CN106192419A - A kind of fabric softener and preparation method thereof - Google Patents

A kind of fabric softener and preparation method thereof Download PDF

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Publication number
CN106192419A
CN106192419A CN201610563416.3A CN201610563416A CN106192419A CN 106192419 A CN106192419 A CN 106192419A CN 201610563416 A CN201610563416 A CN 201610563416A CN 106192419 A CN106192419 A CN 106192419A
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Prior art keywords
parts
acid
fabric
fabric softener
carbimide
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CN201610563416.3A
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Chinese (zh)
Inventor
张冲
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Nantong Rich Island Bedding Development Co Ltd
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Nantong Rich Island Bedding Development Co Ltd
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Priority to CN201610563416.3A priority Critical patent/CN106192419A/en
Publication of CN106192419A publication Critical patent/CN106192419A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144—Alcohols; Metal alcoholates
    • D06M13/148—Polyalcohols, e.g. glycerol or glucose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/203—Unsaturated carboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2243—Mono-, di-, or triglycerides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/376—Oximes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/395—Isocyanates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
    • D06M13/41—Amides derived from unsaturated carboxylic acids, e.g. acrylamide
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a kind of fabric softener, be made up of the raw material of following weight portion: ethylene glycol 48 parts, 0.5 1 parts of acrylic acid, acrylamide 13 parts, octamethylcyclotetrasiloxane 10 15 parts, hydroxy silicon oil 15 20 parts, citric acid 58 parts, glyceryl monostearate 35 parts, 6 10 parts of kieselguhr, polyoxyethylene ether 0.8 1.5 parts, Salicyl Hydroximic Acid 45 parts, octadecane carbimide 69 parts, plants essential oil 1 1.5 parts, deionized water 100 300 parts.The fabric softener manufacturing process of the present invention is simple, and low cost is low in the pollution of the environment, it is possible to is effectively improved fabric softness, and realizes anti-hairy effect, and the color that simultaneously can also be fabric keeps bright-coloured, thus improves combination property and the production efficiency of fabric.

