CN103194892B - Anti-yellowing agent - Google Patents
Anti-yellowing agent Download PDFInfo
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- CN103194892B CN103194892B CN201310144270.5A CN201310144270A CN103194892B CN 103194892 B CN103194892 B CN 103194892B CN 201310144270 A CN201310144270 A CN 201310144270A CN 103194892 B CN103194892 B CN 103194892B
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- yellowing
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- yellowing agent
- yellowing change
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Abstract
The invention relates to a prescription of an anti-yellowing agent and in particular relates to a prescription of a anti-yellowing agent for fibers (such as nylon and nylon elastic fiber). The anti-yellowing agent is characterized by comprising the following components in parts by weight: 10.0-20.0 parts of an emulsifying agent, 20.0-50.0 parts of sulfonic acid, 10.0-40.0 parts of alcohols and the balance being 40.0-10.0 parts of water. The cost of the prescription of the anti-yellowing agent is low and reduced by 10-15% in comparison with the cost of imported finished products, and the anti-yellowing agent has a good anti-yellowing effect. The anti-yellowing agent has the advantages of no formaldehyde, no heavy metal ions, no teratogenesis, no mutagenesis, no carcinogenic actions, no toxic side effect on a human body, conforms to the requirements of the EU (European Union) OeKo-TEX Standard 100 and the requirements of the REACH (Registration, Evaluation, Authorization and Restriction of Chemicals) standard, and can well keep the whiteness and the vividness of fabrics.
Description
Technical field
The present invention relates to a kind of formula of anti-yellowing change agent, be specifically related to the formula of a kind of fiber (comprising the fiber such as nylon, nylon elastic) anti-yellowing change agent.
Background technology
As everyone knows, the fabric such as wite textiles and dyed textiles can be processed into various clothes, the dark favor by consumer.But for row high-temperature process, as HEAT SETTING, arrange if the white of high temperature press mold etc. and light fibres fabric do not carry out anti-yellowing change, it easily produces xanthochromia in long-time storage and transportation, not only appearance damage, and service life also has a greatly reduced quality.
Fiber is because having good ABRASION RESISTANCE, fatigue durability and resilience, be widely used in silk stocking, elastic knitted fabric coat, slim seamless underwear, high-grade swimming suit, sportswear and western-style clothes liner etc., the dark favor by consumer, but, during fiber high temperature process, terminal amino group is very easily oxidized and produces yellowing phenomenon, affects the final performance of fabric.Therefore, for white and the light fibres fabric that need carry out high-temperature process (as HEAT SETTING), anti-yellowing change process should be carried out.
Existing anti-yellowing change agent prescription cost of material is higher, and what most of producer used is all imported product, and home products is difficult to reach imported product effect level.
Summary of the invention
Main purpose of the present invention is for above the deficiencies in the prior art, provides a kind of formula material cost lower, and yellowing resistance can good anti-yellowing change agent.
Another main purpose of the present invention be in order to provide a kind of anti-yellowing change and preparation method.
A kind of anti-yellowing change agent, it is characterized in that, it is containing, for example the component of lower parts by weight:
Emulsifying agent 10.0-20.0
Sulfonic acid 20.0-50.0
Alcohols 10.0-40.0
Surplus 40.0-10.0
Wherein, described surplus is water.
Preferably, described emulsifying agent is one or more any mixture in glycerin monostearate, tween, sapn, fatty alcohol-polyoxyethylene ether.
Preferably, described alcohols is the derivative of monoethanolamine, ethylene glycol, propylene glycol and propanediol derivative, monoethanolamine.
The present invention can be applicable to the anti-yellowing change process of fiber, nylon, nylon elastic fiber.
Formulation cost of the present invention is lower, compared with import finished product, can reduce the cost of 10-15%, and anti-yellowing change effect is better.This product is not containing formaldehyde, not containing heavy metal ion, without allergy, without teratogenesis, without mutagenesis, without carcinogenesis, to human non-toxic's side effect, meet European Union OeKo-TEX Standard 100 standard-required, and REACH standard-required, keep whiteness and vividness, the excellent effect of fabric.
