CN107740268A - Mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof - Google Patents
Mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof Download PDFInfo
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- CN107740268A CN107740268A CN201710897080.9A CN201710897080A CN107740268A CN 107740268 A CN107740268 A CN 107740268A CN 201710897080 A CN201710897080 A CN 201710897080A CN 107740268 A CN107740268 A CN 107740268A
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- parts
- fabric
- softening agent
- mould proof
- smooth fluffy
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- 239000004744 fabric Substances 0.000 title claims abstract description 74
- 239000004902 Softening Agent Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 64
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 42
- 235000010254 Jasminum officinale Nutrition 0.000 claims abstract description 24
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 22
- 229920000742 Cotton Polymers 0.000 claims abstract description 21
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 21
- 229910021538 borax Inorganic materials 0.000 claims abstract description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 21
- 239000000194 fatty acid Substances 0.000 claims abstract description 21
- 229930195729 fatty acid Natural products 0.000 claims abstract description 21
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims abstract description 21
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 21
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 21
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 21
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 21
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 21
- -1 sorbitan fatty acid ester Chemical class 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000008367 deionised water Substances 0.000 claims abstract description 18
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 18
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 27
- 241000207840 Jasminum Species 0.000 claims description 23
- 239000012456 homogeneous solution Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 238000007664 blowing Methods 0.000 claims description 7
- 238000005538 encapsulation Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000003780 insertion Methods 0.000 claims description 7
- 230000037431 insertion Effects 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 230000035484 reaction time Effects 0.000 claims description 7
- 238000002242 deionisation method Methods 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims 2
- 229910052719 titanium Inorganic materials 0.000 claims 2
- 239000010936 titanium Substances 0.000 claims 2
- 238000005452 bending Methods 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 238000010008 shearing Methods 0.000 abstract description 3
- 230000007423 decrease Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- 240000005385 Jasminum sambac Species 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 description 16
- 239000000835 fiber Substances 0.000 description 12
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 6
- 239000004753 textile Substances 0.000 description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 4
- 229940092714 benzenesulfonic acid Drugs 0.000 description 4
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000009987 spinning Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- YWNYZQTZOONLGU-UHFFFAOYSA-N C(CC)Cl.[O] Chemical compound C(CC)Cl.[O] YWNYZQTZOONLGU-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
- D06M11/82—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof, the mould proof smooth fluffy softening agent of the fabric includes the raw material of following parts by weight:Natural 20 30 parts of cotton wax, 10 15 parts of sorbitan fatty acid ester, 10 15 parts of sodium metasilicate, 5 10 parts of diatomite, 10 15 parts of sodium acid carbonate, 59 parts of borax, 13 parts of triethanolamine, 10 20 parts of ethanol, 35 parts of DBSA, 5 10 parts of magnesium chloride, 5 10 parts of epoxychloropropane, 35 parts of butyl titanate, 5 10 parts of Jasmine juice, 30 50 parts of deionized water.After the mould proof smooth fluffy softening agent application of fabric of the present invention, the stiffness of fabric declines a lot, and shearing rigidity and bending stiffness all decline a lot, and creasy recovery angle increase is a lot, and smooth fluffy flexibility improves a lot, and fabric can reach permanent mould proof.The mould proof smooth fluffy softening agent manufacturing process of fabric of the present invention is simple to operation, and low in raw material price easily obtains, and nontoxic, human body is not stimulated, volatility is low.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relate to a kind of mould proof smooth fluffy softening agent of fabric and its
Preparation method.
Background technology
Softening agent is a kind of quiet, the coefficient of kinetic friction chemical substance that can change fiber.When the static friction system for changing fiber
During number, feel, which touches fabric, smooth sense, is easy to move on fiber or fabric;When changing the coefficient of kinetic friction, fiber and fibre
Fine structure between dimension is easy to be mutually shifted, that is, fiber or fabric it is easily deformable.
