CN107740268A - Mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof - Google Patents

Mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof Download PDF

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Publication number
CN107740268A
CN107740268A CN201710897080.9A CN201710897080A CN107740268A CN 107740268 A CN107740268 A CN 107740268A CN 201710897080 A CN201710897080 A CN 201710897080A CN 107740268 A CN107740268 A CN 107740268A
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parts
fabric
softening agent
mould proof
smooth fluffy
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储平
徐有琦
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Jiangsu New Lucky Polytron Technologies Inc
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Jiangsu New Lucky Polytron Technologies Inc
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Priority to CN201710897080.9A priority Critical patent/CN107740268A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic Table
    • DTEXTILES; PAPER
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D06M11/82Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11Compounds containing epoxy groups or precursors thereof
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
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    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
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    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
    • DTEXTILES; PAPER
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    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50Modified hand or grip properties; Softening compositions

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof, the mould proof smooth fluffy softening agent of the fabric includes the raw material of following parts by weight:Natural 20 30 parts of cotton wax, 10 15 parts of sorbitan fatty acid ester, 10 15 parts of sodium metasilicate, 5 10 parts of diatomite, 10 15 parts of sodium acid carbonate, 59 parts of borax, 13 parts of triethanolamine, 10 20 parts of ethanol, 35 parts of DBSA, 5 10 parts of magnesium chloride, 5 10 parts of epoxychloropropane, 35 parts of butyl titanate, 5 10 parts of Jasmine juice, 30 50 parts of deionized water.After the mould proof smooth fluffy softening agent application of fabric of the present invention, the stiffness of fabric declines a lot, and shearing rigidity and bending stiffness all decline a lot, and creasy recovery angle increase is a lot, and smooth fluffy flexibility improves a lot, and fabric can reach permanent mould proof.The mould proof smooth fluffy softening agent manufacturing process of fabric of the present invention is simple to operation, and low in raw material price easily obtains, and nontoxic, human body is not stimulated, volatility is low.

