CN109056389A - With uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/polyester fibre/spandex fabric dyeing and finishing process - Google Patents
With uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/polyester fibre/spandex fabric dyeing and finishing process Download PDFInfo
- Publication number
- CN109056389A CN109056389A CN201810714672.7A CN201810714672A CN109056389A CN 109056389 A CN109056389 A CN 109056389A CN 201810714672 A CN201810714672 A CN 201810714672A CN 109056389 A CN109056389 A CN 109056389A
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- China
- Prior art keywords
- uvioresistant
- crease
- drying
- fabric
- polyester fibre
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/41—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using basic dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/38—Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
Abstract
The invention discloses it is a kind of with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/polyester fibre/spandex fabric dyeing and finishing process, it has follow steps: 1. fabric being immersed in dye liquor, adding acid for adjusting pH is 4.0~5.0, is then handled in 110 DEG C~130 DEG C dyeing;2. fabric successively to be carried out to hot water wash, reduction cleaning and acid to neutralize;3. fabric is first dehydrated, post-finishing liquid is then padded, finally bakes sizing.Method of the invention only carries out crease-resistant functionalization in final finishing link, and uvioresistant functionization with absorbent functionization is carried out simultaneously with dyeing, and special water suction processing agent and ultraviolet absorbing agent are used for fabric of the invention, the special functionalization mode can especially obtain preferable anti-ultraviolet function and moisture-absorbing and fast-drying function, and the CDP fabrics/polyester fibre/spandex fabric is finally enabled to be provided simultaneously with the preferable uvioresistant of effect, absorbing fast-drying, crease-resistant three kinds of functions.
Description
Technical field
The invention belongs to technical field of textile printing, and in particular to one kind has uvioresistant, absorbing fast-drying, crease-resistant compound
The CDP fabrics of function/polyester fibre/spandex fabric dyeing and finishing process.
Background technique
Increasingly mature with functions of textile fabrics processing technology, the requirement to functions of textile fabrics is also higher and higher.Single function
The textile of energy can no longer meet the demand of specific area, and there are broad mass markets for complex function textile.
The functionalization of fabric there are mainly two types of approach:
(1) functional fiber is first prepared, then prepares functionalization fabric.
The approach is primarily adapted for use in chemical fibre, and advantage is that functionalization effect is preferable, disadvantage be then process equipment requirement compared with
Height, production cost are higher.
(2) functionalization final finishing is carried out to common fabric.
The approach is primarily adapted for use in natural fiber, that is, the functionalization effect for natural fiber is preferable, and for chemistry
The functionalization of fiber is ineffective, and especially Complex Function effect is more undesirable.
Summary of the invention
The purpose of the present invention is to solve the above problem, provides that a kind of process equipment is simple, lower production costs, functionalization
Effect preferably has the CDP fabrics/polyester fibre/spandex fabric dye of uvioresistant, absorbing fast-drying, crease-resistant complex function
Whole technique.
Realize the object of the invention technical solution be: it is a kind of with uvioresistant, absorbing fast-drying, crease-resistant complex function sun
Ion can contaminate terylene/polyester fibre/spandex fabric dyeing and finishing process, have follow steps:
1. the CDP fabrics/polyester fibre/spandex fabric is immersed in dye liquor, adding acid for adjusting pH is 4.0~5.0, then 110
DEG C~130 DEG C at a temperature of dyeing processing 20min~60min;
The dye liquor is every liter containing 1.0g~3.0g refining emulsifier, 0.5g~3.0g suspending agent, 3.0g~6.0g member
Bright powder, 2.0g~4.0g water suction processing agent, 1.0g~4.0g ultraviolet absorbing agent and 0.1g~4.0g dye of positive ion water
Solution;And the total weight of the dye of positive ion is the 0.1%~4.0% of fabric weight;
2. 1. dyeing that treated by step, fabric first carries out 50 DEG C~70 DEG C of hot water wash 8min~15min, then carries out
85 DEG C~95 DEG C of reduction cleaning 15min~30min finally carries out 10 DEG C~40 DEG C of acid and neutralizes 5min~30min;
3. will by step, 2. treated that fabric is first dehydrated, post-finishing liquid is then padded, finally at 150 DEG C~200 DEG C
Bake sizing 100~150 seconds.
