CN101406191B - Fungicidal compositions - Google Patents
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- CN101406191B CN101406191B CN2007101756285A CN200710175628A CN101406191B CN 101406191 B CN101406191 B CN 101406191B CN 2007101756285 A CN2007101756285 A CN 2007101756285A CN 200710175628 A CN200710175628 A CN 200710175628A CN 101406191 B CN101406191 B CN 101406191B
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Abstract
The invention discloses a fungicide composition, which contains the following synergic compounds as active ingredients: component A which is selected from azole compounds shown in a general formula (I), and component B which is selected from compounds and salts thereof with antifungal activities such as triazoles, thiocarbamate salts, methoxy acrylic esters, carbamates, antibiotics, acidamides and the like. As above, each radical in the general formula is as defined in the introduction. The weight ratio of the component A to the component B in the composition is between 1 to 200 and 200 to 1.
Description
Technical field
The invention belongs to the disinfectant use in agriculture field, relate to a kind of Fungicidal composition particularly.
Background technology
Reported a kind of substituted azole compounds among Chinese invention patent CN1657524A and the PCT application WO2005080344A1; This compounds for example all has the better prevention effect to fungal diseases such as rice blast, false smut, rice sheath blight disease, sclerotinia rot of colza, tomato leaf mildew, tomato gray mold, ring rot of apple, apple valsa canker, melon anthracnose, cucumber fusarium axysporum, cucumber downy mildew, powdery mildew of cucumber, cotton verticillium wilt, cotton wilt, wheat powdery mildews for the good control efficiency of disease fungus to the plurality of plant diseases on the crops such as cereal, paddy rice, fruit tree, vegetables.
This compounds is the mitochondrial respiratory inhibitor.Because it is very single to suppress mitochondrial electronics transfer function site, germ produces adaptive variation to medicament easily, possibly cause the preventive effect of medicament to reduce even invalid, and this type of medicament is existing drug-fast relevant report in Europe.Actual agriculture experience also shows; Long-term repeat and single-mindedly use a kind of reactive compound and prevent and treat the fast selective that harmful fungoid can cause fungal bacterial strain under many circumstances; Said bacterial strain develops innately or the resistance that adapts to particular active compounds, causes re-using said reactive compound and comes effectively these fungies of control.Therefore people pay special attention to this type problem.
Summary of the invention
Optionally dangerous in order to reduce the resistance fungal bacterial strain, use the mixture of different activities compound to prevent and treat harmful fungoid usually.Compound through having different effects mechanism makes up, and effectively preventing influences the harmful fungoid of plant growth more, prolongs the service life of each component in the mixture.The present invention aims to provide a kind of Fungicidal composition that contains the different activities compound and have synergistic function, to reach effective processing resistance and the purpose of effectively preventing and treating plant pathogenic fungi.
Technical scheme of the present invention is following:
The invention provides a kind of Fungicidal composition, the following compound that comprises Synergistic is selected from substituted azole compounds or its salt shown in general formula (I) as active component: component A:
In the formula:
X
1Be selected from CH or N, X
2Be selected from O, S or NR
7, X
3Be selected from O, S or NR
8
A
1Be selected from N or CR
9, A
2Be selected from N or CR
10, A
3Be selected from N or CR
11, A wherein
1, A
2, A
3The number that is selected from N simultaneously less than, equal 1;
R
1, R
2Can be identical or different, be selected from hydrogen, C respectively
1-C
12Alkyl or halo C
1-C
12Alkyl;
R
3Be selected from hydrogen, halogen atom, C
1-C
12Alkyl, halo C
1-C
12Alkyl or C
1-C
12Alkoxyl;
R
7Be selected from hydrogen or C
1-C
12Alkyl;
R
8Be selected from hydrogen, C
1-C
12Alkyl, halo C
1-C
12Alkyl, C
1-C
12Alkoxy carbonyl or C
1-C
12Alkoxy carbonyl C
1-C
12Alkyl;
R
4, R
5, R
6, R
9, R
10, R
11Can be identical or different, be selected from hydrogen, halogen atom, nitro, cyanic acid, CONH respectively
2, CH
2CONH
2, CH
2CN, C
1-C
12Alkyl, halo C
1-C
12Alkyl, C
1-C
12Alkoxyl, halo C
1-C
12Alkoxyl, C
1-C
12Alkylthio group, C
1-C
12Alkane sulfonyl, C
1-C
12Alkyl-carbonyl, C
1-C
12Alkoxy C
1-C
12Alkyl, C
1-C
12Alkoxy carbonyl, C
1-C
12Alkoxy carbonyl C
1-C
12Alkyl, C
1-C
12Halogenated alkoxy C
1-C
12Alkyl, can any substituted following groups: amido C
1-C
12Alkyl, aryl, heteroaryl, aryloxy group, aryl C
1-C
12Alkyl, fragrant C
1-C
12Alkyl oxy, heteroaryl C
1-C
12Alkyl or heteroaryl C
1-C
12Alkoxyl; And stereoisomer.
B component is selected from acceptable isomers or its salt on be described below six compounds and their agricultural synthetic or that derive from natural products with Fungicidally active:
Triazole class compounds (B
1), for example fluorine ring azoles, triazolone, Difenoconazole, alkene azoles alcohol, nitrile bacterium azoles, Tebuconazole, propiconazole, prothioconazoles, oxygen ring azoles, bromuconazole, Cyproconazole, Difenoconazole, efficient alkene azoles alcohol, RH-7592, Flusilazole, Flutriafol, own azoles alcohol, glyoxalin, kind bacterium azoles, metconazole, penconazole, simeconazoles, tetraconazole, Triadimenol, triticonazole, bitertanol, tricyclazole.
