CN107006482A - A kind of composition of containing fluazinam, pyridaben - Google Patents
A kind of composition of containing fluazinam, pyridaben Download PDFInfo
- Publication number
- CN107006482A CN107006482A CN201710244409.1A CN201710244409A CN107006482A CN 107006482 A CN107006482 A CN 107006482A CN 201710244409 A CN201710244409 A CN 201710244409A CN 107006482 A CN107006482 A CN 107006482A
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- Prior art keywords
- fluazinam
- pyridaben
- composition
- composition according
- weight
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
Abstract
The invention discloses a kind of containing fluazinam, the composition of pyridaben, said composition active ingredient is made up of fluazinam, pyridaben, and composition also includes auxiliary element.Fluazinam, pyridaben part by weight are 60:1~1:60, mite class, the disease that fluazinam, pyridaben combine to crops of causing harm within the specific limits have notable synergistic function, hence it is evident that the single using effect of lifting.The present invention is used to prevent and treat crops evil mite and germ, includes red spider, Tetranychus urticae and gray mold, late blight.
Description
Technical field
The present invention relates to composition pesticide and its application technology, specifically active ingredient is fluazinam, pyridaben group
Close, the preventing and treating for agricultural pest.
Background technology
Fluazinam (fluazinam), chemical name：The chloro- N- of 3- (the chloro- 5- trifluoromethyls -2- pyridine radicals of 3-)-α, α, α-three
Fluoro- 2,6- dinitros-ρ-toluidines, 2,6- dinitroanilines are a kind of protective fungicides, can prevented and treated by grey Portugal
Disease caused by grape born of the same parents, to interlink spore genus, Botrytis, Phytophthora, Plasmopara, Sclerotinia and black cultivate Pseudomonas bacterium and has very much
Effect.Find that fluazinam has certain absorbability study simultaneously in, and miticidal effect is also preferable.Fluazinam acaricidal action document
CN105010370A, CN104222125A are disclosed.
Pyridaben (pyridaben) chemical name：2- tertiary butyls-5- ((the H)-pyridazines of 4- tertiary butyl benzylthios-4- chloro- 3-
3- ketone, belongs to pyridazinone compound, action of contace poison, for preventing and treating a variety of food vegetalitas evil mites.It is to the whole growth period of mite
Ovum, young mite, deutonymph and there is good effect into mite.
It is one of agricultural production important step that information system of crop pest distribution in China, which is administered, is always the weight of agricultural science and technology worker concern
Point problem.With the continuity year in year out, the increase of Pesticide use amount and non-science that prevent and treat harmful organism chemicals
Using the influence of the factors such as agricultural chemicals, cause pest and disease damage resistance increasingly serious, produce the insect of resistance, germ species and be on the increase.
Simultaneously as the use agricultural chemicals of high intensity, causes a series of social concerns such as exceeded, the pollution environment of Practice for Pesticide Residue in Agricultural Products, no
Beneficial to the sustainable development of agricultural.
For expand fluazinam, pyridaben new application, strengthen using effect, prevent it is long-term, largely use above-mentioned single medicine
Agent and cause target life to survey resistance generation, the present inventor furthers investigate to fluazinam and pyridaben, two kinds of medicines of discovery
Agent mixture in the range of certain proportion has notable synergistic effect, expands preventing and treating spectrum, while being also beneficial to reduce the use of medicament
Amount, reduces spray number of times, delays the generation of target resistance.After further study, the present invention is completed.
The content of the invention
The present invention provides one kind by fluazinam, pyridaben binary composition, and there is said composition significant Synergistic to make
With expansion preventing and treating spectrum.
Another object of the present invention is to improve fluazinam, pyridaben using effect, expand new application, improve using effect
Really, consumption is reduced, residual quantity of the agricultural chemicals on crops is reduced, delays target disease, the generation of worm resistance.
It is a feature of the present invention that：Composition active ingredient is combined by fluazinam, pyridaben, fluazinam, the weight of pyridaben
Amount is than being 60:1~1:60, preferably 30:1~1:30, further preferred 10:1~1:10, most preferably 1:4.
It is a feature of the present invention that：Active ingredient account for composition total weight preferably 5~50%, further preferred 10~
40%, most preferably 30%, remaining is auxiliary agent.
It is a feature of the present invention that：For preventing and treating crops evil mite and germ, red spider, Tetranychus urticae and grey mold are included
Disease, late blight.
