CN107724086A - A kind of silicone softening agent and preparation method thereof - Google Patents
A kind of silicone softening agent and preparation method thereof Download PDFInfo
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- CN107724086A CN107724086A CN201710821118.4A CN201710821118A CN107724086A CN 107724086 A CN107724086 A CN 107724086A CN 201710821118 A CN201710821118 A CN 201710821118A CN 107724086 A CN107724086 A CN 107724086A
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- softening agent
- oil
- silicone softening
- essential oil
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- 239000004902 Softening Agent Substances 0.000 title claims abstract description 62
- 229920001296 polysiloxane Polymers 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000003921 oil Substances 0.000 claims abstract description 41
- 239000000341 volatile oil Substances 0.000 claims abstract description 34
- -1 amido silicon Chemical compound 0.000 claims abstract description 24
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 21
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 claims abstract description 21
- QWDQYHPOSSHSAW-UHFFFAOYSA-N 1-isocyanatooctadecane Chemical compound CCCCCCCCCCCCCCCCCCN=C=O QWDQYHPOSSHSAW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 20
- 239000010703 silicon Substances 0.000 claims abstract description 20
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 34
- 241000196324 Embryophyta Species 0.000 claims description 23
- 238000007664 blowing Methods 0.000 claims description 7
- 238000005538 encapsulation Methods 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 4
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- 244000111489 Gardenia augusta Species 0.000 claims description 2
- 235000018958 Gardenia augusta Nutrition 0.000 claims description 2
- 241001272567 Hominoidea Species 0.000 claims description 2
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 2
- 240000005385 Jasminum sambac Species 0.000 claims description 2
- 244000178870 Lavandula angustifolia Species 0.000 claims description 2
- 235000010663 Lavandula angustifolia Nutrition 0.000 claims description 2
- 240000005819 Magnolia denudata Species 0.000 claims description 2
- 235000016094 Magnolia denudata Nutrition 0.000 claims description 2
- 241000234479 Narcissus Species 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 239000001102 lavandula vera Substances 0.000 claims description 2
- 235000018219 lavender Nutrition 0.000 claims description 2
- DEDOPGXGGQYYMW-UHFFFAOYSA-N molinate Chemical compound CCSC(=O)N1CCCCCC1 DEDOPGXGGQYYMW-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims 6
- 229910021529 ammonia Inorganic materials 0.000 claims 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical group C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims 1
- 240000002853 Nelumbo nucifera Species 0.000 claims 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 claims 1
- 235000011449 Rosa Nutrition 0.000 claims 1
- 229920013822 aminosilicone Polymers 0.000 claims 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 claims 1
- 238000002242 deionisation method Methods 0.000 claims 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 23
- 238000005452 bending Methods 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 238000010008 shearing Methods 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 230000007423 decrease Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 10
- 239000004753 textile Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004855 creaseproofing Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 239000003305 oil spill Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/192—Polycarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/395—Isocyanates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
- D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
- D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
The invention discloses a kind of silicone softening agent and preparation method thereof, the silicone softening agent includes the raw material of following parts by weight：20 30 parts of amido silicon oil, 5 10 parts of dimethylaminoethyl methacrylate, 5 10 parts of emulsifying agent, 5 10 parts of turkey red oil, 35 parts of octadecylisocyanate, 10 15 parts of octamethylcyclotetrasiloxane, 46 parts of citric acid, 5 10 parts of diatomite, 35 parts of APEO, 5 10 parts of plants essential oil, 50 80 parts of deionized water.After the silicone softening agent application of the present invention, the stiffness of fabric declines a lot, and shearing rigidity and bending stiffness all decline a lot, and creasy recovery angle increase is a lot, and flexibility improves a lot.The silicone softening agent manufacturing process of the present invention is simple to operation, and low in raw material price easily obtains, and nontoxic, human body is not stimulated, volatility is low.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relates to a kind of silicone softening agent and preparation method thereof.
Background technology
Softening agent is a kind of quiet, the coefficient of kinetic friction chemical substance that can change fiber.When changing confficient of static friction, hand
Thoughts and feelings touches with smooth sense, is easy to move on fiber or fabric；It is fine between fiber and fiber when changing the coefficient of kinetic friction
Structure is easy to be mutually shifted, that is, fiber or fabric it is easily deformable.
