CN101516195A - Pesticidal mixtures comprising an anthranilamide insecticide and a fungicide - Google Patents

Pesticidal mixtures comprising an anthranilamide insecticide and a fungicide Download PDF

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CN101516195A
CN101516195A CN 200780034041 CN200780034041A CN101516195A CN 101516195 A CN101516195 A CN 101516195A CN 200780034041 CN200780034041 CN 200780034041 CN 200780034041 A CN200780034041 A CN 200780034041A CN 101516195 A CN101516195 A CN 101516195A
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methyl
yl
carboxamide
1h
pyrazole
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CN 200780034041
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J·兰杰瓦德
R·施蒂尔
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巴斯夫欧洲公司
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Publication of CN101516195A publication Critical patent/CN101516195A/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
    • Y02A50/38Medical treatment of vector-borne diseases characterised by the agent
    • Y02A50/381Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a virus
    • Y02A50/384Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a virus of the genus Flavivirus
    • Y02A50/385Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a virus of the genus Flavivirus the disease being Dengue
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
    • Y02A50/38Medical treatment of vector-borne diseases characterised by the agent
    • Y02A50/381Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a virus
    • Y02A50/384Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a virus of the genus Flavivirus
    • Y02A50/387Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a virus of the genus Flavivirus the disease being Yellow fever, i.e. Ochropyra
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
    • Y02A50/38Medical treatment of vector-borne diseases characterised by the agent
    • Y02A50/408Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a protozoa
    • Y02A50/409Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a protozoa of the genus Leishmania i.e. Leishmaniasis, Sand-fly fever, phlebotomus fever, kala-azar, black fever or Dumdum fever
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
    • Y02A50/38Medical treatment of vector-borne diseases characterised by the agent
    • Y02A50/408Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a protozoa
    • Y02A50/411Medical treatment of vector-borne diseases characterised by the agent the vector-borne disease being caused by a protozoa of the genus Plasmodium, i.e. Malaria

Abstract

Pesticidal mixtures comprising, as active components, 1 ) an anthranilamid compound of the formula I wherein the variables are defined according to the description, and 2) at least one fungicidal compound Il selected from the following groups: strobilurins, carboxamides, heterocylic compounds and other active compounds according to the description, in a synergistically effective amount, methods for controlling pests, and harmful fungi, methods of protecting plants from attack or infestation by insects, acarids or nematodes, methods for treating, controlling, preventing or protecting an animal against infestation or infection by parasites, compositions containing these mixtures, and methods for their preparation.

Description

包含邻氨基苯甲酰胺杀虫剂和杀真菌剂的农药混合物 Anthranilamide comprising a mixture of pesticides and insecticides fungicides

本发明涉及以协同增效有效量包含如下物质作为活性组分的三元农药混合物: The present invention relates to three yuan pesticides synergistically effective amount of a mixture comprising the substance as an active ingredient:

1)式I的邻氨基苯甲酰胺(anthranilamide)化合物: 1) of formula I of anthranilamide (anthranilamide) compound:

其中取代基如下所定义: Wherein the substituents are defined as follows:

B 1为氢、氰基或氯; B 1 is hydrogen, cyano or chloro;

B 2为溴或CF 3 ;和 B 2 is a bromine or CF 3; and

R为氢或C 1 -C 6烷基; R is hydrogen or C 1 -C 6 alkyl;

with

2)一种选自下列组的杀真菌化合物II: 2) A fungicidal compound II is selected from the group of:

A)唑类,尤其是:双苯三唑醇(bitertanol)、糠菌唑(bromuconazole)、环唑醇(cyproconazole)、噁醚唑(difenoconazole)、烯唑醇(diniconazole)、烯菌灵(enilconazole)(imazalil)、氧唑菌(epoxiconazole)、喹唑菌酮(fluquinconazole)、腈苯唑(fenbuconazole)、氟硅唑(flusilazole)、粉唑醇(flutriafol)、己唑醇(hexaconazole)、酰胺唑(imibenconazole)、环戊唑醇(ipconazole)、环戊唑菌(metconazole)、腈菌唑(myclobutanil)、戊菌唑(penconazole)、丙环唑(propiconazole)、丙硫菌唑(prothioconazole)、硅氟唑(simeconazole)、三唑酮(triadimefon)、唑菌醇(triadimenol)、戊唑醇(tebuconazole)、氟醚唑(tetraconazole)、戊叉唑菌(triticonazole); A) azoles, especially: bitertanol (bitertanol), bromuconazole (bromuconazole), cyproconazole (cyproconazole), difenoconazole (Difenoconazole), diniconazole (diniconazole), alkenyl bacteria Ling (enilconazole ) (imazalil), epoxiconazole (epoxiconazole), fluquinconazole (fluquinconazole), fenbuconazole (fenbuconazole), flusilazole (flusilazole), flutriafol (flutriafol), hexaconazole (hexaconazole), oxazole amide (imibenconazole), ipconazole (ipconazole), metconazole (metconazole), myclobutanil (myclobutanil), penconazole (penconazole), propiconazole (propiconazole), prothioconazole (prothioconazole), silicon fluorine-yl (simeconazole), triadimefon (triadimefon), triadimenol (triadimenol), tebuconazole (tebuconazole), fluoro difenoconazole (tetraconazole), triticonazole (triticonazole);

丙氯灵(prochloraz)、稻瘟酯(pefurazoate)、烯菌灵(imazalil)、氟菌唑(triflumizole)、氰霜唑(cyazofamid); Prochloraz (prochloraz), pefurazoate (pefurazoate), alkenyl benomyl (imazalil), triflumizole (triflumizole), Cyazofamid (cyazofamid);

苯菌灵(benomyl)、多菌灵(carbendazim)、涕必灵(thiabendazole)、麦穗宁(fuberidazole); Benomyl (benomyl), carbendazim (carbendazim), thiabendazole (thiabendazole), fuberidazole (fuberidazole);

噻唑菌胺(ethaboxam)、氯唑灵(etridiazole)、土菌消(hymexazole); Ethaboxam (ethaboxam), cloxacillin spirit (etridiazole), hymexazol (hymexazole);

B)嗜球果伞素(strobilurins),尤其是:腈嘧菌酯(azoxystrobin)、醚菌胺(dimoxystrobin)、烯肟菌酯(enestroburin)、氟嘧菌酯(fluoxastrobin)、亚胺菌(kresoxim-methyl)、叉氨苯酰胺(metominostrobin)、肟醚菌胺(orysastrobin)、啶氧菌酯(picoxystrobin)、唑菌胺酯(pyraclostrobin)、肟菌酯(trifloxystrobin); B) strobilurins (strobilurins), in particular: azoxystrobin (azoxystrobin), dimoxystrobin (dimoxystrobin), enestroburin (enestroburin), fluoxastrobin (fluoxastrobin), kresoxim (kresoxim -methyl), metominostrobin (metominostrobin), orysastrobin (orysastrobin), picoxystrobin (picoxystrobin), pyraclostrobin (pyraclostrobin), trifloxystrobin (trifloxystrobin);

C)羧酰胺,尤其是:萎锈灵(carboxin)、苯霜灵(benalaxyl)、啶酰菌胺(boscalid)、环酰菌胺(fenhexamid)、氟酰胺(flutolanil)、丙氧灭绣胺(mepronil)、甲霜灵(metalaxyl)、精甲霜灵(mefenoxam)、甲呋酰胺(ofurace)、噁霜灵(oxadixyl)、氧化萎锈灵(oxycarboxin)、吡噻菌胺(penthiopyrad)、溴氟唑菌(thifluzamide)、5-氟-1,3-二甲基-1H-吡唑-4-甲酸[2-(1,2-二甲基-丙基)-苯基]-酰胺、烯酰吗啉(dimethomorph)、氟吗啉(flumorph); C) carboxamides, in particular: carboxin (carboxin), benalaxyl (benalaxyl), boscalid (of boscalid), fenhexamid (fenhexamid), flutolanil (flutolanil), propoxyphene off embroidery amine ( mepronil), metalaxyl (metalaxyl), metalaxyl-M (mefenoxam), ofurace (ofurace), oxadixyl (oxadixyl), oxycarboxin (oxycarboxin), penthiopyrad (penthiopyrad), bromo-fluoro pyraclostrobin (thifluzamide), 5- fluoro-1,3-dimethyl--1H- pyrazole-4-carboxylic acid [2- (1,2-dimethyl - propyl) - phenyl] - amide, enoyl morpholine (dimethomorph), flumorph (flumorph);

氟吡菌胺(fluopicolide)(picobenzamid)、苯酰菌胺(zoxamide); Fluopicolide (fluopicolide) (picobenzamid), zoxamide (zoxamide);

双氯氰菌胺(diclocymet)、双炔酰菌胺(mandipropamid); Diclocymet (diclocymet), mandipropamid amine (mandipropamid);

D)杂环化合物,尤其是:氟啶胺(fluazinam)、啶斑肟(pyrifenox); D) heterocyclic compounds, in particular: fluazinam (fluazinam), pyrifenox (pyrifenox);

磺嘧菌灵(bupirimate)、环丙嘧啶(cyprodinil)、异嘧菌醇(fenarimol)、嘧菌腙(ferimzone)、嘧菌胺(mepanipyrim)、氟苯嘧啶醇(nuarimol)、二甲嘧菌胺(pyrimethanil); Sulfo ethyl benomyl (bupirimate), cyprodinil (cyprodinil), iso triarimol (fenarimol), ferimzone (ferimzone), mepanipyrim (mepanipyrim), nuarimol (nuarimol), pyrimethanil (pyrimethanil);

嗪氨灵(triforine)、唑菌嗪(triazoxide); Triforine (triforine), triazoxide (triazoxide);

拌种咯(fenpiclonil)、氟噁菌(fludioxonil); Fenpiclonil (fenpiclonil), fludioxonil (fludioxonil);

吗菌灵(dodemorph)、丁苯吗啉(fenpropimorph)、克啉菌(tridemorph); It benomyl (dodemorph), fenpropimorph (fenpropimorph), tridemorph (Tridemorph);

苯锈啶(fenpropidin)、异丙定(iprodione)、杀菌利(procymidone)、烯菌酮(vinclozolin); Fenpropidin (fenpropidin), iprodione (iprodione), procymidone (procymidone), vinclozolin (vinclozolin);

噁唑酮菌(famoixadone)、咪唑菌酮(fenamidone)、噻菌灵(probenazole); Oxazolone bacteria (famoixadone), fenamidone (fenamidone), thiabendazole (probenazole,);

吲唑磺菌胺(amisulbrom)、敌菌灵(anilazine)、哒菌清(diclomezine)、咯喹酮(pyroquilon)、丙氧喹啉(proquinazid)、三环唑(tricyclazole); Indazol flusulfamide (amisulbrom), anilazine (anilazine), diclomezine (diclomezine), pyroquilon (pyroquilon), proquinazid (proquinazid), tricyclazole (tricyclazole);

噻二唑素(acibenzolar-S-methyl)、敌菌丹(captafol)、克菌丹、灭菌丹、氰菌胺(fenoxanil)、喹氧灵(quinoxyfen); Acibenzolar (acibenzolar-S-methyl), captafol (captafol), captan, folpet, fenoxanil (fenoxanil), quinoxyfen (quinoxyfen);

E)氨基甲酸盐类,尤其是:代森锰锌(mancozeb)、代森锰、威百亩、代森联(metiram)、福美铁、甲基代森锌(propineb)、福美双、代森锌、福美锌; E) carbamates, in particular: mancozeb (mancozeb), maneb, metam, metiram (metiram), ferbam, propineb (propineb), thiram, zineb zinc, ziram;

乙霉威(diethofencarb)、异丙菌胺(iprovalicarb)、苯噻菌胺(flubenthiavalicarb)、百维灵(propamocarb); Diethofencarb (diethofencarb), iprovalicarb (iprovalicarb), benthiavalicarb (flubenthiavalicarb), propamocarb (propamocarb);

3-(4-氯苯基)-3-(2-异丙氧羰基氨基-3-甲基丁酰氨基)丙酸甲酯; 3- (4-Chlorophenyl) -3- (2-isopropoxycarbonyl-amino-3-methylbutyrylamino) propanoate;

with

F)选自下列的其它活性化合物: The following additional active compound F) is selected from:

胍类:多果定、双胍辛醋酸盐(iminoctadine)、双胍盐(guazatine); Guanidines: dodine, iminoctadine acetate (iminoctadine), guazatine (Guazatine);

抗菌素类:春雷素(kasugamycin)、多氧霉素(polyoxine)、井冈霉素(validamycin A); Class antibiotics: kasugamycin hormone (kasugamycin), polyoxin (polyoxine), validamycin (validamycin A);

硝基苯基衍生物:敌螨普(dinocap), Nitrophenyl derivatives: dinocap (dinocap),

含硫的杂环基化合物:二噻农(dithianon)、稻瘟灵(isoprothiolane); Sulfur-containing heterocyclyl compounds: dithianon (dithianon), isoprothiolane (isoprothiolane);

有机金属化合物:三苯锡基盐 Organometallic compounds: fentin salts,

有机磷化合物:克瘟散(edifenphos)、异稻瘟净(iprobenfos)、乙膦铝(fosetyl-aluminum)、定菌磷(pyrazophos)、甲基立枯磷(tolclofos-methyl); Organophosphorus compounds: edifenphos (edifenphos), iprobenfos (iprobenfos), fosetyl aluminum (fosetyl-aluminum), gnotobiotic phosphorus (pyrazophos), tolclofos-methyl (tolclofos-methyl);

有机氯化合物:百菌清(chlorothalonil)、抑菌灵(dichlofluanid)、磺菌胺(flusulfamide)、四氯苯酞(phthalide)、戊菌隆(pencycuron)、五氯硝基苯(q uintozene)、对甲抑菌灵(tolylflu anid); Organochlorine compounds: chlorothalonil (chlorothalonil), dichlofluanid (dichlofluanid), flusulfamide (flusulfamide), tetrachlorophthalide (phthalide), pencycuron (pencycuron), quintozene (q uintozene), tolylfluanid (tolylflu anid);

无机活性化合物:波尔多液(Bordeaux mixture)、氢氧化铜、王铜、碱式硫酸铜、硫; Inorganic active compounds: Bordeaux mixture (Bordeaux mixture), copper hydroxide, copper oxychloride, basic copper sulfate, sulfur;

其他:环氟菌胺(cyflufenamid)、清菌脲(cymoxanil)、甲菌定(dimethirimol)、乙菌定(ethirimol)、呋氨丙灵(furalaxyl)、苯菌酮(metrafenone)和螺噁茂胺(spiroxamine); Other: cyflufenamid (cyflufenamid), cymoxanil (cymoxanil), A bacterium set (dimethirimol), chlozolinate set (ethirimol), furosemide metalaxyl (furalaxyl), metrafenone (metrafenone) and spiroxamine (spiroxamine);

with

3)一种选自上述A)-F)和G)-J)组的杀真菌化合物III: 3) one selected from the above A) -F) and G) -J) fungicidal compound III group:

G)选自下列的嗜球果伞素(Strobilurins):(2-氯-5-[1-(3-甲基苄氧亚氨基)乙基]苄基)氨基甲酸甲酯、(2-氯-5-[1-(6-甲基吡啶-2-基甲氧亚氨基)乙基]苄基)氨基甲酸甲酯和2-(邻-(2,5-二甲基苯氧基亚甲基)苯基)-3-甲氧基丙烯酸甲酯; G) selected from the group consisting of strobilurin (Strobilurins) :( 2- chloro-5- [1- (3-methyl-benzyloxyimino) ethyl] benzyl) carbamate, (2-chloro- 5- [1- (6-methyl-pyridin-2-yl-methoxyimino) ethyl] benzyl) carbamate and 2- (o - (2,5-dimethyl-phenoxy ylmethyleneamino yl) phenyl) -3-methoxy-acrylate;

H)选自下列的羧酰胺:呋吡唑灵(furametpyr)、噻酰菌胺(tiadinil)、N-(4'-溴联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-三氟甲基联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-氯-3'-氟联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(3',4'-二氯-4-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺、N-(3',4'-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺;3,4-二氯-N-(2-氰基苯基)异噻唑-5-甲酰胺;N-(2′,4′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4 H) selected from the group consisting of carboxamide: furosemide pyrazole spirit (furametpyr), tiadinil (tiadinil), N- (4'- bromo-biphenyl-2-yl) -4-fluoromethyl-2-carboxylic thiazole-5-yl-carboxamide, N- (4'- trifluoromethyl-biphenyl-2-yl) -4-difluoromethyl-2-methylthiazole-5-carboxamide, N- (4'- chloro-3'-fluoro-2-yl) -4-difluoromethyl-2-methylthiazole-5-carboxamide, N- (3 ', 4'- dichloro-biphenyl-4-fluoro - 2- yl) -3-difluoromethyl-1-methylpyrazole-4-carboxamide, N- (3 ', 4'- dichloro-biphenyl-2-yl) -3- difluoromethyl-1-methylpyrazole-4-carboxamide; 3,4-dichloro -N- (2- cyanophenyl) isothiazole-5-carboxamide; N- (2 ', 4'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- dichloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- difluoro-biphenyl-2-yl) -3-difluoro-methyl-1 - methyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazol - 4-carboxamide; N- (2 ', 5'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 5'-dichloro-2-yl) -1-methyl-3-trifluoromethyl-pyrazol -4 -1H- -甲酰胺;N-(2′,5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联苯-2-基)-3-二-氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺、N-(3′,5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺、N-(3′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′-氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺、N-(3′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′-氟联苯-2-基)-3-二氟甲基-1-甲基-1 - carboxamide; N- (2 ', 5'- difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2' , 5'-dichloro-2-yl) -3-- fluoro-1-methyl -1H- pyrazole-4-carboxamide; N- (3 ', 5'- difluoro-biphenyl 2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3 ', 5'- dichloro-biphenyl-2-yl) -1- -1H- pyrazole-3-trifluoromethyl-4-carboxamide, N- (3 ', 5'- difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl - 1H- pyrazole-4-carboxamide; N- (3 ', 5'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide ; N- (3'- fluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide, N- (3'- chloro-2 yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3'- fluoro-2-yl) -3-difluoromethyl-1- yl -1H- pyrazole-4-carboxamide, N- (3'- chloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N - (2'-fluoro-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N-(2'-chloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-2-yl) -3-difluoromethyl-1-methyl - 1 H-吡唑-4-甲酰胺;N-(2′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟-4′-氯-5′-甲基联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-3-氯氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺、N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,2-四氟乙氧基)苯基]-3-二氟甲基-1- H- pyrazole-4-carboxamide; N- (2'- chloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N-( 2'-fluoro-4'-chloro-5'-methylbiphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3 ' , 4 ', 5'-trifluoro-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3', 4 ', 5' - trifluorobiphenyl-2-yl) -1-methyl-3-difluoromethyl--1H- pyrazole-4-carboxamide; N- (2 ', 4', 5'- trifluoromethyl-biphenyl - 2- yl) -1-methyl-3-difluoromethyl--1H- pyrazole-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-2-yl) -3 - chlorofluoro-1-methyl -1H- pyrazole-4-carboxamide; N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) phenyl] -1 - methyl-3-trifluoromethyl--1H- pyrazole-4-carboxamide; N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) phenyl] -3 - difluoro-1-methyl -1H- pyrazole-4-carboxamide, N- [2- (2- chloro-1,1,2-trifluoroethoxy) phenyl] -1-methyl -1H- pyrazole-3-trifluoromethyl-4-carboxamide; N- [2- (2- chloro-1,1,2-trifluoroethoxy) phenyl] -3-difluoromethyl -1H- pyrazole-1-methyl-4-carboxamide; N- [2- (1,1,2,2- tetrafluoroethoxy) phenyl] -3-difluoromethyl-1 基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,2-四氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(4′-(三氟甲硫基)联苯-2-基)-3-二-氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(4′-(三氟甲硫基)联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;5-氟-1,3-二甲基-1H-吡唑-4-甲酸[2-(1,2-二甲基-丙基)-苯基]-酰胺、氟联苯菌(flumetover)、氯环丙酰胺(carpropamid),以及N-(2-(4-[3-(4-氯苯基)丙-2-炔基氧基]-3-甲氧基苯基)乙基)-2-甲磺酰氨基-3-甲基丁酰胺、N-(2-(4-[3-(4-氯苯基)丙-2-炔基氧基]-3-甲氧基苯基)乙基)-2-乙磺酰氨基-3-甲基丁酰胺; Yl -1H- pyrazole-4-carboxamide; N- [2- (1,1,2,2- tetrafluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -3-- fluoro-1-methyl -1H- pyrazole-4-carboxylic acid amide; N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; 5-fluoro -1 , 3-methyl -1H- pyrazole-4-carboxylic acid [2- (1,2-dimethyl - propyl) - phenyl] - amide, flurbiprofen bacteria (flumetover), carpropamid ( carpropamid), and N- (2- (4- [3- (4- chlorophenyl) prop-2-ynyloxy] -3-methoxyphenyl) ethyl) -2-methanesulfonylamino- -3-methylbutanamide, N- (2- (4- [3- (4- chlorophenyl) prop-2-ynyloxy] -3-methoxyphenyl) ethyl) -2- ethylsulfonyl-amino-3-methylbutyramide;

I)选自下列的杂环化合物: I) a heterocyclic compound selected from the group consisting of:

4-十二烷基-2,6-二甲基吗啉(aldimorph)、异噻菌酮(octhilinone)、吲唑磺菌胺(amisulbrom)、哒菌清(diclomezine)、5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)[1,2,4]三唑并[1,5-a]嘧啶、6-(3,4-二氯苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-(4-叔丁基苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-甲基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-乙基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-丙基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲氧基甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-三氟甲基-[1,2,4]三唑并 4-dodecyl-2,6-dimethyl morpholine (aldimorph), isothiazol cycloheximide (octhilinone), indazol flusulfamide (amisulbrom), diclomezine (diclomezine), 5- chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine, 6- (3 , 4-dichlorophenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6- (4-tert-butylphenyl) - 5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methyl-6- (3,5,5-trimethyl-hexyl) - [ 2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-methyl-5-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-ethyl-5-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-ethyl-6-octyl - [1,2,4] triazolo [1,5- a] pyrimidin-7-ylamine, 5-ethyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7 ylamine, 6-octyl-5-propyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methoxy-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-octyl-5-trifluoromethyl - [1,2,4] triazolo [1,5-a]嘧啶-7-基胺和5-三氟甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、2-丁氧基-6-碘-3-丙基苯并吡喃-4-酮;棉隆(dazomet)、3-[5-(4-氯苯基)-2,3-二甲基异噁唑烷-3-基]吡啶; [1,5-a] pyrimidin-7-ylamine and 5-trifluoromethyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5- -a] pyrimidin-7-ylamine, 2-butoxy-6-iodo-3-propyl-benzopyran-4-one; dazomet (dazomet), 3- [5- (4- chlorophenyl ) -2,3-dimethyl-isoxazol-3-yl] pyridine;

with

J)选自下列的其它活性化合物:威百亩、3-(4-氯苯基)-3-(2-异丙氧羰基氨基-3-甲基丁酰氨基)丙酸甲酯;链霉素(streptomycin)、乐杀螨(binapacryl)、敌螨通(dinobuton); J) selected from the group consisting of other active compounds: metam, 3- (4-chlorophenyl) -3- (2-isopropoxycarbonyl-amino-3-methylbutyrylamino) propanoate; streptavidin Su (streptomycin), binapacryl (binapacryl), through enemy mite (dinobuton);

薯瘟锡(fentin-acetate)、藻菌磷(fosetyl)、亚磷酸及其盐、六氯苯(hexachlorobenzene)、甲基托布津(thiophanate-methyl),和醋酸铜。 Fentin (fentin-acetate), fosetyl (of fosetyl), phosphorous acid and its salts, hexachlorobenzene (hexachlorobenzene), thiophanate-methyl (thiophanate-methyl), and copper acetate.

此外,本发明涉及一种使用化合物I和活性化合物II和III的混合物防治害虫,包括动物害虫和有害真菌的方法,化合物I和活性化合物II和III在制备该类混合物中的用途以及包含这类混合物的组合物。 Further, the present invention relates to a mixture of compound I and controlling pests the active compounds II and III, the method comprising animal pests and harmful fungi, the compounds I and active compounds II and III use in preparing such mixtures, and include such the composition of the mixture.

在本发明的一个实施方案中,提供了防治昆虫、螨虫或线虫的方法,其包括使所述昆虫、螨虫或线虫或其食物供应源、栖息地、繁殖地或其场所与杀虫有效量的化合物I和两种化合物II和III的混合物接触。 In one embodiment of the present invention, there is provided a method of controlling insects, acarids or nematodes, which comprises contacting said insects, acarids or nematodes or their food supply, habitat, breeding ground or its locus with a pesticidally effective amount of a a mixture of two compounds I and compounds II and III of the contact.

此外,在另一个实施方案中,本发明还涉及一种保护植物免受昆虫、螨虫或线虫侵袭或侵染的方法,其包括使植物,或植物在其中生长的土壤或水体与杀虫有效量的化合物I和两种化合物II和III的混合物接触。 Further, in another embodiment, the present invention also relates to a method of protecting plants against insects, acarids or nematodes attack or infestation, which comprises contacting a plant, or soil or water in the plant with a pesticidally effective amount of growth which a mixture of two compounds I and compounds II and III of the contact.

本发明还提供了一种处理、防治、预防或保护动物免受寄生虫侵袭或侵染的方法,其包括将杀寄生虫有效量的化合物I和两种化合物II和III的混合物口服、局部或肠胃外给药或施用于动物。 The present invention also provides a method for treating, controlling, infestation or infection by a method of preventing or protecting from an animal, which comprises a parasiticidally effective amount of a compound I and a mixture of the two compounds II and III for oral, topical or or parenteral administration to animals.

本发明还提供了一种制备用于处理、防治、预防或保护温血动物或鱼免受昆虫、螨虫或线虫侵袭或侵染的组合物的方法,该组合物包含杀虫有效量的化合物I和两种化合物II和III的混合物。 The present invention further provides a process for preparing for treating, controlling, preventing or protecting warm-blooded animals or fish against insects, mites, or nematode infestation or infection methods composition, the composition comprising a pesticidally effective amount of compound I Both compounds II and III and mixtures thereof.

此外,本发明涉及一种使用化合物I和活性化合物II和III的混合物防治有害真菌的方法,化合物I和活性化合物II和III在制备该类混合物中的用途以及包含这些混合物的组合物。 Further, the present invention relates to a mixture of compound I and active compounds II and III of controlling harmful fungi using the compounds I and active compounds II and III use in preparing such mixtures and compositions comprising these mixtures.

上面称为组分1的式I的邻氨基苯甲酰胺化合物、其制备及其对昆虫和螨虫害虫的作用是已知的(WO 2004/67528;WO 2004/46129;WO2004/33468;WO 2003/24222;WO 2003/15518)。 Anthranilamide compounds of formula I referred to above as component 1, its preparation and its action against insect pests and mites are known (WO 2004/67528; WO 2004/46129; WO2004 / 33468; WO 2003 / 24222; WO 2003/15518).

式I化合物与其它杀虫剂的对害虫有用的混合物通常由WO2004/67528;WO 2004/46129;WO 2004/33468;WO 2003/24222;WO 2003/15518已知。 Compounds of formula I useful in a mixture with other insecticides against pests usually consists of WO2004 / 67528; WO 2004/46129; WO 2004/33468; WO 2003/24222; WO 2003/15518 known. WO 2006/055922公开了作为单独化合物和混合物的邻氨基苯甲酰胺化合物衍生物。 WO 2006/055922 discloses anthranilic derivatives of benzamide compounds as single compounds and mixtures. 式I化合物与杀真菌剂的二元混合物描述在WO 2006/108552中。 Binary mixtures of compounds of formula I with fungicides are described in WO 2006/108552.

