CN108041061A - A kind of miticide composition containing diflubenzuron and second azoles mite nitrile - Google Patents
A kind of miticide composition containing diflubenzuron and second azoles mite nitrile Download PDFInfo
- Publication number
- CN108041061A CN108041061A CN201711300443.2A CN201711300443A CN108041061A CN 108041061 A CN108041061 A CN 108041061A CN 201711300443 A CN201711300443 A CN 201711300443A CN 108041061 A CN108041061 A CN 108041061A
- Authority
- CN
- China
- Prior art keywords
- diflubenzuron
- azoles mite
- mite nitrile
- composition containing
- azoles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of miticide composition containing diflubenzuron and second azoles mite nitrile, effective ingredient is made of diflubenzuron, second azoles mite nitrile, and composition also includes auxiliary component；The ratio of weight and number of diflubenzuron and second azoles mite nitrile is 20:1~1:20, the weight percent content of both diflubenzuron and second azoles mite nitrile accumulation is between 1% 80%.The present invention is harmful to mite class etc. for preventing pest agriculturally, particularly for prevention crops.
Description
Technical field
The present invention relates to composition pesticide and its application technologies, specifically effective ingredient diflubenzuron and second azoles mite nitrile group
It closes, for the prevention of agricultural pest.
Background technology
Information system of crop pest distribution in China improvement is one of agricultural production important step, is the emphasis class of agricultural science and technology worker concern
Topic.With the continuity year in year out, the increase of Pesticide use amount and not scientifical use that prevent harmful organism chemicals
The influence of the factors such as pesticide causes pest and disease damage resistance getting worse, generates the pest of resistance, germ species is on the increase.Meanwhile
Pesticide is used due to high intensity, causes a series of social concerns such as exceeded, the pollution environment of Practice for Pesticide Residue in Agricultural Products, is unfavorable for agriculture
The sustainable development of industry.
Diflubenzuron inhibits the synthesis of the chitin synthetase of insect, prevents insect lopsided and dead from the polypide that normally casts off a skin.
Second azoles mite nitrile inhibits amber dehydrogenase, acts on the complex II of respiratory electron transport chain, failure energy synthesis.
For the using effect of enhancing diflubenzuron, second azoles mite nitrile, extend the lasting period, prevent it is long-term, largely using above-mentioned single
Medicament and target life is caused to survey resistance generation, the present inventor furthers investigate diflubenzuron and second azoles mite nitrile, finds two
Kind medicament mixture in the range of certain proportion has notable synergistic effect, expands prevention spectrum, while is also beneficial to reduction medicament
Usage amount reduces spray number, delays the generation of target resistance.After further study, the present invention is completed.
The content of the invention
The present invention provides a kind of effective ingredient as diflubenzuron and the miticide composition of second azoles mite nitrile, and composition has significant
Synergistic function extends the lasting period, improves using effect, reduces dosage, reduces residual quantity of the pesticide on crops, delays
The generation of Pest-resistant.
Another object of the present invention is using combinations of the above object, is equipped with auxiliary agent known to a person skilled in the art,
The dosage form of the present invention can be made in method known to a person skilled in the art, prevented applied to the harmful mite class of agricultural.
Technical scheme：A kind of miticide composition containing diflubenzuron and second azoles mite nitrile, effective ingredient is by deinsectization
The ratio of weight and number of urea and second azoles mite nitrile composition, diflubenzuron and second azoles mite nitrile is 20:1~1:20, diflubenzuron and second azoles mite nitrile two
The weight percent content of person's accumulation is between 1%-80%.
The preferred weight portion rate of diflubenzuron and second azoles mite nitrile is 5:1~1:5.
The further preferred ratio of weight and number of diflubenzuron and second azoles mite nitrile is 1:1.
The miticide composition of the present invention, in addition to effective ingredient diflubenzuron, second azoles mite nitrile, further includes auxiliary agent, to be configured to agriculture
Pharmaceutically dosage form.The miticide composition of the present invention is made in practical application including suspending agent, dispersible oil-suspending agent, wettable powder
Agent, the dosage form of water dispersible granules.
The auxiliary component is solvent, emulsifier, wetting agent, dispersant, stabilizer, antifreezing agent, thickener, disintegration
The combination of one or more of agent, binding agent, antifoaming agent, bleeding agent, synergist, fire retardant and filler, more than substance are
Common known substance in pesticidal preparations.
