngenta Seeds SAS, Chemin de I ' Hobit 27, F-31 790St.Sauveur, the Bt11 maize of France, number of registration C/FR/96/05/10.The genetic modification corn (Zea mays) of anti-European corn snout moth's larva (European corn borer and powder stem snout moth's larva (Sesamianonagrioides)) invasion and attack by transgene expression brachymemma CryIA (b) toxin.The Bt11 maize also transgene expression enzyme PAT to obtain tolerance to weed killer herbicide grass ammonium phosphine.

2. from Syngenta Seeds SAS, Chemin de I ' Hobit 27, F-31 790St.Sauveur, the Bt176 maize of France, number of registration C/FF/96/05/10.The genetic modification corn of anti-European corn snout moth's larva (European corn borer and powder stem snout moth's larva) invasion and attack by transgene expression CryIA (b) toxin.The Bt176 maize also transgene expression enzyme PAT to obtain tolerance to weed killer herbicide grass ammonium phosphine.

3. from Syngenta Seeds SAS, Chemin de I ' Hobit 27, F-31 790St.Sauveur, the MIR604 maize of France, number of registration C/FR/96/05/10.The maize that presents insect-resistant by the CryIHA toxin of transgene expression modification.This toxin is for by inserting the Cry3A055 that cathepsin-the D-protease recognition sequence is modified.The preparation of these transgenosis maize plants is described among the WO 03/018810.

4. from Monsanto Europe S.A.270-272Avenue de Tervuren, B-1150Brussels, Belgian MON 863 maizes, number of registration C/DE/02/9.MON 863 expresses CryIIIB (bi) toxin and has resistance to some coleopteron.

5. from Monsanto Europe S.A.270-272Avenue de Tervuren, B-1150Brussels, Belgian IPC 531 cottons, number of registration C/ES/96/02.

6. from Pioneer Overseas Corporation, Avenue Tedesco, 7B-1160Brussels, Belgian 1507 maizes, number of registration C/NLJ00/10.Expressing protein Cry1F is to obtain the resistance of some lepidopterous insects and to express PAT albumen to obtain the genetic modification maize to the tolerance of weed killer herbicide grass ammonium phosphine.

7. from Monsanto Europe S.A.270-272Avenue de Tervuren, B-1150Brussels, Belgian NK603x MON 810 maizes, number of registration C/GB/02/M3/03.By constituting by the conventional breeding hybridization maize kind that genetic modification kind NK603 and MON 810 hybridization are obtained.Express by giving weed killer herbicide that Agrobacterium (Agrobacterium sp.) bacterial strain CP4 obtains on NK603x MON 810 maize transgenosiss ground

The PROTEIN C P4EPSPS of the tolerance of (containing glyphosate) and the generation that obtained by bacillus thuringiensis Que Shi KOH-KAE (kurstaki) subspecies are to CryIA (b) toxin of the tolerance of some lepidopterous insects of comprising the European corn snout moth's larva.

The genetically modified crops of anti-insect plant also are described in BATS (Clarastrasse 13,4058Basel, Switzerland for Zentrum f ü r Biosicherheitund Nachhaltigkeit, Zentrum BATS) report 2003, ( Http:// bats.ch) in.

For the purpose of the present invention, antimycotic genetically modified crops are interpreted as making it can synthesize those crops of the antipathogen (for example so-called " pathogenesis-related protein " (PRP is for example referring to EP-A 392 225)) with selectively acting by using recombinant DNA technology to transform.These antipathogens are for example known by EP-A 392 225, WO95/33818 and EP-A 353 191 with the example of the genetically modified plants that can synthesize these antipathogens.Normally those skilled in the art are known to produce the methods of these genetically modified plants, and for example are described in the publication mentioned above.

Can for example comprise the ion channel blocking agent by the antipathogen that these genetically modified plants are expressed, the blocking agent of sodium and calcium channel for example, for example viral KP1, KP4 or KP6 toxin; 1,2-benzene divinyl synzyme; The bibenzyl synzyme; Chitinase; Dextranase; So-called " pathogenesis-related protein " (PRP is for example referring to EP-A 392 225); Antipathogen by microorganisms, for example peptide antibiotic or heterocycle antibiotic (for example referring to WO 95/33818) or phytopathogen are defendd related protein or polypeptide factor (so-called " disease resistance in plants gene " is described in WO 03/000906).Other field of the use present composition stores goods and storeroom for protection and protects raw material (for example timber, textile, flooring material or building) and in health field, particularly protect the mankind, domestic animal and yielding ability livestock to prevent the insect of mentioned type.

For the purpose of the present invention, genetically modified plants can contain gene (for example, the RR of one or more coded insect-killing resistances and Herbicid resistant as mentioned above

Or RR

Feature).Those plants are considered to contain dual or even the genetically modified plants of triple accumulation gene (stacked gene).In addition, also can consider this multiple accumulation of gene in the genetically modified plants or incident is defined at more extensive and more applications, for example fungicide resistance or arid resistance.The latter is interpreted as being provided at stress resistance under the arid selection pressure by using recombinant DNA technology to transform to make it can carry to crop.In addition, in the multiple accumulation definition of genetically modified crops, must consider that when introducing gene that the specific physiological pathway by the modification crop provides extra yield to increase the yield potentiality of specific crop itself is for example in the soybean by the transformation technology that uses recombinant DNA

In addition, the mixture of Compound I and reactive compound II and III also is suitable for preventing and treating the product of harmful fungoid with protective material (as timber, paper, lacquer dispersion, fiber or fabric) and protection storage.In wood protection, should note following harmful fungoid especially: the Ascomycetes fungi, belong to (Ophiostoma spp.) as line mouth shell, long beak shell belongs to (Ceratocystis spp.), Aureobasidium pullulans (Aureobasidium pullulans), Sclerophoma spp., Chaetomium (Chaetomium spp.), Humicola (Humicola spp.), Peter's shell belongs to (Petriella spp.), the mould genus of pieces (Trichurusspp.); The Basidiomycetes fungi; belong to (Coniophora spp.) as cellar fungus; Coriolus Qu61 (Coriolusspp.); sticking gill fungus belongs to (Gloeophyllum spp.); Lentinus (Lentinus spp.); Pleurotus (Pleurotus spp.); hole genus (Poria spp.) crouches; Merulius (Serpula spp.) and cheese Pseudomonas (Tyromyces spp.); the deuteromycetes fungi; as aspergillus (Aspergillus spp.); Cladosporium (Cladosporium spp.); Penicillium (Penicillium spp.); trichoderma (Trichoderma spp.), Alternaria (Alternaria spp.), paecilomyces (Paecilomyces spp.) and Zygomycetes (Zygomycetes) fungi; as mucor (Mucor spp.), should note following yeast in this external material protection: candida (Candida spp.) and saccharomyces cerevisiae (Saccharomyces cerevisae).

Compound I and Compound I I are usually with 5000: 1-1: 5000, preferred 500: 1-1: 100, more preferably 100: 1-1: 100, especially 20: 1-1: 20, most preferably 10: 1-1: 10 weight ratio is used.

Compound III is with 20: 1-1: 20 weight ratio adds in the Compound I.

Perhaps, compound III is with 20: 1-1: 20 weight ratio adds among the Compound I I.

When the preparation mixture, preferred pure reactive compound I, II and the III of using, can be as required to the reactive compounds that wherein add other antagonism harmful fungoids or other insects such as insect, spider or nematode or activity of weeding or growth regulating-activity compound or fertilizer with as other active component.

Usually, the mixture of Compound I and two kinds or suitable more kinds of active components of words may be favourable.

Other suitable on above-mentioned meaning active components especially start reactive compound II and the III that is mentioned, particularly above-mentioned preferred reactive compound.

The mixture of Compound I and reactive compound II and III need prevent maybe that by handling fungi with the reactive compound of antifungal effective dose plant, seed, material or the soil of fungal attack from using.Use and before material, plant or seed are by fungal infection and afterwards, to carry out.

In the method for antagonism harmful fungoid, depend on the type and the required effect of compound, the rate of application of mixture of the present invention is 5-2000g/ha, preferred 50-900g/ha, especially 50-750g/ha.