上面作为组分2和3提到的活性化合物II和III、其制备及其对有害真菌的作用通常是已知的(参见http://www.hclrss.demon.co.uk/index.html );它们可以市购。 2 and 3 above as the active component compounds II and III mentioned above, their preparation and their action against harmful fungi are generally known (see http://www.hclrss.demon.co.uk/index.html) ; they are commercially available. 它们尤其已知为:双苯三唑醇(bitertanol)、β-([1,1'-联苯]-4-基氧基)-α-(1,1-二甲基乙基)-1H-1,2,4-三唑-1-乙醇(DE 2324020),糠菌唑,1-[[4-溴-2-(2,4-二氯苯基)四氢-2-呋喃基]甲基]-1H-[1,2,4]-三唑(Proc.1990Br.Crop.Prot.Conf.-PestsDis.,第1卷,第459页);环唑醇,2-(4-氯苯基)-3-环丙基-1-[1,2,4]三唑-1-基丁-2-醇(US 4664696);噁醚唑,1-{2-[2-氯-4-(4-氯苯氧基)苯基]-4-甲基-[1,3]二氧戊环-2-基甲基}-1H-[1,2,4]三唑(GB-A 2098607);烯唑醇,(βE)-β-[(2,4-二氯苯基)亚甲基]-α-(1,1-二甲基乙基)-1H-1,2,4-三唑-1-乙醇(Noyaku Kagaku,1983,第8卷,第575页);烯菌灵(imazalil),1-[2-(2,4-二氯苯基)-2-(2-丙烯氧基)乙基]-1H-咪唑(Fruits,1973,第28卷,第545页);氧唑菌,(2RS,3SR)-1-[3-(2-氯苯基)-2,3-环氧-2-(4-氟苯基)丙基]-1H-1,2,4-三唑(EP-A 196 038);喹唑菌酮,3-(2,4-二氯苯基)-6-氟-2-[1,2,4]三唑-1-基-3H- In particular, they are known as: bitertanol (bitertanol), β - ([1,1'- biphenyl] -4-yl oxy) -α- (1,1- dimethylethyl) -1H 1,2,4-triazol-1-ethanol (DE 2324020), bromuconazole, 1 - [[4-bromo-2- (2,4-dichlorophenyl) tetrahydro-2-furanyl] methyl] -1H- [1,2,4] - triazole (Proc.1990Br.Crop.Prot.Conf.-PestsDis, Vol. 1, p. 459.); cyproconazole, 2- (4-chloro phenyl) -3-cyclopropyl-1- [1,2,4] triazol-1-2-ol (US 4664696); difenoconazole, 1- {2- [2-chloro-4 - (4-chlorophenoxy) phenyl] -4-methyl - [1,3] dioxolan-2-ylmethyl} -1H- [1,2,4] triazole (GB-A 2,098,607); diniconazole, (βE) -β - [(2,4- dichlorophenyl) methylene] -α- (1,1- dimethylethyl) -1H-1,2,4 - triazol-1-ethanol (Noyaku Kagaku, 1983, Vol. 8, p. 575); ethylenically benomyl (imazalil), 1- [2- (2,4- dichlorophenyl) -2- (2- propenyloxy) ethyl] -1H- imidazole (Fruits, 1973, Vol. 28, p. 545); epoxiconazole, (2RS, 3SR) -1- [3- (2- chlorophenyl) -2, epoxy-2-3- (4-fluorophenyl) propyl] -1H-1,2,4- triazole (EP-A 196 038); fluquinconazole, 3- (2,4-dichloro phenyl) -6-fluoro-2- [1,2,4] triazol-1-yl -3H- 唑啉-4-酮(Proc.Br.Crop Prot.Conf.-Pests Dis.,5-3,411(1992));腈苯唑,α-[2-(4-氯苯基)乙基]-α-苯基-1H-1,2,4-三唑-1-丙腈(Proc.1988Br.Crop Prot.Conf.-Pests Dis.,第1卷,第33页);氟硅唑,1-{[二(4-氟苯基)甲基硅烷基]甲基}-1H-[1,2,4]三唑(Proc.Br.Crop Prot.Conf.-Pests Dis.,1,413(1984));粉唑醇,α-(2-氟苯基)-α-(4-氟苯基)-1H-1,2,4-三唑-1-乙醇(EP-A 15 756);己唑醇,2-(2,4-二氯苯基)-1-[1,2,4]三唑-1-基己-2-醇(CAS RN 79983-71-4);酰胺唑,N-(2,4-二氯苯基)-1H-1,2,4-三唑-1-硫代乙亚胺酸(4-氯苯基)甲基酯((Proc.1988Br.CropProt.Conf.-Pests Dis.,第2卷,第519页);硫代亚胺酸酯((Proc.1988Br.Crop Prot.Conf.-Pests Dis.,第2卷,第519页);环戊唑醇,2-[(4-氯苯基)甲基]-5-(1-甲基乙基)-1-(1H-1,2,4-三唑-1-基甲基)环戊醇(EP-A 267778);环戊唑菌,5-(4-氯苄基)-2,2-二甲基-1-[1,2,4]三唑-1-基甲基环戊醇(GB857 383);腈菌唑, -4-one (Proc.Br.Crop Prot.Conf.-Pests Dis, 5-3,411 (1992).); Fenbuconazole, α- [2- (4- chlorophenyl) ethyl] -α- 1,2,4-triazol-1-phenyl-propan-lH-carbonitrile (Proc.1988Br.Crop Prot.Conf.-Pests Dis, Vol. 1, p. 33.); flusilazole, 1 - {[bis (4-fluorophenyl) methyl silyl] methyl} -1H- [1,2,4] triazole (Proc.Br.Crop Prot.Conf.-Pests Dis, 1,413 ( 1984)); flutriafol, α- (2- fluorophenyl) -α- (4- fluorophenyl) -1H-1,2,4- triazole-1-ethanol (EP-A 15 756); hexaconazole, 2- (2,4-dichlorophenyl) -1- [1,2,4] triazol-1-yl-hexyl-2-ol (CAS RN 79983-71-4); amides oxazole, N- (2,4- dichlorophenyl) -1H-1,2,4- triazol-1-thioacetate imidic acid (4-chlorophenyl) methyl ester ((Proc.1988Br.CropProt. Conf.-Pests Dis, Vol. 2, p. 519);. thioimidate ((Proc.1988Br.Crop Prot.Conf.-Pests Dis, Vol. 2, p. 519.); metconazole alcohol, 2 - [(4-chlorophenyl) methyl] -5- (1-methylethyl) -1- (1H-1,2,4- triazol-1-ylmethyl) cyclopentanol (EP-A 267778); metconazole, 5- (4-chlorobenzyl) -2,2-dimethyl-1- [1,2,4] triazol-1-ylmethyl cyclopentanol (GB857 383); myclobutanil, 2-(4-氯苯基)-2-[1,2,4]三唑-1-基甲基戊腈(CAS RN88671-89-0);戊菌唑,1-[2-(2,4-二氯苯基)戊基]-1H-[1,2,4]三唑(PesticideManual,第12版(2000),第712页);丙环唑,1-[[2-(2,4-二氯苯基)-4-丙基-1,3-二氧戊环-2-基]甲基]-1H-1,2,4-三唑(BE 835 579);丙硫菌唑,2-[2-(1-氯环丙基)-3-(2-氯苯基)-2-羟基丙基]-2,4-二氢[1,2,4]三唑-3-硫酮(WO 96/16048);硅氟唑,α-(4-氟苯基)-α-[(三甲基甲硅烷基)甲基]-1H-1,2,4-三唑-1-乙醇[CAS RN 149508-90-7];三唑酮,1-(4-氯苯氧基)-3,3-二甲基-1-(1H-1,2,4-三唑-1-基)-2-丁酮;唑菌醇,β-(4-氯苯氧基)-α-(1,1-二甲基乙基)-1H-1,2,4-三唑-1-乙醇;戊唑醇,1-(4-氯苯基)-4,4-二甲基-3-[1,2,4]三唑-1-基甲基戊-3-醇(EP-A 40 345);氟醚唑,1-[2-(2,4-二氯苯基)-3-(1,1,2,2-四氟乙氧基)丙基]-1H-1,2,4-三唑(EP-A 234 242);戊叉唑菌,(5E)-5-[(4-氯苯基)亚甲基]-2,2-二甲基-1-( 2- (4-chlorophenyl) -2- [1,2,4] triazol-1-yl-methyl valeronitrile (CAS RN88671-89-0); penconazole, 1- [2- (2, 3,4-dichlorophenyl) pentyl] -1H- [1,2,4] triazole (Pesticide Manual, 12th Edition (2000), p. 712); propiconazole, 1 - [[2- (2, 3,4-dichlorophenyl) -4-propyl-1,3-dioxolan-2-yl] methyl] -1H-1,2,4- triazole (BE 835 579); prothioconazole , 2- [2- (1-chloro-cyclopropyl) -3- (2-chlorophenyl) -2-hydroxypropyl] -2,4-dihydro [1,2,4] triazol-3 thione (WO 96/16048); simeconazole, α- (4- fluorophenyl) -α - [(trimethylsilyl) methyl] -1H-1,2,4- triazole -1 - ethanol [CAS RN 149508-90-7]; triadimefon, 1- (4-chlorophenoxy) -3,3-dimethyl -1- (1H-1,2,4- triazol -1 - yl) -2-butanone; triadimenol, β- (4- chlorophenoxy) -α- (1,1- dimethylethyl) -1H-1,2,4- triazole -1 - ethanol; tebuconazole, 1- (4-chlorophenyl) -4,4-dimethyl-3- [1,2,4] triazol-1-ylmethyl-3-ol (EP- A 40 345); fluoro difenoconazole, 1- [2- (2,4-dichlorophenyl) -3- (1,1,2,2-tetrafluoroethoxy) propyl] -1H-1, 2,4-triazole (EP-A 234 242); triticonazole, (5E) -5 - [(4- chlorophenyl) methylene] -2,2-dimethyl-1- ( 1H-1,2,4-三唑-1-基甲基)环戊醇(FR 26 4 1277);丙氯灵,N-{丙基-[2-(2,4,6-三氯苯氧基)乙基]}咪唑-1-甲酰胺(US 3 991 071);稻瘟酯,2-[(2-呋喃基甲基)(1H-咪唑-1-基羰基)氨基]丁酸4-戊烯基酯[CASRN 101903-30-4];氟菌唑,(4-氯-2-三氟甲基苯基)-(2-丙氧基-1-[1,2,4]三唑-1-基亚乙基)胺(JP-A 79/119 462);氰霜唑,4-氯-2-氰基-N,N-二甲基-5-(4-甲基苯基)-1H-咪唑-1-磺酰胺(CAS RN 120116-88-3);苯菌灵,N-丁基-2-乙酰氨基苯并咪唑-1-甲酰胺(US 3 631 176);多菌灵,(1H-苯并咪唑-2-基)氨基甲酸甲酯(US 3 657 443);涕必灵,2-(1,3-噻唑-4-基)苯并咪唑(US 3 017415);麦穗宁,2-(2-呋喃基)-1H-苯并咪唑(DE-A 12 09 799);噻唑菌胺,N-(氰基-2-噻吩基甲基)-4-乙基-2-(乙氨基)-5-噻唑甲酰胺(EP-A 639 574);氯唑灵;土菌消,5-甲基-1,2-噁唑-3-醇(JP 518249,JP 532202);腈嘧菌酯,2-{2-[6-(2-氰基-1-乙烯基戊-1,3-二烯氧基)嘧啶-4 1H-1,2,4- triazol-1-ylmethyl) cyclopentanol (FR 26 4 1277); prochloraz, N- {propyl - [2- (2,4,6-trichlorobenzene oxy) ethyl]} imidazole-1-carboxamide (US 3 991 071); pefurazoate, 2 - [(2-furylmethyl) (lH-imidazol-1-yl-carbonyl) amino] butanoic acid 4 - pentenyl ester [CASRN 101903-30-4]; triflumizole, (4-chloro-2-trifluoromethyl-phenyl) - (2-propoxy-1- [1,2,4] -1-methylethylidene) amine (JP-A 79/119 462); cyazofamid, 4-chloro-2-cyano -N, N- dimethyl-5- (4-methylphenyl ) lH-imidazole-1-sulfonamide (CAS RN 120116-88-3); benomyl, N- butyl-2-acetylamino-benzimidazole-1-carboxamide (US 3 631 176); polymicrobial Ling, (lH-benzimidazol-2-yl) carbamate (US 3 657 443); thiabendazole, 2- (1,3-thiazol-4-yl) benzimidazole (US 3 017415); fuberidazole, 2- (2-furyl) lH-benzo imidazole (DE-A 12 09 799); ethaboxam, N- (cyano-2-thienylmethyl) -4-ethyl - 2- (ethylamino) -5-thiazole-carboxamide (EP-A 639 574); chlorazol spirit; hymexazol, 5-methyl-1,2-3-ol (JP 518249, JP 532202) ; azoxystrobin, 2- {2- [6- (2-cyano-1-vinyl-1,3-diene-yloxy) pyrimidin-4 -基氧基]苯基}-3-甲氧基丙烯酸甲酯(EP-A 382 375);醚菌胺,(E)-2-(甲氧亚氨基)-N-甲基-2-[α-(2,5-二甲苯氧基)-邻甲苯基]乙酰胺(EP-A 477 631);氟嘧菌酯,(E)-{2-[6-(2-氯苯氧基)-5-氟嘧啶-4-基氧基]苯基}(5,6-二氢-1,4,2-二噁嗪-3-基)甲酮O-甲基肟(WO 97/27189);亚胺菌,(E)-甲氧亚氨基[α-(邻甲苯氧基)-邻甲苯基]乙酸甲酯(EP-A 253 213);叉氨苯酰胺,(E)-2-(甲氧亚氨基)-N-甲基-2-(2-苯氧基苯基)乙酰胺(EP-A 398 692);肟醚菌胺,(2E)-2-(甲氧亚氨基)-2-{2-[(3E,5E,6E)-5-(甲氧亚氨基)-4,6-二甲基-2,8-二氧杂-3,7-二氮杂壬-3,6-二烯-1-基]苯基}-N-甲基乙酰胺(WO 97/15552);啶氧菌酯,3-甲氧基-2-[2-(6-三氟甲基吡啶-2-基氧基甲基)苯基]丙烯酸甲酯(EP-A 278 595);唑菌胺酯,N-{2-[1-(4-氯苯基)-1H-吡唑-3-基氧基甲基]苯基}(N-甲氧基)氨基甲酸甲酯(WO 96/01256);肟菌酯,(E)-甲氧亚氨基-{(E)-α-[1-(α,α,α-三氟 - yloxy] phenyl} -3-methoxyacrylate (EP-A 382 375); dimoxystrobin, (E) -2- (methoxyimino) -N- methyl-2- [ α- (2,5- dimethylphenoxy) - o-tolyl] acetamide (EP-A 477 631); fluoxastrobin, (E) - {2- [6- (2- chlorophenoxy) 5-fluoro-pyrimidin-4-yloxy] phenyl} (5,6-dihydro-1,4,2-dioxazin-3-yl) methanone O- methyloxime (WO 97/27189) ; kresoxim-methyl, (E) - -methoxyimino [alpha] (o-tolyloxy) - o-tolyl] acetate (EP-A 253 213); metominostrobin, (E) -2- ( methoxyimino) -N- methyl-2- (2-phenoxyphenyl) acetamide (EP-A 398 692); orysastrobin, (2E) -2- (methoxyimino) - 2- {2 - [(3E, 5E, 6E) -5- (methoxyimino) -4,6-dimethyl-2,8-dioxa-3,7-diaza-nonyl -3, 6- dien-1-yl] phenyl} -N- methylacetamide (WO 97/15552); picoxystrobin, 3-methoxy-2- [2- (6-trifluoromethyl pyridine 2-yloxymethyl) phenyl] acrylate (EP-A 278 595); pyraclostrobin, N- {2- [1- (4- chlorophenyl) lH-pyrazol-3 - yloxymethyl] phenyl} (N- methoxy) carbamate (WO 96/01256); trifloxystrobin, (E) - -methoxyimino - {(E) -α- [1 - (α, α, α- trifluoro -间甲苯基)亚乙基氨基氧基]-邻甲苯基}乙酸甲酯(EP-A 460 575);萎锈灵,5,6-二氢-2-甲基-N-苯基-1,4-氧硫杂芑-3-甲酰胺(US 3 249 499);苯霜灵,N-(苯基乙酰基)-N-(2,6-二甲苯基)-DL-丙氨酸甲酯(DE 29 03 612);啶酰菌胺,2-氯-N-(4'-氯联苯-2-基)烟酰胺(EP-A 545 099);环酰菌胺,N-(2,3-二氯-4-羟基苯基)-1-甲基环己烷甲酰胺(Proc.Br.Crop Prot.Conf.-Pests Dis.,1998,第2卷,第327页);氟酰胺,α,α,α-三氟-3'-异丙氧基-邻甲苯甲酰苯胺(JP1104514);呋吡唑灵,5-氯-N-(1,3-二氢-1,1,3-三甲基-4-异苯并呋喃基)-1,3-二甲基-1H-吡唑-4-甲酰胺[CAS RN 123572-88-3];丙氧灭绣胺,3'-异丙氧基-邻甲苯甲酰苯胺(US 3 937 840);甲霜灵,N-(甲氧基乙酰基)-N-(2,6-二甲苯基)-DL-丙氨酸甲酯(GB 15 00 581);精甲霜灵,N-(2,6-二甲苯基)-N-(甲氧基乙酰基)-D-丙氨酸甲酯;甲呋酰胺,(RS)-α-(2-氯-N-2,6-二甲苯基乙酰胺基) - m-tolyl) oxy ethylidene amino] - o-tolyl} acetate (EP-A 460 575); carboxin, 5,6-dihydro-2-phenyl-1-methyl -N- , 4-dioxin-thia-oxo-3-carboxamide (US 3 249 499); benalaxyl, N- (phenylacetyl) -N- (2,6- xylyl) -DL-alanine methyl ester (DE 29 03 612); boscalid, 2-chloro -N- (4'- chlorobiphenyl-2-yl) nicotinamide (EP-A 545 099); fenhexamid, N- (2 , 2,3-dichloro-4-hydroxyphenyl) -1-methyl-cyclohexane carboxamide (Proc.Br.Crop Prot.Conf.-Pests Dis, 1998, vol. 2, p. 327);. flutolanil , α, α, α- trifluoro-3'-isopropoxy-o - toluoyl aniline (JP1104514); Ling furosemide pyrazole, 5-chloro -N- (1,3- dihydro-1,1, 3- trimethyl-4-isobenzofuranyl) -1,3-dimethyl--1H- pyrazole-4-carboxamide [CAS RN 123572-88-3]; propoxy off embroidery amine, 3 ' - isopropoxy - toluoyl aniline (US 3 937 840); metalaxyl, N- (methoxyacetyl) -N- (2,6- xylyl) -DL-alanine methyl ester (GB 15 00 581); mefenoxam, N- (2,6- dimethylphenyl) -N- (methoxyacetyl) -D- alaninate; ofurace, (RS) -α- (2- chloro -N-2,6- dimethylphenyl acetamido) -γ-丁内酯[CAS RN 58810-48-3];噁霜灵,N-(2,6-二甲基苯基)-2-甲氧基-N-(2-氧代-3-噁唑烷基)乙酰胺(GB 20 58 059);氧化萎锈灵,5,6-二氢-2-甲基-1,4-氧硫杂芑-3-甲酰苯胺4,4-二氧化物(US 3 399 214);吡噻菌胺,N-[2-(1,3-二甲基丁基)-3-噻吩基]-1-甲基-3-(三氟甲基)-1H-吡唑-4-甲酰胺(JP 10/130268);溴氟唑菌,N-[2,6-二溴-4-(三氟甲氧基)苯基]-2-甲基-4-(三氟甲基)-5-噻唑甲酰胺;噻酰菌胺,3'-氯-4,4'-二甲基-1,2,3-噻二唑-5-甲酰苯胺[CAS RN 223580-51-6];烯酰吗啉,3-(4-氯苯基)-3-(3,4-二甲氧基苯基)-1-吗啉-4-基丙烯酮(EP-A 120 321);氟吗啉,3-(4-氟苯基)-3-(3,4-二甲氧基苯基)-1-吗啉-4-基丙烯酮(EP-A 860 438);氟联苯菌,2-(3,4-二甲氧基苯基)-N-乙基-α,α,α-三氟-N-甲基对甲苯甲酰胺[AGROW No.243,22(1995)];氟吡菌胺(picobenzamid),2,6-二氯-N-(3-氯-5-三氟甲基吡啶-2-基甲基)苯甲酰胺(WO 99/42447) -γ- butyrolactone [CAS RN 58810-48-3]; Oxadixyl, N- (2,6- dimethylphenyl) -2-methoxy -N- (2- oxo-3- oxazolidinyl) acetamide (GB 20 58 059); oxycarboxin, 5,6-dihydro-2-methyl-1,4-oxo-thia-4,4-dioxin-3-carboxylic aniline oxide (US 3 399 214); penthiopyrad, N- [2- (1,3- dimethylbutyl) -3-thienyl] -1-methyl-3- (trifluoromethyl) -1H- pyrazole-4-carboxamide (JP 10/130268); thifluzamide, N- [2,6- dibromo-4- (trifluoromethoxy) phenyl] -2-methyl - 4- (trifluoromethyl) -5-thiazole-carboxamide; tiadinil, 3'-chloro-4,4'-dimethyl-1,2,3-thiadiazole-5-carboxanilide [ CAS RN 223580-51-6]; dimethomorph, 3- (4-chlorophenyl) -3- (3,4-dimethoxyphenyl) -1-morpholin-4-yl propenone ( EP-A 120 321); flumorph, 3- (4-fluorophenyl) -3- (3,4-dimethoxyphenyl) -1-morpholin-4-yl-propenone (EP-A 860 438); bacteria-fluoro-biphenyl, 2- (3,4-dimethoxyphenyl) -N- ethyl -α, α, α- trifluoro -N- methyl p-toluamide [aGROW No. 243,22 (1995)]; fluopicolide (picobenzamid), 2,6- dichloro -N- (3- chloro-5-trifluoromethyl-pyridin-2-ylmethyl) benzamide (WO 99 / 42447) ;苯酰菌胺,(RS)-3,5-二氯-N-(3-氯-1-乙基-1-甲基-2-氧代丙基)-对甲苯甲酰胺[CAS RN 156052-68-5];氯环丙酰胺,2,2-二氯-N-[1-(4-氯苯基)乙基]-1-乙基-3-甲基环丙烷甲酰胺[CAS RN 104030-54-8];双氯氰菌胺,2-氰基-N-[(1R)-1-(2,4-二氯苯基)乙基]-3,3-二甲基丁酰胺;双炔酰菌胺,(RS)-2-(4-氯苯基)-N-[3-甲氧基-4-(丙-2-炔基氧基)苯乙基]-2-(丙-2-炔基氧基)乙酰胺[CAS RN 374726-62-2];氟啶胺,3-氯-N-[3-氯-2,6-二硝基-4-(三氟甲基)苯基]-5-(三氟甲基)-2-吡啶胺(The Pesticide Manual,publ.The BritishCrop Protection Council,第10版(1995),第474页);啶斑肟,1-(2,4-二氯苯基)-2-(3-吡啶基)乙酮O-甲基肟(EP-A 49 854);磺嘧菌灵,5-丁基-2-乙基氨基-6-甲基嘧啶-4-基二甲基氨基磺酸酯[CAS RN 41483-43-6];环丙嘧啶,(4-环丙基-6-甲基嘧啶-2-基)苯基胺(EP-A 310 550);异嘧菌醇,(4-氯苯基)(2-氯苯基)嘧啶-5-基甲醇(GB 12 18 623); ; Zoxamide, (RS) -3,5- dichloro -N- (3- chloro-1-ethyl-1-methyl-2-oxopropyl) - p-toluamide [CAS RN 156052 -68-5]; carpropamid, 2,2-dichloro -N- [1- (4- chlorophenyl) ethyl] -1-ethyl-3-methyl-cyclopropanecarboxamide [CAS RN 104030-54-8]; diclocymet, 2-cyano -N - [(1R) -1- (2,4- dichlorophenyl) ethyl] -3,3-dimethyl butanamide ; amine mandipropamid, (RS) -2- (4- chlorophenyl) -N- [3- methoxy-4- (prop-2-ynyloxy) phenethyl] -2- ( prop-2-ynyloxy) acetamide [CAS RN 374726-62-2]; fluazinam, 3-chloro -N- [3- chloro-2,6-dinitro-4- (trifluoromethyl yl) phenyl] -5- (trifluoromethyl) -2-pyridinamine (The Pesticide Manual, publ.The BritishCrop Protection Council, 10th Edition (1995), p. 474); pyrifenox, 1- ( 2,4-dichlorophenyl) -2- (3-pyridyl) ethanone O- methyloxime (EP-A 49 854); sulfo ethyl benomyl, 5-butyl-2-ethyl-amino-6 - dimethyl-methyl-pyrimidin-4-yl sulfamate [CAS RN 41483-43-6]; cyprodinil, (4-cyclopropyl-6-methyl-pyrimidin-2-yl) phenylamine ( EP-A 310 550); heterologous triarimol, (4-chlorophenyl) (2-chlorophenyl) pyrimidin-5-ylmethanol (GB 12 18 623); 菌腙,(Z)-2'-甲基苯乙酮-4,6-二甲基嘧啶-2-基腙[CAS RN 89269-64-7];嘧菌胺,(4-甲基-6-丙-1-炔基嘧啶-2-基)苯基胺(EP-A 224 339);氟苯嘧啶醇,α-(2-氯苯基)-α-(4-氟苯基)-5-嘧啶甲醇(GB 12 18 623);二甲嘧菌胺,4,6-二甲基嘧啶-2-基苯基胺(DD-A 151404);嗪氨灵,N,N'-{哌嗪-1,4-二基二[(三氯甲基)亚甲基]}二甲酰胺(DE 1901 421);唑菌嗪,7-氯-3-咪唑基-1-基-1,2,4-苯并三嗪-1-氧化物[CAS-No.72459-58-6];拌种咯,4-(2,3-二氯苯基)-1H-吡咯-3-甲腈(Proc.1988Br.CropProt.Conf.-Pests Dis.,第1卷,第65页);氟噁菌,4-(2,2-二氟苯并[1,3]二氧杂环戊烯-4-基)-1H-吡咯-3-甲腈(The Pesticide Manual,publ.TheBritish Crop Protection Council,第10版(1995),第482页);4-十二烷基-2,6-二甲基吗啉,包含65-75%2,6-二甲基吗啉和25-35%2,5-二甲基吗啉的4-烷基-2,5(或2,6)-二甲基吗啉,其中超过85%为4-十二烷基-2,5(或2,6)- Bacteria hydrazone, (Z) -2'- methylacetophenone 4,6-dimethylpyrimidine-2-yl hydrazone [CAS RN 89269-64-7]; mepanipyrim, (4-methyl-6 - prop-1-ynyl-pyrimidin-2-yl) phenylamine (EP-A 224 339); nuarimol, α- (2- chlorophenyl) -α- (4- fluorophenyl) -5- - pyrimidine methanol (GB 12 18 623); pyrimethanil, 4,6-dimethyl-pyrimidin-2-yl phenylamine (DD-A 151404); triforine, N, N '- {piperazine 1,4-diylbis [(trichloromethyl) methylene]} dicarboxamide (DE 1901 421); triazoxide, 7-chloro-3-imidazol-1-yl-1,2, 4- benzotriazine-1-oxide [CAS-No.72459-58-6]; fenpiclonil, 4- (2,3-dichlorophenyl) lH-pyrrole-3-carbonitrile (Proc .1988Br.CropProt.Conf.-Pests Dis, Vol. 1, p. 65);. fludioxonil, 4- (2,2-difluorobenzo [1,3] dioxol-4 yl) lH-pyrrole-3-carbonitrile (The Pesticide Manual, publ.TheBritish Crop Protection Council, 10th Edition (1995), p. 482); 4-dodecyl-2,6-dimethylmorpholine morpholine, comprising 65-75% of 2,6-dimethylmorpholine and 25-35% 2,5-dimethyl-morpholin-4-alkyl-2,5 (or 2,6) - dimethylmorpholine morpholine, of which more than 85% of 4-dodecyl-2,5 (or 2,6) - 二甲基吗啉且其中“烷基”还包括辛基、癸基、十四烷基或十六烷基以及其中顺/反比为1∶1;吗菌灵,4-环十二烷基-2,6-二甲基吗啉(DE 1198125);丁苯吗啉,(RS)-顺式-4-[3-(4-叔丁基苯基)-2-甲基丙基]-2,6-二甲基吗啉(DE27 52 096);克啉菌,2,6-二甲基-4-十三烷基吗啉(DE 11 64 152);苯锈啶,(RS)-1-[3-(4-叔丁基苯基)-2-甲基丙基]哌啶(DE 27 52 096);异丙定,N-异丙基-3-(3,5-二氯苯基)-2,4-二氧代咪唑烷-1-甲酰胺(GB 13 12 536);杀菌利,N-(3,5-二氯苯基)-1,2-二甲基环丙烷-1,2-二甲酰亚胺(US 3 903 090);烯菌酮,3-(3,5-二氯苯基)-5-甲基-5-乙烯基噁唑烷-2,4-二酮(DE-OS 22 07 576);噁唑酮菌,(RS)-3-苯胺基-5-甲基-5-(4-苯氧基苯基)-1,3-噁唑烷-2,4-二酮;咪唑菌酮,(S)-1-苯胺基-4-甲基-2-甲硫基-4-苯基咪唑啉-5-酮;异噻菌酮;噻菌灵,3-烯丙氧基-1,2-苯并噻唑1,1-二氧化物;吲唑磺菌 Dimethylmorpholine and wherein "alkyl" also includes octyl, decyl, tetradecyl or hexadecyl and where the cis / inverse is 1:1; it benomyl, 4-dodecyl - 2,6-dimethyl-morpholine (DE 1198125); fenpropimorph, (RS) - cis-4- [3- (4-tert-butylphenyl) -2-methylpropyl] -2 2,6-dimethyl-morpholine (DE27 52 096); tridemorph, 2,6-dimethyl-4-tridecyl-morpholine (DE 11 64 152); fenpropidin, (RS) -1 - [3- (4-tert-butylphenyl) -2-methylpropyl] piperidine (DE 27 52 096); iprodione, N- isopropyl-3- (3,5-dichlorophenoxy yl) -2,4-dioxo-imidazolidin-1-carboxamide (GB 13 12 536); procymidone, N- (3,5- dichlorophenyl) -1,2-dimethyl-cyclopropane - 1,2-dicarboximide (US 3 903 090); vinclozolin, 3- (3,5-dichlorophenyl) -5-methyl-5-vinyl-2,4-oxazolidine dione (DE-OS 22 07 576); oxazolone bacteria, (RS) -3- anilino-5-methyl-5- (4-phenoxyphenyl) -1,3-oxazolidine - 2,4-dione; fenamidone, (S) -1- anilino-4-methyl-2-methylthio-4-phenyl-imidazol-5-one; isothiazol cycloheximide; thiabendazole , 3-allyloxy-1,2-benzothiazole 1,1-dioxide; indazol flusulfamide ,N,N-二甲基-3-(3-溴-6-氟-2-甲基吲哚-1-磺酰基)-[1,2,4]三唑-1-磺酰胺(WO03/053145);敌菌灵,4,6-二氯-N-(2-氯苯基)-1,3,5-三嗪-2-胺(US 2 720 480);哒菌清,6-(3,5-二氯苯基)-对甲苯基)哒嗪-3(2H)-酮;咯喹酮;丙氧喹啉,6-碘-2-丙氧基-3-丙基喹唑啉-4(3H)-酮(WO 97/48684);三环唑,5-甲基-1,2,4-三唑并[3,4-b]苯并噻唑(GB 14 19 121);噻二唑素,苯并[1,2,3]噻二唑-7-硫代羰酸甲基酯;敌菌丹,N-(1,1,2,2-四氯乙硫基)环己-4-烯-1,2-二甲酰亚胺;克菌丹,2-三氯甲硫基-3a,4,7,7a-四氢异氮杂茚-1,3-二酮(US 2 553 770);棉隆,3,5-二甲基-1,3,5-噻二嗪烷-2-硫酮;灭菌丹,2-三氯甲硫基异氮杂茚-1,3-二酮(US 2 553 770);氰菌胺,N-(1-氰基-1,2-二甲基丙基)-2-(2,4-二氯苯氧基)丙酰胺;喹氧灵,5,7-二氯-4-(4-氟苯氧基)喹啉(US 5 240 940);代森锰锌,亚乙基二(二硫代氨基甲酸)锰 , N, N- dimethyl-3- (3-bromo-6-fluoro-2-methyl-indol-1-sulfonyl) - [1,2,4] triazol-1-sulfonamide (WO03 / 053 145); anilazine, 4,6-dichloro -N- (2- chlorophenyl) -1,3,5-triazin-2-amine (US 2 720 480); diclomezine, 6- ( 3,5-dichlorophenyl) - p-tolyl) pyridazin -3 (2H) - one; pyroquilon; proquinazid, 6-iodo-2-propoxy-3-propyl quinazoline -4 (3H) - one (WO 97/48684); tricyclazole, 5-methyl-1,2,4-triazolo [3,4-b] benzothiazole (GB 14 19 121); thiazol Su oxadiazole, benzo [1,2,3] thiadiazole-7-carbothioic acid methyl ester carbonyl; captafol, N- (1,1,2,2- tetrachloro-ethylthio) cyclohexyl 4-ene-1,2-dicarboximide; captan, 2-trichloromethyl-methylthio--3a, 4,7,7a- tetrahydro-1,3-isoindolyl dione (US 2,553,770); dazomet, 3,5-dimethyl-1,3,5-thiadiazine-2-thione; folpet, 2-trichloromethyl-methylthio-isoindolyl -1 3- dione (US 2 553 770); fenoxanil, N- (1- cyano-1,2-dimethylpropyl) -2- (2,4-dichlorophenoxy) propanamide; quinoxyfen, 5,7-dichloro-4- (4-fluorophenoxy) quinoline (US 5 240 940); mancozeb, ethylenebis (dithiocarbamic acid) manganese 配合物(US 3 379 610);代森锰,亚乙基二(二硫代氨基甲酸)锰(US 2 504 404);威百亩,甲基二硫代氨基甲酸(US 2791 605);代森联,亚乙基二(二硫代氨基甲酸)锌氨合物(US 3 248 400);甲基代森锌,亚丙基二(二硫代氨基甲酸)锌聚合物(BE 611 960);福美铁,二甲基二硫代氨基甲酸铁(3+)(US 1 972 961);福美双,二(二甲基硫代氨基甲酰基)二硫化物(DE 642 532);福美锌,二硫代氨基甲酸二甲基酯;代森锌,亚乙基二(二硫代氨基甲酸)锌(US 2 457 674);乙霉威,3,4-二乙氧基苯胺基甲酸异丙基酯;异丙菌胺,[(1S)-2-甲基-1-(1-对甲苯基乙基氨基甲酰基)丙基]氨基甲酸异丙酯(EP-A 472 996);苯噻菌胺(benthiavalicarb),{(S)-1-[(1R)-1-(6-氟苯并噻唑-2-基)乙基氨基甲酰基]-2-甲基丙基}氨基甲酸异丙基酯(JP-A09/323 984);百维灵,3-(二甲基氨基)丙基氨基甲酸丙基酯(DE 16 43 040);多果定,(2,4-二氯苯氧基) Complex (US 3 379 610); maneb, ethylenebis (dithiocarbamic acid) manganese (US 2 504 404); metam, methyl dithiocarbamate (US 2791 605); substituting metiram, ethylenebis (dithiocarbamic acid) zinc ammine (US 3 248 400); propineb, propylene bis (dithiocarbamate) polymer zinc (BE 611 960) ; ferbam, dimethyl dithiocarbamate iron (3 +) (US 1 972 961); thiram, bis (dimethyl thiocarbamoyl) disulfide (DE 642 532); ziram, dithiocarbamic acid dimethyl ester; propineb, ethylenebis (dithiocarbamic acid) zinc (US 2 457 674); diethofencarb, 3,4-diethoxy-anilino-carboxylic acid isopropyl ester; iprovalicarb, [(1S) -2- methyl-1- (1-p-tolyl-ethylcarbamoyl) -propyl] -carbamic acid isopropyl ester (EP-A 472 996); tiaprofenic bacteria amine (benthiavalicarb), {(S) -1 - [(1R) -1- (6- fluorobenzo thiazol-2-yl) ethylcarbamoyl] -2-methylpropyl} carbamic acid isopropyl ester (JP-A09 / 323 984); propamocarb, 3- (dimethylamino) propyl carbamic acid propyl ester (DE 16 43 040); dodine, (2,4-dichlorophenoxyacetic base) 酸(US 2 867 562);双胍辛醋酸盐,二(8-胍基辛基)胺(GB 11 14 155);双胍盐,由亚氨基二(八亚甲基)二胺的酰胺化形成的产物混合物,主要是双胍辛醋酸盐;春雷素,1L-1,3,4/2,5,6-1-脱氧-2,3,4,5,6-五羟基环己基2-氨基-2,3,4,6-四脱氧-4-(α-亚氨基甘氨酰)-α-D-阿拉伯吡喃己糖;链霉素,O-2-脱氧-2-甲基氨基-α-L-吡喃葡糖基-(1→2)-O-5-脱氧-3-C-甲酰基-α-L-呋喃来苏糖基-(1→4)N 1 ,N 3 -二脒基-D-链霉胺;多氧霉素,5-(2-氨基-5-O-氨基甲酰基-2-脱氧-L-木质酰胺基)-1-(5-羧基-1,2,3,4-四氢-2,4-二氧代嘧啶-1-基)-1,5-二脱氧-β-D-呋喃阿洛糖醛酸及其盐;井冈霉素;乐杀螨,3-甲基巴豆酸(RS)-2-仲丁基-4,6-二硝基苯基酯;敌螨普,巴豆酸2,6-二硝基-4-辛基苯基酯和巴豆酸2,4-二硝基-6-辛基苯基酯的混合物,其中“辛基”为1-甲基庚基、1-乙基己基和1-丙基戊基的混合物(U Acid (US 2 867 562); Iminoctadine acetate, bis (8-guanidinooctyl) amine (GB 11 14 155); guazatine, imino amide formed from di (octamethylene) diamine the product mixture, mainly Iminoctadine acetate; Jubilee hormone, 1L-1,3,4 / 2,5,6-1- five 2,3,4,5,6-deoxy-2-amino-hydroxycyclohexyl 2,3,4,6-tetradeoxy -4- (α- imino-glycyl) -α-D- pyran Arab hexose; streptomycin, O-2- deoxy-2-methylamino - α-L- glucopyranosyl group - (1 → 2) -O- 5- formyl-deoxy -3-C- -α-L- lyxose furyl group - (1 → 4) N 1 , N 3 - -D- streptavidin-diamidino-amine; polyoxin, 5- (2-amino -5-O- carbamoyl-2-deoxy--L- wood amido) -1- (5-carboxy-1, 2,3,4-tetrahydro-2,4-dioxo-1-yl) -1,5-dideoxy -β-D- allose furan uronic acid and its salts; validamycin; Le kill mites, crotonic acid, methyl (RS) -2- sec-butyl-4,6-dinitrophenyl ester; dinocap, crotonic acid, 2,6-dinitro-4-octylphenyl ester and a mixture of octylphenyl crotonate ester of 2,4-dinitro-6, wherein "octyl" is a 1-methylheptyl, 1-ethylhexyl and 1-propyl-pentyl mixture of (U S 2 526 660);敌螨通,碳酸(RS)-2-仲丁基-4,6-二硝基苯基异丙基酯;二噻农,5,10-二氧代-5,10-二氢萘并[2,3-b][1,4]二噻英-2,3-二甲腈(GB 857 383);稻瘟灵,吲哚-3-基乙酸;薯瘟锡,醋酸三苯基锡(US 3 499 086); S 2 526 660); mites through enemy carbonate (RS) -2- sec-butyl-4,6-dinitrophenyl isopropyl carbonate; dithianon, 5,10-dioxo -5,10 - dihydro-naphtho [2,3-b] [1,4] dithiino-2,3-dicarbonitrile (GB 857 383); isoprothiolane, indol-3-yl acetate; fentin acetate, triphenyltin acetate (US 3 499 086);

克瘟散,二硫代膦酸O-乙基S,S-二苯基酯;异稻瘟净,硫代膦酸S-苄基O,O-二异丙基酯(Jpn.Pesticide Inf.,第2期,第11页(1970));藻菌磷,乙膦铝,膦酸乙酯(铝)(FR 22 54 276);定菌磷,2-二乙氧基硫代膦酰氧基-5-甲基吡唑并[1,5-a]嘧啶-6-甲酸乙酯(DE 15 45 790);甲基立枯磷,硫代膦酸O-2,6-二氯对甲苯基O,O-二甲基酯(GB 14 67 561);百菌清,2,4,5,6-四氯间苯二甲腈(US 3 290 353);抑菌灵,N-二氯一氟甲硫基-N',N'-二甲基-N-苯基磺酰胺(DE 11 93 498);磺菌胺,2',4-二氯-α,α,α-三氟-4′-硝基间甲苯磺酰苯胺(EP-A 199 433);六氯苯(CRSeances Acad.Agric.Fr.,第31卷,第24页(1945));四氯苯酞(DE 16 43 347);戊菌隆,1-(4-氯苄基)-1-环戊基-3-苯基脲(DE 27 32 257);五氯硝基苯,五氯代硝基苯(DE 682 048);甲基托布津,1,2-亚苯基二(亚氨基硫代羰基)二(氨基甲酸二甲基酯)(DE-OS 19 30540);对甲抑菌 Edifenphos, O- dithiophosphoric acid ethyl S, S- diphenyl; iprobenfos, phosphorothioate S- benzyl O, O- diisopropyl ester (Jpn.Pesticide Inf. , No. 2, page 11 (1970)); fosetyl, fosetyl aluminum, ethyl phosphonate (Al) (FR 22 54 276); gnotobiotic phosphate, 2-phosphonooxy diethoxythiobenzamide -5-methyl-pyrazolo [1,5-a] pyrimidine-6-carboxylate (DE 15 45 790); tolclofos-methyl, phosphorothioate O-2,6- dichloro-p group O, O- dimethyl ester (GB 14 67 561); chlorothalonil, 2,4,5,6-tetrachloro-isophthalonitrile (US 3 290 353); dichlofluanid, N- dichloro a difluoromethylthio group -N ', N'- dimethyl--N- phenyl-sulfonamide (DE 11 93 498); flusulfamide, 2', 4-dichloro -α, α, α- trifluoro - 4'-nitro-aniline room toluenesulfonyl (EP-A 199 433); hexachlorobenzene (CRSeances Acad.Agric.Fr, Vol. 31, p. 24 (1945).); tetrachlorophthalide (DE 16 43 347); pencycuron, 1- (4-chlorobenzyl) -1-cyclopentyl-3-phenylurea (DE 27 32 257); quintozene, five chloronitrobenzene (DE 682 048); thiophanate-methyl, 1,2-phenylene bis (imino-thiocarbonyl) di (carbamic acid dimethyl ester) (DE-OS 19 30540); toluenesulfonic antibacterial 灵,N-二氯一氟甲硫基-N,N-二甲基-N-对甲苯基磺酰胺(DE11 93 498);波尔多液,氢氧化钙和硫酸铜(II)的混合物;氢氧化铜,Cu(OH) 2 ;王铜,Cu 2 Cl(OH) 3 ;环氟菌胺,(Z)-N-[α-(环丙基甲氧亚氨基)-2,3-二氟-6-(三氟甲基)苄基]-2-苯基乙酰胺(WO 96/19442);清菌脲,1-(2-氰基-2-甲氧亚氨基乙酰基)-3-乙基脲(US 3 957 847);甲菌定,5-丁基-2-二甲基氨基-6-甲基嘧啶-4-醇(GB 11 82 584);乙菌定,5-丁基-2-乙基氨基-6-甲基嘧啶-4-醇(GB11 82 584);呋氨丙灵,N-(2-糠酰基)-N-(2,6-二甲苯基)-DL-丙氨酸甲酯(GB14 48 810);苯菌酮,3'-溴-2,3,4,6'-四甲氧基-2',6-二甲基二苯甲酮(US 5 945567);螺噁茂胺,(8-叔丁基-1,4-二氧杂螺[4.5]癸-2-基)二乙基胺(EP-A 281842)。 Ling, N- dichlorofluoro- methylthio -N, N- dimethyl-p-tolyl-sulfonamide -N- (DE11 93 498); Bordeaux mixture, copper sulfate and calcium hydroxide (II) mixture; hydroxide copper, Cu (OH) 2; copper oxychloride, Cu 2 Cl (OH) 3 ; cyflufenamid, (Z) -N- [α- (cyclopropylmethoxy imino) -2,3-difluoro - 6- (trifluoromethyl) benzyl] -2-phenylacetamide (WO 96/19442); cymoxanil, 1- (2-cyano-2-methoxyimino-acetyl) -3- urea (US 3 957 847); fixed bacteria A, 5-butyl-2-dimethylamino-6-methyl-pyrimidin-4-ol (GB 11 82 584); chlozolinate set, 5-butyl - 2-ethyl-6-methyl pyrimidin-4-ol (GB11 82 584); furosemide metalaxyl, N- (2- furoyl) -N- (2,6- xylyl) -DL-propyl methyl ester (GB14 48 810); metrafenone, 3'-bromo--2,3,4,6'- tetramethoxy-2 ', 6-dimethyl-benzophenone (US 5 945567) ; spiroxamine, (8-tert-butyl-1,4-dioxaspiro [4.5] dec-2-yl) diethylamine (EP-A 281842).

根据IUPAC命名的化合物、其制备及其杀真菌作用同样是已知的:(2-氯-5-[1-(3-甲基苄氧基亚氨基)乙基]苄基)氨基甲酸甲酯、(2-氯-5-[1-(6-甲基吡啶-2-基甲氧亚氨基)乙基]苄基)氨基甲酸甲酯(EP-A 12 01 648);2-(邻-((2,5-二甲基苯氧基亚甲基)苯基)-3-甲氧基丙烯酸甲酯(EP-A 226 917);5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)-[1,2,4]三唑并[1,5-a]嘧啶(WO98/46608),3,4-二氯-N-(2-氰基苯基)异噻唑-5-甲酰胺(WO 99/24413),N-(2-{4-[3-(4-氯苯基)丙-2-炔氧基]-3-甲氧苯基}乙基)-2-甲磺酰氨基-3-甲基丁酰胺、N-(2-{4-[3-(4-氯苯基)丙-2-炔氧基]-3-甲氧苯基}乙基)-2-乙磺酰氨基-3-甲基丁酰胺(WO 2004/049804),N-(4'-溴联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-三氟甲基联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-氯-3'-氟联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(3',4'-二氯-4-氟联苯-2-基 Compound according to the IUPAC nomenclature, their preparation and their fungicidal action are likewise known: (2-chloro-5- [1- (3-methyl-benzyloxyimino) ethyl] benzyl) carbamate , (2-chloro-5- [1- (6-methyl-pyridin-2-yl-methoxyimino) ethyl] benzyl) carbamate (EP-A 12 01 648); 2- (ortho - ((2,5-methylene-methylphenoxy) phenyl) -3-methoxyacrylate (EP-A 226 917); 5- chloro-7- (4-methyl-piperidin - 1- yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazolo [1,5-a] pyrimidine (WO98 / 46608), 3,4- dichloro -N- (2- cyanophenyl) isothiazole-5-carboxamide (WO 99/24413), N- (2- {4- [3- (4- chlorophenyl) prop-2-ynyloxy ] -3-methoxy phenyl} ethyl) -2-methanesulfonyl-amino-3-methylbutyramide, N- (2- {4- [3- (4- chlorophenyl) prop-2-ynyl oxy] -3-methoxyphenyl} ethyl) -2- ethanesulfonylamino-3-methylbutyramide (WO 2004/049804), N- (4'- bromo-biphenyl-2-yl) - 4-difluoromethyl-2-methylthiazole-5-carboxamide, N- (4'- trifluoromethyl-biphenyl-2-yl) -4-difluoromethyl-2-methylthiazole-5 - carboxamide, N- (4'- chloro-3'-fluoro-2-yl) -4-difluoromethyl-2-methylthiazole-5-carboxamide, N- (3 ', 4' - dichloro-4-fluoro-2-yl )-3-二氟甲基-1-甲基吡唑-4-甲酰胺(WO 2003/066609)、N-(3′,4′-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺(WO2003/053145);2-丁氧基-6-碘-3-丙基苯并吡喃-4-酮(WO 03/14103);3-[5-(4-氯苯基)-2,3-二甲基异噁唑烷-3-基]吡啶(EP-A 1035122);吲唑磺菌胺,N,N-二甲基-3-(3-溴-6-氟-2-甲基吲哚-1-磺酰基)-[1,2,4]三唑-1-磺酰胺(WO03/053145);3-(4-氯苯基)-3-(2-异丙氧基羰基氨基-3-甲基丁酰氨基)丙酸甲酯(EP-A 1028125);6-(3,4-二氯苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-(4-叔丁基苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-甲基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-乙基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-辛基-[1,2,4]三唑并[1,5-a ) -3-difluoromethyl-1-methylpyrazole-4-carboxamide (WO 2003/066609), N- (3 ', 4'- dichloro-biphenyl-2-yl) - 3-difluoromethyl-1-methylpyrazole-4-carboxamide (WO2003 / 053145); 2- butoxy-6-iodo-3-propyl-benzopyran-4-one (WO 03 / 14103); 3- [5- (4-chlorophenyl) -2,3-dimethyl-isoxazol-3-yl] pyridine (EP-A 1035122); indazol flusulfamide, N, N- dimethyl-3- (3-bromo-6-fluoro-2-methyl-indol-1-sulfonyl) - [1,2,4] triazol-1-sulfonamide (WO03 / 053145); 3- (4-chlorophenyl) -3- (2-isopropoxy-carbonyl-amino-3-methylbutyrylamino) propionate (EP-A 1028125); 6- (3,4- dichlorophenyl ) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6- (4-tert-butyl-phenyl) -5-methyl - [1 , 2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] pyrazolo [1,5-a] pyrimidin-7-ylamine, 5-methyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, methyl-5-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-octyl-ethyl-5 - [l, 2,4 ] triazolo [1,5-a] pyrimidin-7-ylamine, 5-ethyl-6-octyl - [1,2,4] triazolo [1,5-a ]嘧啶-7-基胺、5-乙基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-丙基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲氧基甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-三氟甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺和5-三氟甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺已知于EP-A 71 792;EP-A 141 317;WO2003/009687;WO 05/087771;WO 2005/087772;WO 2005/087773;WO2006/087325;和/或WO 2006/092428; ] Pyrimidin-7-ylamine, 5-ethyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-yl amine, 6-octyl-5-propyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methoxy-6-octyl - [ 2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-octyl-5-trifluoromethyl - [1,2,4] triazolo [1,5- a] pyrimidin-7-ylamine and 5-trifluoromethyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidine - 7- ylamine known from EP-A 71 792; EP-A 141 317; WO2003 / 009687; WO 05/087771; WO 2005/087772; WO 2005/087773; WO2006 / 087325; and / or WO 2006/092428;

N-(2′,4′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺、N-(3′,5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3 N- (2 ', 4'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2', 4'- dichloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- difluoro-biphenyl-2-yl) 3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- dichloro-biphenyl-2-yl) -3-difluoro-methyl-1 - methyl -1H- pyrazole-4-carboxamide; N- (2 ', 5'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazol - 4-carboxamide; N- (2 ', 5'- dichloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 5'-difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2', 5'- dichloro-biphenyl 2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (3 ', 5'- difluoro-biphenyl-2-yl) -1- -1H- pyrazole-3-trifluoromethyl-4-carboxamide; N- (3 ', 5'- dichloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl - 1H- pyrazole-4-carboxamide, N- (3 ', 5'- difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide ; N- (3 ', 5'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (3 ′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺; '- fluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide;

N-(3′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′-氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺; N- (3'- chloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3'- fluoro-biphenyl-2-yl ) -3-fluoro-1-methyl -1H- pyrazole-4-carboxamide;

N-(3′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′-氟联苯-2-基)-3--二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟-4′-氯-5′-甲基联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-3-氯氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)-苯基]-3-二氟甲基-1-甲基-1H- N- (3'- chloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-2-yl ) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2'- chloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-2-yl) -3---difluoro-1-methyl -1H- pyrazole-4-carboxamide; N - (2'-chloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N-(2'-fluoro-4'-chloro-5 '- methylbiphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3', 4 ', 5'- trifluoromethyl-biphenyl 2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-2-yl) - 3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3 - difluoromethyl -1H- pyrazole-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-2-yl) -3-chlorofluoromethyl-1-methyl - 1H- pyrazole-4-carboxamide; N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) phenyl] -1-methyl-3 - 1H- pyrazole-4-carboxamide; N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) - phenyl] -3-difluoromethyl-1-methyl -1H- 吡唑-4-甲酰胺, Pyrazole-4-carboxamide,

N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;4-甲酸-N-[2-(1,1,2,2-四氟乙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,2-四氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(4′-(三氟甲硫基)联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;以及N-(4′-(三氟甲硫基)联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺已知于WO 2006/087343、WO 2001/42223、WO 2005/34628、WO 2005/123689、WO 2005/123690、WO 2006/120219、WO 2007/017450和/或EP申请号06123463.9。 N- [2- (2- chloro-1,1,2-trifluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- [2- (2-chloro-1,1,2-trifluoroethoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; 4- carboxylic acid - N- [2- (1,1,2,2- tetrafluoroethoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- [2 - (1,1,2,2-tetrafluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (4 '- (three fluoro-methylthio) biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; and N- (4 '- (trifluoromethylthio) biphenyl phenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide known from WO 2006/087343, WO 2001/42223, WO 2005/34628, WO 2005/123689 , WO 2005/123690, WO 2006/120219, WO 2007/017450 and / or EP application No. 06123463.9.

为了降低已知化合物的施用率并拓宽其活性谱,本发明的目的是提供在活性化合物的总施用量降低下对害虫具有改进活性的混合物。 In order to reduce the application rates known compounds and widening of the activity spectrum, an object of the present invention is to provide a mixture having an improved activity against pests at a reduced total amount of active compound.

出现在害虫防治领域内的一个典型问题为需要降低活性成分的剂量率以在仍允许有效的害虫防治时减少或避免不利的环境或毒物学影响。 One typical problem arising in the field of pest control is necessary to reduce the dose of the active ingredient to reduce or avoid unfavorable environmental or toxicological impact still allowing effective pest control time.

关于本发明,术语害虫包括动物害虫和有害真菌。 About the present invention, the term pests include harmful fungi and animal pests.

遇到的另一问题涉及需要对宽范围害虫有效的害虫防治剂。 Another problem encountered concerns the need for a wide range of pests and effective pest control agents.

还存在对结合了击倒(knock down)活性与长期防治,即快速作用与长久持续作用的害虫防治剂的需要。 There, the need for a combination of down (knock down) activity and long-term prevention of pest control agents, fast action with long lasting effects.

关于使用农药的另一困难为,反复和单一施用单独的农药化合物在很多情况下导致害虫出现快速选择性,即意味着对所述活性化合物具有天然或适应的耐药性的害虫和有害真菌。 Another difficulty on the use of pesticides, for the single and repeated administration of the individual pesticidal compound leads to selective rapid emergence of pests, which means natural or drug-resistant pests and harmful fungi adaptation of the active compound in many cases. 为此,存在对有助于防止或克服耐药性的害虫防治剂的需要。 For this reason, there is a need to help prevent or overcome resistance to the pest control agent.

为此,本发明的目的为提供解决了降低剂量率和/或增强了活性谱和/或结合了击倒活性和长期防治和/或耐药性管理的问题的农药混合物。 To this end, an object of the present invention to provide a solution mixture of reducing the dosage rate of pesticide and / or enhance the activity spectrum and / or a combination of knockdown activity and long-term problems prevention and / or resistance management.

我们发现该目的部分或全部由开头所定义的活性化合物的组合实现。 We have found that the combination of some or all object defined at the outset by the implementation of the active compound. 此外,我们发现与单一化合物可能的防治率相比,同时,即联合或分开施用化合物I和两种或更多种化合物II或III可以增强对害虫,即动物害虫和有害真菌的防治(协同增效混合物)。 Furthermore, we have found that compared to a single compound may be the prevention of, simultaneously, that is joint or separate administration of two or more compounds I and II or III compounds may enhance pest, i.e. harmful fungi and animal pests prevention (synergy by efficiency mixture).

在对式I所给符号的定义中,使用通常代表下列取代基的集合性术语: In the definition of Formula I given symbols, using the following collective terms usually represents a substituent:

烷基:具有1-6,优选至多4个碳原子的饱和直链或支化烃基,例如C 1 -C 4烷基,如甲基、乙基、丙基、1-甲基乙基、丁基、1-甲基丙基、2-甲基丙基、1,1-二甲基乙基。 Alkyl: 1-6, most preferably straight-chain or branched saturated hydrocarbon group having 4 carbon atoms, for example C 1 -C 4 alkyl such as methyl, ethyl, propyl, 1-methylethyl, butyl group, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl.

