CN106223061A - The CDP fabrics/terylene/chinlon/spandex fabric dyeing method - Google Patents

The CDP fabrics/terylene/chinlon/spandex fabric dyeing method Download PDF

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Publication number
CN106223061A
CN106223061A CN201610540248.6A CN201610540248A CN106223061A CN 106223061 A CN106223061 A CN 106223061A CN 201610540248 A CN201610540248 A CN 201610540248A CN 106223061 A CN106223061 A CN 106223061A
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China
Prior art keywords
fabric
dye
acid
terylene
chinlon
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CN201610540248.6A
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Chinese (zh)
Inventor
黄庄芳容
侯丽丽
马方方
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Changzhou New Wide Knitting & Dyeing Co Ltd
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Changzhou New Wide Knitting & Dyeing Co Ltd
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Priority to CN201610540248.6A priority Critical patent/CN106223061A/en
Priority to PCT/CN2016/106384 priority patent/WO2018010356A1/en
Publication of CN106223061A publication Critical patent/CN106223061A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613Polyethers without nitrogen
    • D06P1/6131Addition products of hydroxyl groups-containing compounds with oxiranes
    • D06P1/6133Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/621Compounds without nitrogen
    • D06P1/627Sulfates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82Textiles which contain different kinds of fibres
    • D06P3/8204Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8214Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing ester and amide groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds

Abstract

The invention discloses a kind of the CDP fabrics/terylene/chinlon/spandex fabric dyeing method, have steps of: 1. fabric is immersed in the first dye liquor containing refine emulsifying agent, disperse dyes and the dye of positive ion, adding acid for adjusting pH is 4.0~5.5, then processes 20min~60min at a temperature of 120 DEG C~135 DEG C;2. fabric after 1. step processes carries out hot water wash, reduction cleaning and acid successively neutralize;3. being immersed in the second dye liquor containing acid stain by the fabric after 2. step processes, adding acid for adjusting pH is 4.0~7.0, then processes 20min~60min at a temperature of 90 DEG C~105 DEG C;4. the fabric after 3. step processes is carried out room temperature washing, after discharge opeing, carry out acid fixation again.The colouring method of the present invention not only has preferable dyefastness and quality, and shortens dyeing time, decreases water consumption, thus is greatly saved energy consumption.