Soft finish is the important finishing process in dyeing and printing process.Textile in process, through repeatedly processing after
Feel can become coarse, and general synthetic fabrics feel is worse, especially Superfine Fibre Fabric.Put down in order that fabric has
Sliding, fluffy, soft, smooth, comfortable feel, it is necessary to arranged to it, widely used at present carried out with softening agent
Arrange.In addition softening agent largely is used during chemical fibre spinning, the spinning of various fibers, weaving etc., because
With a large amount of uses of textile processing high speed and short liquor ratio mode, the phase mutual friction between fabric and equipment between fabric
Increase, phenomena such as being also easy to produce scratch, bar defect.It can make fiber that there is the softness being adapted with processing conditions to put down in itself using softening agent
Slip is to avoid damage to.Therefore fabric is a kind of important textile auxiliary with softening agent.
With the improvement of living standards, the requirement more and more higher to textile material, it is desirable to which fabric has necessarily smooth fluffy
The soft wrinkle resistance of pine, to the quality requirements of smooth fluffy softening agent also more and more higher, which also promotes smooth fluffy softening agent
Development.
The content of the invention
It is an object of the invention to provide a kind of mould proof smooth fluffy softening agent of fabric and preparation method, to solve the above-mentioned back of the body
The problem of being proposed in scape technology.
To achieve the above object, the present invention provides following technical scheme:
The mould proof smooth fluffy softening agent of a kind of fabric, according to parts by weight, including following components:Natural cotton wax 20-30 parts,
Sorbitan fatty acid ester 10-15 parts, sodium metasilicate 10-15 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts, borax 5-9
Part, triethanolamine 1-3 parts, ethanol 10-20 parts, DBSA 3-5 parts, magnesium chloride 5-10 parts, epoxychloropropane 5-10
Part, butyl titanate 3-5 parts, Jasmine juice 5-10 parts, deionized water 30-50 parts.
Preferably, the ethanol is absolute ethyl alcohol, and purity is pure to analyze.
Preferably, the mould proof smooth fluffy softening agent of described fabric, according to parts by weight, including following components:Natural cotton
20 parts of wax, 10 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, 10 parts of sodium acid carbonate, 5 parts of borax, three second
1 part of hydramine, 10 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 5 parts of epoxychloropropane, 3 parts of butyl titanate, jasmine
5 parts of juice of flower, 30 parts of deionized water.
Preferably, the mould proof smooth fluffy softening agent of described fabric, according to parts by weight, including following components:Natural cotton
25 parts of wax, 13 parts of sorbitan fatty acid ester, 13 parts of sodium metasilicate, 8 parts of diatomite, 13 parts of sodium acid carbonate, 7 parts of borax, three second
2 parts of hydramine, 15 parts of ethanol, 4 parts of DBSA, 8 parts of magnesium chloride, 8 parts of epoxychloropropane, 4 parts of butyl titanate, jasmine
8 parts of juice of flower, 40 parts of deionized water.
Preferably, the mould proof smooth fluffy softening agent of described fabric, according to parts by weight, including following components:Natural cotton
30 parts of wax, 15 parts of sorbitan fatty acid ester, 15 parts of sodium metasilicate, 10 parts of diatomite, 15 parts of sodium acid carbonate, 9 parts of borax, three second
3 parts of hydramine, 20 parts of ethanol, 5 parts of DBSA, 10 parts of magnesium chloride, 10 parts of epoxychloropropane, 5 parts of butyl titanate, jasmine
10 parts of jasmine juice, 50 parts of deionized water.
A kind of preparation method of the mould proof smooth fluffy softening agent of fabric, is comprised the following steps that:
(1) natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, deionization are added inside three-necked flask
Water 30-50 parts, in 70-80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1-2L/min, keeps charging flatly,
Insertion agitator flatly, mixing speed are 1000-2000 revs/min, reaction time 3-4h;
(2) first by borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, with ultrasonic disperse 10-20 minutes, ultrasonic work(
Rate is 1200-1500W, obtains homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 500-1000 revs/min, 20-30 points of stirring
Clock;
(4) temperature is reduced to 50-60 DEG C, adds epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, sodium metasilicate 10-15
Part, DBSA 3-5 parts, magnesium chloride 5-10 parts, 500-1000 revs/min, stir 20-30 minutes;
(5) 40-50 DEG C is cooled to, adds Jasmine juice 5-10 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts,
500-1000 revs/min, stir 1-2 hours;
(6) 20-30 DEG C is cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system
Obtain finished product.
