CN108041042A - A kind of composition pesticide containing cyflumetofen and fluazinam - Google Patents

A kind of composition pesticide containing cyflumetofen and fluazinam Download PDF

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Publication number
CN108041042A
CN108041042A CN201711300451.7A CN201711300451A CN108041042A CN 108041042 A CN108041042 A CN 108041042A CN 201711300451 A CN201711300451 A CN 201711300451A CN 108041042 A CN108041042 A CN 108041042A
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China
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cyflumetofen
fluazinam
methyl
composition
bases
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CN201711300451.7A
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Chinese (zh)
Inventor
王礼文
刘鹏
朱刚
张志伟
陈佛祥
吴泽伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of composition pesticide containing cyflumetofen and fluazinam, active ingredient is fluazinam and cyflumetofen, and the ratio of weight and number of fluazinam and cyflumetofen in the composition is 60:1~1:60, the weight percent of fluazinam and cyflumetofen weight summation in the composition is 0.1% 80%；The composition pesticide of the present invention reduces the dosage of pesticide, reduces drug cost, extend the service life of medicament, reduce adverse effect of the pesticide to ecological environment for preventing tomato Tetranychus cinnabarinus, panonychus citri.

Description

A kind of composition pesticide containing cyflumetofen and fluazinam
Technical field
The invention belongs to synergetic pesticide composition field, the specific one kind that provides contains active ingredient fluazinam and cyflumetofen Synergetic pesticide composition.
Background technology
Fluazinam (Fluazinam), is new substituted phenyl amines wide-spectrum bactericide and acaricide, to caused by Botrytis cinerea A variety of gray molds have special efficacy；There is preferable control effect to mite class such as citrus red mite, citrus blister mites, can be used for preventing Control other crop mite class.
Cyflumetofen (Cyflumetofen) is new acyl acetonitrile class contact killing type acaricide, can inhibit mite class mitochondria Respiration, to young mite effect be better than into mite, with the acaricide no interactions resistance used at present.It is complete to be mainly used for prevention citrus Pawl mite, it is also efficient to cotton safflower Tetranychus urticae.
Tetranychus cinnabarinus (Tetranychus cinnabarinus), Arachnoidea belong to Acariformes, Tetranychidae.It is a kind of extensive The agricultural major pest in world temperate zone is distributed in, there is generation all over China, the plant that can cause harm has 113 kinds of 32 section, wherein vegetable 18 kinds of dish, mainly there is eggplant, capsicum, watermelon, beans, green onion and three-coloured amaranth.To draw juice in blade back into deutonymph.Eggplant, Pepper Leaves After aggrieved, blade face begins to show canescence dot, becomes canescence afterwards；After kidney bean, cowpea, melon blade are aggrieved, it is thin to form withered yellow Spot, full leaf, which dries up, when serious comes off, and shortens fruiting period, influences yield.Tetranychus cinnabarinus population changes in field in the shape of a saddle, May Part field is difficult to see, and into after June, quantity gradually increases.In normal year, before and after wheat harvest, the population of field red spider Quantity can increase sharply, and field harm aggravates, and July is the red spider annual rampant phase occurred and aggrieved main of vegetables Period often reaches annual peak period in mid or late July population.Cause harm to 7 the end of month to early August, due to high temperature, population Quantity can decline quickly, and in August, after the last ten-days period, population density is maintained in a relatively low level, is no longer damaged, and It is maintained always to autumn.In the fall, polypide is moved to successively lives on the weeds of underground, overwintering in early November.
Panonychus citri, the also known as species under citrus red mite (Panonychus citri McGregor) Tetranychidae it One, host's blade epidermis is punctured with mouthpart and sucks juice, blade face is killed and countless canescence flecks, full leaf chlorosis when serious is presented Become canescence, cause largely to fall leaves；Also can cause harm fruit and green branch, influence tree vigo(u)r and yield for the production of China's citrus No.1 pest, it is partly overwintering in branch crack mainly in ovum and the stiff leaf caused harm into mite in leaf miner and blade back is overwintering.Have Area without apparent overwintering phenomenon.Generation overlap.General 1 year 12-20 generation.Development and 20-28 DEG C of the preference temperature of breeding When temperature is more than 30 DEG C, the death rate of mite increases；Became 40 DEG C of then its unfavorable existence.The generation of citrus red mite takes out the tip phase with citrus Close with Relationship between temperature, autumn growth pumping is sent out, and abundant foodstuff is provided for citrus red mite, enters a large amount of pests overwintering, if Winter gas temperature is high, and rainwater is few, and second year occurs early and weighs.It is observed according in Sichuan, the 3-5 months, it is generally a large amount of in citrus SPRING WHEAT BEFORE AND AFTER FLOWERING Occur, first time mite mouthful peak occur；In Guangdong Province, when weather turns warm after the beginning of spring, there is 1-2 Sheng and incubates the phase in hibernating egg.This When be to prevent number most period.The mandarin tree that 9 to November, autumn growth pumping was sent out, it also occur that second of peak.In general, The peak in spring is more serious than the peak in autumn, and when autumn growth is aggrieved serious, winter is present with a large amount of fallen leaves.The both sexes of citrus red mite row are given birth to Grow, sometimes also can single-female generation, the egg hatching not being fertilized is male mite, and fertilized eggs then hatch development as female mite.But offspring is mostly Male mite.It is more on female mite oviposition blade, and tow sides have, but it is in the majority with blade back master pulse both sides.Citrus red mite light becomes tender, In tree crown periphery middle and upper part, mountainous region, the tailo in hilly ground orchard, bright and clear position；Generation is more, is often transferred to from old leaf Cause harm on light green branches and leaves, fruit, egg laying amount than in old leaf feeding it is more.Therefore, treelet seedling dies population number and generally relatively grows up Tree is big, aggrieved heavy.
The single use of pesticide can bring resistance risk, and agriculture chemical compounding is the effective way for solving resistance problem.
Develop new product fungicide is expensive, the cycle is long, and in contrast, exploitation is efficient, less toxic, low-residual with research Compounding has with mixture invests that small, the lead time is short and is subject to attention both domestic and external, numerous and confused to increase development dynamics.
The combination of fluazinam and cyflumetofen has not been reported.
The content of the invention
The present invention provides a kind of composition pesticide containing cyflumetofen and fluazinam, for prevent panonychus citri, kind Eggplant Tetranychus cinnabarinus.
The invention is realized by the following technical scheme：
A kind of composition pesticide containing cyflumetofen and fluazinam, contains active ingredient fluazinam and cyflumetofen, fluorine The ratio of weight and number of pyridine amine and cyflumetofen is 60:1~1:60, preferred weight portion rate is 40:1~1:40, further preferably Ratio of weight and number is 15:1~1:15, still more preferably ratio of weight and number is 4:1 and 7:3.
A kind of composition pesticide containing fluazinam and cyflumetofen, contains active ingredient fluazinam and fourth fluorine mite Ester also contains insecticides adjuvant, in order to be processed into insecticides adjuvant, wherein fluazinam and cyflumetofen weight summation in the composition Weight percent for 0.1%~80%, remaining is insecticides adjuvant；Preferred fluazinam and cyflumetofen weight summation are combining Weight percent in object is 5%~60%, remaining is insecticides adjuvant.
A kind of composition pesticide containing fluazinam and cyflumetofen, can be processed into aqueous suspension agent, moisture dissipates Granula.
The aqueous suspension agent dosage form weight percent forms：Fluazinam 0.1~40%, cyflumetofen 0.1~30%, The total content of active ingredient is no more than 60%, dispersant 0.1~10%, wetting agent 0.1~10%, thickener 0.1~1%, anti- Freeze agent 0.1~5%, deionized water carrier complements to 100%；Specifically production stage is：Active ingredient and other auxiliary agents are mixed, After high speed shear is disperseed, is sanded in sand mill, high dispersive, the suspension system of stabilization are formed in water-medium, is made corresponding The aqueous suspension agent of weight percentage.
The dosage form of water dispersible granule weight percent forms：Fluazinam 0.01~60%, cyflumetofen 0.01~ 60%, the total content of active ingredient is no more than 80%, and dispersant 0.1~15%, disintegrant 0.1~10%, wetting agent 0.1~ 7%, solid carrier complements to 100%；Specifically production stage is：Active ingredient and other auxiliary agents are uniformly mixed, with ultra micro gas It flows pulverizer to crush, through mediating, then adds in fluidized-bed granulation dryer and be granulated, dry, sieve, corresponding weight is made The water dispersible granules of percentage composition；The active ingredient total content is no more than 80%.
The antifoaming agent can be one or more of silicone compound, epoxidized soybean oil, methanol, silicone oil etc. Combination.
The antifreezing agent can be combinations one or more of in glycerine, propylene glycol, diethylene glycol (DEG), urea etc..