Thiocarbamate compounds (B
2), for example mancozeb, maneb, zineb, Propineb, ambam, tmtd, ziram.
Methoxy acrylic ester compounds (B
3), for example Fluoxastrobin, fluoxastrobin, oxime bacterium ester, ZEN 90160, pyraclostrobin, ether bacterium amine, kresoxim-methyl, SSF 126, orysastrobin, Enestroburin (SYP-Z071), alkene oxime amine (SYP-1620), ZJ0712, UBF-307, KZ165.
Carbamate compound (B
4), the for example mould prestige of second, iprovalicarb, benzene metsulfovax, valiphenal (IR5885), Propamocarb, methasulfocarb, pyribencarb, meptyldinocap.
Antibiotics compound (B
5), for example blasticidin-S, kasugarnycin, myxothiazol, polyoxin, Polyoxin, pseudomycin, PSF-D, valida, jinggangmeisu, streptomycin.
Amides compound (B
6), for example flumorph, dimethomorph, thiophene fluorine bacterium amine, ring propionyl bacterium amine, fenhexamid, zarilamid, isotianil, silicon metsulfovax, furan pyrrole bacterium amine, zoxamide, metalaxyl, furalaxyl, M 9834, two chlorine zarilamid, flusulfamide.
Weight ratio between A, B two components is 1: 200～200: 1.
In the Fungicidal composition of the present invention more preferably technical scheme be:
Component A is selected from the substituted azole compounds shown in the general formula (I) or its salt:
In the formula:
X
1Be selected from CH, X
2Be selected from O, X
3Be selected from NCH
3
A
1, A
3Be selected from CH respectively, A
2Be selected from C-Cl;
R
1, R
2Be selected from CH respectively
3, R
3Be selected from hydrogen, R
4, R
5, R
6Be selected from hydrogen respectively; Structure is following:
The azoles bacterium ester Chinese general by name of compound (1), chemical name is:
(E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate
[(E)-methyl?2-(2-((3-(4-chlorophenyl)-1-methyl-1H-pyrazol-5-yloxy)methyl)phenyl)-3-methoxyacrylate]。
The more preferably compound of B component is selected from:
Triazole class compounds (B
1) comprising: (2) fluorine ring azoles (epoxiconazole), (3) triazolone (triadimefon), (4) Difenoconazole (difenoconazole), (5) alkene azoles alcohol (diniconazole), (6) nitrile bacterium azoles (myclobutanil), (7) propiconazole (propiconazole) or (8) Tebuconazole (tebuconazole);
Thiocarbamate compounds (B
2) comprising: (9) mancozeb (mancozeb), (10) maneb (maneb), (11) zineb (zineb), (12) Propineb (propineb), (13) ambam (amobam), (14) tmtd (thiram) or (15) ziram (ziram);
Methoxy acrylic ester compounds (B
3) comprising: (16) Fluoxastrobin (azoxystrobin), (17) oxime bacterium ester (trifloxystrobin), (18) ZEN 90160 (picoxystrobin), (19) pyraclostrobin (pyraclostrobin) or (20) ether bacterium amine (dimoxystrobin);
Carbamate compound (B
4) comprising: the mould prestige of (21) second (diethofencarb), (22) iprovalicarb (iprovalicarb), (23) benzene metsulfovax (benthiavalicarb-isopropyl), (24) methasulfocarb (methasulfocarb) or (25) Propamocarb (propamocarb);
Antibiotics compound (B
5) comprising: (26) blasticidin-S (blasticidin-S), (27) kasugarnycin (kasugamycin), (28) polyoxin (polyoxins) or (29) Polyoxin (polyoxorim).
Amides compound (B
6) comprising: (30) flumorph (flumorph), (31) dimethomorph (Dimethomorph).
Above-mentioned B component composition is the control medicament commonly used of various crop disease; In long-term use, shown good control efficiency; It is described in detail sees " The Pesticide Manual " (12th ed UK:BCPC; 2000), " The PesticideManual " (13th ed UK:BCPC, 2003).
In the composition A, B two components more preferably weight ratio be 1: 100～100: 1; Further be preferably 1: 50～50: 1.
Further optimized technical scheme is:
Component A is selected from (E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate; B component is selected from fluorine ring azoles, triazolone, Difenoconazole, alkene azoles alcohol, nitrile bacterium azoles, propiconazole or Tebuconazole; Weight ratio in the composition between A, B two components is 1: 40～40: 1.
Perhaps, component A is selected from (E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate; B component is selected from mancozeb, maneb, zineb, Propineb, ambam, tmtd or ziram; Weight ratio in the composition between A, B two components is 1: 20～20: 1.
Perhaps, component A is selected from (E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate; B component is selected from Fluoxastrobin, oxime bacterium ester, ZEN 90160, pyraclostrobin or ether bacterium amine; Weight ratio in the composition between A, B two components is 1: 20～20: 1.
Perhaps, component A is selected from (E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate; B component is selected from the mould prestige of second, iprovalicarb, benzene metsulfovax, methasulfocarb or Propamocarb; Weight ratio in the composition between A, B two components is 1: 20～20: 1.
Perhaps, component A is selected from (E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate; B component is selected from blasticidin-S, kasugarnycin, polyoxin or Polyoxin; Weight ratio in the composition between A, B two components is 1: 20～20: 1.
Perhaps, component A is selected from (E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate; B component is selected from flumorph or dimethomorph; Weight ratio in the composition between A, B two components is 1: 20～20: 1.
