CN106259417A - Suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin - Google Patents

Suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin Download PDF

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Publication number
CN106259417A
CN106259417A CN201610655777.0A CN201610655777A CN106259417A CN 106259417 A CN106259417 A CN 106259417A CN 201610655777 A CN201610655777 A CN 201610655777A CN 106259417 A CN106259417 A CN 106259417A
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CN
China
Prior art keywords
silthiopham
pyraclostrobin
ethiprole
seed
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610655777.0A
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Chinese (zh)
Inventor
孙琼珂
李蓓
刘天辉
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Luoyang Mingli Science and Technology Development Co Ltd
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Luoyang Mingli Science and Technology Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Luoyang Mingli Science and Technology Development Co Ltd filed Critical Luoyang Mingli Science and Technology Development Co Ltd
Priority to CN201610655777.0A priority Critical patent/CN106259417A/en
Publication of CN106259417A publication Critical patent/CN106259417A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Toxicology (AREA)
  • Soil Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention relates to a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin, including ethiprole 1 8%, pyraclostrobin 12 20%, Silthiopham 5 15%, defoamer 0.2 2%, film former 5 10%, thickening agent 2 4%, stabilizer 3 9%, dispersant 2 6%, emulsifying agent 6 9%, preservative 3 4%, remaining is water.The seed coat agent of the present invention has the effect of pesticide-germicide, can improve the germination percentage of seed, it is ensured that seedling stage, crop was not endangered by pest and disease damage, and can reduce dosing, and parasitosis is double to be controlled, and reduces cost, and non-environmental-pollution.