Above-mentioned steps 1. described in refining emulsifier main component be polyoxyethylene nonylphenol ether;The precipitating is anti-
Only the main component of agent is fatty alcohol polyoxyethylene ether;The dye of positive ion is cationic black dyestuff Sunacryl Black
CD-BR H/C and/or cation navy dye Sunacryl Navy Blue SDR.
Above-mentioned steps 1. described in water suction processing agent main component be polyether polyester.
Above-mentioned steps 1. described in ultraviolet absorbing agent main component be polyoxyethylene sorbitol acid anhydride laurate.
Above-mentioned steps 2. described in reduction cleaning contain the water-soluble of 1.5g~4.0g acidic reduction agent using every liter
Liquid;Above-mentioned steps 2. described in acid neutralize using every liter of aqueous solution containing 0.5g~1.0g citric acid.
The main component of the acidic reduction agent is sodium hydrogensulfite.
Above-mentioned steps 3. described in post-finishing liquid be every liter of nothing containing 50g~150g textile wash and wear noniron finish
The aqueous solution of formaldehyde crosslinking agent.
The main component of the formaldehyde-less crosslinker of the textile wash and wear noniron finish is modified dimethyl dihydroxy
Base ethylene urea.
Above-mentioned steps 1. described in the CDP fabrics/polyester fibre/spandex fabric be the CDP fabrics fiber, wash
Fabric or the CDP fabrics fiber, polyester fiber that synthetic fibre fiber and spandex fibre interweave and spandex fibre is blended knits
Object.
The good effect that the present invention has: method of the invention only carries out crease-resistant functionalization in final finishing link,
And uvioresistant functionization is then to carry out simultaneously with dyeing, and use special suction for fabric of the invention with absorbent functionization
Water processing agent and ultraviolet absorbing agent, the special functionalization mode can especially obtain preferable anti-ultraviolet function and suction
Wet drying function finally enables to the CDP fabrics/polyester fibre/spandex fabric to be provided simultaneously with the preferable uvioresistant of effect
Line, absorbing fast-drying, crease-resistant three kinds of functions.
Specific embodiment
(embodiment 1)
The CDP fabrics/the polyester fibre/spandex with uvioresistant, absorbing fast-drying, crease-resistant complex function of the present embodiment is knitted
Object dyeing and finishing technology has follow steps:
1. the CDP fabrics/polyester fibre/spandex fabric is immersed in dye liquor, adding acid for adjusting pH is 4.5, then at 120 DEG C
At a temperature of dyeing processing 30min.
The dye liquor is every liter containing 1.4g refining emulsifier, 0.9g suspending agent, 5.0g anhydrous sodium sulphate, 2.5g water suction processing
The aqueous solution of agent, 2.0g ultraviolet absorbing agent and the 2.55g dye of positive ion;And the total weight of the dye of positive ion is fabric weight
The 2.55% of amount.
Wherein, refining emulsifier refines emulsifier using the SEM-35N for abiding by chemical inc's production,
Main component is polyoxyethylene nonylphenol ether;It is heavy that suspending agent is produced using Jiangsu De Wang chemical engineering industry Co., Ltd
Shallow lake preventing agent HT-77, main component are fatty alcohol polyoxyethylene ether.
Processing agent absorb water using Wuxi Tai Zhan Chemical Industry Science Co., Ltd (or limited public affairs of platform circle chemical industry share
Department) production ABLUTEX QM-200A, main component is polyether polyester (namely terephthalic acid (TPA) and ethylene glycol and poly- second two
The polymer of alcohol, No. CAS is 9016-88-0).