Have now found that Fungicidal composition of the present invention has very obvious role in synergism, the control efficiency of corps diseases is significantly increased, can enlarge fungicidal spectrum simultaneously, delay the drug-fast generation of pathogen.Therefore technical scheme of the present invention has comprised the application of controlling plant diseases aspect.
The present composition is suitable for preventing and treating multiple harmful fungoid, the especially multiple diseases of cereal class, vegetables, fruit tree, ornamental plants, lawn and tropical crop, and multiple storage disease.
When the preparation said composition; Pure reactive compound (1) and at least a B component composition of preferred use; Can be to wherein adding other to harmful pathogen or the effective active substance of other insect, or have the reactive compound or the fertilizer of herbicide effect and growth regulating effect.No matter use said composition in any form; Be the using of mixture of compound (1) and at least a B component composition independent or co-administered or compound (1) and at least a B component composition; All appear and prevent and treat significantly that the disease scope increases and the preventive effect of some disease is improved, comprise the plurality of plant diseases that sac fungi, basidiomycetes, imperfect fungus etc. are caused.Composition is to preventing and treating the fungal disease of various crops such as cereal, paddy rice, vegetables, fruit tree, flowers, and the cover crop that is used to dress seed is particularly important.Be particularly suitable for preventing and treating the following plants fungal disease: powdery mildew of cucumber, cucumber downy mildew, gray mold of cucumber, scab of cucumber, muskmelon powdery mildew, soybean rust, tomato gray mold, tomato powdery mildew, watermelon anthrax, rice blast, rice green smut, wheat powdery mildew, wheat rust, pear scab, leaf spot of peanut, powdery mildew of strawberry, sigatoka etc.
According to the occurrence degree of corps diseases, the working concentration of the present composition is 1～1500g/hm in the proportion of crop planting zone
2, preferred 15～400g/hm
2Here the working concentration of compound (1) is 0.02～400g/hm
2, preferred 5～250g/hm
2Accordingly, compound (B
1)～(B
5) working concentration be 0.02～1000g/hm
2, preferred 15～600g/hm
2
Handle kind of a period of the day from 11 p.m. to 1 a.m, the working concentration of composition is generally 1～1000g/kg, preferred 1～800g/kg.
In the process of controlling plant diseases, the using period of composition of the present invention can be before or after the plant seeding, also can be before or after plant emerges mode such as seed, plant or soil spraying or loose powder be carried out.
Can Fungicidal composition of the present invention be formulated as direct spray solution, powder, suspension, water-based, oiliness or other suspension, dispersion, emulsion, oil dispersion, paste, the pulvis that highly concentrate, broadcast sowing with mixture or particle, and can be through spraying, atomizing, dusting, broadcast sowing or mode such as topple over and use.Administration form depends on specific purpose; Under various situation, should guarantee the meticulous and even distribution of the present composition.
Fungicidal composition of the present invention maybe will be prevented and treated plant corpus, seed, soil, zone, material or the space that they are infected with dosage control harmful fungoid, its habitat that suitable formulation, use are fit to.Using of compound can be carried out before or after harmful fungoid infects, emphasis should be before infect or the initial stage of infecting use.
Can prepare the preparation of Fungicidal composition of the present invention with known method.At least comprise two kinds of carriers in the composition of the present invention, carrier can be solid or liquid, and any carrier that is generally used for preparing microbicide compositions all can use.At least a carrier is a surfactant in the composition, for example can be emulsifier, dispersant or wetting agent etc.Surfactant is commercially available, and its selection is that those skilled in the art are known, for example, and lauryl sodium sulfate, Teepol, neopelex, polyoxyethylene fatty acid fat, polyoxyethylene aliphatic alcohol ether or polyoxyethylene fatty amine etc.
The present composition can be mixed with missible oil, suspending agent, (water) emulsion, wetting powder, (aqueous dispersion) granula etc., and these preparations can be prepared by method in common.In the composition, the active constituent content sum of A, B component is that the weight content of active component is 0.1～95%, preferred 0.1～80%.
Composition of the present invention is that the instance (the concrete application is not limited only to this) of several kinds of common formulations that active substance was mixed with is listed below:
One, the product of dilute with water
1.10% aqueous emulsion (EW)
Reactive compound 10%, polyvinyl alcohol 0.8%, alkylaryl polyoxyethylene poly-oxygen propylene aether 8.5%, farming breast 2,201 16%, dimethyl formamide 11%, ethylene glycol 5%, water complements to 100%.
2.20% missible oil (EC)
Reactive compound 20%, agricultural newborn 500# 10%, agricultural newborn OX-635 5%, methyl alcohol 10%, xylol complements to 100%.
3.40% suspending agent (SC)
Reactive compound 40%, calcium lignosulfonate 5%, white carbon black 0.3%, ethylene glycol 4%, antifoaming agent a little, water complements to 100%.
4.50% water dispersible granules (WG)
Reactive compound 50%, methyl naphthalene sulfonate formaldehyde condensate 12%, epoxidized polyether 5%, soluble starch 15%, gypsum complements to 100%.
5.70% wetting powder (WP)
Reactive compound 70%, lauryl sodium sulfate 1.5%, carboxymethyl cellulose 1%, sodium lignin sulfonate 10%, precipitated calcium carbonate complements to 100%.
The product that two, can use without dilution
6.5% pulvis (DP)
Fully mix with 5 parts of taskwork property compound grindings in small, broken bits and with the kaolin in small, broken bits of 95 parts of weights and to obtain pulvis.