Solvent can be solvent naphtha S-200, trimethylbenzene, durene, methyl naphthalene, methyl oleate, fatty acid methyl ester, Song Ji
The group of one or more of oil, soybean oil, biodiesel, sec-Butyl Acetate, dimethyl carbonate, diesel oil, white oil, machine oil etc.
It closes.
Emulsifier can be that calcium dodecyl benzene sulfonate, fatty alcohol polyoxyethylene ether, triphenoethyl benzene phenol polyoxypropylene gather
Ethylene oxide block polymer, dibenzyl xenyl polyoxyethylene ether, phenethyl phenol polyethenoxy ether, castor oil polyoxyethylene ether,
Phenethyl phenol formaldehyde resin polyoxyethylene ether, phenethyl phenol polyoxyethylene polyoxypropylene ether, alkylaryl polyoxypropylene polyoxy
Vinethene, phenethyl phenol formaldehyde resin polyoxyethylene ether, Sorbitan aliphatic ester, sorbitan fatty acid ester polyoxy second
In alkene ether, natural fatty alcohol and ethylene oxide adduct, aliphatic acid and ethylene oxide condensate, polyoxyethylene fatty acid ester etc.
One or more of combinations.
Wetting agent can be sodium butylnaphthalenesulfonate, lauryl sodium sulfate, aliphatic alcohol polyethenoxy (6-7) ether, sulfonation amber
The combination of one or more of amber dioctyl phthalate sodium salt, Morwet EFW, alkylnaphthalene sulfonate etc..
Disintegrant can be compound sodium nitrophenolate, sodium acid carbonate, magnesium chloride, aluminium chloride, sodium chloride, urea, ammonium sulfate, bentonite
Deng one or more of combination.
Dispersant can be polycarboxylate, the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium lignin sulfonate, lignin sulfonic acid
Calcium, sodium lignin sulfonate, naphthalene sulfonic acid condensate sodium salt, alkylnaphthalene to methoxyl group fatty acyl anilinesulfonic acid, desugar and classification
The combination of one or more of sulfonic acid condensation polymer sodium salt, APES formaldehyde condensation product sulfuric acid etc..
Thickener can be one or more of xanthans, aluminium-magnesium silicate, bentonite, white carbon etc..
PH adjusting agent can be in ammonium hydroxide, potassium hydroxide, sodium hydroxide, hydrochloric acid, acetic acid, citric acid, phosphoric acid etc.
One or more of combinations.
Stabilizer can be dibutyl phthalate, hexamethylene diisocyanate, epoxidized soybean oil, epoxy chloropropionate
One or more of alkane, butylated hydroxy anisole, dibutyl hydroxy toluene, propylgallate, tert-butylhydroquinone etc.
Combination.
Antifoaming agent can be the combination of one or more of silicone compound, methanol, silicone oil, azone etc..
Antifreezing agent can be combinations one or more of in glycerine, ethylene glycol, propylene glycol, sorbierite, polyethylene glycol etc..
Sustained release agent can be the combination of one or both of polyvinyl alcohol, Arabic gum.
Binding agent can be the combination of one or both of polyethylene glycol, industrial gelatine.
Carrier can be kaolin, diatomite, bentonite, white carbon, precipitated calcium carbonate, attapulgite, clay, talcum
The combination of one or more of powder, quartz sand, starch, alkyl polyglycoside, urea, potassium chloride, ammonium chloride etc..
The frequency of administration and method of administration of the present composition change with crops, pest, weather condition and have small quantitative change
Change, can achieve the purpose that effectively to prevent by using appropriate adjustment.
Compared with prior art, the advantage of the invention is that：
1st, synergistic function improves using effect, extends the matter effect phase；
2nd, target resistance is delayed to generate, ensures using effect, extend the service life of compound；
3rd, compound usage amount is reduced, the pollution to environment is alleviated, reduces use cost.
Specific embodiment
To better understand the essence of the present invention, present disclosure is described further with reference to embodiment,
But limitation of the present invention cannot be considered as.
Embodiment 1：Indoor biological toxicity test is tested
Test method：With reference to《Farm-chemical indoor determination test rule NY/T1154.7-2006》, using drop method.
Statistical analysis is carried out with DPS statistical analysis softwares, calculates the EC of each medicament50, and mixture is calculated according to the abundant methods of Sun Yun
Co-toxicity coefficient (CTC values), co-toxicity coefficient (CTC) >=120 shows as synergistic effect；Co-toxicity coefficient (CTC)≤80 shows as short of money
Anti- effect；80 ＜ co-toxicity coefficients (CTC) ＜ 120 show as summation action.