Detailed description of the invention
Below by way of specific embodiment, the present invention is further described.
embodiment one
Anti-yellowing change agent of the present invention, comprises the component of following parts by weight:
Glycerin monostearate 10.0;
Sulfonic acid 30.0;
Monoethanolamine 20.0;
Surplus 40.0;
Wherein, described surplus is water, directly said components is uniformly mixed, and obtains anti-yellowing change agent finished product.
embodiment two
Anti-yellowing change agent of the present invention, comprises the component of following parts by weight:
Glycerin monostearate 15.0;
Sulfonic acid 40.0;
Monoethanolamine 25.0;
Surplus 20;
Wherein, described surplus is water, directly said components is uniformly mixed, and obtains anti-yellowing change agent finished product.
embodiment three
Anti-yellowing change agent of the present invention, comprises the component of following parts by weight:
Glycerin monostearate 18.0;
Sulfonic acid 42.0;
Monoethanolamine 20.0;
Surplus 10.0;
Wherein, described surplus is water, directly said components is uniformly mixed, and obtains anti-yellowing change agent finished product.
embodiment four
Anti-yellowing change agent of the present invention, comprises the component of following parts by weight:
Glycerin monostearate 20.0;
Sulfonic acid 45.0;
Monoethanolamine 25.0;
Surplus 10.0;
Wherein, described surplus is water, directly said components is uniformly mixed, and obtains anti-yellowing change agent finished product.
embodiment five
Anti-yellowing change agent of the present invention, comprises the component of following parts by weight:
Glycerin monostearate 10.0;
Sulfonic acid 50.0;
Ethylene glycol 20.0;
Surplus 10.0-40.0;
Wherein, described surplus is water, directly said components is uniformly mixed, and obtains anti-yellowing change agent finished product.
embodiment six
Anti-yellowing change agent of the present invention, comprises the component of following parts by weight:
Glycerin monostearate 10.0;
Sulfonic acid 50.0;
Propylene glycol 20.0;
Surplus 10.0-40.0;
Wherein, described surplus is water, directly said components is uniformly mixed, and obtains anti-yellowing change agent finished product.
Embodiment 1 ~ 6 to obtain the technical indicator of anti-yellowing change agent as follows:
For white polyamide fibre 6 knitted cloth.First white polyamide fibre 6 knitted cloth is carried out preboarding technique: the anti-yellowing change agent → ovens dry → setting of the present embodiment 1 ~ 6 is pricked in a leaching one, is carrying out afterboarding technique: one soak an anti-yellowing change agent of rolling the present embodiment 1 ~ 6 → dry → bake (180 DEG C × 30s) after test.
Wherein, the anti-yellowing change agent consumption of the present embodiment on the impact/level of the anti-phenol yellowness index of polyamide fibre as following table
As seen from the above table, the anti-yellowing change agent adding the present embodiment effectively can improve the phenol Yellowing of polyamide fibre 6, polyamide fibre 66 fabric.Its reason is that the anti-yellowing change agent of the present embodiment is covered in fiber surface, has blocked NO in fabric and air
2and SO
2contact, prevent fabric from absorbing Yoshinox BHT analog derivative.
The above embodiment is only that protection scope of the present invention is not limited thereto in order to absolutely prove the preferred embodiment that the present invention lifts.The equivalent alternative or conversion that those skilled in the art do on basis of the present invention, all within protection scope of the present invention.Protection scope of the present invention is as the criterion with claims.
Claims (2)
1. an anti-yellowing change agent, is characterized in that, it is containing, for example the component of lower parts by weight:
Wherein, described surplus is water.
