CN102154822B - Multifunctional scouring and dyeing agent and preparation method thereof - Google Patents
Multifunctional scouring and dyeing agent and preparation method thereof Download PDFInfo
- Publication number
- CN102154822B CN102154822B CN 201110026414 CN201110026414A CN102154822B CN 102154822 B CN102154822 B CN 102154822B CN 201110026414 CN201110026414 CN 201110026414 CN 201110026414 A CN201110026414 A CN 201110026414A CN 102154822 B CN102154822 B CN 102154822B
- Authority
- CN
- China
- Prior art keywords
- parts
- surfactant
- agent
- experienced
- functional
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a multifunctional scouring and dyeing agent. The agent is characterized by comprising the following components by weight: 85-110 parts of solvents, 80-95 parts of surfactants A, 70-85 parts of surfactants B, 195-215 parts of chelating agents, 160-190 parts of stabilizing agents and 260-300 parts of water. The multifunctional scouring and dyeing agent has the following beneficial effects: the agent utilizes special functional chemicals, has the best effect in the dyeing process of such fabrics mainly containing cellulose fibers as cottons, cotton polyurethane and artificial cottons such as viscose, tencel, modal and other products, can selectively remove partial impurities under lower temperature, helps dyeing and levelling in the dyeing process and realizes the effects of low energy consumption, low water consumption, process time reduction, power consumption reduction, reduction of use of softening agents and the like; and the agent does not have the swelling function of strong base, has good wettability and levelling effect, combines refining and reactive dyeing into one and excludes APEO (alkylphenol ethoxylates), formaldehyde and the like.
Description
Technical field
The present invention relates to a kind of multi-functional experienced stain and preparation method thereof.
Background technology
All-cotton fabric is before concise; Contain the impurity that have an appointment 10% natural impurity and preceding working procedure are left over; As: pectin substance, nitrogen substance, wax, salt, pigment, cotton seed hulls and finish etc.; The existence of these materials has influenced the coloration of textile materials performance, and is mainly reflected in and several aspects such as dyes on water imbibition, color and luster and the prevention dyestuff.In traditional handicraft; Mainly be to adopt hydrogen peroxide solution, caustic soda and surfactant high temperature degumming; This method has been removed various impurity basically; But traditional handicraft is generally handled at 95-100 ℃, needs washing after finishing dealing with, neutralizes and remove step prefaces such as remaining hydrogen peroxide solution, has problems such as highly energy-consuming, high water consumption, high weightlessness.
Summary of the invention
The objective of the invention is provides the multi-functional experienced stain of a kind of low power consuming, low water consumption in order to overcome deficiency of the prior art.
For realizing above purpose, the present invention realizes through following technical scheme:
A kind of multi-functional experienced stain is characterized in that, comprises following component according to parts by weight: 85～110 parts of solvents; 80～95 parts of surfactant A; 70～85 parts of surfactant B; 195～215 parts of chelating agents; 160～190 parts of stabilizing agents; 260～300 parts in water.
Preferably, said solvent is selected from one or more in isooctanol, ethylene glycol, diethylene glycol, butyl cellosolve, ethylene glycol monobutyl ether, isopropyl alcohol and the butanediol.
Preferably, surfactant A is selected from one or more in ethoxylated dodecyl alcohol, tridecanol polyoxyethylene ether, polyoxyethylene oleic acid ester and the polyoxyethylene stearic acid ester.
Preferably, said surfactant B is selected from one or more in laurate, laruyl alcohol phosphate, trioctyl phosphate and the tributyl phosphate.
Preferably, said chelating agent is selected from one or more in aminotriacetic acid, EDTA, three methenes, HEDP, citric acid, gluconic acid sodium salt and the triethanolamine.
Preferably, said stabilizing agent is selected from one or more in sodium metasilicate, sodium phosphate trimer, magnesium chloride and the tertiary sodium phosphate.
Preferably, the experienced stain pH value among the present invention is 4-6.Preferably, use pH regulator agent adjustment pH value, said pH regulator agent is selected from one or more in formic acid, acetate, citric acid, malic acid, potassium hydroxide and the NaOH.Be higher than 6 like the pH value, then use acid to regulate; Be lower than 4 like the pH value, then use alkali to regulate.Above acid or alkali all can use.
