CN103210938A - Pesticide composition - Google Patents

Pesticide composition Download PDF

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CN103210938A
CN103210938A CN2013101489542A CN201310148954A CN103210938A CN 103210938 A CN103210938 A CN 103210938A CN 2013101489542 A CN2013101489542 A CN 2013101489542A CN 201310148954 A CN201310148954 A CN 201310148954A CN 103210938 A CN103210938 A CN 103210938A
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chlorantraniliprole
kresoxim
pyrazole
active ingredient
seed
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CN2013101489542A
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Chinese (zh)
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杨会营
刘晓娇
吴勇
马嵩岳
王占娣
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北京燕化永乐农药有限公司
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Priority to CN2013101489542A priority Critical patent/CN103210938A/en
Publication of CN103210938A publication Critical patent/CN103210938A/en

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Abstract

The invention relates to a pesticide composition. The pesticide composition is composed of chlorantraniliprole and pyraclostrobin, wherein the weight ratio of chlorantraniliprole to pyraclostrobin is (1-50):(50-1). The pesticide composition can be prepared into a suspended seed coating, the aim of increasing yield is achieved while insects and bacteria are killed, and the labour cost of farmers can be reduced.

Description

农药组合物 Pesticidal composition

技术领域 FIELD

[0001] 本发明属于农药技术领域具有增效作用的农药组合物,其有效成分为氯虫苯甲酰胺和吡唑醚菌酯。 [0001] The present invention belongs to the technical field of pesticide a synergistic pesticidal compositions, the active ingredient is chlorantraniliprole and kresoxim-pyrazole.

背景技术 Background technique

[0002] 氯虫苯甲酰胺(Chlorantraniliprole)是美国杜邦公司开发的一种全新低毒高效杀虫剂,氯虫苯甲酰胺高效广谱,对鳞翅目的夜蛾科、螟蛾科、蛀果蛾科、卷叶蛾科、粉蛾科、菜蛾科、麦蛾科、细蛾科等均有很好的控制效果,还能控制鞘翅目象甲科,叶甲科,双翅目潜蝇科,烟粉虱等多种非鳞翅目害虫。 [0002] of chlorantraniliprole (chlorantraniliprole) developed by DuPont is a new low toxicity and efficient pesticides, chlorantraniliprole efficient broad-spectrum of Lepidoptera Noctuidae, Pyralidae, fruit moth moth, Tortricidae, flour moth, plutellidae, Gelechiidae, fine moth and so have a good result, but also to control Coleoptera Curculionidae, Chrysomelidae, Diptera Agromyzidae, smoke powder lice and other non-lepidopteran pests. 据初步试用,对鳞翅目的害虫效果确实非常好、控制时间很长。 According to preliminary trial, the effect of the pest Lepidoptera really very good, very long time control.

[0003]卩比唑醚菌酯(Pyraclostrobin)为新型的低毒、高效、广谱杀菌剂。 [0003] Jie-pyrazol kresoxim (pyraclostrobin) are novel low toxicity, efficient, broad-spectrum fungicide. 该成分为线粒体呼吸抑制剂,即通过·在细胞色素合成中阻止电子转移,从而达到杀菌的目的。 The content of the mitochondrial respiratory inhibitors, i.e., to prevent the electron transfer in the dye cell by-synthesis, so as to achieve the purpose of sterilization. 该成分具有保护、治疗、叶片渗透传导作用。 The component has a protective, therapeutic, leaf osmotic conduction. 吡唑醚菌酯乳油经田间药效试验结果表明对黄瓜白粉病、霜霉病和香蕉黑星病、叶斑病有较好的防治效果。 Pyrazole Kresoxim EC by field experiments showed that cucumber powdery mildew, downy mildew and scab banana, leaf spot better control effect. 该成分经过田间药效实验表明对黄瓜、香蕉安全,未见药害发生。 The ingredients through the field efficacy experiment shows cucumber, banana safe, no injury occurred.