Correspondingly, the rate of application of Compound I is generally 1-1000g/ha, preferred 10-900g/ha, especially 20-750g/ha.

Correspondingly, reactive compound II and III rate of application separately is generally 1-2000g/ha, preferred 10-900g/ha, especially 40-500g/ha.

Methods for fighting harmful mushrooms by before or after the plant seeding or plant emerge before or after by to seed, plant or soil spraying or dusting separates or co-administered Compound I and reactive compound II and III, or the mixture of Compound I and reactive compound II and III and carrying out.

Processing can be carried out in seed-box before kind of implantation ground.

Compound I, u and III or mixture or corresponding preparaton pass through the mixture with the antifungal effective dose, or the Compound I under the situation of separate administration, II and III handle harmful fungoid, need prevent their plant, seed, soil, zone, material or space and use.Use and before or after harmful fungoid infects, to carry out.

The mixture of Compound I, II and III, or simultaneously, i.e. associating or the Compound I, II and the III that separately use have also shown the effect of the outstanding following order insect of antagonism:

Lepidopterous insects (Lepidoptera (Lepidoptera)); black cutworm (Agrotis ypsilon) for example; white line dart moth of turnip (Agrotis segetum); kapok worm (Alabama argillacea); Anticarsia (Anticarsia gemmatalis); Argyresthia conjugella; fork Autographa spp (Autographagamma); tree looper (Bupalus piniarius); Cacoecia murinana; Capuareticulana; Cheimatobia brumata; dragon spruce Choristoneura spp (Choristoneurafumiferana); Choristoneura occidentalis; striped rice borer (Cirphis unipuncta); codling moth (Cydia pomonella); pine caterpillars (Dendrolimus pini); Diaphanianitidalis; southwest corn straw crambid (Diatraea grandiosella); Egyptian brill noctuid (Eariasinsulana); South America maize seedling phycitid (Elasmopalpus lignosellus); ligustrum fine tortricidae (Eupoecilia ambiguella); Evetria bouliana; Feltia subterranea; galleria mellonella waxmoth (Galleria mellonella); Lee's Grapholita spp (Grapholith a funebrana); oriental fruit moth (Grapholitha molesta); cotton bollworm (Heliothis armigera); tobacco budworm (Heliothisvirescens); corn earworm (Heliothis zea); Oeobia undalis (Hellula undalis); Hiberniadefoliaria; fall webworm (Hyphantria cunea); apple ermine moth (Hyponomeutamalinellus); tomato worm moth (Keiferia lycopersicella); Lambdina fiscellaria; beet armyworm (Laphygma exigua); coffee leafminer (Leucoptera coffeella); pear leaf blister moth (Leucoptera scitella); Lithocolletis blancardella; grape berry steinernema (Lobesiabotrana); beet webworm (Loxostege sticticalis); gypsymoth (Lymantria dispar); lymantria monacha (Lymantria monacha); peach leaf miner (Lyonetia clerkella); malacosoma neustria (Malacosoma neustria); tomato moth (Mamestra brassicae); Douglas fir poison moth (Orgyiapseudotsugata); corn borer (Ostrinia nubilalis); small noctuid (Panolis flammea); cotton pink bollworm (Pectinophora gossypiella); boundary noctuid (Peridroma saucia); circle palm boat moth (Phalera bucephala); tobacco split worm (Phthorimaea operculella); citrus leaf-miner (Phyllocnistis citrella); Pieris brassicae (Pieris brassicae); the green noctuid of clover (Plathypena scabra); diamond-back moth (Plutella xylostella); soybean noctuid (Pseudoplusiaincludens); Rhyacionia frustrana; Scrobipalpula absoluta; gelechiid (Sitotrogacerealella); grape berry moth (Sparganothis pilleriana); fall army worm (Spodopterafrugiperda); sea spodoptera (Spodoptera littoralis); prodenia litura (Spodopteralitura); Thaumatopoea pityocampa; green oak moth (Tortrix viridana); cabbage looper (Trichoplusia ni) and Zeiraphera canadensis

Beetle (coleoptera (Coleoptera)), the narrow lucky fourth of pears (Agrilus sinuatus) for example, vertical bar click beetle (Agriotes lineatus), dark-coloured click beetle (Agriotes obscurus), Amphimallussolstitialis, Anisandrus dispar, Mexico's cotton boll resembles (Anthonomus grandis), the apple flower resembles (Anthonomus pomorum), Aphthona euphoridae, Athoushaemorrhoidalis, Atomaria linearis (Atomaria linearis), vertical pit cutting pin small moth (Blastophagus piniperda), Blitophaga undata, broad bean weevil (Bruchusrufimanus), pea weevil (Bruchus pisorum), Lens culinaris resembles (Bruchus lentis) in Europe, the apple volume resembles (Byctiscus betulae), the big tortoise plastron of beet (Cassida nebulosa), Cerotomatrifurcata, golden flower cockchafer (Cetonia aurata), Chinese cabbage seed tortoise resembles (Ceuthorrhynchusassimilis), the blister beetle tortoise resembles (Ceuthorrhynchus napi), beet shin flea beetle (Chaetocnematibialis), Conoderus vespertinus, asparagus scotellaris (Crioceris asparagi), Ctenicera ssp., northern corn root-worm (Diabrotica longicornis), Diabroticasemipunctata, Diabrotica 12-punctata, South America chrysomelid (Diabrotica speciosa), corn root leaf A (Diabrotica virgifera), mexican bean ladybird (Epilachna varivestis), tobacco flea beetle (Epitrix hirtipennis), cotton ash covers and resembles mutation (Eutinobothrus brasiliensis), Europe hylobius abietis (Hylobius abietis), Egyptian cloverleaf resembles (Hypera brunneipennis), alfalfa leaf resembles (Hypera postica), ips typographus (Ips typographus), tobacco scotellaris (Lema bilineata), black angle scotellaris (Lema melanopus), colorado potato beetles (Leptinotarsadecemlineata), Limonius californicus, rice water weevil (Lissorhoptrusoryzophilus), Melanotus communis, rape nitidulid (Meligethes aeneus), Da Li gill cockchafer (Melolontha hippocastani), gill cockchafer in May (Melolontha melolontha), Oulema oryzae (Oulema oryzae), vine black ear beak resembles (Ortiorrhynchus sulcatus), Otiorhynchus spp (Otiorrhynchus ovatus), horseradish ape chrysomelid (Phaedon cochleariae), leaf of pear tree resembles (Phyllobius pyri), Phyllotreta chrysocephala, food phyllobranchia cockchafer belongs to (Phyllophaga sp.), rutelian (Phyllopertha horticola) is sent out in the flower garden, the light sufficient flea beetle of soybean (Phyllotreta nemorum), Phyllotreta striolata (Phyllotreta striolata), Japanese beetle (Popillia japonica), the pea leaf resembles (Sitona lineatus) and grain weevil (Sitophilus granaria)