式I尤其代表其中R为甲基、乙基、正丙基、异丙基、正丁基、仲丁基或叔丁基的化合物。 In particular, representative of formula I wherein R is methyl, ethyl, n-propyl, isopropyl, n-butyl, sec-butyl or tert-butyl compound.

式I尤其代表其中B 1为氯和氰基的化合物。 In particular, representative of formula I compound wherein B 1 is chloro and cyano.

式I尤其代表其中B 2为溴的化合物。 In particular, a compound represented by formula I wherein B 2 is a bromine.

一个实施方案代表其中R为氢的式I化合物。 Representative of one embodiment of the compounds of formula I R wherein is hydrogen. 另一实施方案代表其中R为C 1 -C 4烷基的式I化合物。 Another embodiment is representative of compound of the formula wherein R is C I 1 -C 4 alkyl.

尤其考虑到它们在本发明混合物中的用途,优选汇集在下表中的化合物I: Particularly in view of their use in the mixtures of the present invention, preferably the compounds together in the following Table I:

表I Table I

序号 No. B 1 B 1 B 2 B 2 R R I-1 I-1 H H Br Br H H I-2 I-2 CN CN Br Br H H I-3 I-3 Cl Cl Br Br H H I-4 I-4 H H CF 3 CF 3 H H I-5 I-5 CN CN CF 3 CF 3 H H I-6 I-6 Cl Cl CF 3 CF 3 H H I-7 I-7 H H Br Br CH 3 CH 3 I-8 I-8 CN CN Br Br CH 3 CH 3 I-9 I-9 Cl Cl Br Br CH 3 CH 3 I-10 I-10 H H CF 3 CF 3 CH 3 CH 3 I-11 I-11 CN CN CF 3 CF 3 CH 3 CH 3 I-12 I-12 Cl Cl CF 3 CF 3 CH 3 CH 3 I-13 I-13 H H Br Br CH 2 CH 3 CH 2 CH 3 I-14 I-14 CN CN Br Br CH 2 CH 3 CH 2 CH 3 I-15 I-15 Cl Cl Br Br CH 2 CH 3 CH 2 CH 3 I-16 I-16 H H CF 3 CF 3 CH 2 CH 3 CH 2 CH 3 I-17 I-17 CN CN CF 3 CF 3 CH 2 CH 3 CH 2 CH 3 I-18 I-18 Cl Cl CF 3 CF 3 CH 2 CH 3 CH 2 CH 3 I-19 I-19 H H Br Br CH 2 CH 2 CH 3 CH 2 CH 2 CH 3 I-20 I-20 CN CN Br Br CH 2 CH 2 CH 3 CH 2 CH 2 CH 3 I-21 I-21 Cl Cl Br Br CH 2 CH 2 CH 3 CH 2 CH 2 CH 3 I-22 I-22 H H CF 3 CF 3 CH 2 CH 2 CH 3 CH 2 CH 2 CH 3 I-23 I-23 CN CN CF 3 CF 3 CH 2 CH 2 CH 3 CH 2 CH 2 CH 3 I-24 I-24 Cl Cl CF 3 CF 3 CH 2 CH 2 CH 3 CH 2 CH 2 CH 3 I-25 I-25 H H Br Br CH(CH 3 ) 2 CH (CH 3) 2 I-26 I-26 CN CN Br Br CH(CH 3 ) 2 CH (CH 3) 2 I-27 I-27 Cl Cl Br Br CH(CH 3 ) 2 CH (CH 3) 2 I-28 I-28 H H CF 3 CF 3 CH(CH 3 ) 2 CH (CH 3) 2 I-29 I-29 CN CN CF 3 CF 3 CH(CH 3 ) 2 CH (CH 3) 2 I-30 I-30 Cl Cl CF 3 CF 3 CH(CH 3 ) 2 CH (CH 3) 2

特别优选化合物I-2和I-3中任一个与开头定义的化合物II和III中任一个的组合。 Particularly preferred combination of compounds I-2 and I-3 as defined in any one of compounds II and III at the beginning of any one. 特别优选化合物I-3,3-溴-4′-氯-1-(3-氯-2-吡啶基)-2′-甲基-6′-(甲基氨基甲酰基)吡唑-5-甲酰苯胺(carboxanilide),其暂时的ISO名为氯虫酰胺(chlorantraniliprole)。 Particularly preferred compounds I-3,3- bromo-4'-chloro-1- (3-chloro-2-pyridyl) -2'-methyl-6 '- (methylcarbamoyl) pyrazol-5 formanilide (carboxanilide), which is temporarily called ISO chlorantraniliprole (chlorantraniliprole).

本发明的优选实施方案提供了化合物I,尤其是化合物I-2和I-3中任一个与选自下列的化合物II的三元混合物: Preferred embodiments of the present invention provides a compound I, in particular any I-2 I-3 and a compound selected from the group consisting of a ternary mixture of compound II:

唑类,尤其是:氰霜唑、烯菌灵、稻瘟酯、丙氯灵、氟菌唑; Azoles, especially: cyazofamid, alkenyl benomyl, pefurazoate, prochloraz, triflumizole;

嗜球果伞素,尤其是:腈嘧菌酯、醚菌胺、烯肟菌酯、叉氨苯酰胺、肟醚菌胺; Strobilurins, in particular: azoxystrobin, dimoxystrobin, enestroburin, metominostrobin, orysastrobin;

羧酰胺,尤其是:氯环丙酰胺、双氯氰菌胺、氟酰胺、呋吡唑灵、双炔酰菌胺、丙氧灭绣胺、甲霜灵、精甲霜灵、甲呋酰胺、噁霜灵、氧化萎锈灵、吡噻菌胺、溴氟唑菌、噻酰菌胺; Carboxamide, in particular: carpropamid, diclocymet, flutolanil, furosemide pyrazole spirit, mandipropamid amines, amine embroidery off propoxycarbonyl, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil;

杂环化合物,尤其是:吲唑磺菌胺、敌菌灵、哒菌清、噁唑酮菌、咪唑菌酮、异噻菌酮、噻菌灵、咯喹酮、丙氧喹啉、三环唑。 Heterocyclic compounds, in particular: indazol flusulfamide, anilazine, diclomezine, oxazolone bacteria, fenamidone, isothiazole, cycloheximide, thiabendazole, pyroquilon, proquinazid, tricyclo azole.

本发明的另一优选实施方案提供了腈嘧菌酯与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of azoxystrobin compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了氯环丙酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture with any carpropamid compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了双氯氰菌胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture with any of diclocymet compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了呋吡唑灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of furosemide pyrazol spirit and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了肟醚菌胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of orysastrobin and compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了噻菌灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of thiabendazole and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了噻酰菌胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture with any tiadinil compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了溴氟唑菌与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of thifluzamide compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了三环唑与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of tricyclazole in Table I together with a compound of formula I a.

本发明的另一优选实施方案提供了氟菌唑与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of triflumizole and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了咯喹酮与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of pyroquilon and compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了醚菌胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture with any dimoxystrobin compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了氟嘧菌酯与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides any mixture of fluoxastrobin compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了啶氧菌酯与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides any mixture of picoxystrobin and compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了唑菌胺酯与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of pyraclostrobin are compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了肟菌酯与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides any mixture trifloxystrobin compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了双苯三唑醇与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture with any bitertanol compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了环唑醇与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of cyproconazole and any compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了氧唑菌与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of epoxiconazole and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了喹唑菌酮与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture fluquinconazole and any compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了粉唑醇与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of flutriafol and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了环戊唑菌与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides any mixture of metconazole and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了环戊唑醇与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of ipconazole and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了丙硫菌唑与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of prothioconazole with either compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了丙氯灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of prochloraz and any compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了唑菌醇与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of triadimenol and compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了戊唑醇与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of tebuconazole to either compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了噁醚唑与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of difenoconazole and any compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了涕必灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of thiabendazole in Table I together with a compound of formula I a.

本发明的另一优选实施方案提供了丙环唑与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of propiconazole and compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了烯菌灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any ethylenically benomyl and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了氟噁菌与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides any mixture of fludioxonil compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了环丙嘧啶与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of cyprodinil and any compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了二甲嘧菌胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of pyrimethanil and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了双胍盐与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of guazatine and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了烯酰吗啉与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides any mixture of dimethomorph in Table I is a compound of Formula I and pooled.

本发明的另一优选实施方案提供了丁苯吗啉与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of fenpropimorph in Table I is a compound of Formula I and pooled.

本发明的另一优选实施方案提供了苯锈啶与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides mixtures of fenpropidin and any compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了福美双与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides any mixture of thiram and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了克菌丹与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of captan in Table I together with a compound of formula I a.

本发明的另一优选实施方案提供了甲霜灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of metalaxyl in Table I together with a compound of formula I a.

本发明的另一优选实施方案提供了精甲霜灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of mefenoxam and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了甲基托布津与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of thiophanate methyl with either compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了百菌清与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of chlorothalonil and compiled in Table I the compounds of Formula I a.

本发明的另一优选实施方案提供了萎锈灵与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of carboxin in Table I together with a compound of formula I a.

本发明的另一优选实施方案提供了啶酰菌胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of boscalid and any compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了噻唑菌胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of ethaboxam and compiled in Table I is a compound of formula I.

本发明的另一优选实施方案提供了N-(3′,4′-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- (3 ', 4'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methylpyrazole-4-carboxylic acid a mixture of compounds of formula I with an amide according to any compiled in table I.

本发明的另一优选实施方案提供了N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- (3 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-trifluoromethyl-pyrazol -4 -1H- - a mixture of a compound of formula I together with any of the carboxamide in table I.

本发明的另一优选实施方案提供了N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- (3 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-difluoromethyl--1H- pyrazol -4 - a mixture of a compound of formula I together with any of the carboxamide in table I.

本发明的另一优选实施方案提供了N-(2′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- (2 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-difluoromethyl--1H- pyrazol -4 - a mixture of a compound of formula I together with any of the carboxamide in table I.

本发明的另一优选实施方案提供了N-(3′,4′,5′-三氟联苯-2-基)-3-氯氟甲基-1-甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- (3 ', 4', 5'- trifluoromethyl-2-yl) -3-chlorofluoromethyl-1-methyl -1H- pyrazol -4 - a mixture of a compound of formula I together with any of the carboxamide in table I.

本发明的另一优选实施方案提供了N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) phenyl] -1-methyl-3 - 1H- pyrazole-4-carboxamide and compiled in table I in the mixture of compounds of formula I a.

本发明的另一优选实施方案提供了N-[2-(1,1,2,3,3,3-六氟丙氧基)-苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) - phenyl] -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide and compiled in table I in the mixture of compounds of formula I a.

本发明的另一优选实施方案提供了N-[2-(1,1,2,2-四氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- [2- (1,1,2,2- tetrafluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole a mixture of compounds of formula I-4- carboxamide and any compiled in table I.

本发明的另一优选实施方案提供了N-(4′-(三氟甲硫基)联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazol-4 a mixture of compounds of formula I together with any of the carboxamide in table I.

本发明的另一优选实施方案提供了N-(4′-(三氟甲硫基)联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -1-methyl-3-trifluoromethyl-pyrazol-4 -1H- a mixture of compounds of formula I together with any of the carboxamide in table I.

本发明的另一优选实施方案提供了5-氟-1,3-二甲基-1H-吡唑-4-甲酸[2-(1,2-二甲基-丙基)-苯基]-酰胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a 5-fluoro-1,3-dimethyl--1H- pyrazole-4-carboxylic acid [2- (1,2-dimethyl - propyl) - phenyl] - a mixture of compounds of formula I with an amide according to any compiled in table I.

本发明的另一优选实施方案提供了5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)-[1,2,4]三唑并[1,5-a]嘧啶与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4 ] triazolo 1,5-a] pyrimidine of formula with either a compiled in table I is the compound I [.

本发明的另一优选实施方案提供了6-(3,4-二氯-苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the invention provides 6- (3,4-dichloro - phenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7 a mixture of compounds of formula I and any amine groups compiled in table I.

本发明的另一优选实施方案提供了6-(4-叔丁基苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the invention provides 6- (4-tert-butyl-phenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and any mixture of compounds I compiled in table I is a formula.

本发明的另一优选实施方案提供了5-甲基-6-(3,5,5-三甲基-己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a 5-methyl-6- (3,5,5-trimethyl - hexyl-yl) - [1,2,4] triazolo [1,5-a] pyrimidine - 7- a mixture of compounds of formula I and any amine groups compiled in table I.

本发明的另一优选实施方案提供了5-甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides octyl methyl-6 - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and compiled in Table I a mixture of compounds of formula I according to any.

本发明的另一优选实施方案提供了6-甲基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides 6-methyl-5-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and compiled in Table I a mixture of compounds of formula I according to any.

本发明的另一优选实施方案提供了6-乙基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides 6-ethyl-5-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and compiled in Table I a mixture of compounds of formula I according to any.

本发明的另一优选实施方案提供了5-乙基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provide ethyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and compiled in Table I a mixture of compounds of formula I according to any.

本发明的另一优选实施方案提供了5-乙基-6-(3,5,5-三甲基-己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a 5-ethyl-6- (3,5,5-trimethyl - hexyl-yl) - [1,2,4] triazolo [1,5-a] pyrimidine - 7- a mixture of compounds of formula I and any amine groups compiled in table I.

本发明的另一优选实施方案提供了6-辛基-5-丙基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides 6-octyl-5-propyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and compiled in Table I a mixture of compounds of formula I according to any.

本发明的另一优选实施方案提供了5-甲氧基甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a 5-methoxy-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and summarized in Table a mixture of compounds of the formula I according to any of I.

本发明的另一优选实施方案提供了6-辛基-5-三氟甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides 6-octyl-5-trifluoromethyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and are summarized in Table I a mixture of compounds of formula I is any.

本发明的另一优选实施方案提供了5-三氟甲基-6-(3,5,5-三甲基-己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a 5-trifluoromethyl-6- (3,5,5-trimethyl - hexyl-yl) - [1,2,4] triazolo [1,5-a] the mixture in table I according to any one of the compounds of formula I together with ylamine.

本发明的另一优选实施方案提供了唑菌嗪与汇集在表I中的任一式I化合物的混合物。 Another preferred embodiment of the present invention provides a mixture of any of triazoxide in Table I of a compound of formula I together.

包含式I化合物作为组分1、杀真菌剂II作为组分2和另一杀真菌剂作为组分3的优选的三元混合物汇集在下表中。 Comprising as component a compound of formula I, II fungicides together as component 2 and a further fungicide component is preferably a ternary mixture of the following Table 3.

如下组合,其中组分1为化合物I-2,以及组分2和3的组合的对各三元组合而言对应于表A的一行。 The following composition, wherein the component is a compound I-2, and the row components of the combination 2 and 3 to each ternary compositions of Table A corresponding to the terms.

如下组合,其中组分1为化合物I-3,以及组分2和3的组合的对各三元组合而言对应于表A的一行。 The following composition, wherein component a compound I-3, and corresponding to a line of Table A for each component in terms of ternary compositions of 3 and 2 combinations.

如下缩写用在表A中: The following abbreviations are used in Table A:

B1:N-(3′,4′-二氯-4-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺, B1: N- (3 ', 4'- dichloro-4-fluoro-2-yl) -3-difluoromethyl-1-methylpyrazole-4-carboxamide,

B2:N-(3′,4′-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺; B2: N- (3 ', 4'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methylpyrazole-4-carboxamide;

B3:3,4-二氯-N-(2-氰基苯基)异噻唑-5-甲酰胺; B3: 3,4- Dichloro -N- (2- cyanophenyl) isothiazole-5-carboxamide;

B4:N-(3′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺; B4: N- (3 ', 5'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide;

B5:N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺; B5: N- (3 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide;

B6:N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺; B6: N- (3 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-difluoromethyl--1H- pyrazole-4-carboxamide;

B7:N-(2′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺; B7: N- (2 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-difluoromethyl--1H- pyrazole-4-carboxamide;

B8:N-(3′,4′,5′-三氟联苯-2-基)-3-氯氟甲基-1-甲基-1H-吡唑-4-甲酰胺; B8: N- (3 ', 4', 5'- trifluoromethyl-2-yl) -3-chlorofluoromethyl-1-methyl -1H- pyrazole-4-carboxamide;

B9:N-[2-(1,1,2,3,3,3-六氟丙氧基)-苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺, B9: N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) - phenyl] -3-difluoromethyl-1-methyl -1H- pyrazol-4 carboxamide,

B10:N-[2-(1,1,2,2-四氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺; B10: N- [2- (1,1,2,2- tetrafluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide;

B11:N-(4′-(三氟甲硫基)联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺; B11: N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide;

B12:N-(4′-(三氟甲硫基)联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺; B12: N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide;

B13:5-氟-1,3-二甲基-1H-吡唑-4-甲酸[2-(1,2-二甲基丙基)-苯基]-酰胺; B13: 5- fluoro-1,3-dimethyl--1H- pyrazole-4-carboxylic acid [2- (1,2-dimethylpropyl) - phenyl] - amide;

B14:5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)-[1,2,4]三唑并[1,5-a]嘧啶; B14: 5- chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazolo [1,5- -a] pyrimidine;

B15:6-(3,4-二氯-苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B15: 6- (3,4- dichloro - phenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B16:6-(4-叔丁基苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B16: 6- (4- tert-butyl-phenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B17:5-甲基-6-(3,5,5-三甲基-己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B17: 5- methyl-6- (3,5,5-trimethyl - hexyl-yl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B18:5-甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B18: 5- methyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B19:6-甲基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B19: 6- methyl-5-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B20:6-乙基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B20: 6- octyl-ethyl-5 - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B21:5-乙基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B21: 5- ethyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B22:5-乙基-6-(3,5,5-三甲基-己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B22: 5- ethyl-6- (3,5,5-trimethyl - hexyl-yl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B23:6-辛基-5-丙基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B23: 6- 5-propyl-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B24:5-甲氧基甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B24: 5- octyl-methoxymethyl-6 - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B25:6-辛基-5-三氟甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺; B25: 6- octyl-5-trifluoromethyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine;

B26:5-三氟甲基-6-(3,5,5-三甲基-己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺。 B26: 5- trifluoromethyl-6- (3,5,5-trimethyl - hexyl-yl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine.

表A Table A

序号 No. 组分2 Component 2 组分3 Component 3 A-1 A-1 噁醚唑 Difenoconazole 环唑醇 Cyproconazole A-2 A-2 噁醚唑 Difenoconazole 环戊唑醇 Ipconazole A-3 A-3 噁醚唑 Difenoconazole 环戊唑菌 Metconazole A-4 A-4 噁醚唑 Difenoconazole 唑菌嗪 Triazoxide A-5 A-5 噁醚唑 Difenoconazole 戊叉唑菌 Triticonazole A-6 A-6 噁醚唑 Difenoconazole 腈嘧菌酯 Azoxystrobin A-7 A-7 噁醚唑 Difenoconazole 醚菌胺 Dimoxystrobin A-8 A-8 噁醚唑 Difenoconazole 氟嘧菌酯 Fluoxastrobin A-9 A-9 噁醚唑 Difenoconazole 亚胺菌 Kresoxim A-10 A-10 噁醚唑 Difenoconazole 叉氨苯酰胺 Metominostrobin A-11 A-11 噁醚唑 Difenoconazole 肟醚菌胺 Orysastrobin A-12 A-12 噁醚唑 Difenoconazole 啶氧菌酯 Picoxystrobin A-13 A-13 噁醚唑 Difenoconazole 唑菌胺酯 Pyraclostrobin A-14 A-14 噁醚唑 Difenoconazole 肟菌酯 Trifloxystrobin A-15 A-15 噁醚唑 Difenoconazole 萎锈灵 Carboxin A-16 A-16 噁醚唑 Difenoconazole 啶酰菌胺 Boscalid A-17 A-17 噁醚唑 Difenoconazole B1 B1 A-18 A-18 噁醚唑 Difenoconazole B2 B2 A-19 A-19 噁醚唑 Difenoconazole B3 B3 A-20 A-20 噁醚唑 Difenoconazole B4 B4 A-21 A-21 噁醚唑 Difenoconazole B5 B5 A-22 A-22 噁醚唑 Difenoconazole B6 B6 A-23 A-23 噁醚唑 Difenoconazole B7 B7 A-24 A-24 噁醚唑 Difenoconazole B8 B8 A-25 A-25 噁醚唑 Difenoconazole B9 B9 A-26 A-26 噁醚唑 Difenoconazole B10 B10 A-27 A-27 噁醚唑 Difenoconazole B11 B11 A-28 A-28 噁醚唑 Difenoconazole B12 B12 A-29 A-29 噁醚唑 Difenoconazole B13 B13 A-30 A-30 噁醚唑 Difenoconazole 精甲霜灵 Mefenoxam

序号 No. 组分2 Component 2 组分3 Component 3 A-31 A-31 噁醚唑 Difenoconazole 代森锰锌 Mancozeb A-32 A-32 噁醚唑 Difenoconazole 代森锰 Maneb A-33 A-33 噁醚唑 Difenoconazole 代森联 Metiram A-34 A-34 噁醚唑 Difenoconazole 甲基代森锌 Propineb A-35 A-35 噁醚唑 Difenoconazole 福美双 Thiram A-36 A-36 噁醚唑 Difenoconazole 代森锌 Zineb A-37 A-37 噁醚唑 Difenoconazole 福美锌 Ziram A-38 A-38 氧唑菌 Epoxiconazole 异丙定 Iprodione A-39 A-39 氧唑菌 Epoxiconazole 丙氯灵 Prochloraz A-40 A-40 氧唑菌 Epoxiconazole 二甲嘧菌胺 Pyrimethanil A-41 A-41 氧唑菌 Epoxiconazole 唑菌嗪 Triazoxide A-42 A-42 氧唑菌 Epoxiconazole 腈嘧菌酯 Azoxystrobin A-43 A-43 氧唑菌 Epoxiconazole 醚菌胺 Dimoxystrobin A-44 A-44 氧唑菌 Epoxiconazole 氟嘧菌酯 Fluoxastrobin A-45 A-45 氧唑菌 Epoxiconazole 亚胺菌 Kresoxim A-46 A-46 氧唑菌 Epoxiconazole 叉氨苯酰胺 Metominostrobin A-47 A-47 氧唑菌 Epoxiconazole 肟醚菌胺 Orysastrobin A-48 A-48 氧唑菌 Epoxiconazole 啶氧菌酯 Picoxystrobin A-49 A-49 氧唑菌 Epoxiconazole 唑菌胺酯 Pyraclostrobin A-50 A-50 氧唑菌 Epoxiconazole 肟菌酯 Trifloxystrobin A-51 A-51 氧唑菌 Epoxiconazole 啶酰菌胺 Boscalid A-52 A-52 氧唑菌 Epoxiconazole B1 B1 A-53 A-53 氧唑菌 Epoxiconazole B2 B2 A-54 A-54 氧唑菌 Epoxiconazole B3 B3 A-55 A-55 氧唑菌 Epoxiconazole B4 B4 A-56 A-56 氧唑菌 Epoxiconazole B5 B5 A-57 A-57 氧唑菌 Epoxiconazole B6 B6 A-58 A-58 氧唑菌 Epoxiconazole B7 B7 A-59 A-59 氧唑菌 Epoxiconazole B8 B8 A-60 A-60 氧唑菌 Epoxiconazole B9 B9 A-61 A-61 氧唑菌 Epoxiconazole B10 B10 A-62 A-62 氧唑菌 Epoxiconazole B11 B11 A-63 A-63 氧唑菌 Epoxiconazole B12 B12 A-64 A-64 氧唑菌 Epoxiconazole B13 B13 A-65 A-65 氧唑菌 Epoxiconazole B14 B14 A-66 A-66 氧唑菌 Epoxiconazole B15 B15

序号 No. 组分2 Component 2 组分3 Component 3 A-67 A-67 氧唑菌 Epoxiconazole B16 B16 A-68 A-68 氧唑菌 Epoxiconazole B17 B17 A-69 A-69 氧唑菌 Epoxiconazole B18 B18 A-70 A-70 氧唑菌 Epoxiconazole B19 B19 A-71 A-71 氧唑菌 Epoxiconazole B20 B20 A-72 A-72 氧唑菌 Epoxiconazole B21 B21 A-73 A-73 氧唑菌 Epoxiconazole B22 B22 A-74 A-74 氧唑菌 Epoxiconazole B23 B23 A-75 A-75 氧唑菌 Epoxiconazole B24 B24 A-76 A-76 氧唑菌 Epoxiconazole B25 B25 A-77 A-77 氧唑菌 Epoxiconazole B26 B26 A-78 A-78 氧唑菌 Epoxiconazole 代森锰锌 Mancozeb A-79 A-79 氧唑菌 Epoxiconazole 代森锰 Maneb A-80 A-80 氧唑菌 Epoxiconazole 代森联 Metiram A-81 A-81 氧唑菌 Epoxiconazole 甲基代森锌 Propineb A-82 A-82 氧唑菌 Epoxiconazole 福美双 Thiram A-83 A-83 氧唑菌 Epoxiconazole 代森锌 Zineb A-84 A-84 氧唑菌 Epoxiconazole 福美锌 Ziram A-85 A-85 喹唑菌酮 Fluquinconazole 腈嘧菌酯 Azoxystrobin A-86 A-86 喹唑菌酮 Fluquinconazole 醚菌胺 Dimoxystrobin A-87 A-87 喹唑菌酮 Fluquinconazole 氟嘧菌酯 Fluoxastrobin A-88 A-88 喹唑菌酮 Fluquinconazole 亚胺菌 Kresoxim A-89 A-89 喹唑菌酮 Fluquinconazole 叉氨苯酰胺 Metominostrobin A-90 A-90 喹唑菌酮 Fluquinconazole 肟醚菌胺 Orysastrobin A-91 A-91 喹唑菌酮 Fluquinconazole 啶氧菌酯 Picoxystrobin A-92 A-92 喹唑菌酮 Fluquinconazole 唑菌胺酯 Pyraclostrobin A-93 A-93 喹唑菌酮 Fluquinconazole 肟菌酯 Trifloxystrobin A-94 A-94 喹唑菌酮 Fluquinconazole 丙氯灵 Prochloraz A-95 A-95 喹唑菌酮 Fluquinconazole 唑菌嗪 Triazoxide A-96 A-96 喹唑菌酮 Fluquinconazole 啶酰菌胺 Boscalid A-97 A-97 喹唑菌酮 Fluquinconazole B1 B1 A-98 A-98 喹唑菌酮 Fluquinconazole B2 B2 A-99 A-99 喹唑菌酮 Fluquinconazole B3 B3 A-100 A-100 喹唑菌酮 Fluquinconazole B4 B4 A-101 A-101 喹唑菌酮 Fluquinconazole B5 B5 A-102 A-102 喹唑菌酮 Fluquinconazole B6 B6

序号 No. 组分2 Component 2 组分3 Component 3 A-103 A-103 喹唑菌酮 Fluquinconazole B7 B7 A-104 A-104 喹唑菌酮 Fluquinconazole B8 B8 A-105 A-105 喹唑菌酮 Fluquinconazole B9 B9 A-106 A-106 喹唑菌酮 Fluquinconazole B10 B10 A-107 A-107 喹唑菌酮 Fluquinconazole B11 B11 A-108 A-108 喹唑菌酮 Fluquinconazole B12 B12 A-109 A-109 喹唑菌酮 Fluquinconazole B13 B13 A-110 A-110 喹唑菌酮 Fluquinconazole B14 B14 A-111 A-111 喹唑菌酮 Fluquinconazole B15 B15 A-112 A-112 喹唑菌酮 Fluquinconazole B16 B16 A-113 A-113 喹唑菌酮 Fluquinconazole B17 B17 A-114 A-114 喹唑菌酮 Fluquinconazole B18 B18 A-115 A-115 喹唑菌酮 Fluquinconazole B19 B19 A-116 A-116 喹唑菌酮 Fluquinconazole B20 B20 A-117 A-117 喹唑菌酮 Fluquinconazole B21 B21 A-118 A-118 喹唑菌酮 Fluquinconazole B22 B22 A-119 A-119 喹唑菌酮 Fluquinconazole B23 B23 A-120 A-120 喹唑菌酮 Fluquinconazole B24 B24 A-121 A-121 喹唑菌酮 Fluquinconazole B25 B25 A-122 A-122 喹唑菌酮 Fluquinconazole B26 B26 A-123 A-123 环戊唑菌 Metconazole 啶酰菌胺 Boscalid A-124 A-124 环戊唑菌 Metconazole B1 B1 A-125 A-125 环戊唑菌 Metconazole B2 B2 A-126 A-126 环戊唑菌 Metconazole B3 B3 A-127 A-127 环戊唑菌 Metconazole B4 B4 A-128 A-128 环戊唑菌 Metconazole B5 B5 A-129 A-129 环戊唑菌 Metconazole B6 B6 A-130 A-130 环戊唑菌 Metconazole B7 B7 A-131 A-131 环戊唑菌 Metconazole B8 B8 A-132 A-132 环戊唑菌 Metconazole B9 B9 A-133 A-133 环戊唑菌 Metconazole B10 B10 A-134 A-134 环戊唑菌 Metconazole B11 B11 A-135 A-135 环戊唑菌 Metconazole B12 B12 A-136 A-136 环戊唑菌 Metconazole B13 B13 A-137 A-137 环戊唑菌 Metconazole B14 B14 A-138 A-138 丙氯灵 Prochloraz 甲霜灵 Metalaxyl

序号 No. 组分2 Component 2 组分3 Component 3 A-139 A-139 丙氯灵 Prochloraz 戊叉唑菌 Triticonazole A-140 A-140 丙氯灵 Prochloraz 环戊唑醇 Ipconazole A-141 A-141 丙氯灵 Prochloraz 环戊唑菌 Metconazole A-142 A-142 丙硫菌唑 Prothioconazole 腈嘧菌酯 Azoxystrobin A-143 A-143 丙硫菌唑 Prothioconazole 醚菌胺 Dimoxystrobin A-144 A-144 丙硫菌唑 Prothioconazole 氟嘧菌酯 Fluoxastrobin A-145 A-145 丙硫菌唑 Prothioconazole 亚胺菌 Kresoxim A-146 A-146 丙硫菌唑 Prothioconazole 叉氨苯酰胺 Metominostrobin A-147 A-147 丙硫菌唑 Prothioconazole 肟醚菌胺 Orysastrobin A-148 A-148 丙硫菌唑 Prothioconazole 啶氧菌酯 Picoxystrobin A-149 A-149 丙硫菌唑 Prothioconazole 唑菌胺酯 Pyraclostrobin A-150 A-150 丙硫菌唑 Prothioconazole 肟菌酯 Trifloxystrobin A-151 A-151 丙硫菌唑 Prothioconazole 环戊唑醇 Ipconazole A-152 A-152 丙硫菌唑 Prothioconazole 环戊唑菌 Metconazole A-153 A-153 丙硫菌唑 Prothioconazole 丙氯灵 Prochloraz A-154 A-154 丙硫菌唑 Prothioconazole 戊唑醇 Tebuconazole A-155 A-155 丙硫菌唑 Prothioconazole 唑菌嗪 Triazoxide A-156 A-156 丙硫菌唑 Prothioconazole 戊叉唑菌 Triticonazole A-157 A-157 丙硫菌唑 Prothioconazole 甲霜灵 Metalaxyl A-158 A-158 丙硫菌唑 Prothioconazole 代森锰锌 Mancozeb A-159 A-159 丙硫菌唑 Prothioconazole 代森锰 Maneb A-160 A-160 丙硫菌唑 Prothioconazole 代森联 Metiram A-161 A-161 丙硫菌唑 Prothioconazole 甲基代森锌 Propineb A-162 A-162 丙硫菌唑 Prothioconazole 福美双 Thiram A-163 A-163 丙硫菌唑 Prothioconazole 代森锌 Zineb A-164 A-164 丙硫菌唑 Prothioconazole 福美锌 Ziram A-165 A-165 丙硫菌唑 Prothioconazole 啶酰菌胺 Boscalid A-166 A-166 丙硫菌唑 Prothioconazole B1 B1 A-167 A-167 丙硫菌唑 Prothioconazole B2 B2 A-168 A-168 丙硫菌唑 Prothioconazole B3 B3 A-169 A-169 丙硫菌唑 Prothioconazole B4 B4 A-170 A-170 丙硫菌唑 Prothioconazole B5 B5 A-171 A-171 丙硫菌唑 Prothioconazole B6 B6 A-172 A-172 丙硫菌唑 Prothioconazole B7 B7 A-173 A-173 丙硫菌唑 Prothioconazole B8 B8 A-174 A-174 丙硫菌唑 Prothioconazole B9 B9

序号 No. 组分2 Component 2 组分3 Component 3 A-175 A-175 丙硫菌唑 Prothioconazole B10 B10 A-176 A-176 丙硫菌唑 Prothioconazole B11 B11 A-177 A-177 丙硫菌唑 Prothioconazole B12 B12 A-178 A-178 丙硫菌唑 Prothioconazole B13 B13 A-179 A-179 戊唑醇 Tebuconazole 腈嘧菌酯 Azoxystrobin A-180 A-180 戊唑醇 Tebuconazole 醚菌胺 Dimoxystrobin A-181 A-181 戊唑醇 Tebuconazole 氟嘧菌酯 Fluoxastrobin A-182 A-182 戊唑醇 Tebuconazole 亚胺菌 Kresoxim A-183 A-183 戊唑醇 Tebuconazole 叉氨苯酰胺 Metominostrobin A-184 A-184 戊唑醇 Tebuconazole 肟醚菌胺 Orysastrobin A-185 A-185 戊唑醇 Tebuconazole 啶氧菌酯 Picoxystrobin A-186 A-186 戊唑醇 Tebuconazole 唑菌胺酯 Pyraclostrobin A-187 A-187 戊唑醇 Tebuconazole 肟菌酯 Trifloxystrobin A-188 A-188 戊唑醇 Tebuconazole 丙氯灵 Prochloraz A-189 A-189 戊唑醇 Tebuconazole 唑菌嗪 Triazoxide A-190 A-190 戊唑醇 Tebuconazole 代森锰锌 Mancozeb A-191 A-191 戊唑醇 Tebuconazole 代森锰 Maneb A-192 A-192 戊唑醇 Tebuconazole 代森联 Metiram A-193 A-193 戊唑醇 Tebuconazole 甲基代森锌 Propineb A-194 A-194 戊唑醇 Tebuconazole 福美双 Thiram A-195 A-195 戊唑醇 Tebuconazole 代森锌 Zineb A-196 A-196 戊唑醇 Tebuconazole 福美锌 Ziram A-197 A-197 戊叉唑菌 Triticonazole 氧唑菌 Epoxiconazole A-198 A-198 戊叉唑菌 Triticonazole 丙氯灵 Prochloraz A-199 A-199 戊叉唑菌 Triticonazole 唑菌嗪 Triazoxide A-200 A-200 戊叉唑菌 Triticonazole 异丙定 Iprodione A-201 A-201 戊叉唑菌 Triticonazole 二甲嘧菌胺 Pyrimethanil A-202 A-202 戊叉唑菌 Triticonazole 腈嘧菌酯 Azoxystrobin A-203 A-203 戊叉唑菌 Triticonazole 醚菌胺 Dimoxystrobin A-204 A-204 戊叉唑菌 Triticonazole 氟嘧菌酯 Fluoxastrobin A-205 A-205 戊叉唑菌 Triticonazole 亚胺菌 Kresoxim A-206 A-206 戊叉唑菌 Triticonazole 叉氨苯酰胺 Metominostrobin A-207 A-207 戊叉唑菌 Triticonazole 肟醚菌胺 Orysastrobin A-208 A-208 戊叉唑菌 Triticonazole 啶氧菌酯 Picoxystrobin A-209 A-209 戊叉唑菌 Triticonazole 唑菌胺酯 Pyraclostrobin A-210 A-210 戊叉唑菌 Triticonazole 肟菌酯 Trifloxystrobin

序号 No. 组分2 Component 2 组分3 Component 3 A-211 A-211 戊叉唑菌 Triticonazole 甲霜灵 Metalaxyl A-212 A-212 戊叉唑菌 Triticonazole 代森锰锌 Mancozeb A-213 A-213 戊叉唑菌 Triticonazole 代森锰 Maneb A-214 A-214 戊叉唑菌 Triticonazole 代森联 Metiram A-215 A-215 戊叉唑菌 Triticonazole 甲基代森锌 Propineb A-216 A-216 戊叉唑菌 Triticonazole 福美双 Thiram A-217 A-217 戊叉唑菌 Triticonazole 代森锌 Zineb A-218 A-218 戊叉唑菌 Triticonazole 福美锌 Ziram A-219 A-219 戊叉唑菌 Triticonazole 啶酰菌胺 Boscalid A-220 A-220 戊叉唑菌 Triticonazole B1 B1 A-221 A-221 戊叉唑菌 Triticonazole B2 B2 A-222 A-222 戊叉唑菌 Triticonazole B3 B3 A-223 A-223 戊叉唑菌 Triticonazole B4 B4 A-224 A-224 戊叉唑菌 Triticonazole B5 B5 A-225 A-225 戊叉唑菌 Triticonazole B6 B6 A-226 A-226 戊叉唑菌 Triticonazole B7 B7 A-227 A-227 戊叉唑菌 Triticonazole B8 B8 A-228 A-228 戊叉唑菌 Triticonazole B9 B9 A-229 A-229 戊叉唑菌 Triticonazole B10 B10 A-230 A-230 戊叉唑菌 Triticonazole B11 B11 A-231 A-231 戊叉唑菌 Triticonazole B12 B12 A-232 A-232 戊叉唑菌 Triticonazole B13 B13 A-233 A-233 戊叉唑菌 Triticonazole B14 B14 A-234 A-234 戊叉唑菌 Triticonazole B15 B15 A-235 A-235 戊叉唑菌 Triticonazole B16 B16 A-236 A-236 戊叉唑菌 Triticonazole B17 B17 A-237 A-237 戊叉唑菌 Triticonazole B18 B18 A-238 A-238 戊叉唑菌 Triticonazole B19 B19 A-239 A-239 戊叉唑菌 Triticonazole B20 B20 A-240 A-240 戊叉唑菌 Triticonazole B21 B21 A-241 A-241 戊叉唑菌 Triticonazole B22 B22 A-242 A-242 戊叉唑菌 Triticonazole B23 B23 A-243 A-243 戊叉唑菌 Triticonazole B24 B24 A-244 A-244 戊叉唑菌 Triticonazole B25 B25 A-245 A-245 戊叉唑菌 Triticonazole B26 B26 A-246 A-246 唑菌嗪 Triazoxide B1 B1

序号 No. 组分2 Component 2 组分3 Component 3 A-247 A-247 唑菌嗪 Triazoxide B2 B2 A-248 A-248 唑菌嗪 Triazoxide B3 B3 A-249 A-249 腈嘧菌酯 Azoxystrobin 啶酰菌胺 Boscalid A-250 A-250 醚菌胺 Dimoxystrobin 啶酰菌胺 Boscalid A-251 A-251 氟嘧菌酯 Fluoxastrobin 啶酰菌胺 Boscalid A-252 A-252 亚胺菌 Kresoxim 啶酰菌胺 Boscalid A-253 A-253 叉氨苯酰胺 Metominostrobin 啶酰菌胺 Boscalid A-254 A-254 肟醚菌胺 Orysastrobin 啶酰菌胺 Boscalid A-255 A-255 啶氧菌酯 Picoxystrobin 啶酰菌胺 Boscalid A-256 A-256 唑菌胺酯 Pyraclostrobin 啶酰菌胺 Boscalid A-257 A-257 肟菌酯 Trifloxystrobin 啶酰菌胺 Boscalid A-258 A-258 腈嘧菌酯 Azoxystrobin B1 B1 A-259 A-259 醚菌胺 Dimoxystrobin B1 B1 A-260 A-260 氟嘧菌酯 Fluoxastrobin B1 B1 A-261 A-261 亚胺菌 Kresoxim B1 B1 A-262 A-262 叉氨苯酰胺 Metominostrobin B1 B1 A-263 A-263 肟醚菌胺 Orysastrobin B1 B1 A-264 A-264 啶氧菌酯 Picoxystrobin B1 B1 A-265 A-265 唑菌胺酯 Pyraclostrobin B1 B1 A-266 A-266 肟菌酯 Trifloxystrobin B1 B1 A-267 A-267 腈嘧菌酯 Azoxystrobin B2 B2 A-268 A-268 醚菌胺 Dimoxystrobin B2 B2 A-269 A-269 氟嘧菌酯 Fluoxastrobin B2 B2 A-270 A-270 亚胺菌 Kresoxim B2 B2 A-271 A-271 叉氨苯酰胺 Metominostrobin B2 B2 A-272 A-272 肟醚菌胺 Orysastrobin B2 B2 A-273 A-273 啶氧菌酯 Picoxystrobin B2 B2 A-274 A-274 唑菌胺酯 Pyraclostrobin B2 B2 A-275 A-275 肟菌酯 Trifloxystrobin B2 B2 A-276 A-276 腈嘧菌酯 Azoxystrobin B3 B3 A-277 A-277 醚菌胺 Dimoxystrobin B3 B3 A-278 A-278 氟嘧菌酯 Fluoxastrobin B3 B3 A-279 A-279 亚胺菌 Kresoxim B3 B3 A-280 A-280 叉氨苯酰胺 Metominostrobin B3 B3 A-281 A-281 肟醚菌胺 Orysastrobin B3 B3 A-282 A-282 啶氧菌酯 Picoxystrobin B3 B3