The wetting agent can be lauryl sodium sulfate, neopelex, sodium butylnaphthalenesulfonate, alkyl sulphur The combination of one or more of sour sodium, tea seed cake powder, spaonin powder, spaonin powder, wheat bran, sorghum starch, buckwheat etc..
The dispersant can be APES formaldehyde condensation product, naphthalenesulfonate formaldehyde condensation compound, to first Oxygroup fatty acyl anilinesulfonic acid, lignosulfonates, polycarboxylate, alkylphenol polyoxyethylene ether sulfate, alkyl benzene sulphonate Calcium salt, aliphatic ester sulfate, alkylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, polyethylene glycol stearate, sorbose The combination of one or more of alcohol oleate, nekal, polyoxyethylene poly-oxygen propylene aether block polymer etc..
The disintegrant can be sodium carboxymethyl starch, low-substituted hydroxypropyl cellulose, croscarmellose sodium, Crospovidone, chitosan, sodium alginate sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite etc. One or more of combination.
The solid carrier can be precipitated calcium carbonate, clay, kaolin, diatomite, bentonite, white carbon, clay, One or more of attapulgite, talcum powder, quartz sand, wood powder, walnut parting, lignin, wheat bran, rice chaff, sawdust etc. Combination.
The binding agent can be sucrose, polyvinyl alcohol, polyethylene glycol, sodium carboxymethylcellulose, polyvinylpyrrolidine Ketone, calcium carboxymethylcellulose, carboxy-propyl cellulose, dextrin, amylodextrin, polyvinylpyrrolidone, sticky kaolin, paraffin, The combination of one or more of rosin, wood powder etc..
The emulsifier can be agriculture breast 33#, agriculture breast 34#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#, Agriculture breast 1602#, T60, S80, TX-10, OP-10, NP-10, Nonyl pheno (EO=10) ether phosphate, triphenoethyl benzene The combination of one or more of phenol polyethenoxy ether phosphate, BBM-3, epoxychloropropane etc..
The solvent can be toluene, dimethylbenzene, trimethylbenzene, solvent naphtha S-150, solvent naphtha S-200, ethyl alcohol, isopropanol, N-butanol, n-octyl alcohol, n-amyl alcohol, acetone, cyclohexanone, hexane, dimethylformamide, N-Methyl pyrrolidone, acetonitrile, dichloromethane The combination of one or more of alkane, ethyl acetate, methyl oleate, dibutyl phthalate, sec-Butyl Acetate etc..
The water is deionized water.
The composition pesticide containing fluazinam and cyflumetofen is suitable for prevention tomato Tetranychus cinnabarinus, the full pawl of citrus Mite can be used for preventing other crop evil mites.
The present composition can also be composed or with improving control effect or expanding prevention to target tool with other combined use of pesticides There is synergistic effect, they can be：
(1) inhibitor of ergosterol synthesis:(1.1) aldimorph (1704-28-5), (1.2) penta ring azoles (azaconazole) (60207-31-0), (1.3) Bitertanol (bitertanol), (1.4) bromuconazole (bromuconazole), (1.5) cyproconazole (cyproconazole) (113096-99-4), (1.6) diclobutrazol (diclobutrazole) (75736-33-3), (1.7) Difenoconazoles (difenoconazole), (1.8) olefin conversion (diniconazole) (83657-24-3), (1.9) olefin conversion-M (diniconazole-M) (83657-18-5), (1.10) ten Two cyclomorpholines (dodemorph), (1.11) dodemorfe (dodemorph acetate) (31717-87-0), (1.12) epoxiconazole (epoxiconazole), (1.13) etaconazole (etaconazole) (60207-93-4), (1.14) fenarimol (fenarimol) (60168-88-9), (1.15) benzoxazole (fenbuconazole), (1.16) fenhexamid (fenhexamid) (126833-17-8), (1.17) fenpropidin (fenpropidin), (1.18) butadiene morpholine (fenpropimorph) (67306-03-0), (1.19) Fluquinconazole (fluquinconazole), (1.20) flurprimidol (flurprimidole) (56425-91-3), (1.21) Flusilazole (flusilazole) (85509-19-9), (1.22) powder azoles Alcohol (flutriafol), (1.23) furconazole (furconazole) (112839-33-5), (1.24) furconazole_cis (furconazole-cis), (1.25) hexaconazole (hexaconazole) (79983-71-4), (1.26) enzyme (imazalil), (1.27) enzyme sulfate (imazalil sulfate) (58594-72-2), (1.28) glyoxalin (imibenconazole), (1.29) kind bacterium azoles (ipconazole) (125225-28-7), (1.30) metconazole (metconazole), (1.31) nitrile bacterium azoles (myclobutanil) (88671-89-0), (1.32) Naftifine (naftifine) Imidazoles is disliked in (65472-88-0), (1.33) nuarimol (nuarimol) (63284-71-9), (1.34) (oxpoconazole) (174212-12-5), (1.35) paclobutrazol (paclobutrazol) (76738-62-0), (1.36) rice Pest ester (pefurazoate), (1.37) penconazole (penconazole) (66246-88-6), (1.38) disease spend spirit (piperalin) (3478-94-2), (1.39) Prochloraz (prochloraz) (67747-09-5), (1.40) propiconazole (propiconazole) (60207-90-1), (1.41) prothioconazoles (prothioconazole), (1.42) pyributicarb (pyributicarb) (88678-67-5), (1.43) pyrifenox (pyrifenox) (88283-41-4) (1.44) azoles oxolinic acide (quinconazole), (1.45) simeconazoles (simeconazole) (149508-90-7), (1.46) Loazolamines (spiroxamine), (1.47) Tebuconazole (tebuconazole) (107534-96-3), (1.48) Terbinafine (terbinafine), (1.49) fluorine ether azoles (tetraconazole) (112281-77-3), (1.50) triazolone (triadimefon), (1.51) Triadimenol (triadimenol) (89482-17-7), (1.52) tridemorph (tridemorph), (1.53) fluorine bacterium azoles (triflumizole) (68694-11-1), (1.54) triforine (triforine) (26644-46-2), (1.55) triticonazole (triticonazole), (1.56) uniconazole P (uniconazole) (83657- 22-1), (1.57) high uniconazole P (uniconazole-p), (1.58) alkene frost benzyl azoles (viniconazole) (77174-66-4), (1.59) voriconazole (voriconazole) (137234-62-9), (1.60) 1- (4- chlorphenyls) -2- (1H-1,2,4- tri- Azoles -1- bases) suberol (129586-32-9), (1.61) 1- (2,2- dimethyl -2,3- dihydro -1H- indenes -1- bases) -1H- imidazoles - 5- carboxylate methyl esters (110323-95-0), (1.62) N'- { 5- (difluoromethyl) -2- methyl -4- [3- (trimethyl silyl) third Oxygroup] phenyl-N- ethyl-N-methyl imino groups formamide, (1.63) N- ethyl-N-methyls-N'- { 2- methyl -5- (fluoroforms Base) -4- [3- (trimethyl silyl) propoxyl group] phenyl } imino group formamide and (1.64) O- { 1- [(4- methoxycarbonyl phenoxies Base) -3,3- dimethyl butyrate -2- bases } -1H- imidazoles -1- sulfocarbonates (111226-71-2).
