CN106689148A - Pesticide composition containing dichloroxazole and dimethomorph - Google Patents
Pesticide composition containing dichloroxazole and dimethomorph Download PDFInfo
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- CN106689148A CN106689148A CN201611231255.4A CN201611231255A CN106689148A CN 106689148 A CN106689148 A CN 106689148A CN 201611231255 A CN201611231255 A CN 201611231255A CN 106689148 A CN106689148 A CN 106689148A
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- dimethomorph
- bacterium azoles
- composition
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- evil bacterium
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention relates to a pesticide composition containing dichloroxazole and dimethomorph. The weight ratio of the two effective ingredients is (1-90):(90-1), the weight percentage of the effective ingredients in the bactericide is 5-80% and preferably 10-70%, and the balance is auxiliaries and carriers allowed in pesticides. The composition has an obvious synergism effect, the pesticide use amount can be reduced, and the pesticide composition is environmentally friendly and safe.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to be a kind of Evil bacterium azoles of Lv containing Er and dimethomorph agricultural chemicals group
Compound.
Background technology
Er Lv Evil bacterium azoles is the Yi Zhong oxazole sulfone series bactericidal agents found by Guizhou University.Sulfone compound is because with wide spectrum life
Thing activity and cause concern of the people to it, especially sulfone group is incorporated into a variety of compound structures, by knot
Structure modification can produce a series of compounds with broad-spectrum biological activity so that it has given play in novel super-high effect pesticides discovery
More and more important effect.
Dimethomorph be it is single-minded kill Oomycete fungal bactericide, its action character be destroy cell envelope formation, to ovum
There is effect in each stage of the bacterium history of life, particularly sensitive in the formation stages of sporangiophore and egg spore, at much lower concentrations
(<0.25 μ g/ml) it is to be suppressed.Vegetable downy mildew, epidemic disease, seedling sudden fall ill, tobacco black shank etc. are widely used in by flagellum
The disease control that bacterium subphylum Oomycete fungal causes, has systemic activity.Exclusive use have comparing resistance risk high, so often with
The protective fungicide compounding use such as Mancozeb, with the generation of delaying drug resistance.
Downy mildew is a kind of worldwide disease generally occurred on many important crops.Particularly on the south ground in this year
Area, downy mildew allows many friends peasant and means of agricultural production dealer's headache, also causes irremediable huge to agricultural production
Loss.Downy mildew is by the microbial plant disease of downy mildew in fungi.Downy mildew is obligate parasite, and some downy mildews may be used
Artificial culture, such as cause the standing grain of the downy mildew of millet to be given birth to and refer to stalk Peronospora parasitic that is mould, causing Chinese cabbage downy mildew all yes.It is common
Downy mildew have Chinese cabbage downy mildew, cucumber downy mildew, downy mildew of garpe, water melon frost mildew.
For this inventor specially solves downy mildew this great problem, inventor is found by experiment that, the mechanism of action is different
Dimethomorph and Er Lv Evil bacterium azoles prevent and treat the bactericide compounded of downy mildew class disease, have significant synergies, can significantly
Improve treatment, the prevention effect of protection, cost accounting reduced, to crop safety.
The content of the invention
The purpose of the present invention is to propose to a kind of with synergistic function, the Evil bacterium of Lv containing Er that use cost is low, preventive effect is good
The composition pesticide of azoles and dimethomorph.
The present invention is to be achieved through the following technical solutions:
The mass percent of effective active composition Er Lv Evil bacterium azoles and dimethomorph is 1- in composition pesticide preparation of the invention
90:90-1, there is different degrees of synergistic effect in this proportion.After enhancing proportions scope substantially is determined, we
Proportion is reduced again, and emphasis has done the proportioning test screening of some a small ranges, on the basis of specific aim formula test,
The quality percentage of effective active composition Er Lv Evil bacterium azoles and dimethomorph can be more preferably 5-70 by we:75-50.
In composition pesticide preparation of the invention the weight percentage of active component be 1-90%, preferably 20-50%, its
The remaining auxiliary element in Pesticide formulation.
The purpose of the present invention is to solve the shortcomings of the prior art, there is provided rationally, synergistic effect is significantly, sterilized for a kind of component
Effect is good, and drug cost is low to be not likely to produce the resistance to the action of a drug, the agricultural bactericidal composition to crop safety；Another object of the present invention exists
In the bactericidal composition described in offer as the application for preventing and treating downy mildew, epidemic disease, medicine of dampinging off.
Above-mentioned bactericidal composition is re-dubbed the formulation allowed on agricultural chemicals with known auxiliary agent and excipient.It for example can be breast
Oil, in wettable powder, suspending agent, aqueous emulsion, water dispersible granules, microemulsion any one.