Compared with prior art, the beneficial effects of the invention are as follows:
1st, after the mould proof smooth fluffy softening agent application of fabric of the invention, the stiffness of fabric declines a lot, and shearing is firm
Degree and bending stiffness all decline a lot, and creasy recovery angle increase is a lot, and smooth fluffy flexibility raising is a lot, and fabric can reach
It is permanent mould proof.
2nd, after the mould proof smooth fluffy softening agent application fabric of fabric of the invention, fabric has excellent smooth fluffy soft
Soft feel, the sense of touch of fabric, sliding sense are greatly improved, and suede class, fiber, the fluffy degree of fabric are improved.
3rd, the mould proof smooth fluffy softening agent wide adaptability of fabric of the invention, is applicable various fibers.
4th, the mould proof smooth fluffy softening agent environmental protection of fabric of the invention, without APEO.
5th, the mould proof smooth fluffy softening agent manufacturing process of fabric of the invention is simple to operation, and low in raw material price easily obtains
, and it is nontoxic, human body is not stimulated, volatility is low.
6th, mutual compatibility, synergy between various raw materials used in the mould proof smooth fluffy softening agent of fabric of the invention, altogether
With the product that component property is excellent.
7th, the addition of sodium acid carbonate, the smooth fluffy softness of fabric is improved.
8th, technique is simplified, safe operation is simple, is easy to industrialized production.
9th, after smooth fluffy softening agent application fabric of the invention, fabric is not easy yellowing, can ensure the color of fabric
It is transparent, it is smooth submissive, reduce fabric ages.
10th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally
Cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, sodium metasilicate 10-15 parts, diatomite 5-10 parts, sodium acid carbonate 10-
15 parts, borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, DBSA 3-5 parts, magnesium chloride 5-10 parts, ring
Oxygen chloropropane 5-10 parts, butyl titanate 3-5 parts, Jasmine juice 5-10 parts, deionized water 30-50 parts.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, deionization are added inside three-necked flask
Water 30-50 parts, in 70-80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1-2L/min, keeps charging flatly,
Insertion agitator flatly, mixing speed are 1000-2000 revs/min, reaction time 3-4h;
(2) first by borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, with ultrasonic disperse 10-20 minutes, ultrasonic work(
Rate is 1200-1500W, obtains homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 500-1000 revs/min, 20-30 points of stirring
Clock;
(4) temperature is reduced to 50-60 DEG C, adds epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, sodium metasilicate 10-15
Part, DBSA 3-5 parts, magnesium chloride 5-10 parts, 500-1000 revs/min, stir 20-30 minutes;
(5) 40-50 DEG C is cooled to, adds Jasmine juice 5-10 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts,
500-1000 revs/min, stir 1-2 hours;
(6) 20-30 DEG C is cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system
Obtain finished product.
Embodiment 1
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally
20 parts of cotton wax, 10 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, 10 parts of sodium acid carbonate, 5 parts of borax, three
1 part of monoethanolamine, 10 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 5 parts of epoxychloropropane, 3 parts of butyl titanate, jasmine
5 parts of jasmine juice, 30 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 20 parts of cotton wax, 10 parts of sorbitan fatty acid ester, deionized water 30 are added inside three-necked flask
Part, in 70 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1L/min, keeps charging flatly, flatly insertion stirring
Device, mixing speed are 1000 revs/min, reaction time 3h;
(2) first by 5 parts of borax, 1 part of triethanolamine, 10 parts of ethanol, with ultrasonic disperse 10 minutes, ultrasonic power 1200W,
Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 900 revs/min, stirred 20 minutes;
(4) temperature is reduced to 50 DEG C, adds 5 parts of epoxychloropropane, 3 parts of butyl titanate, 10 parts of sodium metasilicate, dodecyl
3 parts of benzene sulfonic acid, 5 parts of magnesium chloride, 900 revs/min, stir 20 minutes;
(5) 40 DEG C are cooled to, 5 parts of Jasmine juice, 5 parts of diatomite, 10 parts of sodium acid carbonate is added, 900 revs/min, stirs
Mix 1 hour;
(6) 20 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system
Obtain finished product.
Embodiment 2
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally
25 parts of cotton wax, 13 parts of sorbitan fatty acid ester, 13 parts of sodium metasilicate, 8 parts of diatomite, 13 parts of sodium acid carbonate, 7 parts of borax, three
2 parts of monoethanolamine, 15 parts of ethanol, 4 parts of DBSA, 8 parts of magnesium chloride, 8 parts of epoxychloropropane, 4 parts of butyl titanate, jasmine
8 parts of jasmine juice, 40 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 25 parts of cotton wax, 13 parts of sorbitan fatty acid ester, deionized water 40 are added inside three-necked flask
Part, in 75 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1.5L/min, keeps charging flatly, and insertion flatly is stirred
Device is mixed, mixing speed is 1500 revs/min, reaction time 3.5h;
(2) first by 7 parts of borax, 2 parts of triethanolamine, 15 parts of ethanol, with ultrasonic disperse 15 minutes, ultrasonic power 1500W,
Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 800 revs/min, stirred 25 minutes;
(4) temperature is reduced to 55 DEG C, adds 8 parts of epoxychloropropane, 4 parts of butyl titanate, 13 parts of sodium metasilicate, dodecyl
4 parts of benzene sulfonic acid, 8 parts of magnesium chloride, 900 revs/min, stir 25 minutes;
(5) 45 DEG C are cooled to, 8 parts of Jasmine juice, 8 parts of diatomite, 13 parts of sodium acid carbonate is added, 800 revs/min, stirs
Mix 1.5 hours;
(6) 25 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system
Obtain finished product.
Embodiment 3
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally
30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, 15 parts of sodium metasilicate, 10 parts of diatomite, 15 parts of sodium acid carbonate, 9 parts of borax, three
3 parts of monoethanolamine, 20 parts of ethanol, 5 parts of DBSA, 10 parts of magnesium chloride, 10 parts of epoxychloropropane, 5 parts of butyl titanate,
10 parts of Jasmine juice, 50 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, deionized water 50 are added inside three-necked flask
Part, in 80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 2L/min, keeps charging flatly, flatly insertion stirring
Device, mixing speed are 2000 revs/min, reaction time 4h;
(2) first by 8 parts of borax, 3 parts of triethanolamine, 20 parts of ethanol, with ultrasonic disperse 20 minutes, ultrasonic power 1500W,
Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 1000 revs/min, stirred 30 minutes;
(4) temperature is reduced to 60 DEG C, adds 10 parts of epoxychloropropane, 5 parts of butyl titanate, 15 parts of sodium metasilicate, dodecane
5 parts of base benzene sulfonic acid, 10 parts of magnesium chloride, 1000 revs/min, stir 30 minutes;
(5) it is cooled to 50 DEG C, adds 10 parts of Jasmine juice, 10 parts of diatomite, 15 parts of sodium acid carbonate, 1000 revs/min,
Stirring 2 hours;
(6) 30 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system
Obtain finished product.
Embodiment 4
The invention discloses a kind of mould proof smooth fluffy softening agent of fabric, according to parts by weight, including following components:Naturally
30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, 15 parts of sodium acid carbonate, 9 parts of borax, three
3 parts of monoethanolamine, 20 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 10 parts of epoxychloropropane, 4 parts of butyl titanate,
8 parts of Jasmine juice, 30 parts of deionized water.