Description

A kind of fabric softener and preparation method thereof
Technical field
The invention belongs to textile production technical field, be specifically related to a kind of fabric softener and preparation method thereof.
Background technology
In order to make fabric, particularly bafta has good hairy effect soft, anti-, and textile enterprise generally uses cotton The method that fiber and other fibers carry out blending, but this method needs to transform bafta, and cost is bigger.Existing Although anti-fluffing finishing agent can reach to realize to a certain extent the effect of anti-fluffing, but cannot carry out fabric at softness simultaneously Reason, and processing cost is the highest.
Summary of the invention
The technical problem to be solved is to provide one can be effectively improved fabric softness, and realizes anti-fluffing Fabric softener of effect and preparation method thereof.
For solving above-mentioned technical problem, the technical solution used in the present invention is:
A kind of fabric softener, is made up of the raw material of following weight portion: ethylene glycol 4-8 part, acrylic acid 0.5-1 part, acrylamide 1-3 part, octamethylcyclotetrasiloxane 10-15 part, hydroxy silicon oil 15-20 part, citric acid 5-8 part, glyceryl monostearate 3-5 part, Kieselguhr 6-10 part, polyoxyethylene ether 0.8-1.5 part, Salicyl Hydroximic Acid 4-5 part, octadecane carbimide 6-9 part, plants essential oil 1-1.5 part, deionized water 100-300 part.
Further, above-mentioned fabrics softening agent is made up of the raw material of following weight portion: ethylene glycol 6 parts, 0.8 part of acrylic acid, Acrylamide 2 parts, octamethylcyclotetrasiloxane 12 parts, hydroxy silicon oil 17 parts, citric acid 6 parts, glyceryl monostearate 4 parts, diatom 8 parts of soil, polyoxyethylene ether 1.3 parts, Salicyl Hydroximic Acid 4 parts, octadecane carbimide 7 parts, plants essential oil 1 part, deionized water 200 Part.
The preparation method of above-mentioned fabrics softening agent, comprises the following steps:
1) by octamethylcyclotetrasiloxane, hydroxy silicon oil, glyceryl monostearate, kieselguhr, polyoxyethylene ether, Salicyl Hydroximic Acid with And deionized water puts in reactor, stirring at low speed 10-15min at a temperature of 50-60 DEG C；
2) continue to put into octadecane carbimide, ethylene glycol, acrylic acid, acrylamide and citric acid in reactor, at 50-60 It is down to room temperature after stirring high speed 10-15min at a temperature of DEG C；
3) plants essential oil is put in reactor, stir 4-6min under room temperature, get product.
The invention has the beneficial effects as follows: the fabric softener manufacturing process of the present invention is simple, low cost, environmental pollution Few, it is possible to be effectively improved fabric softness, and realize anti-hairy effect, the color that simultaneously can also be fabric keeps bright-coloured, thus Improve combination property and the production efficiency of fabric.
Detailed description of the invention:
Below in conjunction with embodiment, the present invention is described in further details, but these embodiments are not limitation of the invention.
Embodiment 1
A kind of fabric softener, is made up of the raw material of following weight portion: ethylene glycol 4 parts, 0.5 part of acrylic acid, acrylamide 1 part, Octamethylcyclotetrasiloxane 10 parts, hydroxy silicon oil 15 parts, citric acid 5 parts, glyceryl monostearate 3 parts, 6 parts of kieselguhr, polyoxy second 0.8 part of alkene ether, Salicyl Hydroximic Acid 4 parts, octadecane carbimide 6 parts, plants essential oil 1 part, deionized water 100 parts.
The preparation method of above-mentioned fabrics softening agent, comprises the following steps:
1) by octamethylcyclotetrasiloxane, hydroxy silicon oil, glyceryl monostearate, kieselguhr, polyoxyethylene ether, Salicyl Hydroximic Acid with And deionized water puts in reactor, stirring at low speed 10min at a temperature of 50 DEG C；
2) continue to put into octadecane carbimide, ethylene glycol, acrylic acid, acrylamide and citric acid in reactor, at 50 DEG C At a temperature of stir after high speed 10min and be down to room temperature；
3) plants essential oil is put in reactor, stir 4min under room temperature, get product.
Embodiment 2
A kind of fabric softener, is made up of the raw material of following weight portion: ethylene glycol 6 parts, 0.8 part of acrylic acid, acrylamide 2 parts, Octamethylcyclotetrasiloxane 12 parts, hydroxy silicon oil 17 parts, citric acid 6 parts, glyceryl monostearate 4 parts, 8 parts of kieselguhr, polyoxy second 1.3 parts of alkene ether, Salicyl Hydroximic Acid 4 parts, octadecane carbimide 7 parts, plants essential oil 1 part, deionized water 200 parts.
The preparation method of above-mentioned fabrics softening agent, comprises the following steps:
1) by octamethylcyclotetrasiloxane, hydroxy silicon oil, glyceryl monostearate, kieselguhr, polyoxyethylene ether, Salicyl Hydroximic Acid with And deionized water puts in reactor, stirring at low speed 12min at a temperature of 60 DEG C；
2) continue to put into octadecane carbimide, ethylene glycol, acrylic acid, acrylamide and citric acid in reactor, at 60 DEG C At a temperature of stir after high speed 15min and be down to room temperature；
3) plants essential oil is put in reactor, stir 5min under room temperature, get product.
Embodiment 3
A kind of fabric softener, is made up of the raw material of following weight portion: ethylene glycol 8 parts, 1 part of acrylic acid, acrylamide 3 parts, eight Methyl tetrasiloxane 15 parts, hydroxy silicon oil 20 parts, citric acid 8 parts, glyceryl monostearate 5 parts, 10 parts of kieselguhr, polyoxyethylene 1.5 parts of ether, Salicyl Hydroximic Acid 5 parts, octadecane carbimide 9 parts, plants essential oil 1.5 parts, deionized water 300 parts.
The preparation method of above-mentioned fabrics softening agent, comprises the following steps:
1) by octamethylcyclotetrasiloxane, hydroxy silicon oil, glyceryl monostearate, kieselguhr, polyoxyethylene ether, Salicyl Hydroximic Acid with And deionized water puts in reactor, stirring at low speed 15min at a temperature of 60 DEG C；
2) continue to put into octadecane carbimide, ethylene glycol, acrylic acid, acrylamide and citric acid in reactor, at 60 DEG C At a temperature of stir after high speed 15min and be down to room temperature；
3) plants essential oil is put in reactor, stir 6min under room temperature, get product.