Composition pesticide of the present invention has obvious sterilization synergistic effect, compared with prior art, can effectively solve alkene
The resistance problem of morpholide, and the bactericidal activity of Er Lv Evil bacterium azoles is improve, the lasting effect of Er Lv Evil bacterium azoles is enhanced, delay
Disease produces the speed of resistance to two kinds of medicines, extends the Er Lv Evil bacterium azoles product life-span commercially, reduces effectively
Ingredient Amount and repeatedly times for spraying, reduce agricultural cost, delay the generation of pest resistance to insecticide, reduce residues of pesticides, subtract
The light pollution to environment, to more environment-friendly.
Specific embodiment
The present invention is further described with reference to specific embodiment, so that those skilled in the art knows more about
The present invention, but and it is not so limited the present invention.
The method that the present invention is combined using indoor bioassay and field test.Unless otherwise instructed, ratio mentioned below
Example (including percentage) is all mass ratio.It should be pointed out that it is all done within the spirit and principles in the present invention any repair
Change, equivalent and improvement etc., should be included within the scope of the present invention.
Different crop, it is adaptable to which the different formulations of pesticide, the researcher of this formulations of pesticide technical field can be made into phase
The formulations of pesticide of adaptation, its simple component and implementation method are as follows:
The Er Lv Evil bacterium azoles of example of formulations one 40% and dimethomorph suspending agent
Er Lv Evil bacterium azoles 10g, dimethomorph 30g, alkylphenol-polyethenoxy base ether phosphate 8g, polyethylene glycol 4g, Magnesiumaluminumsilicate
10g, silicone oil 2g, water surplus complement to 100g, and other auxiliary agents are mixed, well mixed through high speed shear, add Er Lv Evil bacterium azoles
And dimethomorph, abrading-ball 2-3 hours in ball crusher, make a diameter below 3 microns, 40% Er Lv Evil bacterium azoles and alkene is obtained
Morpholide suspending agent.
The Er Lv Evil bacterium azoles dimethomorph water dispersion granulas of example of formulations 2 49%
Er Lv Evil bacterium azoles 14g, dimethomorph 35g, TERSPERSE 2700 11g, spaonin powder 9g, citric acid 3g, white carbon 28g.
Er Lv Evil bacterium azoles and dimethomorph and dispersant, wetting agent, disintegrant and filler are well mixed, micro jet is used
Crush, through mediating, be subsequently adding in fluidized-bed granulation dryer granulated, dried, sieve after through sampling analysis, prepared 49%
Er Lv Evil bacterium azoles dimethomorph water dispersion granulas.
The Er Lv Evil bacterium azoles dimethomorph missible oil of example of formulations 3 25%
Er Lv Evil bacterium azoles 20g, dimethomorph 5g, calcium dodecyl benzene sulfonate 6g, aliphatic acid polyethenoxy ether 5g, toluene, diformazan
Benzene supplies 100g.Two enough chlorine Evil bacterium azoles and dimethomorph are dissolved in a solvent according to formula rate, adds surface-active
Agent (being used after heating for dissolving if necessary) and other components, are uniformly mixed and 25% Er Lv Evil bacterium azoles dimethomorphs are obtained
Missible oil.
The Er Lv Evil bacterium azoles dimethomorph wettable powders of example of formulations 4 55%
Er Lv Evil bacterium azoles 50g, dimethomorph 5g, alkylphenol-polyethenoxy base ether sulfonic acid ester 14g, lauryl sodium sulfate 7g are swollen
Profit soil 24g, by above-mentioned formula by Er Lv Evil bacterium azoles and dimethomorph and alkylphenol-polyethenoxy base ether sulfonic acid ester, dodecyl
Sodium sulphate and bentonite mix, the uniform stirring in stirred tank, well mixed after airslide disintegrating mill, you can be made 55% 2
The wettable powder of Lv Evil bacterium azoles dimethomorphs.
The Er Lv Evil bacterium azoles dimethomorph aqueous emulsions of example of formulations 5 21%
Er Lv Evil bacterium azoles 20g, dimethomorph 1g, polyoxyethylene aliphatic alcohol ether 7g, methyl oleate 20g, ethylene glycol 3g, silicone oil 1g,
Xanthans 6g, water complements to 100g.The method input mixing kettle high speed that above raw material routinely prepares aqueous emulsion is mixed, system
Into 21% Er Lv Evil bacterium azoles dimethomorph aqueous emulsions.