[0004] 悬浮种衣剂是悬浮剂的一种,由原药、成膜剂、润湿剂、分散剂、润湿剂、着色剂、填料和水经过研磨后制得的一种可流动的均匀悬浮液,主要用于种子处理,由于其使用方便、安全可靠而备受农民青睐。 [0004] The flowable concentrate is a suspension, the original drug, film formers, wetting agents, dispersing agents, wetting agents, colorants, filler and water after polishing system of a flowable homogeneous suspension, mainly used for seed treatment, because of its ease of use, safe, reliable and highly favored by farmers. 利用种子处理剂在种子播种前进行处理,制剂能够在种子表面固化成膜,所含的农药成分能够缓慢的释放,在种子发芽期间保护种子,杀灭地下害虫以及土传病害,防治苗期病害和系统性病害,提高种子发芽率。 Seed treatment agent before sowing of the seed in the formulation is capable of curing the surface of the film-forming seed, pesticide component can be contained in a slow release of the protection of seeds during seed germination, killing soil pests and soil-borne diseases, prevention of seedling diseases and systemic diseases, improve seed germination rate.

[0005] 农作物在生长过程中,除了面临虫害也会面临病害,一些病菌对植物影响反过来也会加剧植物的虫害。 [0005] During the growth of crops, in addition to facing the pest will face disease, some of the bacteria on plants in turn will exacerbate pest plants. 以往对植物的病害和虫害总是分别进行处理,这就导致了虫害和病害处理不同步,从而不能彻底的杀灭病虫害,导致反复。 Plant diseases and insect pests of the past is always processed separately, which led to the deal with pests and diseases are not synchronized, and thus can not completely kill the pests, causing repeated. 我们将氯虫苯甲酰胺和吡唑醚菌酯进行科学复配,以期达到同时杀菌杀虫的目的,从而降低植物病虫害的发生率,促进植物生长,达到增产目的的同时也可以减少农民的劳动成本。 We chlorantraniliprole and pyrazole Kresoxim scientific complex, in order to achieve simultaneous sterilization insecticide, thereby reducing the incidence of plant pests, promote plant growth, to increase production purposes while farmers can also reduce labor cost.

发明内容 SUMMARY

[0006] 本发明的目的是提供一种安全环保的杀虫杀菌组合物,实现一种药剂同时杀虫杀菌、减少污染、降低劳动成本的目的。 [0006] The object of the present invention is to provide an environmentally safe pesticidal fungicidal compositions, insecticidal realize a sterilizing agents simultaneously, reduce pollution, the purpose of reducing labor costs. 具体的涉及氯虫苯甲酰胺和吡唑醚菌酯复配的农药组合物。 Particularly relates chlorantraniliprole and Kresoxim pyrazole compound pesticidal composition.

[0007] 利用所述的农药组合物,配以本领域内技术人员公知的助剂,以本领域内技术人员公知的方法,制成本发明所涉及的悬浮种衣剂。 [0007] The use of the pesticide composition, together with well-known to those skilled in the aid to those skilled in known manner, a flowable concentrate invention costs involved.

[0008] 上述组合物中,氯虫苯甲酰胺和吡唑醚菌酯的重量比为1:50-50:1。 [0008] The composition, the weight ratio of chlorantraniliprole and pyrazole Kresoxim ratio of 1: 50-50: 1.

[0009] 氯虫苯甲酰胺和吡唑醚菌酯组合物具有以下特点:①杀菌作用强,对卵菌纲、半知菌纲、子囊菌纲等类植物病害有很强的防治效果;②杀虫作用强,对鳞翅目害虫有很好的防治效果添加了成膜剂,能够很好的在种子表面包衣两种成分无明显的交互抗性与常规剂型相比,能够延缓有效成分的释放,大大延长持效期;⑥两种成分复配,还具有增效作用。 [0009] of chlorantraniliprole and pyrazole Kresoxim composition has the following characteristics: ① strong bactericidal effect on Oomycetes, Deuteromycetes, Ascomycetes and other types of plant diseases has a strong controlling effect; ② strong insecticidal effect on lepidopteran pests have good control effect of adding a film-forming agent can be a good no significant cross-resistance with conventional dosage forms the seed surface coating compared to two components, the active ingredient can delay release, greatly extended persistence; ⑥ complex two components, also have a synergistic effect.