2. the anti-yellowing change agent of one according to claim 1, is characterized in that: described emulsifying agent is one or more any mixture in glycerin monostearate, tween, sapn, fatty alcohol-polyoxyethylene ether.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310144270.5A CN103194892B (en) | 2013-04-24 | 2013-04-24 | Anti-yellowing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310144270.5A CN103194892B (en) | 2013-04-24 | 2013-04-24 | Anti-yellowing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103194892A CN103194892A (en) | 2013-07-10 |
| CN103194892B true CN103194892B (en) | 2015-05-13 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310144270.5A Active CN103194892B (en) | 2013-04-24 | 2013-04-24 | Anti-yellowing agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN103194892B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105133313B (en) * | 2015-10-15 | 2017-09-19 | 东华大学 | A kind of anti-yellowing agent for nylon |
| CN108004768B (en) * | 2017-11-14 | 2020-04-14 | 广州先盈生物科技有限公司 | Storage-yellowing-resistant agent for nylon and preparation method thereof |
| CN108085986B (en) * | 2018-01-29 | 2020-05-19 | 广州市协运来实业有限公司 | Fiber antioxidant and preparation method thereof |
| CN109021351A (en) * | 2018-06-26 | 2018-12-18 | 上海涵点科技有限公司 | A kind of resistance to phenol Huang functional agglomerate, preparation method, purposes and the Huang of resistance to phenol polyolefine fiber |
| CN109021509A (en) * | 2018-06-26 | 2018-12-18 | 上海涵点科技有限公司 | A kind of resistance to phenol Huang functional agglomerate, preparation method, purposes and the Huang of resistance to phenol terylene |
| CN108795028A (en) * | 2018-06-26 | 2018-11-13 | 上海涵点科技有限公司 | A kind of resistance to phenol Huang functional agglomerate, preparation method, purposes and the Huang of resistance to phenol polyamide fibre |
| CN110558684A (en) * | 2019-09-10 | 2019-12-13 | 健力粘扣带有限公司 | Method for manufacturing anti-yellowing sulfur-resistant nylon fastening tape |
| CN111663331B (en) * | 2020-06-13 | 2022-11-25 | 广东传化富联精细化工有限公司 | Novel nylon anti-phenol yellowing agent and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004012877A1 (en) * | 2003-12-23 | 2005-07-21 | Ge Bayer Silicones Gmbh & Co. Kg | Formulations containing amino- and/or ammonium-polysiloxane with a low content of hydroxy and alkoxy groups attached to silicon, used in detergent formulations and cosmetics or as textile softeners |
| CN102093562A (en) * | 2009-12-11 | 2011-06-15 | 张家港科道化学有限公司 | Preparation method of low-yellowing negative ion-modified organic silicon emulsion |
-
2013
- 2013-04-24 CN CN201310144270.5A patent/CN103194892B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004012877A1 (en) * | 2003-12-23 | 2005-07-21 | Ge Bayer Silicones Gmbh & Co. Kg | Formulations containing amino- and/or ammonium-polysiloxane with a low content of hydroxy and alkoxy groups attached to silicon, used in detergent formulations and cosmetics or as textile softeners |
| CN102093562A (en) * | 2009-12-11 | 2011-06-15 | 张家港科道化学有限公司 | Preparation method of low-yellowing negative ion-modified organic silicon emulsion |
Non-Patent Citations (2)
| Title |
|---|
| 亲水性低黄变氨基改性有机硅乳液的研制;王春姣等;《有机硅材料》;20041231;第18卷(第5期);第16-19页 * |
| 尹耐冬等.2.6.9 抗黄变整理剂.《国外纺织染料助剂使用指南》.2008,第226页. * |
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| CN103194892A (en) | 2013-07-10 |
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Address after: 510000 Room 101, building 4, No. 23, sukeng street, Panyu District, Guangzhou City, Guangdong Province Patentee after: Guangzhou xieyanlai Industrial Co., Ltd Address before: One of the Meishan village of Panyu District Hualong Town, Guangzhou city of Guangdong Province Grid 510434, three, two of the gang of four Patentee before: Guangzhou Panyu Xie Yun Lai Chemical Necessities Factory |