Fly, mosquito (diptera (Diptera)), Aedes aegypti (Aedes aegyptii) for example, aedes albopictus (Aedes albopictus), perversely disturb yellow-fever mosquito (Aedes vexans), Mexico fruit bat (Anastrephaludens), anopheles maculipennis (Anopheles maculipennis), Anopheles crucians, white sufficient anopheles (Anopheles albimanus), anopheles costalis (Anopheles gambiae), Anophelesfreeborni, Hainan Island anopheles leucosphyrus leucosphyrus (Anopheles leucosphyrus), Yunnan anopheles minius (Anopheles minimus), anopheles quadrimaculatus (Anopheles quadrimaculatus), calliphora erythrocephala (Calliphora vicina), Mediterranean fruitfly (Ceratitis capitata), maggot disease gold fly (Chrysomyabezziana), Chrysomya hominivorax, Chrysomya macellaria, deerfly (Chrysops discalis), Chrysops silacea, Chrysops atlanticus, screwfly (Cochliomyia hominivorax), Chinese sorghum cecidomyiia (Contarinia sorghicola), cordylobia anthropophaga maggot (Cordylobia anthropophaga), furious storehouse midge (Culicoides furens), northern house (Culex pipiens), spot mosquito (Culex nigripalpus), Culex quinquefasciatus (Culexquinquefasciatus), matchmaker's spot mosquito (Culex tarsalis), Culiseta inornata, Culisetamelanura, melon fly (Dacus cucurbitae), dacus oleae (Dacus oleae), rape leave cecidomyiia (Dasineura brassicae), Delia antique, wheat field kind fly (Delia coarctata), delia platura (Delia platura), fly (Delia radicum) is planted on wild cabbage ground, Dermatobia hominis, little Mao latrine fly (Fannia canicularis), Geomyza Tripunctata, horse botfly (Gasterophilus intestinalis), glossina morsitans (Glossina morsitans), glossina palpalis (Glossina palpalis), Glossina fuscipes, glue tsetse fly (Glossina tachinoides), Haematobia irritans, Haplodiplosis equestris, Hippelates (Hippelates spp.), peanut field delia platura (Hylemyia platura), heel fly (Hypoderma lineata), Leptoconops torrens, vegetables liriomyza bryoniae (Liriomyza sativae), U.S. Liriomyza (Liriomyza trifolii), Lucilia caprina, lucilia cuprina (Lucilia cuprina), lucilia sericata (Lucilia sericata), Lycoria pectoralis, Mansonia titillanus, wheat cecidomyiia (Mayetiola destructor), housefly (Musca domestica), false stable fly (Muscinastabulans), oestrosis of sheep (Oestrus ovis), Opomyza florum, Europe wheat stem maggot (Oscinellafrit), henbane seed spring fly (Pegomya hysocyami), onion fly (Phorbia antiqua), radish fly (Phorbia brassicae), wheat field kind fly (Phorbia coarctata), phlebotomus argentipes (Phlebotomusargentipes), Psorophora columbiae, carrot fly (Psila rosae), Psorophora discolor, Prosimulium mixtum, cherry fruit fly (Rhagoletiscerasi), Rhagoletis pomonella (Rhagoletis pomonella), Sarcophaga haemorrhoidalis (Sarcophagahaemorrhoidalis), flesh fly belongs to (Sarcophaga), Simulium vittatum, tatukira (Stomoxys calcitrans), the gadfly (Tabanus bovinus), Tabanus atratus, red former horsefly (Tabanus lineola), Tabanus similis, Tipula oleracea and European daddy-longlegs (Tipula paludosa)

Thrips (thrips (Thysanoptera)); orchid thrips (Dichromothripscorbetti) for example; Dichromothrips ssp.; cigarette brown thrip (Frankliniella fusca); honeysuckle thrips (Frankliniella occidentalis); east flower thrips (Frankliniella tritici); the hard thrips of tangerine (Scirtothrips citri); rice thrips (Thrips oryzae); palm thrips (Thrips palmi) and onion thrips (Thrips tabaci)

Termite (Isoptera (Isoptera)), for example Calotermes flavicollis, Leucotermesflavipes, golden yellow different termite (Heterotermes aureus), yellow limb reticulitermes flavipe (Reticulitermesflavipes), U.S. little black reticulitermes flavipe (Reticulitermes virginicus), European reticulitermes flavipe (Reticulitermes lucifugus), Termes natalensis and Taiwan formosanes (Coptotermesformosanus)

Cockroach (Blattaria (Blattaria-Blattodea), for example Groton bug (Blattellagermanica), Blattella asahinae, American cockroach (Periplaneta americana), the big Lian (Periplaneta japonica) of Japan, brown blattaria (Periplaneta brunnea), Periplanetafuligginosa, Australia blattaria (Periplaneta australasiae) and oriental cockroach (Blattaorientalis)

Real bedbug (Semiptera (Hemiptera)) is for example intended green stinkbug (Acrosternum hilare), corn chinch bug (Blissus leucopterus), blackspot cigarette fleahopper (Cyrtopeltis notatus), red cotton bug (Dysdercus cingulatus), Dysdercus intermedius, wheat Eurygasterspp (Eurygasterintegriceps), tobacco stinkbug (Euschistus impictiventris), cotton red bell beak coried (Leptoglossus phyllopus), America tarnished plant bug (Lygus lineolaris), tarnished plant bug (Lygus pratensis), green rice bug (Nezara viridula), beet is intended lace bug (Piesmaquadrata), Solubea insularis, Thyanta perditor, Acyrthosiphononobrychis, adelge laricis (Adelges laricis), Aphidula nasturtii, aphis fabae (Aphis fabae), strawberry root aphid (Aphis forbesi), apple aphid (Aphis pomi), cotten aphid (Aphis gossypii), North America tea bamboo trunk aphid (Aphis grossulariae), Xi Naide aphid (Aphisschneideri), leaf roll aphid (Aphis spiraecola), elder aphid (Aphis sambuci), acyrthosiphum pisim (Acyrthosiphon pisum), eggplant does not have net aphid (Aulacorthum solani), Bemisia argentifolii (Bemisia argentifolii), welted thistle short-tail aphid (Brachycaudus cardui), Lee's short-tail aphid (Brachycaudus helichrysi), peach short-tail aphid (Brachycaudus persicae), Brachycaudus prunicola, cabbage aphid (Brevicoryne brassicae), Capitophorushorni, Cerosipha gossypii, knurl nail hair aphid (Chaetosiphon fragaefolii) in the strawberry, the tea bit of a bridle is concealed knurl aphid (Cryptomyzus ribis), abies nordmanniana vertebra adelgid (Dreyfusianordmannianae), dragon spruce vertebra adelgid (Dreyfusia piceae), Ju Genxi rounded tail aphid (Dysaphisradicola), Dysaulacorthum pseudosolani, rounded tail aphid (Dysaphisplantaginea) before the car, pears west rounded tail aphid (Dysaphis pyri), broad bean Empoasca spp (Empoascafabae), mealy plum aphid (Hyalopterus pruni), Hyperomyzus lactucae, English grain aphid (Macrosiphum avenae), root of Beijing euphorbia Macrosiphus spp (Macrosiphum euphorbiae), rose pipe aphid (Macrosiphon rosae), the nest Lay is repaiied tail aphid (Megoura viciae), Melanaphispyrarius, wheat does not have net aphid (Metopolophium dirhodum), Myzodes persicae, shallot knurl volume aphid (Myzus ascalonicus), Myzus cerasi, Lee's knurl aphid (Myzus varians), black tea bit of a bridle is patched up Macrosiphus spp (Nasonovia ribis-nigri), rice fulgorid (Nilaparvata lugens), suspensor goitre woolly aphid (Pemphigus bursarius), sugarcane plant hopper (Perkinsiella saccharicida), phorodon aphid (Phorodon humuli), apple leaf sucker (Psylla mali), pear sucker (Psylla piri), shallot knurl moth aphid (Rhopalomyzus ascalonicus), corn leaf aphids (Rhopalosiphum maidis), cereal is overflow and manages aphid (Rhopalosiphum padi), apple grass Rhopalosiphum spp (Rhopalosiphum insertum), Sappaphis mala, Sappaphis mali, greenbug (Schizaphis graminum), Schizoneura lanuginosa, English grain aphid (Sitobion avenae), trialeurodes vaporariorum (Trialeurodes vaporariorum), black citrus aphid (Toxoptera aurantiiand), grape phylloxera (Viteus vitifolii), bed bug (Cimex lectularius), cimex hemipterus (Cimexhemipterus), Reduvius senilis, Triatoma belongs to and Arilus critatus.