(1) red spider is measured into mite synergy
As it can be seen from table 1 diflubenzuron, second azoles mite nitrile have greater activity, diflubenzuron, second azoles mite nitrile to citrus red mite
Portfolio ratio 20:1~1:20 co-toxicity coefficients (CTC) are all higher than 120, show synergistic function, especially ratio 4:1 synergy
Coefficient highest.
1 diflubenzuron of table, second azoles mite nitrile and combinations thereof are to the indoor joint toxicity measuring result of red spider
(2) blister mite synergy is measured
From table 2 it can be seen that diflubenzuron, second azoles mite nitrile have blister mite greater activity, diflubenzuron, the combination of second azoles mite nitrile
Ratio 20:1~1:20 co-toxicity coefficients (CTC) are all higher than 120, show synergistic function, especially ratio 1:1 coefficient of synergism
Highest.
2 diflubenzuron of table, second azoles mite nitrile and combinations thereof are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
(3) Tetranychus cinnabarinus synergy is measured
From table 3 it can be seen that diflubenzuron, second azoles mite nitrile have greater activity, diflubenzuron, second azoles mite to citrus red mite ovum
Nitrile portfolio ratio 20:1~1:20 co-toxicity coefficients (CTC) are all higher than 120, show synergistic function, especially ratio 1:1 increases
Imitate coefficient highest.
3 diflubenzuron of table, second azoles mite nitrile and combinations thereof are to the indoor joint toxicity measuring result of Tetranychus cinnabarinus
(4) diflubenzuron, second azoles mite nitrile and combinations thereof are to red spider resistant determination
For the 50%-80% lethal doses of red spider, the test worm that leaves continues in captive breeding the concentration that test medicine uses,
So 10 generation test worms are handled repeatedly.If the liquid processing containing only auxiliary agent is blank control.Measure each medicament to 1st generation, the 5th generation and
The half lethal concentration LC of 10th generation test worm50, by comparing LC of each treatment agent to 1st generation, the 5th generation and the 10th generation test worm50Come
Test worm is evaluated to change the resistance to the action of a drug of reagent agent.
As can be seen from Table 5, diflubenzuron, second azoles mite nitrile and combinations thereof continuous processing 10 generation red spider, red spider is to combination
The resistance to the action of a drug of medicament is significantly lower than the resistance to the action of a drug that diflubenzuron, second azoles mite nitrile single dose generate.Experiments have shown that diflubenzuron and second azoles mite nitrile
Combination effectively delays red spider resistance to generate.
5 red spider of table is to the resistance indoor measurement result of diflubenzuron, second azoles mite nitrile and combinations thereof
Embodiment 2：Example of formulations
Effective ingredient is using diflubenzuron active compound, second azoles mite nitrile active compound, each component percentage composition in following examples
Roll over hundred contents.
(1) 30% diflubenzuron second azoles mite nitrile suspending agent technical recipe and its application.
Diflubenzuron 15%, second azoles mite nitrile 15%, sodium alkyl sulfonate 6%, calcium dodecyl benzene sulfonate 5%, fatty alcohol polyoxy
Vinethene 3%, aluminum magnesium silicate 0.3%, gum arabic 0.5%, pull open powder 3%, propylene glycol 2%, methanol 3%, deionized water
Supply 100%.Above-mentioned material is mixed, disperses through high speed shear, be sanded in sand mill, the high score formed in water-medium
The suspension system for dissipating, stablizing, you can 30% diflubenzuron second azoles mite nitrile suspending agent is made.
10 days, 20 days, 30 days effects after prevention European red mite medicine：30% diflubenzuron second azoles mite nitrile suspending agent uses
2000 times of preventive effects 96.06%, 95.02%, 83.47%；30% diflubenzuron suspension of comparison medicament uses 2000 times of preventive effects
83.04%th, 87.53%, 72.05%；30% second azoles mite nitrile suspending agent of comparison medicament using 2000 times of preventive effects 87.12%,
85.84%th, 77.04%.Each treatment agent has no adverse effects to Apple safety.
The dispersible oil-suspending agent technical recipe of (2) 21% diflubenzuron second azoles mite nitriles and its application.
