CN107385956A - The manufacture method of flower fabric in a kind of antiultraviolet water - Google Patents

The manufacture method of flower fabric in a kind of antiultraviolet water Download PDF

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Publication number
CN107385956A
CN107385956A CN201710780408.9A CN201710780408A CN107385956A CN 107385956 A CN107385956 A CN 107385956A CN 201710780408 A CN201710780408 A CN 201710780408A CN 107385956 A CN107385956 A CN 107385956A
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Prior art keywords
fabric
water
antiultraviolet
flower
parts
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陈茂哲
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FUJIAN FORTUNES TEXTILE PRINTING AND DYEING TECHNOLOGY Co Ltd
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FUJIAN FORTUNES TEXTILE PRINTING AND DYEING TECHNOLOGY Co Ltd
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Priority to CN201710780408.9A priority Critical patent/CN107385956A/en
Publication of CN107385956A publication Critical patent/CN107385956A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
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    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/342Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
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    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
    • D06M15/6436Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
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    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
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    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof
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    • D06P1/5264Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
    • D06P1/5292Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds containing Si-atoms
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    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
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    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
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    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
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    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/25Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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    • D06M2200/40Reduced friction resistance, lubricant properties; Sizing compositions

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  • Engineering & Computer Science (AREA)
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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Abstract

The present invention relates to a kind of manufacture method of flower fabric in antiultraviolet water, comprise the following steps:S1 piece dyeing finishings;S2 removes loose colour;S3 fabric stamps:The pattern of design is printed on basic fabric by printing machine, printing paste of swimming is imprinted on designed floating-like watermark pattern is formed on the pattern of design;The processing of S4 fabrics;S5 pads processing:Flower fabric is immersed in the padding liquid that antiultraviolet processing uses in the water that will be obtained in S4 steps, an immersing and rolling, pick-up rate >=82%, is dried at 142 148 DEG C, produces flower fabric in antiultraviolet water.The present invention has the advantages of environment-friendly, uniform color, water-fastness and ultraviolet isolation performance is good.

Description

The manufacture method of flower fabric in a kind of antiultraviolet water
Technical field
The present invention relates to fabric manufacturing technology field, and in particular to the manufacture method of flower fabric in a kind of antiultraviolet water.
Background technology
Flower fabric such as lotus flower when fully open, this stamp are exclusively used in swimming suit, Bermuda Shorts and some clothing relevant with water in water Thing and other items, such as raincoat, umbrella, waterproof cloth, towel, such Printing are more popular in the international market at present.Watermark Flower is one kind of textile color-changing printing.Color-changing printing refers to certain special material being printed on weaving using screen painting mode On product so that design on textile is suddenly hidden with the appearance such as change of ambient temperature, bright and dark light, fabric dry and wet Suddenly infinite printing technique is now changed.And water becomes a kind of printing method that the change that stamp is exactly foundation fabric dry and wet turns to condition. When textile is drying regime, there is design its surface is invisible, after fabric meets water, either yarn dyed fabric or white Design presentation is just had on fabric, after moisture evaporation is dried on fabric, design can vanish from sight again.This mistake Journey can circulate repeatedly it is infinite, it be with fabric on fiber it is flickering and produce design is presented with or without moisture A kind of raw magical dynamic effect, makes one to experience enjoyment changeable, therefore be called dynamic stamp again.
Injury of the ultraviolet outside line to human body, is paid attention to by increasing consumer.Ultraviolet in solar spectrum Not only make textile colour fading and embrittlement, can also make human body skin sunburn aging, produce melanin and color spot, more serious can also lure Canceration is sent out, endangers human health.With the enhancing of people's health consciousness, injury of the ultraviolet to human body is prevented, by more next More consumers are paid attention to.Requirement to clothing fabric also more and more higher, it is nonirritant to human body skin, there is UV resistance The effect of line.