Description

Mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relate to a kind of mould proof smooth fluffy softening agent of fabric and its Preparation method.
Background technology
Softening agent is a kind of quiet, the coefficient of kinetic friction chemical substance that can change fiber.When the static friction system for changing fiber During number, feel, which touches fabric, smooth sense, is easy to move on fiber or fabric;When changing the coefficient of kinetic friction, fiber and fibre Fine structure between dimension is easy to be mutually shifted, that is, fiber or fabric it is easily deformable.
Soft finish is the important finishing process in dyeing and printing process.Textile in process, through repeatedly processing after Feel can become coarse, and general synthetic fabrics feel is worse, especially Superfine Fibre Fabric.Put down in order that fabric has Sliding, fluffy, soft, smooth, comfortable feel, it is necessary to arranged to it, widely used at present carried out with softening agent Arrange.In addition softening agent largely is used during chemical fibre spinning, the spinning of various fibers, weaving etc., because With a large amount of uses of textile processing high speed and short liquor ratio mode, the phase mutual friction between fabric and equipment between fabric Increase, phenomena such as being also easy to produce scratch, bar defect.It can make fiber that there is the softness being adapted with processing conditions to put down in itself using softening agent Slip is to avoid damage to.Therefore fabric is a kind of important textile auxiliary with softening agent.
With the improvement of living standards, the requirement more and more higher to textile material, it is desirable to which fabric has necessarily smooth fluffy The soft wrinkle resistance of pine, to the quality requirements of smooth fluffy softening agent also more and more higher, which also promotes smooth fluffy softening agent Development.
The content of the invention
It is an object of the invention to provide a kind of mould proof smooth fluffy softening agent of fabric and preparation method, to solve the above-mentioned back of the body The problem of being proposed in scape technology.
To achieve the above object, the present invention provides following technical scheme:
The mould proof smooth fluffy softening agent of a kind of fabric, according to parts by weight, including following components:Natural cotton wax 20-30 parts, Sorbitan fatty acid ester 10-15 parts, sodium metasilicate 10-15 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts, borax 5-9 Part, triethanolamine 1-3 parts, ethanol 10-20 parts, DBSA 3-5 parts, magnesium chloride 5-10 parts, epoxychloropropane 5-10 Part, butyl titanate 3-5 parts, Jasmine juice 5-10 parts, deionized water 30-50 parts.
Preferably, the ethanol is absolute ethyl alcohol, and purity is pure to analyze.
Preferably, the mould proof smooth fluffy softening agent of described fabric, according to parts by weight, including following components:Natural cotton 20 parts of wax, 10 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, 10 parts of sodium acid carbonate, 5 parts of borax, three second 1 part of hydramine, 10 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 5 parts of epoxychloropropane, 3 parts of butyl titanate, jasmine 5 parts of juice of flower, 30 parts of deionized water.
Preferably, the mould proof smooth fluffy softening agent of described fabric, according to parts by weight, including following components:Natural cotton 25 parts of wax, 13 parts of sorbitan fatty acid ester, 13 parts of sodium metasilicate, 8 parts of diatomite, 13 parts of sodium acid carbonate, 7 parts of borax, three second 2 parts of hydramine, 15 parts of ethanol, 4 parts of DBSA, 8 parts of magnesium chloride, 8 parts of epoxychloropropane, 4 parts of butyl titanate, jasmine 8 parts of juice of flower, 40 parts of deionized water.
Preferably, the mould proof smooth fluffy softening agent of described fabric, according to parts by weight, including following components:Natural cotton 30 parts of wax, 15 parts of sorbitan fatty acid ester, 15 parts of sodium metasilicate, 10 parts of diatomite, 15 parts of sodium acid carbonate, 9 parts of borax, three second 3 parts of hydramine, 20 parts of ethanol, 5 parts of DBSA, 10 parts of magnesium chloride, 10 parts of epoxychloropropane, 5 parts of butyl titanate, jasmine 10 parts of jasmine juice, 50 parts of deionized water.
A kind of preparation method of the mould proof smooth fluffy softening agent of fabric, is comprised the following steps that:
(1) natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, deionization are added inside three-necked flask Water 30-50 parts, in 70-80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1-2L/min, keeps charging flatly, Insertion agitator flatly, mixing speed are 1000-2000 revs/min, reaction time 3-4h;