7.0.5% granule (GR)
With 0.5 part of taskwork property compound grinding in small, broken bits and combine the carrier of 99.5 parts of weights, current methods be extrude, atomized drying or fluid bed, obtain the particle that can use without dilution.
The product that the present invention describes provides with the finished product preparation form, and promptly each material mixes in the composition.Simultaneously, the composition of composition also separately the form of preparation directly mixing in bucket (jar) before using is provided.Concentrate of the present invention mixes the concentration that obtains required active substance with water usually, by spraying, atomizing, dusting, broadcast sowing or pour into a mould and use.Type of service depend on fully the purpose that will reach, guarantee that under various situation the best of reactive compound of the present invention possibly distribute.
Moisture type of service can be prepared by emulsion concentrates, paste or wettable powder (sprayable powder, oil dispersion) through adding entry.Be preparation emulsion, paste or oil dispersion, can be with this material directly or be dissolved in back homogenizing in water in oil or the solvent by wetting agent, tackifier, dispersant or emulsifier.Perhaps, can prepare the concentrate that is suitable for dilute with water and forms by active substance, wetting agent, tackifier, dispersant or emulsifier, solvent or oil.
Various types of oil, wetting agent, adjuvant, weed killer herbicide, fungicide, other agricultural chemicals or bactericide all can add in the reactive compound, if suitable, just before the next-door neighbour uses, add (bucket mixes).These reagent mix with 1: 30～30: 1 weight ratio with mixture of the present invention usually.
Embodiment
Fungicidal composition of the present invention can be explained through following instance the synergistic function of harmful fungoid, but the present invention only limits to this absolutely not.
Reactive compound independent or associating is prepared into acetone or the DMSO liquid storage that contains 0.25% (weight) reactive compound.Emulsifier Uniperol
EL (BASF AG's product) of 1% (weight) is added in this liquid storage, and water is with desired concn in this reactive compound or mixture diluted to the following instance.
Infect percentage evaluation through measuring leaf area.These percentages are changed into effectiveness.Use the Abbot formula to calculate and render a service (W) according to following formula:
W＝(1-α/β)×100
α handles the fungal infection percentage of plant;
The be untreated fungal infection percentage of (blank) plant of β.
Render a service to " 0 " and represent that the level that infects of processing plant is identical with the level that infects of untreated control plant; Render a service to plant is represented to handle in " 100 " and infected.
The expection effectiveness use Colby formula [R.S.Colby, weeds (Weeds) 15,20-22 (1967)] of active compound combinations is confirmed and is compared with observed effectiveness.
Colby formula: E=x+y-xy/100
E: the expection when working concentration is respectively the mixture of reactive compound A and B of a and b is renderd a service, and representes with the % of untreated control.
Effectiveness when the x working concentration is the reactive compound A of a is represented with the % of untreated control;
Effectiveness when the y working concentration is the reactive compound B of b is represented with the % of untreated control.
In the following example, employed crop seedling is all planted cultivation with potted plant mode in the greenhouse.Treat growth of seedling to tri-leaf period, the healthy seedling that selects the growth neat and consistent is used for giving birth to test and tests.The mixing ratio of listed A, B two composition activity compounds is a weight ratio in each table.
The 1 control wheat powdery mildew test of application implementation example
Cultivar is sprayed to the drip point for the aqueous suspension that the potted plant wheat seedling leaf of " the Liao Dynasty spring No. 10 " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of white powder germ (Blumeria graminis).Place 22～24 ℃ to be that 75% climatic chamber is regulated 7 days test plants then with relative atmospheric humidity.The development degree of infection process on the leaf is measured in range estimation then.
The reactive compound that table 1 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 1 | Contrast (being untreated) | - | (95% infects) |
| 2 | (1) azoles bacterium ester | 0.1 | 22.95 |
| 0.05 | 17.21 | ||
| 0.025 | 11.48 | ||
| 3 | (2) fluorine ring azoles | 0.025 | 13.93 |
| 4 | (3) triazolone | 1 | 18.55 |
| 5 | (5) alkene azoles alcohol | 0.025 | 15.57 |
| 6 | (6) nitrile bacterium azoles | 0.1 | 12.35 |
| 7 | (7) propiconazole | 0.1 | 22.66 |
| 8 | (8) Tebuconazole | 0.1 | 17.45 |
Table 2 present composition
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 9 | (1)+(2) 0.1+0.025 4∶1 | 60.25 | 33.68 |
| 10 | (1)+(2) 0.05+0.025 2∶1 | 51.39 | 28.74 |
| 11 | (1)+(2) 0.025+0.025 1∶1 | 43.59 | 23.81 |
| 12 | (1)+(3) 0.1+1 1∶10 | 58.36 | 37.24 |
| 13 | (1)+(3) 0.05+1 1∶20 | 49.52 | 32.57 |
| 14 | (1)+(3) 0.025+1 1∶40 | 41.71 | 27.90 |
| 15 | (1)+(5) 0.1+0.025 4∶1 | 66.75 | 34.95 |
| 16 | (1)+(5) 0.05+0.025 2∶1 | 51.73 | 30.10 |
| 17 | (1)+(5) 0.025+0.025 1∶1 | 46.59 | 25.26 |
| 18 | (1)+(6) 0.1+0.1 1∶1 | 60.51 | 32.47 |
| 19 | (1)+(6) 0.05+0.1 1∶2 | 54.69 | 27.43 |
| 20 | (1)+(6) 0.025+0.1 1∶4 | 41.87 | 22.41 |
| 21 | (1)+(7) 0.1+0.1 1∶1 | 65.90 | 40.41 |
| 22 | (1)+(7) 0.05+0.1 1∶2 | 58.36 | 35.97 |
| 23 | (1)+(7) 0.025+0.1 1∶4 | 52.04 | 31.54 |
| 24 | (1)+(8) 0.1+0.1 1∶1 | 56.77 | 36.40 |
| 25 | (1)+(8) 0.05+0.1 1∶2 | 47.28 | 31.66 |
| 26 | (1)+(8) 0.025+0.1 1∶4 | 39.33 | 26.93 |
"
*": the effectiveness of using the Colby formula to calculate.
