CN107675530A - A kind of preparation method of woolen color fixing agent - Google Patents

A kind of preparation method of woolen color fixing agent Download PDF

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Publication number
CN107675530A
CN107675530A CN201710794432.8A CN201710794432A CN107675530A CN 107675530 A CN107675530 A CN 107675530A CN 201710794432 A CN201710794432 A CN 201710794432A CN 107675530 A CN107675530 A CN 107675530A
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China
Prior art keywords
parts
fixing agent
color fixing
woolen
revs
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CN201710794432.8A
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Inventor
储平
徐有琦
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Jiangsu New Lucky Polytron Technologies Inc
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Jiangsu New Lucky Polytron Technologies Inc
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Priority to CN201710794432.8A priority Critical patent/CN107675530A/en
Publication of CN107675530A publication Critical patent/CN107675530A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65118—Compounds containing hydroxyl groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65125—Compounds containing ester groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651—Compounds without nitrogen
    • D06P1/65106—Oxygen-containing compounds
    • D06P1/65131—Compounds containing ether or acetal groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/14—Wool

Abstract

The invention discloses a kind of preparation method of woolen color fixing agent, the woolen color fixing agent is made up of the raw material of following parts by weight：20 30 parts of diethylenetriamine, 10 20 parts of epoxychloropropane, 20 30 parts of hydroquinones, 5 10 parts of ethyl acetate, 10 20 parts of butyl acrylate, 5 10 parts of acryloyl chloride, 35 parts of octadecyl dimethyl amine oxide, 46 parts of dimethylamine, 46 parts of dicyandiamide, 5 10 parts of coumaric acid, 10 20 parts of sodium hydroxide, 40 50 parts of ethanol, 30 40 parts of deionized water.After the woolen color fixing agent application of the present invention, the soaping fastness after textile dyeing can reach 45 grades, and fastness to rubbing reaches 45 grades, and sunlight fastness can reach 34 grades.The woolen color fixing agent of the present invention, manufacturing process is simple to operation, and low in raw material price easily obtains, and volatility is low.

Description

A kind of preparation method of woolen color fixing agent
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relates to a kind of woolen color fixing agent.
Background technology
Color fixing agent is one of important auxiliary agent in dyeing, and it is that one kind can improve dyestuff color moisture-proof on fabric The auxiliary agent used in fastness is handled, it can form insoluble colored substance with dyestuff on fabric and improve the washing of color, sweat stain Fastness, its light fastness can be also improved sometimes.
The color fixing agent that wool fabric uses at present, it is very undesirable to colour fixation woolen after dyeing, and to the color of fabric Light has a great influence, and has the generation of free formaldehyde in building-up process.
The content of the invention
It is an object of the invention to provide a kind of woolen color fixing agent and preparation method, to solve to carry in above-mentioned background technology The problem of going out.
To achieve the above object, the present invention provides following technical scheme：
A kind of woolen color fixing agent, according to parts by weight, including following components：Diethylenetriamine 20-30 parts, epoxy chloropropionate Alkane 10-20 parts, hydroquinones 20-30 parts, ethyl acetate 5-10 parts, butyl acrylate 10-20 parts, acryloyl chloride 5-10 parts, ten Eight alkyl dimethyl amine oxide 3-5 parts, dimethylamine 4-6 parts, dicyandiamide 4-6 parts, coumaric acid 5-10 parts, sodium hydroxide 10-20 parts, Ethanol 40-50 parts, deionized water 30-40 parts.
Preferably, the ethanol in described woolen color fixing agent is absolute ethyl alcohol, and purity is pure to analyze.
Preferably, described woolen color fixing agent, according to parts by weight, including following components：20 parts of diethylenetriamine, ring 10 parts of oxygen chloropropane, 20 parts of hydroquinones, 5 parts of ethyl acetate, 10 parts of butyl acrylate, 5 parts of acryloyl chloride, hexadecyldimethylamine 3 parts of base amine oxide, 4 parts of dimethylamine, 4 parts of dicyandiamide, 5 parts of coumaric acid, 10 parts of sodium hydroxide, 40 parts of ethanol, 30 parts of deionized water.