Another object of the present invention provides a kind of preparation method of aforementioned multi-functional experienced stain, it is characterized in that, water, solvent and surfactant A are mixed, and is warming up to 90 ℃～110 ℃, adds chelating agent and stabilizing agent; Kept 50～70 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 25～40 minutes.
Preferably, in the preparation process, mix liquid all the time, mixing speed is 45～60rpm.
Multi-functional experienced stain among the present invention; Be to utilize special Functional Chemicals; Use cellulose fibre for main fabric like the product dyeing course of cotton, cotton ammonia, artificial cotton such as viscose glue, sky silk, model etc. in best results, can under lower temperature, selectively remove partial impurities; And dye and level dyeing in dyeing course, helping, realize low power consuming, low water consumption, minimizing process time, reduced power consumption, reduced the effects such as use of softener.Experienced stain among the present invention does not have the swelling action of highly basic, to be easy to generate folding line, abrasive fiber has clear improvement; Pre-treatment fabric not had good cleaning strength and impurity elimination effect in whole dyeing course; Have good wettability and even dyeing effect, refining and vital staining are united two into one; Can the bubble of hydrophilic fibre be cemented out, suppress foam and produce, its dye bath is gone on well; And do not contain APEO, formaldehyde etc.
The specific embodiment
Below in conjunction with embodiment the present invention is carried out detailed description:
Embodiment 1
Multi-functional experienced stain comprises following component according to parts by weight:
85 parts of solvents; Solvent is an isooctanol.
80 parts of surfactant A; Surfactant A is an ethoxylated dodecyl alcohol.
70 parts of surfactant B; Surfactant B is a laurate.
195 parts of chelating agents; Chelating agent is an aminotriacetic acid.
160 parts of stabilizing agents; Stabilizing agent is a sodium metasilicate.
260 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 90 ℃, adds chelating agent and stabilizing agent; Kept 50 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 25 minutes.
In the preparation process, mix liquid all the time, mixing speed is 45rpm.Use the pH regulator agent that the pH value is adjusted to 4.
Embodiment 2
Multi-functional experienced stain comprises following component according to parts by weight:
110 parts of solvents; Solvent is an isooctanol.
90 parts of surfactant A; Surfactant A is an ethoxylated dodecyl alcohol.
70 parts of surfactant B; Surfactant B is a laurate.
200 parts of chelating agents; Chelating agent is an aminotriacetic acid.
170 parts of stabilizing agents; Stabilizing agent is a sodium metasilicate.
260 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 100 ℃, adds chelating agent and stabilizing agent; Kept 60 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 30 minutes.
In the preparation process, mix liquid all the time, mixing speed is 50rpm.Use the pH regulator agent that the pH value is adjusted to 5.
Embodiment 3
Multi-functional experienced stain comprises following component according to parts by weight:
110 parts of solvents, solvent are isooctanol.
95 parts of surfactant A, surfactant A are ethoxylated dodecyl alcohol.
85 parts of surfactant B, surfactant B are laurate.
215 parts of chelating agents, chelating agent are aminotriacetic acid.
190 parts of stabilizing agents, stabilizing agent are sodium metasilicate.
300 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 110 ℃, adds chelating agent and stabilizing agent; Kept 70 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 40 minutes.
In the preparation process, mix liquid all the time, mixing speed is 60rpm.Use the pH regulator agent that the pH value is adjusted to 6.
Embodiment 4
Multi-functional experienced stain comprises following component according to parts by weight:
110 parts of solvents, solvent are ethylene glycol.
86 parts of surfactant A, surfactant A are tridecanol polyoxyethylene ether.
80 parts of surfactant B; Surfactant B is the laruyl alcohol phosphate.
200 parts of chelating agents; Chelating agent is EDTA.
170 parts of stabilizing agents; Stabilizing agent is a sodium phosphate trimer.
280 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 100 ℃, adds chelating agent and stabilizing agent; Kept 60 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 30 minutes.
In the preparation process, mix liquid all the time, mixing speed is 50rpm.Use the pH regulator agent that the pH value is adjusted to 4.5.
Embodiment 5
Multi-functional experienced stain comprises following component according to parts by weight:
95 parts of solvents, solvent are butyl cellosolve.
87 parts of surfactant A, surfactant A are polyoxyethylene oleic acid ester.
72 parts of surfactant B, surfactant B are trioctyl phosphate.