[0010] 不同的有效成分混合后,由于各个活性组分的组成、结构、理化性质差异,使得各个有效成分之间的联合作用通常有增效作用、加成作用以及拮抗作用。 [0010] After mixing the different active ingredients, since the composition of each active ingredient, structure, differences in physical and chemical properties, such that the combined effects of each active ingredient is usually between synergism, additivity and antagonism. 所谓增效作用就是有效成分共同产生的效果大于各个成分的效果总合;加成作用就是有效成分共同产生的效果接近各个成分效果的总合;拮抗作用就是有两种有效成分作用于机体时,一种物质干扰另一种物质的效果,导致总体效果下降。 The so-called synergistic effect of the active ingredient is greater than the effect of co-produced individual components of the aggregate; additive effect is the effect of the active ingredient together produce the sum of the individual components of the proximity effect; antagonism that has two active ingredients acting on the body, another effect of a substance interfering substances, resulting in an overall effect is reduced.

具体实施方式 Detailed ways

[0011] 为确定氯虫苯甲酰胺和吡唑醚菌酯两种有效成分复配的增效作用,申请人首先使用这两种成分进行了室内生测试验,试验方法以及结果如下: [0011] To determine the synergistic effect of chlorantraniliprole and pyrazole Kresoxim two active ingredients mixed, Applicants were the first to use these two ingredients indoor bioassay test, test methods and results were as follows:

[0012] 首先分析了两种有效成分的作用特点后,我们将生测防治的作物定为玉米,防治对象为玉米大斑病和玉米螟。 After [0012] Firstly, the effect of the characteristics of the two active ingredients, we measured the crops as corn prevention, control and object turcicum corn borer.

[0013] 室内生测的试验方法:采用生长速率法测定药剂对玉米大斑病病原菌菌丝生长的抑制作用。 [0013] Test Method bioassay: Determination of inhibitory agent on turcicum mycelial growth of maize growth rate method. 在预备试验的基础上,从各药剂对病菌菌丝生长抑制率达10%-90%范围内设计5个浓度,先将95%吡唑醚菌酯原药以甲醇为溶剂配成系列浓度的药液备用,然后将药液按1%比例加入到已融化并冷却到室温的PDA培养基中,充分摇匀后,倒入灭菌的培养皿(ΦΘΟμπι)中制成带毒平板,每处理四次重复,以加入1%的甲醇的处理为空白对照;用灭菌的打孔器(Φ5_)挑取黄瓜霜霉病菌菌饼,菌丝面朝下无菌接种于带毒平板的中央,置于25°C的恒温培养箱内培养,培养6d后采用十字交叉法测量菌落直径,计算出各药剂对病原菌的EC5tl。 On the basis of the preliminary test, each agent from the mycelial growth inhibition rate on the design concentration in the range 5 10% -90%, 95% first Kresoxim-pyrazol-methanol as solvent the original drug concentration series dubbed liquid reserve, and the liquid added in a proportion of 1% to the melted and cooled to room temperature and the PDA medium was thoroughly shaken, poured into sterilized Petri dish (ΦΘΟμπι) to prepare a poison plate per treatment was repeated four times, by the addition of 1% methanol process as blank control; with a sterile hole punch (Φ5_) picked cubensis bacteria cake, face down hyphae in infected central aseptically inoculated plates, placed in the incubator of 25 ° C incubator, the culture colony diameter measuring method using the cross 6D, each agent is calculated to EC5tl pathogens.

[0014] 采用毛细管微量点滴法测定药剂对玉米螟的抑制作用,毛细管微量点滴器容积为1.Ομί。 [0014] Determination of inhibitory agent on Corn microtiter capillary, capillary dropper micro volume 1.Ομί. 用微量点滴器将药液逐头点滴于玉米螟的背面,每一浓度处理100头左右玉米螟,处理后玉米螟放入一个养虫笼内,笼内置玉米叶供取食,另用甲醇点滴100头幼虫作为对照。 A microtiter liquid will drip on the back of the head by corn borer, each about 100 concentrations corn borer, corn borer into a post-treatment insect rearing cage, the cage built for feeding corn leaves, other drip methanol 100 as the control larvae. 经处理后的玉米螟仍放在饲养室内,48h后检查死亡率。 The treated corn borer feeding on the remains indoors, check mortality after 48h. 计算各药剂对玉米螟的EC5Q。 Calculation of each agent EC5Q corn borer.