Description

Suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin
Technical field
The present invention relates to pesticide field, especially relate to a kind of seed coat agent, particularly a kind of containing ethiprole, Silthiopham Suspension seed-coating agent with pyraclostrobin.
Background technology
Fipronil insecticidal spectrum is wide, have tag, stomach toxicity and moderate systemic action.Subterranean pest-insect can be prevented and treated, can prevent and treat again Insect on the ground.Can be not only used for stem and leaf to process and soil treatment, can be used for again seed treatment.The main controlling object of ethiprole includes The insects such as aphid, leafhopper, lepidopterous larvae, flies and coleoptera.It is recommended as replacing high-toxic organic phosphorus by numerous pesticide experts One of first-selected kind of pesticide.
Pyraclostrobin is a kind of wide-spectrum bactericide, can suppress the growth of fungal mycelium, ultimately results in pathogenic bacteria dead, right Multiple fungal disease is respectively provided with prevention and therapeutic effect well, its former medicine low toxicity, and effect is rapid, lasting medicine, it is recommended that agent To crop safety under amount, and the resistance against diseases that plant performance is potential can be induced to a certain extent.
Silthiopham chemical name N-pi-allyl-4,5-dimethyl-2-(TMS) thiophene-3-Methanamide, tool Having good protection activity, the lasting period is long.Mainly make seed treatment, dress seed strong inhibition Oryza sativa L. full rot.
In modern agricultural production, utilizing seed coat agent that seed carries out chemicals treatment is to prevent subterranean pest-insect and crops soil Pass, one of the method for economical and convenient of seed-borne disease.Seed coat agent is a kind of to process for crop or other plant seed, have The pesticidal preparations of film forming characteristics, it can solidify to form at the surface of the seed and referred to as plant the film of clothing.Seed coat agent absorbs water swollen in soil Swollen and be not dissolved, it is allowed to seed normally germinates required moisture and air passes through, and the material such as contained pesticide and seed manure is slow Release, it is possible to kill subterranean pest-insect, insect in seedling stage, has preventing and treating sprout term disease and systematicness disease, improves percentage of seedgermination, rush Enter the effects such as seedling healthy growth.
Summary of the invention
It is an object of the invention to provide a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin, By this seed coat agent, seed is coated process, there is the effect of pesticide-germicide, the germination percentage of seed can be improved, it is ensured that seedling stage is made Thing is not endangered by pest and disease damage, and can reduce dosing, and parasitosis is double to be controlled, and reduces cost, and non-environmental-pollution.
The object of the invention to solve the technical problems realizes by the following technical solutions.
A kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin proposed according to the present invention, wherein, Including ethiprole, pyraclostrobin, Silthiopham, defoamer, film former, thickening agent, stabilizer, dispersant, emulsifying agent, anticorrosion Agent and water.
The object of the invention to solve the technical problems also can be applied to the following technical measures to achieve further.
Aforesaid a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin, wherein, the weight of each composition Amount content is: ethiprole 1-8%, pyraclostrobin 12-20%, Silthiopham 5-15%, defoamer 0.2-2%, film former 5- 10%, thickening agent 2-4%, stabilizer 3-9%, dispersant 2-6%, emulsifying agent 6-9%, preservative 3-4%, remaining is water.
Aforesaid a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin, wherein, the weight of each composition Amount content is: ethiprole 2%, pyraclostrobin 20%, Silthiopham 10%, defoamer 2%, film former 7%, thickening agent 3%, Stabilizer 4%, dispersant 4%, emulsifying agent 6%, preservative 4%, water 38%.
Aforesaid a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin, wherein, described defoamer For polydimethylsiloxane.
Aforesaid a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin, wherein, described film former For acrylic acid-acrylic acid butyl ester-styrol copolymer.
The preparation method of aforesaid a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin is: will Described each composition mixes, and stirs, then puts in grinder and be ground, and the mean diameter being milled to material is less than 5um, grinds Time consuming for 4-8h, ground after, filter.
The present invention compared with prior art has clear advantage and beneficial effect, by technique scheme, the present invention A kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin can reach suitable technological progress and practicality Property, and there is the extensive value in industry, it at least has the advantage that
(1) present invention is by pyraclostrobin, ethiprole and Silthiopham ternary built, has significant Synergistic and makees With, and preparation method is easy, effect is notable, slow down the drug-fast generation of pest and disease damage, extends the service life of pesticide, simplifies Agricultural production process.
(2) the seed coat agent good film-forming property of the present invention, it is possible to stable preservation and use, drug effect is notable, decreases making of pesticide Consumption, cost-effective, reduce investment, reduce the pollution to environment and harm.
In sum, a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin of the present invention is in technology On have significantly progressive, and there is obvious good effect, be really a new and innovative, progressive, practical new design.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of description, and in order to allow the above and other objects, features and advantages of the present invention can Become apparent, below especially exemplified by preferred embodiment, describe in detail as follows.
Accompanying drawing explanation
Nothing
Detailed description of the invention
By further illustrating the technological means and effect that the present invention taked by reaching predetermined goal of the invention, below in conjunction with Preferred embodiment, to a kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin proposed according to the present invention, Its detailed description of the invention, structure, feature and effect thereof, after describing in detail such as.
A kind of suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin, by following component according to weight hundred Proportion by subtraction forms: ethiprole 1-8%, pyraclostrobin 12-20%, Silthiopham 5-15%, defoamer 0.2-2%, film former 5- 10%, thickening agent 2-4%, stabilizer 3-9%, dispersant 2-6%, emulsifying agent 6-9%, preservative 3-4%, remaining is water.
It is preferred that the consisting of of this suspension seed-coating agent: ethiprole 2%, pyraclostrobin 20%, Silthiopham 10%, disappear Infusion 2%, film former 7%, thickening agent 3%, stabilizer 4%, dispersant 4%, emulsifying agent 6%, preservative 4%, water 38%.
Described defoamer is used for preventing from producing a large amount of bubble when using, and defoamer can be selected for polydimethylsiloxane.
Described thickening agent is for improving the viscosity of suspension, thus reduces the sedimentation velocity of particle, improves the steady of suspension Qualitative, thickening agent can use xanthan gum.Xanthan gum is the one of thickening agent, and film forming has aqueous, breathability.
Described film former can make active component concentrate on the surface of the seed, reduces pesticide diffusion in the environment, thus reduces Infringement to environment, described film former can be selected for acrylic acid-acrylic acid butyl ester-styrol copolymer.
The preparation method of above-mentioned seed coat agent is: is mixed by the above each composition, stirs, then put in grinder Being ground, milling time is 4-8h, is milled to the mean diameter of material less than 5um, filtration, collection filtrate.
The ethiprole pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 1:21%
Each constituent content is: ethiprole 1%, pyraclostrobin 15%, Silthiopham 5%, defoamer 0.2%, film former 8%, thickening agent 3%, stabilizer 5%, dispersant 6%, emulsifying agent 8%, preservative 3%, water 45.8%.
Grinding 6h after being mixed by above composition, mean diameter is less than 5um.
The ethiprole pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 2:25%
Each constituent content is: ethiprole 5%, pyraclostrobin 12%, Silthiopham 8%, defoamer 1%, film former 10%, thickening agent 4%, stabilizer 9%, dispersant 2%, emulsifying agent 9%, preservative 4%, water 36%.
Grinding 6h after being mixed by above composition, mean diameter is less than 5um.
The ethiprole pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 3:32%
Each constituent content is: ethiprole 2%, pyraclostrobin 20%, Silthiopham 10%, defoamer 2%, film former 7%, thickening agent 3%, stabilizer 4%, dispersant 4%, emulsifying agent 6%, preservative 4%, water 38%.
Grinding 6h after being mixed by above composition, mean diameter is less than 5um.
The ethiprole pyraclostrobin Silthiopham suspension seed-coating agent of embodiment 4:35%
Each constituent content is: ethiprole 8%, pyraclostrobin 12%, Silthiopham 15%, defoamer 1%, film former 5%, thickening agent 2%, stabilizer 3%, dispersant 3%, emulsifying agent 6%, preservative 3%, water 42%.
Grinding 6h after being mixed by above composition, mean diameter is less than 5um.
Above-described embodiment products obtained therefrom carries out indoor germination rate and germinating energy detection and field efficacy investigation, and step is such as Under:
(1) first, dressing seed seed, selected full seed, each processes according to pesticide-seeds ratio is 1:60, after weighing up Put in culture dish, close the lid, fully shake, make seed pelleting uniform, dry.
(2) indoor germination rate and germinating energy investigation, process every time and choose 100 full seeds, test in indoor.
(3) field efficacy investigation, choosing Oryza sativa L. is experimental subject, investigates vermins-proof effect.
Result is as follows:
The seed coat agent of table 1. heterogeneity is on Oryza sativa L. germination percentage and the impact of germinating energy
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Blank
Germination percentage (%) 96 95 98 94 86
Germinating energy (%) 95 91 94 93 88
As it can be seen from table 1 after the seed coat agent of the present invention is to seed pelleting, its germination percentage and germinating energy are all had certain Facilitation.
Through field test it has been observed that prevention effect highly significant to rice pest, its insect protected protection effect up to More than 95%, effectively inhibit the generation of rice pest.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, though So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people being familiar with this specialty Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or modification For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention Any simple modification, equivalent variations and the modification being made above example, all still falls within the range of technical solution of the present invention.