The Hipom UV-330 that ultraviolet absorbing agent is produced using Suzhou Wei Ming chemical industry Co., Ltd, it is main
Ingredient is polyoxyethylene sorbitol acid anhydride laurate (namely Tween-20).
The cationic black dyestuff Sunacryl that the dye of positive ion is produced using Jiangsu De Wang chemical engineering industry Co., Ltd
Black CD-BR H/C and cation navy dye Sunacryl Navy Blue SDR;Wherein, cationic black dyestuff
The weight of Sunacryl Black CD-BR H/C is the 2.0% of fabric weight, cationic navy dye Sunacryl Navy
The weight of Blue SDR is the 0.55% of fabric weight.
The CDP fabrics that the present embodiment uses/polyester fibre/spandex fabric is+44% terylene of 44% the CDP fabrics
+ 12% spandex intertexture Cotton Stretch Knitted.
2. 1. dyeing that treated by step, fabric first carries out the hot water wash of 60 DEG C × 10min, then carry out 90 DEG C ×
The reduction cleaning of 20min, the acid for finally carrying out 20 DEG C × 10min neutralize.
Wherein, reduction cleaning is neutralized using every liter of aqueous solution containing 2.0g acidic reduction agent, acid using every
Rise the aqueous solution containing 0.7g citric acid.
Wherein, the HC007 acidic reduction agent that acidic reduction agent is produced using Hong Chen Chemical Co., Ltd. of Suzhou City,
Main component is sodium hydrogensulfite.
3. will by step, 2. treated that fabric is first dehydrated, then pad post-finishing liquid, using second dipping and rolling, roll
Remaining rate is 80~85%, and sizing 120 seconds is finally baked at 180 DEG C.
The post-finishing liquid is the aqueous solution of every liter of formaldehyde-less crosslinker containing 80g textile wash and wear noniron finish.
Wherein, the formaldehyde-less crosslinker of textile wash and wear noniron finish is raw using BASF China
The flat NF of clothes silk of production, main component are modified dimethyl dihydroxy ethylene urea.
(2~embodiment of embodiment 5)
The dyeing and finishing technology of each embodiment is substantially the same manner as Example 1, and difference is shown in Table 1.
Table 1
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
The CDP fabrics/wash Synthetic fibre/spandex fabric | 44% the CDP fabrics+44% are washed + 12% spandex intertexture Cotton Stretch Knitted of synthetic fibre | 40% the CDP fabrics+45% are washed + 15% spandex intertexture Cotton Stretch Knitted of synthetic fibre | 45% the CDP fabrics+40% are washed + 15% spandex intertexture Cotton Stretch Knitted of synthetic fibre | 55% the CDP fabrics+40% are washed + 5% spandex intertexture Cotton Stretch Knitted of synthetic fibre | + 40% terylene of 50% the CDP fabrics + 10% spandex intertexture Cotton Stretch Knitted |
Cationic black dyestuff Sunacryl Black CD- BR H/C | 2.0% | 2.0% | 1.0% | 0.8% | 2.3% |
Cationic navy dye Sunacryl Navy Blue SDR | 0.55% | 0.5% | 1.0% | 1.5% | 0.5% |
UV protection factor (UPF) | 57.2 | 55.6 | 53.9 | 54.2 | 55.1 |
Humidity exposure time | 0″55 | 0″68 | 0″38 | 0″76 | 0″72 |
Evaporation rate (g/cm2S) | 1.03×104 | 1.04×104 | 1.02×104 | 1.05×104 | 1.04×104 |
Fabric flatness | 4 grades | 4 grades | 4 grades | 4 grades | 4 grades |
Wherein, fabric flatness is according to U.S. textile chemist and printing and dyeing teacher's association criterion " AATCC 128-2013 ".
(1~comparative example of comparative example 3)
The dyeing and finishing technology of each comparative example is substantially the same manner as Example 1, and difference is shown in Table 2.