196 parts of chelating agents, chelating agent are HEDP.
165 parts of stabilizing agents, stabilizing agent are sodium phosphate trimer.
270 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 90 ℃, adds chelating agent and stabilizing agent; Kept 68 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 30 minutes.
In the preparation process, mix liquid all the time, mixing speed is 45rpm.Use the pH regulator agent that the pH value is adjusted to 4.3.
Embodiment 6
Multi-functional experienced stain comprises following component according to parts by weight:
98 parts of solvents; Solvent is an ethylene glycol monobutyl ether.
82 parts of surfactant A, surfactant A are polyoxyethylene stearic acid ester.
73 parts of surfactant B; Surfactant B is a laurate.
207 parts of chelating agents, chelating agent are aminotriacetic acid.
189 parts of stabilizing agents, stabilizing agent are sodium metasilicate.
290 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 110 ℃, adds chelating agent and stabilizing agent; Kept 65 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 25 minutes.
In the preparation process, mix liquid all the time, mixing speed is 60rpm.Use the pH regulator agent that the pH value is adjusted to 4.5.
Embodiment 7
Multi-functional experienced stain comprises following component according to parts by weight:
97 parts of solvents, solvent are isooctanol.
85 parts of surfactant A, surfactant A are ethoxylated dodecyl alcohol.
80 parts of surfactant B, surfactant B are the laruyl alcohol phosphate.
197 parts of chelating agents, chelating agent are aminotriacetic acid.
165 parts of stabilizing agents, stabilizing agent are sodium metasilicate.
260 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 100 ℃, adds chelating agent and stabilizing agent; Kept 70 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 30 minutes.
In the preparation process, mix liquid all the time, mixing speed is 50rpm.Use the pH regulator agent that the pH value is adjusted to 5.5.
Embodiment 8
Multi-functional experienced stain comprises following component according to parts by weight:
96 parts of solvents; Solvent is a butanediol.
86 parts of surfactant A; Surfactant A is selected from one or more in ethoxylated dodecyl alcohol, tridecanol polyoxyethylene ether, polyoxyethylene oleic acid ester and the polyoxyethylene stearic acid ester.
77 parts of surfactant B, surfactant B are trioctyl phosphate.
205 parts of chelating agents, chelating agent are citric acid.
162 parts of stabilizing agents; Stabilizing agent is selected from one or more in sodium metasilicate, sodium phosphate trimer, magnesium chloride and the tertiary sodium phosphate.
280 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 90 ℃, adds chelating agent and stabilizing agent; Kept 70 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 25 minutes.
In the preparation process, mix liquid all the time, mixing speed is 45rpm.Use the pH regulator agent that the pH value is adjusted to 6.
Embodiment 9
Multi-functional experienced stain comprises following component according to parts by weight:
105 parts of solvents, solvent are isopropyl alcohol.
95 parts of surfactant A, surfactant A are polyoxyethylene stearic acid ester.
83 parts of surfactant B, surfactant B are tributyl phosphate.
211 parts of chelating agents, chelating agent are gluconic acid sodium salt.
162 parts of stabilizing agents, stabilizing agent are sodium metasilicate.
270 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 90 ℃～110 ℃, adds chelating agent and stabilizing agent; Kept 50～70 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 30 minutes.
In the preparation process, mix liquid all the time, mixing speed is 50rpm.Use the pH regulator agent that the pH value is adjusted to 5.2.
Embodiment 10
Multi-functional experienced stain comprises following component according to parts by weight:
88 parts of solvents, solvent are isooctanol.
81 parts of surfactant A, surfactant A are ethoxylated dodecyl alcohol.
72 parts of surfactant B, surfactant B are laurate.
199 parts of chelating agents, chelating agent is selected from aminotriacetic acid.
190 parts of stabilizing agents, stabilizing agent is selected from sodium metasilicate.
280 parts in water.
The preparation method mixes water, solvent and surfactant A, is warming up to 95 ℃, adds chelating agent and stabilizing agent; Kept 50 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 25 minutes.
In the preparation process, mix liquid all the time, mixing speed is 45rpm.Use the pH regulator agent that the pH value is adjusted to 5.