Preferably, described woolen color fixing agent, according to parts by weight, including following components：25 parts of diethylenetriamine, ring 15 parts of oxygen chloropropane, 25 parts of hydroquinones, 8 parts of ethyl acetate, 15 parts of butyl acrylate, 8 parts of acryloyl chloride, hexadecyldimethylamine 4 parts of base amine oxide, 5 parts of dimethylamine, 5 parts of dicyandiamide, 8 parts of coumaric acid, 15 parts of sodium hydroxide, 45 parts of ethanol, 35 parts of deionized water.
Preferably, described woolen color fixing agent, according to parts by weight, including following components：30 parts of diethylenetriamine, ring 20 parts of oxygen chloropropane, 30 parts of hydroquinones, 10 parts of ethyl acetate, 20 parts of butyl acrylate, 10 parts of acryloyl chloride, octadecyl two 5 parts of methyl oxidation amine, 6 parts of dimethylamine, 6 parts of dicyandiamide, 10 parts of coumaric acid, 20 parts of sodium hydroxide, 50 parts of ethanol, deionized water 40 Part.
Preferably, the preparation method of described a kind of woolen color fixing agent, is comprised the following steps that：
(1) diethylenetriamine 20-30 parts, sodium hydroxide 10-20 parts, epoxychloropropane 10- are added inside three-necked flask 20 parts, hydroquinones 20-30 parts, in 60-70 DEG C of heating of oil bath pan, nitrogen are passed through flatly, the speed for being passed through nitrogen is the 5-7 seconds one Individual bubble, charging being kept flatly, inserting agitator flatly, mixing speed is 500-1000 revs/min, reaction time 3-4h；
(2) first deionized water 30-40 parts, dimethylamine 4-6 parts, dicyandiamide 4-6 parts with ultrasonic disperse 10-20 minutes, are obtained To homogeneous solution；
(3) homogeneous solution of step (2) is added in the solution of step (1), 500-1000 revs/min, 20-30 points of stirring Clock；
(4) temperature is raised to 70-80 DEG C, adds butyl acrylate 10-20 parts, acryloyl chloride 5-10 parts, octadecyl two Methyl oxidation amine 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；
(5) 40-50 DEG C is cooled to, ethyl acetate 5-10 parts, coumaric acid 5-10 parts is added, 500-1000 revs/min, stirs 1-2 hours；
(6) 20-30 DEG C is cooled to, ethanol 40-50 parts is added, 500-1000 revs/min, stirs 1-2 hours；
(7) stirring is closed down, the liquid wool fabric color fixing agent prepared；
(8) stand and be cooled in three-necked flask liquid wool fabric color fixing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Compared with prior art, the beneficial effects of the invention are as follows：
1st, after woolen color fixing agent of the invention application, woolen washing fastness reaches 4-5 levels, fastness to rubbing Reach 4-5 levels, sunlight fastness reaches more than 3-4 levels.
2nd, woolen color fixing agent manufacturing process of the invention is simple to operation, and low in raw material price easily obtains, and volatility is low.
3rd, mutual compatibility, synergy between various raw materials used in woolen color fixing agent of the invention, collectively constitute performance Excellent product.
4th, the addition of epoxychloropropane, the fixing property of woolen color fixing agent is improved.
5th, technique is simplified, safe operation is simple, is easy to industrialized production.
6th, woolen color fixing agent of the invention is efficient, does not produce formaldehyde.
7th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of woolen color fixing agent, according to parts by weight, including following components：Diethylenetriamine 20- 30 parts, epoxychloropropane 10-20 parts, hydroquinones 20-30 parts, ethyl acetate 5-10 parts, butyl acrylate 10-20 parts, propylene Acyl chlorides 5-10 parts, octadecyl dimethyl amine oxide 3-5 parts, dimethylamine 4-6 parts, dicyandiamide 4-6 parts, coumaric acid 5-10 parts, hydrogen Sodium oxide molybdena 10-20 parts, ethanol 40-50 parts, deionized water 30-40 parts.