序号 No. 组分2 Component 2 组分3 Component 3 A-283 A-283 唑菌胺酯 Pyraclostrobin B3 B3 A-284 A-284 肟菌酯 Trifloxystrobin B3 B3 A-285 A-285 腈嘧菌酯 Azoxystrobin B4 B4 A-286 A-286 醚菌胺 Dimoxystrobin B4 B4 A-287 A-287 氟嘧菌酯 Fluoxastrobin B4 B4 A-288 A-288 亚胺菌 Kresoxim B4 B4 A-289 A-289 叉氨苯酰胺 Metominostrobin B4 B4 A-290 A-290 肟醚菌胺 Orysastrobin B4 B4 A-291 A-291 啶氧菌酯 Picoxystrobin B4 B4 A-292 A-292 唑菌胺酯 Pyraclostrobin B4 B4 A-293 A-293 肟菌酯 Trifloxystrobin B4 B4 A-294 A-294 腈嘧菌酯 Azoxystrobin B5 B5 A-295 A-295 醚菌胺 Dimoxystrobin B5 B5 A-296 A-296 氟嘧菌酯 Fluoxastrobin B5 B5 A-297 A-297 亚胺菌 Kresoxim B5 B5 A-298 A-298 叉氨苯酰胺 Metominostrobin B5 B5 A-299 A-299 肟醚菌胺 Orysastrobin B5 B5 A-300 A-300 啶氧菌酯 Picoxystrobin B5 B5 A-301 A-301 唑菌胺酯 Pyraclostrobin B5 B5 A-302 A-302 肟菌酯 Trifloxystrobin B5 B5 A-303 A-303 腈嘧菌酯 Azoxystrobin B6 B6 A-304 A-304 醚菌胺 Dimoxystrobin B6 B6 A-305 A-305 氟嘧菌酯 Fluoxastrobin B6 B6 A-306 A-306 亚胺菌 Kresoxim B6 B6 A-307 A-307 叉氨苯酰胺 Metominostrobin B6 B6 A-308 A-308 肟醚菌胺 Orysastrobin B6 B6 A-309 A-309 啶氧菌酯 Picoxystrobin B6 B6 A-310 A-310 唑菌胺酯 Pyraclostrobin B6 B6 A-311 A-311 肟菌酯 Trifloxystrobin B6 B6 A-312 A-312 腈嘧菌酯 Azoxystrobin B7 B7 A-313 A-313 醚菌胺 Dimoxystrobin B7 B7 A-314 A-314 氟嘧菌酯 Fluoxastrobin B7 B7 A-315 A-315 亚胺菌 Kresoxim B7 B7 A-316 A-316 叉氨苯酰胺 Metominostrobin B7 B7 A-317 A-317 肟醚菌胺 Orysastrobin B7 B7 A-318 A-318 啶氧菌酯 Picoxystrobin B7 B7

序号 No. 组分2 Component 2 组分3 Component 3 A-319 A-319 唑菌胺酯 Pyraclostrobin B7 B7 A-320 A-320 肟菌酯 Trifloxystrobin B7 B7 A-321 A-321 腈嘧菌酯 Azoxystrobin B8 B8 A-322 A-322 醚菌胺 Dimoxystrobin B8 B8 A-323 A-323 氟嘧菌酯 Fluoxastrobin B8 B8 A-324 A-324 亚胺菌 Kresoxim B8 B8 A-325 A-325 叉氨苯酰胺 Metominostrobin B8 B8 A-326 A-326 肟醚菌胺 Orysastrobin B8 B8 A-327 A-327 啶氧菌酯 Picoxystrobin B8 B8 A-328 A-328 唑菌胺酯 Pyraclostrobin B8 B8 A-329 A-329 肟菌酯 Trifloxystrobin B8 B8 A-330 A-330 腈嘧菌酯 Azoxystrobin B9 B9 A-331 A-331 醚菌胺 Dimoxystrobin B9 B9 A-332 A-332 氟嘧菌酯 Fluoxastrobin B9 B9 A-333 A-333 亚胺菌 Kresoxim B9 B9 A-334 A-334 叉氨苯酰胺 Metominostrobin B9 B9 A-335 A-335 肟醚菌胺 Orysastrobin B9 B9 A-336 A-336 啶氧菌酯 Picoxystrobin B9 B9 A-337 A-337 唑菌胺酯 Pyraclostrobin B9 B9 A-338 A-338 肟菌酯 Trifloxystrobin B9 B9 A-339 A-339 腈嘧菌酯 Azoxystrobin B10 B10 A-340 A-340 醚菌胺 Dimoxystrobin B10 B10 A-341 A-341 氟嘧菌酯 Fluoxastrobin B10 B10 A-342 A-342 亚胺菌 Kresoxim B10 B10 A-343 A-343 叉氨苯酰胺 Metominostrobin B10 B10 A-344 A-344 肟醚菌胺 Orysastrobin B10 B10 A-345 A-345 啶氧菌酯 Picoxystrobin B10 B10 A-346 A-346 唑菌胺酯 Pyraclostrobin B10 B10 A-347 A-347 肟菌酯 Trifloxystrobin B10 B10 A-348 A-348 腈嘧菌酯 Azoxystrobin B11 B11 A-349 A-349 醚菌胺 Dimoxystrobin B11 B11 A-350 A-350 氟嘧菌酯 Fluoxastrobin B11 B11 A-351 A-351 亚胺菌 Kresoxim B11 B11 A-352 A-352 叉氨苯酰胺 Metominostrobin B11 B11 A-353 A-353 肟醚菌胺 Orysastrobin B11 B11 A-354 A-354 啶氧菌酯 Picoxystrobin B11 B11

序号 No. 组分2 Component 2 组分3 Component 3 A-355 A-355 唑菌胺酯 Pyraclostrobin B11 B11 A-356 A-356 肟菌酯 Trifloxystrobin B11 B11 A-357 A-357 腈嘧菌酯 Azoxystrobin B12 B12 A-358 A-358 醚菌胺 Dimoxystrobin B12 B12 A-359 A-359 氟嘧菌酯 Fluoxastrobin B12 B12 A-360 A-360 亚胺菌 Kresoxim B12 B12 A-361 A-361 叉氨苯酰胺 Metominostrobin B12 B12 A-362 A-362 肟醚菌胺 Orysastrobin B12 B12 A-363 A-363 啶氧菌酯 Picoxystrobin B12 B12 A-364 A-364 唑菌胺酯 Pyraclostrobin B12 B12 A-365 A-365 肟菌酯 Trifloxystrobin B12 B12 A-366 A-366 腈嘧菌酯 Azoxystrobin B13 B13 A-367 A-367 醚菌胺 Dimoxystrobin B13 B13 A-368 A-368 氟嘧菌酯 Fluoxastrobin B13 B13 A-369 A-369 亚胺菌 Kresoxim B13 B13 A-370 A-370 叉氨苯酰胺 Metominostrobin B13 B13 A-371 A-371 肟醚菌胺 Orysastrobin B13 B13 A-372 A-372 啶氧菌酯 Picoxystrobin B13 B13 A-373 A-373 唑菌胺酯 Pyraclostrobin B13 B13 A-374 A-374 肟菌酯 Trifloxystrobin B13 B13 A-375 A-375 腈嘧菌酯 Azoxystrobin B14 B14 A-376 A-376 醚菌胺 Dimoxystrobin B14 B14 A-377 A-377 氟嘧菌酯 Fluoxastrobin B14 B14 A-378 A-378 亚胺菌 Kresoxim B14 B14 A-379 A-379 叉氨苯酰胺 Metominostrobin B14 B14 A-380 A-380 肟醚菌胺 Orysastrobin B14 B14 A-381 A-381 啶氧菌酯 Picoxystrobin B14 B14 A-382 A-382 唑菌胺酯 Pyraclostrobin B14 B14 A-383 A-383 肟菌酯 Trifloxystrobin B14 B14 A-384 A-384 腈嘧菌酯 Azoxystrobin B15 B15 A-385 A-385 醚菌胺 Dimoxystrobin B15 B15 A-386 A-386 氟嘧菌酯 Fluoxastrobin B15 B15 A-387 A-387 亚胺菌 Kresoxim B15 B15 A-388 A-388 叉氨苯酰胺 Metominostrobin B15 B15 A-389 A-389 肟醚菌胺 Orysastrobin B15 B15 A-390 A-390 啶氧菌酯 Picoxystrobin B15 B15

序号 No. 组分2 Component 2 组分3 Component 3 A-391 A-391 唑菌胺酯 Pyraclostrobin B15 B15 A-392 A-392 肟菌酯 Trifloxystrobin B15 B15 A-393 A-393 腈嘧菌酯 Azoxystrobin B16 B16 A-394 A-394 醚菌胺 Dimoxystrobin B16 B16 A-395 A-395 氟嘧菌酯 Fluoxastrobin B16 B16 A-396 A-396 亚胺菌 Kresoxim B16 B16 A-397 A-397 叉氨苯酰胺 Metominostrobin B16 B16 A-398 A-398 肟醚菌胺 Orysastrobin B16 B16 A-399 A-399 啶氧菌酯 Picoxystrobin B16 B16 A-400 A-400 唑菌胺酯 Pyraclostrobin B16 B16 A-401 A-401 肟菌酯 Trifloxystrobin B16 B16 A-402 A-402 腈嘧菌酯 Azoxystrobin B17 B17 A-403 A-403 醚菌胺 Dimoxystrobin B17 B17 A-404 A-404 氟嘧菌酯 Fluoxastrobin B17 B17 A-405 A-405 亚胺菌 Kresoxim B17 B17 A-406 A-406 肟醚菌胺 Orysastrobin B17 B17 A-407 A-407 叉氨苯酰胺 Metominostrobin B17 B17 A-408 A-408 啶氧菌酯 Picoxystrobin B17 B17 A-409 A-409 唑菌胺酯 Pyraclostrobin B17 B17 A-410 A-410 肟菌酯 Trifloxystrobin B17 B17 A-411 A-411 腈嘧菌酯 Azoxystrobin B18 B18 A-412 A-412 醚菌胺 Dimoxystrobin B18 B18 A-413 A-413 氟嘧菌酯 Fluoxastrobin B18 B18 A-414 A-414 亚胺菌 Kresoxim B18 B18 A-415 A-415 叉氨苯酰胺 Metominostrobin B18 B18 A-416 A-416 肟醚菌胺 Orysastrobin B18 B18 A-417 A-417 啶氧菌酯 Picoxystrobin B18 B18 A-418 A-418 唑菌胺酯 Pyraclostrobin B18 B18 A-419 A-419 肟菌酯 Trifloxystrobin B18 B18 A-420 A-420 腈嘧菌酯 Azoxystrobin B19 B19 A-421 A-421 醚菌胺 Dimoxystrobin B19 B19 A-422 A-422 氟嘧菌酯 Fluoxastrobin B19 B19 A-423 A-423 亚胺菌 Kresoxim B19 B19 A-424 A-424 叉氨苯酰胺 Metominostrobin B19 B19 A-425 A-425 肟醚菌胺 Orysastrobin B19 B19 A-426 A-426 啶氧菌酯 Picoxystrobin B19 B19

序号 No. 组分2 Component 2 组分3 Component 3 A-427 A-427 唑菌胺酯 Pyraclostrobin B19 B19 A-428 A-428 肟菌酯 Trifloxystrobin B19 B19 A-429 A-429 腈嘧菌酯 Azoxystrobin B20 B20 A-430 A-430 醚菌胺 Dimoxystrobin B20 B20 A-431 A-431 氟嘧菌酯 Fluoxastrobin B20 B20 A-432 A-432 亚胺菌 Kresoxim B20 B20 A-433 A-433 叉氨苯酰胺 Metominostrobin B20 B20 A-434 A-434 肟醚菌胺 Orysastrobin B20 B20 A-435 A-435 啶氧菌酯 Picoxystrobin B20 B20 A-436 A-436 唑菌胺酯 Pyraclostrobin B20 B20 A-437 A-437 肟菌酯 Trifloxystrobin B20 B20 A-438 A-438 腈嘧菌酯 Azoxystrobin B21 B21 A-439 A-439 醚菌胺 Dimoxystrobin B21 B21 A-440 A-440 氟嘧菌酯 Fluoxastrobin B21 B21 A-441 A-441 亚胺菌 Kresoxim B21 B21 A-442 A-442 叉氨苯酰胺 Metominostrobin B21 B21 A-443 A-443 肟醚菌胺 Orysastrobin B21 B21 A-444 A-444 啶氧菌酯 Picoxystrobin B21 B21 A-445 A-445 唑菌胺酯 Pyraclostrobin B21 B21 A-446 A-446 肟菌酯 Trifloxystrobin B21 B21 A-447 A-447 腈嘧菌酯 Azoxystrobin B22 B22 A-448 A-448 醚菌胺 Dimoxystrobin B22 B22 A-449 A-449 氟嘧菌酯 Fluoxastrobin B22 B22 A-450 A-450 亚胺菌 Kresoxim B22 B22 A-451 A-451 叉氨苯酰胺 Metominostrobin B22 B22 A-452 A-452 肟醚菌胺 Orysastrobin B22 B22 A-453 A-453 啶氧菌酯 Picoxystrobin B22 B22 A-454 A-454 唑菌胺酯 Pyraclostrobin B22 B22 A-455 A-455 肟菌酯 Trifloxystrobin B22 B22 A-456 A-456 腈嘧菌酯 Azoxystrobin B23 B23 A-457 A-457 醚菌胺 Dimoxystrobin B23 B23 A-458 A-458 氟嘧菌酯 Fluoxastrobin B23 B23 A-459 A-459 亚胺菌 Kresoxim B23 B23 A-460 A-460 叉氨苯酰胺 Metominostrobin B23 B23 A-461 A-461 肟醚菌胺 Orysastrobin B23 B23 A-462 A-462 啶氧菌酯 Picoxystrobin B23 B23

序号 No. 组分2 Component 2 组分3 Component 3 A-463 A-463 唑菌胺酯 Pyraclostrobin B23 B23 A-464 A-464 肟菌酯 Trifloxystrobin B23 B23 A-465 A-465 腈嘧菌酯 Azoxystrobin B24 B24 A-466 A-466 醚菌胺 Dimoxystrobin B24 B24 A-467 A-467 氟嘧菌酯 Fluoxastrobin B24 B24 A-468 A-468 亚胺菌 Kresoxim B24 B24 A-469 A-469 叉氨苯酰胺 Metominostrobin B24 B24 A-470 A-470 肟醚菌胺 Orysastrobin B24 B24 A-471 A-471 啶氧菌酯 Picoxystrobin B24 B24 A-472 A-472 唑菌胺酯 Pyraclostrobin B24 B24 A-473 A-473 肟菌酯 Trifloxystrobin B24 B24 A-474 A-474 腈嘧菌酯 Azoxystrobin B25 B25 A-475 A-475 醚菌胺 Dimoxystrobin B25 B25 A-476 A-476 氟嘧菌酯 Fluoxastrobin B25 B25 A-477 A-477 亚胺菌 Kresoxim B25 B25 A-478 A-478 叉氨苯酰胺 Metominostrobin B25 B25 A-479 A-479 肟醚菌胺 Orysastrobin B25 B25 A-480 A-480 啶氧菌酯 Picoxystrobin B25 B25 A-481 A-481 唑菌胺酯 Pyraclostrobin B25 B25 A-482 A-482 肟菌酯 Trifloxystrobin B25 B25 A-483 A-483 腈嘧菌酯 Azoxystrobin B26 B26 A-484 A-484 醚菌胺 Dimoxystrobin B26 B26 A-485 A-485 氟嘧菌酯 Fluoxastrobin B26 B26 A-486 A-486 亚胺菌 Kresoxim B26 B26 A-487 A-487 叉氨苯酰胺 Metominostrobin B26 B26 A-488 A-488 肟醚菌胺 Orysastrobin B26 B26 A-489 A-489 啶氧菌酯 Picoxystrobin B26 B26 A-490 A-490 唑菌胺酯 Pyraclostrobin B26 B26 A-491 A-491 肟菌酯 Trifloxystrobin B26 B26 A-492 A-492 腈嘧菌酯 Azoxystrobin 克菌丹 Captan A-493 A-493 醚菌胺 Dimoxystrobin 克菌丹 Captan A-494 A-494 氟嘧菌酯 Fluoxastrobin 克菌丹 Captan A-495 A-495 亚胺菌 Kresoxim 克菌丹 Captan A-496 A-496 叉氨苯酰胺 Metominostrobin 克菌丹 Captan A-497 A-497 肟醚菌胺 Orysastrobin 克菌丹 Captan A-498 A-498 啶氧菌酯 Picoxystrobin 克菌丹 Captan

序号 No. 组分2 Component 2 组分3 Component 3 A-499 A-499 唑菌胺酯 Pyraclostrobin 克菌丹 Captan A-500 A-500 肟菌酯 Trifloxystrobin 克菌丹 Captan A-501 A-501 腈嘧菌酯 Azoxystrobin 灭菌丹 Folpet A-502 A-502 醚菌胺 Dimoxystrobin 灭菌丹 Folpet A-503 A-503 氟嘧菌酯 Fluoxastrobin 灭菌丹 Folpet A-504 A-504 亚胺菌 Kresoxim 灭菌丹 Folpet A-505 A-505 叉氨苯酰胺 Metominostrobin 灭菌丹 Folpet A-506 A-506 肟醚菌胺 Orysastrobin 灭菌丹 Folpet A-507 A-507 啶氧菌酯 Picoxystrobin 灭菌丹 Folpet A-508 A-508 唑菌胺酯 Pyraclostrobin 灭菌丹 Folpet A-509 A-509 肟菌酯 Trifloxystrobin 灭菌丹 Folpet A-510 A-510 腈嘧菌酯 Azoxystrobin 甲霜灵 Metalaxyl A-511 A-511 醚菌胺 Dimoxystrobin 甲霜灵 Metalaxyl A-512 A-512 氟嘧菌酯 Fluoxastrobin 甲霜灵 Metalaxyl A-513 A-513 亚胺菌 Kresoxim 甲霜灵 Metalaxyl A-514 A-514 叉氨苯酰胺 Metominostrobin 甲霜灵 Metalaxyl A-515 A-515 肟醚菌胺 Orysastrobin 甲霜灵 Metalaxyl A-516 A-516 啶氧菌酯 Picoxystrobin 甲霜灵 Metalaxyl A-517 A-517 唑菌胺酯 Pyraclostrobin 甲霜灵 Metalaxyl A-518 A-518 肟菌酯 Trifloxystrobin 甲霜灵 Metalaxyl A-519 A-519 腈嘧菌酯 Azoxystrobin 精甲霜灵 Mefenoxam A-520 A-520 醚菌胺 Dimoxystrobin 精甲霜灵 Mefenoxam A-521 A-521 氟嘧菌酯 Fluoxastrobin 精甲霜灵 Mefenoxam A-522 A-522 亚胺菌 Kresoxim 精甲霜灵 Mefenoxam A-523 A-523 叉氨苯酰胺 Metominostrobin 精甲霜灵 Mefenoxam A-524 A-524 肟醚菌胺 Orysastrobin 精甲霜灵 Mefenoxam A-525 A-525 啶氧菌酯 Picoxystrobin 精甲霜灵 Mefenoxam A-526 A-526 唑菌胺酯 Pyraclostrobin 精甲霜灵 Mefenoxam A-527 A-527 肟菌酯 Trifloxystrobin 精甲霜灵 Mefenoxam A-528 A-528 腈嘧菌酯 Azoxystrobin 烯酰吗啉 Dimethomorph A-529 A-529 醚菌胺 Dimoxystrobin 烯酰吗啉 Dimethomorph A-530 A-530 氟嘧菌酯 Fluoxastrobin 烯酰吗啉 Dimethomorph A-531 A-531 亚胺菌 Kresoxim 烯酰吗啉 Dimethomorph A-532 A-532 叉氨苯酰胺 Metominostrobin 烯酰吗啉 Dimethomorph A-533 A-533 肟醚菌胺 Orysastrobin 烯酰吗啉 Dimethomorph A-534 A-534 啶氧菌酯 Picoxystrobin 烯酰吗啉 Dimethomorph

序号 No. 组分2 Component 2 组分3 Component 3 A-535 A-535 唑菌胺酯 Pyraclostrobin 烯酰吗啉 Dimethomorph A-536 A-536 肟菌酯 Trifloxystrobin 烯酰吗啉 Dimethomorph A-537 A-537 腈嘧菌酯 Azoxystrobin 甲基托布津 Thiophanate-methyl A-538 A-538 醚菌胺 Dimoxystrobin 甲基托布津 Thiophanate-methyl A-539 A-539 氟嘧菌酯 Fluoxastrobin 甲基托布津 Thiophanate-methyl A-540 A-540 亚胺菌 Kresoxim 甲基托布津 Thiophanate-methyl A-541 A-541 叉氨苯酰胺 Metominostrobin 甲基托布津 Thiophanate-methyl A-542 A-542 肟醚菌胺 Orysastrobin 甲基托布津 Thiophanate-methyl A-543 A-543 啶氧菌酯 Picoxystrobin 甲基托布津 Thiophanate-methyl A-544 A-544 唑菌胺酯 Pyraclostrobin 甲基托布津 Thiophanate-methyl A-545 A-545 肟菌酯 Trifloxystrobin 甲基托布津 Thiophanate-methyl A-546 A-546 甲霜灵 Metalaxyl 啶酰菌胺 Boscalid A-547 A-547 甲霜灵 Metalaxyl B1 B1 A-548 A-548 甲霜灵 Metalaxyl B2 B2 A-549 A-549 甲霜灵 Metalaxyl B3 B3 A-550 A-550 甲霜灵 Metalaxyl B4 B4 A-551 A-551 甲霜灵 Metalaxyl B5 B5 A-552 A-552 甲霜灵 Metalaxyl B6 B6 A-553 A-553 甲霜灵 Metalaxyl B7 B7 A-554 A-554 甲霜灵 Metalaxyl B8 B8 A-555 A-555 甲霜灵 Metalaxyl B9 B9 A-556 A-556 甲霜灵 Metalaxyl B10 B10 A-557 A-557 甲霜灵 Metalaxyl B11 B11 A-558 A-558 甲霜灵 Metalaxyl B12 B12 A-559 A-559 甲霜灵 Metalaxyl B13 B13 A-560 A-560 甲霜灵 Metalaxyl B14 B14 A-561 A-561 精甲霜灵 Mefenoxam 啶酰菌胺 Boscalid A-562 A-562 精甲霜灵 Mefenoxam B1 B1 A-563 A-563 精甲霜灵 Mefenoxam B2 B2 A-564 A-564 精甲霜灵 Mefenoxam B3 B3 A-565 A-565 精甲霜灵 Mefenoxam B4 B4 A-566 A-566 精甲霜灵 Mefenoxam B5 B5 A-567 A-567 精甲霜灵 Mefenoxam B6 B6 A-568 A-568 精甲霜灵 Mefenoxam B7 B7 A-569 A-569 精甲霜灵 Mefenoxam B8 B8 A-570 A-570 精甲霜灵 Mefenoxam B9 B9

序号 No. 组分2 Component 2 组分3 Component 3 A-571 A-571 精甲霜灵 Mefenoxam B10 B10 A-572 A-572 精甲霜灵 Mefenoxam B11 B11 A-573 A-573 精甲霜灵 Mefenoxam B12 B12 A-574 A-574 精甲霜灵 Mefenoxam B13 B13 A-575 A-575 双胍盐 Guazatine 氧唑菌 Epoxiconazole A-576 A-576 双胍盐 Guazatine 噁醚唑 Difenoconazole A-577 A-577 双胍盐 Guazatine 环戊唑菌 Metconazole A-578 A-578 双胍盐 Guazatine 戊唑醇 Tebuconazole A-579 A-579 双胍盐 Guazatine 戊叉唑菌 Triticonazole A-580 A-580 双胍盐 Guazatine 萎锈灵 Carboxin A-581 A-581 甲基托布津 Thiophanate-methyl 氧唑菌 Epoxiconazole A-582 A-582 甲基托布津 Thiophanate-methyl 噁醚唑 Difenoconazole A-583 A-583 甲基托布津 Thiophanate-methyl 环戊唑菌 Metconazole A-584 A-584 甲基托布津 Thiophanate-methyl 戊唑醇 Tebuconazole A-585 A-585 甲基托布津 Thiophanate-methyl 戊叉唑菌 Triticonazole A-586 A-586 甲基托布津 Thiophanate-methyl 萎锈灵 Carboxin A-587 A-587 克菌丹 Captan 氧唑菌 Epoxiconazole A-588 A-588 克菌丹 Captan 噁醚唑 Difenoconazole A-589 A-589 克菌丹 Captan 环戊唑菌 Metconazole A-590 A-590 克菌丹 Captan 戊唑醇 Tebuconazole A-591 A-591 克菌丹 Captan 戊叉唑菌 Triticonazole A-592 A-592 克菌丹 Captan 萎锈灵 Carboxin A-593 A-593 灭菌丹 Folpet 氧唑菌 Epoxiconazole A-594 A-594 灭菌丹 Folpet 噁醚唑 Difenoconazole A-595 A-595 灭菌丹 Folpet 环戊唑菌 Metconazole A-596 A-596 灭菌丹 Folpet 戊唑醇 Tebuconazole A-597 A-597 灭菌丹 Folpet 戊叉唑菌 Triticonazole A-598 A-598 灭菌丹 Folpet 萎锈灵 Carboxin A-599 A-599 氟噁菌 Fludioxonil 噁醚唑 Difenoconazole A-600 A-600 氟噁菌 Fludioxonil 粉唑醇 Flutriafol A-601 A-601 氟噁菌 Fludioxonil 环戊唑醇 Ipconazole A-602 A-602 氟噁菌 Fludioxonil 环戊唑菌 Metconazole A-603 A-603 氟噁菌 Fludioxonil 戊唑醇 Tebuconazole A-604 A-604 氟噁菌 Fludioxonil 戊叉唑菌 Triticonazole A-605 A-605 氟噁菌 Fludioxonil 腈嘧菌酯 Azoxystrobin A-606 A-606 氟噁菌 Fludioxonil 醚菌胺 Dimoxystrobin

序号 No. 组分2 Component 2 组分3 Component 3 A-607 A-607 氟噁菌 Fludioxonil 氟嘧菌酯 Fluoxastrobin A-608 A-608 氟噁菌 Fludioxonil 亚胺菌 Kresoxim A-609 A-609 氟噁菌 Fludioxonil 叉氨苯酰胺 Metominostrobin A-610 A-610 氟噁菌 Fludioxonil 肟醚菌胺 Orysastrobin A-611 A-611 氟噁菌 Fludioxonil 啶氧菌酯 Picoxystrobin A-612 A-612 氟噁菌 Fludioxonil 唑菌胺酯 Pyraclostrobin A-613 A-613 氟噁菌 Fludioxonil 肟菌酯 Trifloxystrobin A-614 A-614 氟噁菌 Fludioxonil 萎锈灵 Carboxin A-615 A-615 氟噁菌 Fludioxonil 环丙嘧啶 Cyprodinil A-616 A-616 氟噁菌 Fludioxonil 精甲霜灵 Mefenoxam A-617 A-617 氟噁菌 Fludioxonil 啶酰菌胺 Boscalid A-618 A-618 氟噁菌 Fludioxonil B1 B1 A-619 A-619 氟噁菌 Fludioxonil B2 B2 A-620 A-620 氟噁菌 Fludioxonil B3 B3 A-621 A-621 氟噁菌 Fludioxonil B4 B4 A-622 A-622 氟噁菌 Fludioxonil B5 B5 A-623 A-623 氟噁菌 Fludioxonil B6 B6 A-624 A-624 氟噁菌 Fludioxonil B7 B7 A-625 A-625 氟噁菌 Fludioxonil B8 B8 A-626 A-626 氟噁菌 Fludioxonil B9 B9 A-627 A-627 氟噁菌 Fludioxonil B10 B10 A-628 A-628 氟噁菌 Fludioxonil B11 B11 A-629 A-629 氟噁菌 Fludioxonil B12 B12 A-630 A-630 氟噁菌 Fludioxonil B13 B13

对本发明用途而言,可以将本发明混合物或化合物I和活性化合物II和III转化成常规配制剂,例如溶液、乳液、悬浮液、粉剂、粉末、糊和颗粒。 For the purposes of the present invention, the present invention can be mixtures or compounds I and active compounds II and III is converted into the customary formulations, e.g. solutions, emulsions, suspensions, dusts, powders, pastes and granules. 使用形式取决于特定的意欲目的;在每种情况下应确保本发明化合物精细和均匀地分布。 The use form depends on the particular intended purpose; in each case, the compounds of the present invention should ensure a fine and uniformly distributed.

配制剂以已知的方式制备,例如通过将活性化合物与溶剂和/或载体混合而制备,需要的话使用乳化剂和分散剂。 Formulations prepared in a known manner, for example, be prepared by mixing the active compound with solvents and / or carriers, if desired using emulsifiers and dispersants needed. 合适的溶剂/助剂主要为: Suitable solvents / adjuvants are essentially:

-水、芳族溶剂(如Solvesso产品、二甲苯)、石蜡(如矿物油馏分)、醇类(如甲醇、丁醇、戊醇、苄醇)、酮类(如环己酮、γ-丁内酯)、吡咯烷酮(NMP、NOP)、乙酸酯(乙二醇二乙酸酯)、二元醇、脂肪酸二甲基酰胺、脂肪酸及脂肪酸酯。 - water, aromatic solvents (for example Solvesso products, xylene), paraffins (for example mineral oil fractions), alcohols (e.g., methanol, butanol, pentanol, benzyl alcohol), ketones (e.g., cyclohexanone, [gamma] butyrate butyrolactone), pyrrolidones (NMP, NOP), acetates (glycol diacetate), glycols, fatty acid dimethyl amides, fatty acids and fatty acid esters. 原则上还可以使用溶剂混合物。 In principle, solvent mixtures may also be used.

-载体如磨碎的天然矿物(如高岭土、粘土、滑石、白垩)和磨碎的合成矿物(如高度分散的硅石、硅酸盐);乳化剂如非离子和阴离子乳化剂(如聚氧乙烯脂肪醇醚、烷基磺酸盐和芳基磺酸盐)以及分散剂如木素亚硫酸盐废液和甲基纤维素。 - carriers such as ground natural minerals (e.g. kaolins, clays, talc, chalk) and ground synthetic minerals (e.g. highly disperse silica, silicates); emulsifiers such as nonionic and anionic emulsifiers (e.g. polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose.

合适的表面活性剂是木素磺酸、萘磺酸、苯酚磺酸、二丁基萘磺酸的碱金属盐、碱土金属盐和铵盐,烷基芳基磺酸盐,烷基硫酸盐,烷基磺酸盐,脂肪醇硫酸盐,脂肪酸和硫酸化脂肪醇乙二醇醚,还有磺化萘和萘衍生物与甲醛的缩合物,萘或萘磺酸与苯酚和甲醛的缩合物,聚氧乙烯辛基酚醚,乙氧基化异辛基酚、辛基酚、壬基酚,烷基酚聚乙二醇醚,三丁基苯基聚乙二醇醚,三硬脂基苯基聚乙二醇醚,烷基芳基聚醚醇,醇和脂肪醇/氧化乙烯缩合物,乙氧基化蓖麻油,聚氧乙烯烷基醚,乙氧基化聚氧丙烯,月桂醇聚乙二醇醚缩醛,山梨醇酯,木素亚硫酸盐废液和甲基纤维素。 Suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid alkali metal, alkaline earth metal and ammonium salts, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde condensates, polyoxyethylene octylphenol ethers, ethoxylated isooctylphenol, octylphenol, nonylphenol, alkylphenol polyglycol ethers, tributylphenyl polyglycol ether, tristearyl phenyl polyglycol ethers, alkylaryl polyether alcohols, alcohol and fatty alcohol / ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylated polyoxypropylene, lauryl alcohol polyethoxylate glycol ether acetal, sorbitol esters, lignosulfite waste liquors and methylcellulose.

适于制备可直接喷雾溶液、乳液、糊或油分散体的物质是中沸点到高沸点的矿物油馏分,如煤油或柴油,此外还有煤焦油和植物或动物来源的油,脂族、环状和芳族烃,例如甲苯、二甲苯、石蜡、四氢化萘、烷基化萘或其衍生物、甲醇、乙醇、丙醇、丁醇、环己醇、环己酮、异佛尔酮,强极性溶剂,例如二甲亚砜、N-甲基吡咯烷酮和水。 Substances suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are medium to high boiling point mineral oil fractions, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and like aromatic hydrocarbons, such as toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethyl sulfoxide, N- methylpyrrolidone and water.

防冻剂如甘油、乙二醇、丙二醇以及杀菌剂也可加入配制剂。 Antifreezing agents such as glycerin, ethylene glycol, propylene glycol and bactericides can be added to the formulation.

合适的消泡剂例如为基于聚硅氧烷或硬脂酸镁的消泡剂。 Suitable antifoams, for example silicone-based defoamers, or magnesium stearate.

合适的防腐剂例如为双氯酚(Dichlorophen)和苯甲醇半缩甲醛(enzylalkoholhemiformal)。 Suitable preservatives are for example dichlorophen (dichlorophen) and benzyl alcohol hemiformal (enzylalkoholhemiformal).

种子处理配制剂可额外包含粘合剂和任选着色剂。 Seed treatment formulations may additionally comprise binders and optionally colorants.

添加粘合剂以改进活性材料在处理后对于种子的粘附。 Binder is added to improve the adhesion of the active material to the seed after the treatment. 合适粘合剂为嵌段共聚物EO/PO表面活性剂,以及聚乙烯醇、聚乙烯吡咯烷酮、聚丙烯酸酯、聚甲基丙烯酸酯、聚丁烯、聚异丁烯、聚苯乙烯、聚乙烯胺、聚乙烯酰胺、聚乙烯亚胺 Suitable binders are block copolymers EO / PO surfactants, as well as polyvinyl alcohol, polyvinyl pyrrolidone, polyacrylates, polymethacrylates, polybutenes, polyisobutylenes, polystyrene, polyvinyl amine, polyethylene polyacrylamide, polyethyleneimine 聚醚、聚氨酯、聚乙烯基乙酸酯、纤基乙酸钠和衍生自这些聚合物的共聚物。 Polyethers, polyurethanes, polyvinyl acetates, tylose and copolymers derived from these polymers.

任选在配制剂中也包含着色剂。 Optionally also containing a coloring agent in the formulation. 适用于种子处理配制剂的着色剂或染料为若丹明B、CI颜料红112、CI溶剂红1、颜料蓝15:4、颜料蓝15:3、颜料蓝15:2、颜料蓝15:1、颜料蓝80、颜料黄1、颜料黄13、颜料红112、颜料红48:2、颜料红48:1、颜料红57:1、颜料红53:1、颜料橙43、颜料橙34、颜料橙5、颜料绿36、颜料绿7、颜料白6、颜料棕25、碱性紫10、碱性紫49、酸性红51、酸性红52、酸性红14、酸性蓝9、酸性黄23、碱性红10、碱性红108。 Suitable for seed treatment formulations colorants or dyes as Rhodamine B, CI Pigment Red 112, CI Solvent Red 1, pigment blue 15: 4, Pigment Blue 15: 3, pigment blue 15: 2, Pigment Blue 15: 1 , pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48: 2, pigment red 48: 1, pigment red 57: 1, pigment red 53: 1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, base of red 10, basic red 108..

胶凝剂的实例为角叉菜胶 Examples of the gelling agent is carrageenan

粉末、撒播用材料和可撒粉产品可以通过将活性物质与固体载体混合或同时研磨而制备。 Powder, scattering material can be prepared by mixing and dustable product or active substances with a solid carrier is prepared simultaneously ground.

颗粒如涂覆颗粒、浸渍颗粒和均质颗粒可以通过将活性化合物与固体载体粘附而制备。 Coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active compounds to solid carriers. 固体载体的实例是矿土如硅胶、硅酸盐、滑石、高岭土、活性粘土(attaclay)、石灰石、石灰、白垩、红玄武土、黄土、粘土、白云石、硅藻土、硫酸钙、硫酸镁、氧化镁,磨碎的合成材料,肥料如硫酸铵、磷酸铵、硝酸铵、尿素,以及植物来源的产品如谷粉、树皮粉、木粉和坚果壳粉,纤维素粉和其它固体载体。 Examples of solid carriers are mineral earths such as silica gels, silicates, talc, kaolin, activated clay (Attaclay), limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate , magnesium oxide, ground synthetic materials, fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas, and products of vegetable origin such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders and other solid carriers .

配制剂通常包含0.01-95重量%,优选0.1-90重量%的活性化合物。 The formulations comprise from 0.01 to 95% by weight, preferably from 0.1 to 90% by weight of the active compound. 活性化合物以90-100%,优选95-100%的纯度(根据NMR谱)使用。 90-100% of active compound, preferably 95-100% pure (according to NMR spectrum).

对于种子处理,各种配制剂可在稀释2-10倍后得到活性化合物在即用制剂中的0.01-60重量%,优选0.1-40重量%的浓度。 For seed treatment purposes, respective formulations can be ready to use formulation having an active compound of 0.01 to 60 wt% in diluted 2-10 fold in a concentration of preferably 0.1 to 40% by weight.

下列为配制剂实例: The following are examples of formulations:

1.用水稀释的产品 1. The product was diluted with water

对于种子处理,这些产品可稀释或不经稀释而施用于种子。 For seed treatment purposes, these products can be applied to the seed diluted or undiluted.

A水溶性浓缩物(SL、LS) A Water-soluble concentrates (SL, LS)

将10重量份活性化合物溶于90重量份水或水溶性溶剂中。 10 parts by weight of active compound is dissolved in 90 parts by weight of water or a water-soluble solvent. 或者,加入湿润剂或其它助剂。 As an alternative, wetting agents or other auxiliaries. 活性化合物经水稀释溶解。 Active compound dissolves upon dilution with water. 以此方式得到活性化合物含量为10重量%的配制剂。 In this way an active compound content of 10% by weight of the formulation.

B分散性浓缩物(DC) B Dispersible concentrates (DC)

将20重量份活性化合物溶于70重量份环己酮中并加入10重量份分散剂如聚乙烯基吡咯烷酮。 20 parts by weight of active compound is dissolved in 70 parts by weight of cyclohexanone with addition of 10 parts by weight of a dispersant, for example polyvinylpyrrolidone. 用水稀释得到分散体。 Dilution with water gives a dispersion. 活性化合物含量为20重量%。 The active compound content of 20 wt%.

C乳油(EC) C concentrates (EC)

将15重量份活性化合物溶于75重量份二甲苯中并加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(在每种情况下为5重量份)。 15 parts by weight of active compound is dissolved in 75 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). 用水稀释得到乳液。 Dilution with water gives an emulsion. 该配制剂的活性化合物含量为15重量%。 The active compound content of the formulation was 15 wt%.

D乳液(EW、EO、ES) D Emulsions (EW, EO, ES)

将25重量份活性化合物溶于35重量份二甲苯中并加入十二烷基苯磺酸钙和蓖麻油乙氧基化物(在每种情况下为5重量份)。 25 parts by weight of the active compound is dissolved in 35 parts by weight of xylene with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). 借助乳化机(如Ultraturrax)将该混合物加入30重量份水中并制成均相乳液。 By means of an emulsifying machine (e.g. Ultraturrax) and the mixture was added 30 parts by weight of water and made into a homogeneous emulsion. 用水稀释得到乳液。 Dilution with water gives an emulsion. 配制剂的活性化合物含量为25重量%。 Active compound content of 25% by weight of the formulation.

E悬浮液(SC、OD、FS) E Suspensions (SC, OD, FS)

在搅拌的球磨机中,将20重量份活性化合物粉碎并加入10重量份分散剂和湿润剂以及70重量份水或有机溶剂,得到细碎活性化合物悬浮液。 In an agitated ball mill, 20 parts by weight of the active compounds are comminuted with addition of 10 parts by weight of dispersants and wetting agents and 70 parts by weight of water or an organic solvent to give a fine active compound suspension. 用水稀释得到稳定的活性化合物悬浮液。 Dilution with water gives a stable suspension of the active compound. 配制剂中活性化合物含量为20重量%。 The active compound content 20% by weight of the formulation.

F水分散性颗粒和水溶性颗粒(WG、SG) F Water-dispersible granules and water-soluble granules (WG, SG)

将50重量份活性化合物细碎研磨并加入50重量份分散剂和湿润剂,借助工业装置(如挤出机、喷雾塔、流化床)将其制成水分散性或水溶性颗粒。 50 parts by weight of the active compound are ground finely with addition of 50 parts by weight of dispersants and wetting agents, it was made water-dispersible or water-soluble granules by means of industrial devices (e.g. extrusion, spray tower, fluidized bed). 用水稀释得到稳定的活性化合物分散体或溶液。 Dilution with water gives a stable dispersion or solution of the active compound. 该配制剂的活性化合物含量为50重量%。 Active compound content of the formulation is 50 wt%.

G水分散性粉末和水溶性粉末(WP、SP、SS、WS) G Water-dispersible powders and water-soluble powders (WP, SP, SS, WS)

将75重量份活性化合物在转子-定子磨机中研磨并加入25重量份分散剂、湿润剂和硅胶。 75 parts by weight of the active compound in a rotor - stator mill was added 25 parts by weight of dispersants, wetters and silica gel. 用水稀释得到稳定的活性化合物分散体或溶液。 Dilution with water gives a stable dispersion or solution of the active compound. 该配制剂的活性化合物含量为75重量%。 The active compound content of the formulation is 75 wt%.

H凝胶配制剂(GF) H Gel formulations (GF)

在球磨机中,将20重量份活性化合物、10重量份分散剂,1重量份胶凝剂以及70重量份水或有机溶剂研磨,得到细碎悬浮液。 In a ball mill, 20 parts by weight of active compound, 10 parts by weight of dispersants, 1 part by weight of gelling agent and 70 parts by weight of water or an organic solvent are ground to give a fine suspension. 用水稀释得到活性化合物含量为20重量%的稳定的悬浮液。 Dilution with water gives an active compound content of 20% by weight of a stable suspension.

2.不经稀释而施用的产品 2. applied undiluted product

I可撒粉粉末(DP、DS) I Dustable powders (DP, DS)

将5重量份活性化合物细碎研磨并与95重量份细碎高岭土充分混合。 5 parts by weight of the active compound are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. 这得到活性化合物含量为5重量%的可撒粉产品。 This gives an active compound content of 5% by weight of dustable product.

J颗粒(GR、FG、GG、MG) J Granules (GR, FG, GG, MG)

将0.5重量份活性化合物细碎研磨并结合99.5重量份载体。 0.5 parts by weight of the active compound is ground finely and associated with 99.5 parts by weight of carriers. 现行方法是挤出、喷雾干燥或流化床方法。 Current methods are extrusion, spray-drying or the fluidized bed. 这得到不经稀释而施用的活性化合物含量为0.5重量%的颗粒。 This gives a content of active compound administered undiluted to 0.5% by weight of the particles.

K ULV溶液(UL) K ULV solutions (UL)

将10重量份活性化合物溶于90重量份有机溶剂如二甲苯中。 10 parts by weight of active compound is dissolved in 90 parts by weight of an organic solvent such as xylene. 这得到不经稀释而施用的活性化合物含量为10重量%的产品。 This gives a content of active compound administered undiluted 10% by weight of the product.