Soft finish is the important finishing process in dyeing and printing process.Textile in process, through repeatedly processing after
Feel can become coarse, and general synthetic fabrics is worse, especially Superfine Fibre Fabric.In order that fabric has softness, slided
Refreshing, comfortable feel, it is necessary to arranged to it, widely used at present arranged with softening agent.In addition in chemistry
Softening agent largely is used during fibre spinning, the spinning of various fibers, weaving etc., because with textile processing
A large amount of uses of high speed and short liquor ratio mode, the phase mutual friction increase between fabric and equipment between fabric, be also easy to produce scratch,
Phenomena such as bar defect.It can make fiber that there is the flexible smooth being adapted with processing conditions to avoid damage in itself using softening agent.
Therefore fabric is a kind of important textile auxiliary with softening agent.
Fabric of organosilicon finishing auxiliaries has a wide range of applications in terms of textile finishing.The auxiliary agent can not only be handled naturally
Fabric, it can also handle the various synthetic fibers such as terylene, nylon.Crease-proofing textiles containing, antifouling, antistatic, anti-pilling after processing,
It is plentiful, soft, high resilience and gloss, there is style sliding, refreshing, very.Organosilicon processing can also improve the intensity of fiber, subtract
Light abrasion.Silicone softening agent is that product quality, increase are improved in a kind of up-and-coming softening agent, and textile printing and dyeing processing
A kind of important auxiliary agent of added value of product.
Domestic most fabrics after silicone softening agent arranges are in hydrophobicity, enable a wearer to feel sultry, and be difficult to wash
Wash；Also often there is demulsification floating oil phenomenon in many products.And the hydrophilic polyether silicone oil of tradition, though there is preferable hydrophily and water
Dissolubility, but flexibility and finishing effect durability are poor.Therefore the silicone softening agent with excellent flexibility is developed with very
Strong realistic meaning.
The content of the invention
It is an object of the invention to provide a kind of silicone softening agent and preparation method, to solve to carry in above-mentioned background technology
The problem of going out.
To achieve the above object, the present invention provides following technical scheme：
A kind of silicone softening agent, according to parts by weight, including following components：Amido silicon oil 20-30 parts, methacrylic acid
Dimethylaminoethyl 5-10 parts, emulsifying agent 5-10 parts, turkey red oil 5-10 parts, octadecylisocyanate 3-5 parts, the silicon of prestox four
Oxygen alkane 10-15 parts, citric acid 4-6 parts, diatomite 5-10 parts, APEO 3-5 parts, plants essential oil 5-10 parts, deionized water
50-80 parts.
Preferably, the emulsifying agent is AEO, APES, sorbitan fatty acid
It is one or more than one kinds of in ester, paregal O.
Preferably, the plants essential oil is Lavender, Peppermint essential oil, lemon, jasmine essential oil, rhodamine toner
It is one or more than one kinds of in oil, yulan essential oil, cape jasmine flower essential oil, narcissus flower essential oil.
Preferably, described silicone softening agent, according to parts by weight, including following components：20 parts of amido silicon oil, methyl
5 parts of dimethylaminoethyl acrylate, 5 parts of emulsifying agent, 5 parts of turkey red oil, 3 parts of octadecylisocyanate, octamethylcyclotetrasiloxane
10 parts, 4 parts of citric acid, 5 parts of diatomite, 3 parts of APEO, 5 parts of plants essential oil, 50 parts of deionized water.
Preferably, described silicone softening agent, according to parts by weight, including following components：25 parts of amido silicon oil, methyl
8 parts of dimethylaminoethyl acrylate, 8 parts of emulsifying agent, 8 parts of turkey red oil, 4 parts of octadecylisocyanate, octamethylcyclotetrasiloxane
13 parts, 5 parts of citric acid, 8 parts of diatomite, 4 parts of APEO, 8 parts of plants essential oil, 65 parts of deionized water.