Present invention also offers a kind of preparation method of woolen color fixing agent, comprise the following steps that：
(1) diethylenetriamine 20-30 parts, sodium hydroxide 10-20 parts, epoxychloropropane 10- are added inside three-necked flask 20 parts, hydroquinones 20-30 parts, in 60-70 DEG C of heating of oil bath pan, nitrogen are passed through flatly, the speed for being passed through nitrogen is the 5-7 seconds one Individual bubble, charging being kept flatly, inserting agitator flatly, mixing speed is 500-1000 revs/min, reaction time 3-4h；
(2) first deionized water 30-40 parts, dimethylamine 4-6 parts, dicyandiamide 4-6 parts with ultrasonic disperse 10-20 minutes, are obtained To homogeneous solution；
(3) homogeneous solution of step (2) is added in the solution of step (1), 500-1000 revs/min, 20-30 points of stirring Clock；
(4) temperature is raised to 70-80 DEG C, adds butyl acrylate 10-20 parts, acryloyl chloride 5-10 parts, octadecyl two Methyl oxidation amine 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；
(5) 40-50 DEG C is cooled to, ethyl acetate 5-10 parts, coumaric acid 5-10 parts is added, 500-1000 revs/min, stirs 1-2 hours；
(6) 20-30 DEG C is cooled to, ethanol 40-50 parts is added, 500-1000 revs/min, stirs 1-2 hours；
(7) stirring is closed down, the liquid wool fabric color fixing agent prepared；
(8) stand and be cooled in three-necked flask liquid wool fabric color fixing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 1
The invention discloses a kind of woolen color fixing agent, according to parts by weight, including following components：Diethylenetriamine 20 Part, 10 parts of epoxychloropropane, 20 parts of hydroquinones, 5 parts of ethyl acetate, 10 parts of butyl acrylate, 5 parts of acryloyl chloride, octadecane 3 parts of base dimethyl amine, 4 parts of dimethylamine, 4 parts of dicyandiamide, 5 parts of coumaric acid, 10 parts of sodium hydroxide, 40 parts of ethanol, deionization 30 parts of water.
Present invention also offers a kind of preparation method of woolen color fixing agent, comprise the following steps that：
(1) inside three-necked flask add 20 parts of diethylenetriamine, 10 parts of sodium hydroxide, 10 parts of epoxychloropropane, to benzene 20 parts of diphenol, in 60 DEG C of heating of oil bath pan, nitrogen is passed through flatly, the speed for being passed through nitrogen is 5 seconds bubbles, keeps add flatly Material, agitator is inserted flatly, mixing speed is 500 revs/min, reaction time 3h；
(2) first by 30 parts of deionized water, 4 parts of dimethylamine, 4 parts of dicyandiamide, with ultrasonic disperse 10 minutes, obtain uniformly molten Liquid；
(3) homogeneous solution of step (2) is added in the solution of step (1), 500 revs/min, stirred 20 minutes；
(4) temperature is raised to 70 DEG C, adds 10 parts of butyl acrylate, 5 parts of acryloyl chloride, octadecyl dimethyl amine oxide 3 parts, 500 revs/min, stir 20 minutes；
(5) 40 DEG C are cooled to, 5 parts of ethyl acetate, 5 parts of coumaric acid is added, 500 revs/min, stirs 1 hour；
(6) 20 DEG C are cooled to, 40 parts of ethanol is added, 500 revs/min, stirs 2 hours；
(7) stirring is closed down, the liquid wool fabric color fixing agent prepared；
(8) stand and be cooled in three-necked flask liquid wool fabric color fixing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 2
The invention discloses a kind of woolen color fixing agent, according to parts by weight, including following components：Diethylenetriamine 25 Part, 15 parts of epoxychloropropane, 25 parts of hydroquinones, 8 parts of ethyl acetate, 15 parts of butyl acrylate, 8 parts of acryloyl chloride, octadecane 4 parts of base dimethyl amine, 5 parts of dimethylamine, 5 parts of dicyandiamide, 8 parts of coumaric acid, 15 parts of sodium hydroxide, 45 parts of ethanol, deionization 35 parts of water.