(2) inhibitor of electron transport chain complex I or II:Such as (2.1) bixafen, (2.2) Boscalid (boscalid) (188425-85-6), (2.3) carboxin (carboxin) (5234-68-4), (2.4) fluorine mepanipyrim (diflumetorim) (130339-07-0), (2.5) fenfuram (fenfuram), (2.6) fluopicolide (fluopyram), (2.7) flutolanil (flutolanil) (66332-96-5), (2.8) fluxapyroxad, (2.9) furan pyrazoles spirit (furametpyr) (123572- 88-3), (2.10) seed dressing amine (furmecyclox) (60568-05-0), (2.11) naphthalene pyrrole bacterium amine (isopyrazam, it is cis-poor The mixture of the racemic modification 1RS, 4SR, 9SR of racemic modification 1RS, 4SR, 9RS and trans-epimerism to isomery) (88165-58-1), (2.12) naphthalene pyrrole bacterium amine (isopyrazam, the racemic modification 1RS, 4SR, 9SR of trans-epimerism), (2.13) naphthalene pyrrole bacterium amine (isopyrazam, the enantiomter 1R, 4S, 9S of trans-epimerism), (2.14) naphthalene pyrrole bacterium amine (isopyrazam, the enantiomter 1S, 4R, 9R of trans-epimerism), (2.15) naphthalene pyrrole bacterium amine (isopyrazam, it is suitable The racemic modification 1RS, 4SR, 9RS of formula-epimerism), (2.16) naphthalene pyrrole bacterium amine (isopyrazam, pair of cis-epimerism Reflect isomers 1R, 4S, 9R), (2.17) naphthalene pyrrole bacterium amine (isopyrazam, enantiomter 1S, the 4R of cis-epimerism, 9S), (2.18) mebenil (mepronil) (55814-41-0), (2.19) oxycarboxin (oxycarboxin), (2.20) penta Benzene pyrrole bacterium amine (penflufen), (2.21) pyrrole metsulfovax (penthiopyrad) (183675-82-3), (2.22) ring the third pyrrole bacterium Amine (sedaxane) (874967-67-6), (2.23) thifluzamide (thifluzamide) (130000-40-7), (2.24) 1- Methyl-N- [2- (1,1,2,2- tetrafluoros ethyoxyl) phenyl] -3- (trifluoromethyl) -1H- pyrazole-4-carboxamides, (2.25) 3- (two Methyl fluoride) -1- methyl-N- [2- (1,1,2,2- tetrafluoros ethyoxyl) phenyl] -1H- pyrazole-4-carboxamides, (2.26) 3- (difluoros Methyl)-N- [the fluoro- 2- of 4- (1,1,2,3,3,3- hexafluoros propoxyl group) phenyl] -1- methyl-1 H- pyrazole-4-carboxamides, (2.27) N- [1- (2,4 dichloro benzene base) -1- methoxy propane -2- bases] -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamides Bis- fluoro- N- of (1092400-95-7) (WO2008148570), (2.28) 5,8- [2- (the fluoro- 4- of 2- [4- (trifluoromethyl) pyridine- 2- yls] oxygroup phenyl) ethyl] quinazoline -4- amine (1210070-84-0) (WO2010025451), (2.29) N- [9- (dichloros Methylene) -1,2,3,4- tetrahydrochysene -1,4- methanonaphthalene -5- bases] -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamides, (2.30) N- [(1S, 4R) -9- (dichloromethylene) -1,2,3,4- tetrahydrochysene -1,4- methanonaphthalene -5- bases] -3- (difluoromethyl) - [(1R, 4S) -9- (dichloromethylene) -1,2,3,4- tetrahydrochysenes -1,4- is sub- by 1- methyl-1 H- pyrazole-4-carboxamides and (2.31) N- Methyl naphthalene -5- bases] -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamides.
(3) inhibitor of electron transport chain complex III:Such as (3.1) ametoctradin, (3.2) amisulbrom (amisulbrom), (3.3) nitrile Fluoxastrobin (azoxystrobin), (3.4) cyazofamid (cyazofamid), (3.5) Coumethoxystrobin, (3.6) coumoxystrobin, (3.7) dimoxystrobin (dimoxystrobin), (3.8) alkene oxime bacterium Ester (enestroburin) (238410-11-2) (WO2004/058723), (3.9) famoxadones (famoxadone), (3.10) Imidazoles bacterium (fenamidone), (3.11) fenoxystrobin, (3.12) fluoxastrobin (fluoxastrobin), (3.13) ether Bacterium ester (kresoxim-methyl), (3.14) SSF 126 (metominostrobin), (3.15) orysastrobin (orysastrobin), (3.16) ZEN 90160 (picoxystrobin), (3.17) pyraclostrobin (pyraclostrobin), (3.18)pyrametostrobin、(3.19)pyraoxystrobin、(3.20)pyribencarb、(3.21) Triclopyricarb (902760-40-1), (3.22) trifloxystrobin (trifloxystrobin), (3.23) (2E) -2- (2- { [6- (3- chloro-2-methyls phenoxy group) -5-FU -4- bases] oxygroup } phenyl) -2- (methoxyimino)-N- methyl vinyls Amine (WO2004/058723), (3.24) (2E) -2- (methoxyimino)-N- methyl -2- (2- { [({ (1E) -1- [3- (trifluoros Methyl) phenyl] ethylidene amino) oxygroup] methyl phenyl) acetamide (WO2004/058723), (3.25) (2E) -2- (methoxies Base imino group)-N- methyl -2- { 2- [(E)-({ 1- [3- (trifluoromethyl) phenyl] ethyoxyl } imino group) methyl] phenyl } acetyl Amine (158169-73-4), (3.26) (2E) -2- { 2- [({ [(1E) -1- (3- { [the fluoro- 2- phenyl vinyls of (E) -1-] oxygen } benzene Base) ethylidene] amino } oxygroup) methyl] phenyl } -2- (methoxyimino)-N- methylacetamides (326896-28-0), (3.27) (2E) -2- { 2- [({ [(2E, 3E) -4- (2,6- dichlorophenyls) butyl- 3- alkene -2- subunits] amino } oxygroup) methyl] benzene Base } -2- (methoxyimino)-N- methylacetamides, the chloro- N- of (3.28) 2- (1,1,3- trimethyl -2,3- dihydro -1H- indenes - 4- yls) pyridine-3-carboxamide (119899-14-8), (3.29) 5- methoxyl group -2- methyl -4- (2- { [({ (1E) -1- [3- (three Methyl fluoride) phenyl] ethylidene amino) oxygroup] methyl phenyl) -2,4- dihydro -3H-1,2,4- triazole -3- ketone, (3.30) (2E) -2- { 2- [({ cyclopropyl [(4- methoxyphenyls) imino group] methyl } sulfenyl) methyl] phenyl } -3- methoxy propyl -2- alkene Sour methyl esters (149601-03-6), (3.31) N- (3- ethyl -3,5,5- trimethylcyclohexyls) -3- (formamido group) -2- hydroxy benzenes Formamide (226551-21-9), (3.32) 2- { 2- [(2,5- dimethyl phenoxies) methyl] phenyl } -2- methoxy-. N-methyls Acetamide (173662-97-0) and (3.33) (2R) -2- { 2- [(2,5- dimethyl phenoxies) methyl] phenyl } -2- methoxyl groups - N- methylacetamides (394657-24-0).
(4) mitosis and cell division inhibitor:Such as (4.1) benomyl (benomyl), (4.2) carbendazim (carbendazim), (4.3) benzene imidazoles bacterium (chlorfenazole), (4.4) diethofencarb (diethofencarb), (4.5) Korea Spro Happy peaceful (ethaboxam) (162650-77-3), (4.6) fluopicolide (fluopicolide), (4.7) furidazol (fuberidazole), (4.8) Pencycuron (pencycuron), (4.9) Apl-Luster (thiabendazole), (4.10) methyl Thiophanate (thiophanate-methyl) (23564-05-8), (4.11) thiophanate, (4.12) zoxamide (zoxamide) (156052-68-5), the chloro- 7- of (4.13) 5- (4- methyl piperidine -1- bases) -6- (2,4,6- trifluorophenyls) [1, 2,4] triazole [1,5-a] pyrimidine (214706-53-3) and the chloro- 5- of 3- (6- chloropyridine -3- bases) -6- methyl -4- (2,4,6- tri- Fluorophenyl) pyridazine (1002756-87-7).
(5) there can be the compound that multidigit point acts on:Such as (5.1) Bordeaux mixture (bordeauxmixture), (5.2) Difoltan (captafol), (5.3) captan, (5.4) Bravo (chlorothalonil) (1897-45-6), (5.5) hydrogen-oxygen Change copper, (5.6) copper naphthenate (1338-02-9), (5.7) copper oxide (1317-39-1), (5.8) copper oxychloride (1332-40- 7), (5.9) copper sulphate, (5.10) Euparen (dichlofluanid) (1085-98-9), (5.11) dithianon (dithianon), (5.12) dodine (dodine) (2439-10-3), (5.13) dodine free alkali (dodine free Base), (5.14) fervam (ferbam) (14484-64-1), (5.15) fluorofolpet, (5.16) folpet (folpet) (133-07-3), the pungent salt of (5.17) biguanides (guazatine) (108173-90-6), (5.18) guazatine acetate (guazatine acetate), (5.19) iminoctadine (iminoctadine), (5.20) double eight guanidine salts (iminoctadine Albesilate), (5.21) iminoctadine triacetate (iminoctadine triacetate), (5.22) mancopper (mancopper), (5.23) Mancozeb (mancozeb), (5.24) maneb (maneb), (5.25) Carbatene (metiram) (9006-42-2), (5.26) Carbatene zinc (metiram zinc), (5.27) copper 8-hydroxyquinolinate (oxine-copper) (10380-28-6), (5.28) propamidine (104-32-5), (5.29) Propineb (propineb) (12071-83-9), (5.30) sulphur and sulphur preparation include calcium polysulfide (calcium polysulphide) (7704-34-9), (5.31) thiram (thiram) (137-26-8), (5.32) tolyfluanid (tolylfluanid) (731-27-1), (5.33) zineb (zineb) (12122-67-7) and (5.34) ziram (ziram) (137-30-4).
(6) compound of host defense can be induced:Such as (6.1) diazosulfide (acibenzolar-S- Methyl), (6.2) isotianil (isotianil) (224049-04-1), (6.3) probenazole (probenazole) and (6.3) Tiadinil (tiadinil) (223580-51-6).