通常,将水溶性浓缩物(LS)、悬浮液(FS)、可撒粉粉末(DS)、水分散性和水溶性粉末(WS、SS)、乳液(ES)、乳油(EC)和凝胶配制剂(GF)用于种子处理。 Typically, water-soluble concentrate (the LS), suspensions (FS), dustable powders (the DS), water-dispersible and water-soluble powders (WS, SS), emulsions (ES), emulsifiable concentrates (EC) and gels formulations (GF) used for seed treatment. 这些配制剂可以不经稀释的形式或优选以经稀释的形式施用于种子。 These formulations can undiluted form or preferably in the form applied to the seed diluted. 施用可在播种之前进行。 Administration may be carried out before sowing.

在优选实施方案中,将FS配制剂用于种子处理。 In a preferred embodiment, a FS formulation is used for seed treatment. FS配制剂通常可包含1-800g/l活性成分、1-200g/l表面活性剂、0-200g/l防冻剂、0-400g/l粘合剂、0-200g/l颜料和至多1升溶剂,优选水。 FS formulation may contain 1-800g / l of active ingredient, 1-200g / l of surfactant, 0-200g / l antifreeze agents, 0-400g / l binders, 0-200g / l pigment and up to 1 liter The solvent, preferably water.

活性化合物可以直接、以其配制剂形式或由其制备的使用形式,如可直接喷雾溶液、粉末、悬浮液或分散体、乳液、油分散体、糊、可撒粉产品、撒播用材料或颗粒,借助喷雾、雾化、撒粉、撒播或浇灌来使用。 The active compounds can, in the form of their formulations or the use forms prepared therefrom, such as directly sprayable solutions, powders, suspensions or dispersions, emulsions, oil dispersions, pastes, dustable products, materials for spreading or granules , by means of spraying, atomizing, dusting, spreading or pouring. 使用形式完全取决于意欲的目的;意欲在每种情况下确保本发明活性化合物的最佳可能分布。 Use forms depend entirely on the intended purposes; is intended to ensure the finest possible distribution of the active compounds of the invention in each case.

含水使用形式可通过加入水由乳液浓缩物、糊或可湿性粉末(可喷雾粉末、油分散体)制备。 Aqueous use forms can, pastes or wettable powders (sprayable powders, oil dispersions) by adding water prepared from emulsion concentrates. 为制备乳液、糊或油分散体,可借助湿润剂、增粘剂、分散剂或乳化剂将该物质直接或溶于油或溶剂中后在水中均化。 To prepare emulsions, pastes or oil dispersions, by means of wetting agent, tackifier, dispersant or emulsifier or dissolved in an oil after the material was used directly or solvent, can be homogenized in water. 或者还可以制备由活性物质、湿润剂、增粘剂、分散剂或乳化剂以及合适的话溶剂或油组成的浓缩物且该浓缩物适于用水稀释。 Or also making concentrates composed of active substance, wetter, tackifier, dispersant or emulsifier and, if appropriate solvent or oil, and such concentrates are suitable for dilution with water.

即用制剂中的活性化合物浓度可在较宽范围内变化。 That can be varied within wide ranges The active compound concentration in the formulation. 其通常为0.0001-10%,优选0.01-1%。 Generally 0.0001%, preferably 0.01 to 1%.

活性化合物还可成功地以超低容量法(ULV)使用,其中可以施用包含超过95重量%活性化合物的配制剂或甚至可以在没有添加剂的情况下施用活性化合物。 The active compounds may also be used successfully in the ultra-low-volume process (ULV), it being possible to apply formulations comprising over 95% by weight of the formulation of the active compound, or even to apply the active compound without additives.

可以将各种类型的油、润湿剂、辅助剂、除草剂、杀真菌剂、其它农药或杀菌剂加入活性化合物中,合适的话恰在紧临使用之前(桶混合)加入。 May be various types of oils, wetters, adjuvants, herbicides, fungicides, other pesticides, or bactericides may be added to the active compounds, if appropriate (tank mix) until immediately prior to use. 这些试剂通常可以1∶100-100∶1,优选1∶10-10∶1的重量比与本发明试剂混合。 These agents can 1:100-100:1, preferably the weight ratio of the reagent mixing 1:10-10:1 present invention.

本发明的组合物还可以含有其他活性成分,例如其他农药,除草剂,肥料如硝酸铵、尿素、钾碱和酸性磷酸盐,植物毒素和植物生长调节剂和安全剂。 The composition of the present invention may also contain other active ingredients, for example other pesticides, herbicides, fertilizers such as ammonium nitrate, urea, potash, and superphosphate, phytotoxicants and plant growth regulators and safeners. 这些额外成分可以与上述组合物依次或结合使用,合适的话还在紧临使用前加入(桶混合)。 These additional ingredients may be used sequentially or in combination with the above-described compositions, if appropriate also added only immediately prior to use (tank mix). 例如可以在用其他活性成分处理之前或之后用本发明组合物喷雾植物。 For example, a plant may be sprayed with a composition of the invention prior to treatment with or after the other active ingredients.

化合物I和化合物II和III的混合物,或同时,即联合或分开使用化合物I和化合物II和III对宽范围的植物病原性真菌,尤其是选自子囊菌纲(Ascomycetes)、半知菌纲(Deuteromycetes)、Peronosporomycetes(同义词:卵菌纲(Oomycetes))和担子菌纲(Basidiomycetes)的真菌具有优异的活性。 A mixture of compound I and compound II and III, or the simultaneous, that is joint or separate use of the compounds I and compounds II and III on a wide range of phytopathogenic fungi, in particular selected from Ascomycetes (Ascomycetes), Deuteromycetes ( Deuteromycetes), Peronosporomycetes (synonym: oomycetes (oomycetes)) and Basidiomycetes (Basidiomycetes) fungi having excellent activity. 它们中的一些内吸有效且可以作为叶面杀真菌剂、拌种用杀真菌剂和土壤杀真菌剂用于作物保护中。 Some are systemically effective and can be used as foliar fungicides, fungicides for seed dressing and soil fungicides in crop protection.

它们对在各种栽培植物如香蕉、棉花、蔬菜(如黄瓜、豆类和葫芦科植物)、大麦、禾草、燕麦、咖啡、土豆、玉米、水果、稻、黑麦、大豆、西红柿、葡萄藤、小麦、观赏植物、甘蔗以及多种种子中防治大量真菌尤其重要。 They variety of cultivated plants such as bananas, cotton, vegetables (such as cucumbers, beans and cucurbits), barley, grass, oats, coffee, potatoes, corn, fruit, rice, rye, soybeans, tomatoes, grapes Especially important vine, wheat, ornamentals, sugarcane and a variety of seeds in controlling a large number of fungi.

化合物I和化合物II和III可以同时,即联合或分开施用,或依次施用,在分开施用的情况下,施用顺序通常对防治措施的结果没有任何影响。 Compound I and compounds II and III can be applied simultaneously, that is jointly or separately, or in succession, in the case of separate application, generally administered sequentially no effect on the result of the control measures.

它们对在各种栽培植物如小麦、黑麦、大麦、燕麦、稻、玉米、禾草、香蕉、棉花、大豆、咖啡、甘蔗、葡萄藤、水果和观赏植物以及蔬菜如黄瓜、豆类、西红柿、土豆和葫芦科植物以及这些植物的种子中防治大量真菌尤其重要。 They variety of cultivated plants, such as wheat, rye, barley, oats, rice, corn, grass, bananas, cotton, soybeans, coffee, sugar cane, vines, fruits and ornamental plants, and vegetables such as cucumbers, beans, tomatoes , seed potatoes and cucurbits, and these plants are particularly important in controlling a large number of fungi. 其还可用于由于包括基因工程在内的培育而对昆虫或真菌的侵袭具有抗性的作物中。 It may also be used comprising cultivating crops because of genetic engineering and are resistant to attack by insects or fungi. 此外,其还适用于防治尤其侵袭木材或葡萄藤根部的葡萄座腔菌属(Botryosphaeria)、柱孢属(Cylindrocarpon)、葡萄顶枯病菌(Eutypa lata)、鹅掌楸新丛赤壳菌(Neonectria liriodendri)和毛韧革菌(Stereum hirsutum)。 Furthermore, it is also suitable for controlling particular attack vines wood or roots of the genus Botryosphaeria (of Botryosphaeria), the genus Cylindrocarpon (Cylindrocarpon), grape top nodorum (Eutypa lata), tulip new cluster red globosum (Neonectria liriodendri) tough leather and fur (Stereum hirsutum) bacteria.

它们特别适合防治下列各种植物病害: They are particularly suitable for controlling various plant diseases following:

蔬菜、油菜籽、糖用甜菜、水果、稻和大豆以及土豆上的链格孢(Alternaria)属(例如早疫链格孢(A.solani)或细交链孢(A.alternata)),和西红柿上(例如早疫链格孢(A.solani)或细交链孢(A.alternata)),和小麦上的链格孢(Alternaria)属(黑霉病(black head mold)), Vegetables, rapeseed, sugar beet, fruit, rice and soybean, Alternaria (of Alternaria) on potatoes genus (e.g. Phytophthora early Alternaria (of A. solani) or Alternaria alternata (A.alternata)), and on tomatoes (Alternaria e.g. Phytophthora early (of A. solani) or Alternaria alternata (A.alternata)), and Alternaria (of Alternaria) on Triticum (black mold (black head mold)),

糖用甜菜和蔬菜上的丝囊霉(Aphanomyces)属, Sugar Aphanomyces (Aphanomyces) on sugar beet and vegetable species,

禾谷类和蔬菜上的壳二孢(Ascochyta)属,例如小麦上的小麦裾叶炫菌(Ascochyta tritici)(叶斑病), Cereals and Ascochyta (Ascochyta) on L. vegetables, such as wheat leaf garment Hyun bacteria on wheat (Ascochyta tritici) (leaf spot),

玉米、禾谷类、稻和草坪中的平脐蠕孢(Bipolaris)属和内脐蠕孢(Drechslera)属(例如玉米上的玉米小斑病菌(D.maydis)), Corn, cereals, rice and lawns, Helminthosporium the umbilical level (Bipolaris) and umbilical genus Helminthosporium (of Drechslera) genus (e.g. maydis on corn (D.maydis)),

禾谷类(例如小麦或大麦)中的禾白粉菌(Blumeria graminis)(白粉病), Cereals (such as wheat or barley) of Erysiphe graminis (Blumeria graminis) (powdery mildew),

草莓、蔬菜、花卉、葡萄藤和小麦上的灰葡萄孢(Botrytis cinerea)(根霉病)(head mold), Strawberries, vegetables, flowers, vines and on wheat Botrytis cinerea (Botrytis cinerea) (root mildew) (head mold),

莴苣上的莴苣盘梗霉(Bremia lactucae), Lettuce plate pullulans on lettuce (Bremia lactucae),

玉米、稻、糖用甜菜上的尾孢(Cercospora)属,例如大豆上的大豆尾孢(Cercospora sojina)(叶斑病)或菊池尾孢(Cercospora kikuchii)(叶斑病), Corn, rice, sugar Cercospora (for Cercospora) on sugar beet genus, e.g. soybean Cercospora (Cercospora sojina) (leaf spot) on soybeans or Kikuchi Cercospora (Cercospora kikuchii) (leaf spot),

小麦上的扁豆枝孢(Cladosporium herbarum)(干腐病(ear rot)), Cladosporium lentils on wheat (Cladosporium herbarum) (dry rot (ear rot)),

玉米、禾谷类和稻上的旋孢腔菌(Cochliobolus)属(例如禾谷类上的禾旋孢腔菌(Cochliobolus sativus),和稻上的宫部旋孢腔菌(Cochliobolusmiyabeanus)), Corn, cereals and Cochliobolus (Cochliobolus) on Oryza (e.g. Cochliobolus Wo (Cochliobolus sativus) on cereals, and Miyabe Cochliobolus on rice (Cochliobolusmiyabeanus)),

棉花上的剌盘孢(Colletotricum)属以及例如大豆上的毛豆炭疽病菌(Colletotrichum truncatum)(炭疽病), Colletotrichum puncture (Colletotricum) on Gossypium e.g. soybean and soybean on anthracnose (Colletotrichum truncatum) (anthrax),

大豆上的山扁豆生棒孢(Corynespora cassiicola)(叶斑病) Cassia Health Corynespora (Corynespora cassiicola) (leaf spot) on soybeans

大豆上的白纹羽束丝菌(Dematophora necatrix)(根/颈腐病) Aedes feather beam rhusiopathiae (Dematophora necatrix) (root / crown rot) on soybeans

大豆上的菜豆间座壳(Diaporthe phaseolorum)(茎病害) Zama bean shell (Diaporthe phaseolorum) (stem disease) on soybeans

玉米、禾谷类、稻和草坪上,大麦上(例如大麦网斑内脐蠕孢(D.teres))或小麦上(例如D.tritci-repentis)的内脐蠕孢(Drechslera)属、核腔菌(Pyrenophora)属, On corn, cereals, rice and lawns, barley (e.g., Barley Helminthosporium teres umbilical (D.teres)) or on wheat (e.g. D.tritci-repentis) in umbilical Helminthosporium (of Drechslera) species, Pyrenophora bacteria (Pyrenophora) genus,

由Phaeoacremonium chlamydosporium、Ph.Aleophilum和Formitipora punctata(同义词斑孔木层孔菌(Phellinus punctatus))引起的葡萄藤上的埃斯卡(Esca); Esca on grapevines a Phaeoacremonium chlamydosporium, Ph.Aleophilum and Formitipora punctata (synonym spot hole Phellinus (Phellinus punctatus)) induced (at the Esca);

葡萄藤上的痂囊腔菌(Elsinoe empelina), Elsinochrome bacteria on the vine (Elsinoe empelina),

小麦上的附球菌属(Epicoccum)(黑霉病) Genus Epicoccum (Epicoccum) (black mold) on wheat

玉米上的突脐蠕孢(Exserohilum)属, Exserohilum Helminthosporium (belonging to Exserohilum) on Zea,

黄瓜上的二孢白粉菌(Erysiphe cichoracearum)和单丝壳白粉菌(Sphaerotheca fuliginea), Diplodia powdery mildew (Erysiphe cichoracearum) on cucumber Sphaerotheca fuliginea and Erysiphe graminis (Sphaerotheca fuliginea),

各种植物上的镰孢霉(Fusarium)属和轮枝孢(Verticillium)属,例如禾谷类(例如小麦或大麦)上的禾谷镰刀菌(F.graminearum)或大刀镰孢(F.culmorum)(根腐病)或西红柿上的尖镰孢(F.oxysporum),和大豆上的真马特腐皮镰孢(Fusarium Solani)(茎病害) Fusarium on various plants (of Fusarium) and Verticillium genus (of Verticillium) genus, (F.graminearum) (F.culmorum) e.g. F. graminearum on cereals (such as wheat or barley), or Fusarium culmorum (root rot) or Fusarium oxysporum (F.oxysporum) on tomatoes, Fusarium and true Matt (Fusarium solani) (stem disease) on soybeans

禾谷类(例如小麦或大麦)上的禾顶囊壳(Gaeumanomyces graminis)属(根霉病(root black)), Cereals (such as wheat or barley) Gaeumannomyces graminis (Gaeumanomyces graminis) on the case (root mildew (root black)),

禾谷类和稻上的赤霉(Gibberella)属(例如稻上的藤仓赤霉(Gibberellafujikuroi)), Cereals and gibberellic (Gibberella) on Oryza (e.g. Fujikura gibberellic on rice (Gibberellafujikuroi)),

葡萄藤和其它植物上的围小丛壳(Glomerella cingulata), Vines and other plants around the Glomerella (Glomerella cingulata),

稻上的革兰氏染色配合物(Grainstaining complex), Gram staining complex on rice (Grainstaining complex),

葡萄藤上的葡萄球座菌(Guignardia budwelli), Grapes on the vine tee bacteria (Guignardia budwelli),

玉米和稻上的长蠕孢(Helminthosporium)属, Corn and Helminthosporium (Helminthosporium) on Oryza,

葡萄藤上的褐斑拟棒束孢(Isariopsis clavispora), Quasi Isaria brown spots on grapevines (Isariopsis clavispora),

大豆上的菜豆格孢(Macrophomina phaseolina)(根/茎腐病), Alternaria on soy bean (Macrophomina phaseolina) (root / stem rot),

禾谷类(例如小麦和大麦)上的Michrodochium nivale(雪霉病), Michrodochium nivale on cereals (e.g. wheat and barley) (snow mold),

大豆上的Microsphaera diffusa(白粉病), Microsphaera diffusa on soybean (powdery mildew),

禾谷类、香蕉和花生上的球腔菌(Mycosphaerella)属,例如小麦上的禾生球腔菌(M.graminicola)或香蕉上的M.fijiesis, Cereals, Leptosphaeria (Mycosphaerella) on bananas and Arachis, e.g. Mycosphaerella graminicola (M.graminicola) on wheat or M.fijiesis on bananas,

甘蓝上的霜霉(Peronospora)属(例如芸苔霜霉(P.brassicae)),洋葱上的(例如P.destructor),和例如大豆上的东北霜霉(Peronosporamanshurica)(霜霉病), Downy mildew (Peronospora) on Brassica (e.g. Brassica downy mildew (P.brassicae)),, and the northeast e.g. soybean downy mildew (Peronosporamanshurica) (downy mildew) on onion (e.g. P.destructor),

大豆上的豆薯层锈菌(Phakopsora pachyrhizi)(大豆锈病)和山马蟥层锈菌(Phakopsara meibomiae)(大豆锈病), P. pachyrhizi on soybean (Phakopsora pachyrhizi) (soybean rust) and mountain leech pachyrhizi (Phakopsara meibomiae) (soybean rust),

大豆上的Phialophora gregata(茎病害), Phialophora gregata on soybean (stem disease),

向日葵、葡萄藤和大豆上的拟茎点霉(Phomopsis)属(如葡萄藤上的葡萄拟茎点霉(P.viticola)和大豆上的Phomopsis phaseoli), Phomopsis (Phomopsis) on sunflowers, vines and soya genus (e.g., grapes on grapevines Phomopsis (P.viticola) and on soybeans Phomopsis phaseoli),

各种植物上的疫霉属(Phytophthora),例如柿子椒上的辣椒疫霉(P.capsici),大豆上的大雄疫霉(Phytophthora megasperma)(叶/茎腐病),土豆和西红柿上的致病疫霉(Phytophthora infestans), Phytophthora on various plants (of Phytophthora), for example the pathogenic Phytophthora capsici (P.capsici) on bell peppers, Phytophthora megasperma mildew (Phytophthora megasperma) (leaf / stem rot) on soybeans, potatoes and tomatoes Phytophthora (Phytophthora infestans),

葡萄藤上的葡萄生单轴霉(Plasmopara viticola), Viticola on grapevines (Plasmopara viticola),

苹果上的苹果白粉病菌(Podosphaera leucotricha), Apple powdery mildew on apple (Podosphaera leucotricha),

禾谷类上(小麦或大麦)的小麦基腐病菌(Pseudocercosporellaherpotrichoides)(眼斑病), On cereals (wheat or barley) wheat-Rot (Pseudocercosporellaherpotrichoides) (eyespot),

各种植物上的假霜霉(Pseudoperonospora)属,例如黄瓜上的古巴假霜霉(P.cubenis)或啤酒花上的葎草假霜霉(P.humili), All kinds of false downy mildew (Pseudoperonospora) on the plant species, such as Pseudoperonospora cubensis (P.cubenis) on cucumber downy mildew or false Humulus (P.humili) on hops,

葡萄藤上的Pseudopezicula tracheiphilai, Pseudopezicula tracheiphilai on the vine,

各种植物上的柄锈菌(Puccinia)属,例如禾谷类(例如大麦和小麦)上的小麦锈病菌(P.triticina),条锈病菌(P.striformis),大麦锈病菌(P.hordei)或禾柄锈菌(P.graminis)或芦笋上(芦笋锈病菌(P.asparagi)), Various Puccinia (Puccinia) on a plant genus, for example, wheat rust fungus (P.triticina) on cereals (e.g. wheat and barley), yellow rust (P.striformis), rust of barley (P. hordei) or Puccinia graminis (P. graminis) or on asparagus (asparagus rust (P.asparagi)),

小麦上的稻瘟病菌(Pyricularia oryzae)、笹木伏革菌(Corticiumsasakii)、帚梗柱孢属(Sarocladium oryzae)、稻叶鞘腐败病(S.attenuatum)、Pyrenophora tritici-repentis(叶斑病)或大麦上的Pyrenophora teres(网斑病) Magnaporthe grisea (Pyricularia oryzae) on wheat, Sasagawa wood fungus Corticium (Corticiumsasakii), Alternaria broom stems column (Sarocladium oryzae), rice sheath rot (S.attenuatum), Pyrenophora tritici-repentis (leaf spot) or barley on Pyrenophora teres (net blotch)

稻上的稻叶黑粉菌(Entyloma oryzae), Inaba smut fungus on rice (Entyloma oryzae),

草坪和禾谷类上的稻梨孢菌(Pyricularia grisea), Pyricularia fungus on lawns and cereals (Pyricularia grisea),

草坪、稻、玉米、小麦、棉花、油菜籽、向日葵、糖用甜菜、蔬菜和其他植物上的腐霉(Pythium)属,(例如终极腐霉(P.ultimum)或瓜果腐霉(P.aphanidermatum)), Lawn, rice, corn, wheat, cotton, rapeseed, sunflowers, sugar Pythium (Pythium) on sugar beet, vegetables and other plant genus, (e.g. Pythium ultimum (P.ultimum) or Pythium (P. aphanidermatum)),

大麦上的Ramularia collo-cygni(Ramularia/晒斑(sunburn)复合物/生理叶斑病), Ramularia collo-cygni on barley (Ramularia / sunburn (Sunburn) complex / Physiological leaf spot),

棉花、稻、土豆、草坪、玉米、油菜籽、土豆、糖用甜菜、蔬菜和各种其他植物上的丝核菌(Rhizoctonia)属,例如大豆上的立枯丝核病菌(Rhizoctonia solani)(根/茎腐病)或小麦或大麦上的禾谷丝核菌(Rhizoctoniacerealis)(黄斑病(sharp eyspot)), Cotton, rice, potatoes, lawns, corn, rapeseed, potatoes, sugar beet, vegetables and various Rhizoctonia (, Rhizoctonia) on other plant genus, e.g. pathogen Rhizoctonia (Rhizoctonia solani) on soybean (Root / stem rot) or wheat, or Rhizoctonia cerealis on barley (Rhizoctoniacerealis) (maculopathy (sharp eyspot)),

大麦(叶斑病)、黑麦和黑小麦上的黑麦喙孢(Rhynchosporium secalis), Barley (leaf spot), rye and rye beak spores on triticale (Rhynchosporium secalis),

油菜籽、向日葵和大豆上的核盘菌(Sclerotinia)属,例如大豆上的核盘菌(Sclerotinia sclerotiorum)(茎病害)或Sclerotinia rolfsii(茎病害), Rapeseed, sunflower and Sclerotinia sclerotiorum (Sclerotinia) the genus Glycine, for example, Sclerotinia sclerotiorum (Sclerotinia sclerotiorum) (stem disease) or Sclerotinia rolfsii (stem disease) on soybeans bacteria,

大豆上的大豆壳针孢(Septoria glycines)(叶斑病), Septoria glycines on soybean (Septoria glycines) (leaf spot),

小麦上的小麦壳针孢(Septoria tritici)(叶枯病(leaf septoria))和颖枯壳多孢(Stagonospora nodorum), Septoria tritici (Septoria tritici) (leaf blight (leaf septoria)) and the wheat septoria nodorum spore chitin (Stagonospora nodorum),

葡萄藤上的葡萄钩丝壳(Erysiphe(同义词Uncinula neeator), Uncinula on grapevines (Erysiphe (synonym Uncinula neeator),

玉米和草坪上的Setospaeria属, Setospaeria on corn and lawns,

玉米上的丝轴黑粉菌(Sphacelotheca reilinia), Ustilago wire axis on corn (Sphacelotheca reilinia),

小麦上的颖枯壳多孢(Stagonospora nodorum)(颖枯病(ear septoria)), Septoria nodorum on wheat erythraea shell (Stagonospora nodorum) (glume blotch (ear septoria)),

大豆和棉花上的根串珠霉(Thievaliopsis)属, Thielaviopsis root (Thievaliopsis) on soybeans and cotton genus,

禾谷类上的腥黑粉菌(Tilletia)属, Tilletia (Tilletia) on cereals belong,

小麦或大麦上的肉孢核瑚菌(Typhula incarnate)(雪霉病), Wheat or meat Alternaria fungus on barley nuclear coral (Typhula incarnate) (snow mold),

禾谷类、玉米和甘蔗上的黑粉菌(Ustilago)属(例如玉米上的玉蜀黍黑粉菌(U.maydis)), Cereals, maize and Ustilago (Ustilago) on Saccharum (e.g., Ustilago maydis on corn (U.maydis)),

苹果和梨上的黑星菌(Venturia)属(黑星病)(例如苹果上的苹果黑星病(V.in aequalis))。 Scab fungus (Venturia) on apples and pear (scab) (eg apple scab (V.in aequalis) on apples).

目标作物可为常规植物的作物或基因修饰植物的作物(″GM植物″或″GMO″)。 Target crops crop plants ( "GM plants" or "GMO") genes can be modified to conventional plants or crops.

为此,本发明组合物还适合用于有用植物,尤其是禾谷类、棉花、大豆、糖用甜菜、甘蔗、种植作物(例如柑橘类水果、咖啡、香蕉)、油菜、玉蜀黍和稻的抗除草剂、抗害虫和/或抗真菌转基因作物。 To this end, compositions of the invention are also suitable for useful plants, especially cereals, cotton, soybeans, sugar beets, sugar cane, plantation crops (e.g. citrus fruits, coffee, bananas), rape, maize and rice against the herbicidal agents, pest-resistant and / or antifungal transgenic crops.

抗除草剂作物应理解为包括借助常规育种或基因工程方法而耐受多种除草剂或多类除草剂(例如ALS、GS、EPSPS、PPO和HPPD抑制剂)的那些作物。 Herbicide Resistant Crops are to be understood as including by means of conventional breeding or genetic engineering methods rather tolerant to herbicides or classes of herbicides (for example ALS, GS, EPSPS, PPO and HPPD inhibitors) as a crop. 通过常规育种方法而耐受例如咪唑啉酮如咪草啶酸(imazamox)的作物的实例为 By conventional breeding methods, such as for example imidazolinone tolerant crop Examples imazamox (imazamox) is 夏油菜(卡诺拉(canola))。 Summer oilseed rape (canola (canola)). 通过基因工程方法而耐受除草剂的作物的实例为抗例如草甘膦(glyphosate)或草铵膦(glufosinate)的玉米品种,其分别可以商标名 Examples of crops by genetic engineering methods, for example, an anti-herbicide-tolerant glyphosate (glyphosate) or glufosinate (glufosinate) maize varieties, which are the trade name with 购得。 Purchased.

对本发明而言,抗害虫和/或抗真菌转基因有用植物应明确理解为包括除具有抗害虫性和/或抗真菌性之外还具有除草剂耐受性的那些有用植物。 For the present invention, pest-resistant and / or antifungal transgenic useful plants should be clearly understood to include in addition to a pest-resistant and / or anti-fungal properties than those of useful plants further herbicide tolerance. 根据本发明,在除草剂耐受性有用植物中,优选具有对草甘膦、草铵膦(glufosinate-ammonium)、ALS(乙酰乳酸合成酶)抑制剂,例如磺酰脲,如氟嘧磺隆(primisulfuron)、氟丙黄隆(prosulfuron)及三氟啶黄隆(trifloxysulfuron))或溴苯腈(bromoxynil)的耐受性的有用植物,例如Bt11玉蜀黍或 According to the present invention, the herbicide-tolerant useful plants, preferably glyphosate, glufosinate (glufosinate-ammonium), ALS (acetolactate synthase) inhibitors, such as sulfonylureas, such as primisulfuron (primisulfuron), Long-fluoro-propan-yellow (of prosulfuron) and trifloxysulfuron Huang Long (trifloxysulfuron)) or bromoxynil (bromoxynil) tolerance of useful plants, for example, Bt11 maize or 玉蜀黍。 corn.

对本发明而言,抗害虫转基因作物植物应理解为通过使用重组DNA技术进行转化而使其能够合成一种或多种选择性作用毒素,例如由产生毒素的细菌,特别是那些芽孢杆菌属(Bacillus)细菌已知的毒素的植物。 For the present invention, pest-resistant transgenic crop plants are understood to be by the use of recombinant DNA techniques capable of synthesising transformed to one or more selectively acting toxins, for example, from toxin-producing bacteria, especially those of the genus Bacillus (Bacillus ) plant known bacterial toxins.

可通过这些转基因植物表达的毒素例如包括杀虫蛋白,如来自蜡状芽孢杆菌(Bacillus cereus)或日本甲虫芽孢杆菌(Bacillus popilliae)的杀虫蛋白;或来自苏云金芽孢杆菌(Bacillus thuringiensis)的杀虫蛋白,例如α-内毒素,如CryIA(b)、CryIA(c)、CryIF、CryIF(a2)、CryIIA(b)、CryIIIA、CryIIIB(bi)或Cry9c,或植物杀虫蛋白(VIP),如VIP1、VIP2、VIP3或VIP3A;或寄生在线虫上细菌,例如发光杆菌属(Photorhabdus spp.),致病杆菌属(Xenorhabdus spp.),如发光杆菌(Photorhabdus luminescens)、嗜线虫致病杆菌(Xenorhabdus nematophilus))的杀虫蛋白;由动物产生的毒素,如蝎毒素、蜘蛛类动物毒素、黄蜂毒素及其它昆虫特异性神经毒素;由真菌产生的毒素,例如链霉菌(Streptomycetes)毒素;植物凝血素,例如豌豆凝血素、大麦凝血素或雪花莲凝血素;凝集素;蛋白酶抑制剂,例如胰蛋白酶抑制剂、丝氨酸蛋白酶抑制剂 Toxins can be expressed by transgenic plants include, for example, insecticidal proteins, such as insecticidal proteins from Bacillus cereus (Bacillus cereus), or Japanese beetle bacillus (Bacillus popilliae); and from or insecticidal Bacillus thuringiensis (Bacillus thuringiensis) of proteins, for example, in α- toxin, such as CryIA (b), CryIA (c), CryIF, CryIF (a2), CryIIA (b), CryIIIA, CryIIIB (bi) or Cry9c, or insecticidal protein (the VIP), such as VIP1, VIP2, VIP3 or VIP3A; (. Photorhabdus spp) (. Xenorhabdus spp) parasitic on a nematode, or bacterial, e.g. Photobacterium, Xenorhabdus, such as Photobacterium (Photorhabdus luminescens), Xenorhabdus nematophilus (of Xenorhabdus nematophilus)) insecticidal proteins; toxins produced by animals such as scorpion toxins, arachnids toxins, wasp toxins and other insect-specific neurotoxins; toxins produced by fungi, e.g. Streptomyces (Streptomycetes) toxin; phytohemagglutinin for example pea lectin, or barley lectin Galanthus nivalis lectin; lectin; protease inhibitors, such as trypsin inhibitors, serine protease inhibitors 马铃薯块茎储藏蛋白(patatin)、血清半胱胺酸蛋白酶(cystatin)抑制剂、木瓜蛋白酶抑制剂;核糖体失活蛋白(RIP),例如蓖麻毒蛋白、玉蜀黍RIP、相思豆毒蛋白、丝瓜籽毒蛋白(luffin)、皂草毒蛋白(saporin)或葫芦毒蛋白(bryodin);类固醇代谢酶,如3-羟基类固醇氧化酶、蜕皮类固醇-UDP-糖基转移酶、胆固醇氧化酶、蜕皮激素抑制剂、HMG-COA还原酶、离子通道阻断剂如钠或钙通道的阻断剂、保幼激素酯酶、利尿激素受体、1,2-苯二乙烯合成酶、联苄合成酶、几丁质酶及葡聚糖酶。 Storage protein of potato tubers (a patatin), serum cysteine ​​protease (Cystatin) inhibitors, papain inhibitors; ribosome inactivating protein (the RIP), for example, ricin, maize RIP, abrin, silk seeds toxic protein (Luffin), saporin (eg, saporin) or gourd toxic protein (bryodin); steroid metabolizing enzymes such as 3-hydroxysteroid oxidase, ecdysteroid -UDP- glycosyl transferase, cholesterol oxidases, ecdysone inhibition blocker agents, HMG-COA-reductase, ion channel blockers, such as sodium or calcium channels, juvenile hormone esterase, diuretic hormone receptors, 1,2-divinyl synthase, bibenzyl synthase, several chitinase enzymes and glucanase.

对本发明而言,应理解包括以下物质:d-内毒素,例如CryIA(b)、CryIA(c)、CryIF、CryIF(a2)、CryIIA(b)、CryIIIA、CryIIIB(bi)或Cry9c,或植物杀虫蛋白(VIP),例如VIP1、VIP2、VIP3或VIP3A,还明确包括杂交毒素、截短毒素(truncated toxin)和修饰毒素。 For the present invention, it should be understood to include the following: the d- endotoxin, e.g. CryIA (b), CryIA (c), CryIF, CryIF (a2), CryIIA (b), CryIIIA, CryIIIB (bi) or Cry9c, or plant insecticidal proteins (VIP), for example VIP1, VIP2, VIP3 or VIP3A, also explicitly include hybrid toxins, truncated toxins (truncated toxin) and modified toxins. 杂交毒素通过重新组合那些蛋白的不同结构域而重组产生(例如参见WO 02/15701)。 Hybrid toxins by recombining different domains of those proteins recombinantly produced (see, e.g. WO 02/15701). 截短毒素的实例为截短CryIA(b),其以在如下文所述的Syngenta Seeds SAS的Bt11玉蜀黍中表达。 Examples of truncated toxin is a truncated CryIA (b), which is expressed in the Bt11 maize from Syngenta Seeds SAS, as described below in. 在修饰毒素的情况下,天然存在毒素中的一个或多个氨基酸被替换。 In the case of modified toxins, naturally occurring toxin in one or more amino acids are replaced. 在这种氨基酸替换中,优选将非天然存在的蛋白酶识别序列插入毒素中,例如在CryIIIA055的情况下,将组织蛋白酶-D-识别序列插入CryIIIA毒素中(参见WO 03/018810)。 In such amino acid substitutions it is preferably non-naturally present protease recognition sequences are inserted into the toxin, for example in the case of CryIIIA055, a cathepsin -D- CryIIIA toxin recognition sequences are inserted (see WO 03/018810).

这些毒素或能够合成这些毒素的转基因植物的实例例如公开在EP-A374 753、WO 93/07278、WO 95/34656、EP-A 427 529、EP-A 451 878和WO 03/052073中。 Examples of such toxins or transgenic plants capable of synthesizing such toxins are disclosed, for example, in EP-A374 753, WO 93/07278, WO 95/34656, EP-A 427 529, EP-A 451 878 und WO 03/052073.

生产这些转基因植物的方法通常是本领域熟练技术人员已知的,且例如描述在上文提及的出版物中。 Methods for producing such transgenic plants are generally known to those skilled in the art, and described for example in the publications mentioned above. CryI型脱氧核糖核酸及其制备例如由WO95/34656、EP-A 367 474、EP-A 401 979和WO 90/13651已知。 CryI-type deoxyribonucleic acids and their preparation, for example, EP-A 367 474, EP-A 401 979 are known from WO 90/13651 and WO95 / 34656.

转基因植物中所含的毒素为植物提供了对有害昆虫的耐受性。 Toxin contained in the transgenic plants provides the plants tolerance to harmful insects. 这些昆虫可属于任何昆虫分类,但尤其常见于甲虫(鞘翅目(Coleoptera))、双翅昆虫(双翅目(Diptera))和蝴蝶(鳞翅目(Lepidoptera))中。 These insects may belong to any insect classification, but especially common in beetles (Coleoptera (Coleoptera)), two-winged insects (Diptera (Diptera)) and butterflies (Lepidoptera (Lepidoptera)) in.

以下不同分类的有害昆虫在玉蜀黍作物中尤其常见: The following classification of various harmful insects, especially common in maize crops:

Ostrinia nubilalis,欧洲玉米螟, Ostrinia nubilalis, European corn borer,

Agrotis ipsilon,小地老虎, Agrotis ipsilon, black cutworm,

Helicoverpa zea,玉米穗虫, Helicoverpa zea, corn earworm,

Spodoptera frugiperda,草地夜蛾, Spodoptera frugiperda, fall armyworm,

Diatraea grandiosella,西南玉米杆草螟, Diatraea grandiosella, southwestern corn borer grass stem,

Elasmopalpus lignosellus,南美玉米苗斑螟, Elasmopalpus lignosellus, South Oligochroa corn seedlings,

Diatraea saccharalis,小蔗螟, Diatraea saccharalis, small sugarcane borer,

Diabrotica virgifera virgifera,西部玉米根叶甲, Diabrotica virgifera virgifera, the western corn rootworm beetle,

Diabrotica longicornis barberi,北方长角叶甲, Diabrotica longicornis barberi, northern horned beetle,

Diabrotica undecimpunctata howardi,南方玉米根叶甲, Diabrotica undecimpunctata howardi, southern corn rootworm,

Melanotus spp.,金针虫属 Melanotus spp., Wireworms belong

Cyclocephala borealis,北方圆头犀金龟(蛴螬), Cyclocephala borealis, northern round rhinoceros beetles (grubs),

Cyclocephala immaculata,南方圆头犀金龟(蛴螬), Cyclocephala immaculata, southern round rhinoceros beetles (grubs),

Popillia japonica,日本丽金龟子, Popillia japonica, Japan, Korea beetle,

Chaetocnema pulicaria,玉米跳甲, Chaetocnema pulicaria, corn flea beetle,

Sphenophorus maidis,玉米隐喙象, Sphenophorus maidis, maize Cryptorrhychinae,

Rhopalosiphum maidis,玉米蚜, Rhopalosiphum maidis, corn aphid,

Anuraphis maidiradicis,玉米尾蚜, Anuraphis maidiradicis, corn aphid,

Blissus leucopterus leucopterus,玉米长蝽, Blissus leucopterus leucopterus, corn chinch bug,

Melanoplus femurrubrum,红足黑蝗, Melanoplus femurrubrum, red foot black locust,

Melanoplus sanguinipes,迁飞黑蝗, Melanoplus sanguinipes, black locust migration,

Hylemya platura,种蝇, Hylemya platura, kinds of flies,

Agromyza parvicornis,玉米斑潜蝇, Agromyza parvicornis, corn leaf miner,

Anaphothrips obscurus,黄呆蓟马, Anaphothrips obscurus, yellow thrips stay,

Solenopsis milesta,盗窃蚁, Solenopsis milesta, theft ant,

Tetranychus urticae,二点叶螨。 Tetranychus urticae, two-spotted spider mites.

含有一个或多个编码杀虫剂抗性及表达一种或多种毒素的基因的转基因植物是已知的,且其中一些可购得。 Containing one or more encoding an insecticidal resistance and express one or more genes in transgenic plant toxins are known and some are commercially available. 这些植物的实例为: Examples of these plants are: (表达CryIA(b)毒素的玉蜀黍品种);YieldGard (Expressing CryIA (b) toxin maize varieties); YieldGard (表达CryIIIB(bi)毒素的玉蜀黍品种);YieldGard (Maize variety expressing CryIIIB (bi) toxin); YieldGard (表达CryIA(b)和CryIIIB(bi)毒素的玉蜀黍品种); (Expressing CryIA (b) and maize varieties CryIIIB (bi) toxin); (表达Cry9(c)毒素的玉蜀黍品种);Herculex (Maize variety expressing Cry9 (c) toxin); Herculex (表达CryIF(a2)毒素和草胺膦(phosphinothricin)N-乙酰基-转移酶(PAT)以获得对除草剂草铵膦的耐受性的玉蜀黍品种);NuCOTN (Expression CryIF (a2) toxin and glufosinate (phosphinothricin) N- acetyl - transferase (PAT) to achieve tolerance to the herbicide maize varieties glufosinate ammonium); Nucotn (表达CryIA(c)毒素的棉花品种);Bollgard (Cotton cultivar expressing CryIA (c) toxin); Bollgard (表达CryIA(c)毒素的棉花品种);Bollgard (Cotton cultivar expressing CryIA (c) toxin); Bollgard (表达CryIA(c)和CryIIA(b)毒素的棉花品种); (Cotton cultivar expressing CryIA (c) and a CryIIA (b) toxin); (表达VIP毒素的棉花品种); (Cotton variety expressing VIP toxin); (表达CryIIIA毒素的土豆品种); (Potato variety expressing CryIIIA toxin); know

这些转基因作物的其它实例为: Other examples of such transgenic crops are:

1.来自Syngenta Seeds SAS,Chemin de I′Hobit 27,F-31 790St.Sauveur,法国的Bt11玉蜀黍,注册号C/FR/96/05/10。 1. from Syngenta Seeds SAS, Chemin de I'Hobit 27, F-31 790St.Sauveur, France Bt11 maize, registration number C / FR / 96/05/10. 通过转基因表达截短CryIA(b)毒素而抗欧洲玉米螟虫(欧洲玉米螟及粉茎螟(Sesamianonagrioides))侵袭的基因修饰玉米(Zea mays)。 And resistant to European corn borer (Ostrinia nubilalis and pink stem borer (Sesamianonagrioides)) by transgenic expression of attack a truncated CryIA (b) toxin genetically modified maize (Zea mays). Bt11玉蜀黍也转基因表达酶PAT以获得对除草剂草铵膦的耐受性。 Bt11 maize also transgenic expression of the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium.

2.来自Syngenta Seeds SAS,Chemin de I′Hobit 27,F-31 790St.Sauveur,法国的Bt176玉蜀黍,注册号C/FF/96/05/10。 2. from Syngenta Seeds SAS, Chemin de I'Hobit 27, F-31 790St.Sauveur, Bt176 maize France, registration number C / FF / 96/05/10. 通过转基因表达CryIA(b)毒素而抗欧洲玉米螟虫(欧洲玉米螟及粉茎螟)侵袭的基因修饰玉米。 Gene resistant to European corn borer (European corn borer and pink stalk borer) invasion of expression CryIA (b) toxin modification by transgenic corn. Bt176玉蜀黍也转基因表达酶PAT以获得对除草剂草铵膦的耐受性。 Bt176 maize also transgenic expression of the enzyme PAT to achieve tolerance to the herbicide glufosinate ammonium.