The Er Lv Evil bacterium azoles dimethomorph wettable powders of example of formulations 6 54%
Er Lv Evil bacterium azoles 9g, dimethomorph 45g, lauryl sodium sulfate 8g, dispersing agent NNO 10g, white carbon 5g, kaolin add
To 100g, other auxiliary agents are mixed, it is well mixed through high speed shear, Er Lv Evil bacterium azoles and dimethomorph are added, in ball crusher
Abrading-ball 2-3 hours, make a diameter below 3 microns, 54% Er Lv Evil bacterium azoles dimethomorph wettable powders are obtained.
The Er Lv Evil bacterium azoles dimethomorph aqueous emulsions of example of formulations 7 33%
Er Lv Evil bacterium azoles 3g, dimethomorph 30g, phenethyl phenol polyethenoxy ether phosphate 12g, rapeseed oil 23g, polyethylene glycol
4g, gelatin 2g, add water to 100g.The method input mixing kettle high speed that above raw material routinely prepares aqueous emulsion is mixed, system
Into 33% Er Lv Evil bacterium azoles dimethomorph aqueous emulsions.
The Er Lv Evil bacterium azoles micellar emulsion of dimethomorph of example of formulations 8 42%
Er Lv Evil bacterium azoles 2g, dimethomorph 40g, phenethyl phenol polyethenoxy ether phosphate 3g, phenethyl phenol formaldehyde resin polyoxy
Ethylether 16g, isopropanol l0g, rape-seed oil methyl ester 17g add water to 100g.Above raw material is routinely prepared the side of microemulsion
Mix in method input mixing kettle, be made 42% Er Lv Evil bacterium azoles micellar emulsion of dimethomorph.
2nd, it is raw to survey embodiment
1st, the Toxicity Determination of test example preventing and treating cucumber downy mildew and field efficacy test
1.1 Toxicity Determinations
Definite virulence of the mixture to cucumber downy mildew is combined with two chlorine Evil bacterium azoles in order to understand dimethomorph, the present invention matches somebody with somebody for it
Than being screened.
Subjects:Cucumber downy mildew
Test site：Near the Bai Shi industrial areas of Fushan City, Guangdong Province Gaoming District Geng He towns
Test method:
Acetone solution active compound is first used, two appropriate active compounds are made into several different ratios by the result according to preliminary experiment, then are used
It is stand-by that each treatment is diluted to several concentration gradients by acetone respectively.
By susceptible cucumber cultivation in pot for growing seedlings, it is placed in greenhouse and cultivates, after plant to be planted grows to three to four leaf stage, gathers phase
With the blade of leaf age, culture and measure for cucumber downy mildew germ.
Cucumber downy mildew germ is using plants method 20oCultivated under conditions of C, 12h alternation of light and darkness, generation is turned per 30d
Culture 1 time.With the conidium on aseptic water elution incidence of leaf during inoculation, it is 1 × 10 to be configured to spore concentration6Individual/mL's
Spore suspension.
Toxicity test is carried out using leaf dish moisturizing method.The blade of collection is first prepared into the leaf dish of a diameter of 1.5cm, at random
Mix, be respectively placed in the series concentration liquid for configure and soak 1h, 50 leaf dishes of each concentration, experiment is with the place of not adding medicine
It is blank to manage, and after immersion terminates, leaf is face-up placed on the blotting paper of identical liquor strength wetting, in leaf dish
Liquid blot, the spore suspension that will be prepared be inoculated in leaf dish center, room temperature place 5min after, be placed in 20oC, 12h brightness
Cultivated under the conditions of alternate, the onset area in leaf dish is measured after l0d, calculate prevention effect.
Inhibiting rate is calculated according to the following equation, and calculates that each chemicals treatment to virulence is returned by DPS Software of Data Statistics
Return equation, coefficient correlation, EC50And compounding co-toxicity coefficient.Mycelial growth rate method is used indoors, determines different agents to bacterium
The EC of strain50, using co-toxicity coefficient computational methods, calculate the co-toxicity coefficient of mixture（CTC）, determine the building performance of mixture, specifically
Computational methods are as follows：
With in mixture certain-single dose is as standard agent（Generally select EC50Junior）, calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent is in mixture proportion
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC is 80 ~ 120
Between be summation action.
Er Lv Evil bacterium azoles (A) and dimethomorph (B) is used to be tested the indoor biometricses of cucumber downy mildew with different ratio in table 1,
As shown in Table 1, composition co-toxicity coefficient of the invention is all higher than 120, the i.e. present composition has preferable synergetic,
Its effect is better than single dose kind.
