CN109056389A - With uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/polyester fibre/spandex fabric dyeing and finishing process - Google Patents

With uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/polyester fibre/spandex fabric dyeing and finishing process Download PDF

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Publication number
CN109056389A
CN109056389A CN201810714672.7A CN201810714672A CN109056389A CN 109056389 A CN109056389 A CN 109056389A CN 201810714672 A CN201810714672 A CN 201810714672A CN 109056389 A CN109056389 A CN 109056389A
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China
Prior art keywords
uvioresistant
crease
drying
fabric
polyester fibre
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CN201810714672.7A
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Chinese (zh)
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CN109056389B (en
Inventor
黄庄芳容
侯丽丽
梁军
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Changzhou New Wide Knitting & Dyeing Co Ltd
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Changzhou New Wide Knitting & Dyeing Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402Amides imides, sulfamic acids
    • D06M13/432Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/41General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using basic dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/38Polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/20Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments

Abstract

The invention discloses it is a kind of with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/polyester fibre/spandex fabric dyeing and finishing process, it has follow steps: 1. fabric being immersed in dye liquor, adding acid for adjusting pH is 4.0~5.0, is then handled in 110 DEG C~130 DEG C dyeing;2. fabric successively to be carried out to hot water wash, reduction cleaning and acid to neutralize;3. fabric is first dehydrated, post-finishing liquid is then padded, finally bakes sizing.Method of the invention only carries out crease-resistant functionalization in final finishing link, and uvioresistant functionization with absorbent functionization is carried out simultaneously with dyeing, and special water suction processing agent and ultraviolet absorbing agent are used for fabric of the invention, the special functionalization mode can especially obtain preferable anti-ultraviolet function and moisture-absorbing and fast-drying function, and the CDP fabrics/polyester fibre/spandex fabric is finally enabled to be provided simultaneously with the preferable uvioresistant of effect, absorbing fast-drying, crease-resistant three kinds of functions.