(2) first by borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, with ultrasonic disperse 10-20 minutes, ultrasonic work( Rate is 1200-1500W, obtains homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 500-1000 revs/min, 20-30 points of stirring Clock;
(4) temperature is reduced to 50-60 DEG C, adds epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, sodium metasilicate 10-15 Part, DBSA 3-5 parts, magnesium chloride 5-10 parts, 500-1000 revs/min, stir 20-30 minutes;
(5) 40-50 DEG C is cooled to, adds Jasmine juice 5-10 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts, 500-1000 revs/min, stir 1-2 hours;
(6) 20-30 DEG C is cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
Compared with prior art, the beneficial effects of the invention are as follows:
1st, after the mould proof smooth fluffy softening agent application of fabric of the invention, the stiffness of fabric declines a lot, and shearing is firm Degree and bending stiffness all decline a lot, and creasy recovery angle increase is a lot, and smooth fluffy flexibility raising is a lot, and fabric can reach It is permanent mould proof.
2nd, after the mould proof smooth fluffy softening agent application fabric of fabric of the invention, fabric has excellent smooth fluffy soft Soft feel, the sense of touch of fabric, sliding sense are greatly improved, and suede class, fiber, the fluffy degree of fabric are improved.
3rd, the mould proof smooth fluffy softening agent wide adaptability of fabric of the invention, is applicable various fibers.
4th, the mould proof smooth fluffy softening agent environmental protection of fabric of the invention, without APEO.
5th, the mould proof smooth fluffy softening agent manufacturing process of fabric of the invention is simple to operation, and low in raw material price easily obtains , and it is nontoxic, human body is not stimulated, volatility is low.
6th, mutual compatibility, synergy between various raw materials used in the mould proof smooth fluffy softening agent of fabric of the invention, altogether With the product that component property is excellent.
7th, the addition of sodium acid carbonate, the smooth fluffy softness of fabric is improved.
8th, technique is simplified, safe operation is simple, is easy to industrialized production.
9th, after smooth fluffy softening agent application fabric of the invention, fabric is not easy yellowing, can ensure the color of fabric It is transparent, it is smooth submissive, reduce fabric ages.
10th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally Cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, sodium metasilicate 10-15 parts, diatomite 5-10 parts, sodium acid carbonate 10- 15 parts, borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, DBSA 3-5 parts, magnesium chloride 5-10 parts, ring Oxygen chloropropane 5-10 parts, butyl titanate 3-5 parts, Jasmine juice 5-10 parts, deionized water 30-50 parts.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, deionization are added inside three-necked flask Water 30-50 parts, in 70-80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1-2L/min, keeps charging flatly, Insertion agitator flatly, mixing speed are 1000-2000 revs/min, reaction time 3-4h;
(2) first by borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, with ultrasonic disperse 10-20 minutes, ultrasonic work( Rate is 1200-1500W, obtains homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 500-1000 revs/min, 20-30 points of stirring Clock;
(4) temperature is reduced to 50-60 DEG C, adds epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, sodium metasilicate 10-15 Part, DBSA 3-5 parts, magnesium chloride 5-10 parts, 500-1000 revs/min, stir 20-30 minutes;
(5) 40-50 DEG C is cooled to, adds Jasmine juice 5-10 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts, 500-1000 revs/min, stir 1-2 hours;
(6) 20-30 DEG C is cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
Embodiment 1
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally 20 parts of cotton wax, 10 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, 10 parts of sodium acid carbonate, 5 parts of borax, three 1 part of monoethanolamine, 10 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 5 parts of epoxychloropropane, 3 parts of butyl titanate, jasmine 5 parts of jasmine juice, 30 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 20 parts of cotton wax, 10 parts of sorbitan fatty acid ester, deionized water 30 are added inside three-necked flask Part, in 70 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1L/min, keeps charging flatly, flatly insertion stirring Device, mixing speed are 1000 revs/min, reaction time 3h;
(2) first by 5 parts of borax, 1 part of triethanolamine, 10 parts of ethanol, with ultrasonic disperse 10 minutes, ultrasonic power 1200W, Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 900 revs/min, stirred 20 minutes;