Claims (5)

1. one kind containing ethiprole, Silthiopham and the suspension seed-coating agent of pyraclostrobin, it is characterised in that it include ethiprole, Pyraclostrobin, Silthiopham, defoamer, film former, thickening agent, stabilizer, dispersant, emulsifying agent, preservative and water.
2. suspension seed-coating agent as claimed in claim 1, it is characterised in that the weight content of each composition is: ethiprole 1-8%, pyrrole Azoles kresoxim-methyl 12-20%, Silthiopham 5-15%, defoamer 0.2-2%, film former 5-10%, thickening agent 2-4%, stabilizer 3-9%, dispersant 2-6%, emulsifying agent 6-9%, preservative 3-4%, remaining is water.
3. suspension seed-coating agent as claimed in claim 1, it is characterised in that the weight content of each composition is: ethiprole 2%, pyrazoles Kresoxim-methyl 20%, Silthiopham 10%, defoamer 2%, film former 7%, thickening agent 3%, stabilizer 4%, dispersant 4%, breast Agent 6%, preservative 4%, water 38%.
4. suspension seed-coating agent as claimed in claim 1, it is characterised in that described defoamer is polydimethylsiloxane.
5. suspension seed-coating agent as claimed in claim 1, it is characterised in that described film former is acrylic acid-acrylic acid butyl ester-benzene Ethylene copolymer.
CN201610655777.0A 2016-08-11 2016-08-11 Suspension seed-coating agent containing ethiprole, Silthiopham and pyraclostrobin Pending CN106259417A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108157359A (en) * 2017-12-26 2018-06-15 洛阳神佳窑业有限公司 Suspension seed-coating agent containing ethiprole, Silthiopham and imidacloprid

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1893826A (en) * 2003-12-18 2007-01-10 巴斯福股份公司 Fungicidal mixtures based on carbamate derivatives and insecticides
CN102300456A (en) * 2009-01-27 2011-12-28 巴斯夫欧洲公司 Method for dressing seeds

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1893826A (en) * 2003-12-18 2007-01-10 巴斯福股份公司 Fungicidal mixtures based on carbamate derivatives and insecticides
CN102300456A (en) * 2009-01-27 2011-12-28 巴斯夫欧洲公司 Method for dressing seeds

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
刘步林主编: "《农药剂型加工技术(第二版)》", 31 October 1998 *
张漫漫等: "AMPS/St/BA三元共聚水稻种衣剂用成膜剂的合成", 《化学与黏合》 *
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108157359A (en) * 2017-12-26 2018-06-15 洛阳神佳窑业有限公司 Suspension seed-coating agent containing ethiprole, Silthiopham and imidacloprid

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Application publication date: 20170104