Present invention also offers a kind of preparation method of the mould proof smooth fluffy softening agent of fabric, comprise the following steps that:
(1) natural 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, deionized water 30 are added inside three-necked flask
Part, in 80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 2L/min, keeps charging flatly, flatly insertion stirring
Device, mixing speed are 1000 revs/min, reaction time 4h;
(2) first by 9 parts of borax, 3 parts of triethanolamine, 20 parts of ethanol, with ultrasonic disperse 20 minutes, ultrasonic power 1200W,
Obtain homogeneous solution;
(3) homogeneous solution of step (2) is added in the solution of step (1), 1000 revs/min, stirred 20 minutes;
(4) temperature is reduced to 60 DEG C, adds 10 parts of epoxychloropropane, 4 parts of butyl titanate, 10 parts of sodium metasilicate, dodecane
3 parts of base benzene sulfonic acid, 5 parts of magnesium chloride, 800 revs/min, stir 20 minutes;
(5) 40 DEG C are cooled to, 8 parts of Jasmine juice, 5 parts of diatomite, 15 parts of sodium acid carbonate is added, 900 revs/min, stirs
Mix 2 hours;
(6) 30 DEG C are cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;
(7) stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system
Obtain finished product.
Test case
The smooth fluffy softening agent progress that embodiment 1,2,3,4 is respectively adopted in the fabric of four pieces of formed objects is smooth fluffy soft
Supple-settlement, test result are as follows:
Embodiment | Stiffness | Creasy recovery angle | Shearing rigidity | Bending stiffness |
Former cloth | 3.32 | 130 | 1.72 | 0.8522 |
1 | 1.48 | 179 | 1.48 | 0.4405 |
2 | 1.19 | 184 | 1.33 | 0.3934 |
3 | 1.06 | 192 | 1.21 | 0.3543 |
4 | 1.12 | 190 | 1.28 | 0.3763 |
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding
And modification, the scope of the present invention includes appended claims and its equivalent limits.
Claims (6)
- A kind of 1. mould proof smooth fluffy softening agent of fabric, it is characterised in that:The mould proof smooth fluffy softening agent of the fabric is included such as The raw material of lower parts by weight:Natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, sodium metasilicate 10-15 parts, diatom Native 5-10 parts, sodium acid carbonate 10-15 parts, borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, DBSA 3- 5 parts, magnesium chloride 5-10 parts, epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, Jasmine juice 5-10 parts, deionized water 30-50 parts.
- 2. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:The ethanol is anhydrous second Alcohol, purity are pure to analyze.
- 3. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:According to parts by weight, including Following components:Natural 20 parts of cotton wax, 10 parts of sorbitan fatty acid ester, 10 parts of sodium metasilicate, 5 parts of diatomite, sodium acid carbonate 10 Part, 5 parts of borax, 1 part of triethanolamine, 10 parts of ethanol, 3 parts of DBSA, 5 parts of magnesium chloride, 5 parts of epoxychloropropane, titanium Sour 3 parts of four butyl ester, 5 parts of Jasmine juice, 30 parts of deionized water.
- 4. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:According to parts by weight, including Following components:Natural 25 parts of cotton wax, 13 parts of sorbitan fatty acid ester, 13 parts of sodium metasilicate, 8 parts of diatomite, sodium acid carbonate 13 Part, 7 parts of borax, 2 parts of triethanolamine, 15 parts of ethanol, 4 parts of DBSA, 8 parts of magnesium chloride, 8 parts of epoxychloropropane, titanium Sour 4 parts of four butyl ester, 8 parts of Jasmine juice, 40 parts of deionized water.
- 5. the mould proof smooth fluffy softening agent of fabric according to claim 1, it is characterised in that:According to parts by weight, including Following components:Natural 30 parts of cotton wax, 15 parts of sorbitan fatty acid ester, 15 parts of sodium metasilicate, 10 parts of diatomite, sodium acid carbonate 15 Part, 9 parts of borax, 3 parts of triethanolamine, 20 parts of ethanol, 5 parts of DBSA, 10 parts of magnesium chloride, 10 parts of epoxychloropropane, 5 parts of butyl titanate, 10 parts of Jasmine juice, 50 parts of deionized water.