Diflubenzuron 1%, second azoles mite nitrile 20%, Nongru-700 #10%, sodium lignin sulfonate 4%, white carbon 2%, organic bentonite
Profit soil 2%, glycerine 1.5%, rapeseed oil supplies 100%.Above-mentioned material is mixed in proportion, be uniformly dispersed through high speed shear,
After being sanded in sand mill, you can the 21% dispersible oil-suspending agent of diflubenzuron second azoles mite nitrile is made.
3 days after field control citrus blister mite medicine, 10 days, 20 days effects：The 21% dispersible oil of diflubenzuron second azoles mite nitrile
Suspending agent uses 3000 times of preventive effects 93.71%, 90.03%, 85.28%；The dispersible oil-suspending agent of 21% diflubenzuron of comparison medicament
Use 3000 times of preventive effects 86.02%, 81.40%, 78.15%；The 21% dispersible oil-suspending agent of second azoles mite nitrile is anti-using 3000 times
Effect 76.25%, 79.13%, 72.24%.Each treatment agent has no adverse effects to citrus safety.
(3) 60% diflubenzuron second azoles mite nitrile water dispersible granules and its application.
Diflubenzuron 40%, second azoles mite nitrile 20%, neopelex 4%, viscous powder 2%, polyoxyethylene polyoxypropylene
Base ether block copolymers 3%, polyvinylpyrrolidone 4%, naphthalene sulfonate 2%, precipitated calcium carbonate supplies 100%.By above-mentioned object
Material mixes in proportion, after air-flow crushing is uniformly mixed, mediates granulation, dry screening, you can 60% diflubenzuron second azoles is made
Mite nitrile water dispersible granules.
5 days after field control eggplant Tetranychus cinnabarinus medicine, 10 days, 20 days effects：60% diflubenzuron second azoles mite nitrile moisture dissipates
30 grams/acre of preventive effects of granula dosage 94.13%, 91.58%, 74.66%；60% 30 grams/acre of diflubenzuron water dispersible granules dosage is anti-
Effect 86.30%, 82.83%, 61.29%；60% 30 grams/acre of preventive effects 88.07% of second azoles mite nitrile water dispersible granules dosage,
80.51%th, 63.24%.Each treatment agent has no adverse effects to eggplant safety.
Claims (9)
1. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile, it is characterised in that：Effective ingredient is by diflubenzuron and second azoles
Mite nitrile forms, and the ratio of weight and number of diflubenzuron and second azoles mite nitrile is 20:1~1:20, the accumulation of both diflubenzuron and second azoles mite nitrile
Weight percent content is between 1%-80%.
2. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile according to claim 1, it is characterised in that：Deinsectization
The ratio of weight and number of urea and second azoles mite nitrile is 5:1~1:5.
3. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile according to claim 1, it is characterised in that：Deinsectization
The ratio of weight and number of urea and second azoles mite nitrile is 1:1.
4. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile according to claim 1, it is characterised in that：In reality
Border apply when be made including suspending agent, dispersible oil-suspending agent, wettable powder, water dispersible granules dosage form.
5. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile according to claim 1, which is characterized in that work as group
When conjunction agent type is suspending agent, the weight percent of each component is：Diflubenzuron 15%, second azoles mite nitrile 15%, sodium alkyl sulfonate
6%, calcium dodecyl benzene sulfonate 5%, fatty alcohol polyoxyethylene ether 3%, aluminum magnesium silicate 0.3%, gum arabic 0.5%, drawing
Powder 3% is opened, propylene glycol 2%, methanol 3%, deionized water supplies 100%.
6. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile according to claim 1, which is characterized in that work as group
When conjunction agent type is water dispersible granules, the weight percent of each component is：Diflubenzuron 40%, second azoles mite nitrile 20%, dodecyl
Benzene sulfonic acid sodium salt 4%, viscous powder 2%, polyoxyethylene polyoxypropylene base ether block copolymers 3%, polyvinylpyrrolidone 4%, naphthalene sulphur
Hydrochlorate 2%, precipitated calcium carbonate supplies 100%.
7. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile according to claim 1, which is characterized in that work as group
When conjunction agent type is dispersible oil-suspending agent, the weight percent of each component is：Diflubenzuron 1%, second azoles mite nitrile 20%, agriculture breast
700#10%, sodium lignin sulfonate 4%, white carbon 2%, organobentonite 2%, glycerine 1.5%, rapeseed oil supplies 100%.
8. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile described in claim 1 should prevention crops mite class
With.