Description

With uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process
Technical field
The invention belongs to technical field of textile printing, and in particular to one kind has uvioresistant, absorbing fast-drying, crease-resistant compound The CDP fabrics of function/polyester fibre/spandex fabric dyeing and finishing process.
Background technique
Increasingly mature with functions of textile fabrics processing technology, the requirement to functions of textile fabrics is also higher and higher.Single function The textile of energy can no longer meet the demand of specific area, and there are broad mass markets for complex function textile.
The functionalization of fabric there are mainly two types of approach:
(1) functional fiber is first prepared, then prepares functionalization fabric.
The approach is primarily adapted for use in chemical fibre, and advantage is that functionalization effect is preferable, disadvantage be then process equipment requirement compared with Height, production cost are higher.
(2) functionalization final finishing is carried out to common fabric.
The approach is primarily adapted for use in natural fiber, that is, the functionalization effect for natural fiber is preferable, and for chemistry The functionalization of fiber is ineffective, and especially Complex Function effect is more undesirable.
Summary of the invention
The purpose of the present invention is to solve the above problem, provides that a kind of process equipment is simple, lower production costs, functionalization Effect preferably has the CDP fabrics/polyester fibre/spandex fabric dye of uvioresistant, absorbing fast-drying, crease-resistant complex function Whole technique.
Realize the object of the invention technical solution be: it is a kind of with uvioresistant, absorbing fast-drying, crease-resistant complex function sun Ion can contaminate terylene/polyester fibre/spandex fabric dyeing and finishing process, have follow steps:
1. the CDP fabrics/polyester fibre/spandex fabric is immersed in dye liquor, adding acid for adjusting pH is 4.0~5.0, then 110 DEG C~130 DEG C at a temperature of dyeing processing 20min~60min;
The dye liquor is every liter containing 1.0g~3.0g refining emulsifier, 0.5g~3.0g suspending agent, 3.0g~6.0g member Bright powder, 2.0g~4.0g water suction processing agent, 1.0g~4.0g ultraviolet absorbing agent and 0.1g~4.0g dye of positive ion water Solution;And the total weight of the dye of positive ion is the 0.1%~4.0% of fabric weight;
2. 1. dyeing that treated by step, fabric first carries out 50 DEG C~70 DEG C of hot water wash 8min~15min, then carries out 85 DEG C~95 DEG C of reduction cleaning 15min~30min finally carries out 10 DEG C~40 DEG C of acid and neutralizes 5min~30min;
3. will by step, 2. treated that fabric is first dehydrated, post-finishing liquid is then padded, finally at 150 DEG C~200 DEG C Bake sizing 100~150 seconds.
Above-mentioned steps 1. described in refining emulsifier main component be polyoxyethylene nonylphenol ether;The precipitating is anti- Only the main component of agent is fatty alcohol polyoxyethylene ether;The dye of positive ion is cationic black dyestuff Sunacryl Black CD-BR H/C and/or cation navy dye Sunacryl Navy Blue SDR.
Above-mentioned steps 1. described in water suction processing agent main component be polyether polyester.
Above-mentioned steps 1. described in ultraviolet absorbing agent main component be polyoxyethylene sorbitol acid anhydride laurate.
Above-mentioned steps 2. described in reduction cleaning contain the water-soluble of 1.5g~4.0g acidic reduction agent using every liter Liquid;Above-mentioned steps 2. described in acid neutralize using every liter of aqueous solution containing 0.5g~1.0g citric acid.
The main component of the acidic reduction agent is sodium hydrogensulfite.
Above-mentioned steps 3. described in post-finishing liquid be every liter of nothing containing 50g~150g textile wash and wear noniron finish The aqueous solution of formaldehyde crosslinking agent.
The main component of the formaldehyde-less crosslinker of the textile wash and wear noniron finish is modified dimethyl dihydroxy Base ethylene urea.
Above-mentioned steps 1. described in the CDP fabrics/polyester fibre/spandex fabric be the CDP fabrics fiber, wash Fabric or the CDP fabrics fiber, polyester fiber that synthetic fibre fiber and spandex fibre interweave and spandex fibre is blended knits Object.
The good effect that the present invention has: method of the invention only carries out crease-resistant functionalization in final finishing link, And uvioresistant functionization is then to carry out simultaneously with dyeing, and use special suction for fabric of the invention with absorbent functionization Water processing agent and ultraviolet absorbing agent, the special functionalization mode can especially obtain preferable anti-ultraviolet function and suction Wet drying function finally enables to the CDP fabrics/polyester fibre/spandex fabric to be provided simultaneously with the preferable uvioresistant of effect Line, absorbing fast-drying, crease-resistant three kinds of functions.
Specific embodiment
(embodiment 1)
The CDP fabrics/the polyester fibre/spandex with uvioresistant, absorbing fast-drying, crease-resistant complex function of the present embodiment is knitted Object dyeing and finishing technology has follow steps:
1. the CDP fabrics/polyester fibre/spandex fabric is immersed in dye liquor, adding acid for adjusting pH is 4.5, then at 120 DEG C At a temperature of dyeing processing 30min.
The dye liquor is every liter containing 1.4g refining emulsifier, 0.9g suspending agent, 5.0g anhydrous sodium sulphate, 2.5g water suction processing The aqueous solution of agent, 2.0g ultraviolet absorbing agent and the 2.55g dye of positive ion;And the total weight of the dye of positive ion is fabric weight The 2.55% of amount.
Wherein, refining emulsifier refines emulsifier using the SEM-35N for abiding by chemical inc's production, Main component is polyoxyethylene nonylphenol ether;It is heavy that suspending agent is produced using Jiangsu De Wang chemical engineering industry Co., Ltd Shallow lake preventing agent HT-77, main component are fatty alcohol polyoxyethylene ether.
Processing agent absorb water using Wuxi Tai Zhan Chemical Industry Science Co., Ltd (or limited public affairs of platform circle chemical industry share Department) production ABLUTEX QM-200A, main component is polyether polyester (namely terephthalic acid (TPA) and ethylene glycol and poly- second two The polymer of alcohol, No. CAS is 9016-88-0).
The Hipom UV-330 that ultraviolet absorbing agent is produced using Suzhou Wei Ming chemical industry Co., Ltd, it is main Ingredient is polyoxyethylene sorbitol acid anhydride laurate (namely Tween-20).
The cationic black dyestuff Sunacryl that the dye of positive ion is produced using Jiangsu De Wang chemical engineering industry Co., Ltd Black CD-BR H/C and cation navy dye Sunacryl Navy Blue SDR;Wherein, cationic black dyestuff The weight of Sunacryl Black CD-BR H/C is the 2.0% of fabric weight, cationic navy dye Sunacryl Navy The weight of Blue SDR is the 0.55% of fabric weight.
The CDP fabrics that the present embodiment uses/polyester fibre/spandex fabric is+44% terylene of 44% the CDP fabrics + 12% spandex intertexture Cotton Stretch Knitted.
2. 1. dyeing that treated by step, fabric first carries out the hot water wash of 60 DEG C × 10min, then carry out 90 DEG C × The reduction cleaning of 20min, the acid for finally carrying out 20 DEG C × 10min neutralize.
Wherein, reduction cleaning is neutralized using every liter of aqueous solution containing 2.0g acidic reduction agent, acid using every Rise the aqueous solution containing 0.7g citric acid.
Wherein, the HC007 acidic reduction agent that acidic reduction agent is produced using Hong Chen Chemical Co., Ltd. of Suzhou City, Main component is sodium hydrogensulfite.
3. will by step, 2. treated that fabric is first dehydrated, then pad post-finishing liquid, using second dipping and rolling, roll Remaining rate is 80~85%, and sizing 120 seconds is finally baked at 180 DEG C.
The post-finishing liquid is the aqueous solution of every liter of formaldehyde-less crosslinker containing 80g textile wash and wear noniron finish.
Wherein, the formaldehyde-less crosslinker of textile wash and wear noniron finish is raw using BASF China The flat NF of clothes silk of production, main component are modified dimethyl dihydroxy ethylene urea.
(2~embodiment of embodiment 5)
The dyeing and finishing technology of each embodiment is substantially the same manner as Example 1, and difference is shown in Table 1.
Table 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5
The CDP fabrics/wash Synthetic fibre/spandex fabric 44% the CDP fabrics+44% are washed + 12% spandex intertexture Cotton Stretch Knitted of synthetic fibre 40% the CDP fabrics+45% are washed + 15% spandex intertexture Cotton Stretch Knitted of synthetic fibre 45% the CDP fabrics+40% are washed + 15% spandex intertexture Cotton Stretch Knitted of synthetic fibre 55% the CDP fabrics+40% are washed + 5% spandex intertexture Cotton Stretch Knitted of synthetic fibre + 40% terylene of 50% the CDP fabrics + 10% spandex intertexture Cotton Stretch Knitted
Cationic black dyestuff Sunacryl Black CD- BR H/C 2.0% 2.0% 1.0% 0.8% 2.3%
Cationic navy dye Sunacryl Navy Blue SDR 0.55% 0.5% 1.0% 1.5% 0.5%
UV protection factor (UPF) 57.2 55.6 53.9 54.2 55.1
Humidity exposure time 0″55 0″68 0″38 0″76 0″72
Evaporation rate (g/cm2S) 1.03×104 1.04×104 1.02×104 1.05×104 1.04×104
Fabric flatness 4 grades 4 grades 4 grades 4 grades 4 grades
Wherein, fabric flatness is according to U.S. textile chemist and printing and dyeing teacher's association criterion " AATCC 128-2013 ".
(1~comparative example of comparative example 3)
The dyeing and finishing technology of each comparative example is substantially the same manner as Example 1, and difference is shown in Table 2.
Table 2
Embodiment 1 Comparative example 1 Comparative example 2 Comparative example 3
Ultraviolet absorbing agent type Hipom UV-330 UV-P UV-531 Hipom UV-330
Ultraviolet absorbing agent processing mode Step is 1. in dye liquor Step is 1. in dye liquor Step is 1. in dye liquor Step is 3. in post-finishing liquid
UV protection factor (UPF) 57.2 42.8 39.5 41.7