Present invention also offers a kind of preparation method of woolen color fixing agent, comprise the following steps that：
(1) inside three-necked flask add 25 parts of diethylenetriamine, 15 parts of sodium hydroxide, 15 parts of epoxychloropropane, to benzene 25 parts of diphenol, in 65 DEG C of heating of oil bath pan, nitrogen is passed through flatly, the speed for being passed through nitrogen is 5 seconds bubbles, keeps add flatly Material, agitator is inserted flatly, mixing speed is 800 revs/min, reaction time 3.5h；
(2) first by 35 parts of deionized water, 5 parts of dimethylamine, 5 parts of dicyandiamide, with ultrasonic disperse 15 minutes, obtain uniformly molten Liquid；
(3) homogeneous solution of step (2) is added in the solution of step (1), 800 revs/min, stirred 25 minutes；
(4) temperature is raised to 75 DEG C, adds 15 parts of butyl acrylate, 8 parts of acryloyl chloride, octadecyl dimethyl amine oxide 4 parts, 800 revs/min, stir 25 minutes；
(5) 45 DEG C are cooled to, 8 parts of ethyl acetate, 8 parts of coumaric acid is added, 800 revs/min, stirs 1 hour；
(6) 25 DEG C are cooled to, 45 parts of ethanol is added, 800 revs/min, stirs 2 hours；
(7) stirring is closed down, the liquid wool fabric color fixing agent prepared；
(8) stand and be cooled in three-necked flask liquid wool fabric color fixing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 3
The invention discloses a kind of woolen color fixing agent, according to parts by weight, including following components：Diethylenetriamine 30 Part, 20 parts of epoxychloropropane, 30 parts of hydroquinones, 10 parts of ethyl acetate, 20 parts of butyl acrylate, 10 parts of acryloyl chloride, 18 5 parts of alkyl dimethyl amine oxide, 6 parts of dimethylamine, 6 parts of dicyandiamide, 10 parts of coumaric acid, 20 parts of sodium hydroxide, 50 parts of ethanol, go from Sub- 40 parts of water.
Present invention also offers a kind of preparation method of woolen color fixing agent, comprise the following steps that：
(1) inside three-necked flask add 30 parts of diethylenetriamine, 20 parts of sodium hydroxide, 20 parts of epoxychloropropane, to benzene 30 parts of diphenol, in 70 DEG C of heating of oil bath pan, nitrogen is passed through flatly, the speed for being passed through nitrogen is 7 seconds bubbles, keeps add flatly Material, agitator is inserted flatly, mixing speed is 1000 revs/min, reaction time 4h；
(2) first by 40 parts of deionized water, 6 parts of dimethylamine, 6 parts of dicyandiamide, with ultrasonic disperse 20 minutes, obtain uniformly molten Liquid；
(3) homogeneous solution of step (2) is added in the solution of step (1), 1000 revs/min, stirred 30 minutes；
(4) temperature is raised to 80 DEG C, adds 20 parts of butyl acrylate, 10 parts of acryloyl chloride, octadecyldimethyl oxidation 5 parts of amine, 1000 revs/min, stir 30 minutes；
(5) 50 DEG C are cooled to, 10 parts of ethyl acetate, 10 parts of coumaric acid is added, 1000 revs/min, stirs 2 hours；
(6) 30 DEG C are cooled to, 50 parts of ethanol is added, 1000 revs/min, stirs 2 hours；
(7) stirring is closed down, the liquid wool fabric color fixing agent prepared；
(8) stand and be cooled in three-necked flask liquid wool fabric color fixing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 4
The invention discloses a kind of woolen color fixing agent, according to parts by weight, including following components：Diethylenetriamine 20 Part, 10 parts of epoxychloropropane, 20 parts of hydroquinones, 5 parts of ethyl acetate, 20 parts of butyl acrylate, 10 parts of acryloyl chloride, octadecane 5 parts of base dimethyl amine, 5 parts of dimethylamine, 5 parts of dicyandiamide, 10 parts of coumaric acid, 15 parts of sodium hydroxide, 40 parts of ethanol, deionization 30 parts of water.