[0015] 按照下述公式计算毒力指数,比较不同药剂的毒力及杀菌、杀虫作用。 [0015] toxicity index is calculated according to the following equation, to compare the virulence and bactericidal agents, insecticidal action. 上述生测试验所用原药以及试剂均从其他厂家购买。 The above-described bioassay experiments were purchased from other manufacturers with original drug and a reagent.

[0016] 混配制剂的联合毒力采用孙云沛的共毒系数方法表示: [0016] TOXICITY compounded formulation of toxicity coefficient using Sun Yunpei represented Method:

[0017] [0017]

混剂的实测毒力指数ATI= ~^50~ XlOO Found toxicity index mixture by ATI = ~ ^ 50 ~ XlOO

供试药剂ec5。 Sample Agent ec5.

[0018] 混剂的理论毒力指数TTI= Σ (某药的毒力指数X在混剂中该药有效成分的百分率)。 [0018] Theoretical toxicity index of mixture by TTI = Σ (Toxicity index of a drug X percentage of active ingredient in the mixture the drug agent).

[0019] [0019]

实测毒力指数ATI 湖的共毒系数CTC= XlOO Measured virulence index ATI Lake toxicity coefficient CTC = XlOO

[0020] C大于120时为增效作用,小于80时为拮抗作用,80-120时为加和作用。 When the [0020] C is a synergy of greater than 120, less than antagonistic, additive effect when 80-120 80.

[0021] 室内生测实验数据见下表: [0021] Experimental data bioassay as follows:

[0022] 表I 氯虫苯甲酰胺与吡唑醚菌酯不同配比对玉米大斑病共毒系数的测定结果[0023] [0022] The measurement results of the amine with benzoyl-pyrazol different ratio of Kresoxim corn leaf blight toxicity coefficient chlorantraniliprole Table I [0023]

Figure CN103210938AD00051

[0024] 从上述数据可以明显看出,当氯虫苯甲酰胺和吡唑醚菌酯以不同比例复配时,对玉米大斑病的防治能力都有不同比例的增效作用,配方的共毒系数(CTC)均大于120,增效作用显著。 [0024] As apparent from the above data, when chlorantraniliprole and pyrazole Kresoxim in different proportions complex, has a synergistic effect of different ratios, the total of the formulation to prevent and control corn Leaf Blight toxicity coefficient (CTC) greater than 120, a significant synergism. 其中氯虫苯甲酰胺和吡唑醚菌酯在1:1-20:1之间增效最为显著,共毒系数最小也达到140,远大于增效作用与加和作用的临界点120,可见,氯虫苯甲酰胺和吡唑醚菌酯复配后,对吡唑醚菌酯的杀菌能力有较大的提高。 Wherein chlorantraniliprole and pyrazole Kresoxim 1: 1 to 20: 1 between the most significant synergistic co-toxicity coefficient has reached the minimum 140, is much larger than synergism and additive effect of the critical point 120, the visible after chlorantraniliprole and pyrazole compound kresoxim, has greatly improved the ability of the sterilization of kresoxim-pyrazol.

[0025] 表2氯虫苯甲酰胺与吡唑醚菌酯不同配比对玉米螟共毒系数的测定结果 [0025] Measurement results of Table 2 chlorantraniliprole and different ratio Kresoxim-pyrazol-Co-toxicity coefficients of the corn borer

[0026] [0026]