Described auxiliary component is solvent, emulsifying agent, wetting agent, dispersant, stabilizer, antifreezing agent, thickener, disintegration
One or more combination in agent, binding agent, defoamer, bleeding agent, synergist, fire retardant and filler, above material is agriculture
The known substance commonly used in medicine preparation.
The different formulations of pesticide can be prepared into according to existing formulation technology, formulation technology has no special limit
It is fixed.
Composition pesticide of the present invention can be prepared into any one formulation used in suitable agricultural production with known method,
Relatively good formulation has suspending agent.
The frequency of administration and application process of the present composition change with crops, insect, weather condition and have small quantitative change
Change, the purpose effectively prevented and treated can be reached by using appropriate adjustment.
Compared with prior art, the advantage of the invention is that：
1st, fluazinam, pyridaben combination synergistic function, improve using effect, while expanding preventing and treating spectrum, expand new use
On the way.
2nd, fluazinam, the pyridaben mechanism of action are different, and being used in mixed way can delay target resistance to produce, and extend making for compound
Use the life-span.
3rd, compound usage amount is reduced, the pollution to environment is alleviated, reduces use cost.
Embodiment
Essence for a better understanding of the present invention, is described further with reference to embodiment to present disclosure,
But limitation of the present invention can not be considered as.
The fluazinam of embodiment 1, pyridaben itself and combine to citrus red mite indoor biological toxicity test
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1154.7-2006》, using drop method.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
As it can be seen from table 1 fluazinam, pyridaben have greater activity, fluazinam, pyridaben combination to citrus red mite
Ratio 60:1~1:60 co-toxicity coefficients (CTC) are all higher than 120, show synergistic function, especially ratio 1:4 coefficient of synergism
Highest.
The indoor joint toxicity measuring of the fluazinam of table 1, pyridaben and combinations thereof to citrus red mite
The fluazinam of embodiment 2, pyridaben itself and combine to apple Tetranychus urticae indoor biological toxicity test.
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1154.7-2006》, using drop method.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
From table 2 it can be seen that fluazinam, pyridaben have greater activity, fluazinam, pyridaben group to apple Tetranychus urticae
Composition and division in a proportion example 60:1~1:60 co-toxicity coefficients (CTC) are all higher than 120, show synergistic function, especially ratio 1:4 synergy systems
Number highest.
The indoor joint toxicity measuring of the fluazinam of table 2, pyridaben and combinations thereof to apple Tetranychus urticae
The fluazinam of embodiment 3, pyridaben itself and combine to Botrytis cinerea indoor biological toxicity test.
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.6-2006》, using Plating.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
From table 3 it can be seen that fluazinam, pyridaben have greater activity, fluazinam, pyridaben combination ratio to ash arrhizus bacteria
Example 60:1~1:60 co-toxicity coefficients (CTC) are all higher than 120, show synergistic function, especially ratio 1:4 coefficient of synergism are most
It is high.
The fluazinam of embodiment 4, pyridaben itself and combine to Phytophthora infestans germ indoor biological toxicity test.
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1156.6-2006》, using Plating.
Statistical analysis is carried out with DPS statistical analysis softwares, the EC of each medicament is calculated50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
From table 4, it can be seen that fluazinam, pyridaben have greater activity, fluazinam, pyridaben group to Phytophthora infestans germ
Composition and division in a proportion example 60:1~1:60 co-toxicity coefficients (CTC) are all higher than 120, show synergistic function, especially ratio 1:4 synergy systems
Number highest.
Active ingredient uses fluazinam active compound, pyridaben active compound in following examples, and each component percentage composition is folding
Hundred contents.
The fluazinam Damanling suspension agent of embodiment 5 and its application.
Fluazinam 1~60%；
Pyridaben 1~60%；
Auxiliary agent complements to 100%.
Fluazinam 5%, pyridaben 20%, sodium alkyl sulfonate 5%, polyethylene glycol stearate 5%, Magnesiumaluminumsilicate 0.3%,
Gum arabic 1%, propane diols 2%, methanol 3%, deionized water supply 100%.Above-mentioned material is mixed, through high speed shear point
It is sanded in scattered, sand mill, high dispersive, the stable suspension system formed in water-medium, you can 25% fluazinam is made
Damanling suspension agent.