Application implementation example 2 is prevented and treated the powdery mildew of cucumber test
Cultivar is sprayed to the drip point for the aqueous suspension that the potted plant cucumber seedling leaf of " the close thorn in Shandong " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of white powder germ (Erysiphe cucurbitacearum).Place 22～24 ℃ to be that 75% climatic chamber is regulated 7 days test plants then with relative atmospheric humidity.The development degree of infection process on the leaf is measured in range estimation then.
The reactive compound that table 3 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 27 | Contrast (being untreated) | - | (90% infects) |
| 28 | (1) | 2.5 | 26.92 |
| 1.25 | 19.23 | ||
| 0.625 | 15.38 |
| 29 | (2) fluorine ring azoles | 0.625 | 12.54 |
| 30 | (3) triazolone | 0.625 | 14.86 |
| 31 | (4) Difenoconazole | 0.625 | 12.57 |
| 32 | (5) alkene azoles alcohol | 0.625 | 13.69 |
| 33 | (6) nitrile bacterium azoles | 0.625 | 12.00 |
| 34 | (8) Tebuconazole | 0.625 | 10.99 |
Table 4 present composition
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 35 | (1)+(2) 2.5+0.625 4∶1 | 63.21 | 36.08 |
| 36 | (1)+(2) 1.25+0.625 2∶1 | 58.57 | 29.36 |
| 37 | (1)+(2) 0.625+0.625 1∶1 | 49.82 | 25.99 |
| 38 | (1)+(3) 2.5+0.625 4∶1 | 59.51 | 37.78 |
| 39 | (1)+(3) 1.25+0.625 2∶1 | 49.62 | 31.23 |
| 40 | (1)+(3) 0.625+0.625 1∶1 | 44.26 | 27.95 |
| 41 | (1)+(4) 2.5+0.625 4∶1 | 63.15 | 36.11 |
| 42 | (1)+(4) 1.25+0.625 2∶1 | 58.54 | 29.38 |
| 43 | (1)+(4) | 48.24 | 26.02 |
| 0.625+0.625 1∶1 | |||
| 44 | (1)+(5) 2.5+0.625 4∶1 | 64.54 | 36.92 |
| 45 | (1)+(5) 1.25+0.625 2∶1 | 55.84 | 30.29 |
| 46 | (1)+(5) 0.625+0.625 1∶1 | 51.64 | 26.96 |
| 47 | (1)+(6) 2.5+0.625 4∶1 | 64.57 | 35.69 |
| 48 | (1)+(6) 1.25+0.625 2∶1 | 50.24 | 28.92 |
| 49 | (1)+(6) 0.625+0.625 1∶1 | 47.85 | 25.53 |
| 50 | (1)+(8) 2.5+0.625 4∶1 | 61.65 | 34.95 |
| 51 | (1)+(8) 1.25+0.625 2∶1 | 50.24 | 28.11 |
| 52 | (1)+(8) 0.625+0.625 1∶1 | 49.82 | 24.68 |
"
*": the effectiveness of using the Colby formula to calculate.
The 3 control wheat powdery mildew tests of application implementation example
Cultivar is sprayed to the drip point for the aqueous suspension that the potted plant wheat seedling leaf of " the Liao Dynasty spring No. 10 " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of white powder germ (Blumeria graminis).Place 22～24 ℃ to be that 75～80% climatic chambers are regulated 8 days test plants then with relative atmospheric humidity.The development degree of infection process on the leaf is measured in range estimation then.
The reactive compound that table 5 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 53 | Contrast (being untreated) | - | (95% infects) |
| 54 | (1) azoles bacterium ester | 0.1 | 22.95 |
| 0.05 | 17.21 | ||
| 0.025 | 11.48 | ||
| 55 | (9) mancozeb | 0.1 | 5.68 |
| 56 | (10) maneb | 0.1 | 6.24 |
| 57 | (11) zineb | 0.1 | 5.64 |
| 58 | (12) Propineb | 0.1 | 8.54 |
| 59 | (13) ambam | 0.1 | 7.24 |
| 60 | (14) tmtd | 0.1 | 9.25 |
| 61 | (15) ziram | 0.1 | 4.65 |
Table 6 present composition
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 62 | (1)+(9) 0.1+0.1 1∶1 | 42.21 | 27.33 |
| 63 | (1)+(9) 0.05+0.1 1∶2 | 34.21 | 21.91 |
| 64 | (1)+(9) 0.025+0.1 1∶4 | 24.24 | 16.51 |
| 65 | (1)+(10) 0.1+0.1 1∶1 | 39.64 | 27.76 |
| 66 | (1)+(10) 0.05+0.1 1∶2 | 31.25 | 22.38 |
| 67 | (1)+(10) 0.025+0.1 | 28.54 | 17.00 |
| 1∶4 | |||
| 68 | (1)+(11) 0.1+0.1 1∶1 | 39.54 | 27.30 |
| 69 | (1)+(11) 0.05+0.1 1∶2 | 35.64 | 21.88 |
| 70 | (1)+(11) 0.025+0.1 1∶4 | 29.54 | 16.47 |
| 71 | (1)+(12) 0.1+0.1 1∶1 | 40.97 | 29.53 |
| 72 | (1)+(12) 0.05+0.1 1∶2 | 35.69 | 24.28 |
| 73 | (1)+(12) 0.025+0.1 1∶4 | 32.54 | 19.04 |
| 74 | (1)+(13) 0.1+0.1 1∶1 | 39.58 | 28.53 |
| 75 | (1)+(13) 0.05+0.1 1∶2 | 34.69 | 23.20 |
| 76 | (1)+(13) 0.025+0.1 1∶4 | 29.54 | 17.89 |
| 77 | (1)+(14) 0.1+0.1 1∶1 | 45.62 | 30.08 |
| 78 | (1)+(14) 0.05+0.1 1∶2 | 34.68 | 24.87 |
| 79 | (1)+(14) | 30.21 | 19.67 |
| 0.025+0.1 1∶4 | |||
| 80 | (1)+(15) 0.1+0.1 1∶1 | 39.54 | 26.53 |
| 81 | (1)+(15) 0.05+0.1 1∶2 | 34.62 | 21.06 |
| 82 | (1)+(15) 0.025+0.1 1∶4 | 26.51 | 15.60 |
"
*": the effectiveness of using the Colby formula to calculate.