In the prior art, the printing thin film having in water in flower fabric product is not easy to fall off, washable, cannot after washing for several times Realize that water becomes effect, some stamp feels are not soft, influence comfort level;The color and luster of Printing of swimming also is uneven, influences Coloured light.The stamp wash durability of flower fabric is poor in water, hardly possesses the effect of antiultraviolet, is routinely preparing UV resistance What is used in line fabric substantially belongs to physical isolation, and wherein injury of the superfine silica gel powder to human body is big, easily causes dust pollution, Exist in manufacturing process to human body and endanger.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of manufacturer of flower fabric in antiultraviolet water Method, solve the problems, such as that wash durability is poor, preventing ultraviolet effect is bad.
The purpose of the present invention is achieved through the following technical solutions:
The manufacture method of flower fabric in a kind of antiultraviolet water, it is characterised in that comprise the following steps:
S1 piece dyeing finishings:Fabric is put into flat cylinder, and steam is passed through in flat cylinder, desizing refining agent is subsequently added into and is moved back Refining treatment is starched, fabric is delivered in overflow dyeing machine, after the completion of cloth feeding, softening agent, stabilizer, level dyeing are added into dye bath Agent, basic dispersion dyestuff and water, dyestuff are started to warm up after having entered to 105-145 DEG C, are incubated 45-60min, are cooled to≤60 DEG C;
S2 removes loose colour:Using the combination of one or more kinds of methods in leaven washing, granite-wash, ferment granite-wash to fabric Washed, be 5.0-7.0 until washing obtained water ph value, obtain basic fabric;
S3 fabric stamps:The pattern of design is printed on basic fabric by printing machine, the printing paste that will swim is imprinted on design Pattern on form designed floating-like watermark pattern;
The processing of S4 fabrics:Complete to be dried, bakeed after stamp, water-based de- paste and sizing, obtain flower fabric in water;
S5 pads processing:Flower fabric is immersed in the padding liquid that antiultraviolet processing uses in the water that will be obtained in S4 steps In, an immersing and rolling, pick-up rate >=82%, dried at 142-148 DEG C, produce flower fabric in antiultraviolet water.
In water in the preparation process of flower fabric, piece dyeing finishing is first carried out, then be removed loose colour, fabric stamp and finished product Processing, the PH controls of obtained water will be washed when discoloration cleans in 5.0-7.0, the pH value of close printing paste of swimming, in fabric Hardly change pH value in patterning step, the printing performance for the printing paste that do not influence to swim, print the print of flower fabric in obtained water Spend difficult for drop-off, water-fastness;The material for containing ultraviolet isolation in processing in padding liquid is padded, pick-up rate is high, and what is be prepared is anti- The ultraviolet isolation effect of flower fabric is excellent in ultraviolet water, and preparation technology is simple, can industrialization degree height.
Further, the temperature of the desizing refining is 45-50 DEG C, time 4-5h, bath raio 35-45:12.
Further, the softening agent is polyethers amido silicon oil;The stabilizer is hydrogen peroxide bleaching stabilizer;The levelling agent is Dodecyl sodium sulfate or lauryl sodium sulfate;The basic dispersion dyestuff is light-colored basic disperse dyes.
Basic dispersion dyestuff forms superfine dispersion and dyed, and polyethers amido silicon oil is selected in the selection of auxiliary agent Improve the feel of fabric, addition levelling agent make it that the color uniformity of fabric is higher.
Softening agent is a kind of quiet, the coefficient of kinetic friction chemical substance that can change fiber.When changing confficient of static friction, hand Thoughts and feelings touches with smooth sense, is easy to move on fiber or fabric;It is fine between fiber and fiber when changing the coefficient of kinetic friction Structure is easy to be mutually shifted, that is, fiber or fabric it is easily deformable.The comprehensive of the two feels to be exactly soft.Polyether silicone oil, Refer to polyether-modified dimethyl silicone polymer.The poly modified polyorganosiloxane ramification such as polyethers, belong to new extraordinary organosilicon Surfactant.With characteristic of low surface tension, it is suitable for oleaginous system and the addition in solvent-free system, with alkanes oil Property material and macromolecule filming material have fabulous intersolubility.It can also disperse in water.As additive, this product has profit The performance such as wet, scattered, defoaming, emulsification, infiltration, antistatic, soft, lubrication, solubilising.