Ant, honeybee, wasp, sawfly (Hymenoptera (Hymenoptera)), Xinjiang cabbage sawfly (Athalia rosae) for example, leaf cutting ant (Atta cephalotes), Atta capiguara, Atta laevigata, Atta robusta, Atta sexdens, Atta texana, lift the abdomen ant and belong to (Crematogaster), Hoplocampa minuta, Hoplocampa testudinea, monomorium pharaonis (Monomoriumpharaonis), Solenopsis geminata (Solenopsis geminate), red fire ant (Solenopsis invicta), black fiery ant (Solenopsis richteri), south fiery ant (Solenopsis xyloni), red ant (Pogonomyrmex barbatus), Pogonomyrmex californicus, Pheidolemegacephala, velvet ant (Dasymutilla occidentalis), bombus (Bombus), hornet (Vespula squamosa), Paravespula vulgaris, Paravespulapennsylvanica, Paravespula germanica, Ji wasp (Dolichovespula maculata), yellow limit wasp (Vespa crabro), wasp (Polistes rubiginosa), Camponotusfloridanus and Argentine ant (Linepithema humile)

Cricket, grasshopper, locust (orthoptera (Orthoptera)), residential house Chinese mugwort Xi (Achetadomestica) for example, mole cricket (Gryllotalpa gryllotalpa), migratory locusts (Locusta migratoria), double cut is deceived locust (Melanoplus bivittatus), red foot is deceived locust (Melanoplus femurrubrum), Mexico deceives locust (Melanoplus mexicanus), black locust (Melanoplus sanguinipes) migrates, stone is dwelt and is deceived locust (Melanoplus spretus), the red locust of striped (Nomadacris septemfasciata), America desert locust (Schistocerca americana), desert locust (Schistocerca gregaria), Morocco halberd line locust (Dociostaurus maroccanus), front yard disease kitchen range Zhong (Tachycines asynamorus), plug is received jar (unit of capacitance) dolly locust (Oedaleus senegalensis), Zonozerus variegatus, Africa sugarcane locust (Hieroglyphus daganensis), Kraussaria angulifera, Italy locust (Calliptamusitalicus), grass dwell locust (Chortoicetes terminifera) and brown in Australia intended migratory locusts (Locustanapardalina)

Spider guiding principle (Arachnoidea)), as spider (Acarina (Acarina)), soft ticks section (Argasidae) for example, hard tick section (Ixodidae) and Sarcoptidae (Sarcoptidae), as long star tick (Amblyomma americanum), torrid zone flower tick (Amblyomma variegatum), Ambryomma maculatum, adobe tick (Argas persicus), ox tick (Boophilusannulatus), Boophilus decoloratus, boophilus microplus (Boophilus microplus), Dermacentor silvarum, Dermacentor andersoni (Dermacentor andersoni), the big leather tick in America (Dermacentor variabilis), Hyalomma truncatum, castor bean tick (Ixodesricinus), Ixodes rubicundus, black stiffness of foot in children tick (Ixodes scapularis), ixodes holocyclus (Ixodesholocyclus), ixodes pacificus (Ixodes pacificus), Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus turicata, ornithonyssus bacoti (Ornithonyssusbacoti), Otobius megnini, Dermanyssus gallinae (Dermanyssus gallinae), sheep scabies disease (Psoroptes ovis), Rhipicephalus sanguineus, Rhipicephalusappendiculatus, Rhipicephalus evertsi, Sarcoptes scabiei hominis (Sarcoptes scabiei), goitre mite (Eriophyidae) belongs to, as thorn apple rust mite (Aculus schlechtendali), Phyllocoptrataoleivora and Eriophyes sheldoni; Thin mite (Tarsonemidae) belongs to, as Phytonemuspallidus and Polyphagotarsonemus latus Banks (Polyphagotarsonemus latus); False spider mite (Tenuipalpidae) belongs to, as purplish red short hairs mite (Brevipalpus phoenicis); Tetranychid (Tetranychidae) belongs to, as Tetranychus cinnabarinus (Tetranychus cinnabarinus), kamisawa tetranychus (Tetranychus kanzawai), Pacific Ocean tetranychid (Tetranychus pacificus), cotton spider mites (Tetranychus telarius) and T.urticae Koch (Tetranychus urticae), apple tetranychus (Panonychus ulmi), mandarin orange a tree name tetranychid (Panonychus citri) and meadow unguiculus mite (Oligonychuspratensis); Araneida (Araneida), for example poisonous spiders (Latrodectus mactans) and brown silk spider (Loxosceles reclusa),

Flea (Siphonaptera (Siphonaptera)), for example cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), Xanthopsyllacheopis (Xenopsylla cheopis), Pulex irritans (Pulexirritans), chigo (Tunga penetrans) and ceratophyllus fasciatus (Nosopsyllus fasciatus)

Silverfish, tame silverfish (Thysanoptera (Thysanura)), for example silverfiss (Lepisma saccharina) and spot silverfish (Thermobia domestica),

Centipede (chilopoda (Chilopoda)), Scutigera coleoptrata for example,

Thousand-legger (Diplopoda (Diplopoda)), for example Narceus belongs to,

Qu octopus (Dermaptera (Dermaptera)), European earwig (forficula auricularia) for example,

Lice (hair Anoplura (Phthiraptera)), pediculus humanus capitis (Pediculus humanus capitis) for example, pediculus humanus corporis (Pediculus humanus corporis), crab louse (Pthirus pubis), haematopinus eurysternus (Haematopinus eurysternus), haematopinus suis (Haematopinus suis), Linognathus vituli (Linognathus vituli), Bovicola bovis, chicken lice (Menopon gallinae), Menacanthus stramineus and Solenopotes capillatus

Plant nematode such as root-knot nematode, peanut root-knot nematode (Meloidogyne arenaria), Qi Shi root-knot nematode (Meloidogyne chitwoodi), short and small root-knot nematode (Meloidogyne exigua), northern root-knot nematode (Meloidogyne hapla), Meloidogyne incognita (Meloidogyneincognita), javanese root knot nematode (Meloidogyne javanica) and other Meloidogynes (Meloidogyne); Cyst nematode, globodera rostochiensis (Globodera rostochiensis), potato white line worm (Globodera pallida), tobacco Cyst nematode (Globodera tabacum) and other ball Heteroderas (Globodera); Cereal Cyst nematode (Heterodera avenae), soybean Cyst nematode (Heterodera glycines), beet Cyst nematode (Heterodera schachtii), clover Cyst nematode (Heterodera trifolii) and other Heteroderas (Heterodera); Plant edema during pregnancy goitre nematode, bent grass grain nematode (Anguina funesta), wheat anguina (Anguina tritici) and other Turbatrixs (Anguina); The cauline leaf nematode, aphelenchoides besseyi (Aphelenchoides besseyi), strawberry aphelenchoides (Aphelenchoides fragariae), chrysanthemum aphelenchoides (Aphelenchoidesritzemabosi) and other Aphelenchoides (Aphelenchoides); The thorn nematode, weeds thorn nematode (Belonolaimus longicaudatus) and other acupuncture Turbatrixs (Belonolaimus); The loose ends worm, pine wood nematode (Bursaphelenchus xylophilus) and other umbrella Aphelenchoides (Bursaphelenchus); The annular nematode, ring grain Turbatrix (Criconema), little loop wire Eimeria (Criconemella), wheel Turbatrix (Criconemoides) and Middle Ring Line Eimeria (Mesocriconema); Bulb eelworm, rot stem eelworm (Ditylenchus destructor), sweet potato stem nematode (Ditylenchusdipsaci), mushroom stalk nematode (Ditylenchus myceliophagus) and other Ditylenchus (Ditylenchus); The awl nematode, awl Turbatrix (Dolichodorus); The spirality nematode, two palaces helicotylenchus (Helicotylenchus dihystera), be with spiral (Heliocotylenchus multicinctus) and other helix Eimerias, the strong nematode that spirals (Rotylenchus robustus) and other Turbatrixs that spirals (Rotylenchus) more; The sheath nematode, sheath Turbatrix (Hemicycliophora) and Hemicriconemoides belong to; Hirshmanniella belongs to; The hat nematode, Colombia tie nematode (Hoplolaimus columbus), cap shape tie nematode (Hoplolaimus galeatus) and other tie nematodes (Hoplolaimus) belong to; Pseudo-root-knot nematode, unusual pearl nematode (Nacobbus aberrans) and other pearl curve Eimerias (Nacobbus); The needlework worm stretches minute hand nematode (Longidorus elongatus) and other minute hand Turbatrixs (Longidorus); The needlework worm, needlework Eimeria (Paratylenchus); Pratylenchus, short-tail Pratylenchidae (Pratylenchus brachyurus), coffee Pratylenchidae (Pratylenchus coffeae), Pratylenchus curvitatus, ancient enlightening Pratylenchidae (Pratylenchus goodeyi), carelessness Pratylenchidae (Pratylenchus neglectus), Cobb root (Pratylenchus penetrans), Scribner Pratylenchidae (Pratylenchusscribneri), wounded or disabled Pratylenchidae (Pratylenchus vulnus), corn Pratylenchidae (Pratylenchus zeae) and other Pratylenchidaes belong to (Pratylenchus); Radinaphelenchuscocophilus and other Radinaphelenchus belong to; Similes thorne, radopholus similes thorne (Radopholus similis) and other perforation line Eimerias (Radopholus); Kidney shape nematode, kidney shape kidney nematode (Rotylenchulus reniformis) and other reniform nematodes belong to (Rotylenchulus); Shield Turbatrix (Scutellonema); The undesirable root nematode, original burr nematode (Trichodorus primitivus) and other burr Turbatrixs (Trichodorus); Belong to (Paratrichodorus) than group burr nematode (Paratrichodorus minor) and other class burrs; The long nematode of resistance, the Clayton downgrades nematode (Tylenchorhynchus claytoni), indefinite dwarfing nematode (Tylenchorhynchus dubius) and other dwarfing Turbatrixs (Tylenchorhynchus) and joint streakline Eimeria (Merlinius); Citrus nematode, citrus partly puncture nematode (Tylenchulus semipenetrans) and other pulvinulus sword Turbatrixs (Tylenchulus); Sword nematode, splits tail sword nematode (Xiphinema diversicaudatum) and other Xiphinemas (Xiphinema) at America sword nematode (Xiphinema americanum), standard sword nematode (Xiphinema index); And other plant parasitic nematode.