1.2 field control effectiveness tests
Test process:The difference of this experimental evidence each composition sets two dosings respectively, and dosing is new active ingredient
The quality of product (A) and dimethomorph (B) and.Comparison medicament is respectively that 20% Er Lv Evil bacterium azole suspending agents and 40% dimethomorph are outstanding
Floating agent and blank clean water experiment.
Test method:Each plot area is 66.7m2, it is repeated 3 times;Investigation drug effect side after investigating and prevent and treat before dispenser
Method is:5 points of grab sample in test process area, conventional spraying.Spraying equipment bodyguard's WS-16 type hand sprayers, circular cone
Fog spray head is sprayed, operating pressure 0.2-0.4MPa, flow 0.65-0.88L/min.
10 plants of strain investigation, every plant of investigation leaf of top 10 are separated per small.Grade scale:
0 grade：Do not fall ill；
1 grade：Lesion area accounts for less than the 5% of full wafer leaf area；
3 grades：Lesion area accounts for the 6%~15% of full wafer leaf area；
5 grades：Lesion area accounts for the 16%~25% of full wafer leaf area；
7 grades：Lesion area accounts for the 26%~50% of full wafer leaf area；
9 grades：Lesion area accounts for more than the 50% of full wafer leaf area.
Drug effect computational methods
Result of the test see the table below:
Field efficacy result shows, as shown in Table 2, the present composition has an obvious synergistic function, composition it is anti-
Excellent effect is controlled, prevention effect is better than single dose kind, there is application value in agricultural application.
2nd, test example prevents and treats Toxicity Determination and the field efficacy test of the late blight of potato
2.1 Toxicity Determinations
Definite virulence of the mixture to the late blight of potato is combined with two chlorine Evil bacterium azoles in order to understand dimethomorph, the present invention is for it
Proportioning is screened.
The late blight of potato (is isolated near the flat sea in Huizhou Huidong County), through Koch's Postulates after purifying culture
Verify that be inoculated in strain in PDA culture medium after pathogenic by its, 25oC, cultivates 7d under 90% damp condition, mycelia covers with culture
Bacteria cake is broken into after ware with 0.5cm card punch to use.
Dimethomorph is determined with Er Lv Evil bacterium azoles and the two composition to potato late blight using mycelial growth rate method
The influence of germ mycelial growth, it is 1 to set the two weight proportion:3,2:5,5:1,10:1,20:1,1:5,1:10, and each list
Agent totally 9 kinds of chemicals treatments, totally 9 concentration gradients are made for each treatment setting 0.125,0.25,0.5,1,2,4,8,16,32mg/L
PDA plate, it is control to set without medicament, is repeated 3 times per concentration, and the bacteria cake that will aseptically accomplish fluently is inverted in each treatment
Behind PDA plate center, flat board is placed in 25oC, cultivates under 90% damp condition, treats that mycelial growth diameter reaches culture dish diameter
(10d or so) investigation result when 50% or so.Inhibiting rate is calculated according to the following equation, and calculates each by DPS Software of Data Statistics
Individual chemicals treatment is to virulence regression equation, coefficient correlation, EC50And compounding co-toxicity coefficient.Mycelial growth rate is used indoors
Method, determines EC of the different agents to bacterial strain50, using co-toxicity coefficient computational methods, calculate the co-toxicity coefficient of mixture（CTC）, really
Determine the building performance of mixture, circular is as follows：
With in mixture certain-single dose as standard agent, calculated：
Single dose toxicity index=standard agent EC50/ certain single dose EC50×100
Toxicity index × the B of the toxicity index of theoretical toxicity index=A single doses × A single doses proportion+B single doses in mixture is mono-
Agent is in mixture proportion
Survey the EC of toxicity index=standard single dose50The EC of value/mixture50Value × 100
Co-toxicity coefficient=actual measurement toxicity index/theoretical toxicity index × 100
Co-toxicity coefficient is classified：Mixture has synergetic when CTC is more than 120, is antagonism when CTC is less than 80, and CTC is 80 ~ 120
Between be summation action.
Use Er Lv Evil bacterium azoles (A) and dimethomorph (B) raw to the interior of the late blight of potato with different ratio in table 3
Test is tested, and as shown in Table 3, composition co-toxicity coefficient of the invention is all higher than 120, the i.e. present composition has preferably collaboration
Building performance, its effect is better than single dose kind.
2.2 field control effectiveness tests
Test process:The difference of this experimental evidence each composition sets two dosings respectively, and dosing is new active ingredient
The quality of product (A) and dimethomorph (B) and.Comparison medicament is respectively that 20% Er Lv Evil bacterium azole suspending agents and 40% dimethomorph are outstanding
Floating agent and blank clean water experiment.