Description

The CDP fabrics/terylene/chinlon/spandex fabric dyeing method
Technical field
The invention belongs to technical field of textile printing, be specifically related to a kind of the CDP fabrics/terylene/chinlon/spandex Fabric dyeing method.
Background technology
Along with becoming increasingly abundant of textile fiber material, increasing synthetic fibers are developed, and multiple synthesis fibre Dimension blending, intertexture can be learnt from other's strong points to offset one's weaknesses in performance, not only have the wearability such as cold-proof comfort, also because of different dyeabilities Can, make fabric possess polynary color, but this proposes the highest requirement to dyeing and finishing technology.
Ordinary polyester fiber (being the most all called for short polyster fibre) has the advantages such as intensity is high, be unlikely to deform, but exists thoroughly The shortcomings such as gas is poor, hygroscopicity is poor.The advantages such as nylon fibre wearability is fabulous, good hygroscopicity, but there is poor air permeability, easily wrinkle Roll over, be easily generated the shortcomings such as electrostatic.Spandex fibre has splendid elasticity, but intensity difference, hygroscopicity are poor.The CDP fabrics (English name is Cationic Dyeable PET to fiber, and chemical name is polyethylene terephthalate-5-sodium sulfo group isophthalic Dicarboxylic acid esters copolymer, also known as Cationic Dyeable Pet fiber) have the advantages that anti-ball top is good, soft, woolens can be imitated Thing.
Fine with chinlon for polyster fibre and the CDP fabrics fiber blend or union and polyster fibre Tie up blending or the fabric of intertexture and colouring method thereof, existing document report.
But nylon fibre, the CDP fabrics fiber, polyster fibre and spandex fibre are interweaved or blending Fabric and colouring method thereof, the most not yet find pertinent literature report.
Summary of the invention
It is an object of the invention to solve the problems referred to above, it is provided that the cation that a kind of Color is preferable, energy consumption is relatively low can Dye terylene/terylene/chinlon/spandex fabric dyeing method.
The technical scheme realizing above-mentioned purpose of the present invention is: a kind of the CDP fabrics/terylene/chinlon/spandex fabric Colouring method, has steps of:
1. fabric is immersed in the first dye liquor containing refine emulsifying agent, disperse dyes and the dye of positive ion, adds acid for adjusting pH It is 4.0~5.5, at a temperature of 120 DEG C~135 DEG C, then processes 20min~60min, then be cooled to less than 60 DEG C discharge opeings;
2. the fabric after 1. step processes first is carried out 50 DEG C~hot water wash 10min of 70 DEG C~20min, then carries out 60 DEG C ~reduction cleaning 20min of 80 DEG C~30min, the acid finally carrying out 55 DEG C~65 DEG C neutralizes 10min~30min;
3. the fabric after 2. step processes is immersed in the second dye liquor containing acid stain, add acid for adjusting pH be 4.0~ 7.0, at a temperature of 90 DEG C~105 DEG C, then process 20min~60min, then be cooled to less than 60 DEG C discharge opeings;
4. the fabric after 3. step processes first is carried out room temperature (15 DEG C~25 DEG C, lower same) washing, after discharge opeing, then carries out 50 DEG C~acid fixation 15min of 60 DEG C~30min.
Above-mentioned steps 1. described in the first dye liquor be every liter high containing 1.0g~3.0g refine emulsifying agent, 0.5g~1.0g Temperature dispersion dye leveller, 3.0g~7.0g Matrii Sulfas Exsiccatus, 0.5g~1.5g suspending agent, 0.01g~2.0g disperse dyes and The aqueous solution of 0.25g~the 2.5g dye of positive ion;And 0.01%~2.0% that the gross weight of disperse dyes is fabric weight, sun The gross weight of ionic dye is the 0.25%~2.5% of fabric weight.
Described refine emulsifying agent be mainly composed of polyoxyethylene nonylphenol ether;The master of described High Temperature Disperse dye leveller Wanting composition is polyoxyethylene 2-Ethyl Hexanol ether and alkyl sulfate compound;Being mainly composed of of described suspending agent Fatty alcohol-polyoxyethylene ether;Described disperse dyes are preferably scattered fluorescent yellow dyestuff Neocron Yellow 10GN;Described The dye of positive ion includes for the dye of positive ion Kayacryl Rhodamine BL-ED of fabric weight 0.05%~0.5% with for knitting The dye of positive ion Kayacryl Blue FP-ED of thing weight 0.2%~2.0%.
Above-mentioned steps 2. described in reduction cleaning use every liter containing 1.0g~2.0g sodium carbonate and 1.0g~ The aqueous solution of 2.0g sodium hydrosulfite;Above-mentioned steps 2. described in acid neutralize and to use every liter containing 0.5g~0.7g glacial acetic acid Aqueous solution.
Above-mentioned steps 3. described in the second dye liquor be every liter containing 1.0g~2.0g acidity dye leveller and 0.05g~3.0g The aqueous solution of acid stain;And 0.05%~3.0% that the gross weight of acid stain is fabric weight.
Described acid dye leveller be mainly composed of alkyl alcohol ethoxylates;Described acid stain is preferably acidity Dyestuff Sunacid Orange GSN.
Above-mentioned steps 4. described in acid fixation use every liter of water-soluble containing 0.5g~1.5g acidic color fixing agent Liquid;Described acidic color fixing agent be mainly composed of syntannin acid derivative.
Described the CDP fabrics/terylene/chinlon/spandex fabric is nylon fibre, the CDP fabrics fiber, washs Fabric that synthetic fibre fiber and spandex fibre interweave or nylon fibre, the CDP fabrics fiber, polyster fibre and spandex fibre Blended fabric.