In addition, mixture of the present invention is particularly useful for preventing and treating Lepidoptera, coleoptera, diptera, thrips and Hymenoptera.

In addition, mixture of the present invention is particularly useful for preventing and treating non-crop pests (family, turf, ornamental plants).

Mixture of the present invention can be applied to any of insect and all developmental stage, for example worm's ovum, larva, pupa and adult.Can contact and pest control by mixture of the present invention that makes target pest, its provand source, habitat, breeding spot or its place and insecticidal effective dose or the composition that comprises described mixture.

" place " is meant wherein insect growth or meeting growing plants, seed, soil, zone, material or environment.

Insecticidal effective dose " be often referred to growth is obtained the needed mixture of the present invention of observable effect or comprises the amount of the composition of described mixture; described effect comprises necrosis, death, retardance, prevention and removal effect, execution or reduce the appearance and the movable effect of target organism.For the various mixtures of using in the present invention, insecticidal effective dose can change.The insecticidal effective dose of mixtures also can change according to essential condition such as required insecticidal effect and duration, weather, target species, place, method of application etc.

The composition of mixture of the present invention or these mixtures can also be used for protective plant and avoid insect, acarid or nematosis or infect, and comprises with the soil or the water body of plant or plant growing contacting.

For the purpose of the present invention, the term plant is meant the propagating materials of whole plants, plant part or plant, i.e. seed or rice shoot.

The plant of available mixture process of the present invention comprises all genetically modified plants or genetically modified plants, the crop of herbicide-tolerant or fungicide or insecticide effect for example owing to comprise the breeding of gene engineering method, or compare with the plant that exists and to have by traditional breeding way and/or produce mutant or the plant of the decorative features that produces by the reorganization program.

Therefore some mixtures of the present invention have systemic action and can be used for protective plant branch opposing blade face insect and processing is used for seed and root with the opposing soil pests.The term seed treatment comprises all suitable seed processing technologies known in the art, and for example seed dressing, seed pelleting, seed dusting, seed soak and pellet seeds.

Compound I and Compound I I and III separately can be simultaneously, i.e. associating or separate administration or use successively, under the situation of separate administration order of administration usually to the result of prophylactico-therapeutic measures without any influence.

Mixture of the present invention also is applicable to the root and the branch of protection seed and rice shoot, and preferred seed is with the antagonism soil pests.

The composition that is particularly useful for seed treatment for example is:

The A solubility concentrates thing (SL, LS)

D emulsion (EW, EO, ES)

E suspension (SC, OD, FS)

F water-dispersible granule and water-soluble granular (WG, SG)

G water dispersible pow-ders and water-soluble powder (WP, SP, WS)

H gel formulation (GF)

But I dusting powder (DP, DS)

Conventional seed treatment preparaton for example comprises the concentrate FS that can flow, solution LS, is used for the dry powder DS that handles, is used for water dispersible pow-ders WS, water-soluble powder SS and emulsion ES and EC and gel formulation GF that slurry is handled.These preparatons can dilute or be applied to seed without dilution.Being applied in of seed directly carried out seed before the sowing or carried out after making that seed is pre-and sprouting.Preferred FS preparaton.

In seed treatment, depend on the kind of required effect and seed, the rate of application of mixture of the present invention is generally every 100kg seed 0.001 to 10kg.Rate of application is preferably the 1-1000g/100kg seed, more preferably 1-750g/100kg, especially 5-500g/100kg seed.The mixture of Compound I and II or Compound I and II separately or co-administered by before or after the plant seeding or plant seed, rice shoot, plant or soil spraying or dusting are carried out before or after emerging.

The invention still further relates to the breeding product of plant, particularly comprise, promptly apply and/or contain the seed of following material: mixture as defined above, or contain the composition of the mixture of two or more active components, or two or more provide the mixture of the composition of one of active component separately.Seed comprises mixture of the present invention with the amount of every 100kg seed 0.1g to 10kg.

Mixture of the present invention is by contacting (via soil, glass, wall, bed net, carpet, plant part or animal part) and feed (bait or plant part) and working by trophallaxis and transfer.

Preferred application process is used via soil, crack and crack, pasture, dung heep, sewer for applying water body, applies in the water, be applied on floor, the wall, or by spray application and bait are used on every side.

According to another preferred embodiment of the present invention, in order to be used to resist non-crop pests such as ant, termite, wasp, fly, mosquito, cricket, locust or cockroach, mixture of the present invention is prepared into the bait preparation.

Bait can be liquid, solid or semisolid preparation (for example gel).The bait that is used for composition is to have enough attractions to stimulate such as edible its product of the insects of ant, termite, wasp, fly, mosquito, cricket etc. or cockroach.This attractant can be selected from feed stimulant or puppet and/or sex pheromone.What this area was easy to know is that Compound I and Compound I I are with 500: 1-1: 500, preferred 500: 1-1: 100, more preferably 100: 1-1: 100, especially 20: 1-1: 20, most preferably 10: 1-1: 10 weight ratio is used.

Also comprise by the method for insect-borne infectious disease (for example malaria, dengue fever and yellow fever, lymph filariosis and leishmaniasis (leishmaniasis)) with mixture of the present invention and composition for preventing and controlling separately thereof and to handle surface, house, air-atomizing and dipping curtain, tent, clothing, bed net, tsetse fly catcher or analog.The Pesticidal combination that is applied to fiber, fabric, knit goods, non-woven fabric, Web materials or paillon foil and waterproof cloth preferably comprises the composition that comprises mixture of the present invention, optional expellent and at least a adhesive.

Mixture of the present invention and the composition that comprises them can be used for protecting wood materials such as trees, guardrail, sleeper etc.; and building such as house, annex, factory; also have construction material, furniture, leather, fiber, polrvinyl chloride product, electric wire and cable etc. in case ant and/or termite, and prevent ant and termite infringement crop or mankind's (for example when insect intrusion house and communal facility).

In soil treatment or be applied under the situation of insect habitat or nest, the amount of application of active component is 0.0001-500g/100m ², preferred 0.001-20g/100m ²

Common rate of application in the material protection for example is every square metre and handles material 0.01-1000g reactive compound, it is desirable to every square metre of 0.1-50g reactive compound.

The Pesticidal combination that is used for material soaking contains 0.001-95 weight % usually, preferred 0.1-45 weight %, more preferably at least a expellent of 1-25 weight % and/or insecticide.