3.来自Syngenta Seeds SAS,Chemin de I′Hobit 27,F-31 790St.Sauveur,法国的MIR604玉蜀黍,注册号C/FR/96/05/10。 3. from Syngenta Seeds SAS, Chemin de I'Hobit 27, F-31 790St.Sauveur, France MIR604 maize, registration number C / FR / 96/05/10. 通过转基因表达修饰的CryIHA毒素而呈现昆虫抗性的玉蜀黍。 Presented maize insect resistance by expression of the modified toxin CryIHA transgene. 该毒素为通过插入组织蛋白酶-D-蛋白酶识别序列而修饰的Cry3A055。 The toxin is a protease recognition sequence by inserting a protease -D- tissue modified Cry3A055. 这些转基因玉蜀黍植物的制备描述在WO 03/018810中。 Preparation of these transgenic maize plants is described in the WO 03/018810.

4.来自Monsanto Europe SA270-272Avenue de Tervuren,B-1150Brussels,比利时的MON 863玉蜀黍,注册号C/DE/02/9。 4. from Monsanto Europe SA270-272Avenue de Tervuren, B-1150Brussels, maize, MON 863 Belgium, registration number C / DE / 02/9. MON 863表达CryIIIB(bi)毒素且具有对某些鞘翅目昆虫的抗性。 MON 863 expression CryIIIB (bi) toxin and has resistance to certain Coleoptera insects.

5.来自Monsanto Europe SA270-272Avenue de Tervuren,B-1150Brussels,比利时的IPC 531棉花,注册号C/ES/96/02。 5. from Monsanto Europe SA270-272Avenue de Tervuren, B-1150Brussels, cotton, IPC 531 Belgium, registration number C / ES / 96/02.

6.来自Pioneer Overseas Corporation,Avenue Tedesco,7B-1160Brussels,比利时的1507玉蜀黍,注册号C/NLJ00/10。 6. from Pioneer Overseas Corporation, Avenue Tedesco, 7B-1160Brussels, 1507 maize Belgium, registration number C / NLJ00 / 10. 表达蛋白Cry1F以获得对某些鳞翅目昆虫的抗性且表达PAT蛋白以获得对除草剂草铵膦的耐受性的基因修饰玉蜀黍。 Expression of protein Cry1F for achieving resistance to certain Lepidoptera insects and of the PAT protein gene to obtain tolerance to the herbicide glufosinate modified maize.

7.来自Monsanto Europe SA270-272Avenue de Tervuren,B-1150Brussels,比利时的NK603x MON 810玉蜀黍,注册号C/GB/02/M3/03。 7. from Monsanto Europe SA270-272Avenue de Tervuren, B-1150Brussels, NK603x MON 810 maize Belgium, registration number C / GB / 02 / M3 / 03. 由通过使基因修饰品种NK603与MON 810杂交而获得的常规育种杂交玉蜀黍品种构成。 Conventional breeding hybrid maize varieties by the genetically modified varieties NK603 by the hybrid MON 810 configured obtained. NK603x MON 810玉蜀黍转基因地表达由土壤杆菌属(Agrobacterium sp.)菌株CP4获得的赋予对除草剂 NK603x MON 810 Maize transgenically expressed by Agrobacterium (Agrobacterium sp.) Strain CP4 obtained confers herbicide (含有草甘膦)的耐受性的蛋白CP4EPSPS以及由苏云金芽孢杆菌却氏卡奇(kurstaki)亚种获得的产生对包括欧洲玉米螟虫在内的某些鳞翅目昆虫的耐受性的CryIA(b)毒素。 (Contains glyphosate) resistance proteins and generating CP4EPSPS obtained from Bacillus thuringiensis was apos Qazi (. Kurstaki) subspecies CryIA resistance to certain Lepidoptera, including the European corn borer, including the (b) toxin.

抗昆虫植物的转基因作物也描述在BATS(Zentrum für Biosicherheitund Nachhaltigkeit,Zentrum BATS,Clarastrasse 13,4058Basel,瑞士)报告2003,( http://bats.ch )中。 Transgenic crops of insect-resistant plants are also described in the report BATS (Zentrum für Biosicherheitund Nachhaltigkeit, Zentrum BATS, Clarastrasse 13,4058Basel, Switzerland) 2003, (http://bats.ch) in.

对本发明而言,抗真菌转基因作物应理解为通过使用重组DNA技术进行转化而使其能够合成具有选择性作用的抗病原物质(例如所谓的″病原相关蛋白″(PRP,例如参见EP-A 392 225))的那些作物。 For the present invention, the antifungal GM crops to be understood as by the use of recombinant DNA techniques and transformed it capable of synthesising antipathogenic substances having a selective action (e.g. a so-called "pathogenesis-related proteins" (the PRP, see, for example EP-A 392 225)) of those crops. 这些抗病原物质和能够合成这些抗病原物质的转基因植物的实例例如由EP-A 392 225、WO95/33818和EP-A 353 191已知。 Examples of such antipathogenic substances and transgenic plants capable of synthesising such antipathogenic substances are known from e.g. EP-A 392 225, WO95 / 33818 and EP-A 353 191. 产生这些转基因植物的方法通常是本领域熟练技术人员已知的,且例如描述在上文提及的出版物中。 The method of generating transgenic plants are generally known to those skilled in the art, and described for example in the publications mentioned above.

可由这些转基因植物表达的抗病原物质例如包括离子通道阻断剂,例如钠和钙通道的阻断剂,例如病毒KP1、KP4或KP6毒素;1,2-苯二乙烯合成酶;联苄合成酶;几丁质酶;葡聚糖酶;所谓的″病原相关蛋白″(PRP,例如参见EP-A 392 225);由微生物产生的抗病原物质,例如肽抗生素或杂环抗生素(例如参见WO 95/33818)或植物病原体防御所涉及的蛋白质或多肽因子(所谓的″植物疾病抗性基因″,如WO 03/000906中所述)。 Can be expressed in these transgenic plants antipathogenic substances include, for example, ion channel blockers, such as sodium and calcium channel blockers, such as a viral KP1, KP4 or KP6 toxins; 1,2-divinyl synthase; Synthesis of dibenzyl enzymes; chitinase; glucanase; so-called "pathogenesis-related proteins" (the PRP, see, for example EP-a 392 225); antipathogenic substances produced by microorganisms, for example peptide antibiotics or heterocyclic antibiotics (see e.g. protein or polypeptide factors (so-called "plant disease resistance genes", as described in WO 03/000906) WO 95/33818), or plant pathogen defense involved. 使用本发明组合物的其它领域为保护储存货物和储藏室及保护原料(例如木材、纺织品、楼面料或建筑物)以及在卫生领域中,特别是保护人类、家畜和生产性牲畜防止所提及类型的害虫。 Other fields of use for the compositions of the invention are the protection of stored goods and storerooms and the protection of materials (e.g. wood, textiles, floor coverings or buildings), and in the hygiene sector, especially the protection of humans, domestic animals and productive livestock to prevent the mentioned types of pests.

对本发明而言,转基因植物可如上所述含有一个或多个编码杀虫抗性以及除草剂抗性的基因(例如,RR For the present invention, a transgenic plant as described above may contain one or more genes coding for an insecticidal resistance and herbicide resistance (e.g., RR 或RR Or RR 特征)。 feature). 那些植物被认为是含有双重或甚至三重堆积基因(stacked gene)的转基因植物。 Those plants are considered to contain double or even triple stacked transgenic plant gene (stacked gene) is. 此外,也可考虑将转基因植物中的基因或事件的这种多重堆积定义针对更广泛及更多的应用,例如杀真菌剂抗性或干旱抗性。 In addition, this will also be considered in transgenic plants genes or multiple events defined for the accumulation of a broader and more applications, such as fungicide resistance or drought tolerance. 后者应理解为通过使用重组DNA技术进行转化而使其能够提向作物提供在干旱选择压力下的胁迫抗性。 The latter should be understood that by the use of recombinant DNA techniques it is possible to improve the conversion and provides selective pressure stress resistance to drought in crops. 此外,在转基因作物的多重堆积定义中,必须考虑当通过使用重组DNA的转化技术引入时,通过修饰作物的特定生理途径提供额外产量而增加特定作物本身的产量潜力的基因,例如大豆中的 Further, in a multiple stacking defined transgenic crops must be considered when by using the transformation techniques of recombinant DNA is introduced, to increase the gene yield potential of the particular crop itself to provide an additional production by particular physiological pathway modified crops, for example soybeans

此外,化合物I和活性化合物II和III的混合物还适于防治有害真菌以保护材料(如木材、纸张、漆分散体、纤维或织物)和保护储藏的产品。 Furthermore, mixtures of the compounds I and active compounds II and III are also suitable for controlling harmful fungi in the protection of materials (e.g. wood, paper, paint dispersions, fibers or fabrics) and in the protection of stored products. 在木材保护中,特别应注意下列有害真菌:子囊菌纲真菌,如线嘴壳属(Ophiostoma spp.),长喙壳属(Ceratocystis spp.),出芽短梗霉(Aureobasidium pullulans),Sclerophoma spp.,毛壳属(Chaetomium spp.),腐质霉属(Humicola spp.),彼得壳属(Petriella spp.),毛束霉属(Trichurusspp.);担子菌纲真菌,如粉孢革菌属(Coniophora spp.),革盖菌属(Coriolusspp.),粘褶菌属(Gloeophyllum spp.),香菇属(Lentinus spp.),侧耳属(Pleurotus spp.),卧孔属(Poria spp.),干朽菌属(Serpula spp.)和干酪菌属(Tyromyces spp.),半知菌纲真菌,如曲霉属(Aspergillus spp.),枝孢属(Cladosporium spp.),青霉属(Penicillium spp.),木霉属(Trichoderma spp.),链格孢属(Alternaria spp.),拟青霉属(Paecilomyces spp.)和接合菌纲(Zygomycetes)真菌,如毛霉属(Mucor spp.),此外在材料保护中应注意下列酵母:假丝酵母属(Candida spp.)和酿酒酵母(Saccharomyces cerevisae)。 In the protection of wood, particular attention is paid to the following harmful fungi: (. Ophiostoma spp) (. Ceratocystis spp) Ascomycetes fungi, such as the nozzle housing genus Ceratocystis spp., Aureobasidium pullulans (Aureobasidium pullulans), Sclerophoma spp. , Chaetomium, Humicola, Peter shell genus Geotrichum tufts (Trichurusspp.) (Chaetomium spp.) (Humicola spp.) (Petriella spp.); Basidiomycetes, such as Coniophora spp ( Coniophora spp.), the genus Coriolus (Coriolusspp.), the genus Gloeophyllum (Gloeophyllum spp.), Lentinus (Lentinus spp.), Pleurotus (Pleurotus spp.), the genus Poria (Poria spp.), dried rot species (Serpula spp.), and the genus cheese (Tyromyces spp.), fungi Deuteromycetes, such as Aspergillus (Aspergillus spp.), Cladosporium (Cladosporium spp.), Penicillium (Penicillium spp.) Trichoderma (Trichoderma spp.), Alternaria (Alternaria spp.), Paecilomyces (Paecilomyces spp.) and Zygomycetes (Zygomycetes) fungi, such as Mucor (Mucor spp.), in addition should pay attention to the protection of materials the following yeasts: (. Candida spp) and Candida yeast (Saccharomyces cerevisae).

化合物I和化合物II通常以5000∶1-1∶5000,优选500∶1-1∶100,更优选100∶1-1∶100,尤其是20∶1-1∶20,最优选10∶1-1∶10的重量比使用。 Compounds I and II are usually 5000:1-1:5000, preferably 500:1-1:100, more preferably 100:1-1:100, especially 20:1-1:20, most preferably 10:1- a weight ratio of 1:10.

化合物III以20∶1-1∶20的重量比加入化合物I中。 20:1-1:20 Compound III in a weight ratio of compound I was added.

或者,化合物III以20∶1-1∶20的重量比加入化合物II中。 Alternatively, compound III is added in a weight ratio of the compound 20:1-1:20 II.

当制备混合物时,优选使用纯活性化合物I、II和III,可以根据需要向其中加入其他对抗有害真菌或其他害虫如昆虫、蜘蛛或线虫的活性化合物或除草活性或生长调节活性化合物或肥料以作为其它活性组分。 When preparing the mixtures, it is preferred to use the pure active compounds I, II and III, to which can be added to the other against the required harmful fungi or other pests active compound or herbicidal activity, such as insects, arachnids or nematodes, or growth-regulating active compounds or fertilizers as other active ingredients.

通常而言,化合物I与两种或合适的话更多种活性组分的混合物可能是有利的。 Generally, the compounds I and, if appropriate, a mixture of two or more active ingredients may be advantageous.

在上述意义上合适的其他活性组分尤其是开头所提到的活性化合物II和III,特别是上述优选的活性化合物。 Suitable further active components in the above sense are in particular mentioned at the beginning of the active compounds II and III, in particular the preferred active compounds described above.

化合物I和活性化合物II和III的混合物通过用杀真菌有效量的活性化合物处理真菌或需防止真菌侵袭的植物、种子、材料或土壤而使用。 Mixtures of the compounds I and active compounds II and III by treating the fungi with a fungicidally effective amount of the active compound required to prevent or plants, seeds, materials or soil fungal attack is used. 施用可以在材料、植物或种子被真菌侵染之前和之后进行。 Administration may be performed before the materials, plants or seeds by the fungi and after the infection.

在对抗有害真菌的方法中,取决于化合物的类型以及所需效果,本发明混合物的施用率为5-2000g/ha,优选50-900g/ha,尤其是50-750g/ha。 In the method of combating harmful fungi, depending on the type of compound and the desired effect, the application rate of the mixture of the present invention 5-2000g / ha, preferably 50-900g / ha, in particular 50-750g / ha.

相应地,化合物I的施用率通常为1-1000g/ha,优选10-900g/ha,尤其是20-750g/ha。 Correspondingly, the application rates of the compound I are generally from 1-1000g / ha, preferably 10-900g / ha, in particular 20-750g / ha.

相应地,活性化合物II和III各自的施用率通常为1-2000g/ha,优选10-900g/ha,尤其是40-500g/ha。 Accordingly, the active compounds II and III each application rate is generally 1-2000g / ha, preferably 10-900g / ha, in particular 40-500g / ha.

防治有害真菌的方法通过在植物播种之前或之后或植物出苗之前或之后通过对种子、植物或土壤喷雾或撒粉而分开或联合施用化合物I和活性化合物II和III,或化合物I与活性化合物II和III的混合物而进行。 A method for controlling harmful fungi by prior before sowing the plants or after or emergence of the plants or after the seeds, plants or soil by spraying or dusting the separate or joint administration of compounds I and active compounds II and III, or the compound I with active compounds II III and the mixture is performed.

处理可在种植入地之前在种子箱中进行。 Seed treatment can be carried out in the tank into the ground prior to planting.

化合物I、u和III或混合物或对应的配制剂通过用杀真菌有效量的混合物,或在分开施用的情况下的化合物I、II和III处理有害真菌,需要防止它们的植物、种子、土壤、区域、材料或空间而施用。 Compound I, u and III or the mixtures or the corresponding formulations mixture fungicidally effective amount of a killed by the compound or in the case of separate administration of I, II and III deal with the harmful fungi, it is necessary to prevent them from plants, seeds, soils, areas, materials or spaces to be administered. 施用可以在有害真菌侵染之前或之后进行。 Administration may be performed before or after infection by the harmful fungi.

化合物I、II和III的混合物,或同时,即联合或分开使用的化合物I、II和III也显示了突出的对抗如下目害虫的作用: Compounds I, II and III mixture, or simultaneously, that is jointly or separately compounds I, II and III also show outstanding effects against the following insect pests:

鳞翅目昆虫(鳞翅目(Lepidoptera)),例如小地老虎(Agrotis ypsilon)、黄地老虎(Agrotis segetum)、木棉虫(Alabama argillacea)、黎豆夜蛾(Anticarsia gemmatalis)、Argyresthia conjugella、叉纹夜蛾(Autographagamma)、树尺蠖(Bupalus piniarius)、Cacoecia murinana、Capuareticulana、Cheimatobia brumata、云杉色卷蛾(Choristoneurafumiferana)、Choristoneura occidentalis、二化螟(Cirphis unipuncta)、苹果小卷蛾(Cydia pomonella)、松毛虫(Dendrolimus pini)、Diaphanianitidalis、西南玉米杆草螟(Diatraea grandiosella)、埃及钻夜蛾(Eariasinsulana)、南美玉米苗斑螟(Elasmopalpus lignosellus)、女贞细卷蛾(Eupoecilia ambiguella)、Evetria bouliana、Feltia subterranea、蜡螟(Galleria mellonella)、李小食心虫(Grapholith a funebrana)、梨小食心虫(Grapholitha molesta)、棉铃虫(Heliothis armigera)、烟芽夜蛾(Heliothisvirescens)、玉米穗虫(Heliothis zea)、菜螟(Hellula undalis)、Hiberniadefoliaria、美国白蛾(H Lepidoptera (Lepidoptera (Lepidoptera)), for example, black cutworm (Agrotis ypsilon), cutworm (Agrotis segetum), kapok worm (Alabama argillacea), Anticarsia gemmatalis (Anticarsia gemmatalis), Argyresthia conjugella, fork looper (Autographagamma), tree looper (Bupalus piniarius), Cacoecia murinana, Capuareticulana, Cheimatobia brumata, spruce budworm (Choristoneurafumiferana), Choristoneura occidentalis, stem borer (Cirphis unipuncta), codling moth (Cydia pomonella) , pine moth (Dendrolimus pini), Diaphanianitidalis, oxalyl southwest cornstalk borer (Diatraea grandiosella), Egypt drill armyworm (Eariasinsulana), South American maize seedlings Oligochroa (Elasmopalpus lignosellus), privet fine tortrix (Eupoecilia ambiguella), Evetria bouliana , Feltia subterranea, wax moth (Galleria mellonella), Grapholitha funebrana (Grapholith a funebrana), pear fruit moth (Grapholitha molesta), bollworm (Heliothis armigera), Heliothis virescens (Heliothisvirescens), corn earworm (Heliothis zea) , cabbage webworm (Hellula undalis), Hiberniadefoliaria, fall webworm (H yphantria cunea)、苹果巢蛾(Hyponomeutamalinellus)、番茄虫蛾(Keiferia lycopersicella)、Lambdina fiscellaria、甜菜夜蛾(Laphygma exigua)、咖啡潜叶蛾(Leucoptera coffeella)、旋纹潜蛾(Leucoptera scitella)、Lithocolletis blancardella、葡萄浆果小卷蛾(Lobesiabotrana)、甜菜网螟(Loxostege sticticalis)、舞毒蛾(Lymantria dispar)、模毒蛾(Lymantria monacha)、桃潜蛾(Lyonetia clerkella)、黄褐天幕毛虫(Malacosoma neustria)、甘蓝夜蛾(Mamestra brassicae)、黄杉毒蛾(Orgyiapseudotsugata)、玉米螟(Ostrinia nubilalis)、小眼夜蛾(Panolis flammea)、棉花红铃虫(Pectinophora gossypiella)、疆夜蛾(Peridroma saucia)、圆掌舟蛾(Phalera bucephala)、马铃薯麦蛾(Phthorimaea operculella)、柑桔潜叶蛾(Phyllocnistis citrella)、欧洲粉蝶(Pieris brassicae)、苜蓿绿夜蛾(Plathypena scabra)、菜蛾(Plutella xylostella)、大豆夜蛾(Pseudoplusiaincludens)、Rhyacionia frustrana、Scrobipalpula absoluta、麦蛾(Sitotroga yphantria cunea), apple ermine moth (Hyponomeutamalinellus), tomato worm moth (Keiferia lycopersicella), Lambdina fiscellaria, beet armyworm (Laphygma exigua), coffee leaf miner (Leucoptera coffeella), rotation pattern leafminer (Leucoptera scitella), Lithocolletis blancardella , grape berry moth small volume (Lobesiabotrana), net beet borer (Loxostege sticticalis), gypsy moth (Lymantria dispar), mold moth (Lymantria monacha), peach leafminer (Lyonetia clerkella), Malacosoma caterpillar (Malacosoma neustria), cabbage armyworm (Mamestra brassicae), Douglas fir moth (Orgyiapseudotsugata), corn borer (Ostrinia nubilalis), small eyes armyworm (Panolis flammea), cotton bollworm (Pectinophora gossypiella), Xinjiang armyworm (Peridroma saucia), round the palm boat moth (Phalera bucephala), potato gossypiella (Phthorimaea operculella), citrus leafminer (Phyllocnistis citrella), Europe butterfly (Pieris brassicae), green alfalfa armyworm (Plathypena scabra), diamondback moth (Plutella xylostella), soybean armyworm (Pseudoplusiaincludens), Rhyacionia frustrana, Scrobipalpula absoluta, gossypiella (Sitotroga cerealella)、葡萄卷叶蛾(Sparganothis pilleriana)、草地夜蛾(Spodopterafrugiperda)、海灰翅夜蛾(Spodoptera littoralis)、斜纹夜蛾(Spodopteralitura)、Thaumatopoea pityocampa、绿色橡木飞蛾(Tortrix viridana)、粉纹夜蛾(Trichoplusia ni)和Zeiraphera canadensis, cerealella), grape leaf roller (Sparganothis pilleriana), fall armyworm (Spodopterafrugiperda), Spodoptera littoralis (Spodoptera littoralis), Spodoptera (Spodopteralitura), Thaumatopoea pityocampa, green oak moth (Tortrix viridana), Trichoplusia ni (Trichoplusia ni) and Zeiraphera canadensis,

甲虫(鞘翅目(Coleoptera)),例如梨窄吉丁(Agrilus sinuatus)、直条叩头虫(Agriotes lineatus)、暗色叩头虫(Agriotes obscurus)、Amphimallussolstitialis、Anisandrus dispar、墨西哥棉铃象(Anthonomus grandis)、苹花象(Anthonomus pomorum)、Aphthona euphoridae、Athoushaemorrhoidalis、甜菜隐食甲(Atomaria linearis)、纵坑切梢小蠹(Blastophagus piniperda)、Blitophaga undata、蚕豆象(Bruchusrufimanus)、豌豆象(Bruchus pisorum)、欧洲兵豆象(Bruchus lentis)、苹卷象(Byctiscus betulae)、甜菜大龟甲(Cassida nebulosa)、Cerotomatrifurcata、金花金龟(Cetonia aurata)、白菜籽龟象(Ceuthorrhynchusassimilis)、芫菁龟象(Ceuthorrhynchus napi)、甜菜胫跳甲(Chaetocnematibialis)、Conoderus vespertinus、石刁柏负泥虫(Crioceris asparagi)、Ctenicera ssp.、长角叶甲(Diabrotica longicornis)、Diabroticasemipunctata、Diabrotica 12-punctata、南美叶甲(Diabrotica speciosa)、玉米根叶甲(Diabrotica virgifera)、墨西哥 Beetles (Coleoptera (Coleoptera)), for example Agrilus pears (Agrilus sinuatus), straight click beetles (Agriotes lineatus), dark click beetles (Agriotes obscurus), Amphimallussolstitialis, Anisandrus dispar, Mexico boll weevil (Anthonomus grandis), Ping flowers like (Anthonomus pomorum), Aphthona euphoridae, Athoushaemorrhoidalis, beets hidden food A (Atomaria linearis), Tomicus beetles (Blastophagus piniperda), Blitophaga undata, beans like (Bruchusrufimanus), pea like (Bruchus pisorum), European soldiers bean weevil (Bruchus lentis), a volume as apple (Byctiscus betulae), beet large shells (Cassida nebulosa), Cerotomatrifurcata, Golden beetle (Cetonia aurata), as a white turtle rapeseed (Ceuthorrhynchusassimilis), Meloidae such as turtles (Ceuthorrhynchus napi) , shin beet flea beetle (Chaetocnematibialis), Conoderus vespertinus, asparagus negative mud worm (Crioceris asparagi), Ctenicera ssp., long-horned beetle (Diabrotica longicornis), Diabroticasemipunctata, Diabrotica 12-punctata, the South American leaf beetle (Diabrotica speciosa) corn rootworm (Diabrotica virgifera), Mexico 豆瓢虫(Epilachna varivestis)、烟草跳甲(Epitrix hirtipennis)、棉灰蒙象变种(Eutinobothrus brasiliensis)、欧洲松树皮象(Hylobius abietis)、埃及苜蓿叶象(Hypera brunneipennis)、紫苜蓿叶象(Hypera postica)、云杉八齿小蠹(Ips typographus)、烟草负泥虫(Lema bilineata)、黑角负泥虫(Lema melanopus)、马铃薯叶甲(Leptinotarsadecemlineata)、Limonius californicus、稻水象甲(Lissorhoptrusoryzophilus)、Melanotus communis、油菜露尾甲(Meligethes aeneus)、大栗鳃金龟(Melolontha hippocastani)、五月鳃金龟(Melolontha melolontha)、水稻负泥虫(Oulema oryzae)、葡萄黑耳喙象(Ortiorrhynchus sulcatus)、草莓根象甲(Otiorrhynchus ovatus)、辣根猿叶甲(Phaedon cochleariae)、梨树叶象(Phyllobius pyri)、Phyllotreta chrysocephala、食叶鳃金龟属(Phyllophaga sp.)、庭园发丽金龟(Phyllopertha horticola)、大豆淡足跳甲(Phyllotreta nemorum)、黄曲条菜跳甲(Phyllotreta striolata)、日本金龟子(Popil Bean beetle (Epilachna varivestis), tobacco flea beetle (Epitrix hirtipennis), like dark gray cotton varieties (Eutinobothrus brasiliensis), European pine bark like (Hylobius abietis), Egypt cloverleaf like (Hypera brunneipennis), alfalfa leaf like (Hypera postica), eight toothed spruce bark beetle (Ips typographus), minus the tobacco beetle (Lema bilineata), Pointe Noire negative beetle (Lema melanopus), potato beetle (Leptinotarsadecemlineata), Limonius californicus, rice water weevil (Lissorhoptrusoryzophilus) , Melanotus communis, rapeseed beetle (Meligethes aeneus), Melolontha hippocastani (Melolontha hippocastani), May beetle (Melolontha melolontha), rice Oulema (Oulema oryzae), grape black ear beak like (Ortiorrhynchus sulcatus), strawberry root weevil (Otiorrhynchus ovatus), Phaedon (Phaedon cochleariae), as the pear leaves (Phyllobius pyri), Phyllotreta chrysocephala, leaf-eating beetle genus (Phyllophaga sp.), issued garden beetle (Phyllopertha horticola), soybean light foot flea beetle (Phyllotreta nemorum), striped flea beetle dish (Phyllotreta striolata), Japan chafer (Popil lia japonica)、豌豆叶象(Sitona lineatus)和谷象(Sitophilus granaria), lia japonica), like pea leaf (Sitona lineatus) and Grain Weevil (Sitophilus granaria),

蝇、蚊(双翅目(Diptera)),例如埃及伊蚊(Aedes aegyptii)、白纹伊蚊(Aedes albopictus)、剌扰伊蚊(Aedes vexans)、墨西哥果蝇(Anastrephaludens)、五斑按蚊(Anopheles maculipennis)、Anopheles crucians、白足按蚊(Anopheles albimanus)、冈比亚按蚊(Anopheles gambiae)、Anophelesfreeborni、海南岛白踝按蚊(Anopheles leucosphyrus)、云南微小按蚊(Anopheles minimus)、四斑按蚊(Anopheles quadrimaculatus)、红头丽蝇(Calliphora vicina)、地中海实蝇(Ceratitis capitata)、蛆症金蝇(Chrysomyabezziana)、Chrysomya hominivorax、Chrysomya macellaria、鹿蝇(Chrysops discalis)、Chrysops silacea、Chrysops atlanticus、螺旋蝇(Cochliomyia hominivorax)、高粱瘿蚊(Contarinia sorghicola)、嗜人瘤蝇蛆(Cordylobia anthropophaga)、狂怒库蠓(Culicoides furens)、尖音库蚊(Culex pipiens)、斑蚊(Culex nigripalpus)、致倦库蚊(Culexquinquefasciatus)、媒斑蚊(Culex tarsalis)、Culiseta inornata、Culisetamelanura、瓜蝇(Dacu Flies, mosquitoes (Diptera (Diptera)), for example, Aedes aegypti (Aedes aegyptii), Aedes albopictus (Aedes albopictus), assassination interference Aedes (Aedes vexans), the Mexican fruit fly (Anastrephaludens), five Anopheles (Anopheles maculipennis), Anopheles crucians, white-footed Anopheles (Anopheles albimanus), Anopheles gambiae (Anopheles gambiae), Anophelesfreeborni, Hainan white ankle Anopheles (Anopheles leucosphyrus), Yunnan tiny Anopheles (Anopheles minimus), four spots by mosquito (Anopheles quadrimaculatus), red-headed blowfly (Calliphora vicina), the Mediterranean fruit fly (Ceratitis capitata), maggots disease gold flies (Chrysomyabezziana), Chrysomya hominivorax, Chrysomya macellaria, deer flies (Chrysops discalis), Chrysops silacea, Chrysops atlanticus, spiral flies (Cochliomyia hominivorax), sorghum midge (Contarinia sorghicola), addicted to human tumor maggot (Cordylobia anthropophaga), rage Culicoides (Culicoides furens), Culex mosquito (Culex pipiens), aegypti mosquito (Culex nigripalpus), Culex Culex (Culexquinquefasciatus), media aegypti mosquito (Culex tarsalis), Culiseta inornata, Culisetamelanura, melon fly (Dacu s cucurbitae)、油橄榄实蝇(Dacus oleae)、油菜叶瘿蚊(Dasineura brassicae)、Delia antique、麦地种蝇(Delia coarctata)、灰地种蝇(Delia platura)、甘蓝地种蝇(Delia radicum)、Dermatobia hominis、小毛厕蝇(Fannia canicularis)、Geomyza Tripunctata、马蝇(Gasterophilus intestinalis)、刺舌蝇(Glossina morsitans)、须舌蝇(Glossina palpalis)、Glossina fuscipes、胶舌蝇(Glossina tachinoides)、Haematobia irritans、Haplodiplosis equestris、潜蝇属(Hippelates spp.)、花生田灰地种蝇(Hylemyia platura)、纹皮蝇(Hypoderma lineata)、Leptoconops torrens、蔬菜斑潜蝇(Liriomyza sativae)、美国潜叶蝇(Liriomyza trifolii)、Lucilia caprina、铜绿蝇(Lucilia cuprina)、丝光绿蝇(Lucilia sericata)、Lycoria pectoralis、Mansonia titillanus、麦瘿蚊(Mayetiola destructor)、家蝇(Musca domestica)、厩腐蝇(Muscinastabulans)、羊狂蝇(Oestrus ovis)、Opomyza florum、欧洲麦秆蝇(Oscinellafrit)、天仙子泉蝇(Pegomya hysocyami) s cucurbitae), olive fruit fly (Dacus oleae), rapeseed leaf gall midge (Dasineura brassicae), Delia antique, Michael Delia (Delia coarctata), gray Delia (Delia platura), cabbage Delia (Delia radicum) , Dermatobia hominis, hairs Fannia (Fannia canicularis), Geomyza Tripunctata, horse fly (Gasterophilus intestinalis), barbed tsetse fly (Glossina morsitans), shall tsetse fly (Glossina palpalis), Glossina fuscipes, gum tsetse fly (Glossina tachinoides), Haematobia irritans, Haplodiplosis equestris, maggot genus (Hippelates spp.), ash peanut field Delia (Hylemyia platura), grain leather fly (Hypoderma lineata), Leptoconops torrens, vegetable leafminer (Liriomyza sativae), American leaf miner ( Liriomyza trifolii), Lucilia caprina, Lucilia cuprina (Lucilia cuprina), Lucilia sericata (Lucilia sericata), Lycoria pectoralis, Mansonia titillanus, Mayetiola (Mayetiola destructor), housefly (Musca domestica), stable fly rot (Muscinastabulans), sheep mad fly (Oestrus ovis), Opomyza florum, European wheat straw flies (Oscinellafrit), henbane spring flies (Pegomya hysocyami) 葱蝇(Phorbia antiqua)、萝卜蝇(Phorbia brassicae)、麦地种蝇(Phorbia coarctata)、银足白蛉(Phlebotomusargentipes)、Psorophora columbiae、胡萝卜茎蝇(Psila rosae)、Psorophora discolor、Prosimulium mixtum、樱桃实蝇(Rhagoletiscerasi)、苹果实蝇(Rhagoletis pomonella)、赤尾麻蝇(Sarcophagahaemorrhoidalis)、肉蝇属(Sarcophaga)、Simulium vittatum、厩螫蝇(Stomoxys calcitrans)、牛虻(Tabanus bovinus)、Tabanus atratus、红色原虻(Tabanus lineola)、Tabanus similis、Tipula oleracea和欧洲大蚊(Tipula paludosa), Onion maggot (Phorbia antiqua), carrot fly (Phorbia brassicae), Michael Delia (Phorbia coarctata), silver foot sandflies (Phlebotomusargentipes), Psorophora columbiae, carrot stem flies (Psila rosae), Psorophora discolor, Prosimulium mixtum, solid cherry flies (Rhagoletiscerasi), apple fruit fly (Rhagoletis pomonella), Akao hemp flies (Sarcophagahaemorrhoidalis), flesh flies genus (Sarcophaga), Simulium vittatum, stable flies (Stomoxys calcitrans), gadfly (Tabanus bovinus), Tabanus atratus, red Jungle horsefly ( Tabanus lineola), Tabanus similis, Tipula oleracea and Tipula (Tipula paludosa),

蓟马(缨翅目(Thysanoptera)),例如兰花蓟马(Dichromothripscorbetti)、Dichromothrips ssp.、烟褐蓟马(Frankliniella fusca)、苜蓿花蓟马(Frankliniella occidentalis)、东方花蓟马(Frankliniella tritici)、桔硬蓟马(Scirtothrips citri)、稻蓟马(Thrips oryzae)、棕榈蓟马(Thrips palmi)和烟蓟马(Thrips tabaci), Thrips (Thysanoptera (Thysanoptera)), for example Orchid thrips (Dichromothripscorbetti), Dichromothrips ssp., Brown tobacco thrips (Frankliniella fusca), alfalfa flower thrips (Frankliniella occidentalis), Eastern flower thrips (Frankliniella tritici), orange hard thrips (Scirtothrips citri), rice thrips (thrips oryzae), palm thrips (thrips palmi), and thrips tabaci (thrips tabaci),

白蚁(等翅目(Isoptera)),例如Calotermes flavicollis、Leucotermesflavipes、金黄异白蚁(Heterotermes aureus)、黄肢散白蚁(Reticulitermesflavipes)、美小黑散白蚁(Reticulitermes virginicus)、欧洲散白蚁(Reticulitermes lucifugus)、Termes natalensis和台湾乳白蚁(Coptotermesformosanus), Termites (Isoptera (Isoptera)), for example Calotermes flavicollis, Leucotermesflavipes, golden different termite (Heterotermes aureus), yellow limb subterranean termite (Reticulitermesflavipes), the United States black subterranean termite (Reticulitermes virginicus), the European subterranean termite (Reticulitermes lucifugus), Termes natalensis and Formosan termites (Coptotermesformosanus),

蟑螂(蜚蠊目(Blattaria-Blattodea),例如德国小蠊(Blattellagermanica)、Blattella asahinae、美洲大蠊(Periplaneta americana)、日本大蠊(Periplaneta japonica)、棕色蜚蠊(Periplaneta brunnea)、Periplanetafuligginosa、澳洲蜚蠊(Periplaneta australasiae)和东方蜚蠊(Blattaorientalis), Cockroaches (Blattodea (Blattaria-Blattodea), such as German cockroaches (Blattellagermanica), Blattella asahinae, American cockroach (Periplaneta americana), Japanese cockroach (Periplaneta japonica), brown cockroach (Periplaneta brunnea), Periplanetafuligginosa, Australia enjoys cockroach (Periplaneta australasiae) and oriental cockroach (Blattaorientalis),

真正臭虫(半翅目(Hemiptera)),例如拟绿蝽(Acrosternum hilare)、玉米长蝽(Blissus leucopterus)、黑斑烟盲蝽(Cyrtopeltis notatus)、棉红蝽(Dysdercus cingulatus)、Dysdercus intermedius、麦扁盾蝽(Eurygasterintegriceps)、烟草蝽(Euschistus impictiventris)、棉红铃喙缘蝽(Leptoglossus phyllopus)、美洲牧草盲蝽(Lygus lineolaris)、牧草盲蝽(Lygus pratensis)、稻绿蝽(Nezara viridula)、甜菜拟网蝽(Piesmaquadrata)、Solubea insularis、Thyanta perditor、Acyrthosiphononobrychis、落叶松球蚜(Adelges laricis)、Aphidula nasturtii、甜菜蚜(Aphis fabae)、草莓根蚜(Aphis forbesi)、苹果蚜(Aphis pomi)、棉蚜(Aphis gossypii)、北美茶簏子蚜(Aphis grossulariae)、希奈德蚜(Aphisschneideri)、卷叶蚜(Aphis spiraecola)、接骨木蚜(Aphis sambuci)、豌豆蚜(Acyrthosiphon pisum)、茄无网蚜(Aulacorthum solani)、银叶粉虱(Bemisia argentifolii)、飞廉短尾蚜(Brachycaudus cardui)、李短尾蚜(Brachycaudus helichr True bugs (Hemiptera (Hemiptera)), e.g. intended green stink bug (Acrosternum hilare), corn chinch bug (Blissus leucopterus), Lygus smoke spots (Cyrtopeltis notatus), the red cotton bug (Dysdercus cingulatus), Dysdercus intermedius, wheat flat shield bug (Eurygasterintegriceps), tobacco bug (Euschistus impictiventris), cotton, red bell beak Rhamnomia (Leptoglossus phyllopus), lineolaris (Lygus lineolaris), tarnished plant bug (Lygus pratensis), green stink bug (Nezara viridula), beet intended to lace bug (Piesmaquadrata), Solubea insularis, Thyanta perditor, Acyrthosiphononobrychis, Adelges (Adelges laricis), Aphidula nasturtii, beet aphid (Aphis fabae), strawberry root aphid (Aphis forbesi), apple aphid (Aphis pomi), cotton aphid (Aphis gossypii), the North American sub-basket of tea aphid (Aphis grossulariae), Xi Naide aphid (Aphisschneideri), leaf aphid (Aphis spiraecola), elderberry aphid (Aphis sambuci), the pea aphid (Acyrthosiphon pisum), no eggplant aphid (Aulacorthum solani), silverleaf whitefly (Bemisia argentifolii), short-tailed thistle aphid (Brachycaudus cardui), short-tailed Lee aphid (Brachycaudus helichr ysi)、桃短尾蚜(Brachycaudus persicae)、Brachycaudus prunicola、甘蓝蚜(Brevicoryne brassicae)、Capitophorushorni、Cerosipha gossypii、草莓中瘤钉毛蚜(Chaetosiphon fragaefolii)、茶镳隐瘤蚜(Cryptomyzus ribis)、高加索冷杉椎球蚜(Dreyfusianordmannianae)、云杉椎球蚜(Dreyfusia piceae)、居根西圆尾蚜(Dysaphisradicola)、Dysaulacorthum pseudosolani、车前圆尾蚜(Dysaphisplantaginea)、梨西圆尾蚜(Dysaphis pyri)、蚕豆微叶蝉(Empoascafabae)、桃大尾蚜(Hyalopterus pruni)、Hyperomyzus lactucae、麦长管蚜(Macrosiphum avenae)、大戟长管蚜(Macrosiphum euphorbiae)、蔷薇管蚜(Macrosiphon rosae)、巢莱修尾蚜(Megoura viciae)、Melanaphispyrarius、麦无网蚜(Metopolophium dirhodum)、Myzodes persicae、冬葱瘤额蚜(Myzus ascalonicus)、Myzus cerasi、李瘤蚜(Myzus varians)、黑茶镳子衲长管蚜(Nasonovia ribis-nigri)、稻飞虱(Nilaparvata lugens)、囊柄瘿绵蚜(Pemphigus bursarius)、蔗飞虱(Perkinsiella s ysi), short-tailed peach aphid (Brachycaudus persicae), Brachycaudus prunicola, cabbage aphid (Brevicoryne brassicae), Capitophorushorni, Cerosipha gossypii, strawberries tumor nail Chaito (Chaetosiphon fragaefolii), tea darts hidden Myzus (Cryptomyzus ribis), Caucasian fir vertebral ball aphid (Dreyfusianordmannianae), vertebral ball spruce aphid (Dreyfusia piceae), ranking Guernsey round aphid (Dysaphisradicola), Dysaulacorthum pseudosolani, before the car round aphid (Dysaphisplantaginea), pear West round aphid (Dysaphis pyri), beans leafhopper (Empoascafabae), peach aphid (Hyalopterus pruni), Hyperomyzus lactucae, wheat aphid (Macrosiphum avenae), Euphorbia aphid (Macrosiphum euphorbiae), rose aphid (Macrosiphon rosae), Levin nest repair tail aphid (Megoura viciae), Melanaphispyrarius, wheat aphid (Metopolophium dirhodum), Myzodes persicae, shallots tumor volume aphid (Myzus ascalonicus), Myzus cerasi, Lee Myzus (Myzus varians), black tea darts sub cassock aphid ( Nasonovia ribis-nigri), planthoppers (Nilaparvata lugens), the balloon stem Pemphigus (Pemphigus bursarius), sugarcane planthopper (Perkinsiella s accharicida)、忽布疣蚜(Phorodon humuli)、苹木虱(Psylla mali)、梨木虱(Psylla piri)、冬葱瘤蛾蚜(Rhopalomyzus ascalonicus)、玉米蚜(Rhopalosiphum maidis)、禾谷溢管蚜(Rhopalosiphum padi)、苹草缢管蚜(Rhopalosiphum insertum)、Sappaphis mala、Sappaphis mali、麦二叉蚜(Schizaphis graminum)、Schizoneura lanuginosa、麦长管蚜(Sitobion avenae)、白粉虱(Trialeurodes vaporariorum)、桔二叉蚜(Toxoptera aurantiiand)、葡萄根瘤蚜(Viteus vitifolii)、温带臭虫(Cimex lectularius)、热带臭虫(Cimexhemipterus)、Reduvius senilis、Triatoma属和Arilus critatus。 accharicida), Phorodon aphid (Phorodon humuli), apple sucker (Psylla mali), pear psylla (Psylla piri), winter onions tumor moth aphid (Rhopalomyzus ascalonicus), corn aphid (Rhopalosiphum maidis), Rhopalosiphum aphid ( Rhopalosiphum padi), oxalyl apple aphid (Rhopalosiphum insertum), Sappaphis mala, Sappaphis mali, Schizaphis (Schizaphis graminum), Schizoneura lanuginosa, Sitobion avenae (Sitobion avenae), whitefly (Trialeurodes vaporariorum), two orange fork aphid (Toxoptera aurantiiand), phylloxera (Viteus vitifolii), temperate bedbugs (Cimex lectularius), tropical bugs (Cimexhemipterus), Reduvius senilis, Triatoma spp. and Arilus critatus.