Use the multi-functional experienced stain among the present invention, best method for using is in dip method, uses the experienced stain among the present invention to handle embryo cloth 20～40 minutes, the processing of dyeing then down at 50～70 ℃.During use, the consumption of practicing stain is 0.5-1g/L
Use the effect comparison such as the following table of prior art processing and product of the present invention:
Embodiment among the present invention only is used for that the present invention will be described, does not constitute the restriction to the claim scope, and other substituting of being equal in fact that those skilled in that art can expect are all in protection domain of the present invention.
Claims (5)
1. a multi-functional experienced stain is characterized in that, comprises following component according to parts by weight: 85～110 parts of solvents; 80～95 parts of surfactant A; 70～85 parts of surfactant B; 195～215 parts of chelating agents; 160～190 parts of stabilizing agents; 260～300 parts in water; Said solvent is selected from one or more in isooctanol, ethylene glycol, diethylene glycol, butyl cellosolve, ethylene glycol monobutyl ether, isopropyl alcohol and the butanediol; Surfactant A is selected from one or more in ethoxylated dodecyl alcohol, tridecanol polyoxyethylene ether, polyoxyethylene oleic acid ester and the polyoxyethylene stearic acid ester; Said surfactant B is selected from one or more in laurate, laruyl alcohol phosphate, trioctyl phosphate and the tributyl phosphate; Said chelating agent is selected from one or more in aminotriacetic acid, EDTA, HEDP, citric acid, gluconic acid sodium salt and the triethanolamine; Said stabilizing agent is selected from one or more in sodium metasilicate, sodium phosphate trimer, magnesium chloride and the tertiary sodium phosphate.
2. multi-functional experienced stain according to claim 1 is characterized in that, also comprises the pH regulator agent.
3. multi-functional experienced stain according to claim 2 is characterized in that said pH regulator agent is selected from one or more in formic acid, acetate, citric acid, malic acid, potassium hydroxide and the NaOH.
4. the preparation method of the described multi-functional experienced stain of the arbitrary claim of claim 1-3 is characterized in that, water, solvent and surfactant A are mixed, and is warming up to 90 ℃～110 ℃, adds chelating agent and stabilizing agent; Kept 50～70 minutes; Reduce to room temperature, add surfactant B and pH regulator agent, kept 25～40 minutes.
5. the preparation method of multi-functional experienced stain according to claim 4 is characterized in that, in the preparation process, mixes liquid all the time, and mixing speed is 45～60rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110026414 CN102154822B (en) | 2011-01-25 | 2011-01-25 | Multifunctional scouring and dyeing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110026414 CN102154822B (en) | 2011-01-25 | 2011-01-25 | Multifunctional scouring and dyeing agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102154822A CN102154822A (en) | 2011-08-17 |
| CN102154822B true CN102154822B (en) | 2012-12-12 |
Family
ID=44436481
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110026414 Expired - Fee Related CN102154822B (en) | 2011-01-25 | 2011-01-25 | Multifunctional scouring and dyeing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102154822B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103174019B (en) * | 2011-12-23 | 2015-11-25 | 广东德美精细化工股份有限公司 | A kind of scouringing and bleaching for polyester cotton to be dyeed with terylene component with bathing the multifunctional chemical system of processing |
| CN103174004B (en) * | 2011-12-23 | 2015-04-29 | 广东德美精细化工股份有限公司 | Multifunctional chemical system used for scouring and dyeing cotton knitted fabrics in one bath |
| CN102995468B (en) * | 2012-11-26 | 2015-04-15 | 浙江安诺其助剂有限公司 | Polyester fabric dyeing degreaser and preparation method thereof |
| CN108625169B (en) * | 2018-05-22 | 2020-10-27 | 杭州富强丝绸有限公司 | All-silk yarn-dyed warp knitting preparation process |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3943198B2 (en) * | 1997-07-24 | 2007-07-11 | ミヨシ油脂株式会社 | Textile scouring agent |
| CN101037842A (en) * | 2007-04-19 | 2007-09-19 | 上海祺瑞纺织化工有限公司 | Low-temperature scouring and bleaching agent and preparation method thereof and preprocessing technique |