(7) amino acid and/or protein biology synthetic inhibitor:Such as (7.1) amine puts out (andoprim), (7.2) go out pest Plain (blasticidin-S), (7.3) cyprodinil (cyprodinil), (7.4) kasugarnycin (kasugamycin), (7.5) Kasugamycini hydrochloride hydrate, (7.6) mepanipyrim (mepanipyrim), (7.7) pyrimethanil (pyrimethanil) and 3- (the fluoro- 3,3,4,4- tetramethyls -3,4- dihydro-isoquinolines -1- bases of 5-) quinoline (861647-32-7) (WO2005070917).
(8) ATP generates inhibitor:(8.1) fentin acetate (fentin acetate) (900-95-8), (8.2) three Benzene tin chlorine (fentin chloride) (639-58-7), (8.3) fentin hydroxide (fentin hydroxide) (76-87-9) and (8.4) Silthiopham (silthiofam) (175217-20-6).
(9) Cell wall synthesis inhibitor:Such as (9.1) benzene metsulfovax (benthiavalicarb), (9.2) dimethomorph (dimethomorph) (110488-70-5), (9.3) flumorph (flumorph) (211867-47-9), (9.4) iprovalicarb (iprovalicarb) (140923-17-7), (9.5) mandipropamid (mandipropamid), (9.6) polyoxin (polyoxins) (11113-80-7), (9.7) Polyoxin (polyoxorim) (22976-86-9), (9.8) Validacin (Takeda) (validamycin A) and (9.9) valifenalate.
(10) lipid and film synthetic inhibitor:Such as (10.1) biphenyl (biphenyl) (92-52-4), (10.2) chloroneb (chloroneb) (2675-77-6), (10.3) botran (dicloran) (99-30-9), (10.4) edifenphos (edifenphos) (17109-49-8), (10.5) kobam (etridiazole) (2593-15-9), (10.6) iodocarb, (10.7) different rice blast net (iprobenfos) (26087-47-8), (10.8) Isoprothiolane (isoprothiolane) (50512-35- 1), (10.9) Propamocarb (propamocarb) (25606-41-1), (10.10) propamocarb (propamocarb- Hydrochloride) (25606-41-1), (10.11) prothiocarb (prothiocarb), (10.12) Ppyrazophos (pyrazophos) (13457-18-6), (10.13) pentachloronitrobenzene (quintozene) (82-68-8), (10.14) tetrachloro nitre Base benzene (tecnazene) (117-18-0) and (10.15) tolelofos-methyl (tolclofos-methyl) (57018-04-9).
(11) melanin biosynthesis inhibitor:Such as (11.1) ring propionyl bacterium amine (carpropamid), (11.2) chlorine cyanogen Bacterium amine (diclocymet) (139920-32-4), (11.3) fenoxanil (fenoxanil), (11.4) Rabcide (phthalid) (27355-22-2), (11.5) pyroquilon (pyroquilon), (11.6) tricyclazole (tricyclazole) (41814-78-2) and (11.7) { 3- methyl-1s-[(4- methyl benzoyls) amino] butane -2- bases } carbamic acid 2,2,2- Trifluoro ethyl ester.
(12) nucleic acid synthetic inhibitor:Such as (12.1) M 9834 (benalaxyl) (71626-11-4), (12.2) refining benzene White spirit (benalaxyl-M, kiralaxyl), the phonetic bacterium of (12.3) sulphur clever (bupirimate) (41483-43-6), (12.4) Clozylacon (67932-85-8), (12.5) Milcurb (dimethirimol) (5221-53-4), (12.6) Milstem (ethirimol) (23947-60-6), (12.7) Furalaxyl (furalaxyl) (57646-30-7), (12.8) hydroxyisoxazole (hymexazole) (10004-44-1), (12.9) metalaxyl (metalaxyl) (57837-19-1), (12.10) Metalaxyl-M (metalaxyl-M, mefenoxam) (70630-17-0), (12.11) fenfuram (ofurace) (58810-48-3), (12.12) Evil frost spirits (oxadixyl) (77732-09-3) and (12.13) oxolinic acide (oxolinic acid) (14698-29- 4)。
(13) signal transduction inhibitor:Such as (13.1) chlozolinate (chlozolinate) (84332-86-5), (13.2) Fenpiclonil (fenpiclonil), (13.3) Fu Evil bacterium (fludioxonil) (131341-86-1), (13.4) isopropyl are fixed (iprodione), (13.5) procymidone (procymidone) (32809-16-8), (13.6) quinoxyfen (quinoxyfen) (124495-18-7) and (13.7) vinclozolin (vinclozolin) (50471-44-8).
It (14) can be as the compound of uncoupler:Such as (14.1) binapacryl (binapacryl), (14.2) chlorfenethol General (dinocap) (131-72-6), (14.3) ferimzone (ferimzone), (14.4) fluazinam (fluazinam) and (14.5) meptyldinocap。
(15) other compounds, such as (15.1) benthiozole (benthiazole) (21564-17-0), (15.2) Bethoxazin (163269-30-5), (15.3) capsimycin (capsimycin) (70694-08-5), (15.4) carvol (carvone) (99-49-0), (15.5) chinomethionat (chinomethionat) (2439-01-2), (15.6) pyriofenone (chlazafenone), (15.7) cufraneb (cufraneb) (11096-18-7), (15.8) cyflufenamid (cyflufenamid), (15.9) cymoxanil (cymoxanil) (57966-95-7), (15.10) cyclopropyl-sulfonylamide (cyprosulfamide) (221667-31-8), (15.11) dazomet (dazomet) (533-74-4), (15.12) debacarb (debacarb), (15.13) antiphen (dichlorophen) (97-23-4), (15.14) diclomezin (diclomezine) (62865-36-5), (15.15) difenzoquat (difenzoquat) (49866-87-7), (15.16) difenzoquat Methylsulfate (difenzoquat methylsulphate), (15.17) diphenylamines (diphenylamine), (15.18) ecomate, (15.19) fenpyrazamino, (15.20) fluorine acyl bacterium amine (flumetover), (15.21) fluoromide (fluoroimide), (15.22) flusulfamide (flusulfamide), (15.23) flutianil, (15.24) fosetyl-aluminium (fosetyl-aluminium) (39148-24-8), (15.25) ethane phosphonic acid calcium, (15.26) ethane phosphonic acid sodium (39148-16-8), (15.27) hexachloro-benzene (hexachlorobenzene) (118-74-1), (15.28) human world mycin (irumamycin), (15.29) methasulfocarb (methasulfocarb) (66952-49-6), (15.30) methyl-isorhodanate (556-61-6), (15.31) metrafenone (metrafenone) (220899-03-6), (15.32) midolthromycin (mildiomycin), (15.33) Myprozine (natamycin), (15.34) Sankel (nickel dimethyl dithiocarbamate), (15.35) phthalein Bacterium ester (nitrothal-isopropyl) (10552-74-6), (15.36) different thiophene bacterium ketone (octhilinone), (15.37) Oxamocarb (917242-12-7), (15.38) oxyfenthiin (34407-87-9), (15.39) pentachlorophenol (pentachlorophenol) and its salt (87-86-5), (15.40) phenothrin (phenothrin), (15.41) phosphoric acid and Its salt (13598-36-2), (15.42) propamocarb-fosetylate, (15.43) propanosine-sodium, (15.44) the third oxygen quinoline (proquinazid) (189278-12-4), (15.45) pyrimorph, (15.45e) (2E) -3- (4- Tert-butyl-phenyl) -3- (2- chloropyridine -4- bases) -1- (morpholine -4- bases) propyl- 2- alkene -1- ketone (1231776-28-5), (15.45z) (2Z) -3- (4- tert-butyl-phenyls) -3- (2- chloropyridine -4- bases) -1- (morpholine -4- bases) propyl- 2- alkene -1- ketone (1231776-29-6), (15.46) pyrroles's rhzomorph (pyrrolnitrine) (1018-71-9) (EP-A1559320), (15.47) Tebufloquin (376645-78-2), (15.48) tecloftalam (tecloftalam) (76280-91-6), (15.49) Tolnifanide (304911-98-6), (15.50) azoles bacterium piperazine (triazoxide) (72459-58-6), (15.51) bigcatkin willow bacterium Amine (trichlamide), (15.52) zarilamid (zarilamid) (84527-51-5), (15.53) (3S, 6S, 7R, 8R) -8- Benzyl -3- [({ 3- [(isobutyl acyloxy) methoxyl group] -4-methoxypyridine -2- bases } carbonyl) amino] -6- methyl -4,9- two Oxygen -1,5- dioxolanes -7- base 2 Methylpropionic acid esters (517875-34-2) (WO2003035617), (15.54) 1- (4- { 4- [(5R) -5- (2,6- difluorophenyls) -4,5- dihydro -1,2- oxazole -3- bases] -1,3- thiazol-2-yls } piperidin-1-yl) -2- [5- Methyl -3- (trifluoromethyl) -1H- pyrazol-1-yls] ethyl ketone (1003319-79-6) (WO2008013622), (15.55) 1- (4- { 4- [(5S) -5- (2,6- difluorophenyls) -4,5- dihydro -1,2- oxazole -3- bases] -1,3- thiazol-2-yls } piperidin-1-yl) -2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yls] ethyl ketone (1003319-80-9) (WO2008013622), (15.56) 1- (4- { 4- [5- (2,6- difluorophenyls) -4,5- dihydro -1,2- oxazole -3- bases] -1,3- thiazol-2-yls } piperidin-1-yl) -2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yls] ethyl ketone (1003318-67-9) (WO2008013622), (15.57) 1- (4- methoxyphenoxies) -3,3- dimethylbutane -2- base 1H- imidazoles -1- carboxylates (111227-17-9), (15.58) 2,3, Simultaneously [2,3-d] is phonetic for 5,6- tetra- chloro- 4- (methyl sulphonyl) pyridine (13108-52-6), (15.59) 2,3- dibutyl -6- chlorothiophenes Pyridine -4 (3H) -one (221451-58-7), [1,4] two thiophene English of (15.60) 2,6- dimethyl -1H, 5H- simultaneously [2,3-c:5,6-c'] - 1,3,5,7 (2H, 6H)-tetrone of two pyrroles, (15.61) 2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yls] -1- (4- { 4- [(5R) -5- phenyl -4,5- dihydro -1,2- oxazole -3- bases] -1,3- thiazol-2-yls } piperidin-1-yl) ethyl ketone (1003316- 53-7) (WO2008013622), (15.62) 2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yls] -1- (4- { 4- [(5S) -5- phenyl -4,5- dihydro -1,2- oxazole -3- bases] -1,3- thiazol-2-yls } piperidin-1-yl) ethyl ketone (1003316-54- 8) (WO2008013622), (15.63) 2- [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yls] -1- 4- [4- (5- phenyl - 4,5- dihydro -1,2- oxazole -3- bases) -1,3- thiazol-2-yls] piperidin-1-yl } ethyl ketone (1003316-51-5) (WO2008013622), the iodo- 3- propyl -4H- benzopyran-4-ones of (15.64) 2- butoxy -6-, the chloro- 5- [2- of (15.65) 2- Chloro- 1- (bis- fluoro- 4- methoxyphenyls of 2,6-) -4- methyl-1 H- imidazoles -5- bases] pyridine, (15.66) 2- phenylphenols and its salt (90-43-7), (15.67) 3- (tri- fluoro- 3,3- dimethyl -3,4- dihydro-isoquinoline -1- bases of 4,4,5-) quinoline (861647-85- 0) (WO2005070917) (15.68) 3,4,5- trichloropyridine -2,6- dintrile (17824-85-0), (15.69) 3- [5- (4- chlorine Phenyl) -2,3- dimethyl -1,2- oxazolidine -3- bases] pyridine, (15.70) 3- chloro- 5- (4- chlorphenyls) -4- (2,6- difluorobenzenes Base) -6- methyl pyridazine, (15.71) 4- (4- chlorphenyls) -5- (2,6- difluorophenyls) -3,6- diformazans radical pyridazine, (15.72) 5- Amino -1,3,4- thiadiazoles -2- mercaptan, the chloro- N'- phenyl-N'- of (15.73) 5- (propyl- 2- alkynes -1- bases) thiophene -2- sulfohydrazides (134-31-6), the fluoro- 2- of (15.74) 5- [(4- luorobenzyls) oxygroup] pyrimidine -4- amine (1174376-11-4) (WO2009094442), the fluoro- 2- of (15.75) 5- [(4- methylbenzyls) oxygroup] pyrimidine -4- amine (1174376-25-0) (WO2009094442), (15.76) 5- methyl -6- octyl groups [1,2,4] triazol [1,5-a] pyrimidine -7- amine, (15.77) (2Z) - 3- amino -2- cyano -3- phenyl propyl- 2- acetoacetic esters, (15.78) N'- (4- { [3- (4- chlorobenzyls) -1,2,4- thiadiazoles -5- Base] oxygroup -2,5- 3,5-dimethylphenyls)-N- ethyl-N-methyl imino groups formamide, (15.79) N- (4- chlorobenzyls) -3- [3- Methoxyl group -4- (propyl- 2- alkynes -1- oxygroups) phenyl] propionamide, (15.80) N- [(4- chlorphenyls) (cyano) methyl] -3- [3- first Oxygroup -4- (propyl- 2- alkynes -1- oxygroups) phenyl] propionamide, (15.81) N- [(the bromo- 3- chloropyridines -2- bases of 5-) methyl] -2,4- two Chloropyridine -3- formamides, (15.82) N- [1- (the bromo- 3- chloropyridines -2- bases of 5-) ethyl] -2,4- dichloropyridine -3- formamides, (15.83) N- [1- (the bromo- 3- chloropyridines -2- bases of 5-) ethyl] fluoro- 4- iodo-pyridins -3- formamides of -2-, (15.84) N- (E) - [(cyclo propyl methoxy) imino group] [6- (difluoro-methoxy) -2,3- difluorophenyls] methyl } -2- phenyl-acetamides (221201- 92-9), (15.85) N- { (Z)-[(cyclo propyl methoxy) imino group] [6- (difluoro-methoxy) -2,3- difluorophenyls] methyl } - 2- phenyl-acetamides (221201-92-9), (15.86) N'- { 4- [(3- tertiary butyl -4- cyano -1,2-17 thiazole -5- bases) oxygen Base] the chloro- 5- aminomethyl phenyls of -2--N- ethyl-N-methyl imino groups formamide, (15.87) N- methyl -2- (1- { [5- methyl -3- (trifluoromethyl) -1H- pyrazol-1-yls] acetyl group } piperidin-4-yl)-N- (1,2,3,4- naphthane -1- bases) -1,3- thiazoles -4- Formamide (922514-49-6) (WO2007014290), (15.88) N- methyl -2- (1- [5- methyl -3- (trifluoromethyl) - 1H- pyrazol-1-yls] acetyl group } piperidin-4-yl)-N- [(1R) -1,2,3,4- naphthane -1- bases] -1,3- thiazole -4-carboxamides (922514-07-6) (WO2007014290), (15.89) N- methyl -2- (1- [5- methyl -3- (trifluoromethyl) -1H- pyrazoles - 1- yls] acetyl group } piperidin-4-yl)-N- [(1S) -1,2,3,4- naphthane -1- bases] -1,3- thiazole -4-carboxamides (922514- 48-5) (WO2007014290), (15.90) { 6- [({ [(1- methyl-1 H- tetrazolium -5- bases) (phenyl) methylene] amino } oxygen Base) methyl] pyridine -2- bases amyl carbamate, (15.91) phenazine-1-carboxylic acid, (15.92) quinoline -8- alcohol (134-31-6), (15.93) quinoline -8- alcohol sulfates (2:1) (134-31-6) and (15.94) { 6- [({ [(1- methyl-1 H- tetrazolium -5- bases) (benzene Base) methylene] amino } oxygroup) methyl] pyridine -2- bases } t-butyl carbamate.