9. a kind of miticide composition containing diflubenzuron and second azoles mite nitrile according to claim 8 is in prevention crops mite class
Application, it is characterised in that the crops mite class is red spider, blister mite and Tetranychus cinnabarinus.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711300443.2A CN108041061A (en) | 2017-12-10 | 2017-12-10 | A kind of miticide composition containing diflubenzuron and second azoles mite nitrile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711300443.2A CN108041061A (en) | 2017-12-10 | 2017-12-10 | A kind of miticide composition containing diflubenzuron and second azoles mite nitrile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108041061A true CN108041061A (en) | 2018-05-18 |
Family
ID=62122927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711300443.2A Pending CN108041061A (en) | 2017-12-10 | 2017-12-10 | A kind of miticide composition containing diflubenzuron and second azoles mite nitrile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108041061A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113647400A (en) * | 2021-08-31 | 2021-11-16 | 广东中迅农科股份有限公司 | Acaricidal composition and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104663692A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing insect growth regulator insecticide |
| CN106614677A (en) * | 2015-10-30 | 2017-05-10 | 陕西韦尔奇作物保护有限公司 | Insecticidal pesticide composition containing SYP-9625 |
| CN106818808A (en) * | 2017-02-15 | 2017-06-13 | 海南省植物保护总站（海南省农药检定所） | Pesticidal combination containing second azoles mite nitrile and diafenthiuron |
-
2017
- 2017-12-10 CN CN201711300443.2A patent/CN108041061A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104663692A (en) * | 2013-11-26 | 2015-06-03 | 中国中化股份有限公司 | Insecticidal and acaricidal composition containing insect growth regulator insecticide |
| CN106614677A (en) * | 2015-10-30 | 2017-05-10 | 陕西韦尔奇作物保护有限公司 | Insecticidal pesticide composition containing SYP-9625 |
| CN106818808A (en) * | 2017-02-15 | 2017-06-13 | 海南省植物保护总站（海南省农药检定所） | Pesticidal combination containing second azoles mite nitrile and diafenthiuron |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113647400A (en) * | 2021-08-31 | 2021-11-16 | 广东中迅农科股份有限公司 | Acaricidal composition and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105191946B (en) | Bactericidal composition and its application | |
| CN104663679B (en) | A kind of insecticide acaricide composition containing macrolide insecticide | |
| CN101690480B (en) | Pesticide composition containing strobilurin fungicide and application thereof | |
| CN104255750A (en) | Herbicide composition containing pyraclonil and pretilachlor | |
| CN103271049A (en) | Pyraclostrobin-fluazinam pesticide composition | |
| CN105010358B (en) | Bactericidal composition and application thereof | |
| CN105211075B (en) | Bactericidal composition and its application | |
| CN104488943A (en) | Insecticidal composition | |
| CN108041061A (en) | A kind of miticide composition containing diflubenzuron and second azoles mite nitrile | |
| CN104757006A (en) | Pesticide composition containing trifluzamide | |
| CN104285956B (en) | A kind of composition pesticide containing Fluoxastrobin and propamidine | |
| CN102217638A (en) | Pesticide composition for preventing and treating plant virus diseases | |
| CN106305751B (en) | A kind of composition pesticide | |
| CN109964948A (en) | A kind of Pesticidal combination | |
| CN104472484B (en) | A kind of bactericidal composition containing eugenol and propamidine | |
| CN104365633B (en) | A kind of composition pesticide and application thereof preventing and treating the mould defoliation of bamboo grows rod spore | |
| CN108013044A (en) | A kind of composition pesticide containing fluazinam and second azoles mite nitrile | |
| CN107047563A (en) | A kind of bactericidal composition for preventing and treating Zizyphus maurtiana powdery mildew | |
| CN104542648A (en) | Sterilization composition and application thereof | |
| CN106342833B (en) | A kind of bactericidal composition containing fluoxastrobin and Osthole | |
| CN104285989A (en) | Pesticide composition containing pyraclostrobin and propamidine | |
| CN104886075B (en) | Bactericidal composition containing amisulbrom and organic copper class compound | |
| CN105685057B (en) | A kind of bactericidal composition containing Tebuconazole and sym-closene | |
| CN102726413A (en) | Mite-killing pesticide composition containing pyridaben and fenpyroximate | |
| CN108496985A (en) | A kind of agricultural chemical composition for disinsection of prevention rice grub |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180518 |