(4) temperature is reduced to 50 DEG C, adds 5 parts of epoxychloropropane, 3 parts of butyl titanate, 10 parts of sodium metasilicate, dodecyl 3 parts of benzene sulfonic acid, 5 parts of magnesium chloride, 900 revs/min, stir 20 minutes;
(5) 40 DEG C are cooled to, 5 parts of Jasmine juice, 5 parts of diatomite, 10 parts of sodium acid carbonate is added, 900 revs/min, stirs Mix 1 hour;
(6) 20 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
Embodiment 2
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally 25 parts of cotton wax, 13 parts of sorbitan fatty acid ester, 13 parts of sodium metasilicate, 8 parts of diatomite, 13 parts of sodium acid carbonate, 7 parts of borax, three 2 parts of monoethanolamine, 15 parts of ethanol, 4 parts of DBSA, 8 parts of magnesium chloride, 8 parts of epoxychloropropane, 4 parts of butyl titanate, jasmine 8 parts of jasmine juice, 40 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 25 parts of cotton wax, 13 parts of sorbitan fatty acid ester, deionized water 40 are added inside three-necked flask Part, in 75 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1.5L/min, keeps charging flatly, and insertion flatly is stirred Device is mixed, mixing speed is 1500 revs/min, reaction time 3.5h;
(2) first by 7 parts of borax, 2 parts of triethanolamine, 15 parts of ethanol, with ultrasonic disperse 15 minutes, ultrasonic power 1500W, Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 800 revs/min, stirred 25 minutes;
(4) temperature is reduced to 55 DEG C, adds 8 parts of epoxychloropropane, 4 parts of butyl titanate, 13 parts of sodium metasilicate, dodecyl 4 parts of benzene sulfonic acid, 8 parts of magnesium chloride, 900 revs/min, stir 25 minutes;
(5) 45 DEG C are cooled to, 8 parts of Jasmine juice, 8 parts of diatomite, 13 parts of sodium acid carbonate is added, 800 revs/min, stirs Mix 1.5 hours;
(6) 25 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
Embodiment 3
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, 15 parts of sodium metasilicate, 10 parts of diatomite, 15 parts of sodium acid carbonate, 9 parts of borax, three 3 parts of monoethanolamine, 20 parts of ethanol, 5 parts of DBSA, 10 parts of magnesium chloride, 10 parts of epoxychloropropane, 5 parts of butyl titanate, 10 parts of Jasmine juice, 50 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, deionized water 50 are added inside three-necked flask Part, in 80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 2L/min, keeps charging flatly, flatly insertion stirring Device, mixing speed are 2000 revs/min, reaction time 4h;
(2) first by 8 parts of borax, 3 parts of triethanolamine, 20 parts of ethanol, with ultrasonic disperse 20 minutes, ultrasonic power 1500W, Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 1000 revs/min, stirred 30 minutes;
(4) temperature is reduced to 60 DEG C, adds 10 parts of epoxychloropropane, 5 parts of butyl titanate, 15 parts of sodium metasilicate, dodecane 5 parts of base benzene sulfonic acid, 10 parts of magnesium chloride, 1000 revs/min, stir 30 minutes;
(5) it is cooled to 50 DEG C, adds 10 parts of Jasmine juice, 10 parts of diatomite, 15 parts of sodium acid carbonate, 1000 revs/min, Stirring 2 hours;
(6) 30 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
Embodiment 4
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, 15 parts of sodium acid carbonate, 9 parts of borax, three 3 parts of monoethanolamine, 20 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 10 parts of epoxychloropropane, 4 parts of butyl titanate, 8 parts of Jasmine juice, 30 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, deionized water 30 are added inside three-necked flask Part, in 80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 2L/min, keeps charging flatly, flatly insertion stirring Device, mixing speed are 1000 revs/min, reaction time 4h;
(2) first by 9 parts of borax, 3 parts of triethanolamine, 20 parts of ethanol, with ultrasonic disperse 20 minutes, ultrasonic power 1200W, Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 1000 revs/min, stirred 20 minutes;
(4) temperature is reduced to 60 DEG C, adds 10 parts of epoxychloropropane, 4 parts of butyl titanate, 10 parts of sodium metasilicate, dodecane 3 parts of base benzene sulfonic acid, 5 parts of magnesium chloride, 800 revs/min, stir 20 minutes;
(5) 40 DEG C are cooled to, 8 parts of Jasmine juice, 5 parts of diatomite, 15 parts of sodium acid carbonate is added, 900 revs/min, stirs Mix 2 hours;
(6) 30 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
Test case
The smooth fluffy softening agent progress that embodiment 1,2,3,4 is respectively adopted in the fabric of four pieces of formed objects is smooth fluffy soft Supple-settlement, test result are as follows:
Embodiment Stiffness Creasy recovery angle Shearing rigidity Bending stiffness
Former cloth 3.32 130 1.72 0.8522
1 1.48 179 1.48 0.4405
2 1.19 184 1.33 0.3934
3 1.06 192 1.21 0.3543
4 1.12 190 1.28 0.3763
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention includes appended claims and its equivalent limits.