Present invention also offers a kind of preparation method of woolen color fixing agent, comprise the following steps that：
(1) inside three-necked flask add 20 parts of diethylenetriamine, 15 parts of sodium hydroxide, 10 parts of epoxychloropropane, to benzene 20 parts of diphenol, in 60 DEG C of heating of oil bath pan, nitrogen is passed through flatly, the speed for being passed through nitrogen is 5 seconds bubbles, keeps add flatly Material, agitator is inserted flatly, mixing speed is 1000 revs/min, reaction time 4h；
(2) first by 30 parts of deionized water, 5 parts of dimethylamine, 5 parts of dicyandiamide, with ultrasonic disperse 10 minutes, obtain uniformly molten Liquid；
(3) homogeneous solution of step (2) is added in the solution of step (1), 900 revs/min, stirred 25 minutes；
(4) temperature is raised to 75 DEG C, adds 20 parts of butyl acrylate, 10 parts of acryloyl chloride, octadecyldimethyl oxidation 5 parts of amine, 1000 revs/min, stir 25 minutes；
(5) 40 DEG C are cooled to, 5 parts of ethyl acetate, 10 parts of coumaric acid is added, 800 revs/min, stirs 1 hour；
(6) 25 DEG C are cooled to, 40 parts of ethanol is added, 800 revs/min, stirs 1.5 hours；
(7) stirring is closed down, the liquid wool fabric color fixing agent prepared；
(8) stand and be cooled in three-necked flask liquid wool fabric color fixing agent and be less than 20 DEG C, blowing encapsulation, finished product.
Test case
The wool fabric of four pieces of formed objects uses acid dyeing, and the color fixing agent that embodiment 1,2,3,4 is respectively adopted enters Row fixation treatment, test dyefastness result are as follows：
Embodiment Fastness to washing Fastness to rubbing Sunlight fastness
1 4 4 3
2 4-5 4-5 3-4
3 5 5 4-5
4 4-5 4-5 4
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

  1. A kind of 1. woolen color fixing agent, it is characterised in that：The woolen color fixing agent includes the raw material of following parts by weight：Diethyl Alkene triamine 20-30 parts, epoxychloropropane 10-20 parts, hydroquinones 20-30 parts, ethyl acetate 5-10 parts, butyl acrylate 10- 20 parts, acryloyl chloride 5-10 parts, octadecyl dimethyl amine oxide 3-5 parts, dimethylamine 4-6 parts, dicyandiamide 4-6 parts, coumaric acid 5-10 parts, sodium hydroxide 10-20 parts, ethanol 40-50 parts, deionized water 30-40 parts.
  2. 2. woolen color fixing agent according to claim 1, it is characterised in that：The ethanol is absolute ethyl alcohol, and purity is point Analyse pure.
  3. A kind of 3. woolen color fixing agent according to claim 1, it is characterised in that：According to parts by weight, including with the following group Point：20 parts of diethylenetriamine, 10 parts of epoxychloropropane, 20 parts of hydroquinones, 5 parts of ethyl acetate, 10 parts of butyl acrylate, propylene 5 parts of acyl chlorides, 3 parts of octadecyl dimethyl amine oxide, 4 parts of dimethylamine, 4 parts of dicyandiamide, 5 parts of coumaric acid, 10 parts of sodium hydroxide, second 40 parts of alcohol, 30 parts of deionized water.
  4. A kind of 4. woolen color fixing agent according to claim 1, it is characterised in that：According to parts by weight, including with the following group Point：25 parts of diethylenetriamine, 15 parts of epoxychloropropane, 25 parts of hydroquinones, 8 parts of ethyl acetate, 15 parts of butyl acrylate, propylene 8 parts of acyl chlorides, 4 parts of octadecyl dimethyl amine oxide, 5 parts of dimethylamine, 5 parts of dicyandiamide, 8 parts of coumaric acid, 15 parts of sodium hydroxide, second 45 parts of alcohol, 35 parts of deionized water.