Hydrogen peroxide bleaching stabilizer be mainly used in cotton, fiber crops, synthetic cotton and its with the pre-treatment oxygen bleaching process of the product such as chemical fibre blending, Sodium metasilicate is exceeded to the stabilization of hydrogen peroxide, and " silicon dirt " for being difficult to remove will not be produced, whiteness height, feel after fabric oxygen bleaching It is soft.Also known as hydrogen peroxide stabilizer, it is a kind of white powder, the organic carboxyl acid that can be dissolved in cold water and hot water is answered with extraordinary adjuvant It is fit.It is a kind of high temperature resistant, resistance to highly basic, anti-oxidant, nontoxic new non-silicone oxidation blkeach Stabilizer, hydrogen peroxide bleaching stabilizer is still, environmental protection Type, easily biological-degradable, high temperature resistant is stable in wider pH range, has the function that scattered pollution, can be effectively increased washing effect Fruit.The complexing good to metal ions such as iron, copper, it can effectively prevent fabric from producing damage and broken hole in bleaching, with network The dispersion effect of Complexing/Dispersing Agent can be significantly enhanced by closing dispersant is applied simultaneously when, and have scale inhibition effect, advantageous installation cleaning, and Suitable for one-bath DSB method, cold pad--batch and conventional oxygen bleaching process.
Most of levelling agent is water miscible surfactant, according to levelling agent to dyestuff diffusion and the influence of concentration class. Its concentration class to dyestuff has little to no effect but the affinity to fiber is greater than affinity of the dyestuff to fiber, therefore In dyeing course, such levelling agent can be combined first with fiber, reduce dyestuff dyeing rate, but with the change of dyeing condition, dyestuff Levelling agent can be gradually replaced, anchored on fiber, this kind of levelling agent only has the function that slow dye;Secondly it is the dye level dyeing of parent It can significantly improve dye aggregation degree to agent, be more than affinity of the dyestuff to fiber to the affinity of dyestuff, contaminate it on dyestuff Preceding levelling agents are first combined aggregation of certain stabilization of generation with dyestuff, so as to reduce the diffusion rate of dyestuff and delay dye The color time.With the change of condition, dyestuff progressively disengages levelling agent, is combined with fiber, but now levelling agent still has to dyestuff Certain affinity, dyestuff can also be left behind from fiber for the fabric of not level dyeing, upper dye to the place of lighter color, therefore Not only there is this kind of levelling agent slow dye to act on, and with shifting dye effect.
Further, the parts by weight of the softening agent, stabilizer, levelling agent, basic dispersion dyestuff and water are as follows:
The fabric that weight part ratio dizzy dye within this range obtains is variegated few in uniform color, is adapted to subsequent treatment.
Further, the printing paste of swimming is the copolymer of polyacrylate high polymer and auxiliary agent.Watermark Flower slurry belongs to environment-friendly water-soluble printed slurry, and contamination hazard is small, has good cross-linking properties and filming performance, through printing For fabric after processing without any flower pattern, fabric just shows flower pattern after drenching, and has well durable washable after printing Property, film forming is of light color, does not influence coloured light.In the present invention, printing paste of swimming can be used and had purchased from the profound rich fine chemistry industry in Guangdong The printing paste QH-5607 that swims of limit company.
Further, the weight ratio of the polyacrylate high polymer and auxiliary agent is 1000:2.5-4.0.The auxiliary agent For organic silicon-fluorine compound.The organic silicon-fluorine compound is at least one of Trimethlyfluorosilane or triphenylfluorosilane.