The 4 control cucumber downy mildew tests of application implementation example
Cultivar is sprayed to the drip point for the aqueous suspension that the potted plant cucumber seedling leaf of " the close thorn in Shandong " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of Pseudoperonospora cubensis (Pseudoperonospora cubensis).Place 22～24 ℃ to be that 90% climatic chamber is regulated 7 days test plants then with relative atmospheric humidity.The development degree of infection process on the leaf is measured in range estimation then.
The reactive compound that table 7 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 83 | Contrast (being untreated) | - | (90% infects) |
| 84 | (1) azoles bacterium ester | 2 | 44.44 |
| 1 | 38.89 | ||
| 0.5 | 27.78 | ||
| 85 | (9) mancozeb | 1 | 22.22 |
| 86 | (10) maneb | 1 | 16.67 |
| 87 | (11) zineb | 1 | 27.78 |
| 88 | (12) Propineb | 1 | 11.11 |
| 89 | (13) ambam | 1 | 16.67 |
| 90 | (14) tmtd | 1 | 16.67 |
| 91 | (15) ziram | 1 | 27.78 |
Table 8 composition of the present invention
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 92 | (1)+(9) 2+1 2∶1 | 83.33 | 56.79 |
| 93 | (1)+(9) 1+1 1∶1 | 83.33 | 52.47 |
| 94 | (1)+(9) 0.5+1 1∶2 | 72.22 | 43.83 |
| 95 | (1)+(10) 2+1 2∶1 | 83.33 | 53.70 |
| 96 | (1)+(10) 1+1 1∶1 | 72.22 | 49.07 |
| 97 | (1)+(10) 0.5+1 1∶2 | 66.67 | 39.81 |
| 98 | (1)+(11) 2+1 2∶1 | 88.89 | 59.88 |
| 99 | (1)+(11) 1+1 1∶1 | 83.33 | 55.86 |
| 100 | (1)+(11) 0.5+1 1∶2 | 72.22 | 47.84 |
| 101 | (1)+(12) 2+1 2∶1 | 77.78 | 50.62 |
| 102 | (1)+(12) 1+1 1∶1 | 72.22 | 45.68 |
| 103 | (1)+(12) 0.5+1 1∶2 | 55.56 | 35.80 |
| 104 | (1)+(13) 2+1 2∶1 | 83.33 | 53.70 |
| 105 | (1)+(13) 1+1 1∶1 | 72.22 | 49.07 |
| 106 | (1)+(13) 0.5+1 1∶2 | 61.11 | 39.81 |
| 107 | (1)+(14) 2+1 2∶1 | 83.33 | 53.70 |
| 108 | (1)+(14) 1+1 1∶1 | 72.22 | 49.07 |
| 109 | (1)+(14) 0.5+1 1∶2 | 61.11 | 39.81 |
| 110 | (1)+(15) 2+1 2∶1 | 88.89 | 59.88 |
| 111 | (1)+(15) 1+1 1∶1 | 50.00 | 28.09 |
| 112 | (1)+(15) 0.5+1 1∶2 | 33.33 | 20.06 |
"
*": the effectiveness of using the Colby formula to calculate.
Application implementation example 5 is prevented and treated the wheat scab test
Cultivar is sprayed to the drip point for the aqueous suspension that the potted plant wheat wheat head of " the Liao Dynasty spring No. ten " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of gibberellic hypha (Fusarium graminearum).Place 22～24 ℃ to be that 90% climatic chamber is regulated 14 days test plants then with relative atmospheric humidity.Naked eyes are measured the development degree of infection process on the wheat head then.