  5. A kind of 5. woolen color fixing agent according to claim 1, it is characterised in that：According to parts by weight, including with the following group Point：30 parts of diethylenetriamine, 20 parts of epoxychloropropane, 20 parts of hydroquinones, 10 parts of ethyl acetate, 20 parts of butyl acrylate, third 10 parts of alkene acyl chlorides, 5 parts of octadecyl dimethyl amine oxide, 6 parts of dimethylamine, 6 parts of dicyandiamide, 10 parts of coumaric acid, sodium hydroxide 20 Part, 50 parts of ethanol, 40 parts of deionized water.
  6. 6. a kind of preparation method of any described woolen color fixing agent, its feature exist in a kind of 1-5 using the claims In：Comprise the following steps that：
    Step 1, diethylenetriamine 20-30 parts, sodium hydroxide 10-20 parts, epoxychloropropane 10-20 are added inside three-necked flask Part, hydroquinones 20-30 parts, in 60-70 DEG C of heating of oil bath pan, nitrogen are passed through flatly, the speed for being passed through nitrogen is the 5-7 seconds one Bubble, charging being kept flatly, inserting agitator flatly, mixing speed is 500-1000 revs/min, reaction time 3-4h；
    Step 2, first deionized water 30-40 parts, dimethylamine 4-6 parts, dicyandiamide 4-6 parts with ultrasonic disperse 10-20 minutes, are obtained To homogeneous solution；
    Step 3, the homogeneous solution of step 2 is added in the solution of step 1,500-1000 revs/min, stirs 20-30 minutes；
    Step 4, temperature is raised to 70-80 DEG C, adds butyl acrylate 10-20 parts, acryloyl chloride 5-10 parts, hexadecyldimethylamine Base amine oxide 3-5 parts, 500-1000 revs/min, stir 20-30 minutes；
    Step 5,40-50 DEG C is cooled to, ethyl acetate 5-10 parts, coumaric acid 5-10 parts is added, 500-1000 revs/min, stirs 1-2 hours；
    Step 6,20-30 DEG C is cooled to, ethanol 40-50 parts is added, 500-1000 revs/min, stirs 1-2 hours；
    Step 7, stirring is closed down, the liquid wool fabric color fixing agent prepared；
    Step 8, stand and be cooled in three-necked flask liquid wool fabric color fixing agent and be less than 20 DEG C, blowing encapsulation, finished product.
CN201710794432.8A 2017-09-06 2017-09-06 A kind of preparation method of woolen color fixing agent Pending CN107675530A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112981990A (en) * 2021-03-04 2021-06-18 吉安迅达科技有限公司 Color fixing agent and preparation process thereof
CN116536944A (en) * 2023-04-17 2023-08-04 江西德盛精细化学品有限公司 Sun-proof color fixing agent and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103614934A (en) * 2013-12-02 2014-03-05 湖州金塔地纺织厂 Fabric color fixing agent
CN104562804A (en) * 2015-01-22 2015-04-29 南通优尼科化工有限公司 Dye color fixing agent
CN106676912A (en) * 2016-12-05 2017-05-17 钦州市钦南区生产力促进中心 Color fixing agent for fabric and preparation method thereof
CN106758371B (en) * 2016-11-14 2019-03-22 苏州联胜化学有限公司 Panchromatic system's formaldehyde-free color fixing agent for reactive dyes and preparation method thereof, application method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103614934A (en) * 2013-12-02 2014-03-05 湖州金塔地纺织厂 Fabric color fixing agent
CN104562804A (en) * 2015-01-22 2015-04-29 南通优尼科化工有限公司 Dye color fixing agent
CN106758371B (en) * 2016-11-14 2019-03-22 苏州联胜化学有限公司 Panchromatic system's formaldehyde-free color fixing agent for reactive dyes and preparation method thereof, application method
CN106676912A (en) * 2016-12-05 2017-05-17 钦州市钦南区生产力促进中心 Color fixing agent for fabric and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112981990A (en) * 2021-03-04 2021-06-18 吉安迅达科技有限公司 Color fixing agent and preparation process thereof
CN116536944A (en) * 2023-04-17 2023-08-04 江西德盛精细化学品有限公司 Sun-proof color fixing agent and preparation method thereof

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Application publication date: 20180209