Claims (6)

  1. A kind of 1. mould proof smooth fluffy softening agent of fabric, it is characterised in that:The mould proof smooth fluffy softening agent of the fabric is included such as The raw material of lower parts by weight:Natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, sodium metasilicate 10-15 parts, diatom Native 5-10 parts, sodium acid carbonate 10-15 parts, borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, DBSA 3- 5 parts, magnesium chloride 5-10 parts, epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, Jasmine juice 5-10 parts, deionized water 30-50 parts.
  2. 2. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:The ethanol is anhydrous second Alcohol, purity are pure to analyze.
  3. 3. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:According to parts by weight, including Following components:Natural 20 parts of cotton wax, 10 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, sodium acid carbonate 10 Part, 5 parts of borax, 1 part of triethanolamine, 10 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 5 parts of epoxychloropropane, titanium Sour 3 parts of four butyl ester, 5 parts of Jasmine juice, 30 parts of deionized water.
  4. 4. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:According to parts by weight, including Following components:Natural 25 parts of cotton wax, 13 parts of sorbitan fatty acid ester, 13 parts of sodium metasilicate, 8 parts of diatomite, sodium acid carbonate 13 Part, 7 parts of borax, 2 parts of triethanolamine, 15 parts of ethanol, 4 parts of DBSA, 8 parts of magnesium chloride, 8 parts of epoxychloropropane, titanium Sour 4 parts of four butyl ester, 8 parts of Jasmine juice, 40 parts of deionized water.
  5. 5. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:According to parts by weight, including Following components:Natural 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, 15 parts of sodium metasilicate, 10 parts of diatomite, sodium acid carbonate 15 Part, 9 parts of borax, 3 parts of triethanolamine, 20 parts of ethanol, 5 parts of DBSA, 10 parts of magnesium chloride, 10 parts of epoxychloropropane, 5 parts of butyl titanate, 10 parts of Jasmine juice, 50 parts of deionized water.
  6. 6. the preparation method of any mould proof smooth fluffy softening agent of described fabric in a kind of 1-5 using the claims, its It is characterised by:Comprise the following steps that:
    Step 1, natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, deionization are added inside three-necked flask Water 30-50 parts, in 70-80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1-2L/min, keeps charging flatly, Insertion agitator flatly, mixing speed are 1000-2000 revs/min, reaction time 3-4h;
    Step 2, first by borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, with ultrasonic disperse 10-20 minutes, ultrasonic work( Rate is 1200-1500W, obtains homogeneous solution;
    Step 3, the homogeneous solution of step 2 is added in the solution of step 1,500-1000 revs/min, stirs 20-30 minutes;
    Step 4, temperature is reduced to 50-60 DEG C, adds epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, sodium metasilicate 10-15 Part, DBSA 3-5 parts, magnesium chloride 5-10 parts, 500-1000 revs/min, stir 20-30 minutes;
    Step 5,40-50 DEG C is cooled to, adds Jasmine juice 5-10 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts, 500-1000 revs/min, stir 1-2 hours;
    Step 6,20-30 DEG C is cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
    Step 7, stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
CN201710897080.9A 2017-09-28 2017-09-28 Mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof Pending CN107740268A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108842460A (en) * 2018-06-26 2018-11-20 湖北新海鸿化工有限公司 A kind of fabric post-treatment softening agent
CN110447996A (en) * 2019-09-25 2019-11-15 安徽高梵电子商务有限公司 A kind of natural feather composite heat insulation material

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1151456A (en) * 1995-12-08 1997-06-11 花王株式会社 Antibacterial softener composition
CN102619090A (en) * 2011-01-27 2012-08-01 上海雅运纺织助剂有限公司 Smoothening softener composition for cotton and its blended yarns, and preparation method thereof
CN104264465A (en) * 2014-09-26 2015-01-07 无锡市东北塘宏良染色厂 Softening agent for treating clothes and preparation method thereof
CN106868872A (en) * 2017-03-13 2017-06-20 广东得到宝贝科技有限公司 A kind of fabric softener

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1151456A (en) * 1995-12-08 1997-06-11 花王株式会社 Antibacterial softener composition
CN102619090A (en) * 2011-01-27 2012-08-01 上海雅运纺织助剂有限公司 Smoothening softener composition for cotton and its blended yarns, and preparation method thereof
CN104264465A (en) * 2014-09-26 2015-01-07 无锡市东北塘宏良染色厂 Softening agent for treating clothes and preparation method thereof
CN106868872A (en) * 2017-03-13 2017-06-20 广东得到宝贝科技有限公司 A kind of fabric softener

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108842460A (en) * 2018-06-26 2018-11-20 湖北新海鸿化工有限公司 A kind of fabric post-treatment softening agent
CN110447996A (en) * 2019-09-25 2019-11-15 安徽高梵电子商务有限公司 A kind of natural feather composite heat insulation material
CN110447996B (en) * 2019-09-25 2021-06-22 安徽高梵电子商务有限公司 Down feather composite thermal insulation material

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Application publication date: 20180227