Wherein auxiliary agent is organic silicon-fluorine compound, from the Trimethlyfluorosilane in organic silicon-fluorine compound and triphenyl fluorine Silane, the relatively simple organ of luorosilane of structure is belonged to, the product obtained when being copolymerized with polyacrylate high polymer is uniform Du Genggao, otherness are small.
Further, the padding liquid consists of the following parts by weight:
In padding liquid from Nano grade titanium dioxide and silver powder as physically-isolated main component, amino silicone breast and P-aminobenzoic acid has the effect of certain chemical isolation and lubrication, and the antiultraviolet for not only making to be prepared has good purple Outer isolation effect, moreover it is possible to lubricate cloth, make the sense of touch of cloth moist.
Further, the preparation method of the padding liquid is:
1) nanometer powder is handled:Nano titanium oxide and nano-silver powder is well mixed stand-by as mixture A;
2) mixed processing:P-aminobenzoic acid and mixture A are added in distilled water and stirred, is warming up to 35-40 DEG C, Add amino silicone breast to stir, stand defoaming, be cooled to 20-25 DEG C and remember padding liquid.
The preparation process of padding liquid is simple, first mixes nanometer powder in closed container in preparation, Ran Houzai Somewhat heating prepares liquid and is well mixed.Wherein nanometer powder is prepared in closed container, and the harm to human body is small; Superfine silica gel powder is not contained, is not easily caused occupational disease;Temperature is relatively low, and mixing can be but speeded almost without influence to the physicochemical property of material Speed, faster obtain well mixed padding liquid.
Further, the temperature of the drying is 95-105 DEG C, and the time of drying is 35-45s.
Further, the temperature of the baking is 150-165 DEG C, and the time of baking is 110-130s.
Further, the bath raio of the water elution paste is 1:9-11;The time of the water elution paste is 18-22min;It is described The raw material of water elution paste is degreaser SF-500:Water=1.8-2.2:1000.
Further, the temperature of the sizing is 158-162 DEG C, shaping time 58-62s.
Dry, bakee in S4 steps, flower fabric in the water that water elution is pasted and the temperature and time of sizing is prepared Stamp part has better durable wash durability, film forming of the temperature dried, bakee and shaped to stamp part Energy and tolerance will not have a negative impact.
The beneficial effects of the invention are as follows:
1. in water flower fabric preparation process in, first carry out piece dyeing finishing, then be removed loose colour, fabric stamp and into Product processing, the PH controls of obtained water will be washed when discoloration cleans in 5.0-7.0, the pH value of close printing paste of swimming, in face Hardly change pH value in material patterning step, the printing performance for the printing paste that do not influence to swim, print flower fabric in obtained water Stamp is difficult for drop-off, water-fastness;The material for containing ultraviolet isolation in processing in padding liquid is padded, pick-up rate is high, is prepared The ultraviolet isolation effect of flower fabric is excellent in antiultraviolet water, and preparation technology is simple, can industrialization degree height;
2. printing paste of swimming belongs to environment-friendly water-soluble printed slurry, contamination hazard is small, has good cross-linking properties And filming performance, for the fabric after being handled through printing without any flower pattern, fabric just shows flower pattern after drenching, and has after printing There is good durable washability, film forming is of light color, does not influence coloured light;
3. auxiliary agent is organic silicon-fluorine compound, from the Trimethlyfluorosilane in organic silicon-fluorine compound and triphenyl fluorine silicon Alkane, the relatively simple organ of luorosilane of structure is belonged to, the product uniformity obtained when being copolymerized with polyacrylate high polymer Higher, otherness is small;
4. in padding liquid from Nano grade titanium dioxide and silver powder as physically-isolated main component, be respectively provided with good Good ultraviolet resistance, silver powder also have good bactericidal effect, it may have certain the effect of extending fabric usage time;Ammonia Base silicon breast and p-aminobenzoic acid have the effect of certain chemical isolation and lubrication, and the antiultraviolet for not only making to be prepared has Good ultraviolet isolation effect, moreover it is possible to lubricate cloth, make the sense of touch of cloth moist;
5. nanometer powder is prepared in closed container, the harm to human body is small;Superfine silica gel powder is not contained, is not easily caused occupation Disease;Temperature is relatively low, can but speed mixing rate almost without influence to the physicochemical property of material, faster obtain well mixed padding liquid.