Figure CN103210938AD00052

[0027] 从上述数据可以明显中看出,当氯虫苯甲酰胺和吡唑醚菌酯复配后,氯虫苯甲酰胺的杀虫活性有显著的提高,其中氯虫苯甲酰胺和吡唑醚菌酯配比在1:10-10:1之间增效作用最为显著,共毒系数最小也达到150,远大于增效作用与加和作用的临界点120,可见,氯虫苯甲酰胺和吡唑醚菌酯复配后,对氯虫苯甲酰胺的杀虫能力有较大的提高。 [0027] can be clearly seen from the above data, when chlorantraniliprole and pyrazole compound kresoxim, chlorantraniliprole insecticidal activity have improved significantly, and wherein chlorantraniliprole pyrazol Kresoxim yl ratio of 1: 10-10: 1 between the most significant synergism, minimum coefficient of co-toxicity has reached 150, much greater than the critical point synergism additive effect of 120, visible, chlorantraniliprole benzyloxy and the pyrazole amide compound kresoxim of chlorantraniliprole pesticidal ability is greatly improved. [0028] 通过室内生测试验确定氯虫苯甲酰胺和吡唑醚菌酯两种有效成分复配能够有很好的增效作用,以下通过具体实例用以进一步详细说明本发明,但本发明绝非仅仅限于以下这些实施例。 [0028] determined by a bioassay test chamber chlorantraniliprole and two kinds of esters of an active ingredient kresoxim pyrazole compound to have good synergy, the following specific examples are provided by the present invention in further detail, but the present invention is these by no means limited to the following embodiments. 配方中百分比均为重量百分比,所使用的原药及助剂均为其他厂家购买。 Formulation percentages are by weight, the original drug and additives other manufacturers are used later.

[0029] 配方实例如下: [0029] Formulation examples are as follows:

[0030] 实例一、25.5%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0030] Examples of a, chlorantraniliprole 25.5%. Kresoxim-pyrazol suspension Seed

[0031] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、 [0031] The formulation requirements, water as a medium, the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes,

消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 Defoaming agents added to the kettle stir, transferred into a sand mill grinding, to obtain flowable concentrate.

[0032] [0032]

氯虫苯甲酰胺 0.5% Chlorantraniliprole 0.5%

吡唑醚菌酯 25% Pyrazole Kresoxim 25%

乙二醇 5% Ethylene glycol 5%

十二烷基磺酸钠 b% B% sodium dodecyl sulfate

木质素磺酸钠 10% 羧甲基纤维素 0.8% Sodium lignosulfonate 10% carboxymethylcellulose 0.8%

聚乙烯醇 2% 2% polyvinyl alcohol

永固红 2% Permanent Red 2%

硅酸镁铝 0.5% Magnesium aluminum silicate 0.5%

消泡剂 0.1% Defoamers 0.1%

水 补足100% Water to make up 100%

[0033] 实例二、51%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0033] Example II 51% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0034] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、 [0034] The formulation requirements, water as a medium, the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes,

消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 Defoaming agents added to the kettle stir, transferred into a sand mill grinding, to obtain flowable concentrate.

[0035] [0035]

氯虫苯甲酰胺 ^0/ Chlorantraniliprole ^ 0 /

吡唑醚菌酯 1% Kresoxim-pyrazol-1%

乙二醇 5% Ethylene glycol 5%

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 OS/ Carboxymethylcellulose OS /

聚乙烯醇 2% 2% polyvinyl alcohol

[0036]永固红 Th [0036] Permanent Red Th

硅酸镁铝 0.5% 消泡剂 0.1% Magnesium aluminum silicate 0.5% to 0.1% antifoaming agent

水 补足100% Water to make up 100%

[0037] 实例三、20%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0037] Example III 20% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0038] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、 [0038] The formulation requirements, water as a medium, the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes,

消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 Defoaming agents added to the kettle stir, transferred into a sand mill grinding, to obtain flowable concentrate.

[0039] [0039]

氯虫苯甲酰胺 10% Chlorantraniliprole 10%

吡唑醚菌酯 川/ Kresoxim-pyrazol-Chuan /

乙二醇 b% B% ethylene glycol

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 0.8% 0.8% carboxymethyl cellulose

聚乙烯醇 2% 2% polyvinyl alcohol

永固红 2% Permanent Red 2%

硅酸镁铝 0.5% Magnesium aluminum silicate 0.5%

消泡剂 0.1% Defoamers 0.1%

水 补足100% Water to make up 100%

[0040] 实例四、12%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0040] Example IV 12% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0041] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、 [0041] The formulation requirements, water as a medium, the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes,

消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 Defoaming agents added to the kettle stir, transferred into a sand mill grinding, to obtain flowable concentrate.