Preferably, described silicone softening agent, according to parts by weight, including following components：Amido silicon oil 20-30 parts,
Dimethylaminoethyl methacrylate 5-10 parts, emulsifying agent 5-10 parts, turkey red oil 5-10 parts, octadecylisocyanate 3-5 parts,
Octamethylcyclotetrasiloxane 10-15 parts, citric acid 4-6 parts, diatomite 5-10 parts, APEO 3-5 parts, plants essential oil 5-10
Part, deionized water 50-80 parts.
Preferably, a kind of preparation method of the silicone softening agent, is comprised the following steps that：
(1) amido silicon oil 20-30 parts, dimethylaminoethyl methacrylate 5-10 parts, emulsifying agent are added in a kettle
5-10 parts, deionized water 50-80 parts, 60-70 DEG C is warming up to, 1000-3000 revs/min, stirs 20-30 minutes；
(2) temperature is raised to 70-80 DEG C, adds octamethylcyclotetrasiloxane 10-15 parts, APEO 3-5 parts, 500-
1000 revs/min, stir 20-30 minutes；
(3) it is cooled to 40-50 DEG C, adds octadecylisocyanate 3-5 parts, citric acid 4-6 parts, 500-1000 revs/min
Clock, stir 20-30 minutes；
(4) 30-40 DEG C is cooled to, turkey red oil 5-10 parts is added, 500-1000 revs/min, stirs 20-30 minutes；
(5) 20-30 DEG C is cooled to, diatomite 5-10 parts, plants essential oil 5-10 parts is added, 500-1000 revs/min, stirs
20-30 minutes；
(6) stirring is closed down, the silicone softening agent prepared；
(7) stand and be cooled in stirred tank liquid silicone softening agent and be less than 20 DEG C, blowing encapsulation, finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, after silicone softening agent of the invention application, the stiffness of fabric declines a lot, and shearing rigidity is firm with bending
Degree all declines a lot, and creasy recovery angle increase is a lot, and flexibility improves a lot.
2nd, silicone softening agent of the invention is stable, not stratified, not oil spill.
3rd, after silicone softening agent application fabric of the invention, fabric has more soft, fluffy, smooth feel.
4th, after silicone softening agent application fabric of the invention, the performance of fabric in itself such as air-moisture-permeable etc. will not occur
Change.
5th, silicone softening agent manufacturing process of the invention is simple to operation, and low in raw material price easily obtains, and nontoxic nothing
Evil, is not stimulated human body, volatility is low.
6th, mutual compatibility, synergy between various raw materials used in silicone softening agent of the invention, collectively constitute performance
Excellent product.
7th, the addition of plants essential oil, the softness of fabric is improved.
8th, technique is simplified, safe operation is simple, is easy to industrialized production.
9th, after softening agent application fabric of the invention, fabric is not easy yellowing, can ensure the color transparent of fabric, smoothly
It is submissive, reduce fabric ages performance.
10th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of silicone softening agent, according to parts by weight, including following components：Amido silicon oil 20-30
Part, dimethylaminoethyl methacrylate 5-10 parts, emulsifying agent 5-10 parts, turkey red oil 5-10 parts, octadecylisocyanate 3-5
Part, octamethylcyclotetrasiloxane 10-15 parts, citric acid 4-6 parts, diatomite 5-10 parts, APEO 3-5 parts, plants essential oil 5-
10 parts, deionized water 50-80 parts.