Embodiment
Technical scheme is described in further detail with reference to specific embodiment, but protection scope of the present invention is not It is confined to as described below.
The manufacture method of flower fabric, comprises the following steps in a kind of antiultraviolet water:
S1 piece dyeing finishings:Fabric is put into flat cylinder, and steam is passed through in flat cylinder, desizing refining agent is subsequently added into and is moved back Refining treatment is starched, fabric is delivered in overflow dyeing machine, after the completion of cloth feeding, softening agent, stabilizer, level dyeing are added into dye bath Agent, basic dispersion dyestuff and water, dyestuff are started to warm up after having entered to 105-145 DEG C, are incubated 45-60min, are cooled to≤60 DEG C;
S2 removes loose colour:Using the combination of one or more kinds of methods in leaven washing, granite-wash, ferment granite-wash to fabric Washed, be 5.0-7.0 until washing obtained water ph value, obtain basic fabric;
S3 fabric stamps:The pattern of design is printed on basic fabric by printing machine, the printing paste that will swim is imprinted on design Pattern on form designed floating-like watermark pattern;
The processing of S4 fabrics:Complete to be dried, bakeed after stamp, water-based de- paste and sizing, obtain flower fabric in water;
S5 pads processing:Flower fabric is immersed in the padding liquid that antiultraviolet processing uses in the water that will be obtained in S4 steps In, an immersing and rolling, pick-up rate >=82%, dried at 142-148 DEG C, produce flower fabric in antiultraviolet water.
Specifically, the temperature of the desizing refining is 45-50 DEG C, time 4-5h, bath raio 35-45:12.
Specifically, the softening agent is polyethers amido silicon oil;The stabilizer is hydrogen peroxide bleaching stabilizer;The levelling agent is ten Dialkyl sulfonates or lauryl sodium sulfate;The basic dispersion dyestuff is light-colored basic disperse dyes.
Specifically, the parts by weight of the softening agent, stabilizer, levelling agent, basic dispersion dyestuff and water are as follows:
Specifically, the printing paste of swimming is the copolymer of polyacrylate high polymer and auxiliary agent.
Specifically, the weight ratio of the polyacrylate high polymer and auxiliary agent is 1000:2.5-4.0.
Specifically, the auxiliary agent is organic silicon-fluorine compound.
Specifically, the organic silicon-fluorine compound is at least one of Trimethlyfluorosilane or triphenylfluorosilane.
Specifically, the padding liquid consists of the following parts by weight:
Specifically, the preparation method of the padding liquid is:
1) nanometer powder is handled:Nano titanium oxide and nano-silver powder is well mixed stand-by as mixture A;
2) mixed processing:P-aminobenzoic acid and mixture A are added in distilled water and stirred, is warming up to 35-40 DEG C, Add amino silicone breast to stir, stand defoaming, be cooled to 20-25 DEG C and remember padding liquid.
Specifically, the temperature of the drying is 95-105 DEG C, and the time of drying is 35-45s.
Specifically, the temperature of the baking is 150-165 DEG C, and the time of baking is 110-130s.
Specifically, the bath raio of the water elution paste is 1:9-11;The time of the water elution paste is 18-22min;The water The raw material of elution paste is degreaser SF-500:Water=1.8-2.2:1000.
Specifically, the temperature of the sizing is 158-162 DEG C, shaping time 58-62s.