[0042]氯虫苯甲酰胺 2% [0042] 2% chlorantraniliprole

吡唑醚菌酯 10% Pyrazole Kresoxim 10%

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

乙二醇 5% Ethylene glycol 5%

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 0.8% 0.8% carboxymethyl cellulose

聚乙烯醇 2% 2% polyvinyl alcohol

永固红 2% Permanent Red 2%

娃酸镁招 0.5% 0.5% magnesium baby trick

消泡剂 OI/ Defoamers OI /

[0043] [0043]

水 补足100% Water to make up 100%

[0044] 实例五、25%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0044] Examples of five, 25% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0045] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、 [0045] The formulation requirements, water as a medium, the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes,

消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 Defoaming agents added to the kettle stir, transferred into a sand mill grinding, to obtain flowable concentrate.

[0046] [0046]

氯虫苯甲酰胺 15¾ Chlorantraniliprole 15¾

吡唑醚菌酯 10% Pyrazole Kresoxim 10%

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

乙二醇 5% Ethylene glycol 5%

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 O 8% 聚乙烯醇 2% Carboxymethyl cellulose, polyvinyl alcohol O 8% 2%

永固红 2% Permanent Red 2%

硅酸镁铝 0.5% Magnesium aluminum silicate 0.5%

消泡剂 0.1% Defoamers 0.1%

水 补足100% Water to make up 100%

[0047] 实例六、21%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0047] Example VI 21% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0048] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 [0048] The formulation requirements, water as a medium, stir the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes, antifoaming agents added to the kettle and the like, transferred into a sand mill grinding prepared suspension Seed.

[0049]氯虫苯甲酰胺 1% [0049] 1% chlorantraniliprole

吡唑醚菌酯 20% Pyrazole Kresoxim 20%

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

乙二醇 5% Ethylene glycol 5%

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 0.8% 0.8% carboxymethyl cellulose

聚乙烯醇 2% 2% polyvinyl alcohol

永固红 2% Permanent Red 2%

硅酸镁铝 0.5% Magnesium aluminum silicate 0.5%

消泡剂 0.1% Defoamers 0.1%

水 补足100% Water to make up 100%

[0050] 实例七、10.5%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0050] Example VII, 10.5% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0051] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、 消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 [0051] The formulation requirements, water as a medium, stir the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes, antifoaming agents added to the kettle and the like, transferred into a sand mill grinding prepared suspension Seed.

[0052] [0052]

氯虫苯甲酰胺 10% Chlorantraniliprole 10%

吡唑醚菌酯 0.5% Pyrazole Kresoxim 0.5%

乙二醇 5% Ethylene glycol 5%

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 0.8% 0.8% carboxymethyl cellulose

聚乙烯醇 2% 2% polyvinyl alcohol

永固红 2% Permanent Red 2%

硅酸镁铝 0.5% Magnesium aluminum silicate 0.5%

消泡剂 0.1% Defoamers 0.1%

水 补足100% Water to make up 100%

[0053] 实例八、24%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0053] Example VIII 24% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0054] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、 [0054] The formulation requirements, water as a medium, the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes,

消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 Defoaming agents added to the kettle stir, transferred into a sand mill grinding, to obtain flowable concentrate.

[0055]氯虫苯甲酰胺 2% [0055] 2% chlorantraniliprole

吡唑醚菌酯 m Pyrazole Kresoxim m

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

乙二醇 5% Ethylene glycol 5%

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 0.8% 0.8% carboxymethyl cellulose

聚乙烯醇 2% 2% polyvinyl alcohol

永固红 2% Permanent Red 2%

硅酸镁铝 0.5% Magnesium aluminum silicate 0.5%

消泡剂 0.1% Defoamers 0.1%

水 补足100% Water to make up 100%

[0056] 实例九、33%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂 [0056] Example IX 33% chlorantraniliprole pyrazole Kresoxim suspension Seed

[0057] 根据配方要求,以水为介质,将有效成分、润湿剂、分散剂、增稠剂、成膜剂、染料、消泡剂等加入釜中搅拌均匀,转移到砂磨机中研磨,制得悬浮种衣剂。 [0057] The formulation requirements, water as a medium, stir the active ingredient, wetting agents, dispersants, thickeners, film formers, dyes, antifoaming agents added to the kettle and the like, transferred into a sand mill grinding prepared suspension Seed.