Present invention also offers a kind of preparation method of silicone softening agent, comprise the following steps that：
(1) amido silicon oil 20-30 parts, dimethylaminoethyl methacrylate 5-10 parts, emulsifying agent are added in a kettle
5-10 parts, deionized water 50-80 parts, 60-70 DEG C is warming up to, 1000-3000 revs/min, stirs 20-30 minutes；
(2) temperature is raised to 70-80 DEG C, adds octamethylcyclotetrasiloxane 10-15 parts, APEO 3-5 parts, 500-
1000 revs/min, stir 20-30 minutes；
(3) it is cooled to 40-50 DEG C, adds octadecylisocyanate 3-5 parts, citric acid 4-6 parts, 500-1000 revs/min
Clock, stir 20-30 minutes；
(4) 30-40 DEG C is cooled to, turkey red oil 5-10 parts is added, 500-1000 revs/min, stirs 20-30 minutes；
(5) 20-30 DEG C is cooled to, diatomite 5-10 parts, plants essential oil 5-10 parts is added, 500-1000 revs/min, stirs
20-30 minutes；
(6) stirring is closed down, the silicone softening agent prepared；
(7) stand and be cooled in stirred tank liquid silicone softening agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 1
The invention discloses a kind of silicone softening agent, according to parts by weight, including following components：20 parts of amido silicon oil,
5 parts of dimethylaminoethyl methacrylate, 5 parts of emulsifying agent, 5 parts of turkey red oil, 3 parts of octadecylisocyanate, the silicon of prestox four
10 parts of oxygen alkane, 4 parts of citric acid, 5 parts of diatomite, 3 parts of APEO, 5 parts of plants essential oil, 50 parts of deionized water.
Present invention also offers a kind of preparation method of silicone softening agent, comprise the following steps that：
(1) 20 parts of amido silicon oil, 5 parts of dimethylaminoethyl methacrylate are added in a kettle, 5 parts of emulsifying agent, are gone
50 parts of ionized water, 60 DEG C are warming up to, 1000 revs/min, is stirred 20 minutes；
(2) temperature is raised to 70 DEG C, is added 10 parts of octamethylcyclotetrasiloxane, 3 parts of APEO, 500 revs/min, is stirred
Mix 20 minutes；
(3) 40 DEG C are cooled to, 3 parts of octadecylisocyanate, 4 parts of citric acid is added, 500 revs/min, stirs 20 points
Clock；
(4) 30 DEG C are cooled to, 5 parts of turkey red oil is added, 800 revs/min, stirs 20 minutes；
(5) 20 DEG C are cooled to, 5 parts of diatomite, 5 parts of plants essential oil is added, 900 revs/min, stirs 20 minutes；
(6) stirring is closed down, the silicone softening agent prepared；
(7) stand and be cooled in stirred tank liquid silicone softening agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 2
The invention discloses a kind of silicone softening agent, according to parts by weight, including following components：25 parts of amido silicon oil,
8 parts of dimethylaminoethyl methacrylate, 8 parts of emulsifying agent, 8 parts of turkey red oil, 4 parts of octadecylisocyanate, the silicon of prestox four
13 parts of oxygen alkane, 5 parts of citric acid, 8 parts of diatomite, 4 parts of APEO, 8 parts of plants essential oil, 65 parts of deionized water.
Present invention also offers a kind of preparation method of silicone softening agent, comprise the following steps that：
(1) 25 parts of amido silicon oil, 8 parts of dimethylaminoethyl methacrylate are added in a kettle, 8 parts of emulsifying agent, are gone
65 parts of ionized water, 65 DEG C are warming up to, 2000 revs/min, is stirred 25 minutes；
(2) temperature is raised to 75 DEG C, is added 13 parts of octamethylcyclotetrasiloxane, 4 parts of APEO, 800 revs/min, is stirred
Mix 25 minutes；
(3) 45 DEG C are cooled to, 4 parts of octadecylisocyanate, 5 parts of citric acid is added, 900 revs/min, stirs 25 points
Clock；
(4) 35 DEG C are cooled to, 8 parts of turkey red oil is added, 900 revs/min, stirs 25 minutes；
(5) 25 DEG C are cooled to, 8 parts of diatomite, 8 parts of plants essential oil is added, 900 revs/min, stirs 25 minutes；
(6) stirring is closed down, the silicone softening agent prepared；
(7) stand and be cooled in stirred tank liquid silicone softening agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 3
The invention discloses a kind of silicone softening agent, according to parts by weight, including following components：30 parts of amido silicon oil,
10 parts of dimethylaminoethyl methacrylate, 10 parts of emulsifying agent, 10 parts of turkey red oil, 5 parts of octadecylisocyanate, prestox four
15 parts of siloxanes, 6 parts of citric acid, 10 parts of diatomite, 5 parts of APEO, 10 parts of plants essential oil, 80 parts of deionized water.