Specific experimental data is as shown in table 1 in embodiment 1- embodiments 6:
Specific experimental data in the embodiment 1- embodiments 6 of table 1
Embodiment 1- embodiments 4 are that fabric is spent in the antiultraviolet water that technical solution of the present invention is prepared, in embodiment 5 Swim the auxiliary agent that do not contain of printing paste, and the content of embodiment 5 and padding liquid in embodiment 6 and be not belonging to technical solution of the present invention In scope, embodiment 5- embodiments 6 are contrast test.
Flower fabric is detected to obtain data as shown in table 2 in the water that embodiment 1- embodiments 6 are prepared:
The detection data of flower fabric in the water that the embodiment 1- embodiments 6 of table 2 are prepared
Table 2
Can be drawn from the data of table 2 in the water that embodiment 1- embodiments 4 are prepared the water-fastness of flower fabric and Tear-resistant intensity is all higher than contrast test embodiment 5 and embodiment 6;Printing paste of wherein being swum in embodiment 5 does not add auxiliary agent system The stamp part coloured light difference and the easily damaged color for appearance of embodiment 1- embodiments 4 of flower pattern of flower fabric in standby obtained water Evenly, coloured light is more preferable in pool;The ultraviolet resistance of embodiment 1- embodiments 4 is substantially better than embodiment 5- embodiments 6, wherein in fact Apply that example 4 is different from the proportioning for differing only in padding liquid of embodiment 6, the difference of embodiment 4 and embodiment 5 be auxiliary agent with The proportioning of padding liquid, it can thus be appreciated that the ultraviolet resistance of flower fabric is better than it in the preparation-obtained antiultraviolet water of the present invention He matches.
Described above is only the preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein Form, the exclusion to other embodiment is not to be taken as, and can be used for various other combinations, modification and environment, and can be at this In the text contemplated scope, it is modified by the technology or knowledge of above-mentioned teaching or association area.And those skilled in the art are entered Capable change and change does not depart from the spirit and scope of the present invention, then all should be in the protection domain of appended claims of the present invention It is interior.

Claims (9)

1. the manufacture method of flower fabric in a kind of antiultraviolet water, it is characterised in that comprise the following steps:
S1 piece dyeing finishings:Fabric is put into flat cylinder, and steam is passed through in flat cylinder, desizing refining agent is subsequently added into and carries out desizing essence Refining is handled, and fabric is delivered in overflow dyeing machine, and after the completion of cloth feeding, softening agent, stabilizer, levelling agent, alkali are added into dye bath Property disperse dyes and water, dyestuff started to warm up after having entered to 105-145 DEG C, be incubated 45-60min, be cooled to≤60 DEG C;
S2 removes loose colour:Fabric is carried out using the combination of one or more kinds of methods in leaven washing, granite-wash, ferment granite-wash Washing, it is 5.0-7.0 until washing obtained water PH values, obtains basic fabric;
S3 fabric stamps:The pattern of design is printed on basic fabric by printing machine, printing paste of swimming is imprinted on to the figure of design Designed floating-like watermark pattern is formed in case;
The processing of S4 fabrics:Complete to be dried, bakeed after stamp, water-based de- paste and sizing, obtain flower fabric in water;
S5 pads processing:Flower fabric is immersed in the padding liquid that antiultraviolet processing uses in the water that will be obtained in S4 steps, and one Immersing and rolling, pick-up rate >=82%, dried at 142-148 DEG C, produce flower fabric in antiultraviolet water.
2. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 1, it is characterised in that the softness Agent is polyethers amido silicon oil;The stabilizer is hydrogen peroxide bleaching stabilizer;The levelling agent is dodecyl sodium sulfate or dodecyl Sodium sulphate;The basic dispersion dyestuff is light-colored basic disperse dyes.
3. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 1 or 2, it is characterised in that described Softening agent, stabilizer, levelling agent, the parts by weight of basic dispersion dyestuff and water are as follows:
Softening agent 10-15 parts;
Stabilizer 8-12 parts;
Levelling agent 4-6 parts;
Basic dispersion dyestuff 8-15 parts;
Distilled water 800-900 parts.
4. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 1, it is characterised in that described to swim Printing paste is the copolymer of polyacrylate high polymer and auxiliary agent.
5. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 4, it is characterised in that described poly- third The weight of olefin(e) acid esters high polymer and auxiliary agent ratio is 1000:2.5-4.0.
6. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 4 or 5, it is characterised in that described Auxiliary agent is organic silicon-fluorine compound.
7. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 6, it is characterised in that described organic Fluorine compound is at least one of Trimethlyfluorosilane or triphenylfluorosilane.
8. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 1, it is characterised in that described to pad Liquid consists of the following parts by weight:
Nano titanium oxide 5-9 parts;
Nano-silver powder 4-8 parts;
P-aminobenzoic acid 12-20 parts;
Amino silicone breast 8-15 parts;
Distilled water 35-50 parts.
9. the manufacture method of flower fabric in a kind of antiultraviolet water according to claim 8, it is characterised in that described to pad The preparation method of liquid is:
1)Nanometer powder processing:Nano titanium oxide and nano-silver powder is well mixed stand-by as mixture A;
2)Mixed processing:P-aminobenzoic acid and mixture A are added in distilled water and stirred, is warming up to 35-40 DEG C, is added Amino silicone breast stirs, and stands defoaming, is cooled to 20-25 DEG C and remembers padding liquid.
CN201710780408.9A 2017-09-01 2017-09-01 The manufacture method of flower fabric in a kind of antiultraviolet water Pending CN107385956A (en)

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Publication number Priority date Publication date Assignee Title
CN108193407A (en) * 2018-01-09 2018-06-22 嘉兴涌锦服饰有限公司 A kind of processing method of uvioresistant fabrics
CN108936880A (en) * 2018-07-17 2018-12-07 稳健医疗用品股份有限公司 A kind of mask and its manufacturing process
CN109466129A (en) * 2018-10-12 2019-03-15 江苏熙成新材料科技有限公司 A kind of cotton synthetic fibre fiber cloth with antiultraviolet
CN110172846A (en) * 2019-06-06 2019-08-27 苏州璟思纺织科技有限公司 Nylon fabric wet transfer printing padding liquid and its preparation method
CN110629361A (en) * 2019-09-29 2019-12-31 陕西锦澜科技有限公司 Moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric and preparation method thereof

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CN104233783A (en) * 2014-09-09 2014-12-24 杭州天堂伞业集团有限公司 Ultraviolet-proof finishing method of fabric for umbrellas
CN106835752A (en) * 2017-01-02 2017-06-13 柯金芳 A kind of antiultraviolet is swum printed fabric and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104233783A (en) * 2014-09-09 2014-12-24 杭州天堂伞业集团有限公司 Ultraviolet-proof finishing method of fabric for umbrellas
CN106835752A (en) * 2017-01-02 2017-06-13 柯金芳 A kind of antiultraviolet is swum printed fabric and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108193407A (en) * 2018-01-09 2018-06-22 嘉兴涌锦服饰有限公司 A kind of processing method of uvioresistant fabrics
CN108708111A (en) * 2018-01-09 2018-10-26 嘉兴涌锦服饰有限公司 The processing method of improved uvioresistant fabrics
CN108936880A (en) * 2018-07-17 2018-12-07 稳健医疗用品股份有限公司 A kind of mask and its manufacturing process
CN109466129A (en) * 2018-10-12 2019-03-15 江苏熙成新材料科技有限公司 A kind of cotton synthetic fibre fiber cloth with antiultraviolet
CN110172846A (en) * 2019-06-06 2019-08-27 苏州璟思纺织科技有限公司 Nylon fabric wet transfer printing padding liquid and its preparation method
CN110629361A (en) * 2019-09-29 2019-12-31 陕西锦澜科技有限公司 Moisture-absorbing, sweat-releasing, anti-static and anti-ultraviolet cotton-nylon blended fabric and preparation method thereof

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Application publication date: 20171124