The field of embodiment 5 uses 10 days, 20 days, 30 days effects after preventing and treating citrus red mite medicine：25% fluazinam is rattled away mite
Clever suspending agent uses 2000-3000 times of preventive effect 97.28-94.08%, 93.06-90.13%, 86.72-81.30%；25% fluorine pyridine
Amine suspending agent uses 3000 times of preventive effects 91.44%, 87.61%, 75.65%；25% Damanling suspension agent uses 2000 times of preventive effects
90.67%th, 84.12%, 62.34%.Originally there is hair to citrus safety, have no adverse effects.
The dispersible oil-suspending agent of fluazinam pyridaben of embodiment 6 and its application.
Fluazinam 1~40%；
Pyridaben 1~40%；
Auxiliary agent complements to 100%.
Fluazinam 15%, pyridaben 15%, Nongru-700 #10%, EO-PO block copolymer 6%, white carbon 2%, the third three
Alcohol 1.5%, formicester palm oil supplies 100%.Above-mentioned material is mixed in proportion, is uniformly dispersed through high speed shear, sand mill
After middle sand milling, you can 30% metrafenone 2-cyano-3-amino-3-phenylancryic acetate oil-suspending agent is made.
The field of embodiment 6 uses 10 days, 20 days, 30 days effects after preventing and treating apple Tetranychus urticae medicine：30% fluazinam is rattled away
Mite spirit suspending agent uses 3000-5000 times of preventive effect 96.01-92.78%, 94.11-91.58%, 83.24-80.05%；30% fluorine
Pyridine amine suspending agent uses 5000 times of preventive effects 90.15%, 89.06%, 77.08%；30% Damanling suspension agent is prevented using 3000 times
Effect 88.21%, 80.10%, 68.47%.Originally there is hair to Apple safety, have no adverse effects.
The fluazinam pyridaben water dispersible granule of embodiment 7 and its application.
Fluazinam 1~60%；
Pyridaben 5~60%；
Auxiliary agent complements to 100%.
Fluazinam 5%, pyridaben 40%, neopelex 7%, urea 2%, polyoxyethylene polyoxypropylene base ether
Block copolymer 10%, polyvinylpyrrolidone 5%, kaolin supplies 100%.Above-mentioned material is mixed in proportion, through air-flow
It is pulverized and mixed uniform, kneading granulation, dries after screening, you can 45% fluazinam pyridaben water dispersible granule is made.
The field of embodiment 7 uses 5 days, 10 days, 20 days effects after preventing and treating grape grey mould medicine：45% fluazinam pyridaben
Water dispersible granules consumption 40-80 grams/acre of preventive effect 86.42-93.22%, 82.14-87.48%, 76.80-83.63%；45% fluorine
40 grams/acre of preventive effects of pyridine aqueous amine dispersible granule consumption 87.24%, 84.27%, 78.44%；45% pyridaben water dispersible granule consumption
80 grams/acre of preventive effects 73.04%, 70.93%, 62.06%.Originally there is hair to grape safety, have no adverse effects.
The fluazinam pyridaben wettable powder of embodiment 8 and its application.
Fluazinam 1~60%；
Pyridaben 5~60%；
Auxiliary agent complements to 100%.
Fluazinam 6%, pyridaben 60%, neopelex 6%, sodium lignin sulfonate 4%, NNO 5%, talcum
Powder 2%, white carbon 2%, attapulgite is supplemented to 100%.Above-mentioned material is weighed in proportion, mixes equal into blender
It is even, then after air-flow crushing, that is, 66% fluazinam pyridaben wettable powder is made.
The field of embodiment 8 uses 5 days, 10 days, 20 days effects after preventing and treating tomato late blight medicine：66% fluazinam pyridaben
Wettable powder consumption 30-60 grams/acre of preventive effect 87.71-91.04%, 80.57-82.90%, 72.39-75.22%；66% fluorine
30 grams/acre of preventive effects of pyridine amine wettable powder usage amount 83.07%, 76.34%, 71.63%；66% pyridaben wettable powder is used
Measure 30 grams/acre of preventive effects 73.42%, 63.01%, 53.77%.
Claims (10)
1. the composition of a kind of containing fluazinam, pyridaben, it is characterised in that the active ingredient of composition is by fluazinam, pyridaben two
Member combination, fluazinam, pyridaben part by weight are 60:1~1:60.
2. composition according to claim 1, it is characterised in that：The part by weight of fluazinam and pyridaben is 30:1~1:
30。
3. composition according to claim 1, it is characterised in that：The part by weight of fluazinam and pyridaben is 10:1~1:
10。
4. composition according to claim 1, it is characterised in that：The part by weight of fluazinam and pyridaben most preferably 1:4.