Claims (10)

1. a kind of the CDP fabrics/polyester fibre/spandex fabric with uvioresistant, absorbing fast-drying, crease-resistant complex function contaminates Whole technique, it is characterised in that have follow steps:
1. the CDP fabrics/polyester fibre/spandex fabric is immersed in dye liquor, adding acid for adjusting pH is 4.0~5.0, then 110 DEG C~130 DEG C at a temperature of dyeing processing 20min~60min;
The dye liquor is every liter containing 1.0g~3.0g refining emulsifier, 0.5g~3.0g suspending agent, 3.0g~6.0g member Bright powder, 2.0g~4.0g water suction processing agent, 1.0g~4.0g ultraviolet absorbing agent and 0.1g~4.0g dye of positive ion water Solution;And the total weight of the dye of positive ion is the 0.1%~4.0% of fabric weight;
2. 1. dyeing that treated by step, fabric first carries out 50 DEG C~70 DEG C of hot water wash 8min~15min, then carries out 85 DEG C~95 DEG C of reduction cleaning 15min~30min finally carries out 10 DEG C~40 DEG C of acid and neutralizes 5min~30min;
3. will by step, 2. treated that fabric is first dehydrated, post-finishing liquid is then padded, finally at 150 DEG C~200 DEG C Bake sizing 100~150 seconds.
2. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in refining emulsifier main component be polyoxy Nonylphenol ethylene ether;The main component of the suspending agent is fatty alcohol polyoxyethylene ether.
3. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in water suction processing agent main component be polyethers Polyester.
4. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in the main component of ultraviolet absorbing agent be poly- Ethylene oxide sorbitol anhydride laurate.
5. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in the dye of positive ion be cationic black dyestuff Sunacryl Black CD-BR H/C and/or cation navy dye Sunacryl Navy Blue SDR.
6. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 2. described in reduction cleaning contain using every liter The aqueous solution of 1.5g~4.0g acidic reduction agent;Above-mentioned steps 2. described in acid neutralize using every liter containing 0.5g~ The aqueous solution of 1.0g citric acid.
7. it is according to claim 6 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: the main component of the acidic reduction agent is sodium hydrogensulfite.
8. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 3. described in post-finishing liquid be every liter containing 50g~ The aqueous solution of the formaldehyde-less crosslinker of 150g textile wash and wear noniron finish.
9. it is according to claim 8 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: the master of the formaldehyde-less crosslinker of the textile wash and wear noniron finish Wanting ingredient is modified dimethyl dihydroxy ethylene urea.
10. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/ Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in the CDP fabrics/polyester fibre/spandex knit Object is the fabric that the CDP fabrics fiber, polyester fiber and spandex fibre interweave or the CDP fabrics fiber, washs Synthetic fibre fiber and spandex fibre blended fabric.
CN201810714672.7A 2018-07-03 2018-07-03 Dyeing and finishing process of cationic dyeable terylene/spandex fabric with ultraviolet-resistant, moisture-absorbing, quick-drying and crease-resistant composite functions Active CN109056389B (en)

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