蚂蚁、蜜蜂、黄蜂、锯蝇(膜翅目(Hymenoptera)),例如新疆菜叶蜂(Athalia rosae)、切叶蚁(Atta cephalotes)、Atta capiguara、Atta laevigata、Atta robusta、Atta sexdens、Atta texana、举腹蚁属(Crematogaster)、Hoplocampa minuta、Hoplocampa testudinea、小黄家蚁(Monomoriumpharaonis)、热带火蚁(Solenopsis geminate)、红火蚁(Solenopsis invicta)、黑火蚁(Solenopsis richteri)、南方火蚁(Solenopsis xyloni)、红蚂蚁(Pogonomyrmex barbatus)、Pogonomyrmex californicus、Pheidolemegacephala、天鹅绒蚂蚁(Dasymutilla occidentalis)、熊蜂属(Bombus)、大黄蜂(Vespula squamosa)、Paravespula vulgaris、Paravespulapennsylvanica、Paravespula germanica、姬胡蜂(Dolichovespula maculata)、黄边胡蜂(Vespa crabro)、胡蜂(Polistes rubiginosa)、Camponotusfloridanus和阿根廷蚁(Linepithema humile), Ants, bees, wasps, sawflies (Hymenoptera (Hymenoptera)), e.g. Xinjiang leaves bees (Athalia rosae), leaf-cutting ant (Atta cephalotes), Atta capiguara, Atta laevigata, Atta robusta, Atta sexdens, Atta texana, For abdomen ant genera (Crematogaster), Hoplocampa minuta, Hoplocampa testudinea, small yellow house ant (Monomoriumpharaonis), tropical fire ant (Solenopsis geminate), red imported fire ant (Solenopsis invicta), black fire ant (Solenopsis richteri), southern fire ant (Solenopsis xyloni), red ants (Pogonomyrmex barbatus), Pogonomyrmex californicus, Pheidolemegacephala, velvet ants (Dasymutilla occidentalis), Bombus genus (Bombus), Hornets (Vespula squamosa), Paravespula vulgaris, Paravespulapennsylvanica, Paravespula germanica, Ji Vespa (Dolichovespula maculata), European hornet (Vespa crabro), paper wasp (Polistes rubiginosa), Camponotusfloridanus and Argentine ant (Linepithema humile),

蟋蟀、蚱蜢、蝗虫(直翅目(Orthoptera)),例如居屋艾蟋(Achetadomestica)、蝼蛄(Gryllotalpa gryllotalpa)、飞蝗(Locusta migratoria)、双纹黑蝗(Melanoplus bivittatus)、红足黑蝗(Melanoplus femurrubrum)、墨西哥黑蝗(Melanoplus mexicanus)、迁飞黑蝗(Melanoplus sanguinipes)、石栖黑蝗(Melanoplus spretus)、条纹红蝗(Nomadacris septemfasciata)、美洲沙漠蝗(Schistocerca americana)、沙漠蝗(Schistocerca gregaria)、摩洛哥戟纹蝗(Dociostaurus maroccanus)、庭疾灶螽(Tachycines asynamorus)、塞纳加尔小车蝗(Oedaleus senegalensis)、Zonozerus variegatus、非洲蔗蝗(Hieroglyphus daganensis)、Kraussaria angulifera、意大利蝗(Calliptamusitalicus)、澳洲草栖蝗(Chortoicetes terminifera)和褐色拟飞蝗(Locustanapardalina), Crickets, grasshoppers, locusts (Orthoptera (of the Orthoptera)), e.g. HOS Ai cricket (Achetadomestica), mole cricket (Gryllotalpa gryllotalpa), migratory locust (Locusta migratoria), twisted-Melanoplus (Melanoplus bivittatus), black locust red foot ( Melanoplus femurrubrum), Mexico black locust (Melanoplus mexicanus), black locust migration (Melanoplus sanguinipes), black locust habitat stone (Melanoplus spretus), striped red locust (Nomadacris septemfasciata), the Americas desert locust (Schistocerca americana), desert locust (Schistocerca gregaria), Morocco Ji Wen locust (Dociostaurus maroccanus), Chamber disease foci grasshopper (Tachycines asynamorus), Senegal car locust (Oedaleus senegalensis), Zonozerus variegatus, Africa sugarcane locust (Hieroglyphus daganensis), Kraussaria angulifera, Italy locust (Calliptamusitalicus), Australia grass habitat locust (Chortoicetes terminifera) and brown proposed locusts (Locustanapardalina),

蜘蛛纲(Arachnoidea)),如蜘蛛(蜱螨目(Acarina)),例如软蜱科(Argasidae)、硬蜱科(Ixodidae)和疥螨科(Sarcoptidae),如长星形壁虱(Amblyomma americanum)、热带花蜱(Amblyomma variegatum)、Ambryomma maculatum、波斯锐缘蜱(Argas persicus)、牛壁虱(Boophilusannulatus)、Boophilus decoloratus、微小牛蜱(Boophilus microplus)、Dermacentor silvarum、安氏革蜱(Dermacentor andersoni)、美洲大革蜱(Dermacentor variabilis)、Hyalomma truncatum、蓖子硬蜱(Ixodesricinus)、Ixodes rubicundus、黑脚硬蜱(Ixodes scapularis)、全环硬蜱(Ixodesholocyclus)、太平洋硬蜱(Ixodes pacificus)、Ornithodorus moubata、Ornithodorus hermsi、Ornithodorus turicata、柏氏禽刺螨(Ornithonyssusbacoti)、Otobius megnini、鸡皮刺螨(Dermanyssus gallinae)、绵羊疥病(Psoroptes ovis)、Rhipicephalus sanguineus、Rhipicephalusappendiculatus、Rhipicephalus evertsi、人疥螨(Sarcoptes scabiei),瘿螨(Eriophyidae)属,如苹果刺锈螨(Aculus schl Arachnids (Arachnoidea)), such as arachnids (Acari (Acarina)), for example, soft ticks (Argasidae), hard ticks (Ixodidae) and scabies mites (Sarcoptidae), as long star tick (Amblyomma americanum) , tropical flower tick (Amblyomma variegatum), Ambryomma maculatum, Persian sharp edge tick (Argas persicus), cattle tick (Boophilusannulatus), Boophilus decoloratus, Boophilus (Boophilus microplus), Dermacentor silvarum, Dermacentor andersoni (Dermacentor andersoni) americana ticks (Dermacentor variabilis), Hyalomma truncatum, grate Ixodes (Ixodesricinus), Ixodes rubicundus, Blackfoot hard ticks (Ixodes scapularis), the Global Environment Ixodes (Ixodesholocyclus), Ixodes pacificus (Ixodes pacificus), Ornithodorus moubata, Ornithodorus hermsi, Ornithodorus turicata, Pap fowl mite (Ornithonyssusbacoti), Otobius megnini, chicken mite (Dermanyssus gallinae), sheep scabies disease (Psoroptes ovis), Rhipicephalus sanguineus, Rhipicephalusappendiculatus, Rhipicephalus evertsi, human scabies mite (Sarcoptes scabiei) , gall mites (Eriophyidae) metals such as thorn apple rust mite (Aculus schl echtendali)、Phyllocoptrataoleivora和Eriophyes sheldoni;细螨(Tarsonemidae)属,如Phytonemuspallidus和侧多食跗线螨(Polyphagotarsonemus latus);细须螨(Tenuipalpidae)属,如紫红短须螨(Brevipalpus phoenicis);叶螨(Tetranychidae)属,如朱砂叶螨(Tetranychus cinnabarinus)、神泽叶螨(Tetranychus kanzawai)、太平洋叶螨(Tetranychus pacificus)、棉叶螨(Tetranychus telarius)和二点叶螨(Tetranychus urticae),苹果叶螨(Panonychus ulmi)、柑椐叶螨(Panonychus citri)和草地小爪螨(Oligonychuspratensis);蜘蛛目(Araneida),例如毒蜘蛛(Latrodectus mactans)和褐丝蛛(Loxosceles reclusa), echtendali), Phyllocoptrataoleivora and Eriophyes sheldoni; fine mites (Tarsonemidae) species, such as Phytonemuspallidus and Polyphagotarsonemus latus (Polyphagotarsonemus latus); small to mites (Tenuipalpidae) metals such as Brevipalpus phoenicis (Brevipalpus phoenicis); mite ( Tetranychidae) species, such as carmine spider mite (Tetranychus cinnabarinus), God Ze spider mites (Tetranychus kanzawai), Pacific spider mites (Tetranychus pacificus), cotton spider mites (Tetranychus telarius) and two-spotted spider mite (Tetranychus urticae), apple spider mites (Panonychus ulmi), noted in citrus spider mite (Panonychus citri) and banks grass mite (Oligonychuspratensis); Araneae (Araneida), e.g. poisonous spider (Latrodectus mactans) and brown silk spider (Loxosceles reclusa),

跳蚤(蚤目(Siphonaptera)),例如猫跳蚤(Ctenocephalides felis)、狗跳蚤(Ctenocephalides canis)、印鼠客蚤(Xenopsylla cheopis)、致痒蚤(Pulexirritans)、穿皮潜蚤(Tunga penetrans)和具带病蚤(Nosopsyllus fasciatus), Fleas (Siphonaptera (Siphonaptera)), such as cat flea (Ctenocephalides felis), dog flea (Ctenocephalides canis), Xenopsylla flea (Xenopsylla cheopis), itchy flea (Pulexirritans), transdermal potential flea (Tunga penetrans) and with sick flea (Nosopsyllus fasciatus),

衣鱼、家衣鱼(缨尾目(Thysanura)),例如西洋衣鱼(Lepisma saccharina)和斑衣鱼(Thermobia domestica), Silverfish, firebrat (Thysanura (Thysanura)), for example, Lepisma saccharina (Lepisma saccharina) and spotted firebrat (Thermobia domestica),

百足虫(唇足纲(Chilopoda)),例如Scutigera coleoptrata, Centipedes (Chilopoda (Chilopoda)), for example Scutigera coleoptrata,

千足虫(倍足纲(Diplopoda)),例如Narceus属, Millipedes (Diplopoda (Diplopoda)), for example Narceus belong,

蠼蛸(革翅目(Dermaptera)),例如欧洲球螋(forficula auricularia), Qu octopus (Dermaptera (Dermaptera)), for example Forficula auricularia (forficula auricularia),

虱(毛虱目(Phthiraptera)),例如人头虱(Pediculus humanus capitis)、人体虱(Pediculus humanus corporis)、阴虱(Pthirus pubis)、牛血虱(Haematopinus eurysternus)、猪血虱(Haematopinus suis)、牛颚虱(Linognathus vituli)、Bovicola bovis、鸡虱(Menopon gallinae)、Menacanthus stramineus和Solenopotes capillatus, Lice (gross milkfish (Phthiraptera)), such as human head lice (Pediculus humanus capitis), body louse (Pediculus humanus corporis), pubic lice (Pthirus pubis), bovine blood louse (Haematopinus eurysternus), pig's blood lice (Haematopinus suis), cattle jaw louse (Linognathus vituli), Bovicola bovis, chicken lice (Menopon gallinae), Menacanthus stramineus and Solenopotes capillatus,

植物寄生线虫如根结线虫,花生根结线虫(Meloidogyne arenaria)、奇氏根结线虫(Meloidogyne chitwoodi)、短小根结线虫(Meloidogyne exigua)、北方根结线虫(Meloidogyne hapla)、南方根结线虫(Meloidogyneincognita)、爪哇根结线虫(Meloidogyne javanica)和其他根结线虫属(Meloidogyne);胞囊线虫,马铃薯金线虫(Globodera rostochiensis)、马铃薯白线虫(Globodera pallida)、烟草胞囊线虫(Globodera tabacum)和其他球胞囊线虫属(Globodera);禾谷胞囊线虫(Heterodera avenae)、大豆胞囊线虫(Heterodera glycines)、甜菜胞囊线虫(Heterodera schachtii)、三叶草胞囊线虫(Heterodera trifolii)和其他胞囊线虫属(Heterodera);种子肿瘿线虫,剪股颖粒线虫(Anguina funesta)、小麦粒线虫(Anguina tritici)和其他粒线虫属(Anguina);茎叶线虫,水稻干尖线虫(Aphelenchoides besseyi)、草莓滑刃线虫(Aphelenchoides fragariae)、菊花滑刃线虫(Aphelenchoidesritzemabosi)和其他滑 Plant parasitic nematodes such as root-knot nematode, the peanut root-knot nematode (Meloidogyne arenaria), Qi's root-knot nematode (Meloidogyne chitwoodi), short root-knot nematode (Meloidogyne exigua), northern root-knot nematode (Meloidogyne hapla), M. incognita ( Meloidogyneincognita), Javanese root-knot nematode (Meloidogyne javanica) and other Meloidogyne (Meloidogyne); cyst nematode, Globodera nematodes (Globodera rostochiensis), white potato nematode (Globodera pallida), tobacco cyst nematode (Globodera tabacum) and other ball cyst nematode genera (Globodera); cereal cyst nematode (Heterodera avenae), soybean cyst nematode (Heterodera glycines), beet cyst nematode (Heterodera schachtii), clover cyst nematode (Heterodera trifolii) and other cyst Strongyloides (, Heterodera); swollen seed gall nematodes, grains bentgrass nematode (Anguina funesta), wheat grain nematode (Anguina tritici), and other grains Strongyloides (Anguina); stem and leaf nematodes, Aphelenchoides besseyi (Aphelenchoides besseyi), strawberry Aphelenchoides (Aphelenchoides fragariae), chrysanthemum Aphelenchoides (Aphelenchoidesritzemabosi) and other slip 刃线虫属(Aphelenchoides);刺线虫,杂草刺线虫(Belonolaimus longicaudatus)和其他针刺线虫属(Belonolaimus);松线虫,松材线虫(Bursaphelenchus xylophilus)和其他伞滑刃线虫属(Bursaphelenchus);环形线虫,环纹线虫属(Criconema)、小环线虫属(Criconemella)、轮线虫属(Criconemoides)和中环线虫属(Mesocriconema);球茎线虫,腐烂茎线虫(Ditylenchus destructor)、甘薯茎线虫(Ditylenchusdipsaci)、蘑菇茎线虫(Ditylenchus myceliophagus)和其他茎线虫属(Ditylenchus);锥线虫,锥线虫属(Dolichodorus);螺旋形线虫,双宫螺旋线虫(Helicotylenchus dihystera)、多带螺旋(Heliocotylenchus multicinctus)和其他螺旋线虫属,强壮盘旋线虫(Rotylenchus robustus)和其他盘旋线虫属(Rotylenchus);鞘线虫,鞘线虫属(Hemicycliophora)和Hemicriconemoides属;Hirshmanniella属;冠线虫,哥伦比亚纽带线虫(Hoplolaimus columbus)、帽状纽带线虫(Hoplolaimus galeatus)和其他纽带 Of the Genus (, Aphelenchoides); thorn nematodes, weeds Heteraxine (Belonolaimus longicaudatus) and the other needle nematode genera (Belonolaimus); pine nematodes, pine wood nematode (Bursaphelenchus xylophilus), and other Bursaphelenchus genus (of Bursaphelenchus); annular nematodes, ringed Strongylus (Criconema), small ring genus (Criconemella), wheel Strongyloides (Criconemoides) and ring genus (Mesocriconema); bulb nematodes, Ditylenchus destructor (Ditylenchus destructor), Ditylenchus destructor (Ditylenchusdipsaci), mushroom stem nematode (Ditylenchus myceliophagus) and other Ditylenchus genera (, Ditylenchus); cone nematodes, cone Strongyloides (Dolichodorus); spiral nematodes, Douppion spiral nematode (Helicotylenchus dihystera), a multi-band spiral (Heliocotylenchus multicinctus) and other Helicotylenchus species, strong spiral nematode (Rotylenchus robustus) and other spiral nematode genera (Rotylenchus); sheath nematodes, sheath nematode genus (Hemicycliophora) and Hemicriconemoides genus; Hirshmanniella genera; crown nematodes, Colombia ties nematode (Hoplolaimus columbus), a cap-like ties nematode ( Hoplolaimus galeatus) and other bonds 虫(Hoplolaimus)属;伪根结线虫,异常珍珠线虫(Nacobbus aberrans)和其他珍珠线虫属(Nacobbus);针线虫,伸展长针线虫(Longidorus elongatus)和其他长针线虫属(Longidorus);针线虫,针线虫属(Paratylenchus);根腐线虫,最短尾短体线虫(Pratylenchus brachyurus)、咖啡短体线虫(Pratylenchus coffeae)、Pratylenchus curvitatus、古迪短体线虫(Pratylenchus goodeyi)、疏忽短体线虫(Pratylenchus neglectus)、穿刺短体线虫(Pratylenchus penetrans)、斯克里布纳短体线虫(Pratylenchusscribneri)、伤残短体线虫(Pratylenchus vulnus)、玉米短体线虫(Pratylenchus zeae)和其他短体线虫属(Pratylenchus);Radinaphelenchuscocophilus和其他Radinaphelenchus属;穿孔线虫,香蕉穿孔线虫(Radopholus similis)和其他穿孔线虫属(Radopholus);肾形线虫,肾形肾脏线虫(Rotylenchulus reniformis)和其他肾状线虫属(Rotylenchulus);盾线虫属(Scutellonema);残根线虫,原始毛刺线虫 Insect (Hoplolaimus) genus; Meloidogyne dummy abnormality pearl nematodes (Nacobbus aberrans) pearls and other nematode genera (Nacobbus); Needle nematodes, extending long needle nematode (Longidorus elongatus) long needle and other genera of nematodes (Longidorus); Needle nematodes needle nematodes genus (Paratylenchus); Pratylenchus, the shortest short tail nematode (Pratylenchus brachyurus), coffee Pratylenchus (Pratylenchus coffeae), Pratylenchus curvitatus, Goody Pratylenchus (Pratylenchus goodeyi), negligence Pratylenchus (Pratylenchus neglectus), Pratylenchus puncture (Pratylenchus penetrans), Pratylenchus Scribner (Pratylenchusscribneri), Pratylenchus disability (Pratylenchus vulnus), Pratylenchus maize (Pratylenchus zeae) Pratylenchus and other genera (Pratylenchus) ; Radinaphelenchuscocophilus and other Radinaphelenchus genera; Radopholus similis, Radopholus nematode (Radopholus similis), and other Radopholus genus (, Radopholus); reniform nematodes, reniform kidney nematode (Rotylenchulus reniformis), and other kidney-shaped nematode genera (Rotylenchulus); shield nematodes genus (Scutellonema); root nematodes, Trichodorus original (Trichodorus primitivus)和其他毛刺线虫属(Trichodorus);较小类毛刺线虫(Paratrichodorus minor)和其他类毛刺属(Paratrichodorus);阻长线虫,克莱顿矮化线虫(Tylenchorhynchus claytoni)、不定矮化线虫(Tylenchorhynchus dubius)以及其他矮化线虫属(Tylenchorhynchus)和节纹线虫属(Merlinius);柑桔线虫,柑桔半穿刺线虫(Tylenchulus semipenetrans)和其他小垫刃线虫属(Tylenchulus);剑线虫,美洲剑线虫(Xiphinema americanum)、标准剑线虫(Xiphinema index)、裂尾剑线虫(Xiphinema diversicaudatum)和其他剑线虫属(Xiphinema);以及其他植物寄生线虫。 (Trichodorus primitivus), and other Trichodorus genus (, Trichodorus); Trichodorus small class (Paratrichodorus minor), and other types of burrs genus (Paratrichodorus); long nematode resistance, Clayton dwarf nematodes (Tylenchorhynchus claytoni), variable Tylenchorhunchus (Tylenchorhynchus dubius) and other dwarf nematode genera (Tylenchorhynchus) and section grain nematode genera (Merlinius); citrus nematode, citrus nematode half puncture (Tylenchulus semipenetrans) and other small pad of the genus (Tylenchulus); Xiphinema, the Americas Xiphinema (Xiphinema americanum), standard Xiphinema (Xiphinema index), split tail Xiphinema (Xiphinema diversicaudatum) and other Xiphinema genus (Xiphinema); and other plant parasitic nematodes.

此外,本发明混合物尤其用于防治鳞翅目、鞘翅目、双翅目、缨翅目和膜翅目。 Furthermore, mixtures of the present invention in particular for controlling Lepidoptera, Coleoptera, Diptera, Thysanoptera and Hymenoptera.

此外,本发明混合物尤其用于防治非作物害虫(家庭、草皮、观赏植物)。 Furthermore, mixtures of the present invention in particular for controlling non-crop pests (household, turf, ornamental plants).

可将本发明混合物施用于害虫的任何和所有发育阶段,例如虫卵、幼虫、蛹和成虫。 The mixtures of the invention can be applied to any and all developmental stages of insect pests, e.g. eggs, larvae, pupae and adults. 可以通过使目标害虫、其食物供应源、栖息地、繁殖地或其场所与杀虫有效量的本发明混合物或包含所述混合物的组合物接触而防治害虫。 By contacting the target pest, its food supply, habitat, breeding ground or its locus with a pesticidally effective amount of the inventive mixtures or compositions comprising said mixture in contact for controlling pests.

“场所”是指其中害虫生长或会生长的植物、种子、土壤、区域、材料或环境。 "Locus" means a pest is growing or will grow a plant, seed, soil, area, material or environment in which.

杀虫有效量”通常指对生长获得可观察到的效果所需要的本发明混合物或包含所述混合物的组合物的量,所述效果包括坏死、死亡、阻滞、预防和去除效果,破坏效果或减少目标生物体的出现和活动的效果。对于在本发明中使用的各种混合物/组合物,杀虫有效量可以变化。混合物/组合物的杀虫有效量也会根据主要条件如所需杀虫效果及持续时间、天气、目标物种、场所、施用方式等而变化。 Pesticidally effective amount "generally refers to a mixture of the present invention can be grown to obtain the desired effect is observed or the amount of a composition comprising a mixture, including the effects of necrosis, death, retardation, prevention, and removal, destruction, or diminishing the occurrence and activity of the target organism effect for the various mixtures used in the present invention / compositions pesticidally effective amount can vary. the mixture / pesticidally effective amount of the composition according to the prevailing conditions such as desired also pesticidal effect and duration, weather, target species, locus, mode of application and the like.

本发明混合物或这些混合物的组合物还可以用于保护植物免受昆虫、螨虫或线虫侵袭或侵染,包括与植物或植物生长的土壤或水体接触。 Mixtures thereof or mixtures of these compositions of the present invention may also be used to protect plants from insects, acarids or nematodes attack or infestation, soil or water comprising a body and a contact plant or plant growth.

对本发明而言,术语植物是指整个植物、植物部分或植物的繁殖材料,即种子或秧苗。 For the present invention, the term plant refers to a whole plant, plant part or plant propagation material, i.e., seeds or seedlings.

可用本发明混合物处理的植物包括所有的基因修饰植物或转基因植物,例如由于包括基因工程方法在内的育种而耐受除草剂或杀真菌剂或杀虫剂作用的作物,或与存在的植物相比具有通过传统育种方法和/或产生突变体或通过重组程序而产生的修饰特征的植物。 Available treatment plant of the invention comprises a mixture of all genetically modified plants or transgenic plants, for example due to breeding, including genetic engineering methods rather tolerant to herbicides or fungicides or insecticides crops, plant, or the presence of a phase having a ratio by traditional breeding methods and / or modified features or the generation of mutants produced by recombinant procedures plants.

一些本发明混合物具有内吸作用且因此可用于保护植物枝抵抗叶面害虫以及处理用于种子和根以抵抗土壤害虫。 Some inventive mixtures have systemic action and can therefore be used to protect plants against the branches to pests and foliar treated seeds for root and against soil pests. 术语种子处理包括本领域已知的所有合适的种子处理技术,例如拌种、种子包衣、种子撒粉、种子浸泡和种子造粒。 The term seed treatment comprises all suitable seed treatment techniques known in the art, such as seed dressing, seed coating, seed dusting, seed soaking and seed pelleting.

化合物I和化合物II和III各自可以同时,即联合或分开施用或依次施用,在分开施用的情况下施用顺序通常对防治措施的结果没有任何影响。 Compound I and compounds II and III may each be simultaneously, i.e. jointly or separately administered or administered sequentially, the administration in the case of separate application generally has no effect on the sequence of results of the control measures.

本发明混合物还适用于保护种子和秧苗的根和枝,优选种子以对抗土壤害虫。 The present invention is applicable also to a mixture of protecting the seed and the seedlings' roots and shoots, preferably the seeds against soil pests.

尤其用于种子处理的组合物例如为: In particular, compositions for seed treatment, for example:

A可溶性浓缩物(SL、LS) A Soluble concentrates (SL, LS)

D乳液(EW、EO、ES) D Emulsions (EW, EO, ES)

E悬浮液(SC、OD、FS) E Suspensions (SC, OD, FS)

F水分散性颗粒和水溶性颗粒(WG、SG) F Water-dispersible granules and water-soluble granules (WG, SG)

G水分散性粉末和水溶性粉末(WP、SP、WS) G Water-dispersible powders and water-soluble powders (WP, SP, WS)

H凝胶配制剂(GF) H Gel formulations (GF)

I可撒粉粉末(DP、DS) I Dustable powders (DP, DS)

常规种子处理配制剂例如包括可流动浓缩物FS、溶液LS、用于干燥处理的粉末DS、用于浆料处理的水分散性粉末WS、水溶性粉末SS和乳液ES和EC和凝胶配制剂GF。 Conventional seed treatment formulations include for example flowable concentrates FS, solutions the LS, powders for drying treatment DS, water dispersible powders for slurry treatment WS, water soluble powders SS and emulsion ES and EC and gel formulation GF. 这些配制剂可稀释或不经稀释而施用于种子。 These formulations can be applied to the seed diluted or undiluted. 对种子的施用在播种之前直接对种子进行或在使种子预萌发后进行。 Administration of the seed or the seeds in the seeds after the pre-germinated directly before sowing. 优选FS配制剂。 Preferred are FS formulations.

在种子处理中,取决于所需效果和种子的种类,本发明混合物的施用率通常为每100kg种子0.001至10kg。 In the treatment of seed, depending on the desired effect and the type of seed, application rates of mixture of the present invention is usually from 0.001 per 100kg of seed to 10kg. 施用率优选为1-1000g/100kg种子,更优选1-750g/100kg,尤其是5-500g/100kg种子。 Administration rate is preferably 1-1000g / 100kg of seed, more preferably 1-750g / 100kg, especially 5-500g / 100kg seed. 化合物I和II或化合物I和II的混合物的分开或联合施用通过在植物播种之前或之后或植物出苗之前或之后对种子、秧苗、植物或土壤喷雾或撒粉而进行。 Administered separately or jointly by the seeds, the seedlings, the plants or soil by spraying or dusting before or after sowing the plants or before or after emergence of the plant a mixture of compounds I and II or of the compounds I and II.

本发明还涉及植物的繁殖产品,特别是包含,即涂覆和/或含有下列物质的种子:如上所定义的混合物,或含有两种或更多种活性成分的混合物的组合物,或两种或更多种各自提供活性成分之一的组合物的混合物。 The present invention also relates to the propagation product of plants, in particular comprising, i.e., coating and / or seeds containing the following substances: a mixture as defined above, or a composition comprising a mixture of two or more active ingredients, or both each providing one or a mixture of the active ingredient of the composition more. 种子以每100kg种子0.1g至10kg的量包含本发明混合物。 Seed comprises the inventive mixtures in an amount of 0.1g to 10kg per 100kg of seed.

本发明混合物通过接触(经由土壤、玻璃、墙壁、床网、地毯、植物部分或动物部分)和进食(诱饵或植物部分)以及通过交哺和转移起作用。 The mixture of the present invention through both contact (via soil, glass, wall, bed net, carpet, plant parts or animal parts), and food (bait, or plant part) and through trophallaxis and transfer function.

优选施用方法为施入水体,经由土壤、裂缝和裂隙、牧场、粪肥堆、下水道施用,施入水中,施用于地板、墙壁上,或通过周围喷雾施用和诱饵施用。 The method of administration is preferably administered into the body of water, via soil, cracks and crevices, pastures, manure piles, sewers administration, administration into water, on floor, wall, or by perimeter spray application and bait.

根据本发明的另一优选实施方案,为了用于对抗非作物害虫如蚂蚁、白蚁、黄蜂、蝇、蚊子、蟋蟀、蝗虫或蟑螂,将本发明混合物制备成诱饵制剂。 According to another preferred embodiment of the invention, for use against non crop pests such as ants, termites, wasps, flies, mosquitoes, crickets, locusts, or cockroaches the inventive mixtures are prepared into a bait preparation.

诱饵可以是液体、固体或半固体制剂(例如凝胶)。 The bait can be a liquid, a solid or a semisolid preparation (e.g. a gel). 用于组合物中的诱饵是具有足够的吸引力以刺激诸如蚂蚁、白蚁、黄蜂、蝇、蚊子、蟋蟀等的昆虫或蟑螂食用它的产品。 The bait employed in the composition which is sufficiently attractive to incite such as ants, termites, wasps, flies, mosquitoes, crickets etc. or cockroaches to eat it. 该吸引剂可以选自进食刺激剂或伪和/或性信息素。 This attractant may be chosen from feeding stimulants or dummy and / or sex pheromones. 本领域易于知道的是,化合物I和化合物II以500∶1-1∶500,优选500∶1-1∶100,更优选100∶1-1∶100,尤其是20∶1-1∶20,最优选10∶1-1∶10的重量比施用。 Is readily known in the art, compounds I and II to 500:1-1:500, preferably 500:1-1:100, more preferably 100:1-1:100, especially 20:1-1:20, the most preferred weight ratio 10:1-1:10 administration.

用本发明混合物及其各自的组合物防治由昆虫传播的传染病(例如疟疾、登革热和黄热病、淋巴丝虫病和利什曼病(leishmaniasis))的方法也包括处理房屋表面、空气喷雾和浸渍窗帘、帐篷、衣物、床网、舌蝇捕捉器或类似物。 Infectious diseases transmitted by insects according to the present invention with the mixture and their respective compositions (e.g. malaria, dengue and yellow fever, lymphatic filariasis, and leishmaniasis (leishmaniasis)) The house also comprise treating surfaces, air spray and impregnation of curtains, tents, clothing items, bed nets, tsetse-fly trap or the like. 施用于纤维、织物、针织品、非织造物、网状材料或箔片和防水布的杀虫组合物优选包含包括本发明混合物、任选驱除剂和至少一种粘合剂的组合物。 Insecticidal compositions for application to fibers, fabric, knitwear, non-wovens, netting material or foils and tarpaulins preferably comprise a mixture including the present invention, optionally a repellent and at least one binder composition.

本发明混合物和包含它们的组合物可用于保护木质材料如树木、护栏、枕木等,以及建筑物如房子、附属建筑物、工厂,还有建筑材料、家具、皮革、纤维、聚氯乙烯制品、电线和电缆等以防蚂蚁和/或白蚁,并防止蚂蚁和白蚁损害作物或人类(例如当害虫侵入房子和公共设施时)。 The present invention comprises a mixture thereof and compositions can be used for protecting wooden materials such as trees, board fences, sleepers, etc. and buildings such as houses, ancillary buildings, factories, but also construction materials, furniture, leathers, fibers, vinyl articles, wires and cables etc. from ants and / or termites, and ants and termites from doing harm to crops or human being (e.g. when the pests invade into houses and public facilities).

在土壤处理或施用于害虫栖息地或巢穴的情况下,活性成分的施用量为0.0001-500g/100m 2 ,优选0.001-20g/100m 2 In the case of soil treatment or of application to the pests dwelling place or nest, the quantity of active ingredient is administered 0.0001-500g / 100m 2, preferably 0.001-20g / 100m 2.

材料保护中的通常施用率例如为每平方米处理材料0.01-1000g活性化合物,理想的是每平方米0.1-50g活性化合物。 Application rates in the protection of materials are, for example, per square meter of treated material 0.01-1000g active compound, preferably 0.1-50g per square meter of active compound.

用于材料浸渍的杀虫组合物通常含有0.001-95重量%,优选0.1-45重量%,更优选1-25重量%至少一种驱除剂和/或杀虫剂。 The insecticidal composition used to impregnate materials typically contain from 0.001% by weight, preferably from 0.1 to 45% by weight, more preferably 1 to 25 wt% of at least one repellent and / or insecticide.

用于诱饵组合物的活性成分的典型含量为0.0001-15重量%,理想的是0.001-5重量%活性化合物。 The typical content of active ingredient used in a bait composition from 0.0001 to 15 wt%, desirably from 0.001% by weight of the active compound. 所用组合物还可以包含其它添加剂如活性材料的溶剂、调味剂、防腐剂、染料或苦味剂。 The composition may further contain other additives such as a solvent of the active material, flavorants, preservatives, a dye or a bitter agent. 其吸引力还可以通过特殊颜色、形状或结构而增强。 Attractiveness may also be enhanced by a special color, shape or configuration.

用于喷雾组合物的活性成分混合物含量为0.001-80重量%,优选0.01-50重量%,最优选0.01-15重量%。 The active ingredient content of the mixture for spray composition is from 0.001% by weight, preferably from 0.01 to 50% by weight, most preferably from 0.01 to 15 wt%.

用于处理作物的活性成分混合物的施用率可为每公顷0.1-4000g,理想的是每公顷25-600g,更理想的是每公顷50-500g。 Application rates for the active ingredient mixture may be treated crops per hectare 0.1-4000g, per hectare preferably 25-600g, per hectare is more preferably 50-500g.

本发明的目的还为提供适用于处理、防治、预防和保护,包括人在内的温血动物和鱼对抗害虫侵袭和侵染的混合物。 The present invention also provides for handling, control, prevention and protection, a mixture of pest infestations and infections of warm-blooded animals, including humans and fish fighting. 在动物和/或人身上或体内的害虫防治中可能遇到的问题类似于开头所述的那些,即需要降低剂量率和/或改进的活性谱和/或结合了击倒活性和长期防治和/或耐药性管理。 Or in animals and humans Question / or pest control body may encounter similar to those mentioned in the introduction, namely the need to reduce the dose rate and / or improved activity spectrum and / or a combination of active and long-term prevention and down / or resistance management.

本发明还提供了一种处理、防治、预防和保护包括人的温血动物和鱼对抗蚤目、膜翅目、半翅目、直翅目、蜱螨目、毛虱目和双翅目的害虫侵袭和侵染的方法,其包括将杀虫有效量的本发明混合物口服、局部或肠胃外给药或施用于所述动物。 The present invention also provides a method for treating, controlling, preventing and protecting warm-blooded animals, including humans, and fish against Siphonaptera, Hymenoptera, Hemiptera, Orthoptera, Acarina, Phthiraptera, and Diptera wool pests and infestation, which comprises a pesticidally effective amount of a mixture of the present invention for oral, topical or parenteral administration, or administered to the animal.

本发明还提供了一种制备用于处理、防治、预防或保护温血动物或鱼对抗蚤目、膜翅目、半翅目、直翅目、蜱螨目、毛虱目和双翅目害虫侵袭和侵染的组合物的方法,该组合物包含杀虫有效量的本发明混合物。 The present invention further provides a process for preparing for treating, controlling, preventing or protecting warm-blooded animals or fish against Siphonaptera, Hymenoptera, Hemiptera, Orthoptera, Acarina, Phthiraptera, and Diptera wool pests the method and compositions of infection, the composition comprising a pesticidally effective amount of a mixture of the present invention.

上述方法尤其用于防治和预防在温血动物如牛、绵羊、猪、骆驼、鹿、马、家禽、山羊、狗和猫以及人中的侵袭和侵染。 In particular, the above-mentioned method for controlling and preventing infestations and infections warm-blooded animals such as cattle, sheep, pigs, camels, deer, horses, poultry, goats, dogs and cats as well as humans in.

在温血动物和鱼中的侵袭包括但不限于虱、叮咬虱、蜱、鼻蝇、羊蜱蝇(keds)、叮咬蝇、家蝇(muscoid flies)、蝇、蝇蛆幼虫、恙螨、蚋、蚊子和跳蚤,其可由本发明混合物防治、预防或消除。 Infestations in warm-blooded animals and fish include, but are not limited to, lice, biting lice, ticks, nasal bots, sheep ticks flies (Keds), biting flies, Musca domestica (muscoid flies), flies, maggots, chiggers, gnats , mosquitoes and fleas, which may be mixtures of the present invention, prevention and treatment, prevention or elimination.

对于温血动物的口服给药,可将本发明混合物配制成动物饲料、动物饲料预混物、动物饲料浓缩物、丸剂、溶液、糊、悬浮液、浸液、凝胶、片剂、大丸剂和胶囊。 For oral administration, warm-blooded animals, the mixtures of the invention may be formulated as animal feeds, animal feed premixes, animal feed concentrates, pills, solutions, pastes, suspensions, drenches, gels, tablets, boluses and capsules. 此外,本发明混合物可在其饮用水中给药于动物。 Furthermore, mixtures of the present invention may be administered to the animals in their drinking water. 对于口服给药,所选剂型应给动物提供0.01-100mg/kg动物体重/天的混合物。 For oral administration, the dosage form chosen should provide the mixture 0.01-100mg kg of animal body weight / / day to the animal.

或者,本发明混合物可以肠胃外给药于动物,例如通过腔内(intraruminal)、肌内、静脉内或皮下注射。 Alternatively, the compound of the present invention may be administered to animals parenterally, for example by a cavity (intraruminal), intramuscular, intravenous or subcutaneous injection. 本发明混合物可以分散或溶于对于皮下注射而言生理上可接受的载体中。 The mixture may be dispersed or dissolved in the present invention is for subcutaneous injection in a physiologically acceptable carrier. 或者,可以将本发明混合物配制成皮下给药用植入物。 Alternatively, the compound of the present invention may be formulated into an implant for subcutaneous administration. 此外,本发明混合物可以透皮(transdermally)给药于动物。 Further, the present invention may be a mixture of transdermally (transdermally) administered to the animal. 对于肠胃外给药,所选剂型应给动物提供0.01-100mg/kg动物体重/天的混合物。 For parenteral administration, the dosage form chosen should provide the mixture 0.01-100mg / kg of animal body weight / day to the animal.

本发明混合物还可以浸洗液、粉剂、粉末、项圈、挂牌(medallions)、喷雾剂、蘸点(spot-on)和喷淋配制剂形式局部施用于动物。 The present invention may also be a mixture of dips, dusts, powders, collars, listing (medallions), spray, dip (spot-on) and the shower topical formulation administered to the animal. 对于局部施用,浸洗液和喷雾剂通常含有0.5-5,000ppm,优选1-3,000ppm本发明化合物。 For topical application, dips and sprays usually contain 0.5-5,000ppm, 1-3,000ppm preferred compounds of the present invention. 此外,本发明混合物可以配制成动物,尤其是四足动物如牛和绵羊用耳贴。 Furthermore, mixtures of the present invention may be formulated as an animal, particularly quadrupeds such as cattle and sheep ear tags.

生物实施例: Biological Examples:

1)杀真菌作用 1) fungicidal action

化合物和混合物的杀真菌效果可通过下列试验证实: Fungicidal effect compounds and mixtures can be demonstrated by the following tests:

将活性化合物单独或联合制成包含0.25重量%活性化合物的在丙酮或DMSO中的储备溶液。 The active compound alone or in combination made containing 0.25 wt% stock solution of active compound in acetone or DMSO. 将1重量%乳化剂 The 1% by weight of an emulsifier EL(具有乳化和分散作用的基于乙氧基化烷基酚的润湿剂)加入该溶液,并用水将混合物稀释至所需浓度。 EL (wetting agent based on ethoxylated alkylphenols having emulsifying and dispersing action) was added to the solution, and the mixture was diluted with water to the desired concentration.

将肉眼测定的侵染叶面积百分数转化成以未处理对照的%表示的效力。 The visually determined percentages of infected leaf areas were converted into efficacies expressed in% of the untreated control.

使用Abbot公式按如下计算效力(E): It is calculated as follows using Abbot's formula efficacy (E):

E=(1-α/β)·100 E = (1-α / β) · 100

α对应于处理植物的真菌侵染百分数,和 α corresponds to the percentage of fungal infection treatment plant, and

β对应于未处理(对照)植物的真菌侵染百分数。 β corresponding to the untreated (control) plants in% infection of the fungi.

效力为0表示处理植物的侵染水平相当于未处理的对照植物;效力为100表示处理植物未受侵染。 An efficacy of 0 means that the infection level of the treated plants corresponds to the untreated control plants; an efficacy of 100 means that the treated plants were not infected.

活性化合物的混合物的预期效力使用Colby公式[Colby SR,“计算除草剂组合的协同增效和拮抗响应”,Weeds(杂草), 15 ,第20-22页,1967)]确定并与观察的效力比较。 The expected efficacies of mixtures of active compounds were determined using Colby formula [Colby SR, "Calculation of herbicide combinations synergistic and antagonistic responses", Weeds (weeds), 15, pp. 20-22, 1967)] and compared with the observed comparison of efficacy.

Colby公式:E=x+yx·y/100 Colby's formula: E = x + yx · y / 100

E使用浓度为a和b的活性化合物A和B的混合物时的预期效力,以相对于未处理对照的%表示, E expected efficacy, when a concentration of a mixture of a and b of the active compounds A and B, relative to the untreated control, expressed in%,

x使用浓度为a的活性化合物A时的效力,以相对于未处理对照的%表示, x effect when used at a concentration of active compound A a of the untreated control, expressed in%,

y使用浓度为b的活性化合物B时的效力,以相对于未处理对照的%表示。 y is the efficacy when the concentration of the active compound B b of the untreated control, expressed in%.