The good effect that the present invention has: the method for (1) present invention is by selecting suitable disperse dyes, the dye of positive ion And acid stain such that it is able to realize the dyeing of the CDP fabrics/terylene/chinlon/spandex fabric, the fabric after dyeing Flaw, Washing and the colorfastness to rubbings such as colourless flower, mottle are the highest, and quality is preferable.(2) method of the present invention is by tight Lattice control pH value and the dyeing temperature of each dye liquor, it is possible to realize polyster fibre and the CDP fabrics fiber one-bath process, from And shorten dyeing time, decrease water consumption, be greatly saved energy consumption.
Detailed description of the invention
(embodiment 1)
The CDP fabrics/terylene/chinlon/spandex the fabric dyeing method of the present embodiment has steps of:
1. being immersed in by fabric in the first dye liquor, it is 5.0 that addition glacial acetic acid regulates the pH of the first dye liquor, then the temperature of 130 DEG C Lower carry out refine, dye polyster fibre and dye the CDP fabrics fiber 30min simultaneously, then be cooled to less than 60 DEG C discharge opeings.
This first dye liquor is every liter and contains 2.0g refine emulsifying agent, 1.0g High Temperature Disperse dye leveller, 5.0g Matrii Sulfas Exsiccatus, 0.9g Suspending agent, 0.08g disperse dyes and the aqueous solution of the 0.91g dye of positive ion;And the gross weight of disperse dyes is for knitting The 0.08% of thing weight, the gross weight of the dye of positive ion is the 0.91% of fabric weight.
Wherein, refine emulsifying agent uses Shanghai and abides by the SEM-35N refine emulsifying agent that Chemical Co., Ltd. produces, its It is mainly composed of polyoxyethylene nonylphenol ether;High Temperature Disperse dye leveller use Jiangsu keep one's word chemical inc produce RDT-27N High Temperature Disperse dye leveller, it is mainly composed of polyoxyethylene 2-Ethyl Hexanol ether and alkyl sulfate compound; Suspending agent uses the suspending agent HT-77 that Jiangsu De Wang chemical engineering industry company limited produces, and it is mainly composed of Fatty alcohol-polyoxyethylene ether;Disperse dyes use the scattered fluorescent yellow dyestuff that Shangyu Jing Lian trade Co., Ltd provides Neocron Yellow 10GN;The dye of positive ion uses Shanghai and leans on the cation dye inspiring confidence in the production of dyestuff easy company limited Material Kayacryl Rhodamine BL-ED and Kayacryl Blue FP-ED, dye of positive ion Kayacryl Rhodamine The weight of BL-ED is the 0.17% of fabric weight, and the weight of dye of positive ion Kayacryl Blue FP-ED is fabric weight 0.74%。
The CDP fabrics/terylene/chinlon/spandex fabric that the present embodiment uses is 25% chinlon, 30% cation can Dye terylene, 30% terylene, 15% spandex intertexture Cotton Stretch Knitted.
2. the fabric after 1. step processes first is carried out the hot water wash of 60 DEG C × 10min, then carries out 70 DEG C × 20min Reduction cleaning, finally carry out 60 DEG C × 10min acid neutralization.
Wherein, reduction cleaning uses every liter and contains 2.0g sodium carbonate and the aqueous solution of 2.0g sodium hydrosulfite, and acid neutralizes and adopts Be every liter of aqueous solution containing 0.6g glacial acetic acid.
3. being immersed in the second dye liquor by the fabric after 2. step processes, addition glacial acetic acid regulates the pH of the second dye liquor and is 5.5, then carry out contaminating nylon fibre 30min at a temperature of 98 DEG C, then be cooled to less than 60 DEG C discharge opeings.
This second dye liquor is every liter and contains 1.0g acidity dye leveller and the aqueous solution of 0.15g acid stain;And acid dye Gross weight is fabric weight the 0.15% of material.
Wherein, acid dye leveller uses the acid dye leveller HT-that Jiangsu De Wang chemical engineering industry company limited produces 33N, it is mainly composed of alkyl alcohol ethoxylates;Acid stain uses Jiangsu De Wang chemical engineering industry company limited and produces Acid stain Sunacid Orange GSN.
4. fabric after 3. step processes first carries out room temperature water wash, after discharge opeing, then carry out acid solid at 60 DEG C Color 20min.
Wherein, acid fixation uses every liter of aqueous solution containing 1.0g acidic color fixing agent, and this acidic color fixing agent uses Be Hetai Chemical Co., Ltd., Suzhou produce HT-GL acidic color fixing agent, it is mainly composed of syntannin acid derivative.
(embodiment 2~embodiment 4)
The colouring method of each embodiment is substantially the same manner as Example 1, and difference is shown in Table 1.
Table 1
Fabric Dyestuff
Embodiment 1 25% chinlon+30% the CDP fabrics+30% terylene+ 15% spandex intertexture Cotton Stretch Knitted 0.08% disperse dyes fluorescein Neocron Yellow 10GN, 0.17% dye of positive ion Kayacryl Rhodamine BL-ED, 0.74% dye of positive ion Kayacryl Blue FP-ED, 0.15% acid stain Sunacid Orange GSN
Embodiment 2 20% chinlon+20% the CDP fabrics+45% terylene+ 15% spandex intertexture Cotton Stretch Knitted 0.12% disperse dyes fluorescein Neocron Yellow 10GN, 0.15% dye of positive ion Kayacryl Rhodamine BL-ED, 0.65% dye of positive ion Kayacryl Blue FP-ED, 0.12% acid stain Sunacid Orange GSN
Embodiment 3 25% chinlon+35% the CDP fabrics+35% terylene+ 5% spandex intertexture Cotton Stretch Knitted 0.10% disperse dyes fluorescein Neocron Yellow 10GN, 0.10% dye of positive ion Kayacryl Rhodamine BL-ED, 0.80% dye of positive ion Kayacryl Blue FP-ED, 0.15% acid stain Sunacid Orange GSN
Embodiment 4 10% chinlon+50% the CDP fabrics+30% terylene+ 10% spandex intertexture Cotton Stretch Knitted 0.08% disperse dyes fluorescein Neocron Yellow 10GN, 0.22% dye of positive ion Kayacryl Rhodamine BL-ED, 0.88% dye of positive ion Kayacryl Blue FP-ED, 0.10% acid stain Sunacid Orange GSN
Fabric after the dyeing of each embodiment does not all have the flaws such as color flower, mottle, and Washing is (with reference to GB/T3921- 2008) and colorfastness to rubbing (with reference to GB/T3920-2008) all reaches 4~5 grades.