The reactive compound that table 9 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 113 | Contrast (being untreated) | - | (95% infects) |
| 114 | (1) azoles bacterium ester | 4 | 42.11 |
| 1 | 31.58 | ||
| 0.25 | 8.42 | ||
| 115 | (16) Fluoxastrobin | 1 | 15.79 |
| 116 | (17) oxime bacterium ester | 1 | 10.53 |
| 117 | (18) ZEN 90160 | 1 | 12.63 |
| 118 | (19) pyraclostrobin | 1 | 18.95 |
Table 10 composition of the present invention
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 119 | (1)+(16) 4+1 4∶1 | 81.05 | 51.25 |
| 120 | (1)+(16) 1+1 1∶1 | 70.53 | 42.38 |
| 121 | (1)+(16) 0.25+1 1∶4 | 36.84 | 22.88 |
| 122 | (1)+(17) 4+1 4∶1 | 76.84 | 48.20 |
| 123 | (1)+(1?7) 1+1 1∶1 | 65.26 | 38.78 |
| 124 | (1)+(17) 0.25+1 1∶4 | 42.11 | 18.06 |
| 125 | (1)+(18) | 73.68 | 49.42 |
| 4+1 4∶1 | |||
| 126 | (1)+(18) 1+1 1∶1 | 63.16 | 40.22 |
| 127 | (1)+(18) 0.25+1 1∶4 | 31.58 | 19.99 |
| 128 | (1)+(19) 4+1 4∶1 | 78.95 | 53.07 |
| 129 | (1)+(19) 1+1 1∶1 | 68.42 | 44.54 |
| 130 | (1)+(19) 0.025+1 1∶4 | 38.95 | 25.77 |
"
*": the effectiveness of using the Colby formula to calculate.
The 6 control gray mold of cucumber tests of application implementation example
Cultivar is sprayed to the drip point for the aqueous suspension that the potted plant cucumber seedling leaf of " the close thorn in Shandong " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of ash arrhizus bacteria (Botrytis cinerea).Place 22～24 ℃ to be that 95～99% climatic chambers are regulated 7 days test plants then with relative atmospheric humidity.Naked eyes are measured the development degree of infection process on the leaf then.
The reactive compound that table 11 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 131 | Contrast (being untreated) | - | (95% infects) |
| 132 | (1) azoles bacterium ester | 4 | 22.22 |
| 2 | 13.33 | ||
| 1 | 3.33 | ||
| 133 | (21) the mould prestige of second | 4 | 8.89 |
| 134 | (22) iprovalicarb | 4 | 7.78 |
| 135 | (23) benzene metsulfovax | 4 | 11.11 |
| 136 | (24) methasulfocarb | 4 | 5.56 |
| 137 | (25) Propamocarb | 4 | 7.78 |
Table 12 composition of the present invention
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 138 | (1)+(21) 4+4 1∶1 | 44.44 | 29.14 |
| 139 | (1)+(21) 2+4 1∶2 | 33.33 | 21.04 |
| 140 | (1)+(21) 1+4 1∶4 | 22.10 | 11.93 |
| 141 | (1)+(22) 4+4 1∶1 | 50.00 | 28.27 |
| 142 | (1)+(22) 2+4 1∶2 | 33.33 | 20.07 |
| 143 | (1)+(22) 1+4 1∶4 | 16.67 | 10.85 |
| 144 | (1)+(23) 4+4 1∶1 | 44.44 | 30.86 |
| 145 | (1)+(23) 2+4 1∶2 | 35.56 | 22.96 |
| 146 | (1)+(23) 1+4 1∶4 | 24.44 | 14.07 |
| 147 | (1)+(24) 4+4 1∶1 | 38.89 | 26.54 |
| 148 | (1)+(24) | 25.56 | 18.15 |
| 2+4 1∶2 | |||
| 149 | (1)+(24) 1+4 1∶4 | 16.67 | 8.70 |
| 150 | (1)+(25) 4+4 1∶1 | 41.11 | 28.27 |
| 151 | (1)+(25) 2+4 1∶2 | 30.00 | 20.07 |
| 152 | (1)+(25) 1+4 1∶4 | 16.67 | 10.85 |
"
*": the effectiveness of using the Colby formula to calculate.
The 7 control rice blast tests of application implementation example
Cultivar is sprayed to the drip point for the aqueous suspension that the pot rice seedling leaf of " light more " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of Pyricularia oryzae (Pyricularia grisea).Place 24～28 ℃ to be that 95～99% climatic chambers are regulated 5 days test plants then with relative atmospheric humidity.Naked eyes are measured the development degree of infection process on the leaf then.
The reactive compound that table 29 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 153 | Contrast (being untreated) | - | (95% infects) |
| 154 | (1) azoles bacterium ester | 4 | 31.58 |
| 155 | (26) blasticidin-S | 8 4 2 | 26.32 17.89 12.63 |
| 156 | (27) kasugarnycin | 8 4 2 | 21.05 13.68 5.26 |
| 157 | (28) polyoxin | 8 4 2 | 18.95 15.79 10.53 |
| 158 | (29) Polyoxin | 8 | 21.05 |
| 4 2 | 15.79 5.26 |
Table 30 composition of the present invention
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 159 | (1)+(26) 4+8 1∶2 | 67.68 | 49.58 |
| 160 | (1)+(26) 4+4 1∶1 | 63.16 | 43.82 |
| 161 | (1)+(26) 4+2 2∶1 | 57.89 | 40.22 |
| 162 | (1)+(27) 4+8 1∶2 | 68.42 | 45.98 |
| 163 | (1)+(27) 4+4 1∶1 | 62.11 | 40.94 |
| 164 | (1)+(27) 4+2 2∶1 | 52.63 | 35.18 |
| 165 | (1)+(28) 4+8 1∶2 | 66.32 | 44.54 |
| 166 | (1)+(28) 4+4 1∶1 | 61.05 | 42.38 |
| 167 | (1)+(28) 4+2 2∶1 | 57.89 | 38.78 |
| 168 | (1)+(29) 4+8 | 68.42 | 45.98 |
| 1∶2 | |||
| 169 | (1)+(29) 4+4 1∶1 | 63.16 | 42.38 |
| 170 | (1)+(29) 4+2 2∶1 | 52.63 | 35.18 |
"
*": the effectiveness of using the Colby formula to calculate.