5. composition according to claim 1, it is characterised in that：Active ingredient accounts for composition total weight 5~90%, remaining
For auxiliary agent.
6. composition according to claim 1, it is characterised in that：Active ingredient accounts for the 25% of composition total weight.
7. composition according to claim 1, it is characterised in that：The formulation of said composition is aqueous suspension agent, dispersible oil
Suspending agent, wettable powder, water dispersible granules.
8. composition according to claim 1, it is characterised in that：Fluazinam 5%, pyridaben 20%, sodium alkyl sulfonate 5% gathers
Ethylene glycol stearate 5%, Magnesiumaluminumsilicate 0.3%, gum arabic 1%, propane diols 2%, methanol 3%, deionized water supply 100%；
Above-mentioned material is mixed, is sanded through high speed shear is scattered, in sand mill, it is the high dispersive that is formed in water-medium, stable outstanding
Floating body system, you can 25% fluazinam Damanling suspension agent is made.
9. application of the composition according to claim 1 on preventing and treating crops red spider, Tetranychus urticae.
10. application of the composition according to claim 1 in preventing and treating crops gray mold, late blight.
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| CN201710244409.1A CN107006482A (en) | 2017-04-14 | 2017-04-14 | A kind of composition of containing fluazinam, pyridaben |
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| CN201710244409.1A CN107006482A (en) | 2017-04-14 | 2017-04-14 | A kind of composition of containing fluazinam, pyridaben |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107306961A (en) * | 2017-09-01 | 2017-11-03 | 江西省科学院微生物研究所 | Rynaxypyr oil-suspending agent |
| CN108041042A (en) * | 2017-12-10 | 2018-05-18 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing cyflumetofen and fluazinam |
| CN109169678A (en) * | 2018-08-28 | 2019-01-11 | 侨昌现代农业有限公司 | A kind of fungicide and combinations thereof |
| CN109757491A (en) * | 2018-12-28 | 2019-05-17 | 京博农化科技有限公司 | A kind of miticide composition of containing fluazinam and jervine |
| CN109907052A (en) * | 2018-12-29 | 2019-06-21 | 京博农化科技有限公司 | A kind of miticide composition containing fluazinam and tebufenpyrad |
| CN110800741A (en) * | 2019-12-06 | 2020-02-18 | 李玉洁 | Efficient pesticide for preventing and treating field red spiders and preparation method thereof |
| CN112335666A (en) * | 2020-11-04 | 2021-02-09 | 侨昌现代农业有限公司 | Plant sterilization composition, bactericide and application thereof |
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Cited By (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107306961A (en) * | 2017-09-01 | 2017-11-03 | 江西省科学院微生物研究所 | Rynaxypyr oil-suspending agent |
| CN108041042A (en) * | 2017-12-10 | 2018-05-18 | 广东中迅农科股份有限公司 | A kind of composition pesticide containing cyflumetofen and fluazinam |
| CN113142236A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN109169678A (en) * | 2018-08-28 | 2019-01-11 | 侨昌现代农业有限公司 | A kind of fungicide and combinations thereof |
| CN113142220A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113142227A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113142223A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113040155A (en) * | 2018-08-28 | 2021-06-29 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113040157A (en) * | 2018-08-28 | 2021-06-29 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113040156A (en) * | 2018-08-28 | 2021-06-29 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113142224A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113142235A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN113142225A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
| CN109757491A (en) * | 2018-12-28 | 2019-05-17 | 京博农化科技有限公司 | A kind of miticide composition of containing fluazinam and jervine |
| CN109907052A (en) * | 2018-12-29 | 2019-06-21 | 京博农化科技有限公司 | A kind of miticide composition containing fluazinam and tebufenpyrad |
| CN110800741A (en) * | 2019-12-06 | 2020-02-18 | 李玉洁 | Efficient pesticide for preventing and treating field red spiders and preparation method thereof |
| CN112335666A (en) * | 2020-11-04 | 2021-02-09 | 侨昌现代农业有限公司 | Plant sterilization composition, bactericide and application thereof |
| CN112335666B (en) * | 2020-11-04 | 2022-03-11 | 侨昌现代农业有限公司 | Plant sterilization composition, bactericide and application thereof |
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Application publication date: 20170804 |