The typical content that is used for the active component of bait composition is 0.0001-15 weight %, it is desirable to 0.001-5 weight % reactive compound.Composition therefor can also comprise solvent, flavor enhancement, preservative, dyestuff or the bitters of other additive such as active material.Its attraction can also strengthen by special color, shape or structure.

The mixture of active principles content that is used for spray composite is 0.001-80 weight %, preferred 0.01-50 weight %, most preferably 0.01-15 weight %.

The rate of application that is used to handle the mixture of active principles of crop can be per hectare 0.1-4000g, it is desirable to per hectare 25-600g, and that better is per hectare 50-500g.

Purpose of the present invention also is applicable to processing, control, prevention and protection for providing, and comprises people's warm blooded animal and the mixture that fish antagonism insect attacks and infects.On the animal and/or the person or the question marks that may run in the control of insect in the body be similar to beginning described those, promptly need depressant dose rate and/or improved activity profile and/or combine to knock down active and long-term control and/or drug resistance management.

The method that the present invention also provides warm blooded animal that a kind of processing, control, prevention and protection comprise the people and fish antagonism Siphonaptera, Hymenoptera, Semiptera, orthoptera, Acarina, hair Anoplura and the invasion and attack of dipterous insect and infected, it comprises the mixture of the present invention of insecticidal effective dose is oral, part or parenteral or is applied to described animal.

The present invention also provides a kind of preparation to be used to the method for compositions of handling, prevent and treat, prevent or protect warm blooded animal or fish antagonism Siphonaptera, Hymenoptera, Semiptera, orthoptera, Acarina, hair Anoplura and Diptera pest to attack and infect, and said composition comprises the mixture of the present invention of insecticidal effective dose.

Said method is particularly useful for preventing and treating and prevents the invasion and attack in warm blooded animal such as ox, sheep, pig, camel, deer, horse, poultry, goat, dog and cat and people and infect.

Invasion and attack in warm blooded animal and fish include but not limited to lice, bite lice, tick, nose fly, ked (keds), bite fly, housefly (muscoid flies), fly, fly maggot larva, trombiculid, buffalo gnat, mosquito and flea, and it can or be eliminated by mixture control of the present invention, prevention.

For the oral administration of warm blooded animal, mixture of the present invention can be mixed with animal feed, animal feed premix thing, animal feed concentrate, pill, solution, paste, suspension, immersion liquid, gel, tablet, bolus and capsule.In addition, mixture of the present invention can deliver medicine to animal in its drinking water.For oral administration, selected formulation should provide the mixture in 0.01-100mg/kg the weight of animals/sky to animal.

Perhaps, mixture of the present invention can parenteral in animal, for example by (intraruminal), intramuscular, intravenous or hypodermic injection in the chamber.Mixture of the present invention can disperse or be dissolved in for hypodermic injection in the physiologically acceptable carrier.Perhaps, mixture of the present invention can be mixed with the subcutaneous administration implant.In addition, mixture of the present invention can deliver medicine to animal by transdermal (transdermally).For parenteral, selected formulation should provide the mixture in 0.01-100mg/kg the weight of animals/sky to animal.

Mixture of the present invention can also embathe liquid, pulvis, powder, necklace, list (medallions), spray, dips in point (spot-on) and spray the preparaton form and be locally applied to animal.For local application, embathe liquid and spray and contain 0.5-5 usually, 000ppm, preferred 1-3,000ppm The compounds of this invention.In addition, mixture of the present invention can be mixed with animal, and especially quadruped such as ox and sheep are pasted with ear.

Biological Examples:

1) fungicidal action

The fungicidal effect of compound and mixture can confirm by following test:

With reactive compound separately or unite and make the stock solution in acetone or DMSO that comprises 0.25 weight % reactive compound.With 1 weight % emulsifier

EL (wetting agent based on ethoxylated alkylphenol with emulsification and peptizaiton) adds this solution, and water with mixture diluted to desired concn.

The leaf area percentage that infects that naked eyes are measured changes into the effectiveness that the % with untreated control represents.

Use the Abbot formula to render a service (E) by following calculating:

E＝(1-α/β)·100

α corresponding to the fungal infection percentage of handling plant and

β is corresponding to the fungal infection percentage of (contrast) plant of being untreated.

Effectiveness is that 0 infecting of plant of expression processing is on close level in untreated check plant; Effectiveness is that 100 expression processing plants are infected.

The expection effectiveness use Colby formula of the mixture of reactive compound [Colby S.R., " calculating the Synergistic and the antagonism response of combinations of herbicides ", Weeds (weeds), 15, 20-22 page or leaf, 1967)] determine and with the effectiveness of observing relatively.

Colby formula: E=x+y-xy/100

Expection when the E working concentration is the mixture of the reactive compound A of a and b and B is renderd a service, represents with % with respect to untreated control,

Effectiveness when the x working concentration is the reactive compound A of a is represented with the % with respect to untreated control,

Effectiveness when the y working concentration is the reactive compound B of b is represented with the % with respect to untreated control.

Application Example 1-is to the antifungal control (protectiveness) of the brown spot that caused by palace portion cochliobolus

Use activity component concentration aqueous suspension as described below to be sprayed to the drip point in the blade of potted plant rice sprouts by the stock solution preparation.Make plant air-dry.Second day with the moisture spore suspension inoculation of plant with palace portion cochliobolus.Then test plant is transferred in the moist chamber immediately.22-24 ℃ and near 100% relative moisture under after 6 days, with the degree of fungal attack on the leaf area % visual assessment blade of falling ill.

Result of the test shows, because potent synergistic function, the activity of mixture of the present invention is significantly higher than the activity of using the prediction of Colby formula.

2) effect of combating animal pests

Below test shows the preventing efficiency of the mixture of The compounds of this invention and Compound I I and III to specific insect.Yet the control of insect protective effect that is provided by described compound, mixture or composition is not limited to these species.Effectiveness that can corresponding mensuration ternary mixture of the present invention.In some cases, find that The compounds of this invention and other invertebrate pest control compound or combination of agents demonstrate the cooperative synergism effect of some important invertebrate pests of antagonism.

Use Colby equation is determined synergistic function or the antagonism analysis between mixture or the composition.

Application Example 2

In order to assess the control of the nest Lay being repaiied tail aphid (Megoura viciae) by contact or interior suction measure, test unit is made up of the 24 hole titer plate that contain the broad bean blade.

Use contains solution preparation compound or the mixture of 75% water and 25%DMSO.Use little atomizer customized that the compound or the mixture of the preparation of variable concentrations are sprayed on the blade with 2.5 μ l, repeat twice.

Experimental mixture in these tests is mixing two kinds of mix and match things of equal volume separately under the desired concn.

After using, that blade is air-dry and 5-8 aphid adult placed on the blade in the microtitre plate hole.Aphid is sucked and at 23 ± 1 ℃ on treated blade, 50 ± 5%RH hatching 5 days down.Follow lethality and the fertility of visual assessment aphid.

In this test, use Compound I-2, and N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide (compound 2.1) and 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazol [1,5-a] pyrimidine (compound 2.2).

The results are as follows:

The nest Lay is repaiied the tail aphid	ppm	Average control %
			I-2	0.5	0
I-2	2.5	0
			2.1	1000	0
2.2	40	0
			I-2+2.1	0.5+1000	100 ＊
I-2+2.2	2.5+40	75 ＊

^*Synergistic control efficiency according to the Colby equation

Application Example 3

Resemble the control of (Boll Weevil/Anthonomus grandis) in order to assess Mexico's cotton boll, test unit is made up of the 24 hole titer plate that contain insect food and 20-30 Mexico's boll weevil ovum.

Use contains solution preparation compound or the mixture of 75% water and 25%DMSO.Use little atomizer customized that the compound or the mixture of the preparation of variable concentrations are sprayed on the insect food with 20 μ l, repeat twice.

Experimental mixture in these tests is mixing two kinds of mix and match things of equal volume separately under the desired concn.

After using, at 23 ± 1 ℃, 50 ± 5%RH was hatched 5 days down with titer plate.Follow the lethality of visual assessment worm's ovum and larva.

In this test, use Compound I-2, Prochloraz, pyraclostrobin, N-[2-(1 respectively, 1,2,3,3,3-hexafluoro propoxyl group)-phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide (compound 3.1) and N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide (compound 3.2).