The 8 control cucumber downy mildew tests of application implementation example
Cultivar is sprayed to the drip point for the aqueous suspension that the potted plant cucumber seedling leaf of " Chang Chun Mi Ci " is described below with activity compound concentration.Second day, with the spore aqueous suspension inoculation plant of Pseudoperonospora cubensis (Pseudoperonospora cubensis).Place 22～24 ℃ to be that 90% climatic chamber is regulated 7 days test plants then with relative atmospheric humidity.The development degree of infection process on the leaf is measured in range estimation then.
The reactive compound that table 31 is independent
| The experiment number | Reactive compound | The concentration (mg/L) of reactive compound in spray liquid | Observed effectiveness (%) |
| 171 | Contrast (being untreated) | - | (95% infects) |
| 172 | (1) azoles bacterium ester | 3 | 57.89 |
| 2 | 42.11 | ||
| 1 | 36.84 | ||
| 173 | (30) flumorph | 6 | 16.84 |
| 174 | (31) dimethomorph | 6 | 13.68 |
Table 32 composition of the present invention
| The experiment number | Active compound combinations/concentration (mg/L)/mixing ratio | Observed effectiveness (%) | The effectiveness of calculating (%) * |
| 175 | (1)+(30) 3+6 1∶2 | 81.05 | 64.99 |
| 176 | (1)+(30) 2+6 1∶3 | 63.16 | 51.86 |
| 177 | (1)+(30) 1+6 1∶6 | 57.89 | 47.48 |
| 178 | (1)+(31) 3+6 1∶2 | 76.84 | 63.66 |
| 179 | (1)+(31) 2+6 1∶3 | 64.21 | 50.03 |
| 180 | (1)+(31) 1+6 1∶6 | 55.79 | 45.48 |
"
*": the effectiveness of using the Colby formula to calculate.
Claims (4)
1. Fungicidal composition, the following compound that comprises Synergistic is selected from (E)-2-(2-((3-(4-chlorphenyl)-1-methyl isophthalic acid H-pyrazoles-5-base oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate as active component: component A;
B component is selected from triazole class compounds (B
1), described triazole class compounds is selected from fluorine ring azoles, triazolone, Difenoconazole, alkene azoles alcohol, nitrile bacterium azoles, propiconazole or Tebuconazole;
Weight ratio in the composition between A, B two components is 1: 50～50: 1; The weight content of active component is 0.1～95% in the composition.
2. according to the described Fungicidal composition of claim 1, it is characterized in that:
Weight ratio in the composition between A, B two components is 1: 40～40: 1.
3. according to the described Fungicidal composition of claim 2, it is characterized in that:
Weight ratio in the composition between A, B two components is 1: 40～4: 1, and described B component is selected from fluorine ring azoles, triazolone, Difenoconazole, alkene azoles alcohol, nitrile bacterium azoles or Tebuconazole.
According to the described Fungicidal composition of claim 1 in the application aspect control cereal crop, the vegetable fungi disease.
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| CN 201110409917 Division CN102511490B (en) | 2007-10-09 | 2007-10-09 | Fungus killing composition |
| CN 201210012332 Division CN102578130B (en) | 2007-10-09 | 2007-10-09 | Fungicidal composition |
| CN 201210012456 Division CN102578125B (en) | 2007-10-09 | 2007-10-09 | Fungicidal composition |
| CN 201210012335 Division CN102578100B (en) | 2007-10-09 | 2007-10-09 | Antifungal composition |
| CN 201110410209 Division CN102422837B (en) | 2007-10-09 | 2007-10-09 | Antifungal composition |
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| CN102106355B (en) * | 2009-12-23 | 2013-02-27 | 中国中化股份有限公司 | Antifungal composition containing pyraoxystrobin |
| CN104170837B (en) * | 2009-12-23 | 2016-06-29 | 沈阳中化农药化工研发有限公司 | A kind of Fungicidal composition containing pyraoxystrobin |
| CN103053606B (en) * | 2009-12-23 | 2014-08-06 | 中国中化股份有限公司 | Antifungal composition containing pyraoxystrobin |
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| CN105532696B (en) * | 2013-11-19 | 2018-07-03 | 沈阳中化农药化工研发有限公司 | Fungicidal composition and its application |
| CN103563947B (en) * | 2013-11-19 | 2015-08-19 | 中国中化股份有限公司 | A kind of Fungicidal composition and application thereof |
| EP4014738A1 (en) | 2013-11-26 | 2022-06-22 | UPL Ltd | A method for controlling rust |
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| CN104336036B (en) * | 2014-10-14 | 2017-04-12 | 沈阳中化农药化工研发有限公司 | Fungicidal composition and application thereof |
| CN105766945B (en) * | 2014-12-23 | 2018-08-31 | 沈阳中化农药化工研发有限公司 | A kind of Fungicidal composition and its application |
| CN106256204A (en) * | 2015-06-17 | 2016-12-28 | 沈阳中化农药化工研发有限公司 | A kind of insecticidal and bactericidal composition |
| CN106804601A (en) * | 2017-03-16 | 2017-06-09 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of bactericidal composition containing pyraoxystrobin and probenazole and application thereof |
| CN112471162B (en) * | 2020-12-02 | 2023-06-30 | 青岛海利尔生物科技有限公司 | Sterilization composition containing tetramycin and pyraclostrobin |
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