Present invention also offers a kind of preparation method of silicone softening agent, comprise the following steps that：
(1) in a kettle add 30 parts of amido silicon oil, 10 parts of dimethylaminoethyl methacrylate, 10 parts of emulsifying agent,
80 parts of deionized water, 70 DEG C are warming up to, 3000 revs/min, is stirred 30 minutes；
(2) temperature is raised to 80 DEG C, is added 15 parts of octamethylcyclotetrasiloxane, 5 parts of APEO, 1000 revs/min, is stirred
Mix 30 minutes；
(3) 50 DEG C are cooled to, 5 parts of octadecylisocyanate, 6 parts of citric acid is added, 1000 revs/min, stirs 30 points
Clock；
(4) 40 DEG C are cooled to, 10 parts of turkey red oil is added, 1000 revs/min, stirs 30 minutes；
(5) 30 DEG C are cooled to, 10 parts of diatomite, 10 parts of plants essential oil is added, 1000 revs/min, stirs 30 minutes；
(6) stirring is closed down, the silicone softening agent prepared；
(7) stand and be cooled in stirred tank liquid silicone softening agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 4
The invention discloses a kind of silicone softening agent, according to parts by weight, including following components：30 parts of amido silicon oil,
10 parts of dimethylaminoethyl methacrylate, 10 parts of emulsifying agent, 5 parts of turkey red oil, 3 parts of octadecylisocyanate, prestox four
10 parts of siloxanes, 4 parts of citric acid, 5 parts of diatomite, 5 parts of APEO, 10 parts of plants essential oil, 80 parts of deionized water.
Present invention also offers a kind of preparation method of silicone softening agent, comprise the following steps that：
(1) in a kettle add 30 parts of amido silicon oil, 10 parts of dimethylaminoethyl methacrylate, 10 parts of emulsifying agent,
80 parts of deionized water, 70 DEG C are warming up to, 3000 revs/min, is stirred 20 minutes；
(2) temperature is raised to 80 DEG C, is added 10 parts of octamethylcyclotetrasiloxane, 5 parts of APEO, 900 revs/min, is stirred
Mix 30 minutes；
(3) 45 DEG C are cooled to, 3 parts of octadecylisocyanate, 4 parts of citric acid is added, 1000 revs/min, stirs 20 points
Clock；
(4) 30 DEG C are cooled to, 5 parts of turkey red oil is added, 800 revs/min, stirs 30 minutes；
(5) 20 DEG C are cooled to, 5 parts of diatomite, 10 parts of plants essential oil is added, 1000 revs/min, stirs 20 minutes；
(6) stirring is closed down, the silicone softening agent prepared；
(7) stand and be cooled in stirred tank liquid silicone softening agent and be less than 20 DEG C, blowing encapsulation, finished product.
Test case
The softening agent that embodiment 1,2,3,4 is respectively adopted in the fabric of four pieces of formed objects carries out soft treatment, test result
It is as follows：
| Embodiment | Stiffness | Creasy recovery angle | Shearing rigidity | Bending stiffness |
| Former cloth | 3.05 | 110 | 1.72 | 0.7022 |
| 1 | 1.42 | 172 | 1.42 | 0.4505 |
| 2 | 1.29 | 185 | 1.28 | 0.3924 |
| 3 | 1.12 | 198 | 1.19 | 0.3323 |
| 4 | 1.20 | 192 | 1.20 | 0.3433 |
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention includes appended claims and its equivalent limits.
Claims (7)
- A kind of 1. silicone softening agent, it is characterised in that：The silicone softening agent includes the raw material of following parts by weight：Amino Silicone oil 20-30 parts, dimethylaminoethyl methacrylate 5-10 parts, emulsifying agent 5-10 parts, turkey red oil 5-10 parts, octadecyl are different Cyanate 3-5 parts, octamethylcyclotetrasiloxane 10-15 parts, citric acid 4-6 parts, diatomite 5-10 parts, APEO 3-5 parts, plant Thing essential oil 5-10 parts, deionized water 50-80 parts.
- 2. silicone softening agent according to claim 1, it is characterised in that：The emulsifying agent is aliphatic alcohol polyethenoxy It is one or more than one kinds of in ether, APES, sorbitan fatty acid ester, paregal O.