[0058] [0058]

氯虫苯甲酰胺 30% Chlorantraniliprole 30%

吡唑醚菌酯 3% Kresoxim-pyrazol-3%

[0059] [0059]

乙二醇 5% Ethylene glycol 5%

十二烷基磺酸钠 6% 6% sodium dodecyl sulfate

木质素磺酸钠 10% Sodium lignosulfonate 10%

羧甲基纤维素 0.8% 0.8% carboxymethyl cellulose

聚乙烯醇 2% 2% polyvinyl alcohol

永固红 2% Permanent Red 2%

硅酸镁铝 0.5% Magnesium aluminum silicate 0.5%

消泡剂 0.1% Defoamers 0.1%

水 补足100% Water to make up 100%

[0060] 选择以上实例进行玉米拌种的田间试验,考察复配制剂防治玉米大斑病和玉米螟的效果,同时考察复配制剂拌种后对玉米种子发芽率的影响,确定配方对玉米种子的保护作用,同时通过与氯虫苯甲酰胺悬浮种衣剂单剂、吡唑醚菌酯悬浮种衣剂单剂的效果对比,验证复配后对种子的保护以及增效效果。 [0060] Examples of the above selection field trials of corn seed dressing investigated the effect of compound formulation prevention corn leaf blight and corn borer, also studied effects on seed germination rate after multiplexing dressing formulation, the formulation is determined on Seed protection, while chlorantraniliprole by a single dose of a flowable concentrate, a suspension pyrazole kresoxim seed single dose effect of contrast, the protection of the seed and the synergistic effect of the compound verified. 具体试验方法数据如下: Test Method Specific data are as follows:

[0061] 实验:20%氯虫苯甲酰胺.吡唑醚菌酯悬浮种衣剂以及其它制剂做田间玉米拌种的药效试验。 [0061] Experiment: 20% chlorantraniliprole pyrazol Kresoxim flowable concentrate formulation as well as other field efficacy trials do corn seed dressing. 试验地点为山东寿光,时间为2011年5月5日,试验共五个处理,每个处理三个重复,小区随机排列,将药与玉米种子均匀搅拌后播种,所有小区的种植习惯均与当地的种植习惯相同。 Shandong Shouguang test site, time is May 5, 2011, a total of five experimental treatments with three replicates, residential random arrangement, the uniform mixing drugs and maize seeds are sown later, all cells were planted with local habits planting the same habit.

[0062] 发芽率调查方法为:统计播种的种子以及发芽的种子数量。 [0062] germination rate for the survey methodology: Statistical sowing the seeds and the number of seed germination.

[0063] 玉米大斑病调查方法为:每个小区对角线定两点,每点直线前进定25丛,调查各小区病指,计算防效,并进行邓肯氏新复极差分析。 [0063] Investigation turcicum corn method: for each given cell diagonal two points, each point of the line set 25 proceeds plexus, each cell disease investigation means for calculating the control effect, and Duncan multiple range analysis.

[0064] 病情指数的分级标准: [0064] The disease index grading standards:

[0065] O级:无病斑; [0065] O: no lesion;

[0066] I级:病斑面积占整个叶面积的5%以下; [0066] Class I: lesion area is 5% or less of the entire leaf area;

[0067] 3级:病斑面积占整个叶面积的6%〜10% ; [0067] Level 3: lesion area 6% ~ 10% of the total leaf area;

[0068] 5级:病斑面积占整个叶面积的11%〜25% ; [0068] 5: lesion area is 11% ~ 25% of the total leaf area;

[0069] 7级:病斑面积占整个叶面积的26%〜50% ; [0069] 7: lesion area is 26% ~ 50% of the total leaf area;

[0070] 9级:病斑面积占整个叶面积的51%以上。 [0070] 9: lesion area of ​​more than 51% of the entire leaf area.

[0071] [0071]

Figure CN103210938AD00111

[0073] 玉米螟调查标准为:各小区采用平行取样法取样150丛,调查枯心数,最后计算枯心率和保苗效果。 [0073] Investigation corn borer criteria: each cell using parallel sampling sampling bundle 150, the number of dead heart investigations, and finally calculates the heart rate and seedling blight effects.