Table 2
Embodiment 1 | Comparative example 1 | Comparative example 2 | Comparative example 3 | |
Ultraviolet absorbing agent type | Hipom UV-330 | UV-P | UV-531 | Hipom UV-330 |
Ultraviolet absorbing agent processing mode | Step is 1. in dye liquor | Step is 1. in dye liquor | Step is 1. in dye liquor | Step is 3. in post-finishing liquid |
UV protection factor (UPF) | 57.2 | 42.8 | 39.5 | 41.7 |
Claims (10)
1. a kind of the CDP fabrics/polyester fibre/spandex fabric with uvioresistant, absorbing fast-drying, crease-resistant complex function contaminates
Whole technique, it is characterised in that have follow steps:
1. the CDP fabrics/polyester fibre/spandex fabric is immersed in dye liquor, adding acid for adjusting pH is 4.0~5.0, then 110
DEG C~130 DEG C at a temperature of dyeing processing 20min~60min;
The dye liquor is every liter containing 1.0g~3.0g refining emulsifier, 0.5g~3.0g suspending agent, 3.0g~6.0g member
Bright powder, 2.0g~4.0g water suction processing agent, 1.0g~4.0g ultraviolet absorbing agent and 0.1g~4.0g dye of positive ion water
Solution;And the total weight of the dye of positive ion is the 0.1%~4.0% of fabric weight;
2. 1. dyeing that treated by step, fabric first carries out 50 DEG C~70 DEG C of hot water wash 8min~15min, then carries out
85 DEG C~95 DEG C of reduction cleaning 15min~30min finally carries out 10 DEG C~40 DEG C of acid and neutralizes 5min~30min;
3. will by step, 2. treated that fabric is first dehydrated, post-finishing liquid is then padded, finally at 150 DEG C~200 DEG C
Bake sizing 100~150 seconds.
2. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in refining emulsifier main component be polyoxy
Nonylphenol ethylene ether;The main component of the suspending agent is fatty alcohol polyoxyethylene ether.
3. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in water suction processing agent main component be polyethers
Polyester.
4. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in the main component of ultraviolet absorbing agent be poly-
Ethylene oxide sorbitol anhydride laurate.
5. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in the dye of positive ion be cationic black dyestuff
Sunacryl Black CD-BR H/C and/or cation navy dye Sunacryl Navy Blue SDR.
6. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 2. described in reduction cleaning contain using every liter
The aqueous solution of 1.5g~4.0g acidic reduction agent;Above-mentioned steps 2. described in acid neutralize using every liter containing 0.5g~
The aqueous solution of 1.0g citric acid.
7. it is according to claim 6 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: the main component of the acidic reduction agent is sodium hydrogensulfite.
8. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 3. described in post-finishing liquid be every liter containing 50g~
The aqueous solution of the formaldehyde-less crosslinker of 150g textile wash and wear noniron finish.
9. it is according to claim 8 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: the master of the formaldehyde-less crosslinker of the textile wash and wear noniron finish
Wanting ingredient is modified dimethyl dihydroxy ethylene urea.
10. it is according to claim 1 with uvioresistant, absorbing fast-drying, crease-resistant complex function the CDP fabrics/
Polyester fibre/spandex fabric dyeing and finishing process, it is characterised in that: above-mentioned steps 1. described in the CDP fabrics/polyester fibre/spandex knit
Object is the fabric that the CDP fabrics fiber, polyester fiber and spandex fibre interweave or the CDP fabrics fiber, washs
Synthetic fibre fiber and spandex fibre blended fabric.
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CN201810714672.7A CN109056389B (en) | 2018-07-03 | 2018-07-03 | Dyeing and finishing process of cationic dyeable terylene/spandex fabric with ultraviolet-resistant, moisture-absorbing, quick-drying and crease-resistant composite functions |
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CN201810714672.7A CN109056389B (en) | 2018-07-03 | 2018-07-03 | Dyeing and finishing process of cationic dyeable terylene/spandex fabric with ultraviolet-resistant, moisture-absorbing, quick-drying and crease-resistant composite functions |
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