应用实施例1-对由宫部旋孢腔菌引起的褐斑病的杀真菌防治(保护性) Fungicidal control (protection) Example 1- leaf spot caused by Cochliobolus Miyabe embodiment of the application

将盆栽稻秧苗的叶片用由储备溶液制备的活性成分浓度如下所述的含水悬浮液喷雾至滴流点。 Potted rice seedlings of the blade with the aqueous suspension sprayed to runoff point with the active ingredient concentration of the stock solution prepared as follows. 使植物风干。 The plants dry. 第二天将植物用宫部旋孢腔菌的含水孢子悬浮液接种。 The next day the plants were inoculated with an aqueous spore suspension spin chamber spore bacteria with Miyabe. 接着将试验植物立即转移至潮湿室中。 The test plants were then immediately transferred to a humid chamber. 在22-24℃和接近100%的相对湿度下6天后,以害病叶面积%肉眼评估叶片上真菌侵袭的程度。 After 6 days at 22-24 deg.] C and a relative humidity close to 100%, to the extent of diseased leaf area% fungal attack on the leaves visually evaluated.

试验结果显示,由于强效协同增效作用,本发明混合物的活性显著高于使用Colby公式预测的活性。 The test results show that, due potent synergistic effect, the active mixture of the present invention is significantly higher than that predicted using Colby's formula.

2)对抗动物害虫的作用 2) action against animal pests

以下测试显示本发明化合物和化合物II和III的混合物对特定害虫的防治效力。 The following tests show the control efficacy of compounds of the present invention is a mixture of compounds II and III and the specific pests. 然而,由所述化合物、混合物或组合物提供的害虫防治保护作用并不限于这些物种。 However, by the compound, mixture or protective effect of the pest control composition provides not limited to these species. 可相应测定本发明三元混合物的效力。 The effectiveness of the present invention may be a ternary mixture of the corresponding measurement. 在某些情况下,发现本发明化合物与其它无脊椎害虫防治化合物或试剂的组合显示出对抗某些重要的无脊椎害虫的协同增效效果。 In some cases, a combination of a compound of this invention other invertebrate pest control compounds or agents and exhibits against certain important invertebrate pests synergistic effect.

使用Colby方程确定混合物或组合物之间的协同增效作用或拮抗作用分析。 Colby's equation was used to determine the synergy between the mixtures or compositions or antagonism analysis.

应用实施例2 Application Example 2

为了评估通过接触或内吸措施对巢莱修尾蚜(Megoura viciae)的防治,试验单元由含有蚕豆叶片的24孔微滴定板组成。 To assess absorption through contact or repair measures nest Lai aphid (Megoura viciae) The test unit consists of 24-well-microtiter plates containing broad bean leaf disks.

使用含有75%水和25%DMSO的溶液配制化合物或混合物。 A 75% water and 25% DMSO solution containing the formulated compounds or mixtures. 使用定做的微雾化器将不同浓度的配制的化合物或混合物以2.5μl喷雾至叶片上,重复两次。 Using custom built micro atomizer different concentrations of formulated compounds or mixtures to 2.5μl sprayed onto the leaves, repeated twice.

对于这些试验中的实验混合物,将相同体积的两种混合搭配物在各自所需浓度下混合在一起。 For experimental mixtures in these tests, the same volume of two mixing partners are mixed together at the respective desired concentration.

施用后,将叶片风干且将5-8只蚜虫成虫置于微滴定板孔内的叶片上。 After administration, the blade and the air-dried 58 adult aphids placed on the leaf microtiter plate wells. 接着使蚜虫在经处理的叶片上吮吸且在23±1℃,50±5%RH下孵化5天。 Aphids then allowed to suck on the treated leaf and in 23 ± 1 ℃, incubation at 50 ± 5% RH 5 days. 接着肉眼评估蚜虫的死亡率及繁殖力。 Mortality and fecundity is then visually evaluated aphids.

在该试验中,使用化合物I-2,和N-(3′,4′-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺(化合物2.1)和5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)-[1,2,4]三唑并[1,5-a]嘧啶(化合物2.2)。 In this test, the compound I-2, and N- (3 ', 4'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methylpyrazole -4 - carboxamide (compound 2.1) and 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] pyrazolo [1,5-a] pyrimidine (compound 2.2).

获得如下结果: The following results were obtained:

巢莱修尾蚜 Levin nest repair aphid ppm ppm 平均防治% Average control% I-2 I-2 0.5 0.5 0 0 I-2 I-2 2.5 2.5 0 0 2.1 2.1 1000 1000 0 0 2.2 2.2 40 40 0 0 I-2+2.1 I-2 + 2.1 0.5+1000 0.5 + 1000 100 100 * I-2+2.2 I-2 + 2.2 2.5+40 2.5 + 40 75 * 75

根据Colby方程的协同增效防治效果 * According to the Colby Equation synergistic control effect

应用实施例3 Application Example 3

为了评估墨西哥棉铃象(Boll Weevil/Anthonomus grandis)的防治,试验单元由含有昆虫食物和20-30只墨西哥棉铃象虫卵的24孔微滴定板组成。 To assess Mexico Anthonomus grandis (Boll Weevil / Anthonomus grandis) the test unit consists of 24-well-microtiter plates containing an insect diet and 20-30 Mexico Anthonomus grandis eggs composition.

使用含有75%水和25%DMSO的溶液配制化合物或混合物。 A 75% water and 25% DMSO solution containing the formulated compounds or mixtures. 使用定做的微雾化器将不同浓度的配制的化合物或混合物以20μl喷雾至昆虫食物上,重复两次。 Using custom built micro atomizer different concentrations of formulated compounds or mixtures in 20μl sprayed onto the insect diet at two replications.

对于这些试验中的实验混合物,将相同体积的两种混合搭配物在各自所需浓度下混合在一起。 For experimental mixtures in these tests, the same volume of two mixing partners are mixed together at the respective desired concentration.

施用后,将微滴定板在23±1℃,50±5%RH下孵化5天。 After application, microtiter plates at 23 ± 1 ℃, incubation at 50 ± 5% RH 5 days. 接着肉眼评估虫卵和幼虫的死亡率。 Mortality is then visually evaluated eggs and larvae.

在该试验中,分别使用化合物I-2、丙氯灵、唑菌胺酯、N-[2-(1,1,2,3,3,3-六氟丙氧基)-苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺(化合物3.1)和N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺(化合物3.2)。 In this test, the compound I-2, prochloraz, pyraclostrobin, N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) - phenyl] - 3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide (compound 3.1) and N- (3 ', 4', 5'- trifluoromethyl-2-yl) -1- methyl-3-difluoromethyl--1H- pyrazole-4-carboxamide (compound 3.2).

获得如下结果: The following results were obtained:

墨西哥棉铃象 Mexican boll weevil ppm ppm 平均防治% Average control% I-2 I-2 0.5 0.5 0 0 丙氯灵 Prochloraz 40 40 0 0 唑菌胺酯 Pyraclostrobin 40 40 0 0 3.1 3.1 40 40 0 0 3.2 3.2 200 200 0 0 I-2+丙氯灵 I-2 + prochloraz 0.5+40 0.5 + 40 75 * 75 I-2+唑菌胺酯 I-2 + pyraclostrobin 0.5+40 0.5 + 40 75 * 75 I-2+3.1 I-2 + 3.1 0.5+40 0.5 + 40 100 100 * I-2+3.2 I-2 + 3.2 0.5+200 0.5 + 200 100 100 *

根据Colby方程的协同增效防治效果 * According to the Colby Equation synergistic control effect

应用实施例4 Application Example 4

为了评估地中海实蝇(Ceratitis capitata)的防治,试验单元由含有昆虫食物和50-80只地中海实蝇虫卵的96孔微滴定板组成。 To assess the Mediterranean fruitfly (Ceratitis capitata) the test unit consisted of 96-well-microtiter plates containing an insect diet and 50-80 C. capitata eggs composition.

使用含有75%水和25%DMSO的溶液配制化合物或混合物。 A 75% water and 25% DMSO solution containing the formulated compounds or mixtures. 使用定做的微雾化器将不同浓度的配制的化合物或混合物以5μl喷雾至昆虫食物上,重复两次。 Using custom built micro atomizer different concentrations of formulated compounds or mixtures to 5μl sprayed onto the insect diet at two replications.

对于这些试验中的实验混合物,将相同体积的两种混合搭配物在各自所需浓度下混合在一起。 For experimental mixtures in these tests, the same volume of two mixing partners are mixed together at the respective desired concentration.

施用后,将微滴定板在28±1℃,80±5%RH下孵化5天。 After application, microtiter plates were incubated at 28 ± 1 ℃, 80 ± 5% RH 5 days. 接着肉眼评估虫卵和幼虫的死亡率。 Mortality is then visually evaluated eggs and larvae.

应用实施例5 Application Example 5

为了评估烟芽夜蛾(Heliothis virescens)的防治,试验单元由含有昆虫食物和15-25只烟芽夜蛾虫卵的96孔微滴定板组成。 To assess the tobacco budworm (Heliothis virescens) the test unit consisted of 96-well-microtiter plates containing an insect diet and 15-25 H. virescens eggs composition.

使用含有75%水和25%DMSO的溶液配制化合物或混合物。 A 75% water and 25% DMSO solution containing the formulated compounds or mixtures. 使用定做的微雾化器将不同浓度的配制的化合物或混合物以10μl喷雾至昆虫食物上,重复两次。 Using custom built micro atomizer different concentrations of formulated compounds or mixtures in 10μl sprayed onto the insect diet at two replications.

对于这些试验中的实验混合物,将相同体积的两种混合搭配物在各自所需浓度下混合在一起。 For experimental mixtures in these tests, the same volume of two mixing partners are mixed together at the respective desired concentration.

施用后,将微滴定板在28±1℃,80±5%RH下孵化5天。 After application, microtiter plates were incubated at 28 ± 1 ℃, 80 ± 5% RH 5 days. 接着肉眼评估虫卵和幼虫的死亡率。 Mortality is then visually evaluated eggs and larvae.

在该试验中,分别使用化合物I-2、丙氯灵和唑菌胺酯。 In this test, the compound I-2, prochloraz and pyraclostrobin.

获得如下结果: The following results were obtained:

烟芽夜蛾 Tobacco budworm ppm ppm 平均防治% Average control% I-2 I-2 0.5 0.5 0 0 I-2 I-2 2.5 2.5 37.5 37.5 丙氯灵 Prochloraz 8 8 0 0 唑菌胺酯 Pyraclostrobin 200 200 0 0 I-2+丙氯灵 I-2 + prochloraz 2.5+8 2.5 + 8 87.5 87.5 * I-2+唑菌胺酯 I-2 + pyraclostrobin 0.5+200 0.5 + 200 50 * 50

根据Colby方程的协同增效防治效果 * According to the Colby Equation synergistic control effect

应用实施例6 Application Example 6

为了评估通过内吸措施对桃蚜(Myzus persicae)的防治,试验单元由含有在人工膜下的液体人工食物的96孔微滴定板组成。 To assess the prevention and treatment of green peach aphid (Myzus persicae) by the suction action, the test unit in an artificial membrane containing a liquid artificial diet in 96-well microtiter plates.

使用含有75%水和25%DMSO的溶液配制化合物或混合物。 A 75% water and 25% DMSO solution containing the formulated compounds or mixtures. 使用定做的移液管将不同浓度的配制的化合物或混合物移入蚜虫食物中,重复两次。 Using custom pipette different concentrations of formulated compounds or mixtures of aphids transferred to the food, repeated twice.

对于这些试验中的实验混合物,将相同体积的两种混合搭配物在各自所需浓度下混合在一起。 For experimental mixtures in these tests, the same volume of two mixing partners are mixed together at the respective desired concentration.

施用后,将5-8只蚜虫成虫置于微滴定板孔内的人工膜上。 After application, 5 - 8 adult aphids were placed on the artificial membrane inside the microtiter plate wells. 接着使蚜虫在经处理的蚜虫食物上吮吸且在23±1℃,50±5%RH下孵化3天。 Aphids then allowed to suck on the treated aphid and the food 23 ± 1 ℃, incubation at 50 ± 5% RH 3 days. 接着肉眼评估蚜虫的死亡率和繁殖力。 Aphid mortality is then visually evaluated and fecundity. 对于所试验的混合物,结果列于表2中。 For the mixture tested the results are shown in Table 2 below.

在该试验中,使用化合物I-2、肟醚菌胺、5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)-[1,2,4]三唑并[1,5-a]嘧啶(化合物2.2)和N-[2-(1,1,2,3,3,3-六氟丙氧基)-苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺(化合物3.1)。 In this test, the compound I-2, orysastrobin, 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) - [1,2,4] triazolo [1,5-a] pyrimidine (compound 2.2) and N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) - phenyl ] -3-fluoro-1-methyl -1H- pyrazole-4-carboxamide (compound 3.1).

获得如下结果: The following results were obtained:

桃蚜 Green peach aphid ppm ppm 平均防治% Average control% I-2 I-2 0.5 0.5 0 0 肟醚菌胺 Orysastrobin 40 40 0 0 唑菌胺酯 Pyraclostrobin 8 8 0 0 2.2 2.2 8 8 0 0

桃蚜 Green peach aphid ppm ppm 平均防治% Average control% 3.1 3.1 1000 1000 0 0 I-2+肟醚菌胺 I-2 + orysastrobin 0.5+40 0.5 + 40 50 * 50 I-2+唑菌胺酯 I-2 + pyraclostrobin 0.5+8 0.5 + 8 75 * 75 I-2+2.2 I-2 + 2.2 0.5+8 0.5 + 8 75 * 75 I-2+3.1 I-2 + 3.1 0.5+1000 0.5 + 1000 100 100 *

根据Colby方程的协同增效防治效果 * According to the Colby Equation synergistic control effect

Claims (28)

1.一种以协同增效有效量包含如下物质作为活性组分的三元农药混合物: A synergistically effective amount of a substance comprising the pesticide as an active ingredient a ternary mixture:
1)式I的邻氨基苯甲酰胺氨磺酰化合物: 1) of Formula I, anthranilamide sulfonamide compound:
其中取代基如下所定义: Wherein the substituents are defined as follows:
B 1为氢、氰基或氯; B 1 is hydrogen, cyano or chloro;
B 2为溴或CF 3 ;和 B 2 is a bromine or CF 3; and
R为氢或C 1 -C 6烷基; R is hydrogen or C 1 -C 6 alkyl;
with
2)一种选自下列组的杀真菌化合物II: 2) A fungicidal compound II is selected from the group of:
A)唑类,例如双苯三唑醇、糠菌唑、环唑醇、噁醚唑、烯唑醇、烯菌灵、氧唑菌、喹唑菌酮、腈苯唑、氟硅唑、粉唑醇、己唑醇、酰胺唑、环戊唑醇、环戊唑菌、腈菌唑、戊菌唑、丙环唑、丙硫菌唑、硅氟唑、三唑酮、唑菌醇、戊唑醇、氟醚唑、戊叉唑菌; A) azoles, such as bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, alkenyl benomyl, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, powder cyproconazole, hexaconazole, amides oxazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, triadimefon, triadimenol, pentyl cyproconazole, difenoconazole fluoro, triticonazole;
丙氯灵、稻瘟酯、烯菌灵、氟菌唑、氰霜唑; Prochloraz, pefurazoate, alkenyl benomyl, triflumizole, cyazofamid;
苯菌灵、多菌灵、涕必灵、麦穗宁; Benomyl, carbendazim, thiabendazole, fuberidazole;
噻唑菌胺、氯唑灵、土菌消; Ethaboxam, cloxacillin spirit, hymexazol;
B)嗜球果伞素,例如腈嘧菌酯、醚菌胺、烯肟菌酯、氟嘧菌酯、亚胺菌、叉氨苯酰胺、肟醚菌胺、啶氧菌酯、唑菌胺酯、肟菌酯; B) strobilurins, such as azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin esters, trifloxystrobin;
C)羧酰胺,例如萎锈灵、苯霜灵、啶酰菌胺、环酰菌胺、氟酰胺、丙氧灭绣胺、甲霜灵、精甲霜灵、甲呋酰胺、噁霜灵、氧化萎锈灵、吡噻菌胺、溴氟唑菌、烯酰吗啉、氟吗啉; C) carboxamides, such as carboxin, benalaxyl, boscalid, fenhexamid, flutolanil, propoxycarbonyl off embroidery amine, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, dimethomorph, flumorph;
氟吡菌胺、苯酰菌胺; Fluopicolide, zoxamide;
双氯氰菌胺、双炔酰菌胺; Diclocymet, mandipropamid amine;
D)杂环化合物,例如氟啶胺、啶斑肟; D) heterocyclic compounds such as fluazinam, pyrifenox;
磺嘧菌灵、环丙嘧啶、异嘧菌醇、嘧菌腙、嘧菌胺、氟苯嘧啶醇、二甲嘧菌胺; Sulfo ethyl benomyl, cyprodinil, mepanipyrim isopropyl alcohol, ferimzone, mepanipyrim, nuarimol, pyrimethanil;
嗪氨灵、唑菌嗪; Triforine, triazoxide;
拌种咯、氟噁菌; Fenpiclonil, fludioxonil;
吗菌灵、丁苯吗啉、克啉菌; It benomyl, fenpropimorph, tridemorph;
苯锈啶、异丙定、杀菌利、烯菌酮; Fenpropidin, iprodione, procymidone, vinclozolin;
噁唑酮菌、咪唑菌酮、噻菌灵; Oxazolone bacteria, fenamidone, thiabendazole;
吲唑磺菌胺、敌菌灵、哒菌清、咯喹酮、丙氧喹啉、三环唑; Indazol flusulfamide, anilazine, diclomezine, pyroquilon, proquinazid, tricyclazole;
噻二唑素、敌菌丹、克菌丹、灭菌丹、氰菌胺、喹氧灵; Acibenzolar, captafol, captan, folpet, fenoxanil, quinoxyfen;
E)氨基甲酸盐类,例如代森锰锌、代森锰、威百亩、代森联、福美铁、甲基代森锌、福美双、代森锌、福美锌; E) carbamates, such as mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram;
乙霉威、异丙菌胺、苯噻菌胺、百维灵; Diethofencarb, iprovalicarb, benthiavalicarb, propamocarb;
with
F)选自下列的其它活性化合物: The following additional active compound F) is selected from:
胍类:多果定、双胍辛醋酸盐、双胍盐; Guanidines: dodine, Iminoctadine acetate, guazatine;
抗菌素类:春雷素、多氧霉素、井冈霉素; Class antibiotics: kasugamycin element, polyoxin, validamycin;
硝基苯基衍生物:敌螨普, Nitrophenyl derivatives: dinocap,
含硫的杂环基化合物:二噻农、稻瘟灵; Sulfur-containing heterocyclyl compounds: dithianon, isoprothiolane;
有机金属化合物:三苯锡基盐 Organometallic compounds: fentin salts,
有机磷化合物:克瘟散、异稻瘟净、乙膦铝、定菌磷、甲基立枯磷; Organophosphorus compounds: edifenphos, iprobenfos, fosetyl aluminum, phosphorus gnotobiotic, tolclofos-methyl;
有机氯化合物:百菌清、抑菌灵、磺菌胺、六氯苯、四氯苯酞、戊菌隆、五氯硝基苯、对甲抑菌灵; Organochlorine compounds: chlorothalonil, dichlofluanid, flusulfamide, hexachlorobenzene, fthalide, pencycuron, quintozene, dichlofluanid to A;
无机活性化合物:波尔多液、氢氧化铜、王铜、碱式硫酸铜、硫; Inorganic active compounds: Bordeaux mixture, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur;
其他:环氟菌胺、清菌脲、甲菌定、乙菌定、呋氨丙灵、苯菌酮和螺噁茂胺; Other: cyflufenamid, cymoxanil, fixed bacteria A, B fixed bacteria, furosemide metalaxyl, metrafenone and spiroxamine;
with
3)一种选自上述A)-F)和G)-J)组的杀真菌化合物III: 3) one selected from the above A) -F) and G) -J) fungicidal compound III group:
G)选自下列的嗜球果伞素:(2-氯-5-[1-(3-甲基苄氧亚氨基)乙基]苄基)氨基甲酸甲酯、(2-氯-5-[1-(6-甲基吡啶-2-基甲氧亚氨基)乙基]苄基)氨基甲酸甲酯和2-(邻-(2,5-二甲基苯氧基亚甲基)苯基)-3-甲氧基丙烯酸甲酯; G) selected from the group consisting of strobilurin: (2-chloro-5- [1- (3-methyl-benzyloxyimino) ethyl] benzyl) carbamate, (2-chloro-5- [1- (6-methyl-pyridin-2-yl-methoxyimino) ethyl] benzyl) carbamate and 2- (o - (2,5-dimethyl-phenoxymethyl-methylene) benzene yl) -3-methoxy-acrylate;
H)选自下列的羧酰胺:呋吡唑灵、噻酰菌胺、N-(4'-溴联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-三氟甲基联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-氯-3'-氟联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(3',4'-二氯-4-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺、N-(3',4'-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺;3,4-二氯-N-(2-氰基苯基)异噻唑-5-甲酰胺;N-(2′,4′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′ H) selected from the group consisting of carboxamide: furosemide pyrazole spirit, tiadinil, N- (4'- bromo-biphenyl-2-yl) -4-difluoromethyl-2-methylthiazole-5-carboxylic amide, N- (4'- trifluoromethyl-biphenyl-2-yl) -4-difluoromethyl-2-methylthiazole-5-carboxamide, N- (4'- chloro-3'-fluoro biphenyl-2-yl) -4-difluoromethyl-2-methylthiazole-5-carboxamide, N- (3 ', 4'- dichloro-4-fluoro-2-yl) -3 - difluoromethyl-1-methylpyrazole-4-carboxamide, N- (3 ', 4'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1 methylpyrazole-4-carboxamide; 3,4-dichloro -N- (2- cyanophenyl) isothiazole-5-carboxamide; N- (2 ', 4'- difluoro-biphenyl -2 - yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- dichloro-biphenyl-2-yl) -1-methyl - -1H- pyrazole-3-trifluoromethyl-4-carboxamide; N- (2 ', 4'- difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N - (2 ', 5'-difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N-(2', 5'- chloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ' 5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联苯-2-基)-3-二-氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺、N-(3′,5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺、N-(3′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′-氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺、N-(3′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′-氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺 5'-difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2 ', 5'- dichloro-biphenyl -2 - yl) -3-- fluoro-1-methyl -1H- pyrazole-4-carboxamide; N- (3 ', 5'- difluoro-biphenyl-2-yl) -1-methyl -1H- pyrazole-3-trifluoromethyl-4-carboxamide; N- (3 ', 5'- dichloro-biphenyl-2-yl) -1H-methyl-3 - pyrazole-4-carboxamide, N- (3 ', 5'- difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (3 ', 5'- dichloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (3'- fluoro-biphenyl 2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide, N- (3'- chloro-biphenyl-2-yl) -1-methyl-3- trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3'- fluoro-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxylic acid amide, N- (3'- chloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-biphenyl -2 - yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2'- chloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl methyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide N-(2′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟-4′-氯-5′-甲基联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-3-氯氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺、N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,2-四氟乙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲 N- (2'- chloro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-4'-chloro - 5'-methyl-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-linking phenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-2-yl) 3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl - 3-difluoromethyl--1H- pyrazole-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-2-yl) -3-chlorofluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- [2- (1,1,2,3,3,3- hexafluoro-propoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide, N- [2- (2- chloro-1,1,2-trifluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H - pyrazole-4-carboxamide; N- [2- (2- chloro-1,1,2-trifluoroethoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazol 4-carboxamide; N- [2- (1,1,2,2- tetrafluoroethoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazol-4 armor 胺;N-[2-(1,1,2,2-四氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(4′-(三氟甲硫基)联苯-2-基)-3-二-氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(4′-(三氟甲硫基)联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;5-氟-1,3-二甲基-1H-吡唑-4-甲酸[2-(1,2-二甲基-丙基)-苯基]-酰胺、氟联苯菌、氯环丙酰胺,以及N-(2-(4-[3-(4-氯苯基)丙-2-炔基氧基]-3-甲氧基苯基)乙基)-2-甲磺酰氨基-3-甲基丁酰胺、N-(2-(4-[3-(4-氯苯基)丙-2-炔基氧基]-3-甲氧基苯基)乙基)-2-乙磺酰氨基-3-甲基丁酰胺; Amine; N- [2- (1,1,2,2- tetrafluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -3-- fluoro-1-methyl -1H- pyrazole-4-carboxamide; N-(4' - (three fluoro-methylthio) biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; 5-fluoro-1,3-dimethyl-pyrazol -1H- 4-carboxylic acid [2- (1,2-dimethyl - propyl) - phenyl] - amide, flurbiprofen bacteria, carpropamid, and N- (2- (4- [3- ( 4-chlorophenyl) prop-2-ynyloxy] -3-methoxyphenyl) ethyl) -2-methanesulfonyl-amino-3-methylbutyramide, N- (2- (4- [3- (4-chlorophenyl) prop-2-ynyloxy] -3-methoxyphenyl) ethyl) -2- ethanesulfonylamino-3-methylbutanamide;
I)选自下列的杂环化合物: I) a heterocyclic compound selected from the group consisting of:
4-十二烷基-2,6-二甲基吗啉、异噻菌酮、吲唑磺菌胺、哒菌清、5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)[1,2,4]三唑并[1,5-a]嘧啶、6-(3,4-二氯苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-(4-叔丁基苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-甲基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-乙基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-丙基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲氧基甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-三氟甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺和5-三氟甲基-6-(3, 4-dodecyl-2,6-dimethyl morpholine, isothiazole, cycloheximide, indazole flusulfamide, diclomezine, 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine, 6- (3,4-dichlorophenyl) -5- yl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6- (4-tert-butyl-phenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1, 5-a] pyrimidin-7-ylamine, 5-methyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-methyl - 5- octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-ethyl-5-octyl - [1,2,4] triazolo [ 1,5-a] pyrimidin-7-ylamine, 5-ethyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-acetate -6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-octyl-5-propyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methoxy-6-octyl - [1,2,4] triazolo [1 , 5-a] pyrimidin-7-ylamine, 6-octyl-5-trifluoromethyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and 5- trifluoromethyl-6- (3, 5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、2-丁氧基-6-碘-3-丙基苯并吡喃-4-酮;棉隆、3-[5-(4-氯苯基)-2,3-二甲基异噁唑烷-3-基]吡啶; 5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 2-butoxy-6-iodo-3-propyl-benzo pyran-4-one; dazomet, 3- [5- (4-chlorophenyl) -2,3-dimethyl-isoxazol-3-yl] pyridine;
with
J)选自下列的其它活性化合物:威百亩、3-(4-氯苯基)-3-(2-异丙氧羰基氨基-3-甲基丁酰氨基)丙酸甲酯;链霉素、乐杀螨、敌螨通; J) selected from the group consisting of other active compounds: metam, 3- (4-chlorophenyl) -3- (2-isopropoxycarbonyl-amino-3-methylbutyrylamino) propanoate; streptavidin Su, binapacryl, mites through the enemy;
薯瘟锡、藻菌磷、亚磷酸及其盐、六氯苯、甲基托布津,和醋酸铜。 Fentin acetate, fosetyl, phosphorous acid and its salts, hexachlorobenzene, thiophanate-methyl, and copper acetate.
2.根据权利要求1的农药混合物,其以100∶1-1∶100的重量比包含式I化合物和化合物II。 2. The pesticidal mixture according to claim 1, which comprises in a weight ratio 100:1-1:100 compound of Formula I and the compound II.
3.根据权利要求1或2的农药混合物,其包含式I化合物3-溴-4′-氰基-1-(3-氯-2-吡啶基)-2′-甲基-6′-(甲基氨基甲酰基)吡唑-5-甲酰苯胺作为组分1。 The pesticidal mixture according to claim 1 or 2, comprising a compound of Formula I 3-bromo-4'-cyano-1- (3-chloro-2-pyridyl) -2'-methyl-6 '- ( methylcarbamoyl) pyrazole-5-carboxanilide as component 1.
4.根据权利要求1或2的农药混合物,其包含化合物3-溴-4′-氯-1-(3-氯-2-吡啶基)-2′-甲基-6′-(甲基氨基甲酰基)吡唑-5-甲酰苯胺作为组分1。 The pesticidal mixture according to claim 1 or 2, comprising a compound of 3-bromo-4'-chloro-1- (3-chloro-2-pyridyl) -2'-methyl-6 '- (methylamino formyl) pyrazole-5-carboxanilide as component 1.
5.根据权利要求1-4中任一项的农药混合物,其包含选自根据权利要求1的嗜球果伞素的活性化合物II作为组分2。 Pesticide mixture as claimed in any one of claims 1 to 4, which comprises the active compound is selected from strobilurin II of claim 1 as component 2.
6.根据权利要求1-5中任一项的农药混合物,其包含选自腈嘧菌酯、醚菌胺、烯肟菌酯、叉氨苯酰胺和肟醚菌胺的活性化合物II作为组分2。 The pesticidal mixture according to any one of claims 1-5 claims, selected from the group comprising azoxystrobin, dimoxystrobin, enestroburin, metominostrobin orysastrobin and compound II as an active component 2.
7.根据权利要求1-6中任一项的农药混合物,其包含肟醚菌胺作为组分2。 7. The pesticidal mixture according to any one of claims 1 to 6, comprising as component orysastrobin 2.
8.根据权利要求1-4中任一项的农药混合物,其包含氟菌唑作为组分2。 8. The pesticidal mixture according to any one of claims 1 to 4, comprising as component 2 triflumizole.
9.根据权利要求1-4中任一项的农药混合物,其包含选自氯环丙酰胺、双氯氰菌胺、呋吡唑灵、溴氟唑菌和噻酰菌胺的活性化合物II作为组分2。 The active compounds according to the pesticide mixture as claimed in any one of claims 1-4, selected from the group comprising carpropamid, diclocymet, furosemide pyrazole spirit, thifluzamide tiadinil and II, as component 2.
10.根据权利要求1-4中任一项的农药混合物,其包含选自噻菌灵、咯喹酮和三环唑的活性化合物II作为组分2。 10. The pesticidal mixture according to any one of claims 1-4, selected from the group comprising thiabendazole, pyroquilon and tricyclazole active compound II as component 2.
11.根据权利要求1-10中任一项的农药混合物,其包含选自根据权利要求1的A)-F)组的活性化合物作为组分3。 11. The pesticidal mixture according to any one of claims 1 to 10 claims, comprising A 1 is selected in accordance) -F) set forth in claim 3 as a component of the active compound.
12.根据权利要求1-10中任一项的农药混合物,其包含选自根据权利要求1的G)-J)组的活性化合物III作为组分3。 12. The pesticidal mixture according to any one of claims 1 to 10 claims, according to which G 1 is selected from the group comprising a) -J & lt) set forth in claim active compound III as component 3.
13.根据权利要求1-10和12中任一项的农药混合物,其包含选自H)组的活性化合物III作为组分3。 1-10 and 13. The pesticidal mixture according to any one of 12 claims, comprising selected H) Group III active compound as component 3.
14.根据权利要求1-10、12和13中任一项的农药混合物,其包含选自下列的活性化合物III作为组分3:N-(4'-溴联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-三氟甲基联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(4'-氯-3'-氟联苯-2-基)-4-二氟甲基-2-甲基噻唑-5-甲酰胺、N-(3',4'-二氯-4-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺、N-(3',4'-二氯-5-氟联苯-2-基)-3-二氟甲基-1-甲基吡唑-4-甲酰胺;3,4-二氯-N-(2-氰基苯基)异噻唑-5-甲酰胺;N-(2′,4′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,4′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联 14. The pesticidal mixture according to claim 1-10,12 and in any one of claims 13, comprising an active compound selected from the group consisting of III as component 3: N- (4'- bromo-biphenyl-2-yl) -4 --difluoromethyl-2-methylthiazole-5-carboxamide, N- (4'- trifluoromethyl-biphenyl-2-yl) -4-difluoromethyl-2-methylthiazole-5 carboxamide, N- (4'- chloro-3'-fluoro-2-yl) -4-difluoromethyl-2-methylthiazole-5-carboxamide, N- (3 ', 4'- dichloro-4-fluoro-2-yl) -3-difluoromethyl-1-methylpyrazole-4-carboxamide, N- (3 ', 4'- dichloro-biphenyl 2-yl) -3-difluoromethyl-1-methylpyrazole-4-carboxamide; 3,4-dichloro -N- (2- cyanophenyl) isothiazole-5-carboxamide; N- (2 ', 4'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2', 4'- dichloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- difluoro-biphenyl-2-yl) 3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2 ', 4'- dichloro-biphenyl-2-yl) -3-difluoro-methyl-1 - methyl -1H- pyrazole-4-carboxamide; N- (2 ', 5'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazol - 4-carboxamide; N- (2 ', 5'- dichlorobenzidine -2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′,5′-二氯联苯-2-基)-3-二-氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺、N-(3′,5′-二氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′,5′-二氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(3′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺、N-(3′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′-氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺、N-(3′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2′-氯联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(2 2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (2 ', 5'- difluoro-biphenyl-2-yl) -3- fluoro-1-methyl -1H- pyrazole-4-carboxamide; N- (2 ', 5'- dichloro-biphenyl-2-yl) -3-- fluoro-1-methyl -1H- pyrazole-4-carboxamide; N- (3 ', 5'- difluoro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxylic amide; N- (3 ', 5'- dichloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide, N- (3', 5 '- difluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (3', 5'- dichloro-2 yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (3'- fluoro-biphenyl-2-yl) -1-methyl-3- trifluoromethanesulfonyloxy yl -1H- pyrazole-4-carboxamide, N- (3'- chloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N - (3'-fluoro-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide, N- (3'- chloro-biphenyl-2-yl) 3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-2-yl) -1-methyl-3-trifluoromethyl - 1H- pyrazole-4-carboxamide; N- (2'- chloro-biphenyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N-( 2 -氟联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氯联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(2′-氟-4′-氯-5′-甲基联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(2′,4′,5′-三氟联苯-2-基)-1-甲基-3-二氟甲基-1H-吡唑-4-甲酰胺;N-(3′,4′,5′-三氟联苯-2-基)-3-氯氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,3,3,3-六氟丙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺、N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-[2-(2-氯-1,1,2-三氟乙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;4-甲酸-N-[2-(1 - fluoro-biphenyl-2-yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (2'- chloro-biphenyl-2-yl) -3- fluoro-1-methyl -1H- pyrazole-4-carboxamide; N- (2'- fluoro-4'-chloro-5'-methylbiphenyl-2-yl) -1-methyl - -1H- pyrazole-3-trifluoromethyl-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (3 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-difluoromethyl--1H- pyrazol - 4-carboxamide; N- (2 ', 4', 5'- trifluoromethyl-2-yl) -1-methyl-3-difluoromethyl--1H- pyrazole-4-carboxamide; N - (3 ', 4', 5'-trifluoro-2-yl) -3-chlorofluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- [2- (1 , 1,2,3,3,3-hexafluoro-propoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- [2- (1 , 1,2,3,3,3-hexafluoro-propoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide, N- [2- (2 - chloro-1,1,2-trifluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- [2- (2- chloro 1,1,2-trifluoroethoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; 4- carboxylic acid -N- [2- (1 1,2,2-四氟乙氧基)苯基]-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-[2-(1,1,2,2-四氟乙氧基)苯基]-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺;N-(4′-(三氟甲硫基)联苯-2-基)-3-二氟甲基-1-甲基-1H-吡唑-4-甲酰胺;N-(4′-(三氟甲硫基)联苯-2-基)-1-甲基-3-三氟甲基-1H-吡唑-4-甲酰胺。 1,2,2-tetrafluoroethoxy) phenyl] -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- [2- (1,1,2, 2- tetrafluoroethoxy) phenyl] -1-methyl-3-trifluoromethyl -1H- pyrazole-4-carboxamide; N- (4 '- (trifluoromethylthio) biphenyl - 2- yl) -3-difluoromethyl-1-methyl -1H- pyrazole-4-carboxamide; N- (4 '- (trifluoromethylthio) biphenyl-2-yl) -1- methyl-3-trifluoromethyl--1H- pyrazole-4-carboxamide.
15.根据权利要求1-10和12中任一项的农药混合物,其包含选自下列的活性化合物III作为组分3:5-氯-7-(4-甲基哌啶-1-基)-6-(2,4,6-三氟苯基)[1,2,4]三唑并[1,5-a]嘧啶、6-(3,4-二氯苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-(4-叔丁基苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-甲基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-乙基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-丙基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲氧基甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-三氟甲基-[1,2,4]三唑并[1,5-a]嘧 1-10 and 15. The pesticidal mixture according to any one of 12 claims, comprising an active compound selected from the group consisting of III as component 3: 5-Chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorophenyl) [1,2,4] triazolo [1,5-a] pyrimidine, 6- (3,4-dichlorophenyl) -5- yl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6- (4-tert-butyl-phenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1, 5-a] pyrimidin-7-ylamine, 5-methyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-methyl - 5- octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-ethyl-5-octyl - [1,2,4] triazolo [ 1,5-a] pyrimidin-7-ylamine, 5-ethyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-acetate -6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-octyl-5-propyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methoxy-6-octyl - [1,2,4] triazolo [1 , 5-a] pyrimidin-7-ylamine, 6-octyl-5-trifluoromethyl - [1,2,4] triazolo [1,5-a] pyrimidine 啶-7-基胺和5-三氟甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺。 -7-ylamine and 5-trifluoromethyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7 amine.
16.根据权利要求1-10、12和15中任一项的农药混合物,其包含选自下列的活性化合物III作为组分3:6-(3,4-二氯苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-(4-叔丁基苯基)-5-甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-甲基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-乙基-5-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-乙基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-丙基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、5-甲氧基甲基-6-辛基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺、6-辛基-5-三氟甲基-[1,2,4]三唑并[1,5-a]嘧啶-7-基胺和5-三氟甲基-6-(3,5,5-三甲基己基)-[1,2,4]三唑并[1,5-a] 16. The pesticidal mixture according to claim 1-10,12, and any one of claims 15, comprising an active compound selected from the group consisting of III as component 3: 6- (3,4-dichlorophenyl) -5- yl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6- (4-tert-butyl-phenyl) -5-methyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1, 5-a] pyrimidin-7-ylamine, 5-methyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-methyl - 5- octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-ethyl-5-octyl - [1,2,4] triazolo [ 1,5-a] pyrimidin-7-ylamine, 5-ethyl-6-octyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-acetate -6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 6-octyl-5-propyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine, 5-methoxy-6-octyl - [1,2,4] triazolo [1 , 5-a] pyrimidin-7-ylamine, 6-octyl-5-trifluoromethyl - [1,2,4] triazolo [1,5-a] pyrimidin-7-ylamine and 5- trifluoromethyl-6- (3,5,5-trimethyl-hexyl) - [1,2,4] triazolo [1,5-a] 啶-7-基胺。 Yl-7-amine.
17.一种农药组合物,其包含液体或固体载体和根据权利要求1-16中任一项的混合物。 17. A pesticidal composition, comprising a liquid or solid carrier and a mixture according to any one of 1-16 claims.
18.一种防治植物病原性有害真菌的方法,其中用有效量的根据权利要求1的化合物I、一种化合物II和一种化合物III处理真菌,其栖息地或需防止真菌侵袭的植物,土壤或种子。 18. A method phytopathogenic harmful fungi control, wherein an effective amount of a compound according to claim I 1, the compound II and compound III treating the fungi, the fungi or their habitat a plant to be protected from soil or seeds.
19.一种防治昆虫、蜘蛛或线虫的方法,其包括使昆虫、螨虫或线虫或其食物供应源、栖息地、繁殖地或其场所与杀虫有效量的如权利要求1-11中任一项所定义的混合物接触。 19. A method of controlling insects, arachnids or nematodes, which comprises contacting the insect, mite, or nematode or their food supply, habitat, breeding ground or its locus with a pesticidally effective amount of a claimed in any of claims 1-11 contacting the mixture defined terms.
20.一种保护植物免受昆虫、螨虫或线虫侵袭或侵染的方法,其包括使植物,或植物在其中生长的土壤或水体与杀虫有效量的如权利要求1-11中任一项所定义的混合物接触。 20. A method of protecting plants from insects, acarids or nematodes attack or infestation, which comprises contacting a plant, or plant of any one of 1-11 in which soil or water with a pesticidally effective amount of growth as claimed in claim contacting the mixture defined.
21.根据权利要求19或20的方法,其中以5-2000g/ha的量施用如权利要求1-11中任一项所要求的混合物。 21. The method according to claim 19 or 20 wherein the mixture of any one of claims 1-11 wherein the amount of 5-2000g / ha of administration as claimed in claim.
22.一种保护种子的方法,其包括使种子与杀虫有效量的如权利要求1-11中任一项所定义的混合物接触。 22. A method for protecting a seed, as defined in any one of 1-11 which comprises contacting a mixture of the seed with a pesticidally effective amount of a claim.
23.根据权利要求22的方法,其中以每100kg种子0.001g至10kg的量施用如权利要求1-11中任一项所要求的混合物。 23. The method according to claim 22, wherein an amount of 10kg per 100kg of seed to 0.001g of administration as claimed in any one of the mixture as claimed in claims 1-11.
24.种子,其以每100kg种子0.1g至10kg的量包含如权利要求1-11中任一项所要求的混合物。 24. Seed, comprising an amount of 0.1g to 10kg per 100kg of seed mixture as claimed in any one of 1-11 as claimed in claim.
25.根据权利要求18-23中任一项的方法,其中将如权利要求1-11中任一项所定义的式I化合物和化合物II同时,即联合或分开,或依次施用。 25. The method according to any one of claims 18-23, wherein the as claimed in any of claims 1-11 and a compound as defined in formula I II simultaneously, that is jointly or separately, or in succession.
26.一种处理、防治、预防或保护温血动物或鱼免受寄生虫侵袭或侵染的方法,其包括将杀寄生虫有效量的如权利要求1-11中任一项所定义的混合物口服、局部或肠胃外给药或施用于所述动物或鱼。 26. A method for treating, controlling, preventing or protecting warm-blooded animals or fish parasites from attack or infestation, which comprises a mixture of 1-11 as defined in any one parasiticidally effective amount of a claim oral, topical or parenteral administration, or administered to said animal or fish.
27.一种制备用于处理、防治、预防或保护温血动物或鱼免受昆虫或螨虫侵袭或侵染的组合物的方法,所述组合物包含杀寄生虫有效量的如权利要求1-11中任一项所定义的混合物。 Composition comprising a parasiticidally effective amount 27. A preparation as claimed for treating, controlling, preventing or protecting warm-blooded animals or fish, insects or mites methods from attack or infestation composition, the composition in claim 1- a mixture as defined in any one 11.
28.如权利要求1-11中任一项所定义的混合物在对抗昆虫、蜘蛛或线虫中的用途。 28. The mixture defined in any one of 1-11 claims for combating insects, arachnids or nematodes.
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