Claims (3)

1. a fabric softener, it is characterised in that be made up of the raw material of following weight portion: ethylene glycol 4-8 part, acrylic acid 0.5- 1 part, acrylamide 1-3 part, octamethylcyclotetrasiloxane 10-15 part, hydroxy silicon oil 15-20 part, citric acid 5-8 part, monostearate Glyceride 3-5 part, kieselguhr 6-10 part, polyoxyethylene ether 0.8-1.5 part, Salicyl Hydroximic Acid 4-5 part, octadecane carbimide 6- 9 parts, plants essential oil 1-1.5 part, deionized water 100-300 part.
Fabric softener the most according to claim 1, it is characterised in that be made up of the raw material of following weight portion: ethylene glycol 6 Part, 0.8 part of acrylic acid, acrylamide 2 parts, octamethylcyclotetrasiloxane 12 parts, hydroxy silicon oil 17 parts, citric acid 6 parts, monostearate Glyceride 4 parts, 8 parts of kieselguhr, polyoxyethylene ether 1.3 parts, Salicyl Hydroximic Acid 4 parts, octadecane carbimide 7 parts, plants essential oil 1 Part, deionized water 200 parts.
The preparation method of fabric softener the most according to claim 1 and 2, it is characterised in that comprise the following steps:
1) by octamethylcyclotetrasiloxane, hydroxy silicon oil, glyceryl monostearate, kieselguhr, polyoxyethylene ether, Salicyl Hydroximic Acid with And deionized water puts in reactor, stirring at low speed 10-15min at a temperature of 50-60 DEG C；
2) continue to put into octadecane carbimide, ethylene glycol, acrylic acid, acrylamide and citric acid in reactor, at 50-60 It is down to room temperature after stirring high speed 10-15min at a temperature of DEG C；
3) plants essential oil is put in reactor, stir 4-6min under room temperature, get product.
CN201610563416.3A 2016-07-18 2016-07-18 A kind of fabric softener and preparation method thereof Pending CN106192419A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107724086A (en) * 2017-09-13 2018-02-23 江苏新瑞贝科技股份有限公司 A kind of silicone softening agent and preparation method thereof
CN107740279A (en) * 2017-09-30 2018-02-27 江苏新瑞贝科技股份有限公司 A kind of fluffy softening agent of organic silicon flame-retardant and preparation method thereof
CN109137528A (en) * 2018-08-24 2019-01-04 中国纺织信息中心 A kind of afterfinish method improving woolen feel
CN109403047A (en) * 2018-10-26 2019-03-01 纳派化学(上海)有限公司 A kind of softening agent for making fabric have the strength of calligraphic strokes
CN114687043A (en) * 2022-01-26 2022-07-01 安徽丽达制衣有限公司 Composite fiber school uniform with high fuzzing resistance and high wear resistance and preparation method thereof

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EP0276999A2 (en) * 1987-01-29 1988-08-03 Unilever Plc Fabric conditioning composition
CN102877293A (en) * 2011-07-11 2013-01-16 李晓梅 Softener suitable for plurality of fabrics
CN103556458A (en) * 2013-11-15 2014-02-05 昆山市万丰制衣有限责任公司 Healthcare soft underwear fabric
CN103669002A (en) * 2013-11-27 2014-03-26 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 Leather softener
CN104562651A (en) * 2015-01-27 2015-04-29 江苏紫石化工科技有限公司 Fabric softener
CN105220468A (en) * 2015-11-13 2016-01-06 付淑珍 A kind of novel softener for textile fabric and preparation method thereof

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CN103556458A (en) * 2013-11-15 2014-02-05 昆山市万丰制衣有限责任公司 Healthcare soft underwear fabric
CN103669002A (en) * 2013-11-27 2014-03-26 南通市通州区川姜镇盛世王朝家用纺织品设计工作室 Leather softener
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CN105220468A (en) * 2015-11-13 2016-01-06 付淑珍 A kind of novel softener for textile fabric and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107724086A (en) * 2017-09-13 2018-02-23 江苏新瑞贝科技股份有限公司 A kind of silicone softening agent and preparation method thereof
CN107740279A (en) * 2017-09-30 2018-02-27 江苏新瑞贝科技股份有限公司 A kind of fluffy softening agent of organic silicon flame-retardant and preparation method thereof
CN109137528A (en) * 2018-08-24 2019-01-04 中国纺织信息中心 A kind of afterfinish method improving woolen feel
CN109403047A (en) * 2018-10-26 2019-03-01 纳派化学(上海)有限公司 A kind of softening agent for making fabric have the strength of calligraphic strokes
CN114687043A (en) * 2022-01-26 2022-07-01 安徽丽达制衣有限公司 Composite fiber school uniform with high fuzzing resistance and high wear resistance and preparation method thereof

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Application publication date: 20161207

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