- 3. silicone softening agent according to claim 1, it is characterised in that：The plants essential oil is Lavender, thin Lotus essential oil, lemon, jasmine essential oil, Rosa Damascana, yulan essential oil, cape jasmine flower essential oil, one kind in narcissus flower essential oil or Person more than one.
- 4. silicone softening agent according to claim 1, it is characterised in that：According to parts by weight, including following components：Ammonia 20 parts of base silicone oil, 5 parts of dimethylaminoethyl methacrylate, 5 parts of emulsifying agent, 5 parts of turkey red oil, 3 parts of octadecylisocyanate, 10 parts of octamethylcyclotetrasiloxane, 4 parts of citric acid, 5 parts of diatomite, 3 parts of APEO, 5 parts of plants essential oil, deionized water 50 Part.
- 5. silicone softening agent according to claim 1, it is characterised in that：According to parts by weight, including following components：Ammonia 25 parts of base silicone oil, 8 parts of dimethylaminoethyl methacrylate, 8 parts of emulsifying agent, 8 parts of turkey red oil, 4 parts of octadecylisocyanate, 13 parts of octamethylcyclotetrasiloxane, 5 parts of citric acid, 8 parts of diatomite, 4 parts of APEO, 8 parts of plants essential oil, deionized water 65 Part.
- 6. silicone softening agent according to claim 1, it is characterised in that：According to parts by weight, including following components：Ammonia 30 parts of base silicone oil, 10 parts of dimethylaminoethyl methacrylate, 10 parts of emulsifying agent, 10 parts of turkey red oil, octadecylisocyanate 5 Part, 15 parts of octamethylcyclotetrasiloxane, 6 parts of citric acid, 10 parts of diatomite, 5 parts of APEO, 10 parts of plants essential oil, deionization 80 parts of water.
- A kind of 7. preparation method of any described silicone softening agent in 1-6 using the claims, it is characterised in that：Tool Body step is as follows：Step 1, amido silicon oil 20-30 parts, dimethylaminoethyl methacrylate 5-10 parts, emulsifying agent 5- are added in a kettle 10 parts, deionized water 50-80 parts, 60-70 DEG C is warming up to, 1000-3000 revs/min, stirs 20-30 minutes；Step 2, temperature is raised to 70-80 DEG C, adds octamethylcyclotetrasiloxane 10-15 parts, APEO 3-5 parts, 500- 1000 revs/min, stir 20-30 minutes；Step 3, it is cooled to 40-50 DEG C, adds octadecylisocyanate 3-5 parts, citric acid 4-6 parts, 500-1000 revs/min Clock, stir 20-30 minutes；Step 4,30-40 DEG C is cooled to, turkey red oil 5-10 parts is added, 500-1000 revs/min, stirs 20-30 minutes；Step 5,20-30 DEG C is cooled to, diatomite 5-10 parts, plants essential oil 5-10 parts is added, 500-1000 revs/min, stirs 20-30 minutes；Step 6, stirring is closed down, the silicone softening agent prepared；Step 7, stand and be cooled in stirred tank liquid silicone softening agent and be less than 20 DEG C, blowing encapsulation, finished product.
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| CN108842460A (en) * | 2018-06-26 | 2018-11-20 | 湖北新海鸿化工有限公司 | A kind of fabric post-treatment softening agent |
| CN108978228A (en) * | 2018-06-07 | 2018-12-11 | 广州市德鹏新材料科技有限公司 | A kind of modified organic silicon softening agent and its application method |
| CN109137527A (en) * | 2018-06-26 | 2019-01-04 | 湖北新海鸿化工有限公司 | A kind of material treatment agent |
| CN110117904A (en) * | 2019-05-23 | 2019-08-13 | 绍兴一扬化工助剂有限公司 | A kind of soft finishing agent and its technique for applying |
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| CN110117904A (en) * | 2019-05-23 | 2019-08-13 | 绍兴一扬化工助剂有限公司 | A kind of soft finishing agent and its technique for applying |
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Application publication date: 20180223 |