[0074] 表3 20%氯虫苯甲酰胺•卩比唑醚菌酯悬浮种衣剂及不同药剂对玉米拌种试验结果 [0074] Table 3 20% • chlorantraniliprole Jie-pyrazol kresoxim suspension Seed dressing maize and different agents on test results

[0075] [0075]

Figure CN103210938AD00121

[0076] 注:表中数据为3次重复的平均值,字母相同为Duncan测试差异不显著时间:2011年5月地点;山东寿光 [0076] Note: The data in the table is the average of 3 repetitions, the same letter not significantly different Duncan test time: 2011 location; Shouguang

[0077] 从上述数据可以看出,在使用复配制剂进行玉米拌种后,玉米种子的发芽率都超过了88%,明显高于氯虫苯甲酰胺和吡唑醚菌酯单剂。 [0077] As can be seen from the above data, the use of the compound in corn seed dressing formulation, the germination rate of more than 88%, significantly higher than chlorantraniliprole and pyrazole Kresoxim single dose. 复配制剂对玉米大斑病的防效均超过70%,明显高于吡唑醚菌酯单剂,对玉米螟的保苗效果超过80%,明显高于氯虫苯甲酰胺单剂,同时将两种有效成分复配,能够使复配制剂同时兼具杀虫和杀菌的能力,弥补了单剂的缺点,减少了农民的施药成本,延长持效期,提高药效,具有很高的经济效益。 Mixture control effect corn Leaf Blight more than 70%, significantly higher than the pyrazole Kresoxim single dose, seedling corn borer effect more than 80%, significantly higher than chlorantraniliprole single dose, at the same time two active ingredient compound, can be made both at the same time the ability to complex the formulation of insecticidal and fungicidal, to make up for the shortcomings of single-agent administration reduces the farmer's costs, extend the persistence, improved efficacy, with high economic benefits.

Claims (2)

1.一种农药组合物,其特征在于:所述活性成分由氯虫苯甲酰胺和吡唑醚菌酯构成,所述氯虫苯甲酰胺和吡唑醚菌酯的重量比为1:50〜50:1。 1. A pesticidal composition, characterized in that: said active ingredient consists of chlorantraniliprole and kresoxim-pyrazol, the weight ratio of chlorantraniliprole and pyrazole Kresoxim is 1:50 ~ 50: 1.
2.根据权利要求1所述的农药组合物,其特征在于:由有效成分和辅料制成悬浮种衣剂。 2. The pesticidal composition according to claim 1, wherein: the active ingredient and excipients is made flowable concentrate.
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CN104206398A (en) * 2014-08-15 2014-12-17 成都蜀农昊农业有限公司 Pesticide safe to higher animals and non-target organisms
CN104304252A (en) * 2014-09-15 2015-01-28 浙江泰达作物科技有限公司 Pesticide composition containing picoxystrobin and ryanodine receptor and its preparation and use
CN104396974A (en) * 2014-11-18 2015-03-11 安徽省农业科学院植物保护与农产品质量安全研究所 Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition
CN105794781A (en) * 2016-03-31 2016-07-27 太仓市东泾农场专业合作社 Antibacterial compound containing benzamide fungicide and coumoxystrobin
CN105994347A (en) * 2016-05-26 2016-10-12 洛阳市嘉创农业开发有限公司 Suspension seed-coating agent containing cyantraniliprole, silthiopham and pyraclostrobin

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104206398A (en) * 2014-08-15 2014-12-17 成都蜀农昊农业有限公司 Pesticide safe to higher animals and non-target organisms
CN104304252A (en) * 2014-09-15 2015-01-28 浙江泰达作物科技有限公司 Pesticide composition containing picoxystrobin and ryanodine receptor and its preparation and use
CN104396974A (en) * 2014-11-18 2015-03-11 安徽省农业科学院植物保护与农产品质量安全研究所 Pesticide composition containing thifluzamide and chlorantraniliprole as well as application of pesticide composition
CN105794781A (en) * 2016-03-31 2016-07-27 太仓市东泾农场专业合作社 Antibacterial compound containing benzamide fungicide and coumoxystrobin
CN105994347A (en) * 2016-05-26 2016-10-12 洛阳市嘉创农业开发有限公司 Suspension seed-coating agent containing cyantraniliprole, silthiopham and pyraclostrobin

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