Claims (7)

1. the CDP fabrics/terylene/chinlon/spandex fabric dyeing method, it is characterised in that have steps of:
1. fabric is immersed in the first dye liquor containing refine emulsifying agent, disperse dyes and the dye of positive ion, adds acid for adjusting pH It is 4.0~5.5, at a temperature of 120 DEG C~135 DEG C, then processes 20min~60min, then be cooled to less than 60 DEG C discharge opeings;
2. fabric after 1. step processes carries out hot water wash, reduction cleaning and acid successively neutralize;
3. the fabric after 2. step processes is immersed in the second dye liquor containing acid stain, add acid for adjusting pH be 4.0~ 7.0, at a temperature of 90 DEG C~105 DEG C, then process 20min~60min, then be cooled to less than 60 DEG C discharge opeings;
4. the fabric after 3. step processes is carried out room temperature washing, after discharge opeing, carry out acid fixation again.
The CDP fabrics/terylene/chinlon/spandex fabric dyeing method the most according to claim 1, its feature exists In: above-mentioned steps 1. described in the first dye liquor be every liter and divide containing 1.0g~3.0g refine emulsifying agent, 0.5g~1.0g high temperature Dissipate dye leveller, 3.0g~7.0g Matrii Sulfas Exsiccatus, 0.5g~1.5g suspending agent, 0.01g~2.0g disperse dyes and 0.25g~ The aqueous solution of the 2.5g dye of positive ion;And 0.01%~2.0% that the gross weight of disperse dyes is fabric weight, the dye of positive ion Gross weight is fabric weight 0.25%~2.5%;Described refine emulsifying agent be mainly composed of polyoxyethylene nonylphenol ether; Described High Temperature Disperse dye leveller be mainly composed of polyoxyethylene 2-Ethyl Hexanol ether and alkyl sulfate compound;Described Suspending agent be mainly composed of fatty alcohol-polyoxyethylene ether.
The CDP fabrics/terylene/chinlon/spandex fabric dyeing method the most according to claim 1, its feature exists In: above-mentioned steps 3. described in the second dye liquor be every liter acid containing 1.0g~2.0g acidity dye leveller and 0.05g~3.0g The aqueous solution of dyestuff;And 0.05%~3.0% that the gross weight of acid stain is fabric weight;The master of described acid dye leveller Wanting composition is alkyl alcohol ethoxylates.
4. according to the CDP fabrics/terylene/chinlon/spandex fabric dyeing method one of claims 1 to 3 Suo Shu, its It is characterised by: described disperse dyes are scattered fluorescent yellow dyestuff Neocron Yellow 10GN;Described dye of positive ion bag Include for the dye of positive ion Kayacryl Rhodamine BL-ED of fabric weight 0.05%~0.5% and for fabric weight 0.2%~ The dye of positive ion Kayacryl Blue FP-ED of 2.0%;Described acid stain is acid stain Sunacid Orange GSN。
5. according to the CDP fabrics/terylene/chinlon/spandex fabric dyeing method one of claims 1 to 3 Suo Shu, its Be characterised by: above-mentioned steps 1. described in the first dye liquor to add acid for adjusting pH be 5.0, treatment temperature is 130 DEG C;Above-mentioned steps is 3. Described in the second dye liquor to add acid for adjusting pH be 5.5, treatment temperature is 98 DEG C.
The CDP fabrics/terylene/chinlon/spandex fabric dyeing method the most according to claim 4, its feature exists In: above-mentioned steps 1. described in the first dye liquor to add acid for adjusting pH be 5.0, treatment temperature is 130 DEG C;Above-mentioned steps 3. described in The second dye liquor to add acid for adjusting pH be 5.5, treatment temperature is 98 DEG C.
The CDP fabrics/terylene/chinlon/spandex fabric dyeing method the most according to claim 1, its feature exists In: described the CDP fabrics/terylene/chinlon/spandex fabric is nylon fibre, the CDP fabrics fiber, terylene fibre The fabric of peacekeeping spandex fibre intertexture or nylon fibre, the CDP fabrics fiber, polyster fibre and spandex fibre blending Fabric.
CN201610540248.6A 2016-07-11 2016-07-11 The CDP fabrics/terylene/chinlon/spandex fabric dyeing method Pending CN106223061A (en)

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PCT/CN2016/106384 WO2018010356A1 (en) 2016-07-11 2016-11-18 Dyeing method for cationic dyeable polyester/polyester/nylon/spandex fabrics

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