| CN101418514A (en) * | 2008-11-26 | 2009-04-29 | 山东金鲁化工有限公司 | Five-in-one low-temperature quickly-smelting agent |
| CN101929064A (en) * | 2009-06-22 | 2010-12-29 | 上海雅运纺织助剂有限公司 | Scouring and bleaching agent combination and application thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002275759A (en) * | 2001-03-16 | 2002-09-25 | Kao Corp | Textile treating agent composition |
| JP2007297719A (en) * | 2006-04-27 | 2007-11-15 | Lion Corp | Liquid finishing agent composition for fiber product |
-
2011
- 2011-01-25 CN CN 201110026414 patent/CN102154822B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3943198B2 (en) * | 1997-07-24 | 2007-07-11 | ミヨシ油脂株式会社 | Textile scouring agent |
| CN101037842A (en) * | 2007-04-19 | 2007-09-19 | 上海祺瑞纺织化工有限公司 | Low-temperature scouring and bleaching agent and preparation method thereof and preprocessing technique |
| CN101418514A (en) * | 2008-11-26 | 2009-04-29 | 山东金鲁化工有限公司 | Five-in-one low-temperature quickly-smelting agent |
| CN101929064A (en) * | 2009-06-22 | 2010-12-29 | 上海雅运纺织助剂有限公司 | Scouring and bleaching agent combination and application thereof |
Non-Patent Citations (5)
| Title |
|---|
| JP特开2002-275759A 2002.09.25 |
| JP特开2007-297719A 2007.11.15 |
| JP特许第3943198号B2 2007.07.11 |
| 唐育民等.退、煮、漂三合一前处理剂TL的研制与应用.《染整技术》.2000,第22卷(第6期),第29-31页. * |
| 韦异等.高效低泡精练剂WH-1的研制.《广西工学院学报》.2002,第13卷(第1期),第60-63页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102154822A (en) | 2011-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104088169B (en) | A kind of natural dye dying method of containing cellulose fiber fabric | |
| CN103194917B (en) | Desizing-free polyacrylate emulsion slurry for one-step dyeing and weaving and preparation method thereof | |
| CN102392374B (en) | Anti-back-staining agent used in jeans enzyme washing | |
| CN102154822B (en) | Multifunctional scouring and dyeing agent and preparation method thereof | |
| CN108560241B (en) | Production process of single jeans | |
| CN101275350A (en) | Dyeing pretreatment process of woven fabric | |
| CN105155249B (en) | A kind of low temperature scouring agent, Its Preparation Method And Use | |
| CN102191698A (en) | Method for cleaning dyed terylene viscose blended fabric | |
| CN104894891A (en) | High-fastness natural dye printed product and preparation method thereof | |
| CN105648793A (en) | Print paste with high chlorine resistance as well as preparation method and application of print paste | |
| CN105220531A (en) | A kind of cold-rolling heap staining method of textile fabric | |
| CN103898775A (en) | Fabric cleaning, printing and dyeing process | |
| CN102619111B (en) | Method for dyeing conductive polyester fiber | |
| CN101509204A (en) | Novel dyeing and finishing process of chamois leather velvet fabric | |
| CN104947469A (en) | One-bath bleaching and dyeing treatment process for dyed polyester-cotton twill fabric | |
| CN104894889A (en) | Dyeing method of cotton type polyester staple fibers produced from PET bottom cut pieces | |
| CN113279270A (en) | Reactive dye, preparation method thereof and finished clothes | |
| CN101831772B (en) | Fabric finishing technique | |
| CN103174019B (en) | A kind of scouringing and bleaching for polyester cotton to be dyeed with terylene component with bathing the multifunctional chemical system of processing | |
| CN107740268A (en) | Mould proof smooth fluffy softening agent of a kind of fabric and preparation method thereof | |
| CN108642922B (en) | Pure cotton fabric dyeing and finishing processing method and application thereof | |
| CN115198540A (en) | Dyeing process adopting liquid dye | |
| CN112458668A (en) | Cleaning and finishing process of jean fabric | |
| CN111733588B (en) | Knitted fabric printing and dyeing pretreatment liquid, preparation method and knitted fabric dyeing process | |
| CN103643550A (en) | Dyeing method using crude salt as activated dye accelerating agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Lu Haiqian Inventor after: Cao Wanli Inventor after: Gu Zhian Inventor after: Lv Zhiyang Inventor before: Lu Haiqian Inventor before: Cao Wanli Inventor before: Gu Zhian |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LU HAIQIAN CAO WANLI GU ZHIAN TO: LU HAIQIAN CAO WANLI GU ZHIAN LV ZHIYANG |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121212 Termination date: 20170125 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |