CN107805941A - A kind of low-foaming penetrating agent and preparation method thereof - Google Patents

A kind of low-foaming penetrating agent and preparation method thereof Download PDF

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Publication number
CN107805941A
CN107805941A CN201710983299.0A CN201710983299A CN107805941A CN 107805941 A CN107805941 A CN 107805941A CN 201710983299 A CN201710983299 A CN 201710983299A CN 107805941 A CN107805941 A CN 107805941A
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CN
China
Prior art keywords
parts
low
penetrating agent
sodium
foaming penetrating
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Pending
Application number
CN201710983299.0A
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Chinese (zh)
Inventor
储平
徐有琦
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Jiangsu New Lucky Polytron Technologies Inc
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Jiangsu New Lucky Polytron Technologies Inc
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Priority to CN201710983299.0A priority Critical patent/CN107805941A/en
Publication of CN107805941A publication Critical patent/CN107805941A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/07Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
    • D06M11/11Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
    • D06M11/155Halides of elements of Groups 2 or 12 of the Periodic System
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/144Alcohols; Metal alcoholates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/207Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46Compounds containing quaternary nitrogen atoms
    • D06M13/463Compounds containing quaternary nitrogen atoms derived from monoamines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • D06M15/09Cellulose ethers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain

Abstract

The invention discloses a kind of low-foaming penetrating agent and preparation method thereof, the low-foaming penetrating agent is made up of the raw material of following parts by weight:10 20 parts of SAS, 35 parts of fatty alcohol, 10 15 parts of dioctyl sodium sulfosuccinate, 57 parts of dimethicone, 57 parts of sodium cellulose glycolate, 35 parts of calcium chloride, 37 parts of lauroylamidopropyl betaine, 35 parts of sodium citrate, 30 40 parts of deionized water.The low-foaming penetrating agent manufacturing process of the present invention is simple to operation, and low in raw material price is easily obtained, and nontoxic, and volatility is low, and human body is not stimulated, and penetration is strong, conflicts with other auxiliary agents while using not producing.

Description

A kind of low-foaming penetrating agent and preparation method thereof
Technical field
The invention belongs to technical field of textile auxiliary agent, specifically relates to a kind of low-foaming penetrating agent and preparation method thereof.
Background technology
Bleeding agent has been as its name suggests osmosis, and with fixed hydrophilic lipophilic group, in the surface energy of solution Align, and the material that can be remarkably decreased surface tension.
In dyeing and finishing process, in order that the material such as dyestuff is quickly penetrated into fabric and gone, it is necessary to add bleeding agent. It is poor with other auxiliary agent interworking effects but existing bleeding agent fastness to alkali is not high, capillary effect is poor, bubble is serious, have during high-temperature boiling White powder point produces, so as to influence using effect.Some bleeding agents also contain APEO, not easily biological-degradable, are unfavorable for environmental protection.
The content of the invention
It is an object of the invention to provide a kind of low-foaming penetrating agent and preparation method thereof, to solve to carry in above-mentioned background technology The problem of going out.
To achieve the above object, the present invention provides following technical scheme:
A kind of low-foaming penetrating agent, according to important number, including following components:SAS 10-20 parts, fatty alcohol 3- 5 parts, dioctyl sodium sulfosuccinate 10-15 parts, dimethicone 5-7 parts, sodium cellulose glycolate 5-7 parts, calcium chloride 3-5 Part, lauroylamidopropyl betaine 3-7 parts, sodium citrate 3-5 parts, deionized water 30-40 parts.
Preferably, described low-foaming penetrating agent, according to parts by weight, including following components:10 parts of SAS, fat 3 parts of fat alcohol, 10 parts of dioctyl sodium sulfosuccinate, 5 parts of dimethicone, 5 parts of sodium cellulose glycolate, 3 parts of calcium chloride, bay 3 parts of amido propyl betaine, 3 parts of sodium citrate, 30 parts of deionized water.
Preferably, described low-foaming penetrating agent, according to parts by weight, including following components:15 parts of SAS, fat 4 parts of fat alcohol, 13 parts of dioctyl sodium sulfosuccinate, 6 parts of dimethicone, 6 parts of sodium cellulose glycolate, 4 parts of calcium chloride, bay 5 parts of amido propyl betaine, 4 parts of sodium citrate, 35 parts of deionized water.
Preferably, described low-foaming penetrating agent, according to parts by weight, including following components:20 parts of SAS, fat 5 parts of fat alcohol, 15 parts of dioctyl sodium sulfosuccinate, 7 parts of dimethicone, 7 parts of sodium cellulose glycolate, 5 parts of calcium chloride, bay 7 parts of amido propyl betaine, 5 parts of sodium citrate, 40 parts of deionized water.
A kind of preparation method of low-foaming penetrating agent, is comprised the following steps that:
Step 1, deionized water 30-40 parts are added in a kettle, and rise temperature is to 50-60 DEG C;
Step 2, add SAS 10-20 parts, fatty alcohol 3-5 parts, dioctyl sodium sulfosuccinate 10-15 parts, Dimethicone 5-7 parts, 500-1000 revs/min, stir 10-20 minutes;
Step 3,30-40 DEG C is cooled to, adds sodium cellulose glycolate 5-7 parts, lauroylamidopropyl betaine 3-7 parts, 500-1000 revs/min, stir 20-30 minutes;
Step 4,20-30 DEG C is cooled to, calcium chloride 3-5 parts, sodium citrate 3-5 parts is added, 500-1000 revs/min, stirs Mix 20-30 minutes;
Step 5, stirring is closed down, the liquid low-foaming penetrating agent prepared;
Step 6, stand and be cooled in stirred tank liquid low-foaming penetrating agent and be less than 20 DEG C, blowing encapsulation, finished product.
Compared with prior art, the beneficial effects of the invention are as follows:
1st, low-foaming penetrating agent manufacturing process of the invention is simple to operation, and low in raw material price easily obtains, and nontoxic, Volatility is low, and human body is not stimulated.
2nd, mutual compatibility, synergy between various raw materials used in low-foaming penetrating agent of the invention, it is excellent to collectively constitute performance Different product.
3rd, low-foaming penetrating agent of the invention does not produce poisonous gas or solid matter in application process.
4th, low-foaming penetrating agent penetration of the invention is strong, conflicts with other auxiliary agents while using not producing.
5th, low-foaming penetrating agent of the invention has excellent low bubble, suds function.
6th, technique is simplified, safe operation is simple, is easy to industrialized production.
7th, use of the invention can receive good economic benefit.
Example is embodied
The invention discloses a kind of low-foaming penetrating agent, according to important number, including following components:SAS 10- 20 parts, fatty alcohol 3-5 parts, dioctyl sodium sulfosuccinate 10-15 parts, dimethicone 5-7 parts, sodium cellulose glycolate 5-7 Part, calcium chloride 3-5 parts, lauroylamidopropyl betaine 3-7 parts, sodium citrate 3-5 parts, deionized water 30-40 parts.
Present invention also offers a kind of preparation method of low-foaming penetrating agent, comprise the following steps that:
Step 1, deionized water 30-40 parts are added in a kettle, and rise temperature is to 50-60 DEG C;
Step 2, add SAS 10-20 parts, fatty alcohol 3-5 parts, dioctyl sodium sulfosuccinate 10-15 parts, Dimethicone 5-7 parts, 500-1000 revs/min, stir 10-20 minutes;
Step 3,30-40 DEG C is cooled to, adds sodium cellulose glycolate 5-7 parts, lauroylamidopropyl betaine 3-7 parts, 500-1000 revs/min, stir 20-30 minutes;
Step 4,20-30 DEG C is cooled to, calcium chloride 3-5 parts, sodium citrate 3-5 parts is added, 500-1000 revs/min, stirs Mix 20-30 minutes;
Step 5, stirring is closed down, the liquid low-foaming penetrating agent prepared;
Step 6, stand and be cooled in stirred tank liquid low-foaming penetrating agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 1
The invention discloses a kind of low-foaming penetrating agent, according to important number, including following components:SAS 10 Part, 3 parts of fatty alcohol, 10 parts of dioctyl sodium sulfosuccinate, 5 parts of dimethicone, 5 parts of sodium cellulose glycolate, calcium chloride 3 Part, 3 parts of lauroylamidopropyl betaine, 3 parts of sodium citrate, 30 parts of deionized water.
Present invention also offers a kind of preparation method of low-foaming penetrating agent, comprise the following steps that:
Step 1,30 parts of deionized water is added in a kettle, and rise temperature is to 50 DEG C;
Step 2,10 parts of SAS, 3 parts of fatty alcohol, 10 parts of dioctyl sodium sulfosuccinate, dimethyl-silicon are added 5 parts of oil, 500 revs/min, stir 20 minutes;
Step 3, it is cooled to 30 DEG C, adds 5 parts of sodium cellulose glycolate, 3 parts of lauroylamidopropyl betaine, 500 revs/min Clock, stir 20 minutes;
Step 4,20 DEG C are cooled to, 3 parts of calcium chloride, 3 parts of sodium citrate is added, 500 revs/min, stirs 20 minutes;
Step 5, stirring is closed down, the liquid low-foaming penetrating agent prepared;
Step 6, stand and be cooled in stirred tank liquid low-foaming penetrating agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 2
The invention discloses a kind of low-foaming penetrating agent, according to important number, including following components:SAS 15 Part, 4 parts of fatty alcohol, 13 parts of dioctyl sodium sulfosuccinate, 6 parts of dimethicone, 6 parts of sodium cellulose glycolate, calcium chloride 4 Part, 5 parts of lauroylamidopropyl betaine, 4 parts of sodium citrate, 35 parts of deionized water.
Present invention also offers a kind of preparation method of low-foaming penetrating agent, comprise the following steps that:
Step 1,35 parts of deionized water is added in a kettle, and rise temperature is to 55 DEG C;
Step 2,15 parts of SAS, 4 parts of fatty alcohol, 13 parts of dioctyl sodium sulfosuccinate, dimethyl-silicon are added 6 parts of oil, 900 revs/min, stir 15 minutes;
Step 3, it is cooled to 35 DEG C, adds 6 parts of sodium cellulose glycolate, 5 parts of lauroylamidopropyl betaine, 900 revs/min Clock, stir 25 minutes;
Step 4,25 DEG C are cooled to, 4 parts of calcium chloride, 4 parts of sodium citrate is added, 900 revs/min, stirs 25 minutes;
Step 5, stirring is closed down, the liquid low-foaming penetrating agent prepared;
Step 6, stand and be cooled in stirred tank liquid low-foaming penetrating agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 3
The invention discloses a kind of low-foaming penetrating agent, according to important number, including following components:SAS 20 Part, 5 parts of fatty alcohol, 15 parts of dioctyl sodium sulfosuccinate, 7 parts of dimethicone, 7 parts of sodium cellulose glycolate, calcium chloride 5 Part, 7 parts of lauroylamidopropyl betaine, 5 parts of sodium citrate, 40 parts of deionized water.
Present invention also offers a kind of preparation method of low-foaming penetrating agent, comprise the following steps that:
Step 1,40 parts of deionized water is added in a kettle, and rise temperature is to 60 DEG C;
Step 2,20 parts of SAS, 5 parts of fatty alcohol, 15 parts of dioctyl sodium sulfosuccinate, dimethyl-silicon are added 7 parts of oil, 1000 revs/min, stir 10 minutes;
Step 3, it is cooled to 40 DEG C, adds 7 parts of sodium cellulose glycolate, 7 parts of lauroylamidopropyl betaine, 1000 turns/ Minute, stir 30 minutes;
Step 4,30 DEG C are cooled to, 5 parts of calcium chloride, 5 parts of sodium citrate is added, 1000 revs/min, stirs 30 minutes;
Step 5, stirring is closed down, the liquid low-foaming penetrating agent prepared;
Step 6, stand and be cooled in stirred tank liquid low-foaming penetrating agent and be less than 20 DEG C, blowing encapsulation, finished product.
Embodiment 4
The invention discloses a kind of low-foaming penetrating agent, according to important number, including following components:SAS 20 Part, 4 parts of fatty alcohol, 15 parts of dioctyl sodium sulfosuccinate, 7 parts of dimethicone, 7 parts of sodium cellulose glycolate, calcium chloride 3 Part, 5 parts of lauroylamidopropyl betaine, 4 parts of sodium citrate, 30 parts of deionized water.
Present invention also offers a kind of preparation method of low-foaming penetrating agent, comprise the following steps that:
Step 1,30 parts of deionized water is added in a kettle, and rise temperature is to 60 DEG C;
Step 2,20 parts of SAS, 4 parts of fatty alcohol, 15 parts of dioctyl sodium sulfosuccinate, dimethyl-silicon are added 7 parts of oil, 1000 revs/min, stir 10 minutes;
Step 3, it is cooled to 30 DEG C, adds 7 parts of sodium cellulose glycolate, 5 parts of lauroylamidopropyl betaine, 900 revs/min Clock, stir 20 minutes;
Step 4,20 DEG C are cooled to, 3 parts of calcium chloride, 4 parts of sodium citrate is added, 1000 revs/min, stirs 20 minutes;
Step 5, stirring is closed down, the liquid low-foaming penetrating agent prepared;
Step 6, stand and be cooled in stirred tank liquid low-foaming penetrating agent and be less than 20 DEG C, blowing encapsulation, finished product.
Test case:
The bleeding agent of embodiment 1,2,3,4 is carried out to alkali resistance (naoh concentration 50g/L), sedimentation time survey Examination, test result are as follows:
Embodiment Alkali resistance Sedimentation time (s)
1 Compared with clarification, foam has a bit 14.3
2 Clarification, foam are few 12.2
3 Clarification, basic non-foam 10.4
4 Clarification, foam are few 11.1
Although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of changes, modification can be carried out to these embodiments, replace without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (5)

  1. A kind of 1. low-foaming penetrating agent, it is characterised in that:The low-foaming penetrating agent includes the raw material of following parts by weight:Secondary alkyl sulphur Sour sodium 10-20 parts, fatty alcohol 3-5 parts, dioctyl sodium sulfosuccinate 10-15 parts, dimethicone 5-7 parts, hydroxylmethyl cellulose Plain sodium 5-7 parts, calcium chloride 3-5 parts, lauroylamidopropyl betaine 3-7 parts, sodium citrate 3-5 parts, deionized water 30-40 parts.
  2. A kind of 2. low-foaming penetrating agent according to claim 1, it is characterised in that:According to parts by weight, including following components: 10 parts of SAS, 3 parts of fatty alcohol, 10 parts of dioctyl sodium sulfosuccinate, 5 parts of dimethicone, hydroxymethyl cellulose 5 parts of sodium, 3 parts of calcium chloride, 3 parts of lauroylamidopropyl betaine, 3 parts of sodium citrate, 30 parts of deionized water.
  3. A kind of 3. low-foaming penetrating agent according to claim 1, it is characterised in that:According to parts by weight, including following components: 15 parts of SAS, 4 parts of fatty alcohol, 13 parts of dioctyl sodium sulfosuccinate, 6 parts of dimethicone, hydroxymethyl cellulose 6 parts of sodium, 4 parts of calcium chloride, 5 parts of lauroylamidopropyl betaine, 4 parts of sodium citrate, 35 parts of deionized water.
  4. A kind of 4. low-foaming penetrating agent according to claim 1, it is characterised in that:According to parts by weight, including following components: 20 parts of SAS, 5 parts of fatty alcohol, 15 parts of dioctyl sodium sulfosuccinate, 7 parts of dimethicone, hydroxymethyl cellulose 7 parts of sodium, 5 parts of calcium chloride, 7 parts of lauroylamidopropyl betaine, 5 parts of sodium citrate, 40 parts of deionized water.
  5. A kind of 5. preparation method using a kind of any described low-foaming penetrating agents of the claims 1-4, it is characterised in that:Tool Body step is as follows:
    Step 1, deionized water 30-40 parts are added in a kettle, and rise temperature is to 50-60 DEG C;
    Step 2, SAS 10-20 parts, fatty alcohol 3-5 parts, dioctyl sodium sulfosuccinate 10-15 parts, diformazan are added Base silicone oil 5-7 parts, 500-1000 revs/min, stir 10-20 minutes;
    Step 3,30-40 DEG C is cooled to, adds sodium cellulose glycolate 5-7 parts, lauroylamidopropyl betaine 3-7 parts, 500- 1000 revs/min, stir 20-30 minutes;
    Step 4,20-30 DEG C is cooled to, calcium chloride 3-5 parts, sodium citrate 3-5 parts is added, 500-1000 revs/min, stirs 20- 30 minutes;
    Step 5, stirring is closed down, the liquid low-foaming penetrating agent prepared;
    Step 6, stand and be cooled in stirred tank liquid low-foaming penetrating agent and be less than 20 DEG C, blowing encapsulation, finished product.
CN201710983299.0A 2017-10-20 2017-10-20 A kind of low-foaming penetrating agent and preparation method thereof Pending CN107805941A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114657290A (en) * 2022-04-01 2022-06-24 宜城成雄织造有限公司 Environment-friendly penetrating agent and preparation method thereof
CN115262247A (en) * 2022-08-24 2022-11-01 张家港市德宝化工有限公司 Polyester cotton tooling fabric and one-step dyeing process thereof

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CN105671946A (en) * 2016-02-26 2016-06-15 苏州三和开泰花线织造有限公司 Efficient environment-friendly penetrant for fabric pretreatment and preparation method thereof
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114657290A (en) * 2022-04-01 2022-06-24 宜城成雄织造有限公司 Environment-friendly penetrating agent and preparation method thereof
CN115262247A (en) * 2022-08-24 2022-11-01 张家港市德宝化工有限公司 Polyester cotton tooling fabric and one-step dyeing process thereof
CN115262247B (en) * 2022-08-24 2023-10-31 张家港市德宝化工有限公司 Polyester cotton tooling fabric and one-step dyeing process thereof

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