- 6. the preparation method of any mould proof smooth fluffy softening agent of described fabric in a kind of 1-5 using the claims, its It is characterised by:Comprise the following steps that:Step 1, natural cotton wax 20-30 parts, sorbitan fatty acid ester 10-15 parts, deionization are added inside three-necked flask Water 30-50 parts, in 70-80 DEG C of heating of oil bath pan, nitrogen protection, the speed for being passed through nitrogen is 1-2L/min, keeps charging flatly, Insertion agitator flatly, mixing speed are 1000-2000 revs/min, reaction time 3-4h;Step 2, first by borax 5-9 parts, triethanolamine 1-3 parts, ethanol 10-20 parts, with ultrasonic disperse 10-20 minutes, ultrasonic work( Rate is 1200-1500W, obtains homogeneous solution;Step 3, the homogeneous solution of step 2 is added in the solution of step 1,500-1000 revs/min, stirs 20-30 minutes;Step 4, temperature is reduced to 50-60 DEG C, adds epoxychloropropane 5-10 parts, butyl titanate 3-5 parts, sodium metasilicate 10-15 Part, DBSA 3-5 parts, magnesium chloride 5-10 parts, 500-1000 revs/min, stir 20-30 minutes;Step 5,40-50 DEG C is cooled to, adds Jasmine juice 5-10 parts, diatomite 5-10 parts, sodium acid carbonate 10-15 parts, 500-1000 revs/min, stir 1-2 hours;Step 6,20-30 DEG C is cooled to, closes down stirring, the mould proof smooth fluffy softening agent of the liquid fabric prepared;Step 7, stand and be cooled to the mould proof smooth fluffy softening agent of liquid fabric in three-necked flask less than 20 DEG C, blowing encapsulation, system Obtain finished product.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108842460A (en) * | 2018-06-26 | 2018-11-20 | 湖北新海鸿化工有限公司 | A kind of fabric post-treatment softening agent |
CN110447996A (en) * | 2019-09-25 | 2019-11-15 | 安徽高梵电子商务有限公司 | A kind of natural feather composite heat insulation material |
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CN1151456A (en) * | 1995-12-08 | 1997-06-11 | 花王株式会社 | Antibacterial softener composition |
CN102619090A (en) * | 2011-01-27 | 2012-08-01 | 上海雅运纺织助剂有限公司 | Smoothening softener composition for cotton and its blended yarns, and preparation method thereof |
CN104264465A (en) * | 2014-09-26 | 2015-01-07 | 无锡市东北塘宏良染色厂 | Softening agent for treating clothes and preparation method thereof |
CN106868872A (en) * | 2017-03-13 | 2017-06-20 | 广东得到宝贝科技有限公司 | A kind of fabric softener |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1151456A (en) * | 1995-12-08 | 1997-06-11 | 花王株式会社 | Antibacterial softener composition |
CN102619090A (en) * | 2011-01-27 | 2012-08-01 | 上海雅运纺织助剂有限公司 | Smoothening softener composition for cotton and its blended yarns, and preparation method thereof |
CN104264465A (en) * | 2014-09-26 | 2015-01-07 | 无锡市东北塘宏良染色厂 | Softening agent for treating clothes and preparation method thereof |
CN106868872A (en) * | 2017-03-13 | 2017-06-20 | 广东得到宝贝科技有限公司 | A kind of fabric softener |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108842460A (en) * | 2018-06-26 | 2018-11-20 | 湖北新海鸿化工有限公司 | A kind of fabric post-treatment softening agent |
CN110447996A (en) * | 2019-09-25 | 2019-11-15 | 安徽高梵电子商务有限公司 | A kind of natural feather composite heat insulation material |
CN110447996B (en) * | 2019-09-25 | 2021-06-22 | 安徽高梵电子商务有限公司 | Down feather composite thermal insulation material |
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