The results are as follows:

Mexico's cotton boll resembles	ppm	Average control %
			I-2	0.5	0
Prochloraz	40	0
			Pyraclostrobin	40	0
3.1	40	0
			3.2	200	0
The I-2+ Prochloraz	0.5+40	75 ＊
			The I-2+ pyraclostrobin	0.5+40	75 ＊
I-2+3.1	0.5+40	100 ＊
			I-2+3.2	0.5+200	100 ＊

^*Synergistic control efficiency according to the Colby equation

Application Example 4

In order to assess the control of Mediterranean fruitfly (Ceratitis capitata), test unit is made up of the 96 hole titer plate that contain insect food and 50-80 Mediterranean fruitfly worm's ovum.

Use contains solution preparation compound or the mixture of 75% water and 25%DMSO.Use little atomizer customized that the compound or the mixture of the preparation of variable concentrations are sprayed on the insect food with 5 μ l, repeat twice.

Experimental mixture in these tests is mixing two kinds of mix and match things of equal volume separately under the desired concn.

After using, at 28 ± 1 ℃, 80 ± 5%RH was hatched 5 days down with titer plate.Follow the lethality of visual assessment worm's ovum and larva.

Application Example 5

In order to assess the control of tobacco budworm (Heliothis virescens), test unit is made up of the 96 hole titer plate that contain insect food and 15-25 tobacco budworm worm's ovum.

Use contains solution preparation compound or the mixture of 75% water and 25%DMSO.Use little atomizer customized that the compound or the mixture of the preparation of variable concentrations are sprayed on the insect food with 10 μ l, repeat twice.

Experimental mixture in these tests is mixing two kinds of mix and match things of equal volume separately under the desired concn.

After using, at 28 ± 1 ℃, 80 ± 5%RH was hatched 5 days down with titer plate.Follow the lethality of visual assessment worm's ovum and larva.

In this test, use Compound I-2, Prochloraz and pyraclostrobin respectively.

The results are as follows:

Tobacco budworm	ppm	Average control %
			I-2	0.5	0
I-2	2.5	37.5
			Prochloraz	8	0
Pyraclostrobin	200	0
			The I-2+ Prochloraz	2.5+8	87.5 ＊
The I-2+ pyraclostrobin	0.5+200	50 ＊

^*Synergistic control efficiency according to the Colby equation

Application Example 6

In order to assess by the control of interior suction measure to black peach aphid (Myzus persicae), test unit is made up of the 96 hole titer plate that contain the liquid artificial food under artificial membrane.

Use contains solution preparation compound or the mixture of 75% water and 25%DMSO.Use pipette customized that the compound or the mixture of the preparation of variable concentrations are moved in the aphid food, repeat twice.

Experimental mixture in these tests is mixing two kinds of mix and match things of equal volume separately under the desired concn.

After using, 5-8 aphid adult placed on the artificial membrane in the microtitre plate hole.Aphid is sucked and at 23 ± 1 ℃ on treated aphid food, 50 ± 5%RH hatching 3 days down.Follow lethality and the fertility of visual assessment aphid.For the mixture of being tested, the results are shown in Table 2.

In this test, use Compound I-2, orysastrobin, 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl)-[1,2,4] triazol [1,5-a] pyrimidine (compound 2.2) and N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group)-phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide (compound 3.1).

The results are as follows:

Black peach aphid	ppm	Average control %
			I-2	0.5	0
Orysastrobin	40	0
			Pyraclostrobin	8	0
2.2	8	0

Black peach aphid	ppm	Average control %
			3.1	1000	0
The I-2+ orysastrobin	0.5+40	50 ＊
			The I-2+ pyraclostrobin	0.5+8	75 ＊
I-2+2.2	0.5+8	75 ＊
			I-2+3.1	0.5+1000	100 ＊

^*Synergistic control efficiency according to the Colby equation

Claims (28)

1. one kind comprises the ternary pesticide combination of following material as active component with the Synergistic effective dose:

1) the anthranilamide sulfonamides of formula I:

Wherein substituting group is following defines:

B ¹Be hydrogen, cyano group or chlorine;

B ²Be bromine or CF ₃With

R is hydrogen or C ₁-C ₆Alkyl;

With

2) a kind of Fungicidal compounds II that is selected from following group:

A) azole, for example Bitertanol, bromuconazole, cyproconazole, Difenoconazole, alkene azoles alcohol, IMAZALIL, oxole bacterium, Fluquinconazole, RH-7592, Flusilazole, Flutriafol, own azoles alcohol, acid amides azoles, cycltebuconazole, ring penta azoles bacterium, nitrile bacterium azoles, penconazole, propiconazole, prothioconazoles, simeconazoles, triazolone, triadimenol, Tebuconazole, fluorine ether azoles, triticonazole;

Prochloraz, pefurazoate, IMAZALIL, fluorine bacterium azoles, cyanogen frost azoles;

Benomyl, carbendazim, thiabendazole, furidazol;

Guardian, kobam, hydroxyisoxazole;

B) strobilurins, for example nitrile Fluoxastrobin, ether bacterium amine, Enestroburin, fluoxastrobin, imines bacterium, fork phenalgin acid amides, orysastrobin, ZEN 90160, pyraclostrobin, oxime bacterium ester;

C) carboxylic acid amides, for example carboxin, M 9834, Boscalid, fenhexamid, flutolanil, third oxygen go out and embroider amine, metalaxyl, Metalaxyl-M, the spirit of fenfuram, Evil frost, oxycarboxin, pyrrole metsulfovax, thifluzamide, dimethomorph, flumorph;

Fluorine pyrrole bacterium amine, zoxamide;

Two chlorine zarilamids, mandipropamid amine;

D) heterocyclic compound, for example fluazinam, pyrifenox;

The phonetic bacterium spirit of sulphur, ring third pyrimidine, fenarimol, ferimzone, mepanipyrim, nuarimol, pyrimethanil;

Triforine, azoles bacterium piperazine;

Fenpiclonil, Fu Evil bacterium;

Dodemorfe, butadiene morpholine, tridemorph;

Fenpropidin, different third fixed, sharp, the vinclozolin of sterilization;

Azolactone bacterium, Fenamidone, probenazole;

Indazole flusulfamide, anilazine, diclomezine, pyroquilon, the third oxygen quinoline, tricyclazole;

Thiadiazoles element, difoltan, captan, folpet, zarilamid, quinoxyfen;

E) Carbamates, for example mancozeb, maneb, metham-sodium, Carbatene, ferbam, propineb, tmtd, zineb, ziram;

The mould prestige of second, iprovalicarb, benzene metsulfovax, hundred dimension spirits;

With

F) be selected from other following reactive compound:

Guanidine class: dodine, biguanide spicy acid salt, guazatine;

Antibiotic class: spring thunder element, Polyoxin, jinggangmeisu;

Nitrophenyl derivative: karathane,

Sulfur heterocyclic ring based compound: Delan, Isoprothiolane;

Organo-metallic compound: triphenyltin salt

Organic phosphorus compound: Hinosan, iprobenfos, ethyl phosphine aluminium, Ppyrazophos, tolelofos-methyl;

Organochlorine compound: tpn, Euparen, flusulfamide, hexachloro-benzene, Rabcide, Pencycuron, pcnb, tolyfluanid;

Inorganic active compound: bordeaux mixture, Kocide SD, Cupravit, basic copper sulfate, sulphur;

Other: cyflufenamid, cymoxanil, Milcurb, Milstem, Furalaxyl, metrafenone He the luxuriant amine of Luo Evil;

With

3) a kind ofly be selected from above-mentioned A)-F) and G)-J) the Fungicidal compounds III of group:

G) be selected from following strobilurins: (2-chloro-5-[1-(3-methyl benzyloxy imino) ethyl] benzyl) methyl carbamate, (2-chloro-5-[1-(6-picoline-2-base methoxyimino) ethyl] benzyl) methyl carbamate and 2-(neighbour-(2,5-dimethyl phenoxy methylene) phenyl)-3-methoxy-methyl acrylate;