Test method:Each plot area is 66.7m2, it is repeated 3 times;Investigation drug effect side after investigating and prevent and treat before dispenser
Method is:5 points of grab sample in test process area, conventional spraying.Spraying equipment bodyguard's WS-16 type hand sprayers, circular cone
Fog spray head is sprayed, operating pressure 0.2-0.4MPa, flow 0.65-0.88L/min.
10 plants of strain investigation, every plant of investigation leaf of top 10 are separated per small.Grade scale:
0 grade：Do not fall ill；
1 grade：Lesion area accounts for less than the 5% of full wafer leaf area；
3 grades：Lesion area accounts for the 6%~15% of full wafer leaf area；
5 grades：Lesion area accounts for the 16%~25% of full wafer leaf area；
7 grades：Lesion area accounts for the 26%~50% of full wafer leaf area；
9 grades：Lesion area accounts for more than the 50% of full wafer leaf area.
Drug effect computational methods
Result of the test see the table below:
Field efficacy result shows, as shown in Table 4, the present composition has an obvious synergistic function, composition it is anti-
Excellent effect is controlled, prevention effect is better than single dose kind, there is application value in agricultural application.
Claims (8)
1. a kind of composition pesticide, it is characterised in that active component includes Er Lv Evil bacterium azoles and dimethomorph.
2. composition pesticide according to claim 1, it is characterised in that the weight of the Er Lv Evil bacterium azoles and dimethomorph
Than being 1:20-20：1.
3. composition pesticide according to claim 1, it is characterised in that the weight of active component in the composition pesticide
Percentage composition is 20-50%.
4. the composition pesticide according to any one of claim 1-2 claim, it is characterised in that：The pesticide combination
Thing is aided with Pesticide formulation auxiliary element and is processed into any one formulation for being adapted to agriculturally use.
5. composition pesticide according to claim 3, it is characterised in that the formulation of the composition pesticide is wettable powder
In agent, water dispersible granules, suspending agent, microemulsion, aqueous emulsion it is any in.
6. the composition pesticide according to any one of claim 1-5 claim, it is characterised in that the pesticide combination
Thing also contains other agricultural active compositions.
7. the composition pesticide according to any one of claim 1-4 claim is used to prevent and kill off the purposes of corps diseases.
8. purposes according to claim 5, it is characterised in that the corps diseases are preferably the late blight of potato and Huang
Melon downy mildew.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611231255.4A CN106689148A (en) | 2016-12-28 | 2016-12-28 | Pesticide composition containing dichloroxazole and dimethomorph |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611231255.4A CN106689148A (en) | 2016-12-28 | 2016-12-28 | Pesticide composition containing dichloroxazole and dimethomorph |
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| Publication Number | Publication Date |
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| CN106689148A true CN106689148A (en) | 2017-05-24 |
Family
ID=58902807
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611231255.4A Pending CN106689148A (en) | 2016-12-28 | 2016-12-28 | Pesticide composition containing dichloroxazole and dimethomorph |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109832284A (en) * | 2017-11-29 | 2019-06-04 | 佛山市盈辉作物科学有限公司 | A kind of bactericidal composition for disliking bacterium azoles and flumorph containing dichloro |
| CN113142220A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
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| CN106070246A (en) * | 2016-06-21 | 2016-11-09 | 广东中迅农科股份有限公司 | A kind of containing dichloro evil bacterium azoles and the bactericidal composition of cycloheximide triazole |
| CN106386824A (en) * | 2016-08-31 | 2017-02-15 | 柳州市惠农化工有限公司 | Pesticide composition comprising 2-methyl sulfone-5-(2, 4-dichlorophenyl)-1, 2, 3-oxadiazole and dimethomorph |
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| CN106070246A (en) * | 2016-06-21 | 2016-11-09 | 广东中迅农科股份有限公司 | A kind of containing dichloro evil bacterium azoles and the bactericidal composition of cycloheximide triazole |
| CN106386824A (en) * | 2016-08-31 | 2017-02-15 | 柳州市惠农化工有限公司 | Pesticide composition comprising 2-methyl sulfone-5-(2, 4-dichlorophenyl)-1, 2, 3-oxadiazole and dimethomorph |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109832284A (en) * | 2017-11-29 | 2019-06-04 | 佛山市盈辉作物科学有限公司 | A kind of bactericidal composition for disliking bacterium azoles and flumorph containing dichloro |
| CN113142220A (en) * | 2018-08-28 | 2021-07-23 | 侨昌现代农业有限公司 | Bactericide composition |
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Application publication date: 20170524 |
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