(16) other compounds, such as (16.1) 1- methyl -3- (trifluoromethyl)-N- [2'- (trifluoromethyl) biphenyl -2- Base] -1H- pyrazole-4-carboxamides, (16.2) N- (4'- chlordiphenyl -2- bases) -3- (difluoromethyl) -1- methyl-1 H- pyrazoles -4- Formamide, (16.3) N- (2', 4'- dichlorobenzene -2- bases) -3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamides, (16.4) 3- (difluoromethyl) -1- methyl-N- [4'- (trifluoromethyl) biphenyl -2- bases] -1H- pyrazole-4-carboxamides, (16.5) N- (2', 5'- DfBP -2- bases) -1- methyl -3- (trifluoromethyl) -1H- pyrazole-4-carboxamides, (16.6) 3- (difluoro first Base) -1H- pyrazole-4-carboxamides are (by WO2004/058723 by -1- methyl-N- [4'- (propyl- 1- alkynes -1- bases) biphenyl -2- bases] Know), the fluoro- 1,3- dimethyl-N -s of (16.7) 5- [4'- (propyl- 1- alkynes -1- bases) biphenyl -2- bases] -1H- pyrazole-4-carboxamides (by Known to WO2004/058723), the chloro- N- of (16.8) 2- [4'- (propyl- 1- alkynes -1- bases) biphenyl -2- bases] pyridine-3-carboxamide (by WO2004/058723), (16.9) 3- (difluoromethyl)-N- [4'- (3,3- dimethyl butyrate -1- alkynes -1- bases) biphenyl -2- bases] -1- Methyl-1 H- pyrazole-4-carboxamides (as known to WO2004/058723), (16.10) N- [4'- (3,3- dimethyl butyrate -1- alkynes -1- Base) biphenyl -2- bases] the fluoro- 1,3- dimethyl -1H- pyrazole-4-carboxamides (as known to WO2004/058723) of -5-, (16.11) 3- - 1- methyl-1 H- pyrazole-4-carboxamides are (by WO2004/058723 by (difluoromethyl)-N- (4'- acetenyl biphenyl -2- bases) Know), (16.12) N- (4'- acetenyl biphenyl -2- bases) fluoro- 1,3- dimethyl -1H- pyrazole-4-carboxamides of -5- are (by WO2004/ Known to 058723), pyridine-3-carboxamide is (by WO2004/058723 by the chloro- N- of (16.13) 2- (4'- acetenyl biphenyl -2- bases) Know), the chloro- N- of (16.14) 2- [4'- (3,3- dimethyl butyrate -1- alkynes -1- bases) biphenyl -2- bases] pyridine-3-carboxamide (by Known to WO2004/058723), (16.15) 4- (difluoromethyl) -2- methyl-N- [4'- (trifluoromethyl) biphenyl -2- bases] -1,3- Thiazole -5- formamides (as known to WO2004/058723), the fluoro- N- of (16.16) 5- [4'- (3- hydroxy-3-methyl butyl- 1- alkynes -1- Base) biphenyl -2- bases] -1,3- dimethyl -1H- pyrazole-4-carboxamides (as known to WO2004/058723), the chloro- N- of (16.17) 2- [4'- (3- hydroxy-3-methyl butyl- 1- alkynes -1- bases) biphenyl -2- bases] pyridine-3-carboxamide (as known to WO2004/058723), (16.18) 3- (difluoromethyl)-N- [4'- (3- methoxyl group -3- methyl butyl- 1- alkynes -1- bases) biphenyl -2- bases] -1- methyl-1s H- Pyrazole-4-carboxamide (as known to WO2004/058723), the fluoro- N- of (16.19) 5- [4'- (3- methoxyl group -3- methyl butyl- 1- alkynes - 1- yls) biphenyl -2- bases] -1,3- dimethyl -1H- pyrazole-4-carboxamides (as known to WO2004/058723), (16.20) 2- be chloro- Pyridine-3-carboxamide is (by WO2004/058723 by N- [4'- (3- methoxyl group -3- methyl butyl- 1- alkynes -1- bases) biphenyl -2- bases] Know), (16.21) (the bromo- 2- methoxyl groups -4- picolines -3- bases of 5-) (2,3,4- trimethoxy -6- aminomethyl phenyls) ketone (by Known to EP-A1559320), (16.22) N- [2- (4- { [3- (4- chlorphenyls) propyl- 2- alkynes -1- bases] oxygen } -3- methoxyphenyls) Ethyl]-N2- (methyl sulphonyl) valine amide (220706-93-4), (16.23) 4- oxygen -4- [(2- phenylethyls) amino] fourth Sour and (16.24) { 6- [({ [(Z)-(1- methyl-1 H- tetrazolium -5- bases) (phenyl) methylene] amino } oxygroup) methyl] pyridine - 2- yls } carbamic acid butyl- 3- alkynes -1- esters, N- [9- (dichloromethylene) -1,2,3,4- tetrahydrochysene -1,4- methanonaphthalene -5- bases] - 3- (difluoromethyl) -1- methyl-1 H- pyrazole-4-carboxamides and 3- difluoromethyl -1- methyl-1 H- pyrazoles -4- carboxylic acids [2- (2, 18184- dichlorophenyls) -2- methoxyl group -1- methyl-ethyls]-amine.The blending constituent that wherein all (1) to (16) classes are named can Optionally forming salt --- if their functional group can be such with appropriate alkali or acid.
The bactericide that can be mentioned that has：Bronopol (bronopol), antiphen (dichlorophen), N-Serve (nitrapyrin), Sankel (nickel dimethyldithiocarbamate), kasugarnycin (kasugamycin), pungent Thiophene ketone (octhilinone), furancarboxylic acid, terramycin (oxytetracyclin), probenazole (probenazole), streptomysin (streptomycin), tecloftalam (tecloftalam), copper sulphate and other copper agents.
Insecticide, acaricide and the nematicide that can be mentioned that have：
Acetylcholinesteraseinhibitors inhibitors, such as carbamates, for example, alanycarb (alanycarb), Aldicarb (aldicarb), sulfone goes out prestige (aldoxycarb), allyxycarb (allyxycarb), aminocarb (aminocarb), ficams (bendiocarb), Benfuracard micro (benfuracarb), metalkamate (bufencarb), butacarb (butacarb), butanone Prestige (butocarboxim), butanone sulfone prestige (butoxycarboxim), carbaryl (carbaryl), carbofuran (carbofuran), carbosulfan (carbosulfan), cloethocarb (cloethocarb), dimetilan (dimetilan), second Sulphur benzene prestige (ethiofencarb), Bassa (fenobucarb), fenothiocarb (fenothiocarb), Carzol (formetanate), furathiocarb (furathiocarb), Mobucin (isoprocarb), metham-sodium (metam-sodium), first Sulphur prestige (methiocarb), Methomyl (methomyl), MTMC (metolcarb), oxamyl (oxamyl), Aphox (pirimicarb), Carbamult (promecarb), arprocarb (propoxur), thiodicarb (thiodicarb), thiofanox (thiofanox), Landrin (trimethacarb), XMC and Meobal (xylylcarb)；Or organophosphorus compounds, such as second Acyl acephatemet (acephate), azamethiphos (azamethiphos), azinphos-methyl (azinphos-methyl), ethyl paddy sulphur Phosphorus (azinphos-ethyl), Rilariol (bromophos-ethyl), bromobenzene alkene phosphorus (bromfenvinfos (- Methyl)), special Pyrimitate (butathiofos), cadusafos (cadusafos), carbophenothion (carbophenothion), chlorine oxygen Phosphorus (chlorethoxyfos), chlorfenviphos (chlorfenvinphos), chlormephos (chlormephos), methyl/ethyl poison Dead tick (chlorpyrifos (- methyl/-ethyl)), Resistox (coumaphos), kill at Surecide (cyanofenphos) Snout moth's larva nitrile (cyanophos), chlorfenviphos (chlorfenvinphos), demeton-methyl (demeton-S-methyl), dioxydemeton-s-methyl (demeton-S-methylsulfone), torak (dialifos), basudin (diazinon), dichlofenthion (dichlofenthion), Carbicron (dicrotophos), Rogor (dimethoate), dimethylvinphos (dimethylvinphos), salithion (dioxabenzofos), disulfoton (disulfoton), phenothiazide (EPN), Ethodan (ethion), phonamiphos (ethoprophos), oxygen Diothyl (etrimfos), famphur (famphur), fenamiphos (fenamiphos), fenifrothion (fenitrothion), fensulfothion (fensulfothion), Entex (fenthion), Flupyrazofos, Dyfonate (fonofos), peace fruit (formothion), fosmethilan (fosmethilan), thiazolone phosphorus (fosthiazate), heptenophos (heptenophos), iodfenphos (iodofenphos), different rice blast net (iprobenfos), chlorine Azoles phosphorus (isazofos), isofenphos (isofenphos), O- isopropyl salicylate, oxazolines (isoxathion), malathion (malathion), Afos (mecarbam), methacrifos (methacrifos), acephatemet (methamidophos), methidathion (methidathion), Menite (mevinphos), Azodrin (monocrotophos), 2-dichloroethylk dimethyl phosphate (naled), flolimat (omethoate), oxydemeton_methyl (oxydemeton-methyl), methyl/ethyl parathion (parathion (- methyl/- Ethyl)), phenthoate dimephenthoate cidial (phenthoate), Phosalone (phosalone), phosmet (phosmet), phosphamidon (phosphamidon), the third phosphorus of second prestige (phosphocarb), phoxim (phoxim), Actellic/pirimiphos ethyl (pirimiphos (- methyl/-ethyl)), Profenofos (profenofos), Kayaphos (propaphos), propetamphos (propetamphos), Toyodan (prothiofos), Fac (prothoate), pyraclofos (pyraclofos), pyridazine sulphur Phosphorus (pyridaphenthion), pyridathion, quinalphoses (quinalphos), cadusafos (sebufos), sulfotep (sulfotep), second Toyodan (sulprofos), butyl pyrimidine phosphorus (te bu pi rimf os), Swebate (teme Phos), terbufos (te r buf os), Ravap (tetrachlorvinphos), thiometon (thiometon), Hostathion (triazophos), metrifonate (triclorfon), vamidothion (vamidothion) and imicyafos.