H) be selected from following carboxylic acid amides: the spirit of furan pyrazoles, tiadinil, N-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide; 3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide; N-(2 ', 4 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-3-two-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-3-two-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; 5-fluoro-1, the 3-dimethyl-[2-(1 for 1H-pyrazoles-4-formic acid, 2-dimethyl-propyl group)-phenyl]-acid amides, fluorine biphenyl bacterium, carpropamide, and N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-3-methoxyphenyl) ethyl)-2-methanesulfonamido-3-methylbutyryl amine, N-(2-(4-[3-(4-chlorphenyl) Propargyl oxygen base]-the 3-methoxyphenyl) ethyl)-2-second sulfonamido-3-methylbutyryl amine;

I) be selected from following heterocyclic compound:

4-dodecyl-2, the 6-thebaine, different thiophene bacterium ketone, the indazole flusulfamide, diclomezine, 5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, 6-(3, the 4-dichlorophenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and 5-trifluoromethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 2-butoxy-6-iodo-3-propyl group chromene-4-ketone; Dazomet, 3-[5-(4-chlorphenyl)-2,3-dimethyl isoxazole alkane-3-yl] pyridine;

With

J) be selected from other following reactive compound: metham-sodium, 3-(4-chlorphenyl)-3-(different third oxygen carbonylamino of 2--3-methylbutyryl amino) methyl propionate; Streptomycin, binapacryl, dinobuton;

Fentinacetate, fosetyl, phosphorous acid and salt thereof, hexachloro-benzene, thiophanate methyl, and Schweinfurt green.

2. according to the pesticide combination of claim 1, it is with 100: 1-1: 100 weight ratio comprises formula I compound and Compound I I.

3. according to the pesticide combination of claim 1 or 2, its comprise formula I compound 3-bromo-4 '-cyano group-1-(3-chloro-2-pyridine radicals)-2 '-methyl-6 '-(methylamino formoxyl) pyrazoles-5-formailide is as component 1.

4. according to the pesticide combination of claim 1 or 2, its inclusion compound 3-bromo-4 '-chloro-1-(3-chloro-2-pyridine radicals)-2 '-methyl-6 '-(methylamino formoxyl) pyrazoles-5-formailide is as component 1.

5. according to each pesticide combination among the claim 1-4, it comprises the reactive compound II that is selected from according to the strobilurins of claim 1 as component 2.

6. according to each pesticide combination among the claim 1-5, its comprise be selected from nitrile Fluoxastrobin, ether bacterium amine, Enestroburin, fork phenalgin acid amides and orysastrobin reactive compound II as component 2.

7. according to each pesticide combination among the claim 1-6, it comprises orysastrobin as component 2.

8. according to each pesticide combination among the claim 1-4, it comprises fluorine bacterium azoles as component 2.

9. according to each pesticide combination among the claim 1-4, its comprise be selected from carpropamide, two chlorine zarilamid, the spirit of furan pyrazoles, thifluzamide and tiadinil reactive compound II as component 2.

10. according to each pesticide combination among the claim 1-4, its comprise be selected from probenazole, pyroquilon and tricyclazole reactive compound II as component 2.

11. according to each pesticide combination among the claim 1-10, it comprises the A that is selected from according to claim 1)-F) reactive compound of group is as component 3.

12. according to each pesticide combination among the claim 1-10, it comprises the G that is selected from according to claim 1)-J) the reactive compound III of group is as component 3.

13. according to each pesticide combination in claim 1-10 and 12, its comprise be selected from H) the reactive compound III of group is as component 3.

14. according to claim 1-10, each pesticide combination in 12 and 13, it comprises and is selected from following reactive compound III as component 3:N-(4 '-bromo biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-trifluoromethyl-biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(4 '-chloro-3 '-fluorine biphenyl-2-yl)-4-difluoromethyl-2-methylthiazol-5-formamide, N-(3 ', 4 '-two chloro-4-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide, N-(3 ', 4 '-two chloro-5-fluorine biphenyl-2-yls)-3-difluoromethyl-1-methylpyrazole-4-formamide; 3,4-two chloro-N-(2-cyano-phenyl) isothiazole-5-formamide; N-(2 ', 4 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 4 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 4 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 ', 5 '-DCBP-2-yl)-3-two-methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DfBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 ', 5 '-DfBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 ', 5 '-DCBP-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide, N-(3 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-(3 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(2 '-fluorine biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-chlordiphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(2 '-fluoro-4 '-chloro-5 '-methyl biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(2 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-1-methyl-3-difluoromethyl-1H-pyrazole-4-carboxamide; N-(3 ', 4 ', 5 '-trifluoro-biphenyl-2-yl)-3-chlorine methyl fluoride-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(1,1,2,3,3,3-hexafluoro propoxyl group) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide, N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-[2-(2-chloro-1,1,2-trifluoro ethoxy) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; 4-formic acid-N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-[2-(1,1,2,2-tetrafluoro ethyoxyl) phenyl]-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide; N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-3-difluoromethyl-1-methyl isophthalic acid H-pyrazole-4-carboxamide; N-(4 '-(trifluoromethylthio) biphenyl-2-yl)-1-methyl-3-Trifluoromethyl-1 H-pyrazole-4-carboxamide.

15. according to each pesticide combination in claim 1-10 and 12, it comprises and is selected from following reactive compound III as component 3:5-chloro-7-(4-methyl piperidine-1-yl)-6-(2,4, the 6-trifluorophenyl) [1,2,4] triazol [1,5-a] pyrimidine, 6-(3, the 4-dichlorophenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and 5-trifluoromethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine.

16. according to claim 1-10, each pesticide combination in 12 and 15, it comprises and is selected from following reactive compound III as component 3:6-(3, the 4-dichlorophenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-(4-tert-butyl-phenyl)-5-methyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-methyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-ethyl-5-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-ethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-propyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 5-methoxy-6-octyl group-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine, 6-octyl group-5-trifluoromethyl-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine and 5-trifluoromethyl-6-(3,5,5-trimethyl hexyl)-[1,2,4] triazol [1,5-a] pyrimidin-7-yl amine.

17. a composition pesticide, it comprises the liquid or solid carrier and according to each mixture among the claim 1-16.

18. a method of preventing and treating the plant-pathogenic harmful fungoid is wherein handled fungi with the Compound I according to claim 1 of effective dose, a kind of Compound I I and a kind of compound III, its habitat maybe need prevent plant, soil or the seed of fungal attack.

19. a method of preventing and treating insect, spider or nematode, it comprises makes contacting as each defined mixture among the claim 1-11 of insect, acarid or nematode or its provand source, habitat, breeding spot or its place and insecticidal effective dose.

20. the method that protective plant is avoided insect, acarid or nematosis or infected, it comprises makes plant, or the contacting as each defined mixture among the claim 1-11 of the plant soil of growing therein or water body and insecticidal effective dose.

21., wherein use as each desired mixture among the claim 1-11 with the amount of 5-2000g/ha according to the method for claim 19 or 20.

22. a method of protecting seed, it comprises makes contacting as each defined mixture among the claim 1-11 of seed and insecticidal effective dose.

23., wherein use as each desired mixture among the claim 1-11 with the amount of every 100kg seed 0.001g to 10kg according to the method for claim 22.

24. seed, its amount with every 100kg seed 0.1g to 10kg comprises as each desired mixture among the claim 1-11.

25. according to each method among the claim 18-23, wherein will be simultaneously as each defined formula I compound and Compound I I among the claim 1-11, i.e. associating or separately, or use successively.

26. the method that a processing, control, prevention or protection warm blooded animal or fish avoid parasitic infestation or infect, it comprises, part or the parenteral oral as each defined mixture among the claim 1-11 of antiparasitic effective dose or animal or fish as described in being applied to.

27. one kind prepares the method for compositions that is used to handle, prevent and treat, prevent or protect warm blooded animal or fish to avoid insect or acarid invasion and attack or infect, described composition comprise the antiparasitic effective dose as each defined mixture among the claim 1-11.

28. as the purposes of each defined mixture among the claim 1-11 in antagonism insect, spider or nematode.