The controlled chloride channel antagonists of GABA, such as organochlorine class, such as toxaphene (camphechlor), Niran (chlordane), 5a,6,9,9a-hexahydro-6,9-methano-2,4 (endosulfan), lindane (gamma-HCH), six six six (HCH), heptachlor (heptachlor), woods Red (lindane) and methoxychlor (methoxychlor)；Or Phenylpyrazole (fiprole) class, such as acetoprole, second Worm nitrile (ethiprole), ethiprole (fipronil), pyrazine ethiprole (pyrafluprole), pyriprole and vaniliprole。
Sodium channel modulators/potential dependent (voltage-dependent) sodium channel blockers (blocker), such as Pyrethroid, such as acrinathrin (acrinathrin), allethrin (d- is cis- anti-, and d- is anti-) (allethrin (d- Cis-trans, d-trans)), β-cyfloxylate (beta-cyfluthrin), Biphenthrin (bifenthrin), biological alkene Third chrysanthemum ester (bioallethrin), bioallethrin-S- cyclopenta isomers, bioethanomethrin, biopermethrin (biopermethrin), bioresmethrin (bioresmethrin), chlovaporthrin, alphamethrin (cis- Cypermethrin), cis resmethrin (cis-resmethrin), cis Permethrin (cis-permethrin), Clocythrin, cycloprothrin (cycloprothrin), cyfloxylate (cyfluthrin), lambda-cyhalothrin (cyhalothrin), cypermethrin (α-, β-, θ-, ζ -) (cypermethrin (alpha-, beta-, theta-, zeta-)), Cyphenothrin (cyphenothrin), decis (deltamethrin), Prallethrin ((1R)-isomers) (empenthrin ((1R)-isomer)), S- fenvalerates (esfenvalerate), ethofenprox (etofenprox), phenyl-pentafluoride Chrysanthemum ester (fenfluthrin), Fenpropathrin (fenpropathrin), fenpyrithrin, fenvalerate (fenvalerate), Flubrocythrinate, flucythrinate (flucythrinate), the third benzyl oxide of fluorine (flufenprox), flumethrin (flumethrin), taufluvalinate (fluvalinate), fubfenprox, gamma-cyhalothrin (gamma- Cyhalothrin), miaow alkynes chrysanthemum ester (imiprothrin), kadethrin (kadethrin), λ-lambda-cyhalothrin (lambda- Cyhalothrin), metofluthrin (metofluthrin), Permethrin (cis/trans) (permethrin (cis-rans)), Phenothrin ((1R)-transisomer) (phenothrin (1R-trans-isomer)), prallethrin (prallethrin), the third Flumethrin (profluthrin), protrifenbute, anti-Chryson (pyresmethrin), benzyl furan Chrysanthemum ester (resmethrin), kadethrin (RU15525), silafluofene (silafluofen), τ-taufluvalinate (tau- Fluvalinate), Tefluthrin (tefluthrin), terallethrin (terallethrin), tetramethrin ((1R)-isomery Body) (tetramethrin (1R)-isomer), tralomethrin (tralomethrin), transfluthrin (transfluthrin), brofluthrinate (ZXI8901), pyrethrin (pyrethrin (pyrethrum)), eflusilanat； DDT；Or methoxychlor (methoxychlor).
Acetyl choline receptor agonists/antagonist, such as chlorine nicotine base class (chloronicotinyls), for example, pyridine worm Amidine (acetamiprid), clothianidin (clothianidin), dinotefuran (dinotefuran), imidacloprid (imidacloprid), imidaclothiz, Nitenpyram (nitenpyram), Nithiazine (nithiazine), thiacloprid (thiacloprid), Diacloden (thiamethoxam), AKD-1022；Or nicotine (nicotine), bensultap (bensultap), cartap (cartap), dimehypo (thiosultap-sodium) and thiocyclam (thiocylam).
Allosteric type acetylcholine receptor modulators (agonist), such as multiple killing teichomycin class (spinosyns), such as more sterilizations Plain (spinosad) and spinetoram.
Chloride channel activators, for example, mectins/ macrolideses, such as avermectin (abamectin), Emma Rhzomorph (emamectin), emaricin benzoate (emamectinbenzoate), Olivomitecidin (ivermectin), Lepimectin and Mir's bud rhzomorph (milbemycin)；Or juvenile hormone mimics (juvenile ), such as hydroprene (hydroprene), kinoprene (kinoprene), methoprene hormoneanalogues (methoprene), young ether (epofenonane), sulphur olefin(e) acid ester (triprene), fenoxycarb (fenoxycarb), Nylar are protected (pyriproxyfen) and luxuriant ether (diofenolan) is disliked.
The unknown or non-specific active ingredient of the mechanism of action, such as gas generating agent, such as bromomethane, chloropicrin (chloropicrin) and vikane (sulfuryl fluoride)；Selective antifeedant, such as ice crystal (cryolite), Pymetrozine (pymetrozine), pyrifluquinazon, flonicamide；Or mite growth inhibitor, such as clofentezine (clofentezine) Hexythiazox (hexythiazox), etoxazole (etoxazole).
Oxidative phosphorylation inhibitors class, ATP agent interferings, such as diafenthiuron (diafenthiuron)；Organo-tin compound, Such as azacyclotin (azocyclotin), plictran (cyhexatin) and fenbutatin oxide (fenbutatin oxide)；Or propargite (propargite), tetradiphon (tetradifon).
The oxidative phosphorylation uncoupler class to be worked by being interrupted H- proton gradients, such as capillary (chlorfenapyr), binapacryl (binapacyrl), enemy completely logical (dinobuton), dinocap (dinocap) and elgetol (DNOC)。
Insect gut membrane micro agent interfering, such as bacillus thuringiensis (Bacillus thuringiensis) bacterium Strain.
Benzoylurea derivertives class, such as benzoyl area kind, such as bistrifluron (bistrifluron), fluorine Pyridine urea (chlofluazuron), diflubenzuron (diflubenzuron), fluorine fluazuron (fluazuron), flucycloxuron (flucycloxuron), flufenoxuron (flufenoxuron), flubenzuron (hexaflumuron), lufenuron (lufenuron), Novaluron (novaluron), noviflumuron (noviflumuron), penfluron (penfluron).
Husking interferon, such as cyromazine (cyromazine).
Ecdysone agonist/agent interfering class, such as diacyl hydrazine, such as ring tebufenozide (chromafenozide), Chlorine tebufenozide (halofenozide), methoxyfenozide (methoxyfenozide), tebufenozide (tebufenozide) and furans Tebufenozide (fufenozide, JS118)；Or nimbin (azadirachtin).
Octopaminergic agonist class, such as Amitraz (amitraz).
Site III electron transfer inhibitors class/site II electron transfer inhibitors classes, such as amdro (hydramethylnone), acequinocyl (acequinocyl), fluacrypyrim (fluacrypyrim)；Or cyflumetofen (cyflumetofen) and cyenopyrafen.
Electron transfer inhibitors class, such as site I electron transfer inhibitors classes, METI acaricides, for example, fenazaquin (fenazaquin), fenpyroximate (fenpyroximate), pyrimidifen (pyrimidifen), pyridaben (pyridaben), pyrrole mite Amine (tebufenpyrad), Tolfenpyrad (tolfenpyrad) and rotenone (rotenone)；Or potential dependent (voltage-dependent) sodium channel blockers, such as indoxacarb (indoxacarb) and metaflumizone (metaflumizone)。
Fatty acid biological synthetic inhibitor, such as tetronic acid (tetronic acid) derivative, such as Envidor (spirodiclofen) and Spiromesifen (spiromesifen)；Or tetramic acid (tetramic acid) derivative, example Such as spiral shell worm ethyl ester (spirotetramat).
The unknown neuron inhibitor of the mechanism of action, such as Bifenazate (bifenazate).
Ryanodine (ryanodine) receptor stimulating agent, such as diamides, such as Flubendiamide (flubendiamide), (R), the chloro- N1- of (S) -3- { 2- methyl -4- [1,2,2,2- tetra- fluoro- 1- (trifluoromethyl) ethyl] phenyl }-N 2- (1- methyl -2- Methysulfonylethyl) phthalic amide, Rynaxypyr (chlorantraniliprole (Rynaxypyr)) or bromine Cyanogen insect amide (Cyantraniliprole (Cyazypyr)).
The unknown active component of other mechanisms of action, such as amidoflumet, benclothiaz, benzoximate, bromine Mite ester (bromopropylate), Buprofezin (buprofezin), quinomethionate (chinomethionat), Spanon (chlorodimeform), chlorfenizon (chlorobenzilate), clothiazoben, cycloprene, dicofol (dicofol), dicyclanil, fenoxacrim, fluorine nitre diphenylamines (fentrifanil), thiazole mite (flubenzimine), Flufenerim, flutenzin, gossyplure (gossyplure), japonilure, metoxadiazone (metoxadiazone), Dormant oil (petroleum), potassium oleate, pyridalyl (pyridalyl), sulfluramid (sulfluramid), Diphenylsulfide (tetrasul), benzene match mite (triarathene) or verbutin.
Compared with prior art, the advantage of the invention is that：
1st, fluazinam and cyflumetofen compound the interior to panonychus citri, tomato Tetranychus cinnabarinus in the range of certain proportion Activity has synergistic function.
2nd, two kinds of active ingredient compoundings of fluazinam and cyflumetofen, reduce Pesticide use amount, reduce use cost, subtract Light pollution to environment has delayed the drug-fast service life for generating, adding pesticide of pest and disease damage.
Specific embodiment
The present invention is illustrated by specific examples below, but the invention is not restricted to specific examples below.At these In embodiment, unless otherwise stated, all percentages are weight percentage.
Embodiment one：(test method refers to NY/ to fluazinam with toxicity measure of the cyflumetofen to tomato Tetranychus cinnabarinus The 12nd part of T 1154.12-2008 farm-chemical indoor determination test rules insecticide：Tetranychid slide infusion process).
1 fluazinam of table is with cyflumetofen to the toxicity measurement result of tomato Tetranychus cinnabarinus
The data result that table 1 is recorded shows fluazinam and cyflumetofen parts by weight ratio 60:1~1:In the range of 60 There is synergistic effect to the activity of tomato Tetranychus cinnabarinus, co-toxicity coefficient is more than 120；Fluazinam and cyflumetofen parts by weight ratio 40:1~1:There is synergistic effect to the activity of tomato Tetranychus cinnabarinus in the range of 40, co-toxicity coefficient is more than 130；Fluazinam and fourth Fluorine mite ester parts by weight ratio is 15:1~1:There is synergistic effect, co-toxicity coefficient to the activity of tomato Tetranychus cinnabarinus in the range of 15 More than 140；Fluazinam and cyflumetofen parts by weight ratio are 4:1~1:Have in the range of 5 to the activity of tomato Tetranychus cinnabarinus Synergistic effect, co-toxicity coefficient are more than 170；Especially fluazinam and cyflumetofen parts by weight ratio is 7:3 pairs of tomato cinnabar leaves The active synergistic effect of mite is preferable, co-toxicity coefficient 213.66；And fluazinam and cyflumetofen parts by weight ratio are 1:70 pairs The activity of tomato Tetranychus cinnabarinus does not have synergistic effect then, and co-toxicity coefficient is less than 120.
Embodiment two：(test method refers to NY/T to fluazinam with toxicity measure of the cyflumetofen to panonychus citri The 12nd part of 1154.12-2008 farm-chemical indoor determination test rules insecticide：Tetranychid slide infusion process).
2 fluazinam of table is with cyflumetofen to the toxicity measurement result of panonychus citri
The data result that table 2 is recorded shows fluazinam and cyflumetofen parts by weight ratio 60:1~1:In the range of 60 There is synergistic effect to the toxicity of panonychus citri, co-toxicity coefficient is more than 140；Fluazinam and cyflumetofen ratio of weight and number Example is 40:1~1:There is synergistic effect to the toxicity of panonychus citri in the range of 40, co-toxicity coefficient is more than 160；Fluazinam With cyflumetofen parts by weight ratio 15:1~1:There is synergistic effect to the toxicity of panonychus citri in the range of 15, altogether Malicious coefficient is more than 170；Fluazinam and cyflumetofen parts by weight ratio are 5:1~1:To the interior of panonychus citri in the range of 1 Activity has synergistic effect, and co-toxicity coefficient is more than 209；And fluazinam and cyflumetofen parts by weight ratio 1:70 pairs of full pawls of citrus The toxicity of mite does not have synergistic effect then, and co-toxicity coefficient is less than 120.
Embodiment three：50% fluazinam cyflumetofen aqueous suspension agent
It is fluazinam 35%, cyflumetofen 15%, EO-PO block polymers 10%, fatty alcohol polyoxyethylene ether 6%, wooden Plain sodium sulfonate 7%, Arabic gum 0.1%, glycerine 5%, deionized water supplies 100%；By above-mentioned active ingredient, wetting agent, Dispersant, antifreezing agent, thickener and antifoaming agent disperse through high speed shear, are sanded in sand mill, the height formed in water-medium Suspension system that is scattered, stablizing, you can 50% fluazinam cyflumetofen suspending agent is made.
Example IV：50% fluazinam cyflumetofen water dispersible granules
Fluazinam 40%, cyflumetofen 10%, sodium lignin sulfonate 10%, glucose 5%, sodium polycarboxylate 3%, sodium chloride 3%, white carbon supply to 100%；Active ingredient and other auxiliary agents are uniformly mixed, crushed with micro jet, through pinching It closes, then adds in fluidized-bed granulation dryer and be granulated, dry, sieve, the moisture that corresponding weight percentage is made dissipates Granula.
Embodiment five：50% fluazinam cyflumetofen aqueous suspension agent, five 50% fluorine of gained of embodiment obtained by example IV Pyridine amine cyflumetofen water dispersible granules prevention panonychus citri, tomato Tetranychus cinnabarinus field control effectiveness test (cauline leaf spray-on process, medicine It investigates within 7 days afterwards)
Table 3 respectively handles chemical control panonychus citri, tomato Tetranychus cinnabarinus field control effectiveness test
Table 3 the result shows that, 50% fluazinam cyflumetofen water dispersible granules, 50% fluazinam cyflumetofen suspending agent 50 mg/kg of effective ingredient consumption is respectively provided with preferable control effect to tomato Tetranychus cinnabarinus, panonychus citri.
Synergetic pesticide composition of the present invention can also be prevented in addition to available for prevention tomato Tetranychus cinnabarinus, panonychus citri Other crops evil mites for example Tetranychus urticae, Mite, blister mite, penthaleus major duges, grain spider mite, bean spider mite, privet mite, Yellow tea mite, pink tea rust mite, congo red mite, panonychus ulmi, citrus beginning tetranychid, leaves of Hawthorn are full, Brennandania lambi, carex fruit mite etc..

Claims (8)

1. a kind of composition pesticide containing cyflumetofen and fluazinam, it is characterised in that：Active ingredient is fluazinam and fourth fluorine The ratio of weight and number of mite ester, fluazinam and cyflumetofen in the composition is 60:1~1:60, fluazinam and cyflumetofen weight The weight percent of summation in the composition is 0.1%-80%.
2. a kind of composition pesticide containing cyflumetofen and fluazinam according to claim 1, it is characterised in that：Fluorine pyridine The ratio of weight and number of amine and cyflumetofen in the composition is 40:1~1:40.
3. a kind of composition pesticide containing cyflumetofen and fluazinam according to claim 1, it is characterised in that：Fluorine pyridine The ratio of weight and number of amine and cyflumetofen in the composition is 15:1~1:15.
4. a kind of composition pesticide containing cyflumetofen and fluazinam according to claim 1, it is characterised in that：Fluorine pyridine The ratio of weight and number of amine and cyflumetofen in the composition is 4:1.
5. a kind of composition pesticide containing cyflumetofen and fluazinam according to claim 1, it is characterised in that：Fluorine pyridine The ratio of weight and number of amine and cyflumetofen in the composition is 7:3.
6. a kind of composition pesticide containing cyflumetofen and fluazinam according to claim 1, it is characterised in that：It Dosage form is one kind in aqueous suspension agent, water dispersible granules.
7. a kind of composition pesticide containing cyflumetofen and fluazinam according to claim 1, which is characterized in that prepare During into aqueous suspension agent, each component weight percent is：Fluazinam 35%, cyflumetofen 15%, EO-PO block polymers 10%, Fatty alcohol polyoxyethylene ether 6%, sodium lignin sulfonate 7%, Arabic gum 0.1%, glycerine 5%, deionized water is supplied 100%.
8. a kind of composition pesticide containing cyflumetofen and fluazinam described in claim 1 prevention tomato Tetranychus cinnabarinus, Application on panonychus citri.
CN201711300451.7A 2017-12-10 2017-12-10 A kind of composition pesticide containing cyflumetofen and fluazinam Withdrawn CN108041042A (en)

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CN103283742A (en) * 2012-02-23 2013-09-11 深圳诺普信农化股份有限公司 Acaricidal pesticide composition
CN105010370A (en) * 2015-07-31 2015-11-04 京博农化科技股份有限公司 Acaricidal composition containing fluazinam and bifenazate
CN107006482A (en) * 2017-04-14 2017-08-04 广东中迅农科股份有限公司 A kind of composition of containing fluazinam, pyridaben

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CN102113488A (en) * 2010-12-30 2011-07-06 青岛泰生生物科技有限公司 Cyflumetofen-containing insecticidal/acaricidal composition
CN103283742A (en) * 2012-02-23 2013-09-11 深圳诺普信农化股份有限公司 Acaricidal pesticide composition
CN102626101A (en) * 2012-03-31 2012-08-08 陕西韦尔奇作物保护有限公司 Efficient insecticidal composition containing cyflumetofen
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WO2022166842A1 (en) * 2021-02-07 2022-08-11 山东康乔生物科技有限公司 Composition comprising benzylamine acaricide and use thereof

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